This application claims priority to Chinese Patent Application No. 202111042430.6 filed with the China National Intellectual Property Administration (CNIPA) on Sep. 7, 2021, the disclosure of which is incorporated herein by reference in its entirety.
The present application relates to a technical field of lasers, for example, to a vertical cavity surface emitting laser and a manufacturing method thereof.
A vertical cavity surface emitting laser (VCSEL) is developed on the basis of GaAs semiconductor materials, has the advantages of small volume, circular output spot, single longitudinal mode output, low threshold current, low price, easy integration into large area array, etc., and is widely used in the applications of optical communication, optical interconnection, high power optical storage, and other fields such as industrial cutting, ranging, light detection and ranging (Lidar), and medical.
The VCSEL has attracted much attention for its excellent performance and wide application. To achieve low manufacturing cost requires high production efficiency, so the method used for manufacturing is strictly controllable. However, the manufacturing method of the VCSEL in related art has the conditions that the average total technique process time is long, and the metal consumption is large, and the manufacturing cost is high.
Embodiments of the present application provide a VCSEL and a manufacturing method thereof.
In a first aspect, an embodiment of the present application provides a manufacturing method of the VCSEL, and the method includes steps described below.
A substrate is provided, and a semiconductor epitaxial structure is formed on a side of the substrate, where the semiconductor epitaxial structure includes an N-type ohmic contact layer, an N-type DBR layer, a quantum well layer, a P-type DBR layer, and a P-type ohmic contact layer which are sequentially formed on the substrate.
A trench is etched on the semiconductor epitaxial structure to form a mesa structure, where a portion of the N-type ohmic contact layer is exposed from the trench.
A current confinement layer is formed in the mesa structure, where the current confinement layer 30 has an oxide aperture for forming a emitter region of the mesa structure.
An N-type ohmic metal layer is formed on a side of the portion of the N-type ohmic contact layer away from the substrate and exposed from the trench, where a distance between the N-type ohmic metal layer and a sidewall of the trench is greater than zero.
A first passivation layer is formed on a side of the semiconductor epitaxial structure away from the substrate and on a sidewall and a bottom of the trench; and in a same etching process, a first passivation layer located on a side of the N-type ohmic metal layer away from the substrate is etched to form a first via on a side of the N-type ohmic metal layer away from the substrate to expose the N-type ohmic metal layer, and a first passivation layer located on a side of the P-type ohmic contact layer away from the substrate is etched in the mesa structure to form a second via on a side of the P-type ohmic contact layer away from the substrate in the mesa structure to expose the P-type ohmic contact layer.
In a same metal deposition process, a first electrode layer is formed in the first via, and a P-type ohmic metal layer and a second electrode layer are sequentially formed in the second via.
In a second aspect, an embodiment of the present application provides a VCSEL, and the VCSEL includes a substrate, a semiconductor epitaxial structure located on a side of the substrate, an N-type ohmic metal layer, a first passivation layer, a first electrode layer, a P-type ohmic metal layer and a second electrode layer.
The semiconductor epitaxial structure includes an N-type ohmic contact layer, an N-type DBR layer, a quantum well layer, a P-type DBR layer, and a P-type ohmic contact layer sequentially laminated on the substrate, the semiconductor epitaxial structure includes a trench and a mesa structure surrounded by the trench, a portion of the N-type ohmic contact layer is exposed from the trench, the mesa structure includes a current confinement layer, and the current confinement layer has an oxide aperture for forming a emitter region of the mesa structure.
The N-type ohmic metal layer is located on a bottom of the trench, and a distance between the N-type ohmic metal layer and a sidewall of the trench is greater than zero.
The first passivation layer is located on a side of the semiconductor epitaxial structure away from the substrate, and on a sidewall and a bottom of the trench, the first passivation layer includes a first via and a second via, the N-type ohmic metal layer is exposed from the first via, the P-type ohmic contact layer in the mesa structure is exposed from the second via, and the first via and the second via are formed in a same etching process.
The first electrode layer is in contact with the N-type ohmic metal layer exposed from the first via, the P-type ohmic metal layer is in contact with the P-type ohmic contact layer exposed from the second via, the second electrode layer is located on a side of the P-type ohmic metal layer away from the P-type ohmic contact layer, and the first electrode layer, the P-type ohmic metal layer and the second electrode layer are formed in a same metal deposition process.
The present application is described hereinafter in conjunction with drawings and embodiments.
In related art, a VCSEL is developed on the basis of GaAs semiconductor materials, which is different from other light sources such as light emitting diode (LED) and laser diode (LD). The VCSEL has the advantages of small volume, circular output spot, single longitudinal mode output, low threshold current, low price, easy integration into large area array, etc., and is widely used in the applications of optical communication, optical interconnection, high power optical storage, and other fields such as industrial cutting, ranging, light detection and ranging (Lidar), and medical. The VCSEL has attracted much attention for its excellent performance and wide application. To achieve low manufacturing cost requires high production efficiency, so the method used for manufacturing is strictly controllable. In related art, in the process of manufacturing the VCSEL, a P-type ohmic metal layer and an N-type ohmic metal layer are successively formed on opposite sides of the substrate or on the same side of the substrate by two times metal deposition process, and the process time is long, and a plurality of photomasks and more metal consumptions are required. In addition, in related art, in the case where the P-type ohmic metal layer and the N-type ohmic metal layer are located on the same side of the substrate, after the passivation layer is formed on the sides of the P-type ohmic metal layer and the N-type ohmic metal layer far away from the substrate, an via is provided on the P-type ohmic metal layer and an via is provided on the N-type ohmic metal layer by different times of etching process, so as to manufacture pads on the P-type ohmic metal layer and the N-type ohmic metal layer, which also has a long process time and a complex manufacturing method. According to statistics, it is found that the number of the main process types is greater than 11 steps, the number of photomasks is greater than 7, the number of metallization times is greater than 5, and the average total process cycle time is greater than 3 weeks, which are the basic condition of the main process. As can be seen, there is an urgent need to reduce time and cost in the field.
In view of the above, an embodiment of the present application provides a manufacturing method of the VCSEL.
In S110, a substrate is provided, and a semiconductor epitaxial structure is formed on a side of the substrate, where the semiconductor epitaxial structure includes an N-type ohmic contact layer, an N-type DBR layer, a quantum well layer, a P-type DBR layer, and a P-type ohmic contact layer which are sequentially formed on the substrate.
For example,
The semiconductor epitaxial structure 20 is formed on a side of the substrate 10, where the semiconductor epitaxial structure 20 includes the N-type ohmic contact layer 21, the N-type distributed Bragg reflection (DBR) layer 22, the quantum well layer 23, the P-type DBR layer 24, and the P-type ohmic contact layer 25 which are sequentially formed on the substrate. The N-type ohmic contact layer 21, the N-type DBR layer 22, the quantum well layer 23, the P-type DBR layer 24 and the P-type ohmic contact layer 25 may be formed by means of chemical vapor deposition. The N-type ohmic contact layer 21 is a current diffusion layer, the material of the N-type ohmic contact layer 21 may be a highly doped GaAs material, and the highly doped GaAs material has good conductivity. Similarly, the P-type ohmic contact layer 25 is a current diffusion layer, the material of the P-type ohmic contact layer 25 may be a highly doped GaAs material to facilitate forming ohmic contact with a subsequently deposited P-type ohmic metal layer. The N-type DBR layer 22 is formed by laminating two materials having different refractive indices of the aluminum gallium arsenic material layer and the gallium arsenide material layer, or by laminating two materials having different refractive indices of the aluminum gallium arsenic material layer having a high aluminum component and the aluminum gallium arsenic material layer having a low aluminum component. The quantum well layer 23 is an active layer, including laminated quantum well composite structures, which is formed by materials of GaAs and AlGaAs, or InGaAs and AlGaAs, and the quantum well layer 23 is used for converting electric energy into light energy. The P-type DBR layer 24 is formed by laminating two materials having different refractive indices of the aluminum gallium arsenic material layer and the gallium arsenide material layer, or by laminating two materials having different refractive indices of the aluminum gallium arsenic material layer having the high aluminum component and the aluminum gallium arsenic material layer having the low aluminum component. The N-type DBR layer 22 and the P-type DBR layer 24 are used for enhancing the reflection of light generated by the active layer in the middle, and then emitted from the surface of the P-type DBR layer 24 to form laser beam.
In some embodiments, the N-type DBR layer 22 and the P-type DBR layer 24 each include a series of alternating layers having different refractive index materials, where an effective optical thickness (the thickness of the each alternating layer multiplied by refractive index of the each alternating layer) of each alternating layer in the series of alternating layers is an odd integer multiple of one quarter of operating wavelength of the VCSEL, i.e., the effective optical thickness of each alternating layer is one quarter of an odd integer multiple of operating wavelength of the VCSEL. In some embodiments, the N-type DBR layer 22 and the P-type DBR layer 24 may also be formed by other materials.
In some embodiments, the N-type ohmic contact layer 21 may be formed between the substrate 10 and the N-type DBR layer 22, that is, the N-type ohmic contact layer 21 is first grown on the substrate 10, and then the N-type DBR layer 22 is grown on the N-type ohmic contact layer 21. The N-type ohmic contact layer 21 may be formed among the N-type DBR layers 22, that is, a portion of the N-type DBR layer 22 is first grown on the substrate 10, then the N-type ohmic contact layer 21 is grown on the grown portion of the N-type DBR layer 22, and then another portion of the N-type DBR layer 22 is grown on the N-type ohmic contact layer 21.
In S120, a trench is etched on the semiconductor epitaxial structure to form a mesa structure, where a portion of the N-type ohmic contact layer is exposed from the trench.
For example,
In S130, a current confinement layer is formed in the mesa structure, where the current confinement layer has an oxide aperture for forming a light-emitting region of the mesa structure.
For example,
For another example, the current confinement layer 30 is formed in the high aluminum-containing oxidation layer on the quantum well layer 23.
In S140, an N-type ohmic metal layer is formed on a side of the portion of the N-type ohmic contact layer away from the substrate and exposed from the trench, where a distance between the N-type ohmic metal layer and a sidewall of the trench is greater than zero.
For example,
The ohmic metal layer can also be referred to as the ohmic contact layer, and the ohmic metal layer and the ohmic contact layer are distinguished only for distinguishing different objects.
In S150, a first passivation layer is formed on a side of the semiconductor epitaxial structure away from the substrate and on a sidewall and a bottom of the trench; and in a same etching process, a first passivation layer located on a side of the N-type ohmic metal layer away from the substrate is etched to form a first via on a side of the N-type ohmic metal layer away from the substrate to expose the N-type ohmic metal layer, and a first passivation layer located on a side of the P-type ohmic contact layer away from the substrate in the mesa structure is etched to form a second via on a side of the P-type ohmic contact layer away from the substrate in the mesa structure to expose the P-type ohmic contact layer.
For example,
In S160, in a same metal deposition process, a first electrode layer is formed in the first via, and a P-type ohmic metal layer and a second electrode layer are sequentially formed in the second via.
For example,
According to the manufacturing method of the VCSEL provided in the embodiment of the present application, in the same etching process, the first passivation layer located on the side of the N-type ohmic metal layer away from the substrate is etched to form the first via on the side of the N-type ohmic metal layer away from the substrate to expose the N-type ohmic metal layer, and the first passivation layer located on the side of the P-type ohmic contact layer away from the substrate is etched in the mesa structure 202 to form the second via on the side of the P-type ohmic contact layer away from the substrate in the mesa structure 202 to expose the P-type ohmic contact layer, so that the number of times of via etching process is reduced, and in the same metal deposition process, the first electrode layer is formed in the first via, and the P-type ohmic metal layer and the second electrode layer are sequentially formed in the second via, thus reducing the number of times of metal deposition process and reducing the metal consumptions, further improving the manufacturing efficiency of the laser, shortening the manufacturing cycle time of the laser, and reducing the manufacturing cost of the laser.
In an embodiment, a layer formed by metal deposition in the second via B can simultaneously function as a P-type ohmic contact and an electrode, that is, the P-type ohmic metal layer and the second electrode layer can be completed at one time or are the same layer.
In an embodiment, a second passivation layer is further provided between the first passivation layer on the side of the semiconductor epitaxial structure away from the substrate, and the semiconductor epitaxial structure, before the semiconductor epitaxial structure is etched to form the trench, the method further includes: forming the second passivation layer on the side of the semiconductor epitaxial structure away from the substrate, and etching a second passivation layer located in a region where the trench is located to expose a semiconductor epitaxial structure to be etched.
For example,
In an embodiment, the number of mesa structure 202 is one, and forming the N-type ohmic metal layer 40 on the side of the portion of the N-type ohmic contact layer 21 away from the substrate 10 and exposed from the trench 201 includes: forming the N-type ohmic metal layer 40 on the side of the N-type ohmic contact layer 21 away from the substrate 10 along a direction in which the trench 201 surrounds one mesa structure 202.
For example,
In an embodiment, the number of mesa structures 202 is above one, and forming the N-type ohmic metal layer 40 on the side of the portion of the N-type ohmic contact layer 21 away from the substrate 10 and exposed from the trench 201 includes: forming the N-type ohmic metal layer 40 shared by a plurality of mesa structures 202 in trench 201 on same sides of the plurality of mesa structures 202.
For example, referring to
For example,
Referring to
In an embodiment, in
In another embodiment, referring to
Referring to
The semiconductor epitaxial structure 20 includes an N-type ohmic contact layer 21, an N-type DBR layer 22, a quantum well layer 23, a P-type DBR layer 24, and a P-type ohmic contact layer 25 sequentially laminated on the substrate 10, the semiconductor epitaxial structure 20 includes a trench 201 and a mesa structure 202 surrounded by the trench 201, a portion of the N-type ohmic contact layer 21 is exposed from the trench 201, the mesa structure 202 includes a current confinement layer 30, and the current confinement layer 30 has an oxide aperture for forming a emitter region Q of the mesa structure 202.
The N-type ohmic metal layer 40 is located on a bottom of the trench 201, and a distance between the N-type ohmic metal layer 40 and a sidewall of the trench 201 is greater than zero.
The first passivation layer 50 is located on a side of the semiconductor epitaxial structure 20 away from the substrate 10 and on a sidewall and a bottom of the trench 201, the first passivation layer 50 includes a first via A and a second via B, the N-type ohmic metal layer 40 is exposed from the first via A, the P-type ohmic contact layer 25 in the mesa structure 202 is exposed from the second via B, and the first via A and the second via B are formed in a same etching process.
The first electrode layer 60 is in contact with the N-type ohmic metal layer 40 exposed from the first via A, the P-type ohmic metal layer is in contact with the P-type ohmic contact layer 25 exposed from the second via B, the second electrode layer 70 is located on a side of the P-type ohmic metal layer away from the P-type ohmic contact layer 25, and the N-type electrode layer (the first electrode layer 60), the P-type ohmic metal layer and the P-type electrode layer (the second electrode layer 70) are formed in a same metal deposition process.
In the VCSEL provided in the embodiment of the present application, the first passivation layer 50 includes the first via A and the second via B, the N-type ohmic metal layer 40 is exposed from the first via A, the P-type ohmic contact layer 25 in the mesa structure 202 is exposed from the second via B, and the first via A and the second via B are formed in the same etching process; and in the same etching process, the first passivation layer 50 located on the side of the N-type ohmic metal layer 40 away from the substrate 10 is etched to form the first via A on the side of the N-type ohmic metal layer 40 away from the substrate 10 to expose the N-type ohmic metal layer 40, and the first passivation layer 50 located on the side of the P-type ohmic contact layer 25 away from the substrate 10 is etched in the mesa structure 202 to form the second via B on the side of the P-type ohmic contact layer 25 away from the substrate 10 in the mesa structure 202 to expose the P-type ohmic contact layer 25, thus reducing the number of times of via etching process. In addition, the N-type electrode layer, the P-type ohmic metal layer and the P-type electrode layer in the VCSEL are formed in the same metal deposition process. In the same metal deposition process, the first electrode layer 60 is formed in the first via A, and the P-type ohmic metal layer and the second electrode layer 70 are sequentially formed in the second via B, thereby reducing the number of times of metal deposition process and the amount of metal consumptions, thereby improving the manufacturing efficiency of the laser, shortening the manufacturing duration of the laser and reducing the manufacturing cost of the laser.
In an embodiment, the VCSEL further includes a second passivation layer 80, where the second passivation layer 80 is located between the semiconductor epitaxial structure 20 and the first passivation layer 50, and the second passivation layer 80 covers a surface of the side of the semiconductor epitaxial structure 20 away from the substrate 10.
In an embodiment, the N-type DBR layer and P-type DBR layer are respectively formed by laminating two materials having different refractive indices of the aluminum gallium arsenic material layer and the gallium arsenide material layer, or by laminating two materials having different refractive indices of the aluminum gallium arsenic material layer having the high aluminum component and the aluminum gallium arsenic material layer having the low aluminum component.
In an embodiment, the number of mesa structures 202 is above one, and the N-type ohmic metal layer is an N-type ohmic metal layer 40 shared by a plurality of mesa structures 202, and is located in the trench 201 on same sides of the plurality of mesa structures 202.
In an embodiment, the N-type ohmic metal layer may be located in the trench 201 on the plurality of sides of the mesa structure 202.
The embodiment of the present application further provides a VCSEL, and the VCSEL includes a substrate 10 and a semiconductor epitaxial structure 20 located on a side of the substrate 10, an N-type ohmic metal layer 40, a first electrode layer 60, a P-type ohmic metal layer and a second electrode layer 70.
The semiconductor epitaxial structure 20 includes an N-type ohmic contact layer 21, an N-type DBR layer 22, a quantum well layer 23, a P-type DBR layer 24, and a P-type ohmic contact layer 25 sequentially laminated on the substrate 10, the semiconductor epitaxial structure 20 includes a trench 201 and a mesa structure 202 surrounded by the trench 201, a portion of the N-type ohmic contact layer 21 is exposed from the trench 201, the mesa structure 202 includes a current confinement layer 30, and the current confinement layer 30 has an oxide aperture for forming a emitter region Q of the mesa structure 202.
The N-type ohmic metal layer 40 is located on a bottom of the trench 201, and a distance between the N-type ohmic metal layer 40 and a sidewall of the trench 201 is greater than zero.
The first electrode layer 60 is in contact with the N-type ohmic metal layer 40 exposed from the first via A, the P-type ohmic metal layer is in contact with the P-type ohmic contact layer 25 exposed from the second via B, the P-type ohmic metal layer and the second electrode layer 70 may be the same layer, and the N-type electrode layer, the P-type ohmic metal layer and the P-type electrode layer are formed in a same metal deposition process.
It will be understood by those skilled in the art that the present application is not limited to the specific embodiments described herein. Those skilled in the art can make various modifications, readjustments and substitutions without departing from the scope of the present application. The present application is not limited to the above embodiments but may include more other equivalent embodiments without departing from the present inventive concept.
Number | Date | Country | Kind |
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202111042430.6 | Sep 2021 | CN | national |
Filing Document | Filing Date | Country | Kind |
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PCT/CN2022/075870 | 2/10/2022 | WO |