Patent Grant
10807033
This application is a 371 of International PCT Application No. PCT/FR2016/052649, filed Oct. 13, 2016, which claims priority to French Patent Application No. 1559847, filed Oct. 16, 2015, the entire contents of which are incorporated herein by reference.
The present invention relates to a device for purifying a gas comprising two adsorbers and a particular arrangement of pipework.
Separation devices of this type are essentially used in pressure swing adsorption (PSA) or temperature swing adsorption (TSA) technologies for the production, from a gaseous mixture, of a gaseous constituent of this mixture, in particular of a constituent of air, oxygen or nitrogen, or for the purification of a gaseous mixture, in particular feed air of a cryogenic air separation unit, also for the production of a constituent of air, oxygen and/or nitrogen and/or argon and generally use at least one of the adsorbents selected from the group comprising zeolites, activated carbon, alumina or silica gels. Examples of these technologies are described in particular in documents U.S. Pat. No. 5,223,004, EP 0 092 153, U.S. Pat. Nos. 3,338,030 or 5,137,548.
Purifications, or a purification device, in air separation units (ASUs) make it possible to mainly remove water and CO2 from the air before entry into the cryogenic cold box.
An assembly of valves and pipework enables the transit of the air (to be purified) and of the impure nitrogen (which is used for the regeneration of the purification cylinders) and that connects the lower and upper parts of the cylinders to the various fluid circuits.
Generally, the assembly of valves and pipework is laid “flat” on the floor in front of or between the purification cylinders and the cross-sectional area of this assembly occupies a very large floor space in relation to the cross-sectional areas of the purification cylinders, a floor space factor ranging from 1.5 to 3.5 for ASUs respectively having a capacity of 1000 t/day O2 to 5000 t/day O2.
In small to medium capacity (<1000 t/day O2) air separation units, this assembly may be mounted on a metal frame, except for the purification cylinders and the coupling pipework, in order to limit the work on site. The metal frame comprising the various elements supported thereby is generally referred to as a “skid”.
The layout of the pipework is complex especially due to the difference in levels of the interfaces of the assembly of valves and pipework with the other piece of equipment (adsorbers, exchangers, etc.) and these were large amount of pipes and bends.
Indeed, the distances CC1; DD1; EF; F1G1 are proportional to the height of the cylinders and of the exchangers relative to the assembly of valves and pipework which is itself on the floor. By way of example, for a device treating an air flow rate of around 300,000 Nm3/h, these distances represent respectively 18 m for CC1 and F1G1, 19 m for DD1 and 21 m for EF for a pipework diameter of 40 inches, i.e. 1 m.
This arrangement leads to a large amount of pipes and bends linked to this layout which consequently leads to pressure drops in the process. 0.5 mbar per m of additional pipework and 2.5 mbar per additional bend can be considered.
Starting from here, one problem that is faced is that of providing a purification device that has a smaller amount of pipework.
One solution to the present invention is a gas purification device comprising two adsorbers 1 and 2, a gas compressor 4, a heater 5, a set of exchangers 6, a first assembly of pipework and valves 10 and a second assembly of pipework and valves 11, characterized in that the first assembly of pipework and valves 10 is laid on the floor or on a metal structure and the second assembly of pipework and valves 11 is located high up along the same vertical axis as the first assembly of pipework and valves 10.
The expression “located high up” is understood to mean that the center of gravity of the second assembly of pipework and valves is located approximately (i.e. to within plus or minus 15%) in the same horizontal axis as the product gas outlet point of at least one adsorber.
For a further understanding of the nature and objects for the present invention, reference should be made to the following detailed description, taken in conjunction with the accompanying drawings, in which like elements are given the same or analogous reference numbers and wherein:
Depending on the case, the location device according to the invention may have one or other of the following characteristics:
the second assembly of pipework and valves 11 is supported with the aid of a set of supports resting at least partially on the first assembly of pipework and valves 10;
the set of supports is a metal structure;
the second assembly of pipework and valves 11 is supported directly by the first assembly of pipework and valves 10;
the first and second assemblies of pipework and valves 10 and 11 rest on a metal frame enabling the handling thereof;
the second assembly of pipework and valves 11 is supported with the aid of a set of supports resting at least partially on one of the two adsorbers;
in each pipework-valve assembly, the diameter of the pipework is less than 1200 mm, preferably less than 1000 mm, more preferentially still less than 800 mm;
the heater 5 is supported by the second assembly of pipework and valves 11;
the valves of the first and second assemblies of pipework and valves 10 and 11 are positioned on the facade or on the roof;
the first and second assemblies of pipework and valves 10 and 11 comprise one or more pieces of equipment chosen from check valves, measurement instruments, and pressure regulators, with said pieces of equipment positioned on the facade or on the roof;
the set of exchangers 6 is a cold box of cryogenic exchangers.
For the piece of equipment positioned “on the facade” (check valves, valves, measurement instruments, pressure regulators, etc.), it is understood that the pieces of equipment are positioned facing the user so that he/she can easily gain access thereto. For the piece of equipment positioned “on the roof”, it is understood that the pieces of equipment are positioned facing upwards so that they can be accessible with a lifting appliance (crane, lift truck, etc.).
The objective of the present invention is to divide the assembly of valves and pipework into two sub-assemblies of reduced size that are installed one above the other and that thus reduce the distances CC1; DD1; EF; F1G1 when referring to
The present invention will now be described in greater detail with the aid of
The purification device comprises two adsorbers 1 and 2, two superimposed sub-assemblies of valves and pipework 10 and 11, where 10 is laid on the floor, and 11 supported by means of a set of supports resting on 10. This purification device is connected to a gas compressor 4, a regeneration heater 5, a set of exchangers 6.
Pipework 15 external to the pipework-valve sub-assemblies 10 and 11 may be attached to the device and optionally be supported by one or more elements of the device. The assembly of this external pipework 15 will in general be carried out on the construction site.
The device according to the invention enables the reduction in the installation cost of the purification device by reducing the overall amount of length of pipework.
By way of example, for a system treating an air flow rate of 300,000 Nm3/h, the reduction in length of pipework is of the order of 40% and the reduction in the amount of welds is of the order of 15%.
Moreover, dividing the assembly of valves and pipework 3 into two makes it possible, for the same capacity, to reduce the size of the 2 sub-assemblies of valves and pipework 10 and 11 and to thus envisage the prefabrication thereof on a skid with the advantage of limiting the constraints linked to the transport size.
Furthermore, the device according to the invention makes it possible to significantly reduce the installation times by limiting the construction activities on site to only the connections of the pipework 15 owing to its high degree of prefabrication on a skid.
Finally, as can be seen in
By way of example, for a system treating an air flow rate of 300,000 Nm3/h, the floor area and the civil engineering slab for installing all the pieces of equipment of the purification device is reduced by the order of 51%. The floor space factor of the two sub-assemblies of valves and pipework in relation to the sizes of these purification cylinders is 1.85.
Finally, another subject of the present invention is the use of a purification device according to the invention for producing oxygen from an air flow. In this case, the adsorbers of the purification device will have the main role of removing water and CO2 from the air flow before entry into the cold box of cryogenic exchangers.
Another subject of the invention is the use of the purification device according to the invention for producing carbon monoxide from synthesis gas.
It will be understood that many additional changes in the details, materials, steps and arrangement of parts, which have been herein described in order to explain the nature of the invention, may be made by those skilled in the art within the principle and scope of the invention as expressed in the appended claims. Thus, the present invention is not intended to be limited to the specific embodiments in the examples given above.
| Number | Date | Country | Kind |
|---|---|---|---|
| 15 59847 | Oct 2015 | FR | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/FR2016/052649 | 10/13/2016 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2017/064427 | 4/20/2017 | WO | A |
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| Number | Date | Country |
|---|---|---|
| 204 637 913 | Sep 2015 | CN |
| 0 092 153 | Oct 1983 | EP |
| 1313495 | May 1987 | SU |
| WO 2010 094844 | Aug 2010 | WO |
| Entry |
|---|
| International Search Report for corresponding PCT/FR2016/052649, dated Dec. 9, 2016. |
| Number | Date | Country | |
|---|---|---|---|
| 20180296965 A1 | Oct 2018 | US |
