1. Field of the Invention
This invention relates to vertical transistors, and more particularly, to an organic vertical transistor having a vertical structure.
2. Description of Related Art
With the rapid development of technology, lighter, thinner, portable and flexible displays, such as electronic paper, have drawn people's attention. Accordingly, many well-known companies invest a lot of money in the development of the displays. An organic thin-film vertical transistor (OTFT) includes organic molecules and is applied to electronic products. The organic thin-film vertical transistor may be fabricated in a low temperature environment, and still function normally even if the panel bends. Such an application speeds up the realization of a flexible electronic product (e.g., a display).
An organic thin-film vertical transistor has various advantages, such as low carrier channel length, which allows it to be applied to high-frequency components, and low working bias voltage.
In order to reduce a distance between the source electrode and the drain electrode, N. Stutzmann et al. (2003) Science 299, 1881, R. Parashkov et al. (2003) Appl. Phys. Lett. 82, 4579 and R. Parashkov et al. (2004) Appl. Phys. Lett. 85, 5751 disclose separating the source electrode from the drain electrode with an insulation layer, so as to control the distance between the source electrode and the drain electrode. The method uses a mechanical or chemical process to form grooves on the insulation layer, and then form a carrier transmission channel in the grooves. However, the method includes complicated steps, and the components fabricated thereby do not perform well.
M. S. Meruvia et al. (2004) Appl. Phys. Lett. 84, 3978, W. J. da Silva et al. (2008) Appl. Phys. Lett. 93, 053301, and M. Yi et al. (2008) Appl. Phys. Lett. 92, 243312 disclose using silicon as a collector electrode. Y. C. Chao et al. (2005) Appl. Phys. Lett. 87, 253508, and Y. C. Chao et al. (2008) Appl. Phys. Lett. 92, 093310 disclose a component that does not have a high enough on/off ratio.
Y. Yang et al. (1994) Nature 372, 344, J. McElvain, et al. (1997) J. Appl. Phys. 81, 6468, and U.S. Pat. No. 5,563,424 disclose separating three electrode with two organic molecule layers. However, the method needs to perform a chemical process on the second electrode, which complicates the fabrication steps and limits the selection of organic molecule materials.
Y. C. Chao et al. (2006) Appl. Phys. Lett. 87, 223505 and Y. C. Chao et al. (2008) Organic Electronics 9, 310 disclose a method of fabricating a vertical transistor by using polystyrene balls as a mask. However, the polystyrene balls are disposed on a semiconductor polymer layer, and the semiconductor polymer layer has to have its characteristics unaffected, which limits the selection of the semiconductor polymer layer material. Moreover, no insulation layer is formed between a gate electrode and the other two electrodes, which likely induces the leakage current.
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However, persons skilled in the art are unable to increase an on/off ratio of the vertical transistor through the above thickness teaching, and obtain a better performance.
Therefore, it is an urgent issue to overcome the problems of an organic thin-film vertical transistor having a vertical structure in the prior art.
In view of the above-mentioned problems of the prior art, the present invention provides, in a first aspect, a vertical transistor that includes a substrate, a first electrode formed on the substrate, a first insulation layer formed on the first electrode, with a portion of the first electrode exposed from the first insulation layer, and having a thickness greater than 50 nm and no more than 300 nm, a grid electrode formed on the first insulation layer, a semiconductor layer formed on the first electrode, and a second electrode formed on the semiconductor layer.
In the aforesaid vertical transistor, the semiconductor layer is further formed on the grid electrode, and the second electrode is positioned not in correspondence with the grid electrode.
The present invention provides, in a second aspect, a vertical transistor that includes a substrate, a first electrode formed on the substrate with a portion of a surface of the substrate exposed from the first electrode, a first insulation layer formed on the exposed portion of the surface of the substrate and higher than first electrode, a grid electrode formed on the first insulation layer, a semiconductor layer formed on the grid electrode and the first electrode, and a second electrode formed on the semiconductor layer.
The present invention provides, in a third aspect, a vertical transistor that includes a substrate, a first insulation layer formed on the substrate and having a plurality of grooves formed thereon, a first electrode formed in the grooves and having a height less than a depth of the grooves, a grid electrode formed on the first insulation layer and being positioned not in correspondence with the first electrode, a semiconductor layer formed on the grid electrode and the first electrode, and a second electrode formed on the semiconductor layer.
The aforesaid vertical transistors may further include a second insulation layer formed between the grid electrode and the semiconductor layer, and the first insulation layer and the second insulation layer may include the same material.
The present invention provides, in a fourth aspect, a method of fabricating a vertical transistor including the steps of providing substrate, forming on the substrate a first electrode and a first insulation layer sequentially, forming the patterned grid electrode on the first insulation layer, removing a portion of the first insulation layer on which the grid electrode is not formed by using the grid electrode as a mask so as to expose a portion of the first electrode, covering the grid electrode and the first electrode with a semiconductor layer, and forming a second electrode on the semiconductor layer.
In the fourth aspect of the method, the step of forming the patterned grid electrode includes forming on the first insulation layer a plurality of balls spaced apart at intervals, forming a metal layer on the intervals at which the balls are spaced apart on a portion of the first insulation layer, and removing the balls so as to allow the metal layer to be the grid electrode.
In the fourth aspect of the method, the step of forming the patterned grid electrode includes forming on the first insulation layer a resist layer having a plurality of holes for exposing a portion of the first insulation layer, forming a metal layer on the exposed portion of the first insulation layer, and removing the resist layer, so as to allow the metal layer to be the grid electrode.
In the fourth aspect of the method, the step of forming the patterned grid electrode includes forming a metal layer on the first insulation layer, forming on the metal layer a resist layer having a plurality of holes for exposing a portion of the metal layer, removing the exposed portion of the metal layer, and removing the resist layer, so as to allow the remaining metal layer to be the grid electrode.
The aforesaid method further includes the step of forming a second insulation layer on the grid electrode.
The present invention provides, in a fifth aspect, a method of fabricating a vertical transistor including the steps of providing a substrate, forming a first electrode on the substrate, forming on the first electrode a first insulation layer, a metal layer, and a second insulation layer, pattering the first insulation layer, the metal layer, and the second insulation layer to allow the metal layer to form a grid electrode and expose a portion of the first electrode, forming on the exposed portion of the first electrode a semiconductor layer that is at a position higher than the grid electrode, and forming on the semiconductor layer a second electrode that is positioned not in correspondence with the grid electrode.
The present invention provides, in a sixth aspect, a method of fabricating a vertical transistor including the steps of providing a substrate, forming a first electrode on the substrate, forming on the first electrode a resist layer having a plurality of holes for exposing a portion of the first electrode, forming in the holes a first insulation layer and a metal layer sequentially, removing the resist layer to allow the metal layer to act as a grid electrode, forming a semiconductor layer on the grid electrode and the first electrode, and forming a second electrode on the semiconductor layer.
In the sixth aspect, the method further includes prior to forming the first insulation layer, removing the exposed portion of the first electrode so as to expose a portion of a surface of the substrate, wherein the first insulation layer and the metal layer are formed sequentially on the exposed portion of the surface of the substrate, and the first insulation layer is at a position higher than the first electrode.
In the sixth aspect, the method further includes prior to removing the resist layer, forming a second insulation layer on the metal layer.
The present invention provides, in a seventh aspect, a method of fabricating a vertical transistor including the steps of providing a substrate, forming on the substrate a first insulation layer having a plurality of grooves, forming a metal layer on the first insulation layer, wherein the metal layer in the grooves serves as a first electrode, the metal layer not in the grooves serves as a grid electrode, and the first electrode has a height less than a depth of the grooves, forming a semiconductor layer on the first electrode and the grid electrode, and forming a second electrode on the semiconductor layer.
In the seventh aspect, the method further includes prior to forming the semiconductor layer, forming a second insulation layer on the grid electrode.
The invention can be more fully understood by reading the following detailed description of the preferred embodiments, with reference made to the accompanying drawings, wherein:
FIGS. 2A-2F″ are schematic diagrams illustrating a method of fabricating a vertical transistor of a first embodiment according to the present invention, wherein FIGS. 2F′ and 2F″ show other variants;
FIGS. 3A-3D′ are schematic diagrams illustrating a method of fabricating a vertical transistor of a second embodiment according to the present invention, wherein FIGS. 3A′-3D′ are schematic diagrams illustrating a modified method of fabricating a vertical transistor;
The following illustrative embodiments are provided to illustrate the disclosure of the present invention, these and other advantages and effects can be apparently understood by those in the art after reading the disclosure of this specification. The present invention can also be performed or applied by other different embodiments. The details of the specification may be on the basis of different points and applications, and numerous modifications and variations can be devised without departing from the spirit of the present invention.
The present invention provides a vertical transistor having a thickness that controls a distance of electrodes. The vertical transistor of the present invention may be applied to various industries, such as semiconductor photo-electric industry, flexible electronic application industry, plastic IC industry, illuminating apparatus industry, flat panel display industry and TV industry. Particularly, the vertical transistor of the present invention may be applied to a full-color organic light-emitting display, back-light module of a cellular phone, flexible electronic product, flexible IC, car panel and flat panel TV.
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In the aforesaid method, the formation of the first electrode 21 and the first insulation layer 22 are conventional methods, and thus further description hereby are omitted. When forming the first insulation layer 22 on the substrate 20, the PVP polymer may comprise poly melamine-co-formaldehyde methylated that works as a cross-linking agent.
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As shown in FIG. 2F′, a second insulation layer 25′ is formed by another process. After the metal layer 24a is formed, the second insulation layer 25′ is formed on the metal layer 24a by an evaporation process, to reduce the leakage current between the collector and the grid electrode 24, and then the balls 23 are removed. Alternatively, as shown in FIG. 2F″ a second insulation layer 25″ may be electroplated and formed on the grid electrode 24 after the balls 23 are removed.
The second insulation layer 25″ that is formed by an electroplating process, the second insulation layer 25′ that is formed by the evaporated process, and the oxide (Al2O3) are different materials. However, the second insulation layers 25, 25′ and 25″ may be formed on demands. For example, the first insulation layer 22 and the second insulation layers 25, 25′ and 25″ may include the same material.
In the present invention, the balls 23 are used as a mask to form a space for the grid electrode 24 to be disposed in without a hole forming process that uses a lithography etching technique.
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FIG. 3A′-3D′ show the use of the resist layer. As shown in FIG. 3A′, the metal layer 24a is formed on the first insulation layer 22, and then a resist layer 23′ is formed on the metal layer 24a, wherein the resist layer 23′ has a plurality of holes 230 for exposing a portion of the metal layer 24a. As shown in FIG. 3B′, the metal layer 24a in the holes 230 is etched and removed, to form the grid electrode 24. As shown in FIG. 3C′, the resist layer 23′ is removed, and the pattern process is completed. As shown in FIG. 3D′, a portion of the first insulation layer 22 on which the grid electrode 24 is not formed is removed by oxide plasma, so as to expose a portion of the first electrode 21 and form the second insulation layer 25 on the grid electrode 24. The semiconductor layer 26 and the second electrode 27 are then formed sequentially.
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Please refer to FIGS. 4A′-4D′, which illustrate a variant of a method of fabricating a vertical transistor 4 of the third embodiment according to the present invention. As shown in FIG. 4A′, the substrate 40 is provided, the first electrode 41 is formed on the substrate 40, and a pattern process is then performed, in which the resist layer 43 is formed on the first electrode 41, and the resist layer 43 has a plurality of holes 430 for exposing a portion of the first electrode 41.
As shown in FIG. 4B′, the first insulation layer 42, the metal layer 44a and the second insulation layer 45 are formed in the holes 430 sequentially.
As shown in FIG. 4C′, the resist layer 43 is removed, and the pattern process is completed, so as to form the grid electrode 44. As shown in FIG. 4D′, the semiconductor layer 46′ and the second electrode 47′ are formed sequentially.
The first, second and third embodiments provide the vertical transistor 2, 4, which includes the substrate 20, 40, the first electrode 21, 41 formed on the substrate 20, 40, the first insulation layer 22, 42 formed on the first electrode 21, 41 and with a portion of the first electrode 21, 41 exposed from the first insulation layer 22,42, the grid electrode 24, 44 formed on the first insulation layer 22, 42, the semiconductor layer 26, 46′ formed on the first electrode 21, 41 and the grid electrode 24, 44, and the second electrode 27, 47′ formed on the semiconductor layer 21, 41.
The vertical transistor 2, 4 may further include the second insulation layer 25, 45. In the embodiments shown in
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According to the fourth embodiment, the present invention also provides a vertical transistor 5, which includes the substrate 50, the first electrode 51 formed on the substrate 50 with a portion of a surface of the substrate 50 exposed from the first electrode 51, the first insulation layer 52 formed on the exposed portion of the surface of the substrate 50 and being greater in thickness than the first electrode 51, the grid electrode 54 formed on the first insulation layer 52, the semiconductor layer 56 formed on the grid electrode 54 and the first electrode 51, and the second electrode 57 formed on the semiconductor layer 56.
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According to the fifth embodiment, the present invention further provides a vertical transistor 6, which includes the substrate 60, the first insulation layer 62 formed on the substrate 60 and having a plurality of grooves 620, the first electrode 61 formed in the grooves 620 and having a height less than a depth of the grooves 620, the grid electrode 64 formed on the first insulation layer 62 and positioned not in correspondence with the first electrode 61, the semiconductor layer 66 formed on the grid electrode 64 and the first electrode 61, and the second electrode 67 formed on the semiconductor layer 66.
In the embodiment shown in FIG. 6C′, the vertical transistor 6 further includes the second insulation layer 65 formed between the grid electrode 64 and the semiconductor layer 66.
In sum, with the design of the insulation layer, the vertical transistor of the present invention has a low operation voltage (less than two volts) and a high on/off ratio (about 104, which is obtained by dividing a collector current density when the grid electrode voltage is −1V by another collector current density when the grid electrode voltage is 2.3V), and has an even higher on/off ratio through the use of a thicker PVP. For example, when a PVP having a thickness being 210 nm is used, components have an on/off ratio as high as 3×105. In the vertical transistor shown in
Since the present invention only needs to fabricate a single semiconductor layer, the present invention reduces the fabrication cost and decreases the distance of electrodes, as compared with the prior art which needs to fabricate two semiconductor layers.
The foregoing descriptions of the detailed embodiments are only illustrated to disclose the features and functions of the present invention and not restrictive of the scope of the present invention. It should be understood to those in the art that all modifications and variations according to the spirit and principle in the disclosure of the present invention should fall within the scope of the appended claims.