1. Field of the Invention
This invention relates to devices that generate vibrational energy and to control of that energy. The invention further relates to the use of controlled vibrational energy, especially to the use of controlled vibrational energy to mitigate fouling in heat transfer components (including but not limited to heat exchangers, in particular heat exchangers) used in refineries and petrochemical plants.
2. Discussion of Related Art
Vibration is used in a variety of processes, including manufacturing, particulate flow control, packaging, and testing, for example. Vibration has also been used to prevent particles from settling or accumulating on certain surfaces. One such application is directed to mitigating fouling of equipment due to the build up of material on surfaces that interferes with normal operations of the equipment.
Fouling is generally defined as the accumulation of unwanted materials on the surfaces of processing equipment. In petroleum processing, fouling is the accumulation of unwanted hydrocarbon-based deposits on heat exchanger surfaces. It has been recognized as a nearly universal problem in design and operation of refining and petrochemical processing systems, and affects the operation of equipment in two ways. First, the fouling layer has a low thermal conductivity. This increases the resistance to heat transfer and reduces the effectiveness of the heat exchangers—thus increasing temperature in the system. Second, as deposition occurs, the cross-sectional area is reduced, which causes an increase in pressure drop across the apparatus and creates inefficient pressure and flow in the heat exchanger.
Fouling in heat transfer components (including heat exchangers) associated with petroleum type streams can result from a number of mechanisms including chemical reactions, corrosion, deposit of insoluble materials, and deposit of materials made insoluble by the temperature difference between the fluid and heat exchange wall.
One of the more common root causes of rapid fouling, in particular, is the formation of coke that occurs when crude oil asphaltenes are overexposed to heater tube surface temperatures. The liquids on the other side of the heat transfer component are much hotter than the whole crude oils and result in relatively high surface or skin temperatures. The asphaltenes can precipitate from the oil and adhere to these hot surfaces. Prolonged exposure to such surface temperatures, especially in a late-train exchanger, allows for the thermal degradation of the asphaltenes to coke. The coke then acts as an insulator and is responsible for heat transfer efficiency losses in the heat exchanger by preventing the surface from heating the oil passing through the unit. To return the refinery to more profitable levels, the fouled heat exchangers need to be cleaned, which typically requires removal from service, as discussed below.
Heat exchanger in-tube fouling costs petroleum refineries hundreds of millions of dollars each year due to lost efficiencies, throughput, and additional energy consumption. With the increased cost of energy, heat exchanger fouling has a greater impact on process profitability. Petroleum refineries and petrochemical plants also suffer high operating costs due to cleaning required as a result of fouling that occurs during thermal processing of whole crude oils, blends and fractions in heat transfer equipment. While many types of refinery equipment are affected by fouling, cost estimates have shown that the majority of profit losses occur due to the fouling of whole crude oils and blends in pre-heat train exchangers.
Heat exchanger fouling forces refineries to frequently employ costly shutdowns for the cleaning process. Currently, most refineries practice off-line cleaning of heat exchanger tube bundles by bringing the heat exchanger out of service to perform chemical or mechanical cleaning. The cleaning can be based on scheduled time or usage or on actual monitored fouling conditions. Such conditions can be determined by evaluating the loss of heat exchange efficiency. However, off-line cleaning interrupts service. This can be particularly burdensome for small refineries because there will be periods of non-production.
Mitigating or possibly eliminating fouling of heat transfer components can result in huge cost savings in energy reduction alone. Reduction in fouling leads to energy savings, higher capacity, reduction in maintenance, lower cleaning expenses, and an improvement in overall availability of the equipment.
Attempts have been made to use vibrational forces to reduce fouling in heat exchangers. The basis for using vibration is to provide a mechanism by which motion is induced in the liquid in the tubes to disrupt the formation of deposits on the surface of the heat exchanger. It is difficult, however, to efficiently generate and transmit the vibrational energy to the surface of the heat exchanger in a controlled manner.
A vibrational system has been developed by the assignee of this application, ExxonMobil Research and Engineering Company, that utilizes a mechanical force applied to a fixed mounting element that supports heat exchanger tubes for liquid flow to induce a vibration in the tubes that causes shear motion in the liquid flowing adjacent to the tubes to reduce fouling of the tubes. The system is disclosed in co-pending application U.S. Ser. No. 11/436,802 entitled “Mitigation of In-Tube Fouling in Heat Exchangers Using Controlled Mechanical Vibration” filed May 19, 2006. The contents of that application are incorporated herein by reference.
Other methods of generating vibration include using electromagnetic devices or piezo-electric shakers, which would allow a greater degree of control of frequency and amplitude. However, these types of devices pose a number of problems in refinery settings. They are high in cost, low in reliability in harsh environments, and can raise safety concerns due to the high electric power needed to drive these devices.
An alternative would be a pneumatic vibrator, which is lower in cost, more reliable and safe. Pneumatic vibrators per se are well known. Typically, they operate by generating vibration due to centrifugal force of either rotary ball motion or rotation of an unbalanced turbine when driven by compressed air or gas. The frequency and amplitude of vibration usually increase with the pressure and flow. However, the problem with pneumatic vibrators is that it is difficult to control the frequency and amplitude of such devices. It is particularly difficult to control the frequency and amplitude independently of each other.
There is a need to develop additional methods for reducing in-tube fouling, particularly methods that can enhance control of the energy used to reduce fouling. There is also a need to design pneumatic vibration generation systems that can be more closely controlled, particularly devices in which the frequency and amplitude can be independently controlled.
Aspects of embodiments of the invention relate to a process in which the amplitude and frequency of vibrational energy can be controlled.
Aspects of embodiments of the invention also relate to a process for controlling vibration imparted to equipment, such as a heat exchanger assembly to mitigate fouling.
Another aspect of embodiments of the invention relates to providing a process that can be implemented in an existing system, such as a refinery.
An additional aspect of embodiments of the invention relates to practicing the process of mitigating fouling while a heat exchanger is operational.
The invention is directed to a method of controlling energy output from a pneumatic vibrator comprising producing vibrational energy with a pneumatic vibrator that has a pressurized fluid inlet and an actuator that responds to the pressurized fluid to generate vibrational energy, wherein the flow of the pressurized fluid is adjustable to control the amplitude of the vibrational energy. The process includes modifying the vibrational energy with a resonator that responds to the vibrational energy with a resonance frequency, wherein the resonator comprises a housing having a predetermined resonance frequency and a frequency adjustment member by which a stiffness of the housing is adjustable to control the frequency of the vibrational energy output from the resonator. The method can further include transmitting the modified vibrational energy to apply a controlled mechanical force to equipment, such as a heat exchanger.
The invention is also directed to a process for reducing fouling in a heat exchanger, comprising providing a heat exchanger with a heat exchange surface adjacent a flow of liquid and generating a pneumatic force to induce a vibration in the heat exchanger that causes shear motion in the liquid flowing adjacent to the heat exchange surface to reduce fouling of the heat exchanger. The process includes controlling the frequency of the generated vibration by using a mechanical resonator having a resonance frequency and a range of frequency control, including adjusting the frequency of the mechanical resonator within the range. The process further includes controlling the amplitude of the generated vibration independently from controlling the frequency of vibration. The process can be performed on-line in a refining system.
The invention is also directed to a pneumatic vibrator assembly comprising a pneumatic vibrator that generates a vibrational force and a tunable resonator coupled to the pneumatic vibrator to modify the vibrational force generated by the pneumatic vibrator. The resonator includes a housing having a resonance frequency and a frequency adjustor coupled to the housing to adjust a stiffness of the housing to change the resonance frequency of the resonator. The assembly can be combined with a heat exchanger or a refining operation.
These and other aspects of the invention will become apparent when taken in conjunction with the detailed description and appended drawings.
The invention will now be described in conjunction with the accompanying drawings in which:
In the drawings, like reference numerals indicate corresponding parts in the different figures.
This invention is directed to a method of generating controlled vibrational energy. In particular, the method relates to controlling the amplitude and frequency of vibrational energy independently of each other. The exemplary application discussed herein is the generation of controlled vibrational energy to assist with mitigating fouling of equipment, especially heat transfer components (e.g., heat exchangers) and more particularly heat exchangers used in refining processes. Accordingly, aspects of the invention are directed to a method of mitigating fouling in heat exchangers, in general, and the devices for practicing the method. In a preferred use, the method and devices are applied to heat transfer components used in refining processes, such as in refineries or petrochemical processing plants. The process may be used in heat transfer components while the heat transfer component is on-line and in use.
Of course, it is possible to apply the invention to other processing facilities and heat exchangers, particularly those that are susceptible to fouling in a similar manner as experienced during refining processes and are inconvenient to take off-line for repair and cleaning. It is also contemplated that the control process and devices disclosed herein can be used in a variety of applications, not limited to heat exchangers or refining facilities, where controlled vibration is desired. Other types of equipment that could be used with this invention include, without limitation, fire heaters, equipment that experiences sedimentary and/or deposition fouling, industrial mixers and separators, and dry material handlers, such as fine particle hoppers. It will be appreciated by those of skill in the art that the invention can be broadly applied.
Heat exchange with crude oil involves two important fouling mechanisms: chemical reaction and the deposition of insoluble materials. In both instances, the reduction of the viscous sub-layer (or boundary layer) close to the wall can mitigate the fouling rate. This concept is applied in the process according to this invention.
In the case of chemical reaction, the high temperature at the surface of the heat transfer wall activates the molecules to form precursors for the fouling residue. If these precursors are not swept out of the relatively stagnant wall region, they will associate together and deposit on the wall. A reduction of the boundary layer will reduce the thickness of the stagnant region and hence reduce the amount of precursors available to form a fouling residue. So, one way to prevent adherence is to disrupt the film layer at the surface to reduce the exposure time at the high surface temperature. In accordance with this invention, the process includes introducing energy into the system to cause a disruption in the film layer.
The invention can be applied to any type of equipment that experiences fouling, especially all types of heat exchange devices. For example, many refineries use shell-tube type heat exchangers in which a bundle of individual tubes are supported by a sheet flange and are retained within a shell. The wall surfaces of the tubes, including both the inside and the outside surfaces, are susceptible to fouling or the accumulation of unwanted hydrocarbon based deposits. It will be recognized by those of ordinary skill in the heat exchanger art that while a shell-tube exchanger is described herein as an exemplary embodiment, the invention can be applied to any heat exchanger surface in various types of known heat exchanger devices. Accordingly, the invention should not be limited to shell-type exchangers. This invention can be used to generate vibrations in any type of heat exchange surface or in the adjacent liquids flowing past a heat exchange surface.
In summary in accordance with this invention, energy is provided to a heat exchanger system to mitigate fouling in a controlled manner. Preferably, the energy is supplied with a pneumatic vibrator, and independent control of the frequency and amplitude of the vibration is provided. The pneumatic vibrator is coupled to a resonator that can lock the resonance frequency to a fixed frequency within a frequency range, while the fluid pressure supplied to the vibrator can be varied to change the amplitude. The stiffness of the resonator is adjustable so that the frequency of the resonant vibrations can be adjusted over a broad range.
Referring to
The resonator 14 is formed by a housing 30. The design of the housing provides a normal resonance frequency and a frequency range of control. The factors affecting the resonance frequency include the selection of material, dimensions, and geometric configuration. The design of the housing can be based on a numerical method, such as finite element analysis, or on an empirical method or with a combination of both. The design is determined based on the desired frequency range of control depending on the particular application for the vibrator.
As seen in the embodiment of
As seen in
The resonance frequency of the resonator 14 can be changed two ways. For any given position of the rod 42 along the slot 38, the stiffness of the resonator can be adjusted by the torque applied to the locking nut 44. This control is limited to a small frequency band. For larger frequency control, the position of the rod 42 measured by the distance L from the end wall 36 can be changed. As L increases, the resonator 14 becomes stiffer and produces a higher resonance frequency and higher vibration frequency transmitted from the vibrator 12.
In operation, for each given application, a desirable frequency range is determined, and the mechanical resonator is designed with material properties and dimensions that will produce a normal resonance frequency with a frequency range of control suitable for the desired application. The normal frequency of the mechanical resonator largely depends on the design of the housing 30. The selection of the dimensions and the material of the housing 30 can be accomplished either through numerical methods such as a finite element method, an empirical method or a combined method to meet the requirement of a normal frequency and frequency range of control. The position of the stiffening rod 42 and torque applied to the locking nut 44 are then adjusted to produce a vibration with the desired frequency within the range. Once the frequency is fixed, the compressed fluid pressure is adjusted to generate the desired vibration amplitude. So, vibrations having different frequencies and different amplitudes can be produced using the same resonator.
The resonator 14 may have different designs depending on the desired application and range. For example, a resonator 50 is shown in
Each rod 70, 72 has an end with an annular shoulder 74, 76 and a threaded end 78 and 80. The shoulder 74, 76 is slidably retained in the groove 64 by the ledge 66. The shoulder 74, 76 can pass through the access opening 68 for insertion or removal. Locking nuts 82, 84, or any suitable retainer, are secured to the ends 78, 80, respectively to secure the rods 70, 72 in place by clamping against the housing 52. The ledge 66 ensures that the rods 70, 72 remain in place, but can be dispensed with if desired. Similarly, such a ledge can be used in any of the other embodiments of resonators disclosed herein.
In operation, the resonator 50 operates in a similar manner as resonator 14, with the vibrator 12 coupled to the resonator and providing vibrations that can be varied in amplitude by fluid pressure. The resonance frequency of resonator 50 is adjusted by positioning the rods 70 and 72 at selected locations with the distance L between them controlling the stiffness of the resonator 50 and then fine tuning the frequency by adjusting the torque on the nuts 82 and 84.
When applied to equipment that is susceptible to fouling, vibration generated in accordance with this invention will considerably reduce the extent of fouling. With the proper vibration frequency, the thickness of the oscillating fluid can be made sufficiently small so that the fluid within the sub-laminar boundary layer, otherwise stagnant without shear waves, will be forced to move relative to the wall surface. The shear waves will also exert a shear force on any particles on the heat exchange surface to tear the particle from the surface if the shear force is strong enough. Thus, the cleaning effect of shear waves induced by vibration is highly effective.
It may also be desirable to induce a repetitive impact vibration rather than continuous sinusoidal vibration. The advantage of an impact vibration is the generation of higher harmonics, which can be desirable in certain applications. To produce a repetitive impact vibration, a stopper mechanism can be added to the resonator. For example, as seen in
In another variation, a stopper mechanism is mounted between the pneumatic vibrator and resonator, as shown in
To use the vibrator system of this invention, the pneumatic vibrator with the resonator is mounted on a structure, such as a heat exchanger or a support for a heat exchanger, to induce vibrations in the structure. The system could also be mounted to generate acoustics, such as being mounted on a diaphragm to generate waves in the air or in a liquid that would convey acoustical vibrations to the assembly.
Selection of the precise mounting location, direction, and number of the vibrator assemblies and control of the frequency and the amplitude of the output vibration can be determined based on the system parameters. Ideally, the vibration will be controlled so that sufficient energy is generated to mitigate fouling mechanisms, while keeping the displacement caused by the vibration small enough to avoid damage to the heat exchange structure. The addition of a vibrator assembly can be accomplished by coupling the system to an existing heat exchanger or can be installed at the initial manufacture, and actuation and control of the vibrator system can be practiced while the exchanger is in place and on-line. It is even possible to install the system while the heat exchanger is in service. Fouling can be reduced without modifying the heat exchanger or changing the flow or thermal conditions of the bulk flow.
This type of vibration device can be used continuously or intermittently. Such operation can still realize anti-fouling benefits. For example, the device may be actuated periodically based on a predetermined schedule or may be actuated when it is determined that fouling is occurring.
This invention can be used in combination with other fouling mitigation devices and processes. For example, it has been found that treating the surface of heat exchangers can reduce fouling. To enhance the effectiveness of such surface treatments, the vibration device disclosed herein can be used in conjunction with surface treatment. It has also been found that particular types of crude oils and certain crude oil blends have different fouling tendencies. The device disclosed herein can be used when certain crude oils are being processed in order to mitigate the tendencies of these types of oil to foul the system.
Various modifications can be made in the invention as described herein, and many different embodiments of the device and method can be made while remaining within the spirit and scope of the invention as defined in the claims without departing from such spirit and scope. It is intended that all matter contained in the accompanying specification shall be interpreted as illustrative only and not in a limiting sense.
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