The disclosure relates to a voltage source generator, more particular to a voltage source generator with vertical multi-junction (VMJ) cells.
High voltage electrostatic fields (HVEF) have found a wide range of applications in different areas such as plant growth regulation, food sterilization, and disease prevention. The HVEF system generally works at kilovolts (kV) levels, which are voltage levels that are not available from small- or medium-sized conventional energy sources. Therefore, the HVEF system needs a power source that can supply kilovolts to generate the electrostatic fields that are needed for these applications. However, the use of the conventional kV-level power sources causes the production cost of the HVEF system to become high.
Vertical multi-junction (VMJ) cell is a solar cell device which has a small feature size and allows output voltages higher than conventional single junction cells. Typically a 1 cm×1 cm VMJ cell can generate a voltage of no less than 25 volts under one sun illumination whereas conventional single junction cells can only generate a few volts at best. Nevertheless, generating a kV-level voltage is still challenging to modern VMJ cells lacking high-efficiency optical designs.
In view of the foregoing, it is greatly desired to develop a voltage source generator using VMJ cells which may generate a kV-level voltage and meet small-sized and low-cost demands.
Aspects of the present disclosure are best understood from the following detailed description when read with the accompanying figures. It is emphasized that, in accordance with the standard practice in the industry, various features are not drawn to scale. In fact, the dimensions of the various features may be arbitrarily increased or reduced for clarity of discussion.
a illustrates a side view of a VMJ cell in accordance with some embodiments of the present disclosure.
b illustrates a partial enlarged view of a VMJ cell in accordance with some embodiments of the present disclosure.
It is to be understood that the following disclosure provides many different embodiments or examples, for implementing different features of various embodiments. Specific examples of components and arrangements are described below to simplify the present disclosure. The present disclosure may, however, be embodied in many different forms and should not be construed as being limited to the embodiments set forth herein; rather, these embodiments are provided so that this description will be thorough and complete, and will fully convey the present disclosure to those of ordinary skill in the art. It will be apparent, however, that one or more embodiments may be practiced without these specific details.
In addition, the present disclosure may repeat reference numerals and/or letters in the various examples. This repetition is for the purpose of simplicity and clarity and does not in itself dictate a relationship between the various embodiments and/or configurations discussed.
It will be understood that when an element is referred to as being “on” another element, it can be directly on the other element or intervening elements may be present. In contrast, when an element is referred to as being “directly on” another element, there are no intervening elements present.
It will be understood that singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise.
Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. It will be further understood that terms; such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and the present disclosure, and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
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The light-transmissive component 120 includes an inner space 120S, an inner wall 120W, a first end portion 121, and a second end portion 122. The second end portion 122 is opposite to the first end portion 121. The light-transmissive component 120 also has an internal diameter D and defines a bisecting plane P for dividing the inner space 120S into two spaces S. In some embodiments, the light-transmissive component 120 is made of glass. In some embodiments, the light-transmissive component 120 is made of plastic. In some embodiments, the light-transmissive component 120 can have different cross sectional shapes such as square, round, “D” shaped and other shapes that may serve the same purpose.
The VMJ cells 140 are disposed within the inner space 120S of the light-transmissive component 120 to receive light and perform light-to-electricity conversion. Furthermore, the VMJ cells 140 are located at one of the two spaces S and are in contact with the inner wall 120W. In some embodiments, the VMJ cells 140 are substantially parallel to the bisecting plane P and there is a distance X between each VMJ cell 140 and the bisecting plane P.
To generate the kV-level voltage, the VMJ cells 140 are connected in series. Furthermore, an increase in power conversion efficiency will increase the VMJ cell voltage output. In practice, increasing the light intensity on the VMJ cells 140 can enhance the light-harvesting efficiency, thereby improving the power conversion efficiency. Therefore, directing light on the VMJ cells 140 becomes very important.
Referring to 5, the inner space 120S of the light-transmissive component 120 is filled with an index-matching material 130. The index-matching material 130 can focus light that penetrates the light-transmissive component 120 on the VMJ cells 140 to enhance the light-harvesting efficiency. In some embodiments, the index-matching material 130 has a refractive index between about 1.0 and about 2.0.
In some embodiments, the index-matching material 130 may be selected from the group consisting of silica gel and epoxy resin. Furthermore, the VMJ cells 140 are encapsulated by the index-matching material 130.
In some embodiments, the index-matching material 130 can be an insulating material to prevent unwanted short circuits.
In addition to use the index-matching material 130, the feature sizes and the optical positions of the VMJ cells 140 also must be controlled to obtain the enhanced light-harvesting efficiency. Referring to
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In some embodiments, each VMJ cell 140 includes a first light receiving surface 140a and a second light receiving surface 140b. The second light receiving surface 140b is opposite to the first light receiving surface 140a and faces the light reflector 150. Therefore, the light reflector 150 can direct the light exiting the light-transmissive component 120 toward the second light receiving surfaces 140b of is the VMJ cells 140.
To collect the light exiting the light-transmissive component 120, the light reflector 150 can include at least one concave surface 150S. The at least one concave surface 150S is corresponding to the second light receiving surfaces 140b of the VMJ cells 140. In some embodiments, the light reflector 150 can be a plate reflector. In some embodiments, the light reflector 150 can be made up of angled flat or curved sections.
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In some embodiments, each conducting component 160 includes a metal wire 161 and a polyvinylidene fluoride (PVDF) coating 162. The metal wire 161 is encapsulated with the PVDF coating 162, leading to electrical insulation, thereby preventing unwanted short circuits. In some embodiments, the metal wire 161 may be made of one selected from the group consisting of copper, nickel, tungsten, and molybdenum.
In addition to the conducting components 160, a positive output component 171 and a negative output component 172 are provided to output the kV level voltage of the voltage source generator 100. In some embodiments, the VMJ cells 140 include a positive output VMJ cell 140P and a negative output VMJ cell 140N. The positive output component 171 is connected to the positive output VMJ cell 140P, and the negative output component 172 is connected to the negative output VMJ cell 140N. In some embodiments, the positive and negative output components 171, 172 are made of the same material as the conducting components 160.
To seal the light-transmissive component 120, a first end cap 181 and a second end cap 182 are provided. The first end cap 181 is disposed at the first end is portion 121, and the second end cap 182 is disposed at the second end portion 122. In some embodiments, the positive output component 171 can be connected to the first end cap 181, and the negative output component 172 can be connected to the second end cap 182. Furthermore, the inner space 120S of the light-transmissive component 120 can be a vacuum space. In some embodiments, the inner space 120S of the light-transmissive component 120 can be filled with a gas. In some embodiments, the gas can be argon or other inert gas.
In some embodiments, the first end cap 181 can include an electrical contact 181 C connected to the positive output component 171. The second end cap 182 can also include an electrical contact 182C connected to the negative output component 172.
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It should be noted that although sunlight is referred to as the illuminating source, other light sources such as LED's, incandescent, or other manmade sources can be used as primary or backup illumination sources.
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a illustrates a side view of a VMJ cell in accordance with some embodiments of the present disclosure.
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In order to improve carrier injections and ohmic contacts of the VMJ cell 140, each of the PN junction substrates 142 includes a light receiving surface 142S, a P+ type diffuse doping layer 1421, a P type diffuse doping layer 1422, an N type diffuse doping layer 1423 and an N+ type diffuse doping layer 1424. The P type s diffuse doping layer 1422 is connected to the P+ type diffuse doping layer 1421; the N type diffuse doping layer 1423 is connected to the P type diffuse doping layer 1422; and the N+ type diffuse doping layer 1424 is connected to the N type diffuse doping layer 1423. The P+ type diffuse doping layer 1421 and the N+ type diffuse doping layer 1424 of one PN junction substrate 142 are connected to different electrode layers 144.
The P+ type diffuse doping layer 1421 has a P+ type end surface 1421a. In some embodiments, a doping concentration of the P+ type diffuse doping layer 1421 is between about 1019 atom/cm3 and about 1021 atom/cm3. In some embodiments, a thickness of the P+ type diffuse doping layer 1421 is between about 0.3 μm and is about 3 μm.
The P type diffuse doping layer 1422 has a P type end surface 1422a. In some embodiments, a doping concentration of the P type diffuse doping layer 1422 is between about 1016 atom/cm3 and about 1020 atom/cm3. In some embodiments, a thickness of the P type diffuse doping layer 1422 is between about 1 μm and about 50 μm.
The N type diffuse doping layer 1423 has an N type end surface 1423a. In some embodiments, a doping concentration of the N type diffuse doping layer 1423 is between about 1016 atom/cm3 and about 1020 atom/cm3. In some embodiments, a thickness of the N type diffuse doping layer 1423 is between about 1 μm and about 50 μm.
The N+ type diffuse doping layer 1424 has an N+ type end surface 1424a. In some embodiments, a doping concentration of the N+ type diffuse doping layer 1424 is between about 1019 atom/cm3 and about 1021 atom/cm3. In some embodiments, a thickness of the N+ type diffuse doping layer 1424 is between about 0.3 μm and about 3 μm.
In some embodiments, the light receiving surface 142S includes the P+type end surface 1421a of the P+ type diffuse doping layer 1424, the P type end surface 1422a of the P type diffuse doping layer 1422, the N type end surface 1423a of the N type diffuse doping layer 1423 and the N+ type end surface 1424a of the N+ s type diffuse doping layer 1424. In some embodiments, the light receiving surface 142S is an uneven surface.
Each of the electrode layers 144 has an exposing surface 144S. To prevent the electrode layers 144 from being damaged in the process, there is a height difference h between the exposing surface 144S of each of the electrode layers 144 and the light receiving surface 142S of each of the PN junction substrates 142. In some embodiments, a position of the exposing surface 144S is lower than that of the light receiving surface 142S.
In order to reduce the carrier recombination probability, a passivation layer 146 is provided to cover the P+ type end surfaces 1421a of the P+ type diffuse is doping layers 1421, the P type end surfaces 1422a of the P type diffuse doping layers 1422, the N type end surfaces 1423a of the N type diffuse doping layers 1423, the N+type end surfaces 1424a of the N+ type diffuse doping layers 1424 and the exposing surfaces 144S of the electrode layers 144. The passivation layer 146 is formed by an atomic layer deposition (ALD) process. Furthermore, the passivation layer 146 is penetrable to light and is made of one selected from the group consisting of Al2O3, HfO2, La2O3, SiO2, TiO2, ZnO, ZrO2, Ta2O5, In2O3, SnO2, ITO, Fe2O3, Nb2O5, MgO, Er2O3, WN, Hf3N4, Zr3N4, AlN, and TiN.
In addition to reduce the carrier recombination probability, the passivation layer 146 also can be used to mend surface defects and dangling bonds of the PN junction substrates 142, thereby reducing light induced degradation and enhancing the photovoltaic conversion efficiency. In some embodiments, a thickness of the passivation layer 146 is between about 10 nm and about 180 nm.
To improve a bonding strength between the passivation layer 146 and the electrode layers 144, each of the electrode layers 144 also includes a groove 144G recessed from the exposing surface 144S, and the grooves 144G of the electrode layers 144 are filled with the passivation layer 146. In some embodiments, a depth d of the groove 144G is greater than the height difference h.
The VMJ cell 140 also includes a first end surface 140c, a second end surface 140d and at least two conducting electrodes 147. The second end surface 140d s is opposite to the first end surface 140c. The conducting electrodes 147 are separately disposed on the first and second end surfaces 140c, 140d. The conducting electrodes 147 are used to output electric energy generated from the VMJ cell 140. In some embodiments, the conducting electrodes 147, the first end surface 140c and the second end surface 140d are covered with the passivation layer 146 to reduce the carrier recombination probability. In some embodiments, a width W of each of the conducting electrodes 147 is smaller than a thickness T of the VMJ cell 140.
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The light-transmissive component 230 includes an inner space 230S, an inner wall 230W, a first end portion 231, and a second end portion 232. The second end portion 232 is opposite to the first end portion 231. The light-transmissive component 230 also has an internal diameter D and defines a bisecting plane P for dividing the inner space 230S into two spaces S.
The VMJ cells 250 are disposed within the inner space 230S of the light-transmissive component 230 to receive light and perform light-to-electricity conversion. Furthermore, the VMJ cells 250 are located at one of the two spaces S and are in contact with the inner wall 230W. In some embodiments, the VMJ cells 250 are substantially parallel to the bisecting plane P and there is a distance X between each VMJ cell 250 and the bisecting plane P. In some embodiments, a ratio of the distance X to the internal diameter D of the light-transmissive component 230 is between about 0.15 and about 0.45. In some embodiments, the VMJ cells 250 are connected in series, and each VMJ cell 250 has a width W smaller than the internal diameter D of the light-transmissive component 230.
Each voltage source generator 220 further includes a plurality of conducting components 240. Each conducting component 240 is disposed between and connected to two adjacent VMJ cells 250. The VMJ cells 250 are connected in series through the conducting components 240. In addition to the conducting component 240, a positive output component 271 and a negative output component 272 are provided to output the kV level voltage of each voltage source generator 220. In some embodiments, the VMJ cells 250 include a positive output VMJ cell 250P and a negative output VMJ cell 250N. The positive output component 271 is connected to the positive output VMJ cell 250P, and the negative output component 272 is connected to the negative output VMJ cell 250N. In some embodiments, the positive and negative output components 271, 272 are made of the same material as the conducting components 240.
To seal the light-transmissive component 230, a first end cap 291 and a second end cap 292 are provided. The first end cap 291 is disposed at the first end portion 231, and the second end cap 292 is disposed at the second end portion 232. In some embodiments, the positive output component 271 can be connected to the first end cap 291, and the negative output component 272 can be connected to the second end cap 292. Furthermore, the inner space 230S of the light-transmissive component 230 can be a vacuum space. In some embodiments, the inner space 230S of the light-transmissive component 230 can be filled with a gas.
To protect the voltage source module 200, a casing 210 is provided. In some embodiments, the voltage source generators 220 are disposed in the casing 210. In some embodiments, the voltage source generators 220 and the electrical connector 260 are disposed in the casing 210.
The casing 210 includes a first window 212 and a second window 214. The second window 214 is opposite to the first window 212, and the first and second windows 212, 214 expose the VMJ cells 250 of the voltage source generators 220. In some embodiments, each VMJ cell 250 includes a first light receiving surface 250a and a second light receiving surface 250b, and the second light receiving surface 250b is opposite to the first light receiving surface 250a. In some embodiments, the first light receiving surface 250a corresponds to the first window 212, and the second light receiving surface 250b corresponds to the second window 214.
Referring to
Table 1 presents the photovoltaic performance for voltage source generator with different tube number. Under one sun (0.09 W/cm2) illumination, the voltage source generator with one tube has an open-circuit voltage (Voc) of 0.512 kV. Interestingly, increasing the tube number to 10 improved the Voc to 5.03 kV.
Moreover, the scope of the present application is not intended to be limited to the particular embodiments of the process, machine, manufacture, and composition of matter, means, methods and steps described in the specification. As those skilled in the art will readily appreciate form the present disclosure, processes, machines, manufacture, compositions of matter, means, methods, or steps, presently existing or later to be developed, that perform substantially the same function or achieve substantially the same result as the corresponding embodiments described herein may be utilized according to the present disclosure.
Accordingly, the appended claims are intended to include within their scope such processes, machines, manufacture, and compositions of matter, means, methods or steps. In addition, each claim constitutes a separate embodiment, and the combination of various claims and embodiments are within the scope of the invention.