Vortex inhibitor with sacrificial rod

Information

  • Patent Grant
  • 6723275
  • Patent Number
    6,723,275
  • Date Filed
    Tuesday, January 16, 2001
    23 years ago
  • Date Issued
    Tuesday, April 20, 2004
    20 years ago
Abstract
An improved vortex inhibitor for separating slag from molten metal during the discharge of molten metal through a nozzle includes a uniform castable refractory body with a generally tapering shape, a hollow chamber within the body and an elongated sacrificial member. The hollow chamber receives the sacrificial member or a mount for the sacrificial member. The refractory body and the sacrificial member combination in molten metal has a specific gravity less than the specific gravity of molten metal and is positioned narrow end downward when supported in molten metal. The hollow chamber can fill with molten metal to form a core that aids in orienting the body in a narrow end downward position. The sacrificial member align the with the area in which the vortex forms and minimizes interference with the flow through the discharge nozzle. The body preferably includes swirl obstructing surfaces.
Description




FIELD OF THE INVENTION




The present invention relates to a device for separating slag from molten metal as the molten metal is transferred from a receptacle.




BACKGROUND ART




In metal making processes, a layer of slag comprising metal impurities forms atop the surface of molten metal held within a metal receptacle such as a furnace, tundish or ladle. As the molten metal is drained from the receptacle, the flow of molten metal through the discharge induces a swirl above the discharge nozzle. At a critical level, the energy of the swirl creates a vortex, whereby the slag layer is sucked into the nozzle, thus contaminating the pour. Separation of the slag and molten metal enhances the quality of the discharge.




Several devices have been known to inhibit the introduction of the slag into the nozzle via the sucking effect of the nozzle. Many of the previously known devices for restricting slag flow through the discharge nozzle were in the form of a refractory body and extending rod combination. For example, the abstract of German Disclosure DE 19821981 A1 to Stilkerieg discloses a slag retainer consisting of a closure body and a finned guide bar. The fin elements consist of a refractory material, preferably a refractory concrete. The closure body also has a bar protruding perpendicularly upwards from the base of the closure body. This bar is attachable to an arm which positions the slag retainer over the tapping channel. Although suitable for its intended purpose, the fin elements are expensive to fabricate. Therefore, the use of a finned guide bar substantially increases the costs of metal making. Moreover, the extending rod enters the tap hole and stifles the flow of molten metal through the nozzle during the pouring process. Consequently, metal pouring operation using this refractory body and extending rod combination extends processing time, and thus increases production costs.




U.S. Pat. No. 4,799,650 to LaBate discloses a slag retainer consisting of a tapered, circular refractory closure having a tapered, hexahedron-shaped refractory extension. The circular closure is sized sufficiently to close the tap hole. A metal rod is passed through the center of the circular closure and extends downwardly into the elongated hexahedron shaped extension to join the circular closure and the hexahedron-shaped extension. The hexahedron extension prematurely throttles the flow of molten metal through the discharge nozzle. Consequently, a significant amount of usable molten metal remains in the receptacle after the pour is stopped, substantially decreasing the total molten metal released per pour, and thus increasing operation costs.




U.S. Pat. No. 4,494,734 to LaBate et al. discloses a slag retainer with a modified cone-shaped refractory body and a rod. The rod extends below the center of the body and is covered with refractory sleeves. The upper extension contains a swivel mechanism which is used to engage a mechanical device that positions the slag retaining device over the tap hole. The patent also covers a method of minimizing slag carryover by dropping a body having a plurality of generally irregular faces and a guide means within a restricted area, draining a furnace, monitoring the stream for flaring, and shutting off flow through the tap hole. Unfortunately, continuous intrusion of the guide means extends the time for discharging metal and may encourage operators to prematurely terminate the flow of the molten metal. Additionally, the process of constructing and affixing refractory sleeves to the downward extension significantly increases the cost of manufacturing the slag retainer.




U.S. Pat. No. 4,709,903 to LaBate discloses a slag retainer consisting of a barrel shaped refractory body and a rod. The rod extends vertically through the barrel shaped body and upwardly and downwardly thereof. The upward extension is engaged to a mechanical device used to position the slag retaining device over the tap hole. The downward extension is covered with refractory sleeves. However, the downward extension enters the tap hole and continues to prematurely restrain the flow of molten metal through the discharge nozzle. Consequently, as previously discussed, the problem of premature termination of the pour results. The problems of shaping and assembling previously discussed are also encountered.




U.S. Pat. No. 4,610,436 to LaBate, II et al. discloses a slag retaining closure having a tapered body and an elongated guide means consisting of an elongated guide member and tip portion depending from the closure. A tip portion of the guide member having a recess or a cavity accelerates and aligns the guide member with the tap hole. The portion of the guide member extending below the tapered end of the closure is coated with refractory sleeves. As with the other disclosures, operation costs are increased due to premature throttling and pour termination. Moreover, the use of the intricate elongated guide means substantially increases manufacturing complexity and has been disfavored.




The previously known refractory body and extending rod combinations suffer from additional disadvantages. These combinations require pre-assembly. The resulting unit requires special packaging to ensure that the extending rod does not break off during delivery. Additionally, the cumbersome shape of the body and rod combination decreases the amount of units that can be shipped in any given space. Moreover, the elongated rods of existing devices may strike the wall of the receptacle instead of entering their intended position in the tap hole. Since the vortex forms above the tap hole, incorrectly positioned devices have little or no effect on inhibiting the vortex. The shipping and operational problems contribute to a lack of industry acceptance of vortex inhibitors with a body and rod combination.




SUMMARY OF THE INVENTION




The present invention overcomes the abovementioned disadvantages by providing a vortex inhibitor using a refractory body with a hollow chamber adapted to receive a sacrificial member. The vortex inhibitor has a specific gravity less than the specific gravity of molten metal and is self-orienting in a narrow end downward position in a molten metal bath. The sacrificial member does not inhibit the flow of the molten metal since it can dissipate shortly after introduction into the metal bath. Additionally, even if the sacrificial rod strikes the wall of the receptacle, the rod can dissipate shortly after introduction into the receptacle, thus freeing the body to relocate to the area in which the vortex forms. Furthermore, the sacrificial member may be constructed of inexpensive metal rod, bar, pole, or other types of elongated members such as tubes, rather than the intricate and expensive guide systems of the prior art.




In general, the vortex inhibitor of the present invention comprises a tapering, castable refractory body, a hollow chamber positioned longitudinally to the axis of tapering of the body, and an elongated sacrificial member carried by the hollow chamber. It is to be understood that the term castable refractory is a uniform mixture, but uniform does not require complete homogeneity of material and includes the intermixture of shot, steel fiber or other materials which may be consistently mixed with a castable refractory material to adjust the specific gravity of the body. In any event, the specific gravity of the uniform mixture is selected so that the body and sacrificial member combination is buoyantly supported at the interface of the slag layer and the molten metal layer. Moreover, the vortex inhibitor of the present invention does not require assembly before shipping, thus reducing the difficulty and cost associated with shipping previously known bodies with guides.




The body has a generally tapering shape along a longitudinal axis from a base toward a narrow end. The term generally tapering means that the body generally conforms with the shape of the vortex formed by the swirling molten metal above the discharge nozzle. The cross-sectional area of the base is greater than that of the narrow end. As used herein, the term narrow end is to be understood as not defining any particular shape, and may include a pointed end, a rounded end or a flat surface. The base can be formed from a simple or complex polygon, or a rounded or circular figure. Complex polygonal bases may include flats, recesses or notches. These features may extend lengthwise along the body. The taper is preferably consistent along the length of the body. The refractory body is preferably constructed by creating a mold of the generally tapering shape.




The hollow chamber is positioned longitudinally to the longitudinal axis of the body and extends within the body. The mold used to construct the refractory body has an insert, preferably in the form of a shaft which forms the hollow chamber during the curing process. Depending on the application, the shaft may be separated from the refractory body or retained within the refractory body once the molded mixture cures. If the shaft is separated from the refractory body, the resulting empty hollow chamber snugly receives the elongated sacrificial member. If the shaft is retained after construction, the sacrificial member is attached to an end of the shaft. In either event, when introduced into the molten metal receptacle, the hollow chamber may fill with molten metal that forms a core within the refractory body. The metal core helps orient the refractory body in a narrow end downward position.




The sacrificial elongated member may be constructed of hollow or solid metal and can be coated with a refractory material. If the elongated member is hollow, then the hollow can be filled with refractory material, as well. When the vortex inhibitor is placed in a molten metal receptacle, the sacrificial member can align the vortex inhibitor with the area in which the vortex would be likely to form. As the pouring process continues, the sacrificial member can dissolve into the molten metal bath, and thereby does not interfere with the flow of molten metal through the discharge nozzle.




Thus, the present invention provides a vortex inhibitor having a refractory body, a hollow chamber within the refractory body and a sacrificial member. These features help orient the refractory body so that its narrow end extends downwardly toward the discharge nozzle of a molten metal receptacle while not reducing the flow of molten metal through the discharge nozzle. When inserted into a molten metal bath, the resulting body and sacrificial member combination has a specific gravity less than the specific gravity of the molten metal. Preferably, the refractory body maintains a center of gravity closer to the narrow end than a center of buoyant support even when the rod has dissolved. Additionally, since the elongated member is sacrificial, it can dissolve before creating a throttling effect upon the discharge flow.




As a result, the present invention permits substantially complete drainage of the furnace with minimal intermixture of the slag and molten metal layers. Moreover, it will be understood that the present invention can also be used for other molten metal receptacles, such as ladles and tundishes, in which separation of the slag from molten metal must be maintained while the metal is discharged from the receptacle.











BRIEF DESCRIPTION OF DRAWINGS




The present invention will be more clearly understood by reference to the following detailed description of the embodiments of the present invention when read in conjunction with the accompanying drawings in which like reference characters refer to like parts throughout the views and in which:





FIG. 1

is an elevational view of a molten metal receptacle containing a vortex inhibitor constructed in accordance with the present invention;





FIG. 2

is a perspective view of the vortex inhibitor shown in

FIG. 1

;





FIG. 3

is a sectional view taken substantially along the line


3





3


in

FIG. 2

;





FIG. 4

is a sectional view of an embodiment of a vortex inhibitor constructed in accordance with the present invention;





FIG. 5

is a sectional view of a further embodiment of a vortex inhibitor constructed in accordance with the present invention;





FIG. 6

is a sectional view of yet another embodiment of a vortex inhibitor constructed in accordance with the present invention;





FIG. 7

is a sectional view of a further embodiment of a vortex inhibitor constructed in accordance with the present invention.





FIG. 8

is a top plan view of a modified refractory body constructed in accordance with the present invention;





FIG. 9

is a sectional view taken substantially along the line


9





9


in

FIG. 8

;





FIG. 10

is a top plan view of another modified refractory body constructed in accordance with the present invention;





FIG. 11

is a sectional view taken substantially along the line


11





11


in

FIG. 10

;





FIG. 12

is a top plan view of a further modification of a refractory body constructed in accordance with the present invention;





FIG. 13

is a sectional view taken substantially along the line


13





13


in

FIG. 12

;





FIG. 14

is a top plan view of another modified refractory body constructed in accordance with the present invention;





FIG. 15

is a sectional view taken substantially along the line


15





15


in

FIG. 14

;





FIG. 16

is a top plan view of yet another modified refractory body constructed in accordance with the present invention; and





FIG. 17

is a perspective view of the body shown in FIG.


16


.











DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT




Referring first to

FIG. 1

, a molten metal receptacle


10


is shown having a bottom wall


12


with a discharge nozzle


14


and nozzle opening


16


. The molten metal receptacle


10


can be a furnace, ladle, reservoir, tundish or other receptacle from which molten metal is discharged through a nozzle


14


. Regardless of the type of receptacle, the receptacle


10


is shown containing a layer of molten metal


18


. A layer of slag


20


, having a specific gravity less than the specific gravity of the molten metal


18


, rests on top of the layer of molten metal


18


. A vortex inhibitor


22


according to the present invention is shown supported at the interface of the slag layer


20


and the molten metal layer


18


within the receptacle


10


.




Referring now to

FIGS. 2 and 3

, the vortex inhibitor


22


comprises a body


24


having a base


26


and narrow end


28


, a hollow chamber


30


and an elongated sacrificial member


32


. As depicted by the upward arrows in

FIGS. 2 and 3

, the sacrificial member


32


slides into the hollow chamber


30


to form an integral vortex inhibitor. Alternatively, the refractory body


24


can be molded around the sacrificial member


32


. The sacrificial member


32


may be modified with crimps


25


or protrusions


27


, which mount the sacrificial member


32


in the hollow chamber


30


once the refractory body


24


cures.




The outermost points of the base intersect a circle


33


circumscribed about the base. The diameter of the circle


33


is larger than the diameter of the nozzle opening


16


so that only a portion of the body may become lodged within the nozzle. Due to the harsh environmental conditions within the furnace, the diameter of the circle may be substantially larger than the diameter of the nozzle opening


16


so that erosion of the body does not reduce the maximum diameter of the outermost points of the base to less than the diameter of the nozzle opening.




The body


24


generally tapers downwardly from the base


26


towards the narrow end


28


. The resulting generally tapering shape is substantially regular so that cross-sectional shapes sliced downwardly from and perpendicularly to the base


26


towards the narrow end


28


are substantially congruent. However, some variation in the cross-sectional shapes can be accommodated.




When the body


24


and the sacrificial member


32


combination is supported at the interface of the slag layer


20


and the molten metal layer


18


, the combination is self-orienting in a narrow end downward position. In the present embodiment, this orientation can be aided by the hollow chamber


30


and the sacrificial member


32


. Specifically, after the vortex inhibitor


22


is dropped into the molten metal receptacle


10


, the hollow chamber


30


can fill with molten metal that forms a core. The core acts to stabilize the position of the vortex inhibitor


22


in the molten metal so that the narrow end


28


points downwardly when the vortex inhibitor floats at the slag-metal interface. Additionally, the sacrificial member


32


may enter the discharge nozzle


14


for a limited time before dissipating. During this initial period before dissipation, the sacrificial member steadies the vortex inhibitor


22


in a narrow end


28


downward position. Moreover, the sacrificial member


32


can initially align the vortex inhibitor


22


with the area in which the vortex would be likely to form. Even if the sacrificial rod dissolves, the refractory body maintains a center of gravity


29


closer to the narrow end than a center of buoyant support


31


.




The sacrificial member


32


is preferably a metal pipe, rod or bar. The length and width of the sacrificial member can be varied greatly as long as the resulting vortex inhibitor construction has a specific gravity less than the specific gravity of the molten metal and is self-orienting in a narrow end downward position when supported in molten metal. A refractory coating


34


is optionally attached to the surface of the sacrificial member


32


. If the sacrificial member is hollow, a refractory coating or core


35


may be included within the hollow sacrificial member. Depending on the operating conditions of the molten metal receptacle, an interior or exterior refractory coating may prolong the life of the sacrificial rod


32


. The sacrificial nature of the elongated member does not impinge on the flow of molten metal through the discharge nozzle


14


.




Referring now to

FIG. 4

, the vortex inhibitor


36


is shown with modifications


37


to the hollow chamber


30


and modifications of the system of attaching the elongated sacrificial member


38


to the refractory body


40


. In the embodiment shown, a hollow shaft


42


is snugly positioned in the hollow chamber


30


, for example, by using the sleeve as the mold insert during pouring of the refractory material. The shaft


42


extends beyond the base


44


of the vortex inhibitor


36


. The exposed portion


46


of the hollow shaft


42


contains a notch


45


adaptable for receiving a locating arm (not shown). The locating arm is responsible for positioning the vortex inhibitor


36


over the area in which the vortex would be likely to form and selectively dropping the vortex inhibitor into the molten metal receptacle. In the embodiment shown, the sacrificial member


38


is attached to the hollow shaft


42


by the use of a nipple


48


, which contains external screw threads


50


on both ends. The nipple


48


mates with the hollow shaft


42


, which has internal screw threads


52


, and mates with an end of the sacrificial member


38


, which contains internal screw threads


54


.




Referring now to

FIG. 5

, the vortex inhibitor


56


is shown with a further modification to the system of attaching the sacrificial member


58


to the hollow shaft


60


. The sacrificial member


58


connects to the hollow shaft


60


through screw threading although other connectors may also be used. External screw threads


62


contained on an end of the sacrificial elongated member mates with internal screw threads


64


on the hollow shaft


60


. As with the embodiment shown in

FIG. 4

, the hollow shaft


60


has an exposed portion


66


which may contain a notch


68


for receiving a locating arm (not shown).




Referring now to

FIG. 6

, the vortex inhibitor


70


is shown with modifications


72


to the hollow chamber


30


and modifications as shown at


74


and


76


to the system of attaching the elongated sacrificial member to the refractory body. In the embodiment shown, a solid shaft


78


is snugly positioned in the hollow chamber


30


and extends beyond the base


80


and narrow end


82


of the vortex inhibitor


70


. The portion


84


extending beyond the base


82


of solid shaft


78


contains a bore


86


adaptable for receiving a locating arm (not shown). The locating arm is responsible for positioning the vortex inhibitor


70


over the area in which the vortex would be likely to form and selectively dropping the vortex inhibitor into the molten metal receptacle. In the embodiment shown, the portion


88


extending beyond the narrow end


82


of solid shaft


78


contains external screw threads


91


. Likewise, an end of sacrificial member


74


contains external screw threads


90


, although other connectors may be used. A coupling


92


mates the solid shaft


78


, which has external screw threads


91


, with the end of the sacrificial member


74


containing external screw threads


90


, thus forming an integral refractory body and sacrificial member combination.




Referring now to

FIG. 7

, the vortex inhibitor


94


is shown with further modifications


96


to the hollow chamber


30


and modifications


97


to the system of attaching the elongated sacrificial member to the refractory body. In the embodiment shown, a solid shaft


98


is snugly positioned in the hollow chamber


30


and extends both beyond the base


100


and the narrow end


102


of the vortex inhibitor


94


. Alternatively, the solid shaft


98


may only extend beyond the narrow end


102


of the vortex inhibitor


94


, thus forming a bolt


101


. The portion


104


extending beyond the base


100


of solid shaft


98


contains a bore


106


adaptable for receiving a locating arm (not shown). If the bolt


101


is utilized, the base


100


can be fitted with a hook (not shown) adaptable for receiving the locating arm (not shown). The locating arm is responsible for positioning the vortex inhibitor


94


over the area in which the vortex would be likely to form and selectively dropping the vortex inhibitor into the molten metal receptacle.




In the embodiment shown, the portion


108


of solid shaft


98


or bolt


101


extending beyond the narrow end


102


is of suitable diameter to snugly receive the hollow sacrificial member


97


. This snug fit may be achieved by varying the diameter of the extending portion


108


or creating gripping surface features, for example protrusions


109


, on the surface of the extending portion


108


. However the snug fit is accomplished, the result is an integral refractory body and sacrificial rod combination.




Regardless of the method by which the sacrificial member is joined with the shaft, the specific gravity of the vortex inhibitor supports it at the interface of the slag layer


20


and the molten metal


18


. Further, regardless of the joining method, the outside surface of the sacrificial member may be coated with refractory material. Additionally, the inside surface of a hollow sacrificial member may be coated with refractory material.




Referring now to

FIGS. 8 and 9

, the vortex inhibitor is shown with a modified body


110


having an octagonal base


112


and flat sides


114


. As with the embodiment shown in

FIG. 2

, the vertices


116


of the octagonal base intersect a circle


118


circumscribed about the base and having a diameter dimensioned to exceed the diameter of the nozzle opening


14


. In addition, the body


110


tapers downwardly toward a narrow end


120


in a substantially regular manner.





FIGS. 10 and 11

show a further modification of a generally tapering body


122


of vortex inhibitor. As shown in the drawings, a body


122


has a substantially circular base


124


. However, unlike the flat sides of the bodies


24


and


110


shown in

FIGS. 2 and 8

respectively, surfaces for enhancing fluid contact that inhibiting the vortex are formed by recesses


126


extending along the sides of the refractory body


122


.




The embodiment as shown in

FIGS. 12 and 13

is similar to

FIG. 10

but vortex inhibiting is enhanced by projections extending outwardly from the periphery of a substantially conical body


128


. Like the recesses


126


shown in the body


122


, a projection


130


can be tapered from the base


134


toward the narrow end


132


, preferably tapering. Alternatively, like the recesses


126


in the body


122


, the projections


130


extends from the base


134


to the narrow end


132


as shown in phantom line at


136


. Moreover, while the recesses


126


or the projections


130


are most effective when extending along the entire length from the base to the narrow end, it may be understood that such projections and recesses may be truncated short of the entire length of the body as shown in phantom line at


138


. Variations in the width and the depth of the projections or recesses are also possible, as indicated by the constant height projections illustrated in phantom line at


140


in FIG.


13


. In addition, a combination of vortex inhibiting surfaces, for example, a combination of recesses and projections, can also be employed as desired without departing from the scope of the present invention. As a further example, flat sided recesses


142


are shown in phantom line at


142


in FIG.


12


.




While the previously described embodiments have a base with a simple geometrical shape, it is also to be understood that complex geometrical shapes can also be employed in producing the vortex inhibitor according to the present invention.

FIGS. 14 and 15

disclose a refractory body


144


having a complex polygonal base


146


. In particular, the base


146


combines a plurality of simple polygonal shapes emanating outwardly from the center of the body


144


. The intersection of the rectangular polygons


148


form planar surfaces


150


and


152


which intersect in a “V” and inhibit vortex action, while the depth of the V-shaped recesses control the throttling effect once the body penetrates the nozzle opening


14


.




As shown in

FIGS. 16 and 17

, a substantially spherical body


154


can be modified to include vortex inhibiting surfaces by cutting regular recesses in the spherical structure. The modification shown in

FIGS. 16 and 17

is formed by truncating the sphere at the intersections of a regular tetrahedron and the sphere, although other truncations or protrusions may be added. The flat sides


156


taper downwardly toward the apex


28


.




All of the previously described modifications to the shape of the refractory body have common characteristics. All of the shapes provide inertia against the swirling motion of molten metal above the discharge nozzle


14


. Additionally, the shape of the refractory body inhibits the formation of vortex suction, a phenomena responsible for drawing slag impurities into the molten metal poured through the nozzle. Nevertheless, the sacrificial rod adds additional control and stability without inhibiting the discharge of molten metal. It is also understood that any of the previously described refractory body shapes may be combined with any of the previously described mounts or methods of joining the sacrificial member with the refractory body in order to form an integral refractory body and sacrificial rod combination.




Having thus described the present invention, many modifications thereto will become apparent to those skilled in the art to which it pertains without departing from the scope and spirit of the present invention as defined in the appended claims.



Claims
  • 1. A method for improving yield of molten metal poured from a discharge nozzle of a metal pouring vessel, the method comprising:introducing a vortex inhibitor having a uniform castable refractory body having a generally tapering shape along a longitudinal axis from a base toward a narrow end and a hollow chamber longitudinally to the body extending within the body and an elongate sacrificial member retained by the hollow chamber to form an integral body, whereby the integral body combining the refractory body and the sacrificial member has a specific gravity less than the specific gravity of molten metal, and is self-orienting in a narrow end downward position when supported in molten metal; and maintaining the vortex inhibitor in the metal pouring vessel during at least a portion of the metal pour, while dissolving the elongated sacrificial member before substantially obstructing the discharge nozzle.
  • 2. The method of claim 1 wherein said dissolving step occurs before discharge of molten metal is terminated.
  • 3. The method of claim 1 wherein said dissolving step occurs before the discharge nozzle is closed.
  • 4. The method of claim 1 wherein said dissolving step occurs before entering the discharge nozzle.
  • 5. A method for improving yield of molten metal poured from a discharge nozzle of a metal pouring vessel, the method comprising:introducing a tapering uniform castable refractory body having a hollow chamber positioned longitudinally to the body extending within the body and an elongated sacrificial member retained by the hollow chamber to form an integral body, whereby the integral body combining the refractory body and the sacrificial member has a specific gravity less than the specific gravity of molten metal, and is self-orienting in an elongated sacrificial member downward position when supported in molten metal; and maintaining the tapering uniform castable refractory body in the metal pouring vessel during at least a portion of the metal pour, while dissolving the elongated sacrificial member before substantially obstructing the discharged nozzle.
  • 6. The method of claim 5 wherein said dissolving step occurs before discharge of molten metal is terminated.
  • 7. The method of claim 5 wherein said dissolving step occurs before the discharge nozzle is closed.
  • 8. The method of claim 5 wherein said dissolving step occurs before entering the discharge nozzle.
US Referenced Citations (11)
Number Name Date Kind
4494734 LaBate et al. Jan 1985 A
4601415 Koffron Jul 1986 A
4610436 LaBate, II et al. Sep 1986 A
4634106 LaBate, II Jan 1987 A
4709903 LaBate Dec 1987 A
4799650 Labate Jan 1989 A
4871148 Koffron Oct 1989 A
4968007 Forte et al. Nov 1990 A
5044610 Koffron Sep 1991 A
5451036 Eastwood Sep 1995 A
6074598 Koffron et al. Jun 2000 A
Foreign Referenced Citations (6)
Number Date Country
44 20 869 Dec 1995 DE
19821981 Aug 1999 DE
0 834 367 Apr 1998 EP
2 205 153 Nov 1988 GB
2000-212627 Feb 2000 JP
PCTGB9201757 Apr 1993 WO