The present invention relates to a method and apparatus for providing a bio prevention cycle for an automatic clothes washer, and more particularly to methods and systems for preventing the build-up of microorganisms or other materials in an automatic clothes washer or similar appliances.
Under normal usage of an automatic clothes washer, detergent residues build up with minerals and soils, which harden on the washer, often in areas that the consumer cannot see. This is particularly true when a consumer uses a higher sudsing detergent. These soils then form an excellent medium for supporting and growing bacteria, fungi, and other microorganisms. Consumers rarely see such microorganisms, but the washer will eventually release or have a foul odor due to these microorganisms.
It would therefore be an improvement in the art if there was provided a method or system for killing the microorganisms which are existing in an automatic clothes washer.
The present invention provides an improvement in the art by providing methods and systems for an automatic washer which will kill microorganisms that are present in the washer.
In an embodiment of the invention, an appliance having an enclosure arranged to receive articles to be treated also includes a water container and a steam chamber with a steam outlet. A water dispenser is arranged to dispense water from the water container to the steam chamber. A heating element is thermally associated with the steam chamber. A control is arranged to selectively operate the heating element. A steam path extends between the steam outlet and the enclosure. A chemical dispenser is positioned along the steam path. The heating element heats water in the steam chamber to create steam, and the chemical dispenser adds a chemical to the steam as the steam passes through the steam path.
The present invention is useful in many different types of appliances having a washing or cleaning cycle, such as clothes washers, dish washers, clothes refreshers, dry cleaning appliances, etc., in which various types of articles are to be treated. For the purposes of disclosing an embodiment of the invention, the environment of a clothes washer is used, although the invention is not limited to such an appliance, or to the particular type of clothes washer illustrated.
In
The washer also includes a disinfecting unit 30, which may be connected to an external water supply via a conduit 32 and to the wash tub 14, or elsewhere in the enclosure formed by the outer cabinet 12, via a conduit 34. The location for the disinfecting unit 30 is only schematically illustrated, and it could actually be located in a variety of different locations in the cabinet 12, where space permits, or even remote from the cabinet, such as in an adjacent cabinet or appliance. The invention can also be used with clothes washers that do not include a vertical agitator, such as those that agitate by other mechanisms, such as nutating plates, baffles on the basket, etc., as well as horizontal axis washers which provide agitation via tumbling. Other washing or cleaning appliances do not agitate the materials being washed or cleaned, but rather provide sprays or mists of water or other cleaning, washing, refreshing and rinsing fluids.
In other embodiments, the water container 36 may include an openable cap 50 (
The water container 36 includes a water dispenser 54, which also may be electrically or mechanically controlled, to cause drops of water to be dispensed into the steam chamber 40, preferably located below the water container. The heating element 38 is thermally associated with a portion of the steam chamber 40 to heat the water drops that have entered the steam chamber. Although depicted as being at the bottom of the steam chamber 40, one skilled in the art will recognize that the heating element 38 could be associated with the steam chamber in a number of configurations. For example, the heating element 38 could surround the steam chamber 40, or it could be located in the center of the chamber. When the heating element 38 is located at the bottom of the steam chamber 40, the water drops from the water container 36 will fall on a surface 56 heated by the heating element, and will quickly be converted to steam.
A passageway 58 allows steam to flow along a path from the steam chamber 40 to the mixing chamber 44. The chemical dispenser 48 allows chemical drops from within the chemical container 42 to flow along the wire 46 into the mixing chamber 44. These drops will coat a large surface area of the wire 46, allowing for quick and efficient absorption or adsorption of the chemical by the steam in the mixing chamber 44. One skilled in the art will recognize that other configurations or arrangements to dispense the chemical into the mixing chamber 46 can be used. For example, the chemical could be a solid that dissolves upon contact with the steam, or the chemical could automatically travel down the wire without the dispenser, like a wick.
A wide variety of chemicals may be used with the invention, including various pesticides, for example, common EPA registered antimicrobials, such as the full list of “MICROBAN” products. Also, hydrogen peroxide and its variations, silver, copper or zinc ions, chlorine bleach, and in some instances, simply steam.
The steam chamber 40 may have a collection sump 60 for receiving any condensate from the steam that has not exited the steam chamber. The mixing chamber 44 may have a bottom wall or floor 62 which is sloped downwardly towards the passageway 58, also to allow condensate, or excess chemical liquid, to flow into the collection sump 60 in the steam chamber 40. If the disinfecting unit 30 is permanent or refillable, the sump may have an openable drain to allow removal of collected liquids from time to time. Alternatively, a liquid moving mechanism, such as a pump or piston, could be used to redirect the condensate back to the surface 56 heated by the heating element 38 to assure that all of the chemical and water is dispensed with the steam.
In operation, when a disinfecting cycle is initiated, the water dispenser 54, operated by a control 61, permits drops of water to leave the water container 36 and fall into the steam chamber 40. The heating element 38, also operated by the control 61, heats the water in the steam chamber 40 until steam is formed (step 63,
The heating element 38 continues to heat the water until the temperature in the wash tub 14 reaches a threshold temperature for a given duration (step 66). Temperature sensors 70 provided at appropriate locations within the appliance, which communicate with the control 61, measure the temperature in the region of the wash tub. The threshold temperature may be 65° C., 70° C., 75° C. or higher for durations of 5 minutes, 10 minutes, 15 minutes, or longer to kill the microorganisms. Preferably, the temperature will be elevated to 67-70° C. for 10 minutes, as determined by a clock 74 in the control 61. With increased temperatures, the duration may be shortened and with decreased temperatures, the duration may be increased. After the threshold temperature is reached for the given duration, the control 61 terminates operation of the heating element 38 to stop the heating of the water (step 76) and terminates the dispensing of water and chemical. For some chemicals, such as silver, copper or zinc ions, would allow for ambient temperatures to be used, rather than elevated temperatures for some given period of time.
The steam impregnated with the chemical is used to thermally and/or chemically kill any microorganisms that exist in the appliance, or to provide other chemical treatment in the appliance, such as scale removal. The steam is able to transport the chemical to areas that are not typically reachable by other means, e.g., by rinsing the washer tub or basket with chemically treated water. In a washer environment, the present invention allows for treatment of the inside and outside of the basket, the tub, the sump, and all of the hoses.
The bio prevention (or other chemical treatment) cycle can be performed as an automatic cycle by the control operating the washer 10, such as at the end of each complete wash cycle. Alternatively, or in addition, the bio prevention cycle could be initiated by the user via a manual selection on a control panel of the washer.
The use of the present invention could also provide for reduced water usage in a wash cycle. The water usage savings could come from the utilization of steam as the vehicle to deliver heat to the wash load, rather than a deep water fill. Less energy would be required to heat a smaller volume of water into steam for the heating, in addition to using less water in the wash cycle.
As is apparent from the foregoing specification, the invention is susceptible of being embodied with various alterations and modifications which may differ particularly from those that have been described in the preceding specification and description. It should be understood that we wish to embody within the scope of the patent warranted hereon all such modifications as reasonably and properly come within the scope of our contribution to the art.
Number | Name | Date | Kind |
---|---|---|---|
369609 | Montanye | Sep 1887 | A |
382289 | Ballard | May 1888 | A |
480037 | Rowe et al. | Aug 1892 | A |
647112 | J.J. Pearson | Apr 1900 | A |
956458 | Walter | Apr 1910 | A |
1089334 | Dickerson | Mar 1914 | A |
1616372 | Janson | Feb 1927 | A |
1676763 | Anetsberger et al. | Jul 1928 | A |
1852179 | McDonald | Apr 1932 | A |
2314332 | Ferris | Mar 1943 | A |
2434476 | Wales | Jan 1948 | A |
2800010 | Dunn | Jul 1957 | A |
2845786 | Chrisman | Aug 1958 | A |
2881609 | Brucken | Apr 1959 | A |
2937516 | Czaika | May 1960 | A |
2966052 | Syles | Dec 1960 | A |
3035145 | Rudolph | May 1962 | A |
3060713 | Burkall | Oct 1962 | A |
3223108 | Martz, Jr | Dec 1965 | A |
3347066 | Klausner | Oct 1967 | A |
3550170 | Davis | Dec 1970 | A |
3712089 | Toth | Jan 1973 | A |
3801077 | Pearson | Apr 1974 | A |
3830241 | Dye et al. | Aug 1974 | A |
3869815 | Bullock | Mar 1975 | A |
3890987 | Marcussen et al. | Jun 1975 | A |
3935719 | Henderson | Feb 1976 | A |
4020396 | Gambale et al. | Apr 1977 | A |
4034583 | Miessler | Jul 1977 | A |
4045174 | Fuhring et al. | Aug 1977 | A |
4108000 | Norris | Aug 1978 | A |
4177928 | Bergkvist | Dec 1979 | A |
4207683 | Horton | Jun 1980 | A |
4214148 | Fleischhauer | Jul 1980 | A |
4263258 | Kalasek | Apr 1981 | A |
4332047 | Kuttelwesch | Jun 1982 | A |
4373430 | Allen | Feb 1983 | A |
4386509 | Kuttelwesch | Jun 1983 | A |
4432111 | Hoffmann et al. | Feb 1984 | A |
4489574 | Spendel | Dec 1984 | A |
4496473 | Sanderson | Jan 1985 | A |
4527343 | Danneberg | Jul 1985 | A |
4646630 | McCoy et al. | Mar 1987 | A |
4761305 | Ochiai | Aug 1988 | A |
4777682 | Dreher et al. | Oct 1988 | A |
4784666 | Brenner et al. | Nov 1988 | A |
4809597 | Lin | Mar 1989 | A |
4879887 | Kagi et al. | Nov 1989 | A |
4920668 | Henneberger et al. | May 1990 | A |
4987627 | Cur et al. | Jan 1991 | A |
4991545 | Rabe et al. | Feb 1991 | A |
5032186 | Childers et al. | Jul 1991 | A |
5050259 | Tsubaki et al. | Sep 1991 | A |
5052344 | Kosugi et al. | Oct 1991 | A |
5058194 | Violi | Oct 1991 | A |
5063609 | Lorimer | Nov 1991 | A |
5107606 | Tsubaki et al. | Apr 1992 | A |
5146693 | Dottor et al. | Sep 1992 | A |
5152252 | Bolton et al. | Oct 1992 | A |
5154197 | Auld et al. | Oct 1992 | A |
5172654 | Christiansen | Dec 1992 | A |
5172888 | Ezekoye | Dec 1992 | A |
5199455 | Dlouhy | Apr 1993 | A |
5212969 | Tsubaki et al. | May 1993 | A |
5219370 | Farrington et al. | Jun 1993 | A |
5219371 | Shim et al. | Jun 1993 | A |
5279676 | Oslin et al. | Jan 1994 | A |
5291758 | Lee | Mar 1994 | A |
5293761 | Jang | Mar 1994 | A |
5315727 | Lee | May 1994 | A |
5345637 | Pastryk et al. | Sep 1994 | A |
5570626 | Vos | Nov 1996 | A |
5619983 | Smith | Apr 1997 | A |
5727402 | Wada | Mar 1998 | A |
5732664 | Badeaux, Jr. | Mar 1998 | A |
5743034 | Debourg et al. | Apr 1998 | A |
5758377 | Cimetta et al. | Jun 1998 | A |
5768730 | Matsumoto et al. | Jun 1998 | A |
5815637 | Allen et al. | Sep 1998 | A |
6029300 | Kawaguchi et al. | Feb 2000 | A |
6067403 | Morgandi | May 2000 | A |
6094523 | Zelina et al. | Jul 2000 | A |
6122849 | Kida et al. | Sep 2000 | A |
6161306 | Clodic | Dec 2000 | A |
6178671 | Zwanenburg et al. | Jan 2001 | B1 |
6295691 | Chen | Oct 2001 | B1 |
6434857 | Anderson et al. | Aug 2002 | B1 |
6451066 | Estes et al. | Sep 2002 | B2 |
6585781 | Roseen | Jul 2003 | B1 |
6622529 | Crane | Sep 2003 | B1 |
6647931 | Morgandi et al. | Nov 2003 | B1 |
6691536 | Severns et al. | Feb 2004 | B2 |
6772751 | Deuringer et al. | Aug 2004 | B2 |
6789404 | Kim et al. | Sep 2004 | B2 |
6874191 | Kim et al. | Apr 2005 | B2 |
6889399 | Steiner et al. | May 2005 | B2 |
7021087 | France et al. | Apr 2006 | B2 |
7096828 | Tippmann | Aug 2006 | B2 |
7290412 | Yang et al. | Nov 2007 | B2 |
7325330 | Kim et al. | Feb 2008 | B2 |
7404304 | Yang et al. | Jul 2008 | B2 |
7421752 | Donadon et al. | Sep 2008 | B2 |
7490491 | Yang et al. | Feb 2009 | B2 |
7490493 | Kim et al. | Feb 2009 | B2 |
7520146 | Kim et al. | Apr 2009 | B2 |
20010032599 | Fischer et al. | Oct 2001 | A1 |
20030215226 | Nomura et al. | Nov 2003 | A1 |
20030226999 | Hage | Dec 2003 | A1 |
20040163184 | Waldron et al. | Aug 2004 | A1 |
20040187527 | Kim et al. | Sep 2004 | A1 |
20040187529 | Kim et al. | Sep 2004 | A1 |
20040200093 | Wunderlin et al. | Oct 2004 | A1 |
20040206480 | Maydanik et al. | Oct 2004 | A1 |
20040221474 | Slutsky et al. | Nov 2004 | A1 |
20040237603 | Kim et al. | Dec 2004 | A1 |
20040244432 | Kim et al. | Dec 2004 | A1 |
20040244438 | North | Dec 2004 | A1 |
20040255391 | Kim et al. | Dec 2004 | A1 |
20050000031 | Price et al. | Jan 2005 | A1 |
20050028297 | Kim et al. | Feb 2005 | A1 |
20050034248 | Oh et al. | Feb 2005 | A1 |
20050034249 | Oh et al. | Feb 2005 | A1 |
20050034250 | Oh et al. | Feb 2005 | A1 |
20050034487 | Oh et al. | Feb 2005 | A1 |
20050034488 | Oh et al. | Feb 2005 | A1 |
20050034489 | Oh et al. | Feb 2005 | A1 |
20050034490 | Oh et al. | Feb 2005 | A1 |
20050050644 | Severns et al. | Mar 2005 | A1 |
20050072382 | Tippmann, Sr. | Apr 2005 | A1 |
20050072383 | Powell et al. | Apr 2005 | A1 |
20050092035 | Shin et al. | May 2005 | A1 |
20050132503 | Yang et al. | Jun 2005 | A1 |
20050132504 | Yang et al. | Jun 2005 | A1 |
20050132756 | Yang et al. | Jun 2005 | A1 |
20050144734 | Yang et al. | Jul 2005 | A1 |
20050144735 | Yang et al. | Jul 2005 | A1 |
20050144737 | Roepke et al. | Jul 2005 | A1 |
20050205482 | Gladney | Sep 2005 | A1 |
20050220672 | Takahashi et al. | Oct 2005 | A1 |
20050223503 | Hong et al. | Oct 2005 | A1 |
20050223504 | Lee et al. | Oct 2005 | A1 |
20050252250 | Oh et al. | Nov 2005 | A1 |
20050262644 | Oak et al. | Dec 2005 | A1 |
20060000242 | Yang et al. | Jan 2006 | A1 |
20060001612 | Kim | Jan 2006 | A1 |
20060005581 | Banba | Jan 2006 | A1 |
20060010613 | Jeon et al. | Jan 2006 | A1 |
20060010727 | Fung | Jan 2006 | A1 |
20060010937 | Kim et al. | Jan 2006 | A1 |
20060016020 | Park | Jan 2006 | A1 |
20060090524 | Jeon et al. | May 2006 | A1 |
20060096333 | Park et al. | May 2006 | A1 |
20060101586 | Park et al. | May 2006 | A1 |
20060101588 | Park et al. | May 2006 | A1 |
20060101867 | Kleker | May 2006 | A1 |
20060107468 | Urbanet et al. | May 2006 | A1 |
20060112585 | Choi et al. | Jun 2006 | A1 |
20060117596 | Kim et al. | Jun 2006 | A1 |
20060130354 | Choi et al. | Jun 2006 | A1 |
20060137105 | Hong et al. | Jun 2006 | A1 |
20060137107 | Lee et al. | Jun 2006 | A1 |
20060150689 | Kim et al. | Jul 2006 | A1 |
20060151005 | Kim et al. | Jul 2006 | A1 |
20060151009 | Kim et al. | Jul 2006 | A1 |
20060191077 | Oh et al. | Aug 2006 | A1 |
20060191078 | Kim et al. | Aug 2006 | A1 |
20060277690 | Pyo et al. | Dec 2006 | A1 |
20070006484 | Moschuetz et al. | Jan 2007 | A1 |
20070028398 | Kwon et al. | Feb 2007 | A1 |
20070084000 | Bernardino et al. | Apr 2007 | A1 |
20070101773 | Park et al. | May 2007 | A1 |
20070107472 | Kim et al. | May 2007 | A1 |
20070107884 | Sirkar et al. | May 2007 | A1 |
20070125133 | Oh et al. | Jun 2007 | A1 |
20070130697 | Oh et al. | Jun 2007 | A1 |
20070136956 | Kim et al. | Jun 2007 | A1 |
20070137262 | Kim et al. | Jun 2007 | A1 |
20070169279 | Park et al. | Jul 2007 | A1 |
20070169280 | Kim et al. | Jul 2007 | A1 |
20070169282 | Kim | Jul 2007 | A1 |
20070169521 | Kim et al. | Jul 2007 | A1 |
20070180628 | Ahn | Aug 2007 | A1 |
20070186591 | Kim et al. | Aug 2007 | A1 |
20070186592 | Kim et al. | Aug 2007 | A1 |
20070186593 | Ahn | Aug 2007 | A1 |
20070199353 | Woo et al. | Aug 2007 | A1 |
20070240458 | Kim et al. | Oct 2007 | A1 |
20070283505 | Wong et al. | Dec 2007 | A1 |
20070283508 | Wong et al. | Dec 2007 | A1 |
20070283728 | Wong et al. | Dec 2007 | A1 |
20080006063 | Ahn et al. | Jan 2008 | A1 |
20080019864 | Savage et al. | Jan 2008 | A1 |
20080028801 | Czyzewski et al. | Feb 2008 | A1 |
20080115740 | You | May 2008 | A1 |
Number | Date | Country |
---|---|---|
1330526 | Jul 1994 | CA |
1664222 | Sep 2005 | CN |
1962988 | May 2007 | CN |
1962998 | May 2007 | CN |
1965123 | May 2007 | CN |
101003939 | Jul 2007 | CN |
101008148 | Aug 2007 | CN |
101024915 | Aug 2007 | CN |
12203 | Feb 1881 | DE |
42920 | Apr 1888 | DE |
69929 | Aug 1893 | DE |
132104 | Jul 1902 | DE |
176355 | Oct 1906 | DE |
243328 | Feb 1912 | DE |
283533 | Apr 1915 | DE |
317887 | Jan 1920 | DE |
427025 | Mar 1926 | DE |
435088 | Oct 1926 | DE |
479594 | Jul 1929 | DE |
668963 | Dec 1938 | DE |
853433 | Oct 1952 | DE |
894685 | Oct 1953 | DE |
1847016 | Feb 1962 | DE |
1873622 | Jun 1963 | DE |
2202345 | Aug 1973 | DE |
2226373 | Dec 1973 | DE |
2245532 | Mar 1974 | DE |
7340082 | May 1975 | DE |
2410107 | Sep 1975 | DE |
2533759 | Feb 1977 | DE |
3103529 | Aug 1982 | DE |
3139466 | Apr 1983 | DE |
3408136 | Sep 1985 | DE |
3501008 | Jul 1986 | DE |
3627988 | Apr 1987 | DE |
8703344 | Aug 1988 | DE |
4116673 | Nov 1992 | DE |
4225847 | Feb 1994 | DE |
4413213 | Oct 1995 | DE |
4443338 | Jun 1996 | DE |
29707168 | Jun 1997 | DE |
29712586 | Sep 1998 | DE |
19730422 | Jan 1999 | DE |
19736794 | Feb 1999 | DE |
19742282 | Feb 1999 | DE |
19743508 | Apr 1999 | DE |
19751028 | May 1999 | DE |
19903951 | Aug 2000 | DE |
10028944 | Dec 2001 | DE |
10035904 | Jan 2002 | DE |
10039904 | Feb 2002 | DE |
10043165 | Feb 2002 | DE |
10312163 | Nov 2003 | DE |
102005051721 | May 2007 | DE |
102007023020 | May 2008 | DE |
0043122 | Jan 1982 | EP |
0132884 | Feb 1985 | EP |
0135484 | Mar 1985 | EP |
0217981 | Apr 1987 | EP |
0222264 | May 1987 | EP |
0280782 | Sep 1988 | EP |
0284554 | Sep 1988 | EP |
0287990 | Oct 1988 | EP |
0302125 | Feb 1989 | EP |
363708 | Apr 1990 | EP |
0383327 | Aug 1990 | EP |
0404253 | Dec 1990 | EP |
0511525 | Nov 1992 | EP |
0574341 | Dec 1993 | EP |
0582092 | Feb 1994 | EP |
0638684 | Feb 1995 | EP |
0672377 | Sep 1995 | EP |
0726349 | Aug 1996 | EP |
0768059 | Apr 1997 | EP |
0785303 | Jul 1997 | EP |
0808936 | Nov 1997 | EP |
0816550 | Jan 1998 | EP |
0821096 | Jan 1998 | EP |
0839943 | May 1998 | EP |
1163387 | Dec 2001 | EP |
1275767 | Jan 2003 | EP |
1351016 | Oct 2003 | EP |
1411163 | Apr 2004 | EP |
1437547 | Jul 2004 | EP |
1441059 | Jul 2004 | EP |
1441175 | Jul 2004 | EP |
1464750 | Oct 2004 | EP |
1464751 | Oct 2004 | EP |
1469120 | Oct 2004 | EP |
1505193 | Feb 2005 | EP |
1507028 | Feb 2005 | EP |
1507029 | Feb 2005 | EP |
1507031 | Feb 2005 | EP |
1507032 | Feb 2005 | EP |
1507033 | Feb 2005 | EP |
1529875 | May 2005 | EP |
1544345 | Jun 2005 | EP |
1548175 | Jun 2005 | EP |
1550760 | Jul 2005 | EP |
1555338 | Jul 2005 | EP |
1555340 | Jul 2005 | EP |
1561853 | Aug 2005 | EP |
1584728 | Oct 2005 | EP |
1619284 | Jan 2006 | EP |
1507030 | Feb 2006 | EP |
1655408 | May 2006 | EP |
1659205 | May 2006 | EP |
1681384 | Jul 2006 | EP |
1696066 | Aug 2006 | EP |
1731840 | Dec 2006 | EP |
1746197 | Jan 2007 | EP |
1783262 | May 2007 | EP |
1555339 | Aug 2007 | EP |
1813704 | Aug 2007 | EP |
1813709 | Aug 2007 | EP |
1865099 | Dec 2007 | EP |
1865101 | Dec 2007 | EP |
1889966 | Feb 2008 | EP |
1936023 | Jun 2008 | EP |
2306400 | Oct 1976 | FR |
2525645 | Oct 1983 | FR |
2581442 | Nov 1986 | FR |
2688807 | Sep 1993 | FR |
21286 | Aug 1898 | GB |
10423 | Nov 1909 | GB |
21024 | Feb 1910 | GB |
191010567 | Apr 1911 | GB |
191010792 | Apr 1911 | GB |
191022943 | Sep 1911 | GB |
191024005 | Oct 1911 | GB |
191103554 | Dec 1911 | GB |
102466 | Dec 1916 | GB |
285384 | Nov 1928 | GB |
397236 | Aug 1933 | GB |
514440 | Nov 1939 | GB |
685813 | Jan 1953 | GB |
799788 | Aug 1958 | GB |
835250 | May 1960 | GB |
881083 | Nov 1961 | GB |
889500 | Feb 1962 | GB |
1155268 | Jun 1969 | GB |
1331623 | Sep 1973 | GB |
1352955 | May 1974 | GB |
1366852 | Sep 1974 | GB |
2219603 | Dec 1989 | GB |
2309071 | Jul 1997 | GB |
2348213 | Sep 2000 | GB |
35021275 | Aug 1950 | JP |
36023044 | Sep 1960 | JP |
36000067 | Jul 1961 | JP |
52146973 | Dec 1977 | JP |
54068072 | May 1979 | JP |
57094480 | May 1982 | JP |
57032858 | Jul 1982 | JP |
60138399 | Jul 1985 | JP |
61128995 | Jun 1986 | JP |
62066891 | Mar 1987 | JP |
2049700 | Feb 1990 | JP |
02161997 | Jun 1990 | JP |
02026465 | Jul 1990 | JP |
02198595 | Aug 1990 | JP |
2239894 | Sep 1990 | JP |
2242088 | Sep 1990 | JP |
02267402 | Nov 1990 | JP |
03025748 | Jun 1991 | JP |
3137401 | Jun 1991 | JP |
4158896 | Jun 1992 | JP |
05023493 | Feb 1993 | JP |
05115672 | May 1993 | JP |
05146583 | Jun 1993 | JP |
05269294 | Oct 1993 | JP |
5346485 | Dec 1993 | JP |
06123360 | May 1994 | JP |
08261689 | Oct 1996 | JP |
9133305 | May 1997 | JP |
11047488 | Feb 1999 | JP |
11164979 | Jun 1999 | JP |
11164980 | Jun 1999 | JP |
11226290 | Aug 1999 | JP |
2000176192 | Jun 2000 | JP |
2003019382 | Jan 2003 | JP |
2003093775 | Apr 2003 | JP |
2003311068 | Nov 2003 | JP |
2003311084 | Nov 2003 | JP |
2003320324 | Nov 2003 | JP |
2003326077 | Nov 2003 | JP |
2004061011 | Feb 2004 | JP |
2004121666 | Apr 2004 | JP |
2004167131 | Jun 2004 | JP |
2004298614 | Oct 2004 | JP |
2004298616 | Oct 2004 | JP |
2004313793 | Nov 2004 | JP |
2005058740 | Mar 2005 | JP |
2005058741 | Mar 2005 | JP |
2005177440 | Jul 2005 | JP |
2005177445 | Jul 2005 | JP |
2005177450 | Jul 2005 | JP |
2005192997 | Jul 2005 | JP |
2005193003 | Jul 2005 | JP |
2006109886 | Apr 2006 | JP |
2006130295 | May 2006 | JP |
9319820 | Sep 1993 | KR |
1019950018856 | Jul 1995 | KR |
1019970011098 | Mar 1997 | KR |
1019970070295 | Nov 1997 | KR |
100146947 | Oct 1998 | KR |
200128631 | Dec 1998 | KR |
2019970039170 | Dec 1998 | KR |
20010015043 | Feb 2001 | KR |
1020010010111 | Feb 2001 | KR |
20040085509 | Oct 2004 | KR |
20050017481 | Feb 2005 | KR |
20060031165 | Apr 2006 | KR |
9214954 | Sep 1992 | WO |
9307798 | Apr 1993 | WO |
9319237 | Sep 1993 | WO |
9715709 | May 1997 | WO |
0111134 | Feb 2001 | WO |
0174129 | Oct 2001 | WO |
03012185 | Feb 2003 | WO |
03057966 | Jul 2003 | WO |
2004059070 | Jul 2004 | WO |
2004091359 | Oct 2004 | WO |
2005001189 | Jan 2005 | WO |
2005018837 | Mar 2005 | WO |
2005115095 | Dec 2005 | WO |
2006001612 | Jan 2006 | WO |
2006009364 | Jan 2006 | WO |
2006070317 | Jul 2006 | WO |
2006090973 | Aug 2006 | WO |
2006091054 | Aug 2006 | WO |
2006091057 | Aug 2006 | WO |
2006101372 | Sep 2006 | WO |
2006098571 | Sep 2006 | WO |
2006098572 | Sep 2006 | WO |
2006098573 | Sep 2006 | WO |
2006101304 | Sep 2006 | WO |
2006101312 | Sep 2006 | WO |
2006101336 | Sep 2006 | WO |
2006101345 | Sep 2006 | WO |
2006101358 | Sep 2006 | WO |
2006101360 | Sep 2006 | WO |
2006101361 | Sep 2006 | WO |
2006101362 | Sep 2006 | WO |
2006101363 | Sep 2006 | WO |
2006101365 | Sep 2006 | WO |
2006101376 | Sep 2006 | WO |
2006101377 | Sep 2006 | WO |
2006104310 | Oct 2006 | WO |
2006112611 | Oct 2006 | WO |
2006126778 | Nov 2006 | WO |
2006126779 | Nov 2006 | WO |
2006126799 | Nov 2006 | WO |
2006126803 | Nov 2006 | WO |
2006126804 | Nov 2006 | WO |
2006126810 | Nov 2006 | WO |
2006126811 | Nov 2006 | WO |
2006126813 | Nov 2006 | WO |
2006126815 | Nov 2006 | WO |
2006129912 | Dec 2006 | WO |
2006129913 | Dec 2006 | WO |
2006129915 | Dec 2006 | WO |
2006129916 | Dec 2006 | WO |
2007004785 | Jan 2007 | WO |
2007007241 | Jan 2007 | WO |
2007010327 | Jan 2007 | WO |
2007024050 | Mar 2007 | WO |
2007024056 | Mar 2007 | WO |
2007024057 | Mar 2007 | WO |
2007026989 | Mar 2007 | WO |
2007026990 | Mar 2007 | WO |
2007055475 | May 2007 | WO |
2007055510 | May 2007 | WO |
2007058477 | May 2007 | WO |
2007073012 | Jun 2007 | WO |
2007073013 | Jun 2007 | WO |
2007081069 | Jul 2007 | WO |
2007086672 | Aug 2007 | WO |
2007116255 | Oct 2007 | WO |
2007145448 | Dec 2007 | WO |
2008004801 | Jan 2008 | WO |
Number | Date | Country | |
---|---|---|---|
20080092602 A1 | Apr 2008 | US |