Claims
- 1. A composition for washing keratinous materials, comprising:
- (a) 0.1 to 20% by weight of a silicone containing a hydroxyacylamino functional group chosen from the compounds corresponding to the formula: ##STR12## in which: R.sub.1 and R.sub.2 represent (CH.sub.2).sub.2, (CH.sub.2).sub.3, (CH.sub.2).sub.4, or --CH.sub.2 CH(CH.sub.3)CH.sub.2 --;
- R.sub.3 represents hydrogen, hyroxyl, alkyl or hydroxyalkyl;
- n is an integer varying from 2 to 7;
- x is an integer varying from 20 to approximately 1,500;
- y varies between approximately 0.5 and 10;
- and the y/x ratio is less than 0.05;
- (b) 0.05 to 8% by weight of a substantive polymer wherein the substantive polymer is selected from the group consisting of
- (1) optionally quaternised vinylpyrrolidone/dialkylaminoalkyl acrylate or methacrylate copolymers;
- (2) copolymers of cellulose or of cellulose derivatives grafted with a water-soluble quaternary ammonium monomer;
- (3) quaternised polysaccharides;
- (4) cyclopolymers having a molecular weight of 20,000 to 3,000,000 chosen from the homopolymers containing, as the principal unit of the chain, units of formulae: ##STR13## in which l and t are equal to 0 or 1, and the sum l+t=1;
- R.sub.6 represents hydrogen or methyl;
- R.sub.4 and R.sub.5 represent, independently of each other, an alkyl group having from 1 to 22 carbon atoms, a hydroxyalkyl group, or a lower amidoalkyl group or where R.sub.4 and R.sub.5 represent, jointly with the nitrogen atom to which they are connected, heterocyclic groups, as well as copolymers containing units of formula (II) or (II') and units derived from acrylamide or from diacetoneacrylamide;
- Y.sup.- being an anion;
- (5) quaternary polyammonium polymers selected from the group consisting of:
- (i) the polymer containing repeat units corresponding to the formula: ##STR14## in which R.sub.7 and R.sub.8, R.sub.9 and R.sub.10, being identical or different, represent aliphatic, alicyclic or arylaliphatic radicals containing 1-20 carbon atoms or lower hydroxyalkylaliphatic radicals or else R.sub.7 and R.sub.8, R.sub.9 and R.sub.10, together or separately, form with the nitrogen atoms to which they are connected, heterocycles which optionally contain a second hetero atom other than nitrogen or else R.sub.7, R.sub.8, R.sub.9 and R.sub.10 represent a linear or branched C.sub.1 -C.sub.6 alkyl radical substituted with a nitrile, ester, acyl, amide or ##STR15## group, where R.sub.11 is an alkylene and D a quaternary ammonium group, A.sub.1 and B.sub.1 represent polymethylene groups containing from 2 to 20 carbon atoms which may be linear or branched, saturated or unsaturated, and which may contain, connected to or inserted into its principal chain, one or more aromatic rings or one or more oxygen or sulphur atoms or sulphoxide, sulphone, disulphide, amino, alkylamino, hydroxyl, quaternary ammonium, ureido, amide or ester groups, and
- X.sup.- represents an anion derived from an inorganic or organic acid,
- A.sub.1 and R.sub.7 and R.sub.9 may form, with the two nitrogen atoms to which they are connected, a piperazine ring;
- if A.sub.1 represents a linear or branched, saturated or unsaturated alkylene or hydroxyalkylene radical, B.sub.1 may also represent a group:
- --(CH.sub.2).sub.n --CO--D--OC--(CH.sub.2).sub.n --
- in which D represents a bis-secondary diamine residue; a bis-primary diamine residue; or a ureylene group; and
- (ii) the polymer consisting of units of formula: ##STR16## in which: R.sub.12, R.sub.13, R.sub.14, and R.sub.15 which are identical or different, represent a hydrogen atom or a methyl, ethyl, propyl, b-hydroxyethyl, b-hydroxypropyl or --CH.sub.2 CH.sub.2 (OCH.sub.2 CH.sub.2).sub.P OH radical, where p is 0 to 6, with the proviso that R.sub.12, R.sub.14, and R.sub.15 do not simultaneously represent a hydrogen atom;
- x and y, which are identical or different, are 1 to 6;
- m is 0 to 34;
- X represents a halogen atom; and
- A represents a dihalide radical; and
- (6) polyamines, polyalkyleneimines, polymers containing vinylpyridine or vinylpyridinium units, condensates of polyamines and of epichlorohydrin, quaternary polyureylenes and chitin derivates, and
- (c) between 5and 50% by weight in relation to the total weight of the composition of at least one detergent surface-active agent which is selected from a group of agents consisting of:
- (i) anionic surface-active agents selected from the group consisting of alkali metal salts, ammonium salts, amine salts, aminoalcohol salts of alkyl ether sulphates, alkylamidoether sulphates, alkylarylpolyether sulphates, and monoglyceride sulphates; magnesium salts of alkyl ether sulphates, alkylamidoether sulphates, alkylarylpolyether sulphates, and monoglyceride sulphates; alkylsulphonates, alkylamidesulphonates, alkylarylsulphonates, olefinsulphonates, paraffinsulphonates, alkylsulphosuccinates, alkylethersulphosuccinates, alkylamidesulphosuccinates, alkylsulphosuccinamates, alkylsulphoacetates, alkyl ether phosphates, acylsarcosinates, N-acyltaurates, fatty acid salts, acids of copra oil, acids of hydrogenated copra oil, and acyl lactylates wherein the acyl radical contains from 8 to 20 carbon atoms;
- (ii) amphoteric agents;
- (iii) non-ionic surface active agents selected from the group consisting of polyethoxylated fatty acids with a fatty chain containing 8 to 18 carbon atoms, polypropoxylated fatty acids with a fatty chain containing 8 to 18 carbon atoms, polyglycerolated fatty acids with a fatty chain containing 8 to 18 carbon atoms, alcohols with a fatty chain containing 8 to 18 carbon atoms, .alpha.-diols with a fatty chain containing 8 to 18 carbon atoms, alkylphenols with a fatty chain containing 8 to 18 carbon atoms, copolymers of ethylene oxide and propylene oxide, condensates of ethylene oxide with fatty alcohols, condensates of propylene oxide with fatty alcohols, polyethoxylated fatty amides, polyglycerolated fatty amides, polyethoxylated fatty amines, oxyethylenated fatty acid esters of sorbitan, fatty acid esters of sucrose, fatty acid esters of polyethylene glycol, fatty acids esters of glycols, alkylpolyglycosides, oxides of (C.sub.10 -C.sub.14)alkylamines, oxides of N-acylamidopropylmorpholine and amine oxides; and
- (iv) mixtures thereof, in an aqueous medium, wherein said composition does not contain an alcohol suspending agent having 27 to 44 carbon atoms and one to two functional groups selected from the group consisting of an ether group, a thioether group and a sulphoxide group.
Priority Claims (1)
Number |
Date |
Country |
Kind |
91 08388 |
Jul 1991 |
FRX |
|
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is a divisional application of Ser. No. 08/384,604 filed Feb. 3, 1995, now U.S. Pat. No. 5,627,148, which is a file wrapper continuation of Ser. No. 07/905,540 filed Jun. 30, 1992, now abandoned.
US Referenced Citations (3)
Number |
Name |
Date |
Kind |
4529586 |
De Marco et al. |
Jul 1985 |
|
4978561 |
Cary et al. |
Dec 1990 |
|
5627148 |
Dubief et al. |
May 1997 |
|
Foreign Referenced Citations (1)
Number |
Date |
Country |
2678633 |
Jan 1993 |
FRX |
Divisions (1)
|
Number |
Date |
Country |
Parent |
384604 |
Feb 1995 |
|
Continuations (1)
|
Number |
Date |
Country |
Parent |
905540 |
Jun 1992 |
|