Patent Application
20220162136
The present disclosure relates to a waste treatment system and a waste treatment method.
Patent Document 1 discloses a method in which a raw material containing plant waste is hydrolyzed with steam and is separated into solid and liquid components to produce a biomass fuel from the solid component and a liquid fertilizer from the liquid component.
However, the method disclosed in Patent Document 1 has some problems, such as the inability to appropriately treat waste containing a large amount of nitrogen compounds such as proteins and to produce fermented substances from them.
In view of the above, an object of at least one embodiment of the present disclosure is to provide a waste treatment system and a waste treatment method whereby it is possible to increase a treatable waste range and appropriately produce a fermented substance using treated waste as the raw material.
(1) A waste treatment system according at least one embodiment of the present disclosure comprises: a first hydrothermal treatment device for performing hydrothermal treatment of waste; a first solid-liquid separation device for separating a first reactant of the first hydrothermal treatment device into a solid and a liquid or slurry; a second hydrothermal treatment device for performing hydrothermal treatment of the solid of the first reactant; a second solid-liquid separation device for separating a second reactant of the second hydrothermal treatment device into a solid and a liquid or slurry; and a fermentation device for fermenting the liquid or the slurry of the first reactant and the liquid or the slurry of the second reactant.
Herein, the first hydrothermal treatment device, the second hydrothermal treatment device, the first solid-liquid separation device, the second solid-liquid separation device, and the fermentation device each may include multiple machines that have their functions. For example, the system may be provided with two first hydrothermal treatment devices and one second hydrothermal treatment device.
When waste containing a large amount of nitrogen compounds such as proteins is hydrothermally treated at a temperature of 150° C. or higher, melanoidin is significantly generated by the Maillard reaction. Nitrogen-containing antioxidants such as melanoidin entering the fermentation device inhibit fermentation. With the above configuration (1), since the hydrothermal treatment in the first hydrothermal treatment device is performed at a temperature that suppresses the Maillard reaction, the generation of melanoidin in the first hydrothermal treatment device can be suppressed. Further, since the first solid-liquid separation device solubilizes or slurries nitrogen compounds such as proteins, which may cause melanoidin formation, and separates them as a liquid or slurry of the first reactant, the amount of nitrogen compounds in the raw material of the second hydrothermal treatment device can be reduced, and the generation of melanoidin due to the hydrothermal treatment in the second hydrothermal treatment device can be suppressed. Thus, it is possible to reduce the fermentation inhibition in the fermentation device. As a result, it is possible to increase a treatable waste range and appropriately produce a fermented substance using treated waste as the raw material.
(2) In some embodiments, in the above configuration (1), a temperature of the hydrothermal treatment in the first hydrothermal treatment device is lower than a temperature of the hydrothermal treatment in the second hydrothermal treatment device.
With this configuration, since the hydrothermal treatment in the second hydrothermal treatment device is performed at a higher temperature than the hydrothermal treatment in the first hydrothermal treatment device, persistent organic matter such as cellulose can be degraded to easily degradable organic matter such as saccharide and organic acid and supplied to the fermentation device, so that the fermentation time in the fermentation device can be shortened while suppressing the generation of melanoidin in the second hydrothermal treatment device. Herein, the terms persistent and easily degradable are used in the sense of whether it takes a long time or a short time for enzymes or bacteria in the fermentation device to decompose the raw material.
(3) In some embodiments, in the above configuration (1) or (2), the waste treatment system comprises a colored substance sensor for detecting an index of a colored substance in the liquid or the slurry flowing in the fermentation device.
With this configuration, since the index of melanoidin which is a colored substance in the liquid or the slurry flowing in the fermentation device can be detected, by adjusting the operating conditions of the waste treatment system, such as adjusting the temperature of the hydrothermal treatment in the first hydrothermal treatment device based on the detected index of melanoidin, the index of melanoidin in the liquid or the slurry flowing in the fermentation device can be reduced to reduce the risk of inhibiting fermentation.
(4) A waste treatment method according at least one embodiment of the present disclosure comprises: a first hydrothermal treatment step of performing hydrothermal treatment of waste; a first solid-liquid separation step of separating a first reactant of the first hydrothermal treatment step into a solid and a liquid or slurry; a second hydrothermal treatment step of performing hydrothermal treatment of the solid of the first reactant; a second solid-liquid separation step of separating a second reactant of the second hydrothermal treatment step into a solid and a liquid or slurry; and a fermentation step of fermenting the liquid or the slurry of the first reactant and the liquid or the slurry of the second reactant.
When waste containing a large amount of nitrogen compounds such as proteins is hydrothermally treated at a temperature of 150° C. or higher, melanoidin is generated by the Maillard reaction. Nitrogen-containing antioxidants such as melanoidin inhibit fermentation in the fermentation step. With the above configuration (4), since the hydrothermal treatment in the first hydrothermal treatment step is performed at a temperature that suppresses the Maillard reaction, the generation of melanoidin in the first hydrothermal treatment step can be suppressed. Further, since the first solid-liquid separation step solubilizes or slurries nitrogen compounds such as proteins, which may cause melanoidin formation, and transfers them into a liquid or slurry of the first reactant, the amount of nitrogen compounds in the raw material of the second hydrothermal treatment step can be reduced, and the generation of melanoidin due to the hydrothermal treatment in the second hydrothermal treatment step can be suppressed. Thus, it is possible to reduce the fermentation inhibition in the fermentation step. As a result, it is possible to increase a treatable waste range and appropriately produce a fermented substance using treated waste as the raw material.
(5) In some embodiments, in the above method (4), a temperature of the hydrothermal treatment in the first hydrothermal treatment step is lower than a temperature of the hydrothermal treatment in the second hydrothermal treatment step.
With this method, since the hydrothermal treatment in the second hydrothermal treatment step is performed at a higher temperature than the hydrothermal treatment in the first hydrothermal treatment step, persistent organic matter such as cellulose can be degraded to easily degradable organic matter and fermented, so that the fermentation time in the fermentation step can be shortened while suppressing the generation of melanoidin in the second hydrothermal treatment step.
(6) In some embodiments, in the above method (4) or (5), the first hydrothermal treatment step and the second hydrothermal treatment step are performed in a same hydrothermal treatment device.
With this method, since the waste treatment method (4) or (5) can be performed by one hydrothermal treatment device, the system for implementing the waste treatment method can be downsized.
(7) In some embodiments, in the above method (4) or (5), the second hydrothermal treatment step is performed in a different hydrothermal treatment device from a hydrothermal device that has performed the first hydrothermal treatment step.
For example, at time t1, among four hydrothermal treatment devices with the same function, devices A and B discharge the product and feed the raw waste, device C performs the first hydrothermal treatment step, and device D performs the second hydrothermal treatment step. Then, at time t2, device A performs the first hydrothermal treatment step, device B performs the second hydrothermal treatment step, and devices C and D discharge the product and feed the raw waste. With this method, flexible operation is possible since the process can be performed in any device without choosing the raw material.
According to at least one embodiment of the present disclosure, since the hydrothermal treatment in the first hydrothermal treatment device is performed at a temperature that suppresses the Maillard reaction, the generation of melanoidin in the first hydrothermal treatment device can be suppressed. Further, since the first solid-liquid separation device solubilizes or slurries nitrogen compounds such as proteins, which may cause melanoidin formation, and transfers them into a liquid of the first reactant, the amount of nitrogen compounds in the raw material of the second hydrothermal treatment device can be reduced, and the generation of melanoidin due to the hydrothermal treatment in the second hydrothermal treatment device can be suppressed. Thus, it is possible to reduce the fermentation inhibition in the fermentation device. As a result, it is possible to increase a treatable waste range and appropriately produce a fermented substance using treated waste as the raw material.
Embodiments of the present invention will now be described in detail with reference to the accompanying drawings. However, the scope of the present invention is not limited to the following embodiments. It is intended that dimensions, materials, shapes, relative positions and the like of components described in the embodiments shall be interpreted as illustrative only and not intended to limit the scope of the present invention.
As shown in
The configuration of the first hydrothermal treatment device 2 is not limited, but may be, for example, a batch-type hydrothermal treatment device equipped with a container that can receive waste as it is from a vehicle or a plant that collects the waste, and configured to supply steam to the container. The configuration of the first solid-liquid separation device 3 is not limited, but may be any configuration that separates a liquid (liquid or slurry) passing through the first solid-liquid separation device 3 from a solid not passing through the first solid-liquid separation device 3, such as one that separates solid with at least a certain particle size. For example, it may be a screen, a mesh, a filter, a strainer, a filtration device, or a centrifugal separation device. The configurations of the second hydrothermal treatment device 12 and the second solid-liquid separation device 13 may be the same as or different from the configurations of the first hydrothermal treatment device 2 and the first solid-liquid separation device 3. In the following description, the liquids separated by the first solid-liquid separation device 3 and the second solid-liquid separation device 13 include not only liquid containing no fine solids, but also slurry containing fine solids.
The configuration of the fermentation device 6 is not limited, but may be any configuration that produces a valuable resource using the liquid of the first reactant and the liquid of the second reactant as the raw material through the biological action of microorganisms, bacteria, enzymes, etc. For example, it may be a methane fermentation device for producing biogas, an ethanol fermentation device for producing ethanol, an organic fertilizer production device for producing organic fertilizer, a feed production device for producing feed, or a combination of some of these. A pre-fermentation treatment facility such as an enzymatic saccharification tank, an acid fermentation tank, or a mixing and conditioning tank may be provided upstream of the fermentation device. Further, a facility for removing fine materials unsuitable for fermentation that cannot be removed by the first solid-liquid separation device 3 and the second solid-liquid separation device 13 may be provided. For example, this facility may be a sand separator which utilizes centrifugal force for separation.
Next, operation of the waste treatment system 1 according to the first embodiment of the present disclosure will be described.
As shown in
The first reactant which is a reactant of the hydrothermal treatment in the first hydrothermal treatment device 2 is separated by the first solid-liquid separation device 3 into a solid and a liquid. The separated solid is sent to the second hydrothermal treatment device 12, comes into contact with steam supplied to the second hydrothermal treatment device 12, and is hydrothermally treated using the same principle as the hydrothermal treatment in the first hydrothermal treatment device 2. The temperature of the hydrothermal treatment in the second hydrothermal treatment device 12 may be higher than the temperature of the hydrothermal treatment in the first hydrothermal treatment device 2. For example, preferably, the temperature of the hydrothermal treatment in the first hydrothermal treatment device 2 is 120° C. to 160° C., and the temperature of the hydrothermal treatment in the second hydrothermal treatment device 12 is 200° C. to 240° C.
The second reactant which is a reactant of the hydrothermal treatment in the second hydrothermal treatment device 12 is separated by the second solid-liquid separation device 13 into a solid and a liquid. The separated solid is those that cannot be decomposed by the action of microorganisms and bacteria in the fermentation device 6, such as plastic, metal, stone, sand, etc., and is disposed of as a material unsuitable for fermentation that cannot be used as the raw material for fermentation in the fermentation device 6. Alternatively, of the material unsuitable for fermentation, valuable metal and plastic that can be used as fuel are recycled as resources. On the other hand, the liquids separated by the first solid-liquid separation device 3 and the second solid-liquid separation device 13 are sent to the fermentation device 6 to produce a fermented substance such as biogas, ethanol, organic fertilizer, and feed.
When organic waste containing saccharides and proteins is hydrothermally treated at a temperature of 150° C. or higher, melanoidin is generated by the Maillard reaction. Nitrogen-containing antioxidants such as melanoidin entering the fermentation device 6 inhibit fermentation in the fermentation device 6. In the waste treatment system 1 according to the first embodiment, in the first hydrothermal treatment device 2, the hydrothermal treatment is performed at a lower temperature than the temperature of the hydrothermal treatment in the second hydrothermal treatment device 12, preferably at a temperature that suppresses the Maillard reaction, for example at 120° C., to suppress the generation of melanoidin in the first hydrothermal treatment device 2. Further, the first hydrothermal treatment device 2 solubilizes nitrogen-containing components, which may cause melanoidin formation, and transfers them to the liquid. This reduces the nitrogen-containing components in the solid hydrothermally treated in the second hydrothermal treatment device 12, and suppresses the generation of melanoidin due to the hydrothermal treatment in the second hydrothermal treatment device 12. Thus, it is possible to reduce the fermentation inhibition in the fermentation device 6.
In the second hydrothermal treatment device 12, the hydrothermal treatment is performed at a higher temperature than the hydrothermal treatment in the first hydrothermal treatment device 2, for example at 220° C., to degrade persistent organic matter such as cellulose to easily degradable organic matter such as saccharide and organic acid. Although persistent organic matter such as cellulose takes a long time to ferment in the fermentation device 6, since the persistent organic matter such as cellulose is degraded into easily degradable organic matter by the hydrothermal treatment in the second hydrothermal treatment device 12 and supplied to the fermentation device 6, the fermentation time in the fermentation device 6 can be shortened. Further, when lignocellulosic biomass, such as grasses and paper made from grasses, is hydrothermally treated in the second hydrothermal treatment device 12, lignin decomposes and yields phenols. Phenols entering the fermentation device inhibit fermentation. Especially when the hydrothermal temperature is 240° C. or higher, the decomposition of lignin is accelerated and saccharides produced by the decomposition of cellulose are polycondensed into carbides or precursors thereof. Since carbide is not used as the raw material for fermentation, the temperature of the hydrothermal treatment in the second hydrothermal treatment device 12 is preferably 200° C. to 240° C.
Thus, when the hydrothermal treatment in the first hydrothermal treatment device 2 is performed at a temperature that suppresses the Maillard reaction, the generation of melanoidin in the first hydrothermal treatment device 2 can be suppressed. Further, since the first solid-liquid separation device 3 solubilizes or slurries nitrogen compounds such as proteins, which may cause melanoidin formation, and transfers them into a liquid of the first reactant, the amount of nitrogen compounds in the raw material of the second hydrothermal treatment device 12 can be reduced, and the generation of melanoidin due to the hydrothermal treatment in the second hydrothermal treatment device 12 can be suppressed. Thus, it is possible to reduce the fermentation inhibition in the fermentation device 6. As a result, it is possible to increase a treatable waste range and appropriately produce a fermented substance from treated waste without inhibition.
The waste treatment system 1 may include colored substance sensors 15 and 16 for detecting the index of a colored substance in the liquids separated by the first solid-liquid separation device 3 and the second solid-liquid separation device 13. The colored substance includes, in addition to melanoidin, phenols and furals, which can inhibit fermentation in the fermentation device 6. Since the concentration of melanoidin in the liquid correlates with the index of absorbance in the wavelength region of 400 to 450 nm, and the concentration of phenols in the liquid correlates with the index of absorbance in the wavelength region of 200 to 300 nm, absorbance meters can be used as the colored substance sensors 15, 16. Instead of the colored substance sensors 15, 16, the system may include a colored substance sensor 17 for detecting the index of the colored substance in a liquid after joining the liquids separated by the first solid-liquid separation device 3 and the second solid-liquid separation device 13 and before flowing into the fermentation device 6. In addition, a colored substance sensor 18 may be provided in the fermentation device 6 to detect the index of the colored substance in the fermentation device 6. That is, the colored substance sensors 15 to 18 are used to detect the colored substance in the liquid flowing into the fermentation device 6.
If the amount of colored substance, for example, melanoidin, flowing into the fermentation device 6 is determined to be high based on the detected values by the colored substance sensors 15 to 17, the cause may be, for example, that low solid decomposition rate in the first hydrothermal treatment device 2 causes nitrogen-containing substances to flow into the second hydrothermal treatment device 12 and melanoidin to be generated in the second hydrothermal treatment device 12. If the colored substance sensors 15 and 16 are provided, this phenomenon can be identified by comparing the detected values of both sensors. In this case, increasing the temperature of the hydrothermal treatment in the first hydrothermal treatment device 2 or increasing the residence time of the waste in the first hydrothermal treatment device 2 promotes the shrinkage of the waste and improves the solid decomposition rate, thus reducing the amount of melanoidin flowing into the fermentation device 6. However, if the temperature of the hydrothermal treatment in the first hydrothermal treatment device 2 is excessively increased, melanoidin generated in the first hydrothermal treatment device 2 increases. Therefore, the temperature of the hydrothermal treatment in the first hydrothermal treatment device 2 should be adjusted below the temperature at which melanoidin is not generated in the first hydrothermal treatment device 2. In addition, a camera or video and a light to photograph or record the inside of the first hydrothermal treatment device 2 may be provided to allow the user to check the improved shrinkage of the waste.
In the first embodiment, two hydrothermal treatment devices, i.e., the first hydrothermal treatment device and the second hydrothermal treatment device are provided, and two hydrothermal treatments are performed on the waste by different hydrothermal treatment devices, but the embodiment is not limited thereto. As shown in
Next, the waste treatment system according to the second embodiment will be described. The waste treatment system according to the second embodiment is configured such that washing water is supplied to the first solid-liquid separation device 3 and the second solid-liquid separation device 13 in contrast to the first embodiment. In the second embodiment, the same constituent elements as those in the first embodiment are associated with the same reference numerals and not described again in detail.
As shown in
The operation of hydrothermal treatment of waste in the first hydrothermal treatment device 2 of the waste treatment system 1 according to the second embodiment of the present disclosure is the same as the first embodiment. Then, the first reactant of the first hydrothermal treatment device 2 is separated into a solid and a liquid by the first solid-liquid separation device 3, but water adheres to or is contained in the solid separated by the first solid-liquid separation device 3. If this water contains saccharides and proteins, the hydrothermal treatment in the second hydrothermal treatment device 12 may produce melanoidin. However, in the second embodiment, since the solid is washed by washing water during solid-liquid separation in the first solid-liquid separation device 3, compared to the case without washing, the saccharides and proteins contained in the separated solid can be reduced, and as a result, melanoidin that can be generated by the hydrothermal treatment in the second hydrothermal treatment device 12 can be reduced.
If the waste treatment system 1 includes the colored substance sensors 15 to 18, and it is determined that the amount of melanoidin flowing into the fermentation device 6 is high based on the detected values, the flow rate of washing water supplied to the first solid-liquid separation device 3 may be increased. When the flow rate of washing water is increased, the washing of the solid during solid-liquid separation in the first solid-liquid separation device 3 is enhanced, so that more nitrogen-containing components, which may cause melanoidin formation, can be transferred to the liquid. This reduces the nitrogen-containing components in the solid hydrothermally treated in the second hydrothermal treatment device 12, and thus appropriately reduces melanoidin that can be generated due to the hydrothermal treatment in the second hydrothermal treatment device 12. Further, other effects such as simply reducing the concentration of inhibitors can also be expected by increasing the flow rate of washing water.
The solid separated by the second solid-liquid separation device 13 is disposed of as a material unsuitable for fermentation. However, since the solid separated by the second solid-liquid separation device 13 has moisture attached or contained therein, if this moisture contains easily degradable organic matter, the easily degradable organic matter that should be used as the raw material for fermentation in the fermentation device 6 is disposed of together with the solid such as metal and plastic, and the yield of the fermented substance is reduced. However, in the second embodiment, since the solid is washed by washing water during solid-liquid separation in the second solid-liquid separation device 13, compared to the case without washing, the easily degradable organic matter supplied to the fermentation device 6 can be increased, and the yield of the fermented substance can be improved.
Next, the waste treatment system according to the third embodiment will be described. The waste treatment system according to the third embodiment is configured such that waste is divided and supplied to the first hydrothermal treatment device 2 and the second hydrothermal treatment device 12 in contrast to the first or second embodiment. In the following, the third embodiment will be described in conjunction with the configuration where waste is divided and supplied based on the second embodiment, but the third embodiment may be implemented with the configuration where waste is divided and supplied based on the first embodiment. In the third embodiment, the same constituent elements as those in the second embodiment are associated with the same reference numerals and not described again in detail.
As shown in
In the third embodiment, for example, waste 2 containing a large amount of persistent fibers (e.g., paper such as used paper or recycled paper, biomass containing a large amount of fiber material) can be supplied to the second hydrothermal treatment device 12, while waste 1 other than waste 2 can be supplied to the first hydrothermal treatment device 2. In other words, the waste can be divided and supplied separately to the first hydrothermal treatment device 2 and the second hydrothermal treatment device 12 according to the type. Since the waste 2 contains few nitrogen-containing substances, the waste 2 does not need to undergo hydrothermal treatment at a relatively low temperature in the first hydrothermal treatment device 2. On the other hand, when the waste 2 that only needs to be hydrothermally treated at a relatively high temperature to refine and organically oxidize the fibers is supplied to the second hydrothermal treatment device 12, the efficiency of the hydrothermal treatment in each of the first hydrothermal treatment device 2 and the second hydrothermal treatment device 12 can be improved.
For example,
Fermentation in the organic fertilizer production device 6a preferably allows the added anti-fungal bacteria to grow appropriately. If the liquid received by the organic fertilizer production device 6a contains waste-derived germs, these germs may inhibit the growth of the anti-fungal bacteria and prevent the fermentation from progressing appropriately. However, since the liquid received by the organic fertilizer production device 6a is part of the first reactant and the second reactant hydrothermally treated in the first hydrothermal treatment device 2 and the second hydrothermal treatment device 12 respectively, the germs in the wastes 1 and 2 are sterilized during the hydrothermal treatments in the first hydrothermal treatment device 2 and the second hydrothermal treatment device 12. In the organic fertilizer production device 6a, since the anti-fungal bacteria are added to the liquid where germs have been sterilized, the anti-fungal bacteria can appropriately multiply during fermentation, and the fermentation can proceed appropriately. Further, the first hydrothermal treatment device 2 is expected to solubilize nitrogen-containing components in the waste 1, and the second hydrothermal treatment device 12 is expected to decompose fiber materials in the waste 2.
The ratio of carbon components to nitrogen components (C/N ratio) is important as the index of the composition of a good organic fertilizer produced by the organic fertilizer production device 6a, and the C/N ratio is preferably 40 or less. The nitrogen component is mainly present in the liquid separated by the first solid-liquid separation device 3 from the waste 1 decomposed in the first hydrothermal treatment device 2, while the carbon component is mainly present in the liquid separated by the second solid-liquid separation device 13 from the solid of the first reactant and the waste 2 decomposed in the second hydrothermal treatment device 12. Therefore, by supplying the necessary amount of the liquid separated by the first solid-liquid separation device 3 to the organic fertilizer production device 6a, the C/N ratio can be adjusted to 40 or less.
If not all of the liquid separated by the first solid-liquid separation device 3 is supplied to the organic fertilizer production device 6a in order to adjust the C/N ratio, the waste treatment system 1 may be equipped with a liquid fertilizer production device 6b as the fermentation device 6 to produce a liquid fertilizer from the remaining liquid.
Next, the waste treatment system according to the fourth embodiment will be described. In the waste treatment system according to the fourth embodiment, the fermentation device 6 is limited to a methane fermentation device for producing biogas in contrast to the first embodiment. In the fourth embodiment, the same constituent elements as those in the first embodiment are associated with the same reference numerals and not described again in detail.
As shown in
Although not a required component, the waste treatment system 1 according to the fourth embodiment of the present disclosure may include colored substance sensors 15 and 16 for detecting the index of the colored substance in the liquids separated by the first solid-liquid separation device 3 and the second solid-liquid separation device 13. Instead of the colored substance sensors 15, 16, the system may include a colored substance sensor 17 for detecting the index of the colored substance in a liquid after joining the liquids separated by the first solid-liquid separation device 3 and the second solid-liquid separation device 13 and before flowing into the methane fermentation device 6c. In addition, a colored substance sensor 18 may be provided in the methane fermentation device 6c to detect the index of the colored substance in the methane fermentation device 6c.
Although not a required component, the waste treatment system 1 according to the fourth embodiment of the present disclosure may include pH sensors 25 and 26 for detecting the pH of the liquids separated by the first solid-liquid separation device 3 and the second solid-liquid separation device 13. Instead of the two pH sensors 25, 26, the system may include a pH sensor 27 for detecting the pH of a liquid after joining the liquids separated by the first solid-liquid separation device 3 and the second solid-liquid separation device 13 and before flowing into the methane fermentation device 6c. In addition, a pH sensor 28 may be provided in the methane fermentation device 6c to detect the pH in the methane fermentation device 6c.
Although not a required component, the waste treatment system 1 according to the fourth embodiment of the present disclosure may include sodium sensors 35 and 36 for detecting the concentration of sodium in the liquids separated by the first solid-liquid separation device 3 and the second solid-liquid separation device 13. Instead of the two sodium sensors 35, 36, the system may include a sodium sensor 37 for detecting the concentration of sodium in a liquid after joining the liquids separated by the first solid-liquid separation device 3 and the second solid-liquid separation device 13 and before flowing into the methane fermentation device 6c. In addition, a sodium sensor 38 may be provided in the methane fermentation device 6c to detect the concentration of sodium in the methane fermentation device 6c.
Although not a required component, the waste treatment system 1 according to the fourth embodiment of the present disclosure may include organic acid concentration sensors 45 and 46 for detecting the concentration of organic acid in the liquids separated by the first solid-liquid separation device 3 and the second solid-liquid separation device 13. Instead of the two organic acid concentration sensors 45, 46, the system may include an organic acid concentration sensor 47 for detecting the concentration of organic acid in a liquid after joining the liquids separated by the first solid-liquid separation device 3 and the second solid-liquid separation device 13 and before flowing into the methane fermentation device 6c. In addition, an organic acid concentration sensor 48 may be provided in the methane fermentation device 6c to detect the concentration of organic acid in the methane fermentation device 6c.
Although not a required component, the waste treatment system 1 according to the fourth embodiment of the present disclosure may include ammonia concentration sensors 65 and 66 for detecting the concentration of ammonia in the liquids separated by the first solid-liquid separation device 3 and the second solid-liquid separation device 13. Instead of the two ammonia concentration sensors 65, 66, the system may include an ammonia concentration sensor 67 for detecting the concentration of ammonia in a liquid after joining the liquids separated by the first solid-liquid separation device 3 and the second solid-liquid separation device 13 and before flowing into the methane fermentation device 6c. In addition, an ammonia concentration sensor 68 may be provided in the methane fermentation device 6c to detect the concentration of ammonia in the methane fermentation device 6c.
Next, operation of the waste treatment system 1 according to the fourth embodiment of the present disclosure will be described.
The operation of hydrothermal treatment in the first hydrothermal treatment device 2 and the second hydrothermal treatment device 12 and the operation of solid-liquid separation in the first solid-liquid separation device 3 and the second solid-liquid separation device 13 are the same as the first embodiment. In the fourth embodiment, the liquid of the first reactant and the liquid of the second reactant are separately supplied to the methane fermentation device 6c.
In the methane fermentation device 6c, methane fermentation of the liquid of the first reactant and the liquid of the second reactant produces biogas. Methane fermentation can be performed under anaerobic conditions, for example, between 30° C. and 60° C., preferably between 50° C. and 60° C. for high-temperature methane fermentation using bacteria that act at high temperatures, or between 30° C. and 40° C. for medium-temperature methane fermentation using bacteria that act at medium temperatures. The produced biogas may be purified to obtain methane gas, and the biogas or methane gas may be stored in a storage facility.
In the case where the waste treatment system 1 according to the fourth embodiment of the present disclosure includes the colored substance sensors 15 to 18, as with the operation in the first embodiment, the amount of colored substance flowing into the methane fermentation device 6c can be reduced based on the detected values by the colored substance sensors 15 to 18.
When the pH of the liquid flowing into the methane fermentation device 6c decreases, and the supply amount of organic acid is greater than the amount of organic acid that can be decomposed in the methane fermentation device 6c, the pH in the methane fermentation device 6c decreases, and a phenomenon called rancidification, in which the production amount of biogas decreases or stops, occurs. In response, by supplying an appropriate amount of alkaline substance at an appropriate timing from the alkaline substance supply device 43 based on the detected value by the pH sensor 28, the pH of the liquid can be increased, and the phenomenon where the biogas production decreases or stops can be suppressed.
Generally, a factor that decreases the pH of the liquid is the excessive amount of organic acid produced by the hydrothermal treatment of at least one of the first hydrothermal treatment device 2 or the second hydrothermal treatment device 12. If the pH sensors 25, 26 and the organic acid concentration sensors 45, 46 are provided, by comparing the respective detected values of the sensors, it is possible to determine which hydrothermal treatment produces excessive organic acid. In this case, by lowering the hydrothermal temperature and shortening the residence time in the hydrothermal treatment device that is determined to produce excessive organic acid, the production of excessive organic acid can be suppressed, so that the pH of the liquid can be increased, and the phenomenon where biogas generation stops can be suppressed. In order to directly detect the phenomenon where the production amount of biogas decreases or stops, a gas chromatography or a flow meter may be provided at the gas outlet of the methane fermentation device 6c.
It is known that inhibition of methane fermentation occurs when the sodium concentration in the liquid flowing into the methane fermentation device 6c increases and the sodium concentration in the methane fermentation device 6c increases. In response, by diluting the liquid flowing into the methane fermentation device 6c by adding clean water based on the sodium concentration detected by the sodium sensors 35 to 38, the sodium concentration in the liquid can be reduced before methane fermentation inhibition occurs, so that methane fermentation inhibition can be suppressed.
However, the addition of clean water has the disadvantage of increasing the amount of wastewater discharged outside the waste treatment system 1. Therefore, it is preferable to add clean water while lowering the temperature of the hydrothermal treatment in the second hydrothermal treatment device 12 to shorten the residence time. When the temperature of the hydrothermal treatment in the second hydrothermal treatment device 12 is lowered to shorten the residence time, the organic oxidation and saccharification in the second hydrothermal treatment device 12 are suppressed, and with a large amount of solid residue in the reactant flowing out of the second hydrothermal treatment device 12, the liquid separated by the second solid-liquid separation device 13 is supplied to the methane fermentation device 6c. This reduces the decomposition rate of methane fermentation, resulting in a larger amount of solids discharged from the methane fermentation device 6c and a larger amount of dehydrated sludge discharged outside the waste treatment system 1. As a result, the amount of wastewater discharged outside the waste treatment system 1 can be suppressed. In order to confirm the suppression of organic oxidation in the second hydrothermal treatment device 12, the organic acid concentration sensor 46 may be provided together with the sodium sensor 36.
If compositional changes occur in waste, for example, if the caloric value of waste decreases or if ash or plastic components in waste increases, the amount of material unsuitable for fermentation to be disposed of increases, and the production amount of biogas decreases. In response, a weight sensor 40 for material unsuitable for fermentation may be provided in the waste treatment system 1. If it is judged that ash or plastic components in waste increases based on an increase in the detected value by the weight sensor 40 for material unsuitable for fermentation, the supply amount of waste may be increased to suppress the decrease in the production amount of biogas.
The hydrothermal reaction decomposes nitrogen-containing organic matter in waste to produce ammonia. Since ammonia is an inhibitor of methane fermentation, the ammonia concentration may be reduced by, for example, increasing the supply amount of paper that does not contain nitrogen-containing organic matter to the hydrothermal treatment device based on the ammonia concentration detected by the ammonia concentration sensors 65 to 68. Alternatively, the ammonia concentration may be reduced by adding diluted water to the liquid flowing into the methane fermentation device 6c, or by increasing the amount of washing water supplied to the solid-liquid separation device.
As for the sensors installed in the waste treatment system 1, if continuous or direct detection is impossible, so-called soft sensors may be used, which allow estimation by calculation from one or more other detected values.
Next, the waste treatment system according to the fifth embodiment will be described. In the waste treatment system according to the fifth embodiment, the fermentation device 6 includes both a methane fermentation device and an organic fertilizer production device, in contrast to the fourth embodiment. In the fifth embodiment, the same constituent elements as those in the fourth embodiment are associated with the same reference numerals and not described again in detail.
As shown in
In the fifth embodiment, the operation of hydrothermally treating waste and producing biogas in the methane fermentation device 6c is the same as the fourth embodiment. Further, the operation of fermenting the liquids separated by the first solid-liquid separation device 3 and the second solid-liquid separation device 13 and producing an organic fertilize in the organic fertilizer production device 6a is the same as the third embodiment (see the configuration of
In the fifth embodiment, as well as fermentation in the methane fermentation device 6c, fermentation in the organic fertilizer production device 6a stops when the pH of the liquid flowing into the organic fertilizer production device 6a decreases. In response, by supplying an appropriate amount of alkaline substance at an appropriate timing from the alkaline substance supply device 42 based on the detected value by the pH sensor 29, the pH of the liquid can be increased, and the phenomenon where the fermentation stops in the organic fertilizer production device 6a can be suppressed.
Next, the waste treatment system according to the sixth embodiment will be described. The waste treatment system according to the sixth embodiment is additionally provided with a boiler for combusting residue of methane fermentation in the methane fermentation device 6c, in contrast to the fifth embodiment. In the sixth embodiment, the same constituent elements as those in the fifth embodiment are associated with the same reference numerals and not described again in detail.
As shown in
The operation of producing organic fertilizer and biogas in the waste treatment system 1 according to the sixth embodiment of the present disclosure is the same as the fifth embodiment. In the waste treatment system 1 according to the sixth embodiment of the present disclosure, the solid component obtained by dehydration of residue of methane fermentation by the dehydration/drying device 52 is combusted in the boiler 60. Since ash after combustion in the boiler 60 is alkaline, the ash extracted from the boiler 60 into the extraction line 61 is supplied as an alkaline substance to the methane fermentation device 6c or the organic fertilizer production device 6a via the first ash supply line 62 or the second ash supply line 63. The presence or absence of ash supply and the amount of ash supplied to each can be adjusted appropriately based on the detected value by at least one of the pH sensors 25 to 27.
The liquid component produced by dehydration of residue of methane fermentation by the dehydration/drying device 52 is supplied as washing water to the first solid-liquid separation device 3 and the second solid-liquid separation device 13 via the washing water supply line 55 and the branch line 56, so that the solids can be washed during the solid-liquid separation in the first solid-liquid separation device 3 and the second solid-liquid separation device 13. As already described in the second embodiment, in this case, it is not necessary to prepare water separately as washing water, so the operating cost of the waste treatment system 1 can be reduced.
In the sixth embodiment, steam produced by the boiler 60 may be used as the steam supplied to each or either one of the first hydrothermal treatment device 2 and the second hydrothermal treatment device 12.
Next, the waste treatment system according to the seventh embodiment will be described. In the waste treatment system according to the seventh embodiment, the second hydrothermal treatment device 12 is modified to a pulper in contrast to the first embodiment. In the seventh embodiment, the same constituent elements as those in the first embodiment are associated with the same reference numerals and not described again in detail.
As shown in
The waste treatment system 1 further includes a dehydration device 11 for dehydrating the liquid separated by the second solid-liquid separation device 13. The dehydration device 11 is configured such that water or hot water separated in the dehydration device 11 is supplied to the pulper 10. The liquid separated by the first solid-liquid separation device 3 and the solid component obtained by dehydration in the dehydration device 11 are supplied to the methane fermentation device 6c. The configuration is otherwise the same as that of the first embodiment, except that the second hydrothermal treatment device 12 (see
In the seventh embodiment, the operation of hydrothermal treatment of waste in the first hydrothermal treatment device 2 and solid-liquid separation of the first reactant in the first solid-liquid separation device 3 is the same as the first embodiment. The solid separated by the first solid-liquid separation device 3 is supplied to the pulper 10. Water or hot water is also supplied to the pulper 10. Fibers in the solid supplied to the pulper 10 are disentangled in water or hot water. The effluent from the pulper 10 flows into the screen, which is the second solid-liquid separation device 13, but the disentangled fibers pass through the screen. Those that cannot pass through the screen are disposed of as a material unsuitable for fermentation.
The effluent from the screen is dehydrated by the dehydration device 11, and the dehydrated water or hot water is supplied to the pulper 10 for reuse, while the dehydrated solid component is supplied to the methane fermentation device 6c. The liquid separated by the first solid-liquid separation device 3 is also supplied to the methane fermentation device 6c. The methane fermentation device 6c ferments them to produce biogas.
Thus, since the fibers in the solid separated by the first solid-liquid separation device 3 are disentangled by the pulper 10 and supplied to the methane fermentation device 6c after removing a material unsuitable fermentation by the second solid-liquid separation device 13, the fermentation and decomposition rate in the methane fermentation device 6c can be improved.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2019-066030 | Mar 2019 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2020/004007 | 2/4/2020 | WO | 00 |
