Water-absorbent acrylic acid polymer gels

Abstract

Improved acrylic acid absorbency resins are made utilizing a chain transfer agent during the polymerization process.

Description

INTRODUCTION

Water absorbent resins are used in the manufacture of such items as menstrual articles, diapers, dish cloths and the like. The also find use in the field of agriculture and horticulture as water retentive materials. Further, they are useful in other various fields such as coagulation of sludges, prevention of condensation, the dehydration of oils, etc.

Typical of resins capable of acting as absorbent resins are the crosslinked polyacrylic acid salt polymers. Outstanding resins of this type, in that they exhibit excellent salt solution absorbency, are the acrylic acid resins described in U.S. Pat. No. 4,340,706 The resins of this patent are particularly useful in producing absorbent products such as sanitary napkins and disposable diapers.

The method of producing these resins is generally described in U.S. Pat. No. 4,340,706 as: "a process for producing an alkali metal acrylate or ammonium acrylate polymer having excellent salt solution absorbency, characterized by suspending an aqueous solution of acrylic acid and an alkali metal acrylate or ammonium acrylate, the mole ratio of the acrylic acid to the alkali metal acrylate or ammonium acrylate being 50/50 to 2/98, in an alicyclic or aliphatic hydrocarbon solvent containing a surfactant having an HLB value of 8-12, subjecting the resulting suspension to inverse suspension polymerization in the presence of a water-soluble radical polymerization initiator and, if necessary, crosslinking the resulting polymer with a crosslinking agent."

The disclosure of U.S. Pat. No. 4,340,706 is incorporated herein by reference and is made a part hereof.

While a variety of crosslinking compounds can be used to practice this patented process, the water-soluble glycidyl ether compounds are particularly preferred. Illustrative of such crosslinking agents are the water-soluble diglycidyl ether compound including, for example, (poly)-ethylene glycol diglycidyl ether, (poly)-propylene glycol diglycidyl ether, (poly)-glycerin diglycidyl ether, and the like.

The present invention is directed to a method of producing absorbent resins of the type produced in U.S. Pat. No. 4,340,706 which have a much higher water-holding and saline absorbency capacity than those produced without using the improvements described herein.

THE INVENTION

An improved process for producing an alkali metal acrylate or ammonium acrylate polymer having excellent salt solution absorbency of the type characterized by suspending an aqueous solution of acrylic acid and an alkali metal acrylate or ammonium acrylate, the mole ratio of the acrylic acid to the alkali metal acrylate or ammonium acrylate being 50/50 to 2/98, in an alicyclic or aliphatic hydrocarbon solvent containing a surfactant having an HLB value of 8-12, subjecting the resulting suspension to inverse suspension polymerization in the presence of a water-soluble radical polymerization initiator and, if necessary, crosslinking the resulting polymer with a crosslinking agent, the improvement which comprises conducting the polymerization in the presence of a water-soluble chain transfer agent.

A variety of chain transfer agents can be used such as, for example, thiols, amines, secondary alcohols such as isopropyl alcohol, bisulfite ion, monobasic sodium phosphate and the thiol acids such as 3-mercaptopropionic acid. The preferred chain transfer agent that gives outstanding results is formic acid which may be used as a free acid or in the form of its alkali metal or ammonium salt.

The amount of chain transfer agent used will usually be at least 0.3% by weight based on monomer (BOM) with a preferred range being about 0.4-1 to 2% by weight BOM.

The method of preparing the polymer as previously indicated is described in U.S. Pat. No. 4,340,706. To illustrate the advantages of the invention, there is set forth below a typical reactant menu.

______________________________________Chemical Name Percent______________________________________Heptane 62.56Sorbitan monostearate Rx 4 moles EO .55Acrylic acid 11.5650% sodium hydroxide 10.02DI water 12.12Sodium formate .04Potassium persulfate .04DI water .91Heptane 1.62Sorbitan monolaurate .55Ethylene glycol diglycidyl ether .03 100.00%______________________________________

A typical reaction using the above ingredients would be as follows:

The monomer solution was prepared by first diluting the sodium hydroxide with D.I. water, then adding the acrylic acid slowly while maintaining the temperature below 40.degree. C. with cooling. The chain transfer agent was dissolved in the monomer solution at 25.degree. C. Ethylene oxide sorbitan monostearate was dissolved in heptane and charged to the reactor. Agitation was started and the monomer solution was added followed immediately by the initiator solution. The resulting unstable suspension was heated to 55.degree. C., then purged with nitrogen. The heat of polymerization causes the mixture to reflux. After 1.5 hours sorbitan monolaurate was added, then water was removed by azeotropic distillation. Finally, the crosslinker was added. After cooling, the polymer was collected by filtration and dried.

A number of examples are set forth below illustrating the advantages of the invention using the general preparative techniques and general reaction conditions described above.

EXAMPLE 1

In these laboratory experiments, crosslinker was added after water removal to maximize the effect of the chain transfer agent. Results for sodium formate are shown in Table 1. With 0.12 mole percent EGDGE.sup.1 as the crosslinker, 50 to 90% increases in capacity were obtained in the range 0.4 to 0.5 mole percent formate (BOM). With 1,4-butanediol diglycidyl ether (BDDGE) as the crosslinker, up to 75% increases in capacity were achieved.

.sup.1 Ethylene glycol diglycidyl ether

Capacity was measured for free swell absorption of 1.6% sodium chloride solution. A 1.00 g sample of polymer was added with stirring to 200 g saline. After stirring for 5 minutes the gel was poured onto a 100 mesh screen and the unabsorbed saline was drained off. The capacity equals the grams of 1.6% saline absorbed per gram of polymer.

Speed was measured for absorption of 1.6% sodium chloride solution. A 1.00 g sample of polymer was weighed in a small aluminum dish. 30 grams of saline was added and the time required for complete absorption of the saline without stirring was measured.

TABLE I__________________________________________________________________________Effect of FormateReaction Acid X-Link Level Formate Level Speed CapacityNo. Reactor Lot X-Linker (mole % BOM) (mole % BOM) (sec) (g/g)__________________________________________________________________________1 2 liter 204 EGDGE 0.12 0.0 8.4 472 2 liter 209 EGDGE 0.12 0.2 6.8 503 2 liter 204 EGDGE 0.12 0.3 11.0 624 2 liter 262 EGDGE 0.12 0.4 15.0 705 2 liter 209 EGDGE 0.12 0.4 27.0 906 2 liter 209 EGDGE 0.12 0.4 21.0 757 2 liter 204 EGDGE 0.12 0.5 14.0 728 2 liter 262 EGDGE 0.2 B4 0.10 0.5 11.0 649 2 liter 204 EGDGE 0.08 0.5 14.0 6010 2 liter 204 EGDGE 0.00 0.5 120.0 Too soluble11 2 liter 204 EGDGE 0.12 0.7 31.0 6412 2 liter 1,4-BDDGE 0.10 0.0 8.0 5713 2 liter 209 1,4-BDDGE 0.12 0.2 9.0 5714 2 liter 204 1,4-BDDGE 0.12 0.3 18.0 8015 2 liter 204 1,4-BDDGE 0.10 0.5 45.0 10016 15 liter 209 EGDGE 0.12 0.5 38.0 6517 15 liter 209 EGDGE 0.12 0.3 7.5 44__________________________________________________________________________

EXAMPLE 2

Results for experiments using isopropyl alcohol (IPA) and monobasic sodium phosphate as chain transfer agents are summarized in Table II. Although not as effective as sodium formate, IPA at sufficiently high levels (5.7 mole percent BOM) does lead to .about.10% increase in capacity. Using 0.2 mole percent BOM monobasic sodium phosphate, an increase incapacity of .about.15% was achieved.

TABLE II______________________________________Effect of Chain Transfer AgentRe- Moleac- Mole % % Capac-tion Cross BOM CTA Speed ityNo. Linker X-Linker CTA BOM (sec) (ml/g)______________________________________1 EGDGE 0.12 None 0 5.3 482 EGDGE 0.12 IPA 1.1 4.5 493 EGDGE 0.12 IPA 5.7 16.9 534 EGDGE 0.12 IPA 11.4 >180 245 BDDGE 0.1 None 0 626 BDDGE 0.1 NaH2PO4 0.2 25.2 717 BDDGE 0.1 NaH2PO4 0.5 27.6 72______________________________________

EXAMPLE 3

Several absorbent polymers were prepared using 3-mercaptopropionic acid in place of sodium formate (Table III). High levels severely inhibited the polymerization. Low and moderate levels showed up to 17% increased capacity over the blank. The most active range may lie somewhere between 0.04 and 0.4 mole percent.

TABLE III______________________________________Effect of 3-Mercaptopropionic Acid EGDGE Merc Level LevelReaction Acid (mole % (mole % Speed CapacityNo. Lot BOM) BOM) (sec) (g/g)______________________________________1 262 0.12 0.400 polymerization inhibited2 262 0.12 0.800 polymerization inhibited3 262 0.12 0.004 14 474 262 0.12 0.008 17 485 209 0.12 0.040 8 436 209 0.12 0.000 11 41______________________________________

Claims

1. An improved process for producing an alkali metal acrylate or ammonium acrylate polymer having excellent salt solution absorbency, characterized by suspending an aqueous solution of acrylic acid and an alkali metal acrylate or ammonium acrylate, the mole ratio of the acrylic acid to the alkali metal acrylate or ammonium acrylate being 50/50 to 2/98, in an alicyclic or aliphatic hydrocarbon solvent containing a surfactant having an HLB value of 8-12, subjecting the resulting suspension to inverse suspension polymerization in the presence of a water-soluble radical polymerization initiator and, if necessary, crosslinking the resulting polymer with a crosslinking agent, the improvement which comprises conducting the polymerization in the presence of a water-soluble chain transfer agent.

2. The process of claim 1 where the water-soluble chain transfer agent is formic acid.

3. The method of claim 2 where a glycidyl ether crosslinking agent is employed.