Water-based adhesive

Information

  • Patent Grant
  • 5652298
  • Patent Number
    5,652,298
  • Date Filed
    Wednesday, July 24, 1996
    28 years ago
  • Date Issued
    Tuesday, July 29, 1997
    27 years ago
Abstract
The present invention provides an organic solvent-free composition useful as an adhesive for bonding natural rubber compounds, synthetic rubber compounds and a combination of natural and synthetic rubber compounds.
Description
Claims
  • 1. A composition having no organic solvents contained therein, said composition useful as an adhesive and comprising by weight percent based on total weight of said composition:
  • about 25.0 to 50.0% of an elastomer selected from the group consisting of natural rubber, styrene butadiene rubber, polybutadiene rubber, polychloroprene rubber, nitrile rubber, polyurethane rubber, butyl rubber and mixtures thereof; about 40.0 to 60.0% water;
  • about 0.02 to 0.60% pH adjusters selected from the group consisting of potassium hydroxide, aqueous ammonia and mixtures thereof;
  • about 0.10 to 1.8% surfactant/stabilizer selected from the group consisting of sodium lignosulfate, octylphenoxypolyethoxyethanol, polyoxyethylene sorbitol fatty acid ester, sulfated fatty acid and mixtures thereof; and
  • from about 0.51 to 10.0% carbon black selected from the group consisting of N-300 and N-200 series and mixtures thereof.
  • 2. An article of manufacture, having applied thereupon a composition comprising by weight percent based on total weight of said composition:
  • about 25.0 to 50.0% of an elastomer selected from the group consisting of natural rubber, styrene butadiene rubber, polybutadiene rubber, polychloroprene rubber, nitrile rubber, polyurethane rubber, butyl rubber and mixtures thereof;
  • about 40.0 to 60.0% water;
  • about 0.02 to 0.60% pH adjusters selected from the from the group consisting of potassium hydroxide, aqueous ammonia and mixtures thereof;
  • about 0.10 to 1.8% surfactant/stabilizer selected from the group consisting of sodium lignosulfate, octylphenoxypolyethoxyethanol, polyoxyethylene sorbitol fatty acid ester, sulfated fatty acid and mixtures thereof; and
  • from about 0.51 to 10.0% carbon black selected from the group consisting of N-300 and N-200 series and mixtures thereof.
  • 3. The article of manufacture of claim 2 being a rubber article made of natural or synthetic rubber or a mixture of natural and synthetic rubber.
  • 4. The article of manufacture of claim 3, wherein said composition further comprises up to about 0.50% viscosity adjusters selected from the group consisting of hydroxyethyl cellulose, hydroxypropyl methylcellulose and mixtures thereof.
  • 5. The article of manufacture of claim 3, wherein said composition further comprises up to about 23.0% resin emulsion selected from the group consisting of alkylphenol novolac, hydrogenated rosin, modified rosin ester and mixtures thereof.
  • 6. The composition of claim 1, wherein said composition further comprises from about 0.03 to 0.75% zinc oxide; from about 0.02 to 0.40% sulfur; and from about 0.01 to 0.20% accelerator selected from the group consisting of dibenzothiazyl disulfide, tetraethyl thiuram disulfide, tetramethyl thiuram disulfide, tetramethyl thiuram monosulfide, n-tert-butyl-2-benzothiazolesulfenamide, diphenyl guanidine and mixtures thereof.
  • 7. The article of manufacture of claim 2, wherein said composition further comprises from about 0.03 to 0.75% zinc oxide; from about 0.02 to 0.40% sulfur; and from about 0.01 to 0.20% accelerator selected from the group consisting of dibenzothiazyl disulfide, tetraethyl thiuram disulfide, tetramethyl thiuram disulfide, tetramethyl thiuram monosulfide, n-tert-butyl-2-benzothiazolesulfenamide, diphenyl guanidine and mixtures thereof.
Parent Case Info

This application is a continuation of application Ser. No. 08/470,915, filed Jun. 6, 1995, now abandoned, which is a division of 08/305,017 filed Sep. 13, 1994, allowed which is a continuation-in-part application of application Ser. No. 08/180,679, now U.S. Pat. No. 5,395,879.

US Referenced Citations (9)
Number Name Date Kind
3843484 Kamiyoshi Oct 1974
3857730 Kalafus et al. Dec 1974
3947394 Kalafus et al. Mar 1976
4026744 Elmer May 1977
4285756 Elmer Aug 1981
4440881 Girgis Apr 1984
4463120 Collins et al. Jul 1984
4772499 Greenway Sep 1988
5395879 Murray Mar 1995
Divisions (1)
Number Date Country
Parent 305067 Sep 1994
Continuations (1)
Number Date Country
Parent 470915 Jun 1995
Continuation in Parts (1)
Number Date Country
Parent 180679 Jan 1994