Claims
- 1. A coating composition comprising
- (I) about 20 weight percent to about 35 weight percent of a water-dissipatable polyester comprising:
- (i) monomer residues of at least one dicarboxylic acid;
- (ii) about 4 to 25 mole percent, based on the total of all acid, hydroxy and amino equivalents, of monomer residues of at least one difunctional sulfo monomer containing at least one sulfonate group bonded to an aromatic ring where the functional groups are hydroxy, carboxyl or amino;
- (iii) monomer residues of at least one diol or a mixture of a diol and a diamine; and optionally,
- (iv) monomer residues of at least one difunctional monomer reactant selected from hydroxycarboxylic acids, aminocarboxylic acids and aminoalkanols;
- provided that at least 20 percent of the groups linking the monomeric units are ester linkages; said water dissipatable polyester having from about 0.1 ppm by weight to about 10% by weight of a thermally stable near infrared flouorphoric compound copolymerized therein; and
- (II) about 65 weight percent to about 80 weight percent of water.
- 2. The coating composition of claim 1, wherein component (iii) is comprised of
- (a) at least 15 mole percent, based on the total mole percent of diol monomer residues or diol and diamine monomer residues, of a diol having the formula --(OCH.sub.2 CH.sub.2).sub.n -- where n is 2 to about 20, or
- (b) about 0.1 to less than about 15 mole percent, based on the total mole percent of diol monomer residues or diol and diamine monomer residues, of monomer residues of a poly(ethylene glycol) having the formula --(OCH.sub.2 CH.sub.2).sub.n -- where n is 2 to about 500, provided that the mole percent of such residues is inversely proportional to the value of n.
- 3. The coating composition of claim 1, wherein the near infrared flourescing compound is selected from the classes of phthalocyanines, 2,3-naphthalocyanines and squaraines and correspond to Formulae II, III and IV: ##STR32## wherein Pc and Nc represent the phthalocyanine and 2,3-naphthalocyanine moieties of Formulae IIa and IIIa, ##STR33## respectively, covalently bonded to hydrogen or to various metals, halometals, organometallic groups, and oxymetals selected from a group consisting of AlCl, AlBr, AlF, AlOH, AlOR.sub.5, AlSR.sub.5, Ca, Co, CrF, Fe, Ge, Ga, InCl, Mg, Mn, Ni, Pb, Pt, Pd, SiCl.sub.2, SiF.sub.2, SnCl.sub.2, Sn(OR.sub.6).sub.2, Si(OR.sub.6).sub.2, Sn(SR.sub.6).sub.2, Si(SR.sub.6).sub.2, Sn, VO, TiO, or Zn,
- wherein
- R.sub.5 and R.sub.6 are selected from hydrogen, C.sub.1 -C.sub.12 alkyl, phenyl, lower alkanoyl, trifluoroacetyl and groups of the formulae ##STR34## R.sub.7, R.sub.8 and R.sub.9 are independently selected from C.sub.1 -C.sub.12 alkyl, phenyl or phenyl substituted with lower alkyl, lower alkoxy or halogen;
- X is selected from oxygen, sulfur, selenium, tellurium or a group of the formula --N-R.sub.10, wherein R.sub.10 is hydrogen, C.sub.3 -C.sub.8 cycloalkyl, C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.10 acyl, C.sub.1 -C.sub.12 alkylsulfonyl, or phenyl or R.sub.10 and R taken together form an aliphatic or aromatic ring with the nitrogen atom to which they are attached;
- Y is selected from C.sub.1 -C.sub.12 alkyl, phenyl, halogen and hydrogen;
- R is selected from unsubstituted or substituted C.sub.1 -C.sub.12 alkyl, alkenyl, or
- C.sub.3 -C.sub.8 cycloalkyl, phenyl, heteroaryl, ##STR35## --(X-R).sub.m is alkylsulfonylamino, arylsulfonylamino, or a group selected from the formulae --X(C.sub.2 H.sub.4 O).sub.z R.sup.1, ##STR36## wherein R.sup.1 is hydrogen or R as defined above; Z is an integer of from 1-4;
- or two --(X-R).sub.m groups taken together to form divalent substituents of the formula ##STR37## wherein each X.sup.1 is independently selected from --O--, --S--, and --N-R.sub.10 and A is selected from ethylene; propylene; trimethylene; and said groups substituted with C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, aryl and cycloalkyl; 1,2-phenylene and 1,2-phenylene containing 1-3 substituents selected from C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy and halogen;
- R.sub.1 and R.sub.2 are independently selected from hydrogen, lower alkyl, lower alkoxy, halogen, aryloxy, lower alkylthio, arylthio, lower alkylsulfonyl; arylsulfonyl; lower alkylsulfonylamino, arylsulfonylamino, cycloalkylsulfonylamino, carboxy, unsubstituted and substituted carbamoyl and sulfamoyl, lower alkoxycarbonyl, hydroxy, lower alkanoyloxy, ##STR38## R.sub.3 and R.sub.4 are independently selected from hydrogen, lower alkyl, alkenyl or phenyl; n is an integer from 0-12; n.sub.1 is an integer from 0-24, m is an integer from 4-16; m.sub.1 is an integer from 0-16; provided that the sums of n+m and n.sub.1 +m.sub.1 are 16 and 24, respectively, provided that at least one polyester reactive group is present.
- 4. The coating composition of claim 1, wherein the near infrared fluorescing compound is a squaraine compound of Formula IV, wherein R.sub.1 and R.sub.2 are independently carboxy or lower alkoxycarbonyl.
- 5. The coating composition of claim 1, wherein the near infrared fluorescing compound is a 2,3-naphthalocyanine compound of Formula III, wherein Y is hydrogen, n.sub.1 is 24, and m, is 0.
- 6. The coating composition of claim 1, wherein the near infrared fluorescing compound is a 2,3-naphthalocyanine compound of Formula III, wherein the naphthalocyanine moiety is bonded to SiCl.sub.2, Si(OH).sub.2, or Si(OR.sub.6).sub.2.
- 7. The coating composition of claim 1, wherein the near infrared fluorescing compound is a phthalocyanine compound of Formula II, wherein X is oxygen, R is aryl, Y is hydrogen, m is 4, and n is 12; and wherein the phthalocyanine moiety is bonded to AlCl, AlOH, AlOCOCF.sub.3, AlOR.sub.5, SiCl.sub.2, Si(OH).sub.2, or Si(OR.sub.6).sub.2.
Parent Case Info
This is a divisional application of copending application Ser. No. 08/019,535 filed on Feb. 18, 1993, now U.S. Pat. No. 5,292,855.
US Referenced Citations (27)
Divisions (1)
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Number |
Date |
Country |
Parent |
19535 |
Feb 1993 |
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