The present invention provides a system and method for removing both soluble lead and insoluble lead and other contaminants from water supplied by a water source to provide filtered water suitable for consumption. By directing the source water through a pitcher filter cartridge, soluble lead and insoluble colloidal or particulate lead, as well as other undesirable contaminants including, without limitation, arsenic, chlorine, taste and/or odors, are removed from the source water to provide filtered water suitable for consumption. The source water enters the filter cartridge through a plurality of inlet openings defined through a top portion of the filter cartridge, such as through a top surface and/or sidewall of the filter cartridge, and exits the filter cartridge through a bottom portion of the filter cartridge, such as through a plurality of outlet openings defined through a bottom surface of the filter cartridge housing.
The present invention is described below in reference to its application in connection with and operation of a pitcher filter. However, it should be apparent to those skilled in the art and guided by the teachings herein provided that the invention is likewise applicable to any point of use water filtration system including, without limitation, residential and/or industrial point of use water filtration systems.
Referring to
In one embodiment, filter cartridge 14 includes a housing 17 that defines a chamber 18, as shown in
Housing 17 further defines at least one inlet opening 20 through a top portion of housing 17. Referring to
Chamber 18 has suitable dimensions to define a volume configured to contain a filter 40, such as at least one adsorption medium configured to adsorb total lead, including soluble lead and insoluble colloidal lead, as well as other contaminants including, without limitation, arsenic, taste and/or odors, from the source water. In the exemplary embodiment, filter 40 includes adsorption media suitable to facilitate removing and adsorbing contaminants from the source water. In one embodiment, filter 40 includes granular adsorption media that are contained within a screen material 42 positioned within chamber 18. Screen material 42 is configured to contain the adsorption medium or media within chamber 18.
In the exemplary embodiment, a plurality of adsorption media are contained within housing 17. In this embodiment, a first adsorption medium 44 is contained within housing 17 and configured to facilitate removing insoluble colloidal lead from the source water and a second adsorption medium 46 is contained within housing 17 and configured to facilitate removing soluble lead from the source water.
First adsorption medium 44 is negatively charged to attract the positively charged soluble lead to facilitate removing positively charged soluble lead. In a particular embodiment, negatively charged adsorption medium 44 includes an inorganic adsorption medium, such as an ATS ceramic cation adsorption medium including titanium silicate manufactured by BASF/Engelhard and/or any suitable media having a negative Zeta potential capable of removing and adsorbing positively charged soluble lead from the influent water, such as a weak cation exchange resin. Negatively charged adsorption medium 44 removes soluble lead by electrostatic charge adsorption of positively charged soluble lead.
Additionally, second adsorption medium 46 is positively charged to facilitate removing negatively charged insoluble colloidal lead from the source water. The removal of negatively charged insoluble colloidal lead is facilitated with the use of a positively charged medium that attracts the negatively charged insoluble colloidal lead and removes the negatively charged insoluble colloidal lead from the source water.
Most insoluble colloids in water develop a surface charge that causes the insoluble colloids to repel one another and remain suspended in the water. These electrostatic charges are responsible for charge related phenomena in colloidal systems, such as flocculation and dispersion stability of dilute and concentrated suspensions. At a high pH, colloids are typically negatively charged, while at a lower pH colloids are often positively charged. The pH at which colloids are neutrally charged or where the charge on colloids changes from positive to negative is referred to as the isoelectric point (EEP), or the point of zero charge. The isoelectric point for different inorganic colloids can vary widely as a function of the different types of colloidal materials. For instance, the isoelectric point of silica is at a pH of about 2 to about 3, while that of activated alumina particles is at a pH of about 8 to about 9. Therefore, depending on the charge or the Zeta potential (negative or positive mV) of the inorganic colloidal materials within the source water, either a positively charged medium or a negatively charged medium is utilized to adsorb the charged insoluble colloidal materials.
In this embodiment, positively charged adsorption medium 46 is contained within housing 17 and configured to remove the insoluble colloidal lead by taking advantage of a negative electrostatic charge present on the insoluble colloidal lead suspended in the source water. At the pH found in drinking water, such as a pH of about 6.5 to about 8.5, insoluble colloidal lead is negatively charged. In a pH range of about 6.5 to about 8.5, a measured Zeta potential or charge of colloidal lead is typically in the range of −19 mV to −17 mV, respectively. Therefore, the isoelectric point (IEP) of the colloidal lead is less than 6.5, which is the lower limit for the pH of drinking water.
The aforementioned characterization of the insoluble colloidal lead indicates that a medium that is positively charged will attract the negatively charged insoluble colloidal lead and remove the negatively charged insoluble colloidal lead from the drinking water. Suitable types of materials for enhancing the electrostatic interactions with insoluble colloidal lead include, without limitation, activated alumina having an IEP of about 8.5 to about 9.1. A suitable material for positively charged adsorption medium 46 may depend upon various parameters including, without limitation, the charge of the lead particles at the pH of the water from which the lead particles are to be removed.
In the exemplary embodiment, positively charged adsorption medium 46 includes an inorganic adsorption medium, such as an activated alumina medium and/or any suitable medium having a positive Zeta potential capable of removing and adsorbing negatively charged insoluble lead from the influent water. In a particular embodiment, positively charged adsorption medium 46 includes activated alumina including crystalline boehmite (AlO(OH)). Positively charged adsorption medium 46 removes insoluble lead by electrostatic charge adsorption of negatively charged insoluble lead.
Positively charged adsorption medium 46 contained within filter cartridge 14 is configured to remove the insoluble colloidal lead by taking advantage of a negative electrostatic charge present on the insoluble colloidal lead suspended in the source water, as described above. Further, positively charged adsorption medium 46 is also configured to facilitate removing negatively charged arsenic (V) in the form of H2AsO4−. In alternative embodiments, positively charged adsorption medium 46 includes an any suitable medium known to those skilled in the art and guided by the teachings herein provided that facilitates adsorbing and/or removing undesirable negatively charged contaminants from the source water.
In a further exemplary embodiment, granular activated carbon (GAC) is contained within chamber 18. GAC is configured to facilitate removing chlorine, taste and/or odor from the source water as the source water is filtered through filter cartridge 14.
Referring further to
In an alternative embodiment, a bifunctional lead adsorption medium (not shown) capable of removing soluble lead and insoluble lead is positioned within chamber 18. In a particular embodiment, the bifunctional lead adsorption medium includes both a negatively charged adsorption medium and a positively charged adsorption medium, which facilitate removing soluble lead and insoluble colloidal lead, respectively, from the influent water.
In one embodiment, soluble and insoluble colloidal lead is removed predominantly due to charge adsorption of the variously charged lead species to the adsorption media. The presence of both negatively charged and positively charged adsorption media facilitates removing lead, whether positively charged or negatively charged and/or soluble or insoluble, from the influent water.
The above-described systems and methods for removing soluble and insoluble lead and other contaminants from water supplied by a water source providing filtered water suitable for user consumption. More specifically, by directing the source water from the reservoir through a pitcher filter cartridge, soluble lead and insoluble colloidal or particulate lead, as well as other undesirable contaminants, are removed from the source water. As a result, potable filtered water can be reliably and efficiently collected into the pitcher.
Exemplary embodiments of systems and methods for providing filtered water suitable for user consumption are described above in detail. The systems and methods are not limited to the specific embodiments described herein, but rather, components of the system and/or steps of the method may be utilized independently and separately from other components and/or steps described herein. Further, the described system components and/or method steps can also be defined in, or used in combination with, other systems and/or methods, and are not limited to practice with only the systems and methods as described herein.
While the invention has been described in terms of various specific embodiments, those skilled in the art will recognize that the invention can be practiced with modification within the spirit and scope of the claims.
Number | Date | Country | |
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60834237 | Jul 2006 | US |