The present invention provides a system and method for removing lead and other contaminants from water supplied by a water source to provide filtered drinking water suitable for consumption. By directing the source water through a filter assembly, at a point of entry (POE) or at a point of use (POU), soluble lead and insoluble colloidal or particulate lead, as well as other undesirable contaminants, are removed from the source water to provide filtered drinking water suitable for consumption. More specifically, positively charged soluble lead is removed and adsorbed by at least one negatively charged filter medium and negatively charged insoluble colloidal or particulate lead is removed and adsorbed by at least one positively charged filter medium.
The present invention is described below in reference to its application in connection with and operation of a residential water filtration system. However, it should be apparent to those skilled in the art and guided by the teachings herein provided that the invention is likewise applicable to any water filtration system including, without limitation, industrial water filtration systems.
As used herein, references to “point of entry” are to be understood to refer to a location at which a supply of water from a water source, such as a municipal water distribution system or a well, for example, enters the building through a suitable inlet pipe. Further, as used herein, references to “point of use” are to be understood to refer to a location within or outside the building, such as at a sink or a water dispenser, where a user has access to water through suitable piping and/or connections.
Referring to
Filter assembly 14 is configured to filter source water to remove lead, as well as other contaminants, therefrom and provide filtered water suitable for user consumption. Referring to
Referring further to
Referring to
Dual stage filter 30 also includes second filter medium 42 operatively coupled in series with first filter medium 32 and contained within housing 22. In the embodiment shown in
Most insoluble colloids in water develop a surface charge that causes the insoluble colloids to repel one another and remain suspended in the water. These electrostatic charges are responsible for charged related phenomena in colloidal systems, such as flocculation and dispersion stability of dilute and concentrated suspensions. At a high pH, colloids are typically negatively charged, while at a lower pH colloids are often positively charged. The pH at which colloids are neutrally charged or where the charge on colloids changes from positive to negative is referred to as the isoelectric point (IEP), or the point of zero charge. The isoelectric point for different inorganic colloids can vary widely as a function of the different types of colloidal materials. For instance, the isoelectric point of silica is at a pH of about 2 to about 3, while that of activated alumina particles is at a pH of about 8 to about 9. Therefore, depending on the charge or the Zeta potential (negative or positive mV) of the inorganic colloidal materials within the source water, either a positively charged medium or a negatively charged medium is utilized to adsorb the charged insoluble colloidal materials.
In this embodiment, second filter medium 42 is configured to remove the insoluble colloidal lead by taking advantage of a negative electrostatic charge present on the insoluble colloidal lead suspended in the source water. At the pH found in drinking water, such as a pH of about 6.5 to about 8.5, insoluble colloidal lead is negatively charged. In a pH range of about 6.5 to about 8.5, a measured Zeta potential or charge of colloidal lead is typically in the range of −19 mV to −17 mV, respectively. Therefore, the isoelectric point (IEP) of the colloidal lead is less than 6.5, which is the lower limit for the pH of drinking water.
The aforementioned characterization of the insoluble colloidal lead indicates that a medium that is positively charged will attract the negatively charged insoluble colloidal lead and remove the negatively charged insoluble colloidal lead from the source water. Suitable types of materials for enhancing the electrostatic interactions with insoluble colloidal lead include, without limitation, activated alumina having an IEP of about 8.5 to about 9.1. A suitable material for second filter medium 42 may depend upon various parameters including, without limitation, the charge of the lead particles at the pH of the water from which the lead particles are to be removed.
Second filter medium 42 includes a support matrix 44 within which a second absorbent medium 46 is embedded, dispersed or contained. In one embodiment, second filter medium 42 includes an electropositive support matrix including activated alumina coated glass fibers, such as at least one layer of a NanoCeram® material manufactured by Argonide Corporation located in Sanford, Fla.
As shown in
Water filtration system 10 is operable as a point of entry water filtration system wherein source water is filtered to remove lead and other undesirable contaminants before filtered water is distributed through the building water piping system to coupled point of use fixtures or connections, such as sink facets and/or drinking water dispensers. Alternatively, water filtration system 10 is operable as a point of use water filtration system wherein source water is distributed through the building water piping system to coupled point of use fixtures or connections. In this embodiment, filter assembly 14 is operatively coupled to the building water piping system at or near the point of use to filter the source water.
In an alternative embodiment as shown in
Referring further to
As influent flow of water 70 is filtered through first filter medium 32, positively charged soluble lead is removed from the source water and adsorbed onto negatively charged first adsorption medium 36. In a particular embodiment, at least a portion of insoluble colloidal lead within the source water is removed as the source water is filtered through first filter medium 32.
The flow of partially filtered source water is directed radially inwardly through second filter medium 42 positioned within first core 40. As the partially filtered source water is filtered through second filter medium 42, negatively charged insoluble colloidal lead is removed from the partially filtered source water and adsorbed onto positively charged adsorption medium 46. Effluent flow of filtered water 74 enters axial water conduit 52 and exits filter assembly 14 through outlet opening 54 as filtered water suitable for user consumption, as desired.
In an alternative embodiment, as shown in
In an alternative embodiment, a water filtration system 110 is similar to water filtration system 10, shown in
At least one negatively charged adsorption medium 134, such as an ATS ceramic cation adsorption medium including titanium silicate manufactured by BASF/Engelhard and/or any suitable media having a negative Zeta potential capable of removing and adsorbing positively charged soluble lead from the influent water is integrated within support matrix 132. At least one positively charged adsorption medium 136, such as activated alumina and/or any suitable media having a positive Zeta potential capable of removing and adsorbing negatively charged insoluble lead from the influent water is also integrated within support matrix 132. In one embodiment, support matrix 132 further provides an open matrix for facilitating minimizing a pressure drop during flow of the influent water through the filter.
In a particular embodiment, as shown in
In one embodiment, negatively charged adsorption medium 134 includes an inorganic adsorption medium, such as an ATS ceramic cation adsorption medium including titanium silicate manufactured by BASF/Engelhard and/or any suitable media having a negative Zeta potential capable of removing and adsorbing positively charged soluble lead from the influent water. Negatively charged adsorption medium 134 removes soluble lead by electrostatic charge adsorption of positively charged soluble lead. Positively charged adsorption medium 136 includes an inorganic adsorption medium, such as an activated alumina medium including crystalline boehmite (AlO(OH)) and/or any suitable medium having a positive Zeta potential capable of removing and adsorbing negatively charged insoluble lead from the influent water. Positively charged adsorption medium 136 removes insoluble lead by electrostatic charge adsorption of negatively charged insoluble lead.
In one embodiment, positively charged adsorption medium 136 is configured to remove the insoluble colloidal lead by taking advantage of a negative electrostatic charge present on the insoluble colloidal lead suspended in the source water, as described above. Suitable types of materials for enhancing the electrostatic interactions with insoluble colloidal lead include, without limitation, activated alumina having an IEP of about 8.5 to about 9.1. A suitable material for positively charged adsorption medium 136 may depend upon various parameters including, without limitation, the charge of the lead particles at the pH of the water from which the lead particles are to be removed. Positively charged adsorption medium 136 includes any suitable filter material to facilitate removing and adsorbing negatively charged insoluble colloidal lead from the source water.
Cylindrical side wall 138 at least partially defines an axial water conduit 142 that provides an axial flow path through filter 130. An outlet opening 144 defined by water conduit 142 is in fluid communication with outlet 20 defined in filter assembly cap 16. The source water is directed through filter 130 and the resulting filtered water exits filter 130 into water conduit 142. The filtered water is then directed to flow through outlet opening 144 through outlet 20 and into outlet pipe 56. Outlet pipe 56 is configured to distribute filtered water throughout the building water piping system to suitable water dispensing fixtures, such as a sink faucet and/or a refrigerator water dispensing system, for example.
Water filtration system 110 is operable as a point of entry water filtration system wherein source water is filtered to remove lead and other undesirable contaminants before filtered water is distributed through the building water piping system to coupled point of use fixtures or connections, such as sink facets and/or drinking water dispensers. Alternatively, water filtration system 110 is operable as a point of use water filtration system wherein source water is distributed through the building water piping system to coupled point of use fixtures or connections. Filter assembly 114 is operatively coupled to the building water piping system at or near the point of use to filter the source water.
Referring further to
As influent flow of water 70 is filtered through support matrix 132, positively charged soluble lead is removed from the source water and adsorbed onto negatively charged adsorption medium 134 and negatively charged insoluble colloidal lead is removed from the source water and adsorb onto positively charged adsorption medium 136. Effluent flow of filtered water 74 enters axial water conduit 142 and exits housing 22 through outlet opening 144 as filtered water suitable for user consumption, as desired.
In an alternative embodiment, a bifunctional lead adsorption medium (not shown) capable of removing soluble lead and insoluble lead is integrated within support matrix 132 including a meltblown polypropylene support material. In a particular embodiment, the bifunctional lead adsorption medium is incorporated into the meltblown polypropylene support matrix 132 by doping in the bifunctional lead adsorption medium during the melt blowing process. The presence of a negatively charged adsorption medium and a positively charged adsorption medium facilitates removing lead, whether positively charged or negatively charged and/or soluble or insoluble, from the influent water.
In one embodiment, filter 130 does not rely upon depth filtration to remove the insoluble colloidal lead. Rather, lead removal is predominantly due to charge adsorption of the variously charged lead species to the filter media. Therefore, the porosity of support matrix 132 is desirably relatively high to preclude any significant pressure drop across filter 130. The presence of both positively charged and negatively charged adsorption media facilitates removing lead, whether positively charged or negatively charged and soluble or insoluble lead, respectively, from the influent water.
The above-described systems and methods for removing lead and other contaminants from source water provide filtered water suitable for user consumption. More specifically, the filter assemblies as described above are configured to remove soluble and insoluble colloidal (particulate) lead at pH values similar to those found in drinking water. The filter assemblies are suitable for use in a residential point of use (POU) or a residential point of entry (POE) filter application, as well as in industrial water purification applications. By directing the source water through a filter assembly that includes charged filter media, positively charged soluble lead is removed and adsorbed by at least one negatively charged adsorption medium and negatively charged insoluble colloidal or particulate lead is removed and adsorbed by at least one positively charged adsorption medium. As a result, drinkable filtered water can be reliably and efficiently distributed throughout a building water supply system.
Exemplary embodiments of systems and methods for providing filtered water suitable for user consumption are described above in detail. The systems and methods are not limited to the specific embodiments described herein, but rather, components of the system and/or steps of the method may be utilized independently and separately from other components and/or steps described herein. Further, the described system components and/or method steps can also be defined in, or used in combination with, other systems and/or methods, and are not limited to practice with only the systems and methods as described herein.
While the invention has been described in terms of various specific embodiments, those skilled in the art will recognize that the invention can be practiced with modification within the spirit and scope of the claims.
This application claims the benefit of U.S. provisional application No. 60/834,237 filed Jul. 28, 2006, which is hereby incorporated by reference in its entirety.
Number | Date | Country | |
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60834237 | Jul 2006 | US |