Water heating apparatus for continuous heated water flow and method for use in hydraulic fracturing

Information

  • Patent Grant
  • 9442498
  • Patent Number
    9,442,498
  • Date Filed
    Tuesday, September 30, 2014
    10 years ago
  • Date Issued
    Tuesday, September 13, 2016
    8 years ago
Abstract
A method of hydraulic fracturing of an oil producing formation includes the provision of a heating apparatus which is transportable and that has a vessel for containing water. A water stream of cool or cold water is transmitted from a source to a mixer, the cool or cold water stream being at ambient temperature. The mixer has an inlet that receives cool or cold water from the source and an outlet that enables a discharge of a mix of cool or cold water and the hot water. After mixing in the mixer, the water assumes a temperature that is suitable for mixing with chemicals that are used in the fracturing process, such as a temperature of about 40°-120° F.+(4.4-48.9 C+). An outlet discharges a mix of the cool and hot water to surge tanks or to mixing tanks In the mixing tanks, a proppant and an optional selected chemical or chemicals are added to the water which has been warmed. From the mixing tanks, the water with proppant and optional chemicals is injected into the well for part of the hydraulic fracturing operation.
Description
STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT

Not applicable


REFERENCE TO A “MICROFICHE APPENDIX”

Not applicable


BACKGROUND OF THE INVENTION

1. Field of the Invention


The present invention relates to a method and apparatus for the continuous preparation of heated water flow for use in hydraulic fracturing.


2. General Background of the Invention


In connection with production of oil or gas from a geological formation, the production may have a poor flow rate due to low permeability or from damage or clogging of the formation during drilling particularly in formations of tight sands with low porosity and oil & gas shales. Hydraulic fracturing also known as “fracing” is a process employed after the well has been drilled, for the completion of the well to enhance hydrocarbon production.


Hydraulic fracturing creates porosity by fracturing the formations surrounding the wellbore. These fractures allow the oil or gas to flow more easily from the tight sands or shales to the production well. The common method to create fractures in the formation is to pump a mixture of water, chemicals and sands into the rock or formation. When the pumped fluid mixture reaches sufficient pressures, the formation will fracture, creating the permeability required to release the captured hydrocarbons.


Hydraulic fracturing generally entails injecting fluid into the wellbore at a sufficient rate and pressure to overcome the tensile strength of the formation creating cracks or fractures extending from the wellbore. U.S. Pat. No. 3,816,151, U.S. Pat. No. 3,938,594 and U.S. Pat. No. 4,137,182 (each hereby incorporated herein by reference) relate to hydraulic fracturing processes using various fracturing fluids.


Also incorporated herein by reference are the following US Patent document nos: 2008/0029267; U.S. Pat. Nos. 5,979,549; 5,586,720; 5,183,029; 5,038,853; 4,518,568; 4,076,628; 2,631,017; 2,486,141; 2,395,258; 2,122,900; 2,065,789.


One of the key elements of the fracturing fluid is water, which is the carrying fluid for the proppant (and optional appropriate chemical mix) required for the process. The proppant holds open the fractures and provides porosity to allow hydrocarbons to flow out of the formation. Before the fracing fluid is injected into the well, the water is normally heated to the target temperature (e.g., 40° F. to 120° F.+ (4.4° C. to 48.9° C.+)), which depends on the geologic formation and chemicals used, for example, typically 65° F.-75° F. (18° C.-24° C.) in the Bakken Shale located in North Dakota, Montana, and southern Canada) in order to achieve the proper chemical mix required for each particular hydraulic fracturing operation. A further result of heating the water prior to mixing with chemicals is the reduction of amount of chemicals that may be required for the hydraulic fracturing operation. In addition, a lower density of the heated water reduces the pressure on the pipes and connections and thereby reduces the risk for mechanical failure. In colder months and in colder environments, the temperature of the available water sources are typically less than 50° F. (10° C.) (even as low as below freezing) which is generally an unsuitably cold temperature for the fracing process. It is necessary to heat the available water to a temperature (e.g., 40° F. to 120° F.+ (4.4° C. to 48.9° C.+)) suitable for the fracing process prior to the water and fracing fluids being pumped down hole.


There are common and known methods of providing heated water, which require that prior to the fracing process, the source water is pumped into numerous frac tanks and then the water in each individual frac tank is circulated through a heating unit to raise the temperature in the frac tank to a preset temperature required for the chemical mixing of the frac. However, due to the time lapse between heating (which is typically done the night before the fracing operations) significant thermal loss occurs. Each tank has to be heated to temperatures of for example 10-50° F. (5.6° C. to 27.8° C.) (often 20° F. to 30° F. (−11.1° C. to 16.7° C.)) higher than is operationally necessary. For example, if the required temp is 70° F. (21° C.), then each tank would need to be heated to at least 90°-120° F. (32° C.-48.9° C.). The extensive over-heating is a substantial expense and energy waste. The pumping of water to the frac tanks and the use of heating units to heat the water in the frac tank are well known in the industry. FIG. 5 is an example of a prior art type configuration. There are multiple commercial businesses which provide such services. The number of frac tanks can typically range from 20-700 tanks (the average at the Marcellus Shale (located in western New York extending south to Tennessee) is 500 tanks)—currently it costs around $500-2,000 per frac tank in a typical fracing process (delivery, rental, cleaning, and demobilization of the tank), so these frac tanks are a substantial expense in the fracing process. Typically a substantial amount of safety issues in fracing operations involves the handling of frac tanks. One must heat the frac tanks to enough above the target temperature to allow for thermal loss between heating and use. Because normally heating of frac tanks occurs at night, this can be 10-50 degrees F. (5.6° C. to 27.8° C.), for example. The amount of temperature above target will depend on local weather conditions.


BRIEF SUMMARY OF THE INVENTION

The apparatus and method of the invention requires a water source, pumps and piping that can provide continuous delivery of water, such as up to about 100 barrels (11.9 kl) (sometimes as high as 150 (17.9 kl), and sometimes as low as 30-50 barrels (3.6-6.0 kl)) a minute through a mixer or mixing manifold and to frac tanks.


As the water (usually cool or cold water) is pumped from its source through the mixing manifold, a portion of the water volume (for example 7 barrels (0.83 kl) a minute) is diverted through piping at the manifold to and through a heating unit. This heating device is preferably a mobile unit that can heat a smaller volume of water, such as up to about 7 barrels (0.83 kl) per minute with a for example 22 million BTU (23.2 billion Joules) heater (which consistently heats to that capacity in all weather conditions, regardless of ambient temperatures).


The heating unit creates an increase in the ambient water temperature of the e.g., 7 bbls (0.83 kl) of the diverted water to usually around 190-200° F. (87.8-93.3° C.) (and up to 240° F. (116° C.) in a pressurized piping system). This heating is preferably done on a continuous flow basis (as opposed to a batch process) with the heated water delivered through piping back into the mixing manifold and continuously mixed into the ambient water flow. The mixing of the superheated water with the cooler water results in an increase in water temperature of approximately 5°-15° F. (2.8-8.3° C.) at a rate of e.g. 100 barrels (bbls) (11.9 kl) per minute of continuous pumping flow (per each heater unit). Lower flow rates (such as 20 bbls (2.4 kl) per minute) will increase the temperature faster to result in a higher temperature rise. One can even run at 150 bbls (17.9 kl) per minute, but the temperature rise per unit will be lower.


To achieve higher water temperatures, multiple heating units (for example 2-4 or even more) can be used to heat the water, all of which is preferably done on a continuous flow basis. The moving stream of uniformly heated water is preferably piped to a small number of optional frac tank(s) which can be used as a safety buffer between the water flow and the pumping operations, in the case of a mechanical breakdown or operational problems.


The heating system with manifold can be designed for continuous heating preferably up to about 100 bbls (11.9 kl) per minute (or even more). To meet the required (target) temperature for the water used in the fracing process (e.g., 40° F. to 120° F.+ (4.4° C. to 48.9° C.+), and often about 65°-75° F. (18° C.-24° C.), or 70°-80° F. (21° C.-27° C.)), the rate of flow from the ambient source water can be adjusted to provide greater or lesser volume and multiple, sequential mixing manifolds and heater units can be added to the process.


The mixing manifold includes an intake opening and an outflow opening allowing the source flowing water to pass through the mixing manifold to the frac tanks. Between the intake opening and the outflow opening, the mixing manifold has at least one cold water diversion opening connected to piping to deliver a portion of cold water flow to the heating unit. In the mixing manifold, a hot water return opening is located downstream of the cold water diversion opening, and this second opening, referred to as the hot water return opening, allows the heated water into the mixing manifold mixing with the cold water stream uniformly raising the temperature of the water before the water reaches the frac tanks (or the mixing tank or tanks if frac tanks are omitted).


In another embodiment, before pumping the heated water to a frac tank (or the mixing tank or tanks if frac tanks are omitted), the flow of the mixed heated water can again be passed through a second mixer or second mixing manifold and a portion of the mixed heated water is diverted to a second heating unit to heat that water to 200° F. to 240° F. (93.3° C. to 116° C.), and that superheated water can be returned to the mixing manifold for mixing with the continuously moving water stream at about 100 bbls. (11.9 kl) per minute providing an additional +10° F. to +15° F. (+5.6° C. to +8.4° C.) uniform elevation of the temperature of the water flow. This mixed and heated water can then be piped to optional frac tanks (if used) and then to a mixing tank(s) for mixing with fracing chemicals and then pumped down hole for use in the hydraulic fracing process. If needed, multiple sequential heating units can be attached along the pumping line to continuously raise the temperature of the continuous flow of water to the required or predetermined target temperature.


The mixing manifold can be any length or size of pipe or tank used in the industry and the cold water diversion opening and the hot water return opening can be configured and spaced in the mixing manifold, or along the piping, in any useful manner to allow superheated water to mix with continuously flowing source water.


The mixing manifold or mixer can be for example 6-12 inches (15-30 cm) in diameter, such as a 10 inch (25 cm) diameter tubular member or pipe with a length of approximately 2 to 3 feet (61-91 cm). The pipe diameter and length can vary according to the requirements of the pumping operations. The cold water diversion opening is connected to a smaller pipe (such as a 3 inch (7.6 cm) pipe) that is preferably attached to the mixing manifold at an angle (such as approximately 45°) forming a “y” with the mixing manifold and the cold water diversion pipe. When heating water in Oklahoma, some operators use 10-inch (25 cm) lines, some use 12-inch (30 cm) lines. When heating water in Pennsylvania, some operators use 10-inch (25 cm) lines, and others use four to six 6-inch (10-15 cm) lines.


Preferably, a raised rigid semi-circle shaped lip extends from the backside of the cold water diversion opening into the mixing manifold creating a partial blockage or impediment of the source water flow stream causing a portion of the cold water flow stream to divert into the cold water diversion opening and through the piping to the heating unit. This protruding lip partially blocks and obstructs the water flow inducing suction and flow into the pipe to the heating unit. This partial blockage in the mixing manifold also creates turbulence in the source water flow at and beyond the cold water diversion opening that aids in mixing at the superheated water inflow point. The lip can be a rigid metal concave half circle having for example a ⅛ inch (0.32 cm) width and 1.5 inch to 2 inch (3.81 cm to 5.08 cm) height at its highest point with tapering to meet flush with the side of the mixing manifold at the ends of the semi-circle of the lip; however, the lip can be many shapes, sizes and locations in the mixing manifold to induce suction and create turbulence in the mixing manifold.


The hot water return opening in the manifold for attachment of piping for the superheated water is preferably located downstream of the cold water diversion opening in the flowing source water in the mixing manifold of the outflow pipe. The hot water return opening for delivery of superheated water preferably likewise has a lip extending into the stream of flowing water creating further turbulence in the water resulting in greater mixing action of the superheated water with the continuously flowing cold water creating a rise in temperature of the cold water as it passes along the mixing manifold and through the piping to the frac tanks serving as surge tanks (or directly to mixing tanks if there are no frac tanks acting as surge tanks). This second lip located on the front side or upstream side of the opening provides a partial blocking of the flow of cold water aiding in the flow of the superheated water into the mixing manifold. This lip adjacent to the opening on the hot water return opening is optimally of the same size and shape of the cold water diversion lip; however, this lip can also be utilized in many shapes, sizes and locations in the mixing manifold to partially block flow to facilitate hot water flow into the mixing manifold and create additional turbulence in the mixing manifold.


Additional mixing of the hot and cold water occurs beyond the mixing manifold as the water flow is piped into and fills the optional frac tanks if used and then piped as operations dictate to mixing tanks to frac pumping units and to downhole. The heated water is delivered and can be temporarily held in frac tanks or surge tanks or pumped directly to mixing tanks without surge tanks. The apparatus and process substantially reduce the number of required frac tanks (or even eliminate the need for frac tanks). In one embodiment of the described process, approximately six to eight 500 bbl (59.6 kl) frac tanks are utilized, which are used as a safety buffer between the water flow and the pumping operations, in the case of a mechanical breakdown or operational problems.


Suitable heating units can be commercially purchased through manufacturers or fabricated. Exemplary manufacturers include Rush Sales Company located in Odessa, Tex. (they produce Rush Frac Water Heaters), and Chandler Manufacturing, Inc. in Wichita Falls, Tex. (the diesel unit with six burners and a 22 million BTU (23.2 billion Joules) capacity is preferred) and Vita International. Conventional heating trucks shown in FIG. 5 typically produce much less than 20 million BTU (21.1 billion Joules). They could be used in the system and method of the present invention, but more robust heating units 12 (such as those produced by Chandler Manufacturing, Inc.) capable of delivery of at least 15 million BTU (15.8 billion Joules), preferably up to 25 million BTU (26.4 billion Joules) (e.g. 22 million BTU (23.2 billion Joules) or more) are preferred. The piping, pumps and frac tanks are all readily available from numerous suppliers and contractors in the industry.


There are numerous other conceivable arrangements and configurations of the inflow and outflow of the cold water and hot water and piping in the mixing manifold, including parallel pumping of cold and hot water inflow and use of secondary source of water to the heaters independent of the primary source water passing through the mixing manifold.


The method of this invention can include some or all of the following steps. These steps can be in the following order.


1) Establish a flow of source water at between about 20-150+ bbls (2.4-17.9+ kl) (more typically 60 to 100 bbls (7.2 to 11.9 kl)) per minute through piping to a piping manifold or mixer, which diverts a portion of the source water to one or more heating units,


2) The superheated water returns to the continuous flowing source water to meet the required or target temperatures, and


3) The warmed water (e.g. 60°-120° F.+ (16-48.9° C.+), typically 65°-80° F. (18-27° C.)) sent to the mixing tanks for chemical additives and the eventual fracing process.


Examples of chemicals that can be added to the water include: bentonite gel and other chemicals used by such frac operators as Schlumberger, Halliburton, and BJ Services. Typically proppants (such as sand, ceramic beads, bauxite, or others) are mixed with the water before the water is injected downhole. The proppants help to keep the fractures which are produced open. The proppants can be for example any which are used by such frac operators as Schlumberger, Halliburton, and BJ Services.


In general, it is possible to use water of a lower temperature if one uses more chemicals. For example, while normally one might wish to use water of 40°-120° F. (4.4° C.-48.9° C.) in a particular fracing process at a particular location (“slick water frac” refers to a process where less chemicals are used (or sometimes even no chemicals)—it uses turbulent flow with a lot of pressure—proppants are used with all fracing processes—typically one can carry more (sometimes up to two to three times as much) proppant in a slick water frac compared to a gel frac), one could instead use water at a lower temperature of 60°-120° F. (16° C.-48.9° C.) (“gel frac” refers to this process where more chemicals are used—gel and proppant). Examples of amounts of water used in a fracing process are 30,000 barrels to 350,000 barrels (3,577-41,734 kl), though one might use as few as 10,000 barrels (1,192 kl) to over one million barrels (119,240 kl) (this larger amount may cover multiple wells, for example). Higher water temperature can sometimes result in lower chemical usage. Some of the wells currently are approaching 1 million pounds (453,592 kg) of sand as a proppant with 350,000 barrels (41,734 kl) of water.


Through testing in cold temperatures, the inventor has learned that heating water from around freezing to about 40 degrees F. (4.4° C.) takes a great degree of heat. One might need more heaters when heating water from near freezing, or one might initially preheat some water in frac tanks (e.g., 3 or 4 up to 50 or 100 frac tanks) to add heat one needs to move the temperature of the water up from near freezing to about 40 degrees F. (4.4° C.). One could also add heating in a water pit itself to help raise the water temperature to around 40 degrees F. (4.4° C.). Also, when a water source contains ice, it is best to withdraw only liquid water, and no ice, from the water source. Otherwise, a good amount of heat can be lost melting the ice.


Preferably one places one or two units near the water source and another unit near the fracing pumps. It appears that there is additional heating in the pipeline (due to friction, the inventor believes) of perhaps a degree or two F. (0.6-1.1° C.) when the water travels about a mile (1.61 km).





BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS

For a further understanding of the nature, objects, and advantages of the present invention, reference should be had to the following detailed description, read in conjunction with the following drawings, wherein like reference numerals denote like elements and wherein:


The invention and features of the invention is shown and disclosed by the following Figures and photographs representing informal drawings.



FIG. 1 is a partial perspective view of a preferred embodiment of the apparatus of the present invention;



FIG. 2 is a sectional view taken along lines 2-2 of FIG. 1;



FIG. 3 is a schematic diagram of a preferred embodiment of the apparatus of the present invention and illustrating the method of the present invention;



FIG. 4 is a schematic diagram of another preferred embodiment of the apparatus of the present invention and illustrating a method of the present invention;



FIG. 5 is a schematic diagram of a prior art oil well frac pumping system;



FIG. 6 is a schematic diagram of a preferred embodiment of the apparatus of the present invention;



FIG. 7 is a schematic diagram of an alternative embodiment of the apparatus of the present invention;



FIG. 8 is a schematic diagram of another alternative embodiment of the apparatus of the present invention;



FIG. 9 is a schematic diagram of another alternative embodiment of the apparatus of the present invention;



FIG. 10 is a schematic diagram of another alternative embodiment of the apparatus of the present invention;



FIG. 11 is a schematic diagram of another alternative embodiment of the apparatus of the present invention; and



FIG. 12 is a schematic diagram of another alternative embodiment of the apparatus of the present invention.





DETAILED DESCRIPTION OF THE INVENTION


FIGS. 1-4 and 6-12 show preferred embodiments of the apparatus of the present invention, designated generally by the numeral 10 in FIGS. 3 and 6. Alternate embodiments are designated by the numeral 110 in FIG. 4, by the numeral 210 in FIG. 7, by the numeral 310 in FIG. 8, by the numeral 410 in FIG. 9, by the numeral 510 in FIG. 10, by the numeral 610 in FIG. 11, and by the numeral 710 in FIG. 12. In FIG. 6, a water source 11 can be a reservoir, lake or other source of water.


Mobile heater apparatus 12 is used to super heat water for use in frac operations in an oil well. In general, such frac operations can be seen in U.S. Pat. No. 4,137,182, hereby incorporated herein by reference.


Mobile heater 12 is a transportable heating apparatus and includes a truck 13 and a trailer 14. Trailer 14 carries a heating vessel 15 which can be, for example, a tank or piping that holds water and that can be heated with electrical or other heating elements or with propane or preferably diesel burners. Water to be injected into an oil well 16 as part of a hydraulic fracturing operation include very hot water that is heated by mobile heater 12 and ambient water that is received from water source 11.


A pumping apparatus 17 which can include a truck 13 and trailer 18 pumps the prepared water (water plus selected chemical (optional) and proppant) into the well 16. Water from source 11 flows in flowline 19 to mixer 20. Mixer or mixing manifold 20 can be seen in more detail in FIGS. 1 and 2. Mixer 20 receives ambient temperature water from water source 11 and mixes that ambient temperature water with very hot water that is heated in vessel 15 of mobile heater 12.


The details of mixer 20 are seen in FIGS. 1 and 2. The mixer 20 has a tubular or cylindrically-shaped body 21 defined by a wall 22 which surrounds bore 23. Tubular body 21 has a first inlet 26 in a first inlet end portion 24, and a first outlet 27 in an outlet end portion 25. The bore 23 communicates with flow inlet 26 and flow outlet 27. Arrows 28, 29 illustrate the direction of flow of water in body 21 as shown in FIG. 2. Curved arrows 30 in FIG. 2 illustrate turbulent flow that occurs for ensuring that heated water and ambient temperature water thoroughly mix.


A pair of conduits are connected to tubular body 21. These include conduit 31 and conduit 32. Conduit 31 is a second outlet and removes ambient temperature water from the bore 23 of tubular body 21. Conduit 32 is a second inlet and injects heated water into bore 23 of tubular body 21 and downstream of conduit 31. In this fashion, conduit 31 does not discharge any heated water from bore 23 of tubular body 21. Rather, the water leaving bore 23 of tubular body 21 via conduit 31 is ambient temperature water. This discharge of ambient temperature from tubular body 21 of mixer 20 is illustrated by arrows 39 in FIG. 2.


Each of the conduits 31, 32 has a bore. The conduit 31 has bore 33. The conduit 32 has bore 34. Each of the conduits 31, 32 has an inner end portion and an outer end portion. Conduit 31 has inner end portion 35 and outer end portion 36. Conduit 32 has inner end portion 37 and outer end portion 38. Each of the inner end portions 35, 37 occupies a position within bore 23 of tubular body 21 as shown in FIG. 2. In this fashion, bore 33 of conduit 31 occupies a part of bore 23 of tubular body 21. Similarly, fluid discharging from bore 34 of conduit 32 is discharged directly into the bore 23 of tubular body 21. The arrows 40 in FIG. 2 illustrate the discharge of heated water via conduit 32 into bore 23 of tubular body 21.


While the angle of the longitudinal axis of bore 33 of conduit 31 and the angle of the longitudinal axis of bore 34 of conduit 32 in relation to the longitudinal axis of bore 23 of tubular body 21 are shown to be about 45 degrees, those angles could vary from 0 to 90 degrees, and they need not be the same.


As can be seen in FIG. 2, first inlet 26 is upstream of second outlet 31, which is upstream of second inlet 32, which itself is upstream of first outlet 27.


In FIG. 6, flow lines 41 and 42 are used to transfer water in between mobile heater 12 and mixer 20. The flow line 41 receives water from conduit 31, a second outlet, which is ambient temperature water and transports that ambient temperature water to vessel 15 of heater 12. After water has been heated in vessel 15, it is transported via flow line 42 to conduit 32, a second inlet, of mixer 20. It should be understood that the flow of fluids from flow line 41 to and through vessel 15 of heater 12 and then to flow line 42 can be a continuous process. As an example, the flow of ambient temperature water in flow line 19 can be about 20-150 bbls (2.4-17.9 kl) per minute, and typically around 60-100 barrels (7.2-11.9 kl) per minute. The flow rate in flow lines 41 and 42 can be for example a continuous 7 barrels (0.83 kl) per minute.


The temperature in the super heated flow line 42 can be in excess of 200° F. (93.3° C.) and in excess of 240° F. (116° C.) if flow line 42 is pressurized. Flow lines 43 and 44 illustrate the transfer of warmed water from mixing tanks or downhole tanks 46 to pumping apparatus 17 and then into the well 16 for use in frac operations. In FIG. 6, surge tanks 45 can optionally be used downstream of mixer 20 and upstream of mixing tanks 46.


To achieve higher water temperatures, multiple heating units 12 can be used to heat the water all of which is done on a continuous flow basis as shown in FIG. 4. The moving stream of uniformly heated water can be piped to surge tank(s) which can be used as a safety buffer between the water flow and the pumping operations, in the case of a mechanical breakdown or operational problems.


In FIG. 4, a joint of pipe 47 (commercially available) can be placed in between the two mixers 20 as shown. In FIG. 4, the flow of the mixed heated water can be passed through a second mixer or second mixing manifold 20 and a portion of the mixed heated water is diverted to a second heating unit 12 to heat that water to for example between about 200° F. to 240° F. (93.3° C. to 116° C.). That superheated water can be returned to the mixing manifold 20 for mixing with the continuously moving water stream providing an additional +10° F. to +15° F. (+5.6° C. to +8.4° C.) uniform elevation of the temperature of the water flow. This mixed and heated water can then be piped to mixing tanks 46 for mixing with any selected hydraulic fracturing chemicals and then pumped down hole for use in the hydraulic fracturing process. If needed, multiple sequential heating units 12 (and mixers 20) can be attached along the pumping line to continuously raise the temperature of the continuous flow of water to a required or target temperature. The mixers 20 can be connected in series (as in FIG. 4) or in parallel or a combination of series and parallel (as in FIGS. 10 and 12).


In FIG. 7 (an alternate configuration), the surge tanks have been eliminated. The mixing tanks 46 can be used to mix any selected chemical and proppant or proppants with the water that has been discharged from mixer 20 and that is ready for use in hydraulic fracturing operation in the well 16.


Conventional heater trucks 112 shown in FIG. 5 typically produce much less than 20 million BTU (21.1 billion Joules). They could be used in the system and method of the present invention, but more robust heating units 12 (such as those produced by Chandler Manufacturing, Inc. in Wichita Falls, Tex.) capable of delivery of 22 million BTU (23.2 billion Joules) or more are preferred. Especially preferred are diesel powered heater units commercially available from Chandler Manufacturing, Inc. in which water flows through a series of metal coils, and there are six burners which heat the coils. An example of such a heater unit can be seen at www.chandlermfg.com/item.php?pid=34 and is identified as an oil-fired frac water heater (and shown in US Patent Publication no. US 2010/0000508). However, other heater units which can quickly heat large quantities of water can be used. The diesel powered units are preferred because in colder environments propane tends to liquify and not heat as effectively. Preferably one can run 70-100 barrels (8.3-11.9 kl) per minute per heating truck of the present invention while getting a temperature rise of at least about 15 degrees Fahrenheit (8.4° C.).


Through testing in cold temperatures, the inventor has learned that heating water from around freezing to about 40 degrees F. (4.4° C.) takes a great degree of heat. One might need more heaters 12 when heating water from near freezing, or one might initially preheat some water in additional frac tanks (e.g., 3 or 4 up to 50 or 100 frac tanks) to add heat one needs to move the temperature of the water up from near freezing to about 40 degrees F. (4.4° C.). One could also add heating in a water pit itself (e.g., when the water source 11 is a pond) to help raise the water temperature to around 40 or 45 degrees F. (4.4 or 7.2° C.) (there will be radiant heat loss from the water pit, so typically one would not want to heat the water in the pit much above 40 to 45 degrees F. (4.4 to 7.2° C.)) before further heating the water with the heating system of present invention shown in FIGS. 3 and 4, for example. The heating in the water pit could be done with, for example, a heater or heaters 12 as shown in FIGS. 3 and 4 that circulate water through hoses 41 and 42 to and from the water pit.


Also, while typically water freezes at 32 degrees F. (0° C.), flowing water or water with various substances can sometimes cool below 32 degrees F. (0° C.) without freezing. Thus, sometimes the present invention might start processing water which is below 32 degrees F. (0° C.). Also, sometimes the source water might have ice in it, but it can still be used if the water with ice can flow through mixer 20. However, it is preferred to avoid pulling ice into the intake, as considerable heat can be lost when melting the ice.


Surge or pivot tanks 45 are preferably upright circular tanks where the water flows in and out (similar to or the same as the mixing tanks 46 shown in FIG. 6). The agitation which occurs in the surge tanks 45 is helpful, and seem to add heat to the water (better mixing seems to occur as well, so even if surge or pivot tanks 45 are not needed for surge, one might want to use 2-20 of these anyway).


Manifolding among multiple surge or pivot tanks can be done to balance heat. Pivot or surge tanks 45 could be shaped like mixing tanks 46. Preferably the heated water flows through the surge tanks (as shown in FIG. 10, where mixing tanks 46 are acting as surge tanks). The surge tanks provide a buffer in the event of some breakdown or other problem making it difficult to produce heater water. During the breakdown or other problem, heated water from the surge tanks can be routed to the mixing tanks, even though no heated water will be refilling the surge tanks. Preferably, either enough surge tanks are provided that no interruption in fracing occurs during a breakdown or other problem causing an interruption in heated water production, or enough surge tanks are provided that an orderly shutdown of fracing occurs during a breakdown or other problem causing an interruption in heated water production. Typically surge tanks hold around 480-500 barrels (57.2-59.6 kl) of heated water per tank.


Though pumps and valves are not shown in the drawings, appropriate pumps and valves are provided to direct water as desired, and one of ordinary skill in the art will be able to determine where to place such pumps and valves to achieve desired water flow.


Water lines can be manifolded together and several lines could feed and emanate from a single heating truck.


Flow rates can be 100 barrels (11.9 kl) per minute (though this could be higher or lower) and with the preferred heater trucks of the present invention, there will preferably be around a 15 degree F. (8.4° C.) increase in temperature at 100 barrels (11.9 kl) per minute (for one truck).


The current normal target water temperature is 70-90 degrees F. (21.1-32.2° C.) (but it could be higher). Overheating of the water is not needed (as one must do when heating tanks) as the heat loss (if any) using the on-line heating method of the present invention is typically minimal.


Maintenance of trucks used in the present invention includes chemical (e.g., hydrochloric acid) washing of the coils to keep heat transfer times low (otherwise there can be buildup on the coils which impedes heat transfer).


Probably a vertical, round tank (such as mixing tank 46) will work better for mixing hot and cold water to get a more uniform temperature of water to use in fracing.



FIG. 8 is similar to FIG. 7, but apparatus 310 shown therein includes a mixing tank 46 instead of the manifold 20 shown in FIG. 7 (anything that could cause turbulence could be used instead of the manifold 20 shown in FIG. 1, though the manifold 20 is preferred as it is a relatively simple and compact mixing device). Water drawn from water source 11 travels through flow line 19 and first inlet 56 into mixing tank 46, where some of the water is drawn off through second outlet 61 and line 41 into mobile heater 12, then back through flow line 42 and second inlet 62 into mixing tank 46, where it then continues to flow through first outlet 57 and flow line 19 to mixing tanks 46 which are near frac pumping apparatus 17. From there the water flows as in FIG. 7. It is believed that better mixing of water occurs in tank 46 when first inlet 56 is near the bottom of tank 46, first outlet 57 is near the top of tank 46, and second inlet 62 is somewhere in between. Also, it is believed that better mixing will occur if mixing tank 46 is a vertical cylindrical tank as shown in the drawings.



FIG. 9 is similar to FIG. 8, but apparatus 410 shown therein includes a half manifold 120 and a mixing tank 46 instead of the manifold 20 shown in FIG. 1. As indicated in FIG. 9, water at the temperature of the water source 11 flows through half manifold 120, where some of the water is diverted out through second outlet (conduit) 31 of half manifold 120 into flow line 41 and to heater 12, then out through flow line 42 into second inlet 62 of mixing tank 46. The heated water from line 42 mixes in mixing tank 46 with the water which is at the temperature of water source 11 which enters tank 46 at first inlet 56. The water then flows out through first outlet 57 through flow line 19 to mixing tanks 46 which are near frac pumping apparatus 17. From there the water flows as in FIG. 7.


As can be seen for example in FIG. 9, the flow rate through the mixer is about equal to the flow rate of the fluid being pumped downhole. Also as seen for example in FIG. 9, the volume of the mix of cool or cold and heated fluid flowing out of the leftmost mixing tank 46 in FIG. 9 is greater than the volume of heated fluid flowing through line 42 from mobile heater apparatus 12.



FIG. 10 shows apparatus 510, which includes three mobile heaters 12 with three manifolds 20, two mobile heaters 12 in parallel with one another and located near the water source 11, and one mobile heater 12 closer to the frac pumping apparatus 17. There are three surge tanks 46 in series with one of the mobile heaters 12, though these surge tanks 46 could be in series with both mobile heaters 12 which are in parallel to one another, or they could be in series with all three mobile heaters 12 shown in FIG. 10. Further, there could be as few as none or one surge tank 46 to as many as considered prudent by the operator, which could be for example three or four up to 50 or 100 mixing tanks 46 (or even more). Flow of water through manifolds 20, heaters 12, and surge tanks 46 is as in prior figures.



FIG. 11 shows apparatus 610, which includes two mobile heaters 12 connected directly to the source water 11 (a pond) with the water being withdrawn from and returned to the pond. There are also three mobile heaters 12, each connected to a mixing tank 46, heating water in the mixing tanks 46. Further, there could be as few as none or one surge tank 46 and associated mobile heaters 12 to as many as considered prudent by the operator, which could be for example three or four up to 50 or 100 mixing tanks 46 with associated mobile heaters 12 (or even more).



FIG. 12 is similar to FIG. 11, but in FIG. 12 apparatus 710 differs from apparatus 610 in that one truck has moved from the pond 11 and is heating the water as it runs through the flow line 19. FIG. 12 shows three additional mixing tanks 46 in series with pipe 19 and acting as surge tanks. As in FIG. 11, there are also three mobile heaters 12, each connected to a mixing tank 46, heating water in the mixing tanks 46.


These mixing tanks 46 are in series with one another in a flow line 119 which runs parallel to flow line 19 and then feeds into flow line 19. Further, there could be as few as none or one surge tank 46 and associated mobile heaters 12 to as many as considered prudent by the operator, which could be for example three or four up to 50 or 100 mixing tanks 46 with associated mobile heaters 12 (or even more).


There is a huge lake (Lake Sakakawea) in the middle of western North Dakota. Fracing operations were making a tremendous strain on groundwater. Now it is expected that water will be pulled from Lake Sakakawea with permits currently in process. It is believed that companies will soon pump water out of Lake Sakakawea and put it into insulated tanks, where it will be heated in the tanks. The water will then be taken via insulated trucks to a well site where fracing operations occur. The apparatus of the present invention can heat water as it is pumped from the lake into the tanks (and it can continue to heat the water once it is in the tanks). This method can occur in other areas as well.


The following is a list of parts and materials suitable for use in the present invention:












PARTS LIST








Parts Number
Description











10
hydraulic fracturing pumping system


11
water source


12
mobile heater apparatus


13
truck


14
trailer


15
vessel


16
oil and/or gas well


17
frac pumping apparatus


18
trailer


19
flow line


20
mixer


21
tubular/cylindrically-shaped body


22
wall


23
bore


24
inlet end portion


25
outlet end portion


26
inlet


27
outlet


28
arrow


29
arrow


30
curved arrow


31
conduit (second outlet)


32
conduit (second inlet)


33
bore


34
bore


35
inner end portion


36
outer end portion


37
inner end portion


38
outer end portion


39
arrow


40
arrow


41
flow line


42
flow line


43
flow line


44
flow line


45
surge tank


46
mixing tank or downhole tank or surge tank


47
joint of pipe


56
inlet (first) of mixing tank 46


57
outlet (first) of mixing tank 46


61
second outlet of mixing tank 46


62
second inlet of mixing tank 46


110
hydraulic fracturing pumping system


112
prior art mobile heating truck


119
flow line


120
half manifold


210
hydraulic fracturing pumping system


310
hydraulic fracturing pumping system


410
hydraulic fracturing pumping system


510
hydraulic fracturing pumping system


610
hydraulic fracturing pumping system


710
hydraulic fracturing pumping system









All measurements disclosed herein are at standard temperature and pressure, at sea level on Earth, unless indicated otherwise.


The foregoing embodiments are presented by way of example only; the scope of the present invention is to be limited only by the following claims.

Claims
  • 1. A method of heating while fracturing of the formation occurs, fluid for use in fracturing a formation producing at least one of oil and gas, comprising the steps of: a) providing a heating apparatus for heating fluid to a temperature of at least about 40 degrees F. (4.4 degrees C.);b) transmitting a stream of cool or cold fluid to a mixer, the cool or cold fluid stream being at a temperature of less than a predetermined target temperature;c) the mixer having a first inlet that receives cool or cold fluid from the stream of step “b” and a first outlet that enables discharge of a substantially continuous stream of fluid;d) the mixer having a second inlet that enables heated water to enter the mixer;e) adding heated water from the heating apparatus of step “a” to the mixer via the second inlet;f) wherein the volume of fluid of step “b” is much greater than the volume of water of step “e”;g) wherein fluid exiting the first outlet of the mixer is transmitted into a formation producing at least one of oil and gas and includes a proppant when transmitted into the formation; andh) wherein fluid flows substantially continuously from the first inlet to the first outlet during the fracturing process, wherein the water is heated in the heating apparatus before fracing chemicals are added to the water, wherein the heating apparatus has a heating capacity to add about 100 F. to 150 F. to the fluid at a flow rate of about 100 barrels per minute of fluid discharged from the first outlet, and wherein the fluid exiting the first outlet of the mixer flows at a rate of at least 20 barrels per minute into the formation.
  • 2. The method of claim 1, wherein the volume of fluid flowing through the mixer is about equal to the volume of fluid being pumped into the formation during the fracing process.
  • 3. The method of claim 1, wherein the fluid exiting the first outlet of the mixer flows at a rate of at least 30 barrels per minute into the formation.
  • 4. The method of claim 1, wherein the flow rate through the mixer during the fracing process is about equal to the flow rate of the fluid being pumped downhole.
  • 5. The method of claim 1, wherein the mixer is a mixing tank.
  • 6. The method of claim 1, wherein the mixer has a bore, and the mixer includes a lip that extends into the mixer bore to partially block flow and to create additional turbulence in the mixer bore.
  • 7. The method of claim 1, wherein the mixer has a bore, and the second inlet of the mixer has a wall portion that extends into the mixer bore.
  • 8. A method of heating while fracturing of the formation occurs, fluid for use in fracturing a formation producing at least one of oil and gas, comprising the steps of a) providing as heating apparatus for heating fluid to a temperature of at least about 40 degrees F. (4.4 degrees C.);b) receiving a stream of cool or cold fluid at a mixer, the cool or cold fluid stream being at a temperature of less than a predetermined target temperature;c) the mixer having a first inlet that receives cool or cold fluid from the stream of step “b” and a first outlet that enables discharge of a substantially continuous stream of fluid;d) the mixer having a second net that enables heated water to enter the mixer;e) adding heated water from the heating apparatus of step “a” to the mixer via the second inlet;f) wherein the volume of fluid discharged from the first outlet is greater than the volume of heated water of step “e”;g) wherein the fluid discharged from the mixer after step “f′ is transmitted into a formation producing at least one of oil and gas and transports a proppant into the formation,wherein fluid flows substantially continuously from the first net to the first outlet during the fracturing process,wherein the water is heated in the heating apparatus before fracing chemicals are added to the water, wherein the heating apparatus has a heating capacity to add about 10° F. to 150° F. to the fluid at a flow rate of about 100 barrels per minute of fluid discharged from the first outlet, andwherein the fluid exiting the first outlet of the mixer flows at a rate of at least 20 barrels per minute to provide a substantially continuous flow of fluid and proppant into the formation during the fracturing process.
  • 9. The method of claim 8, wherein the fluid exiting the first outlet of the mixer flows at a rate of at least 30 barrels per minute into the formation.
  • 10. The method of claim 8, wherein the volume of fluid flowing through the mixer during the fracing process is about the same as the volume of fluid being pumped downhole.
  • 11. The method of claim 8, wherein the flow rate through the mixer during the fracing process is about the same as the flow rate of the fluid being pumped downhole.
  • 12. The method of claim 8, wherein the mixer is a mixing tank.
  • 13. The method of claim 8, wherein the heating apparatus comprises at least two heating trucks.
  • 14. The method of claim 8, wherein the mixer has a bore, and the mixer includes a lip that extends into the mixer bore to partially block flow and to create additional turbulence in the mixer bore.
  • 15. The method of claim 8, wherein the mixer has a bore, and the second inlet of the mixer has a wall portion that extends into the mixer bore.
  • 16. The method of claim 8, wherein the fluid is water and the volume of water flowing through the mixer is about the same as the volume of water being pumped into the formation during the fracturing process.
  • 17. The method of claim 8, wherein the flow rate of fluid into the first inlet of the mixer during the fracturing process is about the same as the flow rate of the fluid being pumped to a mixing tank where proppant is added and which is then pumped downhole during the fracturing process.
  • 18. The method of claim 8, wherein the mixer has a bore having a longitudinal axis, and the second inlet of the mixer has a longitudinal axis that is at an angle of between 0 and 90 degrees to the longitudinal axis of the bore of the mixer and wherein substantial mixing of the heated fluid and the cool or cold fluid occurs in the mixer.
  • 19. A method of heating while fracturing of the formation occurs, fluid for use in fracturing a formation producing at east one of oil and gas, the method of heating comprising the steps of: providing a heating apparatus for heating water to a temperature of at least about 40 degrees F. ( 4.4 degrees C.);providing a stream of heated water from the heating apparatus to mix with a stream of cool or cold fluid, the cool or cold fluid stream being at a temperature of less than a predetermined target temperature prior to the mixing, to provide substantially continuously during the [racing process a substantially continuous stream of fluid at or above the target temperature;wherein the volume of the substantially continuous stream of fluid at or above the target temperature is greater than the volume of the stream of the heated water;wherein the flow rate of the substantially continuous stream of fluid at or above the target temperature during the fracing process is about equal to the flow rate of fluid being pumped downhole during the fracing process,wherein the water is heated in the heating apparatus before fracing chemicals are added to the water,wherein the heating apparatus has a heating capacity to add about 10° F. to 150° F. to the fluid at a flow rate of about 100 barrels per minute of fluid discharged from the first outlet,and wherein the flow rate of the substantially continuous stream of fluid at or above the target temperature during the fracing process is at least 20 barrels per minute.
  • 20. The method of claim 19, wherein the flow rate of the substantially continuous stream of fluid at or above the target temperature during the fracing process is at least 30 barrels per minute.
  • 21. The method of claim 19, wherein the volume of the substantially continuous stream of fluid at or above the target temperature during the fracing process is about the same as the volume of fluid being pumped downhole.
  • 22. The method of claim 19, wherein the substantially continuous stream of fluid at or above the target temperature during the fracing process is mixed in a mixing tank.
  • 23. The method of claim 22, wherein the mixing tank receives the stream of heated water and the stream of cool or cold fluid, and the stream of fluid at or above the target temperature flows out of the mixing tank.
  • 24. The method of claim 23, wherein the mixing tank receives the stream of cool or cold fluid from a first inlet, and the stream of fluid at or above the target temperature flows out of the mixing tank through a first outlet.
  • 25. The method of claim 19, wherein the substantially continuous stream of fluid at or above the target temperature during the fracing process is mixed in a mixer having a bore, and the mixer includes a lip that extends into the mixer bore to partially block flow and to create additional turbulence in the mixer bore.
  • 26. The method of claim 25, wherein the mixing tank receives the stream of heated water and the stream of cool or cold fluid, and the stream of fluid at or above the target temperature flows out of the mixing tank.
  • 27. The method of claim 26, wherein the mixer receives the stream of cool or cold fluid from a first inlet, the mixer receives the stream of heated water from a second inlet, and the stream of fluid at or above the target temperature flows out of the mixer through a first outlet.
  • 28. The method of claim 19, wherein the substantially continuous stream of fluid at or above the target temperature during the fracing process is mixed in a mixer having a bore, and the second inlet of the mixer has a wall portion that extends into the mixer bore.
  • 29. The method of claim 19, wherein the mixer receives the stream of cool or cold fluid from a first inlet, the mixer receives the stream of heated water from a second inlet, and the stream of fluid at or above the target temperature flows out of the mixer through a first outlet.
  • 30. The method of claim 19, wherein the fluid comprises water.
CROSS-REFERENCE TO RELATED APPLICATIONS

This is a continuation of U.S. Patent Application No. 14/259,524, filed 23 Apr. 2014, which is a continuation of U.S. Patent Application No. 13/443,678, filed 10 Apr. 2012, now U.S. Patent No. 8,739,875, which is a continuation of U.S. Patent Application No. 12/842,738, filed 23 Jul. 2010, now U.S. Patent No. 8,171,993. Incorporated herein by reference are my prior U.S. Patent Application No. 14/259,524, filed 23 Apr. 2014, my prior U.S. patent application no. 13/443,678, filed 10 Apr. 2012, my prior U.S. patent application no. 12/842,738, filed 23 Jul. 2010, my prior U.S. provisional patent application no. 61/297,097, filed 21 Jan. 2010, my prior U.S. provisional patent application no. 61/254,122, filed 22 Oct. 2009, and my prior U.S. provisional patent application no. 61/276,950, filed 18 Sep. 2009. Priority of these applications is hereby claimed. Also incorporated herein by reference is International Application Serial No. PCT/US2010/045791, filed 17 Aug. 2010 (published 24 Mar. 2011 as International Patent Publication No. WO 2011/034679 A2).

US Referenced Citations (54)
Number Name Date Kind
1522120 Halder Jan 1925 A
1527740 Lipshitz Feb 1925 A
2065789 Bolsinger Dec 1936 A
2122900 Reif Jul 1938 A
2395258 Calvin Feb 1946 A
2486141 Follo Oct 1949 A
2631017 Clyde Mar 1953 A
2645463 Stearns Jul 1953 A
2969451 Logan Jan 1961 A
3232336 Leslie et al. Feb 1966 A
3379250 Matthews et al. Apr 1968 A
3411571 Lawrence Nov 1968 A
3421583 Koons Jan 1969 A
3454095 Webster et al. Jul 1969 A
3572437 Marberry et al. Mar 1971 A
3581822 Cornelius Jun 1971 A
3685542 Daughirda Aug 1972 A
3698430 Van Gasselt et al. Oct 1972 A
3816151 Podlas Jun 1974 A
3938594 Rhudy Feb 1976 A
3980136 Plummer et al. Sep 1976 A
4076628 Clampitt Feb 1978 A
4137182 Golinkin Jan 1979 A
4518568 Shannon May 1985 A
4807701 Hall et al. Feb 1989 A
5018396 Penny May 1991 A
5038853 Callaway Aug 1991 A
5183029 Ranger Feb 1993 A
5190374 Harms Mar 1993 A
5445181 Kuhn et al. Aug 1995 A
5467799 Buccicone et al. Nov 1995 A
5494077 Enoki et al. Feb 1996 A
5551630 Enoki et al. Sep 1996 A
5586720 Spiegel Dec 1996 A
5588088 Flaman Dec 1996 A
5623990 Pirkle Apr 1997 A
5656136 Gayaut et al. Aug 1997 A
5979549 Meeks Nov 1999 A
6024290 Dosani et al. Feb 2000 A
6470836 Manley et al. Oct 2002 B1
7298968 Boros et al. Nov 2007 B1
7477836 White, III Jan 2009 B2
7744007 Beagen et al. Jun 2010 B2
8044000 Sullivan et al. Oct 2011 B2
8171993 Hefley May 2012 B2
8286595 Cerney et al. Oct 2012 B2
8534235 Chandler Sep 2013 B2
8739875 Hefley Jun 2014 B2
20070170273 McIllwain Jul 2007 A1
20080029267 Shampine Feb 2008 A1
20090056645 Hobbs et al. Mar 2009 A1
20090060659 Wallace Mar 2009 A1
20090308613 Smith Dec 2009 A1
20100000508 Chandler Jan 2010 A1
Foreign Referenced Citations (1)
Number Date Country
WO 2010-18356 Feb 2010 WO
Non-Patent Literature Citations (33)
Entry
International Search Report for International application No. PCT/US2010/045791.
Written Opinion of the International Searching Authority for International application No. PCT/US2010/045791.
“Optimizing the Performance of Radiant Heating System” dated Jul. 1, 2008.
PSNC Energy, “Commercial and Industrial Facilities Go ‘Tankless’” available on the Internet at least as early as Nov. 18, 2006, Internet Archive Wayback Machine, http://web.archive.org/web/20061118194825/http://www.psncenergy.com/en/small-to-medium-business/business-sectors/hospitality/commercial-industrialfacilities-go-tankless.htm.
Plaintiffs' Non-Infringement and Invalidity Contentions, US District Court for the District of North Dakota by Energy Heating, LLC, and Rocky Mountain Oilfield Services, LLC against Heat on-the-Fly, LLC and Super Heaters North Dakota, LLC (No. 4:13-cv-00010-DLH-CSM).
Redline Version of Plaintiffs' Amended Non-Infringement and Invalidity Contentions, US District Court for the District of North Dakota by Energy Heating, LLC, and Rocky Mountain Oilfield Services, LLC against Heat on-the-Fly, LLC and Super Heaters North Dakota, LLC (No. 4:13-cv-00010-DLH-CSM).
Reexamination File History for Control No. 90/012,627, 307 Pages.
Deposition of Francis Bostick, dated Aug. 7, 2014.
Deposition of Ron Chandler, dated Jun. 17, 2014.
Deposition of James Cole, dated Jul. 17, 2013.
Deposition of Michael Gibson, dated Jan. 8, 2015.
Deposition of Jonathon Holub, dated Jun. 17, 2014.
30(b)(6) Deposition of Energy Heating, LLC, Wayne Lind, dated Aug. 15, 2013.
Deposition of Ron Lyles, dated Jul. 17, 2013.
30(b)(6) Deposition of Rocky Mountain Oil Field Services, LLC, Matthew Mason deponent, dated Aug. 14, 2013.
Deposition of Matthew Mason, dated Oct. 21, 2014.
30(b)(6) Deposition of Heat Waves Oil Serivce, LLC, Austin Peitz deponent, dated Oct. 23, 2014.
Deposition of Brian Radke, dated Sep. 30, 2014.
Deposition of Michael Siepert, dated Oct. 21, 2014.
30(b)(6) Deposition of StimTech, Roger Torgerson deponent, dated Apr. 23, 2014.
Deposition of Jim Wharry, dated Jan. 8, 2015.
Reexamination File History for Control No. 90/013,260, 2673 Pages (Deposition of Pat Tschacher submitted on Apr. 13, 2015 is removed from the File History. A redacted Pat Tschacher with pp. 51, 52, 123, 124, 164, 176, 178-181, 195, 196, 273, and 274 removed and a petition to expunge information under MPEP §724.06 and 37 C.F.R. §1.59 submitted on May 4, 2015 is included in the File History).
Habib D. Zughbi et al., Mixing in Pipelines with Side and Opposed Tees, Ind. Eng. Chern. Res., American Chemical Society, 42 (21), pp. 5333-5344 (2003).
Keng Seng Chan et al., Oilfield Chemistry at Thermal Extremes, Oilfield Review, pp. 4-17 (Autumn 2006).
Web page describing Firestorm™ Direct-Contact Water Heaters, captured on May 11, 2008 by the Internet Archive, available at brochure http://web.archive.org/web/20080511165612/http://www.heatec.com/products concrete/firestorm/firestorm.htm.
Komax HotShot™ Inline Steam Heater, available at least as early as Apr. 20, 2008, https://web.archive.org/web/20080420074231/http://www.komax.com/products/inline—steam—heater.html.
Armstrong International, Flo-Rite-Temp Bulletin No. AY-408-H, May 2002, available at https://web.archive.org/web/20071213171904/http://www.armstronginternational.com/files/products/wheaters/pdf/ay408.pdf.
Consulting Agency Trade (C.A.T.) GmbH, Hydration Unit, Feb. 29, 2008, available at http://www.consulting-agency-trade.com/files/hydration—unit—04.pdf.
Findings of Fact, Conclusions of Law, and Order for Judgment on Issue of Inequitable Conduct, Civil Case No. 4:13-cv-10, Energy Heating, LLC, et al. v. Heat On-The-Fly, LLC, et al., United States District Court for the District of North Dakota, Record Document No. 619, Dated Jan. 14, 2016.
Declaration of Len Brignac (Offer of Proof), Civil Case No. 4:13-cv-10, Energy Heating, LLC, et al. v. Heat On-The-Fly, LLC, et al., United States District Court for the District of North Dakota, Record Document No. 580, Dated Sep. 18, 2015.
Declaration of Seth Nehrbass (Offer of Proof), Civil Case No. 4:13-cv-10, Energy Heating, LLC, et al. v. Heat On-The-Fly, LLC, et al., United States District Court for the District of North Dakota, Record Document No. 579, Dated Sep. 18, 2015.
Ralph R. Erickson, Chief Judge, Memorandum Opinion and Order Granting Plaintiffs/Third-Party Defendant's Motions For Partial Summary Judgment of Invalidity and Denying Defendants' Motion to Dismiss Inequitable Conduct Claims from 4:13-cv-00010-RRE-ARS, Energy Heating, LLC et al. v. Heat On-The-Fly, LLC et al., pp. 1-22, published on Mar. 31, 2015 by United States District Court for the District of North Dakota, Northwestern Division.
Office Action in Ex Parte Reexamination Control No. 90/013,260, pp. 1-24, Feb. 11, 2015, U.S. Patent and Trademark Office.
Related Publications (1)
Number Date Country
20150013986 A1 Jan 2015 US
Provisional Applications (3)
Number Date Country
61297097 Jan 2010 US
61254122 Oct 2009 US
61276950 Sep 2009 US
Continuations (3)
Number Date Country
Parent 14259524 Apr 2014 US
Child 14502652 US
Parent 13443678 Apr 2012 US
Child 14259524 US
Parent 12842738 Jul 2010 US
Child 13443678 US