The invention relates to a water processing device according to the preamble of claim 1.
Water processing devices which use filter units and adsorption units in order to process water so as to remove pollutants from water have already been proposed. Whereas a processing efficiency is sufficient for most of the pollutants contained in the water, the processing efficiency of water processing devices of this kind in respect of micro-pollutants is significantly reduced, since these pollutants on the one hand are present in a much lower concentration and on the other hand have at least substantially lower molecular weights. Although the concentrations of the individual micro-pollutants usually lie below the critical tolerance limits for the environment and humans, a sum parameter of the various micro-pollutants is not taken into consideration. It is therefore of great interest to remove these pollutants from water with increased efficiency.
The object of the invention is in particular to provide a device of this kind having improved properties in respect of its efficiency, in particular processing efficiency. The object is achieved in accordance with the invention by the features of claim 1, whereas advantageous embodiments and developments of the invention can be derived from the dependent claims.
The invention relates to a water processing device which is provided for removing micro-pollutants, in particular medicaments, from water, said device comprising at least one filter unit which is provided for at least one filtering of water in at least one operating state and which comprises at least one tubular filter element with at least two end portions, and comprising at least one adsorption unit, which at least partially adsorbs the micro-pollutants in at least one operating state.
It is proposed that the end portions enclose an inner angle of from 0° to 90° when in the assembled state. The efficiency, in particular processing efficiency, can be improved as a result. In particular, the flow rates in the case of cross-flow filtration can be improved.
The term “provided” shall be understood here in particular to mean specially designed and/or equipped. The fact that an object is provided for a specific function shall be understood in particular to mean that the object fulfils and/or carries out this specific function in at least one application and/or operating state. A “water processing device” shall be understood in particular to mean a device which is provided for processing, purifying, clarifying, cleaning and/or purging water, in particular drinking water, and advantageously for removing micro-pollutants, in particular in that these are filtered and/or sorbed from the water, in particular absorbed and/or particularly preferably adsorbed. The water processing device is in particular at least a part, in particular a subassembly, of a water processing cartridge, a system for water processing and/or a water processing plant, such as a sewage treatment plant. In particular, the water processing device can fully comprise the water processing cartridge, the system for water processing and/or the water processing plant. In particular, the water processing device can be connected, advantageously directly, to a domestic water supply, preferably to a water tap, and in particular is arranged upstream thereof in respect of the flow direction. An “operating state” of the water processing device shall be understood in particular to mean a state in which water is flowed through the water processing device fully. The term “micro-pollutants” shall be understood in particular to mean pollutants such as industrial chemicals, medicaments, in particular carbamazepine, sulfamethoxazole, diclofenac and/or ethinylestradiol, heavy metals and/or pesticides, which are present in the water, in particular dissolved therein, in a low concentration, more specifically in particular in a concentration of less than 10,000 ppm, preferably less than 1000 ppm, more preferably less than 100 ppm, and particularly preferably less than 10 ppm. In particular, the micro-pollutants have a molecular weight of less than 100 kDa, preferably less than 10 kDa, more preferably less than 1 kDa, and particularly preferably less than 0.1 kDa.
An “adsorption unit” shall be understood in particular to mean a unit having at least one adsorption element, which is provided for at least substantially securely binding and/or adsorbing a micro-pollutant, in particular a dissolved micro-pollutant, in particular by means of at least one adsorbent, preferably a plurality of adsorbents, more specifically in particular on a surface, preferably in a cavity, and particularly preferably in a pore of the adsorbent. In particular, the underlying adsorption mechanism for binding the micro-pollutants is different from a covalent bonding. The adsorption element is advantageously provided for at least substantially securely binding the micro-pollutants by means of the Coulomb and/or van der Waals interaction. The expression “at least substantially securely binding a micro-pollutant” shall be understood in particular to mean that an adsorbed micro-pollutant is washed out in a wash-out test by means of flushing with water within a period of time of at least one hour, advantageously at least two hours, and preferably at least four hours, to an extent of at most one percent, advantageously at most half a percent, and preferably at most a tenth of a percent of a bound substance quantity. The adsorption unit is in particular at least partially chemically regenerable. The term “chemically regenerable” shall be understood in particular to mean that the at least one adsorbent can be regenerated by means of a chemical reaction. In particular, the adsorbent can be chemically regenerated by means of an acid and/or a lye, preferably sodium hydroxide. The adsorbent is also chemically regenerable in particular by means of a saline solution, preferably a NaCl solution. Alternatively or additionally, the adsorbent can be regenerated in particular by being exposed to energy, for example in the form of heat and/or electromagnetic radiation, in particular by being exposed to light, preferably UV light. The adsorption unit is formed in particular as an advantageously water-permeable solid block or as a fill, which block/fill is formed at least in part by at least one adsorption element.
The adsorption unit preferably comprises at least one specific and/or non-specific adsorption element. A “non-specific adsorption element” shall be understood in particular to mean an adsorption element which comprises at least one non-specific adsorbent, which is provided for adsorbing a plurality of micro-pollutants chemically non-specifically, in particular to the same extent and preferably independently of functional groups of the micro-pollutants and/or a charge of the micro-pollutants. The non-specific adsorbent is provided in particular for adsorbing various micro-pollutants in a sterically dependent manner. The non-specific adsorption element can advantageously comprise a plurality of non-specific adsorbents. A “specific adsorption element” shall be understood in particular to mean an adsorption element which comprises at least one specific adsorbent, which is provided for adsorbing specific micro-pollutants in a chemically or physically specific manner, in particular to a different extent and preferably depending on functional groups of the micro-pollutants and/or a charge of the micro-pollutants. The specific adsorbent is provided in particular for adsorbing certain micro-pollutants sterically independently. The specific adsorption element can advantageously comprise a plurality of specific adsorbents.
Alternatively or additionally, the adsorption unit can be formed at least partially in one piece with a further body, for example the filter unit, more specifically advantageously in the form of an impregnation and/or coating. The expression “formed at least partially in one piece” shall be understood in this context in particular to mean that at least one component of at least one object is formed in one piece with at least one component of at least one further object. The term “in one piece” shall be understood in particular to mean connected at least by a substance-to-substance bond, for example by a welding process, an adhesive process, an injection moulding process, and/or another process appearing expedient to a person skilled in the art. The term “in one piece” shall advantageously also be understood to mean “in one part”. The term “in one part” shall be understood in particular to mean formed in a single piece, for example by production from a casting and/or by production in a one-component or multi-component injection moulding method advantageously from an individual blank, and particularly preferably in a spinning method, in particular a wet spinning method, such as reactive spinning, in which the filter unit is produced with integrated adsorbent in particular in a phase inversion process.
A “filter unit” shall be understood in particular to mean a membrane filter unit provided for cleaning micro-pollutants from water by retaining the micro-pollutants at pores of the filter membrane. The filter element of the filter unit is formed in particular as a filter membrane and advantageously as a hollow-fibre filter membrane, in which a wall of the filter element forms the membrane and defines a hollow channel. In principle, the filter element can perform a cleaning of water guided in the hollow channel as the water passes from the closed hollow channel through the filter element into an external space, such that water leaving the hollow channel is cleaned, or the filter element can preferably perform a cleaning of water entering the hollow channel from the external space, the water then being guided in the cleaned state in the hollow channel. The filter unit in particular comprises at least one filter element, preferably at least 5 filter elements, preferably at least 10, and particularly preferably at least 20 filter elements.
An “end portion” of an object shall be understood in particular to mean a portion which extends along an extent, in particular a main extent, of the object as far as an end of the object. The end portion extends along the filter element in particular over at most 10 cm, preferably over at most 5 cm, and particularly preferably over at most 1 cm.
An “inner angle” shall be understood in particular to mean an angle which is enclosed by two vectors which each run parallel to one of the two end portions respectively and which point in the direction of the end of the respective end portions having an opening.
In particular, the filter element, when in the assembled state, is bent at least in portions and is preferably looped. In order to achieve a particularly efficient arrangement of the filter element and advantageously increase flow rate, it is proposed that the filter element, when in the assembled state, is bent at least substantially in a U-shaped manner. The two end portions of the filter element are in particular at least substantially parallel, advantageously anti-parallel, to one another when in the assembled state. The filter element preferably has a plane of main extent which, in the assembled state, intersects the filter element over the entire extent of the filter element. A “plane of main extent” of an object shall be understood in particular to mean a plane which is parallel to the largest side face of the smallest imaginary cuboid which just fully surrounds the object, and runs through the centre point of the cuboid. The term “substantially parallel” shall be understood here in particular to mean the orientation of a direction relative to a reference direction, in particular in a plane, wherein the direction has a deviation in relation to the reference direction in particular of less than 8°, advantageously less than 5°, and particularly advantageously less than 2°.
It is also proposed that the water processing device comprises a holding element, which arranges the end portions fixedly relative to one another in the assembled state. The two end portions of the filter element are in particular fixedly connected to the holding element, preferably at least with a substance-to-substance bond, in the assembled state. The holding element is advantageously formed by a binder, for example an adhesive, preferably a resin, and particularly preferably an epoxy resin. The filter element, in particular the end portions of the filter element, is/are sealed off, in particular at least in part, in such a way that infiltration of the binder into the filter element, in particular into the wall of the filter element, in particular at the end portions, is avoided. At the time of assembly, the end portions are in particular arranged in the binder, which is still liquid. The binder is advantageously cured. The cured binder is also in particular ground in such a way that openings in the end portions of the filter element are exposed. The holding element is preferably cylindrical, tubular and/or planar. The filter element hereby can be fixedly arranged in a simple way.
It is also proposed that the filter unit comprises at least one further filter element, which is formed at least substantially equivalently to the filter element and which surrounds the filter element at least in part. The fact that “two objects are at least substantially equivalent” shall be understood in particular to mean that they, in particular when assembled, are largely identical, preferably have the same shaping and in particular orientation, and preferably differ from one another merely by production tolerances and/or manufacturing defects. In particular, the further filter element is looped in a similar way to the filter element. In addition, the filter elements formed equivalently can differ from one another in particular by a length. The filter element and the further filter element, in particular the end portions of the filter element and the end portions of the further filter element, are arranged at least substantially parallel or preferably anti-parallel to one another, at least in part. The fact that “a further object at least partially surrounds an object” shall be understood in particular to mean that at least one straight line exists which runs firstly through the further object, then through the first object, and then again through the further object. The filter unit can also comprise additional filter elements, in particular a multiplicity of additional filter elements, in particular additional filter elements formed at least substantially equivalently to the filter element, which in turn surround the filter element and the further filter element. Alternatively, the further filter element can be arranged next to the filter element. In particular, the installation space can be reduced hereby, and the fill density of the filter unit can be improved advantageously.
In a preferred embodiment of the invention, it is proposed that the filter element, when assembled, has a plane of main extent and the further filter element, when assembled, as a further plane of main extent, which is different from the plane of main extent of the filter element. In particular, the plane of main extent of the filter element can be arranged at least substantially parallel to the further plane of main extent of the further filter element. A simple arrangement of the filter elements can be achieved hereby.
In a further preferred embodiment of the invention it is proposed that the plane of main extent of the filter element and the further plane of main extent of the further filter element are arranged at an angle to one another. Surface normals of the plane of main extent of the filter element and of the further plane of main extent of the further filter element preferably enclose an angle of at least 20°, preferably of at least 50°, and particularly preferably of at least 80° and/or in particular of at most 160°, preferably of at most 130°, and particularly preferably of at most 100°. The plane of main extent of the filter element and the further plane of main extent of the further filter element are advantageously arranged at least substantially at right angles to one another. The expression “at least substantially at right angles” shall be understood here in particular to mean an orientation of a direction relative to a reference direction, wherein the direction and the reference direction, in particular considered in a plane, enclose an angle of 90° and the angle in particular has a maximum deviation from 90° of in particular less than 8°, advantageously less than 5°, and particularly advantageously less than 2°. A homogeneous flow through the filter elements can be achieved hereby.
In order to further improve in particular a fill density of the filter unit and advantageously a homogeneous flow through the filter elements, it is proposed that the filter unit comprises a group of filter elements and a further group of filter elements. The group of filter elements comprises at least one additional filter element, in particular a plurality of additional filter elements, which is/are formed at least substantially equivalently to the filter element. The further group of further filter elements comprises at least one additional further filter element, in particular a plurality of additional further filter elements, which is/are formed at least substantially equivalently to the further filter element. The filter elements of a group are preferably bundled by means of a mesh. In particular, at least one of the further filter elements of the further group preferably surrounds, in each case, preferably at least one of the filter elements of the first group of filter elements. In particular, at least one of the further filter elements of the further group of further filter elements preferably has, in each case, at least one plane of main extent, which, in each case, is different at least preferably from at least a plane of main extent of at least one filter element of the first group of filter elements. Alternatively or additionally, the filter unit can comprise only one of the groups or additional groups, in particular with additional filter elements which advantageously surround the filter element and the further filter element.
In a preferred embodiment of the invention, it is proposed that the filter unit is at least substantially tubular. Filter elements of the filter unit are preferably arranged in a circular manner and at least in part form a tube wall of the filter unit. The tubular filter unit in particular defines a tube channel, in which the adsorption unit can be arranged advantageously at least in part. The installation space can be further reduced hereby.
In a further preferred embodiment of the invention, it is proposed that the adsorption unit is at least substantially tubular. The tubular adsorption unit in particular defines a tube channel, in which the filter unit can be arranged advantageously at least in part. The installation space can be further reduced hereby.
In order to protect the adsorption unit against damage, it is proposed that the water processing device comprises a filter housing, in which the filter unit is arranged at least in part. The filter housing is formed in particular as a hollow cylinder, which preferably has a cylinder jacket partially surrounding the filter unit. The filter unit is in particular arranged in the filter housing to an extent of less than 80%, preferably less than 60%, and particularly preferably less than 40%. The cylinder jacket also in particular surrounds the holding element at least in part, preferably at least to a large extent, and particularly preferably completely. In particular, the holding element is connected to the filter housing by a substance-to-substance bond.
In order to protect the filter unit against damage, it is proposed that the water processing device comprises an adsorption housing, in which the adsorption unit is arranged at least in part, in particular to a large extent, and preferably completely. The adsorption housing is formed in particular as a hollow cylinder, which preferably has a cylinder jacket surrounding the adsorption unit at least partially, in particular at least to a large extent, and preferably completely. The expression “at least to a large extent” shall be understood here in particular to mean more than 50%, advantageously more than 65%, preferably more than 75%, particularly preferably more than 85%, and particularly advantageously at least 95%. The adsorption unit can be protected against damage hereby.
It is also proposed that the filter housing is arranged upstream of the adsorption housing in respect of the flow direction. In particular, the filter unit arranged in the filter housing is arranged upstream, in respect of the flow direction, of the adsorption unit arranged in the adsorption housing. An efficient arrangement and in particular a resultant efficient flow through the adsorption housing can be achieved hereby.
It is conceivable in particular that the filter housing and the adsorption housing are formed in one piece with one another. In order to increase the flexibility of the water processing device and in particular convenience for the customer, and in order to enable individual components of the water processing device to be replaced, it is proposed that the water processing device comprises a connection unit, which connects the adsorption housing and the filter housing to one another when these are in the assembled state. The connection unit is in particular provided for an at least positively-locking connection of the adsorption housing and the filter housing, Alternatively or additionally, the connection unit can also be provided for connection with a force-locking connection and/or a substance-to-substance bond. The connection unit is in particular formed at least partially in one piece with the adsorption housing and/or the filter housing. The connection unit comprises at least one connection element, which, in the assembled state, connects the filter housing to the adsorption housing. The connection element is in particular formed separately from the adsorption housing and/or the filter housing. The connection element is preferably formed as a preferably tubular sleeve. The connection unit also comprises at least one connection element receptacle, which is provided for receiving the connection element. The connection element receptacle is formed as a recess in the filter housing and/or the adsorption housing.
It is also proposed that the water processing device comprises at least one screen unit separating the filter housing and the adsorption housing from one another and at least partially closing at least the adsorption housing from at least one side. The screen unit in particular comprises at least one screen cover, which is at least provided for separating the adsorption unit from the filter unit. The screen cover in particular comprises a plurality of through-openings in order to allow a flow of water between the filter unit and adsorption unit. The screen cover can be connected to the adsorption housing in particular with positive engagement. Alternatively or additionally, the screen cover can be formed in one piece with the adsorption housing. The screen unit in particular also comprises at least one frit, preferably a porous frit. The fruit is arranged in particular on a side of the screen unit facing towards the adsorption unit and is provided preferably for preventing a contamination of the adsorption unit and particularly preferably for preventing the adsorption unit from escaping from the adsorption housing. The frit is formed in particular from a preferably cross-linked plastics material, in particular from at least one cross-linked polymer, advantageously polyethylene. Alternatively or additionally, the frit can be formed at least partially in one piece with the adsorption unit. In particular, the protection of the sensitive filter unit can be improved hereby, since said filter unit can be protected against particles leaving the adsorption unit, in particular in the event that this is damaged.
It is also proposed that the water processing device comprises a cartridge, in which, in the assembled state, the adsorption housing and the filter housing are arranged and which comprises openings, which are arranged offset relative to one another in the peripheral direction as considered in the axial direction. The term “axial direction” shall be understood in particular to mean a main direction of extent and/or preferably an axis of rotational symmetry of the cartridge, in which said cartridge advantageously has at least threefold rotational symmetry. A “main direction of extent” of an object shall be understood here in particular to mean a direction running parallel to the longest edge of the smallest imaginary cube just surrounding the object completely. A “peripheral direction” shall be understood in particular to mean a direction perpendicular to the main direction of extent and/or in particular a rotary direction about the axis of rotational symmetry of the cartridge. In particular, the openings are arranged around at least a majority of the cartridge in the peripheral direction. The openings are provided in particular so as to allow water that is to be processed to flow against the filter unit. The cartridge advantageously comprises further openings, which are arranged along the axial direction and in particular along the peripheral direction in a manner offset relative to the first openings. The further openings in particular are formed at least substantially equivalently to the first openings. The cartridge is formed in particular from a plastics material, preferably from polypropylene, and particularly preferably from a polypropylene homopolymer. In particular, the filter unit arranged in the filter housing and the adsorption unit arranged in the adsorption housing can be protected hereby. In particular, water can be made to flow against the filter unit in a particularly homogeneous manner.
The water processing device is not intended to be limited here to the above-described application and embodiment. In particular, the water processing device, in order to comply with the operating principle described herein, can have a number of individual elements, components and units differing from the number stated herein. In addition, values lying within the stated limits are also considered to be disclosed and arbitrarily selectable from the value ranges specified in this disclosure.
Further advantages will become clear from the following description of the drawings. The drawings show exemplary embodiments of the invention. The drawings, the description, and the claims contain numerous features in combination. A person skilled in the art will also expediently consider the features individually and combine them to form useful further combinations.
In the drawings:
The water processing device comprises a screen unit 38a. The screen unit 38a separates the filter housing 32a and the adsorption housing 34a from one another. The screen unit 38a also at least partially closes the adsorption housing 34a from at least one side. The screen unit 38a comprises the screen cover 68a. The screen cover 68a at least partially closes the adsorption unit from one side. The screen cover 68a also separates the adsorption unit 18a from the filter unit 10a. The screen cover 68a is connected to the adsorption housing 34a with positive engagement. The screen cover 68a could also be connected to the adsorption housing 34a in a force-locking manner and/or with a substance-to-substance bond. Alternatively or additionally, the screen cover 68a can be formed in one piece with the adsorption housing 34a. The screen cover 68a comprises a plurality of through-openings. The through-openings are provided for enabling a flow of water between the filter unit 10a and the adsorption unit 18a.
The screen unit 38a comprises at least one frit 70a. The frit 70a is planar. The frit 70a is produced from a porous material. The frit 70a is produced from a cross-linked polyethylene. The frit 70a is arranged on a side of the screen unit 38a facing towards the adsorption unit 18a. The frit 70 is arranged in the adsorption housing 34a. The frit 70a is arranged after the screen cover 68a and in particular before the adsorption unit 18a, as considered in the direction of flow. The frit 70a is provided for preventing contamination of the adsorption unit 18a and preferably for preventing the adsorption unit 18a from escaping at least in part from the adsorption housing 34a.
The screen unit 38a comprises a further screen cover 72a. The further screen cover 72a is formed at least substantially equivalently to the screen cover 68a. The further screen cover 72a is formed in one piece with the adsorption housing 34a. It is conceivable that the further screen cover 72a is formed separately from the adsorption housing 34a and in particular is connected thereto in a frictionally engaged and/or positively engaged manner. The further screen cover 72a closes the adsorption housing 34a at least partially from at least one further side. The further screen cover 72a is arranged after the adsorption unit 18a as considered in the direction of flow. The screen unit 38a also comprises a further frit 74a. The further frit 74a is formed at least substantially equivalently to the first frit 70a. The further frit 74a is arranged in the adsorption housing 34a. The further frit 74a is arranged after the adsorption unit 18a and in particular before the further screen cover 72a, as considered in the direction of flow.
The water processing device comprises a connection unit 36a. The connection unit 36a, in the assembled state, connects the adsorption housing 34a and the filter housing 32a to one another, in particular with positive engagement. Alternatively or additionally, the connection unit 36a can also be provided for a force-locking connection and/or a substance-to-substance bond. For example, it is conceivable that the connection unit 36a comprises a thread for an additional force-locking connection. The connection unit 36a comprises at least one connection element 76a, which, in the assembled state, connects the filter housing 32a to the adsorption housing 34a. The connection element 76a is formed separately from the adsorption housing 34a and/or the filter housing 32a. Alternatively or additionally, the connection element 76a can be formed at least partially in one piece with the filter housing 32a and/or the adsorption housing 34a. The connection element 76a is formed as a sleeve.
The connection unit 36a comprises at least one connection element receptacle 78a, which is provided for receiving the connection element 76a. The connection element receptacle 78a is formed correspondingly to the connection element 76a. The connection element receptacle 78a is formed as a recess in the adsorption housing 34a. The connection unit 36a comprises a further connection element receptacle 80a. The further connection element receptacle 80a is formed at least substantially equivalently to the connection element receptacle 78a. The further connection element receptacle 80a is formed as a recess in the filter housing 32a.
At the time of assembly of the water processing device, the further frit 74a is arranged in the adsorption housing 34a. The adsorption unit 18a is also arranged in the adsorption housing 34a, in particular after the further frit 70a as considered in the flow direction. The frit 70a is arranged in the adsorption housing 34a, in particular after the adsorption unit 18a as considered in the flow direction. The screen cover 68a closes the adsorption housing 34a. The filter unit 10a is arranged in the filter housing 32a. The filter housing 32a is arranged after the adsorption housing 34a as considered in the flow direction. The connection unit 36a connects the adsorption housing 34a and the filter housing 32a. The connection element 76a engages in the connection element receptacle 78a. The connection element 76a engages in the further connection element receptacle 80a. The filter housing 32a and the adsorption housing 34a are arranged in the receiving space 60a of the cartridge 40a. The cylinder jacket 58a is closed by the cartridge termination 64a. The cylinder jacket 58a is also connected to the cartridge connector 62a. The cartridge 40a can also be arranged in a superior housing 82a (see
Part of the filter unit 10a is shown schematically in
The filter element 12a is bent at least in portions in the assembled state and in particular has a loop shape. The filter element 12a is bent in such a way that the end portions 14a, 16a of the filter element 12a enclose an inner angle of from 0° to 90°. In the present case the end portions 14a, 16a are at least substantially parallel or preferably antiparallel to one another, such that the filter element 12a is preferably bent in a U shape. In the present case, the inner angle is consequently approximately 0°. The filter element 12a in particular has a plane of main extent 24a. The filter element 12a is intersected by the plane of main extent 24a over the entire extent of the filter element 12a.
The filter unit 10a also comprises at least one further filter element 22a. A further filter element 22a is formed at least substantially equivalently to the filter element 12a, in particular is shaped equivalently thereto and is advantageously fastened equivalently to the holding element 20a. The filter element 12a and the further filter element 22a differ from one another by a length. The further filter element 22a surrounds the filter element 12a at least in part. The further filter element 22a has a further plane of main extent 26a. In the assembled state, the further plane of main extent 26a of the further filter element 22a is different from the plane of main extent 24a of the filter element 12a. The plane of main extent 24a of the filter element 12a and the further plane of main extent 26a of the further filter element 22a are arranged at an angle to one another. In the present case, the plane of main extent 24a of the filter element 12a and the further plane of main extent 26a of the further filter element 22a are at least substantially perpendicular to one another. The planes of main extent 24a, 26a can also be arranged at a different angle to one another, in particular from 20° to 160°, or alternatively can be arranged at least substantially parallel to one another.
The filter unit 10a also comprises a group 28a (see
In
The non-specific adsorption element 50a comprises at least one organic adsorbent. In the present case, the organic adsorbent is activated carbon. The organic adsorbent is present here in the form of a cylindrical block. The organic adsorbent is activated carbon, in particular sintered granulated activated carbon. Alternatively or additionally, the organic adsorbent can be present in the form of a fill, in particular in granulated form. The non-specific adsorption element 50a comprises a main body 54a. The main body 54a forms the adsorption unit 18a to a large extent. The adsorption unit 18a comprises an adsorbent, which forms the main body 54a of the adsorption unit 18a at least in part. In the present case, the organic adsorbent forms the main body 54a at least in part. Alternatively, the organic adsorbent can form the main body 54a completely.
The non-specific adsorption element 50a also comprises at least one mineral adsorbent. The non-specific adsorption element 50a at least comprises the mineral adsorbent to an extent of 5% to 20%. In the present case, the non-specific adsorption element 50a comprises a mineral adsorbent to an extent of 5%. In the present case, the mineral adsorbent is bentonite. The mineral adsorbent also forms the main body 54a of the non-specific adsorption element 50a at least in part. Alternatively or additionally, the non-specific adsorption element 50a can comprise diatomaceous earth, silica gel, alumina and/or zinc oxide as mineral adsorbent.
The adsorption unit 18a comprises a specific adsorption element 52a. The adsorption unit 18a can consist of the specific adsorption element 52a to an extent of at least 2% and at most 90%. In the present case, the adsorption unit 18a consists of the specific adsorption element 52a to an extent of 20%. In particular, the adsorption unit 18a can also consist of the specific adsorption element 52a to an extent of further values of from 2% to 90%. The specific adsorption element 52a comprises at least one specific adsorbent. Alternatively or additionally, the main body 54a of the adsorption unit 18a can be formed at least in part of a specific adsorbent.
The specific adsorption element 52a comprises at least one reversed-phase adsorbent, such as a cross-linked, functionalised organic polymer. The specific adsorption element 52a preferably comprises a cross-linked ethylvinylbenzene as reversed-phase adsorbent. The specific adsorption element 52a further comprises at least one ion exchanger adsorbent. The ion exchanger adsorbent can be formed as a cation exchanger or anion exchanger. In the present case, the ion exchanger adsorbent is formed as an anion exchanger. The ion exchanger adsorbent is an agarose, which is functionalised by means of an ammonium group, preferably a quaternary ammonium group, and particularly preferably diethylaminoethyl (DEAE). The specific adsorption element 52a also comprises at least one adsorbent, which is provided for adsorption by means of hydrogen bridges. In the present case, the adsorbent which is provided for adsorption by means of hydrogen bridges is linear and/or cross-linked polyvinylpyrrolidone (PVPP). The specific adsorption element 52a also comprises at least one complexing agent adsorbent. In the present case, the complexing agent adsorbent is ethylenediaminetetraacetic acid (EDTA). Alternatively or additionally, the specific adsorbent 52a can comprise further specific adsorbents.
The non-specific adsorption element 50a and the specific adsorption element 52a are at least partially in contact with one another. The non-specific adsorption element 50a and the specific adsorption element 52a are arranged at least partially within one another and in particular are mixed with one another.
In an operating state, water that is to be cleaned is flowed through the water processing device fully (see
The water processing device is arranged in the superior housing 82a. The superior housing 82a comprises an outlet with a screw thread for connection to a water pipeline. The pre-filtration unit 56a is arranged in a further superior housing 84a. The further superior housing 84a comprises a connector with screw thread for connection to a water pipeline. The pre-filtration unit 56a and the water processing device are arranged relative to one another such that water which enters the further superior housing 84a firstly passes through the pre-filtration unit 56a and then passes into the superior housing 82a, in which the water is processed by means of the water processing device.
Further exemplary embodiments of the invention are shown in
Number | Date | Country | Kind |
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102016107483.7 | Apr 2016 | DE | national |
This patent application is a Continuation of International Patent Application No. PCT/EP2017/059553, filed Apr. 21, 2017, which claims the benefit of German Patent Application No. 10 2016 107 483.7, filed Apr. 22, 2016, which are each incorporated by reference.
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Number | Date | Country | |
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20190039914 A1 | Feb 2019 | US |
Number | Date | Country | |
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Parent | PCT/EP2017/059553 | Apr 2017 | US |
Child | 16157385 | US |