Patent Application
20120305459
The present invention relates to a water producing system using composite water treatment technologies, and to a system in which freshwater is obtained from raw water, which is treatment target water A and treatment target water B differing from each other in osmotic pressure, through a fresh water conversion technology. In more detail, the present invention relates to a system for producing fresh water that can be applied to the field of water clarification treatment in waterworks, the field of industrial-use water production such as industrial water, food and medical process water, and semiconductor-related component cleaning water, in an energy saving and efficient manner.
In recent years, many water-related technologies have been developed. Among others, membrane separation has been coming into wide use in various fields for its characteristics of being capable of achieving: energy savings; space savings; reduction in power consumption; improvement in quality of the product, and the like.
The separation membrane used in water treatment can generally be classified into two, namely nano-filtration membrane (NF membrane)/reverse osmosis membrane (RO membrane), and microfiltration membrane (MF membrane)/ultrafiltration membrane (UF membrane). The former is used in desalination, deionization and the like from seawater or brackish water, while the other is used in water cleaning process for producing industrial water or tap water from river water, groundwater, or treated sewage. Further, what is actively introduced is “membrane bioreactor (Membrane Bioreacter; MBR)” in which sewage or industrial drainage which has conventionally been treated by the activated sludge process is treated by MF/UF membrane directly immersed in activated sludge tank.
Under recent circumstances where attention to water shortage is called, these water treatment methods using membranes have undergone further technical development. In recent years, a great number of water producing plants that employ a scheme referred to as “integrated membrane system (Integrated Membrane System; IMS)”, in which: pre-treatment of removing organic substances and particulates in seawater or brackish water by using the MF/UF membrane, or of cleaning sewage or industrial waste water by using the MBR is carried out; and thereafter treatment is carried out using the RO membrane, to thereby efficiently obtain fresh water, are built in those regions such as Middle East region, Asia region suffering from water shortage.
Currently, a system that produces freshwater from seawater or brackish water may be based on, for example, the technology in which a pre-treatment by sand filtration which is a conventional water clarification technology is carried out, and thereafter treatment is carried out with the NF/RO membrane. In addition thereto, it may be based on the method as described above, in which seawater or brackish water is pre-treated using the MF/UF membrane, and thereafter treatment is carried out with the NF/RO membrane. However, with this system, since salt in the seawater cannot be removed by the pre-treatment, desalination is entirely carried out with the NF/RO membrane at the rear stage. Then, with the NF/RO membrane treatment method which requires supply pressure being higher than the osmotic pressure, pressure must be applied when supplying raw water to the NF/RO membrane with pump called “booster pump”. That is, as the salt concentration of raw water supplied to the NF/RO membrane is higher, the osmotic pressure becomes higher. Therefore, it becomes necessary to apply higher pressure with the booster pump, and the energy for allowing the booster pump to operate becomes necessary.
For the purpose of solving these problems, the membrane treatment system being the integration of the high-level treatment of sewage and seawater desalination as disclosed in Non-Patent Documents 1 and 2 is developed, and a verification test by a pilot test is about to start. According to the present technology, after sewage is treated by the MBR, fresh water is produced using the RO membrane, and the concentrate resulted from the treatment with the RO membrane is mixed with seawater. Therefore, it becomes possible to produce fresh water more efficiently than in the conventional manner, and to reduce the salt concentration in seawater, whereby the specification of the booster pump for carrying out the RO membrane treatment in seawater desalination can more be simplified than in the conventional manner. Thus, a further energy-saving system is implemented.
However, in the flow diagram of the system disclosed in Non-Patent Documents 1 and 2, the liquid delivery line from the sewage treatment line side to the seawater desalination treatment line side is solely the line that delivers the concentrate from the RO membrane treatment. Such a system involves the following problem. In a case where any trouble happens to occur in the RO membrane used in the system that produces fresh water from sewage, and the system becomes incapable of carrying out treatment, or where the RO membrane stops its operation due to regular inspection or agent cleaning, the liquid delivery from the system that produces fresh water from sewage to the system that produces fresh water from seawater ceases, because of which the advantage of the system disclosed in Non-Patent Documents 1 and 2 is lost. Further, as to sewage or industrial waste water, the treatment-target flow rate fluctuates on an hourly or daily basis. With the system disclosed in Non-Patent Documents 1 and 2, in a case where treated water of sewage or industrial waste water is obtained in an amount more than suppliable to the RO membrane on the sewage treatment side, the clean treated water that can be supplied to the RO membrane should be subjected to discharging or disposal, which is not efficient.
Further, on the seawater desalination treatment line side of the system disclosed in Non-Patent Documents 1 and 2, since seawater is directly supplied to the RO membrane without being subjected to pre-treatment, there is a problem that the organic substances and particulates in seawater are caught by the RO membrane, and thus the RO membrane tends to be clogged and cannot be used for a long term.
Non-Patent Document 1: “Kobelco Eco-Solutions Co., Ltd. and Four Others Conduct Demonstration Experiment of Model Project Launched by Ministry of Economy, Trade and Industry in Shunan-shi,” [online], Mar. 5, 2009, Nihon Suido Shinbun, [searched for on Jul. 2, 2009], via the Internet <http://www.suido-gesuido.co.jp/blog/suido/2009/03/post—2780.html>
Non-Patent Document 2: “Adoption of ‘Discover Technology Seeds Aiming at Low-Carbon Society/Social System Verification Model Project’,” [online], Mar. 2, 2009, press release from Toray Industries, Inc. [searched for on Jul. 2, 2009], via the Internet <http://www.toray.co.jp/news/water/nr090302.html>
The present invention provides a water producing system using composite water treatment technologies, in which a second semipermeable membrane treatment plant used for treating treatment target water B can operate even in a case where any trouble occurs in a first semipermeable membrane treatment plant used for treating treatment target water A and hence treatment cannot be carried out thereby.
In order to solve the problem stated above, the present invention is structured as follows according to exemplary embodiments.
(1) A water producing system that produces fresh water by treating treatment target water A at a first semipermeable membrane treatment plant, that mixes concentrate resulted by the treatment carried out at the first semipermeable membrane treatment plant with treatment target water B, and that treats the mixed water at a second semipermeable membrane treatment plant to produce fresh water, wherein a bypass line that allows the treatment target water A to be mixed with the treatment target water B or the concentrate while bypassing the first semipermeable membrane treatment plant is provided.
(2) The water producing system according to (1), including
bypass line flow rate adjusting means for adjusting flow rate of the treatment target water A to be delivered to the bypass line.
(3) The water producing system according to (2), including
a treatment target water A storage reservoir that stores the treatment target water A, wherein the bypass line flow rate adjusting means is bypass line flow rate adjusting means that adjusts the flow rate of the treatment target water A to be delivered to the bypass line depending on water level of the treatment target water A stored in the treatment target water A storage reservoir.
(4) The water producing system according to one of (2) and (3), including first treatment target water flow rate measuring means for measuring the flow rate of the treatment target water A to be delivered to the first semipermeable membrane treatment plant, wherein the bypass line flow rate adjusting means is bypass line flow rate adjusting means for adjusting the flow rate of the treatment target water A to be delivered to the bypass line depending on flow rate value of the treatment target water A measured by the first treatment target water flow rate measuring means.
(5) The water producing system according to one of (2) to (4), including second treatment target water flow rate measuring means for measuring supply flow rate of the treatment target water A, wherein the bypass line flow rate adjusting means is bypass line flow rate adjusting means for adjusting the flow rate of the treatment target water A to be delivered to the bypass line depending on the flow rate value of the treatment target water A measured by the second treatment target water flow rate measuring means.
(6) The water producing system according to one of (2) to (5), including concentrate flow rate measuring means for measuring flow rate of the concentrate, wherein the bypass line flow rate adjusting means is bypass line flow rate adjusting means for adjusting the flow rate of the treatment target water A to be delivered to the bypass line depending on the flow rate value of the concentrate measured by the concentrate flow rate measuring means.
(7) The water producing system according to one of (1) to (6), including concentrate discharging means for discharging at least part of the concentrate to outside of the system, wherein at least part of the concentrate is discharged by the concentrate discharging means when the treatment target water A is delivered from the bypass line.
(8) The water producing system according to one of (1) to (7), including a concentrate storage reservoir that stores the concentrate, wherein the bypass line communicates with the concentrate storage reservoir.
(9) The water producing system according to (8), including: concentrate discharging means for discharging at least part of the concentrate to outside of the system; and concentrate discharge control means for discharging the concentrate to the outside the system by the concentrate discharging means when a water level of the concentrate storage reservoir is equal to or greater than a prescribed value.
(10) The water producing system according to (9), including: bypass line flow rate measuring means for measuring flow rate of the treatment target water A being delivered through the bypass line, or mixed water flow rate measuring means for measuring flow rate of mixed water of the treatment target water A being delivered through the bypass line and the concentrate; treatment target water B delivery means for delivering the treatment target water B; and treatment target water B flow rate adjusting means for adjusting flow rate of the treatment target water B to be delivered by the treatment target water B delivery means, based on flow rate value measured by the bypass line flow rate measuring means or the mixed water flow rate measuring means.
(11) The water producing system according to one of (1) to (10), wherein the treatment target water A is treated at a first pre-treatment plant, and thereafter treated at the first semipermeable membrane treatment plant, to produce freshwater.
(12) The water producing system according to one of (1) to (11), wherein the treatment target water B is treated at a second pre-treatment plant, and thereafter treated at a second semipermeable membrane treatment plant, to produce fresh water.
According to the present invention, in a water producing system using the composite water treatment technology, even in a case where a trouble occurs in a first semipermeable membrane used for treating treatment target water A and hence treatment cannot be carried out thereby, a second semipermeable membrane treatment plant used for treating treatment target water B is allowed to operate. Thus, a system that continuously operates stably can be structured.
In the following, with reference to the drawings, a description will be given of desirable embodiments of the present invention. It is to be noted that, the scope of the present invention is not limited thereto.
However, with the treatment system in
Accordingly, as a result of elaborate study made by the present inventors for solving the problems, as shown in
Here, for example, in a case where any trouble occurs at the first semipermeable membrane treatment plant 2 or when the first semipermeable membrane treatment plant 2 requires agent cleaning, and hence the first semipermeable membrane treatment plant 2 totally stops, the feed water valve 4, the concentrate valve 5, and the product water valve 6 connected to the first semipermeable membrane treatment plant 2 are all closed, while the bypass line valve 8 is opened, so as to allow the treatment target water A to flow into the bypass line pipe 7 to merge with the treatment target water B treatment line. The treatment target water B merged with the treatment target water A contributes toward a reduction in the osmotic pressure of the treatment target water B, and the product water can be obtained from the second semipermeable membrane treatment plant. Further, for example in a case where the first semipermeable membrane treatment plant 2 is structured with a plurality of system lines, and part of the system lines is stopped, the total supply amount of the treatment target water A to the first semipermeable membrane treatment plant 2 and the flow rate of the concentrate become smaller than those in the normal mode. In such a case, by supplying the whole or part of the treatment target water A not supplied to the first semipermeable membrane treatment plant 2 via the bypass line so as to merge with the treatment target water B, it becomes possible to realize a reduction in the osmotic pressure of the treatment target water B which is equivalent to or more than that in the normal mode, and the product water can be obtained from the second semipermeable membrane treatment plant. Further, in a case where the flow rate of the treatment target water A fluctuates, and the flow rate of the treatment target water A that can be supplied to the first semipermeable membrane treatment plant 2 exceeds the treatable flow rate at the first semipermeable membrane treatment plant 2, the excessive treatment target water A is supplied via the bypass line so as to serve as diluting water for the treatment target water B.
Here, it is preferable that bypass line flow rate adjusting means for adjusting the flow rate of at least part of the treatment target water A delivered to the bypass line is provided. The bypass line flow rate adjusting means is not limited to those that have a function of controlling the flow rate of the treatment target water A delivered through the bypass line, but also includes those that have a function of controlling start and stop of delivery of the treatment target water A through the bypass line. Specifically, a valve, a pump, an overflow pipe and the like may be included.
Further, it is preferable that a treatment target water A storage reservoir that stores the treatment target water A is provided, and the bypass line flow rate adjusting means is bypass line flow rate adjusting means that adjusts the flow rate of the treatment target water A delivered through the bypass line, depending on the water level of the treatment target water A stored in the treatment target water A storage reservoir. The treatment target water A storage reservoir is not particularly limited so long as it has a function of storing the treatment target water A. However, in a case where the treatment target water A undergoes pre-treatment as will be described later, it is preferable that it stores the pre-treated treatment target water A. Further, as the means for adjusting the flow rate of the treatment target water A delivered through the bypass line depending on the water level of the treatment target water A stored in the treatment target water A storage reservoir, there are means shown in
The means shown in
Further, as shown in
Further, it is also preferable that, as shown in
Further, as shown in
Further, it is also preferable that concentrate discharging means 18 for discharging at least part of the concentrate is provided, and when the treatment target water A is delivered from the bypass line 7, at least part of the concentrate is discharged by the concentrate discharging means 18 to the outside of the system. Generally, raw water used as the treatment target water A contains substances, e.g., a scale factor substance, an organic substance and the like, that have an effect of inhibiting the function of the semipermeable membrane treatment plant. Since these function inhibiting substances normally do not transmit through the semipermeable membrane treatment plant, the concentrate is higher in concentration than the treatment target water A. That is, as the raw water supplied to the second semipermeable membrane treatment plant 3, the treatment target water A is more suitable than the concentrate. Hence, in a case where the sum of the flow rate of the treatment target water A supplied from the bypass line 7 and the flow rate of the concentrate is obtained more than the needed amount as the diluting water for the treatment target water B, it becomes possible to suppress the impairment of the function of the second semipermeable membrane treatment plant and to extend the agent cleaning interval and the life of the membrane by discharging at least part of the concentrate by the concentrate discharging means 18 to thereby preferentially use the treatment target water A particularly when the treatment target water A is delivered from the bypass line 7.
Further, as shown in
Here, it is preferable that an overflow pipe to the concentrate storage reservoir 20 is provided, to achieve a structure capable of discharging the concentrate and the treatment target water A to the outside of the system when they are excessively great in amount. What is further preferable is provision of the concentrate discharging means 18 for discharging at least part of the concentrate to the outside of the system and concentrate discharge control means for discharging the concentrate through the concentrate discharging means 18 to the outside of the system when the water level of the concentrate storage reservoir 20 is equal to or greater than a prescribed value. Thus, the treatment target water A can preferentially be used than the concentrate, which further contributes toward the stable operation of the second semipermeable membrane treatment plant. Specific control method may be, for example as shown in
Further, as shown in
Here, the bypass line flow rate measuring means and the mixed water measuring means are not particularly limited, and anything that can measure the flow rate of the liquid, such as a flowmeter, will suffice. The treatment target water B delivery means may be anything so long as it can deliver the treatment target water B. Generally, a liquid delivery pump is applicable, though liquid delivery means using the head difference can also be employed. Further, though the shape or scheme of the treatment target water B flow rate adjusting means is not particularly limited so long as the function that can adjust the flow rate of the treatment target water B is provided, there is a method including, as shown in
Here, a description will be given of the first semipermeable membrane treatment plant 2 and the second semipermeable membrane treatment plant 3 that treat the treatment target water A or the treatment target water B. A semipermeable membrane is a semipermeable membrane that allows part of the components contained in the treatment target liquid, e.g., solvent to permeate through, and that does not allow other components to permeate through. In connection with the water treatment technology, examples of the semipermeable membrane may be an NF membrane, an RO membrane and the like. The NF membrane or the RO membrane is required to possess the performance of being capable of reducing the concentration of the solute contained in the treatment target water to the level at which it can be used as reclaimed water. Specifically, it is required to possess the performance of blocking various ions such as salt, mineral components and the like, e.g., divalent ions such as calcium ions, magnesium ions, and sulfate ions, the monovalent ions such as sodium ions, potassium ions, and chlorine ions, and dissoluble organic substances such as humic acid (molecular weight Mw≦100,000), fulvic acid (molecular weight Mw=100 to 1,000), alcohol, ether, and sugars. The NF membrane is defined as a filtration membrane whose operation pressure is equal to or smaller than 1.5 MPa, and whose molecular weight cutoff ranges from 200 to 1,000, and sodium chloride blocking rate is equal to or smaller than 90%. A membrane whose molecular weight cutoff is smaller than that and which possesses high blocking performance is referred to as the RO membrane. Further, of the RO membranes, one close to the NF membrane is referred also to as the loose RO membrane.
The NF membrane and the RO membrane can take forms of a hollow fiber membrane and a flat sheet membrane, to both of which the present invention can be applied. Further, in order to achieve easier handling, a fluid separation device (element) can be used, in which the hollow fiber membrane or the flat sheet membrane is stored in a casing. Preferably, the fluid separation device has the following structure in a case where the flat sheet membrane is used as the NF membrane or the RO membrane: a membrane unit, including the permeate flow channel member made up of the NF membrane or the RO membrane and tricot and a feed water flow channel member such as a plastic net, is wrapped around a cylindrical center pipe to which a multitude of pores are bored, which is then entirely stored in a cylindrical casing. It is also preferable to connect a plurality of fluid separation devices in series or in parallel so as to form a separation membrane module. In this fluid separation device, the feed water is supplied from one end into the unit, and before it reaches the other end, the permeate permeating through the NF membrane or the RO membrane flows into the center pipe, and taken out of the center pipe at the other end. On the other hand, the feed water that did not permeate through the NF membrane or the RO membrane is taken out as the concentrate at the other end.
As the membrane material for the NF membrane or the RO membrane, polymer materials such as cellulose acetate, cellulose-base polymer, polyamide, and vinyl polymer can be used. Representative NF/RO membranes may be a cellulose acetate-base or polyamide-base asymmetric membrane, and a composite membrane having a polyamide-base or polyurea-base active layer.
Meanwhile, in the present invention, since the treatment target water A and the treatment target water B are directly supplied to the first semipermeable membrane treatment plant 2 and the second semipermeable membrane treatment plant 3 in
Accordingly, in the present invention, as shown in
Here, a detailed description will be given of
Further, in the present invention, it is possible to provide the pre-treatment plants also on the bypass line and/or the concentrate line for discharging from first semipermeable membrane treatment plant 2 as necessary.
Here, a description will be given of the first pre-treatment plant 1, the second pre-treatment plant 9, the third pre-treatment plant 10, and the fourth pre-treatment plant 11. Each of the pre-treatment plants is not particularly limited, and an activated sludge treatment plant, a two-step treatment plant of the activated sludge treatment and the MF/UF membrane or the sand filtration, an MBR plant, an MF/UF membrane filtration treatment plant, a sand filtration treatment plant or the like can be used. Further, in order to allow the pre-treatment plants to operate efficiently, a flocculating agent, a pH adjusting agent, and an oxidizing agent such as sodium hypochlorite may be added. Further, in a case where a membrane is used in each pre-treatment plant, which membrane to use is not particularly limited, and a flat sheet membrane, a hollow fiber membrane, a tubular membrane, and a membrane of any other shape can be used as appropriate. Though the material of the membrane is not particularly limited, it is preferable that at least one selected from the group consisting of polyacrylonitrile, polyphenylene sulfone, polyphenylene sulfide sulfone, polyvinylidene fluoride, polypropylene, polyethylene, polysulfone, polyvinyl alcohol, cellulose acetate, an inorganic material such as ceramics is included.
The present invention relates to a water producing system using a composite water treatment technology, which can be used as a system in which fresh water is obtained through the fresh water conversion technology from raw water, which is treatment target water A and treatment target water B.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2009-169818 | Jul 2009 | JP | national |
This application is the U.S. National Phase application of PCT International Application No. PCT/JP2010/058523, filed May 20, 2010, and claims priority to Japanese Patent Application No. 2009-169818, filed Jul. 21, 2009, the disclosures of which PCT and priority applications are incorporated herein by reference in their entirety for all purposes.
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/JP2010/058523 | 5/20/2010 | WO | 00 | 8/14/2012 |
