Claims
- 1. A composition for producing light comprising in an aqueous solution;
- (a) a dioxetane of the formula: ##STR47## having increased storage stability wherein R.sub.3 and R.sub.4 are each selected from the group consisting of acyclic, cyclic and polycyclic organic groups which can optionally be substituted with heteroatoms and which can optionally be joined together to form a cyclic or polycyclic ring group spiro-fused to the dioxetane ring, wherein R.sub.2 is an aryl ring group selected from the group consisting of phenyl and naphthyl groups which can include additional substituents, wherein Z is selected from the group consisting of a fluorine atom and an alkyl group of 1-4 carbons, M is selected from hydrogen, an alkali metal ion or a quaternary ammonium or phosphonium ion and wherein X is a protecting group which can be removed by an activating agent to produce the light; and
- (b) a non-polymeric cationic enhancer substance which increases the quantity of light produced by reacting the dioxetane with the activating agent compared to the amount which is produced in the absence of the enhancer.
- 2. The composition of claim 1 wherein the enhancer substance is a dicationic surfactant of the formula: ##STR48## wherein each of A is independently selected from the group consisting of P and N atoms, wherein Link is an organic linking group containing at least two carbon atoms selected from the group consisting of substituted and unsubstituted aryl, alkyl, alkenyl and alkynyl groups and wherein Link can optionally contain heteroatoms and wherein R is selected from lower alkyl or aralkyl containing 1 to 20 carbon atoms and wherein Y is an anion.
- 3. The composition of claim 1 wherein the enhancer substance is a dicationic surfactant having the formula: ##STR49## and wherein link is phenylene.
- 4. The composition of any one of claims 1, 2 or 3 wherein the dioxetane has the formula: ##STR50## wherein R.sub.5 is selected from the group consisting of cyclic and polycyclic alkyl groups which are spiro-fused to the dioxetane ring and which contain 6 to 30 carbon atoms and which can optionally include additional substituents.
- 5. The composition of claim 4 wherein R.sub.5 is selected from the group consisting of an adamantyl group and a substituted adamantyl group.
- 6. The composition of claim 4 wherein the dioxetane has the formula: ##STR51##
- 7. The composition of claim 4 wherein the dioxetane has the formula: ##STR52##
CROSS REFERENCE TO RELATED APPLICATION
This application is a divisional of Ser. No. 8/748,107 filed Nov. 8, 1996 now pending, which is a continuation-in-part of Ser. No. 8/509,305 filed Jul. 31, 1995 now pending.
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Number |
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Kind |
5451347 |
Akhavan-Tafti |
Sep 1995 |
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5484556 |
Akhavan-Tafti |
Jan 1996 |
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5631167 |
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Divisions (1)
|
Number |
Date |
Country |
Parent |
748107 |
Nov 1996 |
|
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
509305 |
Jul 1995 |
|