WATER TRANSFER EFFICIENCY IMPROVEMENT IN A MEMBRANE HUMIDIFIER BY REDUCING DRY AIR INLET TEMPERATURE

Abstract
A fuel cell system that employs a heat exchanger and a charge air cooler for reducing the temperature of the cathode inlet air to a fuel cell stack during certain system operating conditions so that the cathode inlet air is able to absorb more moisture in a water vapor transfer unit. The system can include a valve that selectively by-passes the heat exchanger if the cathode inlet air does not need to be cooled to meet the inlet humidity requirements. Alternately, the charge air cooler can be cooled by an ambient airflow.
Description

BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a schematic block diagram of a fuel cell system employing a cathode charge air cooler and a heat exchanger for cooling the cathode inlet air to a fuel cell stack so that it can absorb more humidity, according to an embodiment of the present invention;



FIG. 2 is a schematic block diagram of a fuel cell system employing a charge air cooler for cooling the cathode inlet air to a fuel cell stack so that it can absorb more humidity, according to another embodiment of the present invention; and



FIG. 3 is a schematic block diagram of a fuel cell system employing two charge air coolers for cooling the cathode inlet air to a fuel cell stack so that it can absorb more humidity, according to another embodiment of the present invention.





DETAILED DESCRIPTION OF THE EMBODIMENTS

The following discussion of the embodiments of the invention directed to a fuel cell system that employs a charge air cooler for reducing the temperature of the cathode inlet air sent to a fuel cell stack during certain system operating conditions so that the cathode inlet air is able to absorb more humidity in a water vapor transfer unit is merely exemplary in nature, and is in no way intended to limit the invention or its applications or uses.



FIG. 1 is a schematic block diagram of a fuel cell system 10 including a fuel cell stack 12, according to an embodiment of the present invention. A compressor 14 provides a compressed cathode inlet air stream on a cathode input line 16 depending on the load requirement of the fuel cell stack 12. The cathode inlet air from the compressor 14 is sent to a gas/liquid charge air cooler (CAC) 18 that cools the cathode inlet air that has been heated as a result of the compression of the air in the compressor 14. Those skilled in the art will readily recognize various types of suitable charge air coolers that can perform the function described herein. The cooled cathode inlet air from the CAC 18 is then sent to a WVT unit 20 that humidifies the cathode inlet air to a desired humidity level. A cathode exhaust gas on cathode exhaust gas line 22 provides the water and water vapor in the WVT unit 20 to provide the humidification. WVT units that employ suitable membranes for humidifying the cathode inlet air in this manner are well known to those skilled in the art, and various designs are suitable for the purposes described herein. The humidified and temperature reduced cathode inlet air is then sent to the fuel cell stack 12 on the cathode input line. A temperature sensor 26 measures the temperature of the cathode inlet air from the CAC 18 and a relative humidity (RH) sensor 28 measures the relative humidity of the cathode inlet air being applied to the fuel cell stack 12. Alternately, the RH sensor 28 can be replaced with a sensor that measures the high frequency resistance of the stack 12, as is well understood by those skilled in the art.


Fuel cell systems typically include a stack cooling sub-system that drives a cooling fluid through cooling fluid flow channels in the fuel cell stack 12. The stack cooling fluid flows through a coolant loop 32 outside of the stack 12. The cooling fluid is pumped through the coolant loop 32 and the fuel cell stack 12 by a pump 34. The heated cooling fluid from the fuel cell stack 12 is cooled by a radiator 36 before it is returned to the stack 12 to gather waste heat. The radiator 36 would typically be part of a radiator sub-system that included a cooling fan (not shown). A line 38 directs some of the cooling fluid to the CAC 18, as will be discussed in more detail below.


As is well understood in the art, operation of the stack 12 produces significant water that is transferred to the cathode exhaust gas. If the stack 12 is operated below 100% humidity and the relative humidity set-point of the cathode inlet gas is not achieved, the present invention enables an increase of stack relative humidity without increasing the size of the WVT unit 20. This can occur during certain operating conditions of the system 10, such as at high loads.


According to this embodiment of the invention, the system 10 includes a gas/liquid heat exchanger 40 that receives the cooling fluid on the line 38 before it is sent to the CAC 18. The heat exchanger 40 reduces the temperature of the cooling fluid in the line 38 after the heat exchanger 40 so that the CAC 18 reduces the temperature of the cathode inlet air so that it is able to absorb more water vapor in the WVT unit 20. Therefore, even though the relative humidity of the cathode exhaust gas may be reduced, the ability of the cathode inlet air to absorb water is increased, so that the relative humidity requirements of the cathode inlet air can be maintained.


A three-way valve 42 is provided in the line 38 that is controlled to either send the cooling fluid flowing through the line 38 and the heat exchanger 40, as discussed above, or to by-pass the heat exchanger 40 on by-pass line 44 during those times where the relative humidity of the cathode inlet air is at the desired set-point, where the cathode inlet air does not need to be further cooled by the CAC 18. Particularly, if the cathode outlet gas is 100% or above, then the cathode inlet air typically only needs to be cooled to the temperature of the cooling fluid flowing through the stack 12 to meet the relative humidity requirements of the cathode inlet air. Control algorithms can be employed that use the temperature of the cathode inlet air from the CAC 18, as provided by the temperature sensor 26, and the relative humidity of the cathode inlet air, as provided by the relative humidity sensor 28, to control the valve 42.


The heat exchanger 40 can be any heat exchanger suitable for the purposes described herein. In one embodiment, the heat exchanger uses air to provide the cooling through the movement of the vehicle that receives ambient air on line 46. In one specific example, the heat exchanger 40 is the already existing wheel-house heat exchanger, known to those skilled in the art, positioned proximate to the wheels of a vehicle. In that design, the cooling fluid flow for the stack 12 would be re-plumbed in the vehicle so that it traveled through the heat exchanger 40. However, other heat exchangers can be employed in the system 10 consistent with the discussion herein, including those heat exchangers that may include a cooling fan. The amount of heat that is rejected by the heat exchanger 40 depends on the amount of airflow on line 46, i.e., the speed of the vehicle, and the ambient air temperature.


In an alternate embodiment, the valve 42 can be one or more valves that selectively allow some of the cooling fluid to by-pass the heat exchanger 40 and some of the cooling fluid to flow through the heat exchanger 40 to provide increased cathode inlet air temperature control. A suitable example for providing this type of design is to use two proportional or digital valves. Alternately, a valve can be provided in the line 38 or a valve can be provided in the by-pass line 44, and the pressure drop of the other line can be adapted to provide the flow distribution through the heat exchanger 40 or around the heat exchanger 40. Also, the heat exchanger 40 can be used to heat the cathode inlet air for reasons that will be discussed below



FIG. 2 is a schematic block diagram of a fuel cell system 50, similar to the fuel cell system 10 where like elements are identified by the same reference numeral, according to another embodiment of the present invention. In this embodiment, the cooling fluid that cools the stack 12 is not used to cool the CAC 18, and therefore the valve 42 and the heat exchanger 40 are eliminated. In this embodiment, the charge air cooler is an air/air charge air cooler 52 that receives a cooling airflow on line 54. The CAC 52 includes one or more flaps or dampers 56 that can be selectively opened and closed to allow the cooling air on the line 54 to enter the CAC 52 and reduce the temperature of the cathode inlet air. During those times that the relative humidity of the cathode inlet air drops below the desired RH set-point more air will be forced into the CAC 52 to provide the desired cooling to reduce the temperature of the cathode inlet air and its ability to absorb water vapor, as discussed above. Therefore, the line 54 would be plumbed so that the ambient inlet air to the CAC 52 would increase as the vehicle speed increased. Control algorithms can be employed that use the temperature of the cathode inlet air from the CAC 52, as provided by the temperature sensor 26, and the relative humidity of the cathode inlet air, as provided by the relative humidity sensor 28, to control the dampers 56.


There may be certain operating situations where the temperature of the cathode inlet air is too low, such as during start-ups at ambient temperatures below 0° C., where it may absorb too much water vapor and possibly block the cathode flow channels in the fuel cell stack 12. FIG. 3 is a schematic block diagram of a fuel cell system 60 similar to the fuel cell system 50, where like elements are identified by the same reference numeral, according to another embodiment of the present invention. In this design, a second charge air cooler 62 is provided that receives the cathode inlet air from the compressor 14. The CAC 62 is a liquid/air charge air cooler, and receives the stack cooling fluid on line 64. In this embodiment, the CAC 62 operates as a heater in that it uses the heated cooling fluid on the line 64 to increase the temperature of the cathode inlet air from the compressor 14. Once the stack 12 nears its operating temperature, a valve 66 can be closed to prevent the cooling fluid from traveling through the CAC 62. After this time, the temperature of the cathode inlet air is controlled by the CAC 52, as discussed above.


It may be desirable in certain designs to eliminate the valve 66 so that the CAC 62 is continuously maintaining the temperature of the inlet air at the temperature of the cooling fluid, and use the CAC 52 to decrease the temperature from the temperature of the cooling fluid during those times that the relative humidity of the cathode inlet air is below the RH set-point, as discussed above. Further, it may be desirable to make the valve 66 some type of proportional valve that can be selectively controlled to control the amount of the cooling fluid that travels through the CAC 62. Also, the combination of the CAC 62 and the valve 66 can be provided in the system 10 for the same purposes described herein.


The foregoing discussion discloses and describes merely exemplary embodiments of the present invention. One skilled in the art will readily recognize from such discussion and from the accompanying drawings and claims that various changes, modifications and variations can be made therein without departing from the spirit and scope of the invention as defined in the following claims.

Claims
  • 1. A fuel cell system comprising: a fuel cell stack including a cathode inlet line and a cathode outlet line;a compressor for providing cathode inlet air to the cathode inlet line;a first charge air cooler for reducing the temperature of the cathode inlet air from the compressor;a water vapor transfer unit for humidifying the cathode inlet air traveling through the cathode input line, said water vapor transfer unit receiving a cathode exhaust gas from the cathode exhaust gas line for providing the humidity for the cathode inlet air; anda heat exchanger for reducing the temperature of a stack cooling fluid flow sent to the first charge air cooler to cool the cathode inlet air, said heat exchanger receiving ambient air for cooling the cooling fluid.
  • 2. The system according to claim 1 further comprising a valve assembly for by-passing the cooling fluid on a by-pass line around the heat exchanger, said valve assembly being controlled so that the heat exchanger is by-passed if the relative humidity of the cathode inlet air is at or above a predetermined RH set-point and sending the cooling fluid to the heat exchanger if the relative humidity of the cathode inlet air is below the RH set-point.
  • 3. The system according to claim 2 further comprising a temperature sensor for measuring the temperature of the cathode inlet air and a device for measuring the relative humidity of the cathode inlet air, wherein the valve assembly is controlled using the temperature and relative humidity measurements to maintain the relative humidity of the cathode inlet air at or above the predetermined relative humidity.
  • 4. The system according to claim 2 wherein the valve assembly is selectively controlled so that a portion of the cooling fluid by-passes the heat exchanger and a portion of the cooling fluid flows through the heat exchanger so as to selectively control the temperature of the cooling fluid provided to the first charge air cooler.
  • 5. The system according to claim 2 wherein the valve assembly is a single valve positioned in the by-pass line or in a cooling fluid line coupled to the heat exchanger where the valve controls the amount of cooling fluid by-passing or traveling through the heat exchanger.
  • 6. The system according to claim 1 wherein the heat exchanger is a wheel house heat exchanger.
  • 7. The system according to claim 1 wherein the cooling fluid is a cooling fluid that is used to cool the fuel cell stack.
  • 8. The system according to claim 1 wherein the fuel cell system is on a vehicle.
  • 9. A fuel cell system comprising: a fuel cell stack including a cathode inlet line and a cathode outlet line;a compressor for providing cathode inlet air to the cathode inlet line;a first charge air cooler for reducing the temperature of the cathode inlet air from the compressor, said first charged air cooler being a gas/gas charge air cooler that uses an inlet air flow to cool the cathode inlet air; anda water vapor transfer unit for humidifying the cathode inlet air traveling through the cathode input line, said water vapor transfer unit receiving a cathode exhaust gas from the cathode exhaust gas line for providing the humidity for the cathode inlet air.
  • 10. The system according to claim 9 wherein the first charge air cooler includes at least one damper that is selectively opened and closed to increase or decrease the amount of air cooling provided by the first charge air cooler.
  • 11. The system according to claim 10 further comprising a temperature sensor for measuring the temperature of the cathode inlet air and a device for measuring the relative humidity of the cathode inlet air, wherein the damper is controlled using the temperature and relative humidity measurements to maintain the relative humidity of the cathode inlet air at or above a predetermined relative humidity.
  • 12. The system according to claim 9 further comprising a second charge air cooler for increasing the temperature of the cathode inlet air from the compressor, said second charge air cooler being used to heat the cathode inlet air from the compressor during cold start-up of the system.
  • 13. The system according to claim 12 wherein the second charge air cooler is a gas/liquid charge air cooler where the liquid used to increase the temperature of the cathode inlet air is a cooling fluid that is used to cool the fuel cell stack.
  • 14. The system according to claim 13 further comprising a valve that is selectively opened and closed to provide the cooling fluid to the second charge air cooler, prevent a portion of the cooling fluid to flow to the second charge air cooler or prevent the cooling fluid from flowing to the second charge air cooler.
  • 15. The system according to claim 9 wherein the fuel cell system is on a vehicle.
  • 16. A fuel cell system comprising: a fuel cell stack including a cathode inlet line and a cathode outlet line;a compressor for providing the cathode inlet air to the cathode inlet line; anda charge air cooler for increasing the temperature of the cathode inlet air from the compressor during cold system start-ups.
  • 17. The system according to claim 16 wherein the charge air cooler is a gas/liquid charge air cooler where the liquid used to increase the temperature of the cathode inlet air is a cooling fluid that is used to cool the fuel cell stack.
  • 18. The system according to claim 17 further comprising a valve that is selectively opened and closed to provide the cooling fluid to the charge air cooler, prevent a portion of the cooling fluid to flow to the charge air cooler or prevent the cooling fluid from flowing to the charge air cooler.
  • 19. The system according to claim 16 wherein the fuel cell system is on a vehicle.