The present invention directed to a web structure, and more particularly to a web structure that could be utilized to form structural elements.
Architects, civil and structural engineers conventionally utilize various web structures for supporting, for example, trusses, floors, columns, etc. Typically, web structures form various lattices or framework that support underlying or overlying supports. In this regard, structural engineers are quite familiar with a “Fink truss” (FIG. 2), the geometry of which encodes an approximation of a “Sierpinski triangle” (also known as a 2-web) (FIG. 1).
It has recently been observed that the geometry of the hardest substance known to man, namely diamonds, and the modern roof truss encode and represent the approximations to certain fractals. The Fink truss (
A structure resembling the Sierpinski triangle has been useful to structural engineers because each member or edge 110, 112 and 114 at level-0 (
Turning to diamonds, I recently observed that the diamond lattice encodes the “Sierpinski Cheese,” which is also called a 3-web (FIG. 7). Relative to the 2-web, we can think of the diamond lattice as encoding four “Fink trusses” (level-1 2-webs), one in each face of a tetrahedron—in
The macro-scale observation that bracing in the middle greatly increases strength may also be observed on the micro scale. In the case of diamonds, the cabon-cabon bonding distance (distance between two carbon atoms that share a covalent electron) is 154.1 pm (one pm=10−12 meters). In contrast, silicon exhibits the same diamond lattice structure as diamond, but the silicon-silicon bonding distance is 235.3 pm. Thus, again strength in the case of compressive and tensile forces is directly related to distance (compression and tension at these scales are virtual, i.e., the edges in the diamond lattice (
All of these fractals, the 2-web (limit of Fink truss concept), the 3-web (limit of the diamond lattice concept) provide for adjusting the distances of the compression and tension members by middle bracing. It is a mathematical fact (since we are dealing with line segments) that we can middle brace and never worry about the braces at one level obstructing the braces at the next level. In practice, however, the scales and sizes of the materials used for edges may affect the limit of these fractal designs.
In summary, the Fink truss, which is a level-1 Sierpinski triangle, has been utilized for many years in constructing various support structures. To date, diamond which has the geometry of a level-1 Sierpinski cheese as its basic building structure is known to be the hardest structure. The inventor of the present invention has discovered a geometrical structure that represents the next step.
The principal object of the present invention is to provide a web structure which could be utilized at both macroscopic and microscopic levels to create harder than diamond, and stronger and stable structures. On a microscopic scale, for example, a web structure made in accordance with the present invention would produce new compounds and new crystals. On a macroscopic scale, for example, a web structure made in accordance with the present invention would create super strong and stable architectural and structural support structures. For example, a web structure of the present invention can be utilized to create super strong and stable trusses, beams, floors, columns, panels, airplane wings, etc.
Another object of the present invention is to provide the scientific and solid-state physics communities with access to new fundamental web-structure designs that would indicate how to build new compounds and new crystals having utility, for example, in the solid-state electronics industry.
Yet another object of the present invention is to provide a web structure that accommodates or packs more triangular shapes into a given volume than conventional web structures. A web structure made in accordance with the present invention could be used in building bridges, large buildings, space-stations, etc. In the space-station case, for example, a basic, modular and relatively small web structure can be made on earth, in accordance with the present invention, and a large station could be easily built in space by shipping the relatively small web into space, and then joining it with other members to complete the station.
An additional object of the present invention is to provide a web structure that represents a 4-web in a 3-dimensional space.
Yet an additional object of the present invention is to provide a web structure that at level-1 packs or accommodates ten Fink trusses.
A further object of the present invention is to provide a 4-web structure which packs or accommodates more triangles in a given volume than the corresponding 3-web structure.
In summary, the main object of the present invention is to represent a 4-web in a 3-dimensional space. The invention can be utilized to generate new structural designs that relate to both macroscopic and microscopic structures. These structures would be stronger and more stable than the presently known structures, including diamond.
In accordance with the present invention, a web structure includes a generally hexahedron-shaped frame having a plurality of vertices oriented in a manner that no more than three vertices lie in a common plane. Each pair of the vertices is connected by a line or frame segment.
In accordance with the present invention, a web structure includes a generally hexahedron-shaped outer member having first, second, third, fourth, and fifth vertices. A plane includes the third, fourth, and fifth vertices and the first and second vertices are spaced away from the plane. A plurality of generally hexahedron-shaped inner members, having the same general configuration as the outer member, are disposed in the outer member.
In accordance with the present invention, a method of forming a web structure, includes providing a plurality of generally hexahedron-shaped frames, wherein each of the frames includes a plurality of vertices oriented in a manner that no more than three vertices lie in a common plane. Each pair of the vertices in a hexahedron-shaped frame is connected by a line or frame segment. A plane includes three of the five points and one line or frame segment having first and second ends, passes through the plane. The first and second ends of the one line or frame segment are generally equidistant from the plane. The frames are arranged in a side-by-side manner such that one of the three points in the plane of a frame contacts one of the three points in the plane of an adjacent frame. A plurality of the frames are further arranged in a manner that one of the first and second ends of the one line or frame segment of a frame contacts the other of the first and second ends of the one line or frame segment of an adjacent frame.
In accordance with the present invention, a method of forming a web structure, includes providing a plurality of generally hexahedron-shaped members. Each of the members includes first, second, third, fourth, and fifth vertices. A plane includes the third, fourth, and fifth vertices and the first and second vertices are spaced away from the plane. A plurality of the members are arranged in a side-by-side manner in a manner such that one of the third, fourth, and fifth vertices of a member contacts one of the third, fourth, and fifth vertices of an adjacent member. A plurality of the members are further arranged in a manner that one of the first and second vertices of a member contacts the other of the first and second vertices of an adjacent member.
The patent or application file contains at least one drawing executed in color. Copies of this patent or patent application publication with color drawings(s) will be provided by the U.S. Patent and Trademark Office upon request and payment of the necessary fee.
The above and other objects, novel features and advantages of the present invention will become apparent from the following detailed description of the invention, as illustrated in the drawings, in which:
A 2-web may be viewed as a systematic packing of triangles inside of a triangle. Approximations to 2-webs occur at levels, i.e., there is a level-0 2-web, a level-1 2-web, a level-2 2-web, a level-3 2-web, a level-4 2-web, a level-5 2-web, etc. (See FIGS. 1-6). The building and trades industry uses designs involving triangles as the fundamental construct; and, in particular, the building or design of a roof truss is packing triangles inside of triangles. Thus, in general, a 2-web is a design for packing triangles in a 2-dimensional space, i.e., in a plane.
A 3-web may likewise be viewed as a systematic packing of tetrahedra inside of a tetrahedron. And since a tetrahedron is a systematic packing of four triangles, it can be observed that a 3-web is a way to pack triangles into a 3-dimensional space. And, also like 2-webs, 3-web approximations occur at levels, namely, level-0, level-1, level-2, level-3, etc. (See FIGS. 7-10).
Moreover, let us start with the four triangles (faces) that define a level-0 3-web as illustrated in FIG. 7. If we add edges or line (frame) segments to obtain a higher level 3-web, as illustrated in
This relationship between 2-webs and 3-webs carries over to a similar relationship between 3-webs and 4-webs. For example, in
As an example of how the 3-web encodes the diamond-lattice structure,
In short, 3-webs systematically pack tetrahedra in a 3-dimensional space, and 4-webs (subject of the present invention) systematically pack hexahedra.
To understand why a 4-web structure, made in accordance with the present invention, would allow for configurations that yield super strong structures, suppose we view a level-1 2-web as a simple Fink truss. Then, a level-1 3-web (the basic building block encoded in diamond) packs four Fink trusses into the volume of a tetrahedron. However, the 4-web structure of the invention packs ten Fink trusses into the volume of two tetrahedra. Packing ten such optimum (strength/weight)-structures using only five points in three-dimensions is an important, unique aspect of the invention. To understand how this is accomplished, we may consider the level-0 4-web (FIG. 11). It has five vertices 16, 18, 20, 22, and 24, and (5-choose-2)=10 edges or line segments. When each edge or line segment is braced in the middle according to the 4-web design, thereby obtaining the level-1 4-web (FIG. 16), we find that every three of the vertices 16, 18, 20, 22, and 24 in
The 2-web and 3-web are instances of fractals. These fractals have a generalization known as the 4-web. This 4-web was, until recently, believed to exist only in 4-dimensional space. But it is now known that it also exists in 3-dimensional space [Reference No. 3, incorporated herein in its entirety by reference].
From the theoretical view, these fractals are attractors of iterated function systems. In this case, an iterated function system is a finite set of functions, each of which is a contraction by ½ followed by a translation. For the 2-web, there are three functions that act on the plane, for the 3-web there are four functions that act on 3-space, and for the 4-web there are five functions that act on 4-space. The 4-web is the attractor of those five functions that act on 4-space. Thus, the 4-web lives naturally in 4-space. It had been long believed that it was impossible to move the 4-web into 3-space. This belief was perhaps based on the fact that the 3-web cannot be moved into 2-space. There was really no motivation to guess that the 4-web could be moved into 3-space with its fractal dimension preserved. The fact that it is possible to move the 4-web into 3-space was first documented in [Reference No. 3].
And, like the other attractors, the 4-web at any level provides for systematic middle bracing so that no brace gets in the way or obstructs the other brace. This ability to start with one standard and make it stronger and stronger by adding bracing should prove useful. Experiments (discussed below) document the first step in that direction. The Experiments also indicate the direction for the second step, namely, the next step should be optimization. We anticipate automating the process of redistributing the steel among the various members so that optimum performance can be achieved for the application that one has in mind.
The web structure of the present invention in its simplest form (level-0), is best illustrated in FIG. 11. As shown, the web structure W includes a generally hexahedron-shaped frame F including an upper generally triangular or trihedron-shaped sub-frame 10 and a lower generally triangular or trihedron-shaped sub-frame 12. The upper and lower sub-frames 10 and 12 are joined at their bases to form a common equatorial sub-frame 14.
The frame F includes upper and lower points or apices 16 and 18, respectively, and three equatorial points or apices 20, 22, and 24. The points 16, 18, 20, 22, and 24 are oriented in a three-dimensional space in a manner that no more than three points lie in a same plane. The equatorial points 20, 22, and 24 are disposed in a generally common, generally horizontal plane represented by equatorial sub-frame 14.
As illustrated in
The frame segment 32 is disposed preferably generally perpendicular to the plane of sub-frame 14 and passes generally through the geometrical center thereof. Alternatively, the frame segment 32 may be generally skew or slanted.
The frame F forms ten triangles represented by points 16, 20, and 24; 16, 20, and 22; 16, 22, and 24; 20, 22, and 24; 18, 20, and 24; 18, 22, and 24; 18, 20, and 22; 16,18, and 20; 16, 18, and 22; and 16, 18, and 24. Each of these triangles functions as a Fink truss when each frame segment thereof is braced in the middle.
Preferably, each of the frame segments 26, 28, 30, 32, 34, 36, 38, 40, 42, and 44 is a generally straight segment.
As illustrated in
As illustrated in
As illustrated in
The following illustrates various constructions and testing of computer models of fractal-based columns and beams made in accordance with the present invention.
Level-0, level-1, and level-2 wafers WF (the basic building blocks) were generated via the process of specifying nodes and edges. Nodes are points in 3-space. Each such point represents the center of a joint where two or more tubes and/or solid rods would be welded together. Edges were provided as pairs of nodes. Each edge represents either a tube or solid rod. The tubes/rods are of three distinct kinds, namely, horizontal, slant, and vertical.
The test columns were double-wafer columns. They were constructed in two stages: First, a single-wafer column (
Several level-1 double-wafer columns (also called 4-web columns) were computer modeled and tested. The software utilized was MECHANICA Version 21. Its library of beam finite elements contains dialog boxes that allow for specification of the cross-sectional dimensions of individual members (the slants, verticals, and horizontals).
The adopted standards for all columns were (1) a cross-section that would nominally fit into a 3.5-inch by 3.5-inch square; and (2) a height of 8 feet. The goal was to compare various 4-web columns to standard 8-foot sections of A36 structural steel pipe whose outside diameter (OD) was 3.5 inches. Except for Experiment 3 (below), where it was assumed that one end was fixed and one end was free, the tests were restricted to the case where both ends of each column were fixed.
The standard 3.5-inch OD pipes, as well as the 4-web columns, can fail for one of two reasons—they can bend (buckle) or the A36 steel can fail (A36 steel will support up to 36,000 lbs per square inch.) The load C at which an A36 steel pipe will fail due to steel failure is C=A*36000 where A is the cross-sectional area (inches squared) of the pipe. The load B at which a pipe will buckle was calculated via the compressive strength equations [Reference No. 1, page 2-22] and [Reference No. 2, page 28]. A study of various pipes with OD=3.5 inches was conducted.
To understand the pipes, we held the outside diameter at 3.5 inches and varied the inside diameter in steps of 0.05 inches. That is, we considered pipes whose inside diameters were 3.45, 3.40, 3.35, 3.30, 3.25, . . . , 2.85 inches. For each such pipe, we calculated the buckling load B via the compressive strength equations, except that we used phi=1, instead of phi=0.85. Then, as indicated in the previous paragraph, we calculated the load C that would cause the pipe to fail because of compression of the steel, which is independent of the buckling.
For example, for a 3.45 inch ID, we find B=9066 lbs and C=9825 lbs; and for a 3.40 inch ID, B=17,982 lbs and C=19,509 lbs. So for both of these IDs, B/C=0.92. We repeated similar calculations for each of the inside diameters mentioned above, obtaining the graph (FIG. 39).
As indicated, the buckling loads (the B's) smoothly decreased to approximately 91% of the corresponding (fail-under-compression) loads (the C's).
Moreover, the weights of these columns are their cross-sectional areas (square inches) times 96 (inches) times (weight of steel/cubic inch). So any column whose cross-sectional area is essentially uniform would be stronger than a similar-weight pipe whose fail-under-compression load was C only if it had buckling load more than 91% of C.
The best that we could do is where B=C, i.e., where B/C=1.00. In such a case the column would fail by buckling at the same time that the steel failed under compression.
Thus, under the same weight constraint, we estimate that any column could only be about 10% stronger than its pipe counterpart. The same weight as a 3.5-inch OD pipe allows for only about a 10% improvement (1.0989*0.91 is approximately 1).
The data in Table 2 (below) show, however, that both the 3- and the 6-inch wafer columns have a buckling load B that was more than twice the corresponding buckling load for a pipe of the same weight. Some members of these 4-web columns may, however, experience failure of their steel at a load L<C where C is the steel-failure load of a comparable pipe. We only tested one 4-web column for steel failure. And indeed, in that lone case, L<C.
A 4-web column is comprised of many relatively small members. The Von Mises plots (a measure of stress on the members of the 4-web column) showed that many of these small members experience relatively small stresses, while others experience quite large stresses. In short, even though we now have a 4-web column with buckling load B>C, we do not yet know how to optimally distribute the steel among the individual members so that we can maximize the (steel-failure) load L to the point where L=C.
We concluded that any future study should include an optimization, i.e., how to redistribute the steel among the members of a 4-web column so that those members that experience the most stress have the most steel.
While we did not model 4-web columns that would compare with these larger pipes, we did study these larger pipes to see if the ratio B/C might be smaller, and found that it was.
For example, fixing the outside diameter at 6 inches, we calculated B/C for inside diameter of 5.5, 5.0, 4.5, 4.0, 3.5, 3.0, and 2.5 inches. The results are shown in
These results lead to the following observation: If the buckling loads of comparable 4-web columns also double those of these larger pipes, then the comparable 4-web columns could be up to 20% (1.2048*0.83 is approximately 1) stronger than their pipe counterparts. To test the feasibility of such designs, however, it is again implicit that we would also need an optimization (of steel distribution) study for these larger 6″×6″×16′ 4-web columns.
We started with several level-1 12-inch wafer columns whose members were solid rods. The assumptions underlying the first tests where that the top end of these columns where free, in all other tests the assumption was that we had both ends fixed, allowing movement only in the vertical direction.
The 12-inch level-1 wafer columns whose buckling data appear in
Standard design theory suggests that a decrease in the height of the wafers and a change from solid rods to tubes (on the slants and verticals) would increase resistance to buckling. Such changes require a slight increase in weight (the increase is mainly due to an increase in the number of horizontals). This attempt at optimization provided dramatically positive results.
The members (mostly tubes) of the columns referenced in
The following Table 3 compares two level-1 double-wafer 8-foot columns whose members are solid rods. Note that as we go from the 6″- to the 3″-wafer columns that the increase in steel is only about 22% (7+pounds); but that the buckling load increases by a factor of more than 332%! (“VM” is Von Mises in lbs/(sq inch), which is a measure of the stress.)
Even though a study of level-2 wafer columns was not undertaken, a computer model was encoded. A level-2 single-wafer is shown in FIG. 43.
In general, columns of 3″ wafers were stronger than those of 6″ wafers, just as those of 6″ wafers were stronger than those of 12″ wafers. The cross-sections of the columns fall within a 3.5″ by 3.5″ square. The standard height was 8 feet. Our study was limited to level-1 double-wafer columns. The theory suggests that in addition to making stronger and stronger columns using ever-shorter wafers, we can also use higher and higher levels of wafers to increase the strength. We did not test the higher-level designs, although we did model a level-2 wafer.
The study of level-1 double-wafer columns demonstrates how to design columns with exceptionally high buckling loads. There was one test case, however, where a relatively low column load induced steel failure in some members. It should not be inferred from these data that the design loads for these 4-web columns exceed the corresponding pipe (LRFD) design loads. The pipe LRFD loads merely serve as a reference from which we can observe the increase in buckling loads of 4-webs relative to change in wafer height. Indeed, we did not calculate design loads for 4-web columns. Such results point to the need for determining the optimum distribution of the steel. (Steel would be added to those members receiving maximum stress, and removed from those with minimum stress.)
Upon reconsideration, we might have picked a size of pipe (our standard) that left very little room for improvement. That is, if we work under the same weight constraint, the standard only left room for about 10% improvement. Nevertheless, we demonstrated that these 4-web column designs allow for dramatically increasing buckling loads by reducing wafer height. The 12″-wafer columns had buckling loads that were less than the corresponding (same weight/profile) pipe LRFD design loads. The 6″-wafer column buckling loads exceeded pipe LRFD design loads by more that a factor of 200%; and the 3″-wafer columns exceeded their (similar weight) 6″-wafer counterparts. And since these columns have many members, an optimization might show that 4-web columns can yield the optimum for a given amount of steel. Indeed, the right redistribution of the steel might very well improve the performance beyond anything now available.
Even at our current stage of understanding, i.e., where only two estimates at optimization were made, there is one glaring positive. These high buckling numbers imply that (at the very least) applications may appear in the form of hybrid structures.
We also initiated a study of 4-web beams. A reasonable approach would parallel our study of columns, i.e., it would include the following phases: (1) design; (2) generate computer models; (3) find/define standards for comparisons; (4) make comparisons; (5) try to optimize the design by using the knowledge gained in phase (4).
In phases 1 and 2, we started with a beam built from existing models, namely, a beam built from the single-wafer columns (described in Experiment 1 above). The concept, called an “X-beam,” involved two such columns (FIG. 47). They would be joined together via certain node-to-node identifications.
Then came phase 3, looking for standards. Hindsight shows that the beam case is innately more complex than the column case. In a simple beam test case, it became clear that we needed to think carefully about how we apply loads to such a beam. The X-beam is basically a truss whose cross-section varies but nominally fits inside of a 5″ by 5″ square. These beams/trusses have relatively small members that are strong only as two-force members (compression/tension). To test such a structure, we added about 20+ lbs of steel. Then, looking for a comparable I-beam of the same weight, we estimated at a W6×20. But the 6.2″ (=depth) by 6.018″ (flange-width) rectangle that nominally contains the cross-section of a W6×20 I-beam has an area that is about 50% larger than any cross-section of our X-beam. To get a better match, we could have scaled up our X-beam, but that would have taken us back to the design phase, i.e., phase 1.
In the case of cantilever beams, we had originally planned on encoding a skewed 4-web design. Such a design differs from those described above in that the verticals are not perpendicular to the horizontals (as was the case in each of the designs discussed above). That these kinds of 4-webs exist is established in [Reference 3].
The following is the 4-web construction algorithm, as illustrated in block diagram shown in FIG. 48.
n←a user supplied nonnegative integer
M←a user supplied 3×3 nonsingular matrix with real entries
C←a user supplied 3×1 matrix with real entries
H←the matrix H defined in the paper The generalization of Sierpinski's Triangle that lives in 4-space
While this invention has been described as having preferred sequences, ranges, steps, materials, or designs, it is understood that it includes further modifications, variations, uses and/or adaptations thereof following in general the principle of the invention, and including such departures from the present disclosure as those come within the known or customary practice in the art to which the invention pertains, and as may be applied to the central features hereinbeforesetforth, and fall within the scope of the invention and of the limits of the appended claims.
The following references, to the extent that they provide exemplary procedural or other details supplementary to those set forth herein, are specifically incorporated herein by reference.
The present application claims priority on prior U.S. Provisional Application Ser. No. 60/257,094, filed Dec. 22, 2000, and which is incorporated herein in its entirety by reference.
Number | Name | Date | Kind |
---|---|---|---|
780043 | Korff | Jan 1905 | A |
809293 | Friedenthal | Jan 1906 | A |
889395 | Noyes | Jun 1908 | A |
1200487 | Grimm | Oct 1916 | A |
1444491 | Baldwin | Feb 1923 | A |
1555447 | Bernstein | Sep 1925 | A |
1733779 | Connell | Oct 1929 | A |
2178667 | Littlefield | Nov 1939 | A |
2682235 | Fuller | Jun 1954 | A |
2709975 | Parker | Jun 1955 | A |
2835112 | Monnet | May 1958 | A |
2970388 | Yonkers | Feb 1961 | A |
2986241 | Fuller | May 1961 | A |
3063519 | Richter | Nov 1962 | A |
3105969 | Banche et al. | Oct 1963 | A |
3114176 | Miller | Dec 1963 | A |
3129531 | Connor | Apr 1964 | A |
3139957 | Fuller | Jul 1964 | A |
3164111 | Lanni | Jan 1965 | A |
3220152 | Sturm | Nov 1965 | A |
3277479 | Struble, Jr. | Oct 1966 | A |
3277614 | Marie | Oct 1966 | A |
3292317 | Barrett | Dec 1966 | A |
3305997 | Keay et al. | Feb 1967 | A |
3365790 | Brauer | Jan 1968 | A |
3407560 | Baumann | Oct 1968 | A |
3421280 | Attwood et al. | Jan 1969 | A |
3468503 | Snibbe | Sep 1969 | A |
3494578 | Cureton | Feb 1970 | A |
D218765 | Dattner | Sep 1970 | S |
3563374 | Lund et al. | Feb 1971 | A |
3565442 | Klein | Feb 1971 | A |
3660952 | Wilson | May 1972 | A |
3665882 | Georgiev et al. | May 1972 | A |
3668876 | Koehler | Jun 1972 | A |
D224522 | Amie | Aug 1972 | S |
3877096 | Scesney | Apr 1975 | A |
3937426 | Pearce | Feb 1976 | A |
3942291 | Hirata et al. | Mar 1976 | A |
3953948 | Hogan | May 1976 | A |
3968808 | Zeigler | Jul 1976 | A |
3974600 | Pearce | Aug 1976 | A |
3974611 | Satterthwaite | Aug 1976 | A |
4004429 | Mouton, Jr. | Jan 1977 | A |
4012872 | Stolpin | Mar 1977 | A |
4074497 | Ono | Feb 1978 | A |
4092810 | Sumner | Jun 1978 | A |
4096479 | Van Buskirk | Jun 1978 | A |
4133538 | Ambrose | Jan 1979 | A |
4145765 | Malone | Mar 1979 | A |
4146997 | Diethorn | Apr 1979 | A |
4207715 | Kitrick | Jun 1980 | A |
4219958 | Shulyak | Sep 1980 | A |
4241550 | Sumner | Dec 1980 | A |
4284679 | Blad et al. | Aug 1981 | A |
4309852 | Stolpin | Jan 1982 | A |
4330969 | Quaney | May 1982 | A |
4333446 | Smyth | Jun 1982 | A |
4448832 | Kidwell | May 1984 | A |
4496155 | Goldfarb | Jan 1985 | A |
4603519 | Lew et al. | Aug 1986 | A |
4611441 | Wickens | Sep 1986 | A |
4645379 | Grimsley et al. | Feb 1987 | A |
4655022 | Natori | Apr 1987 | A |
4719726 | Bergman | Jan 1988 | A |
4729197 | Miller | Mar 1988 | A |
4750807 | Chamayou dit Felix | Jun 1988 | A |
4778184 | Fleischer | Oct 1988 | A |
4833843 | Richter | May 1989 | A |
4896656 | Johnson | Jan 1990 | A |
5097645 | Sanderson | Mar 1992 | A |
5146719 | Saito et al. | Sep 1992 | A |
5184789 | Aldrin | Feb 1993 | A |
5201160 | Sanchez | Apr 1993 | A |
5580013 | Velke | Dec 1996 | A |
5704169 | Richter | Jan 1998 | A |
5765326 | Schuster | Jun 1998 | A |
5904006 | Evans | May 1999 | A |
Number | Date | Country |
---|---|---|
1244842 | Sep 1971 | BR |
742407 | Dec 1966 | CA |
1101626 | May 1981 | CA |
314458 | Sep 1919 | DE |
1280634 | Dec 1961 | FR |
17215 | Jul 1910 | GB |
842156 | Jun 1979 | SU |
Number | Date | Country | |
---|---|---|---|
60257094 | Dec 2000 | US |