Weed control and fertilizer

Information

  • Patent Grant
  • 11078128
  • Patent Number
    11,078,128
  • Date Filed
    Thursday, September 28, 2017
    6 years ago
  • Date Issued
    Tuesday, August 3, 2021
    2 years ago
  • Inventors
    • Wolfe; Bradley T. (Boulder, CO, US)
  • Original Assignees
    • One Earth Organics, LLC (Boulder, CO, US)
  • Examiners
    • Hirt; Erin E
    Agents
    • Cooley LLP
Abstract
A composition for weed control and fertilizer comprising iron hydroxyl ethylenediaminetriacetic acid, fertilizer mineral supplement, feed grade urea, a natural-based wetting agent, molasses desugarized solubles, and water, and may further comprise glycerin and/or preservatives, are provided. Methods for weed control and fertilization of plants comprising the steps of providing a composition comprising an effective amount of iron hydroxyl ethylenediaminetriacetic acid, fertilizer mineral supplement, feed grade urea, natural-based wetting agent, and molasses desugarized solubles, and applying an effective amount of the composition to soil or a plant or a weed, are also provided.
Description
BACKGROUND

Soil contains many of the essential elements needed for plant growth. However, to achieve maximum growth and yield fertilizers and various forms of weed control are often employed to enrich the soil and supplement nutrients that are needed for optimum plant growth.


The foregoing examples of related art and limitations related therewith are intended to be illustrative and not exclusive, and they do not imply any limitations on the inventions described herein. Other limitations of the related art will become apparent to those skilled in the art upon a reading of the specification and a study of the drawings.


SUMMARY

The following embodiments and aspects thereof are described and illustrated in conjunction with systems, tools and methods, which are meant to be exemplary and illustrative, not limiting in scope. In various embodiments, one or more of the above-described problems have been reduced or eliminated, while other embodiments are directed to other improvements.


One embodiment may comprise a composition for weed control and fertilizer comprising an effective amount of iron hydroxyl ethylenediaminetriacetic acid, fertilizer mineral supplement, feed grade urea, a natural-based wetting agent, molasses desugarized solubles, and water, and may further comprise glycerin and/or a preservative.


One embodiment may further comprise a method for weed control and fertilization of plants comprising the steps of providing a composition comprising an effective amount of iron hydroxyl ethylenediaminetriacetic acid, fertilizer mineral supplement, feed grade urea, a natural-based wetting agent, molasses desugarized solubles and water, and applying an effective amount of the composition to soil, lawn, or a cultivated area.


One embodiment may further comprise a kit for weed control and fertilizer comprising iron hydroxyl ethylenediaminetriacetic acid, borresol humate HA-1, chelated micronutrients, feed grade urea, a natural-based wetting agent, and molasses desugarized solubles. The kit may further comprise glycerin and/or a preservative.


In addition to the examples, aspects and embodiments described above, further aspects and embodiments will become apparent by study of the following descriptions, any one or all of which are within the invention. The summary above is a list of example implementations, not a limiting statement of the scope of the invention.





BRIEF DESCRIPTION OF THE DRAWINGS

The accompanying figures, which are incorporated herein and form a part of the specification, illustrate some, but not the only or exclusive, example embodiments and/or features. It is intended that the embodiments and figures disclosed herein are to be considered illustrative rather than limiting.


The patent or application file may contain one or more drawings executed in color and/or one or more photographs. Copies of this patent or patent application publication with color drawing(s) and/or photograph(s) will be provided by the Patent Office upon request and payment of the necessary fee.



FIG. 1 is a flow diagram of how to make and use the composition of the present disclosure.



FIG. 2A is a photograph of a broad leaf weed 1 minute after application of the formulation of the present disclosure.



FIG. 2B is a photograph of the broad leaf weed shown in FIG. 2A 15 hours and 2 minutes after application of the formulation of the present disclosure.



FIG. 2C is a photograph of the broad leaf weed shown in FIG. 2A 21 hours and 50 minutes after application of the formulation of the present disclosure.



FIG. 2D is a photograph of the broad leaf weed shown in FIG. 2A 25 hours and 26 minutes after application of the formulation of the present disclosure.



FIG. 2E is a photograph of the broad leaf weed shown in FIG. 2A 42 hours and 12 minutes after application of the formulation of the present disclosure.



FIG. 2F is a photograph of the broad leaf weed shown in FIG. 2A 48 hours and 34 minutes after application of the formulation of the present disclosure.



FIG. 3A is a photograph of a broad leaf weed 2 minutes after application of the formulation of the present disclosure.



FIG. 3B is a photograph of the broad leaf weed shown in FIG. 3A 18 hours and 36 minutes after application of the formulation of the present disclosure.



FIG. 3C is a photograph of the broad leaf weed shown in FIG. 3A 22 hours and 39 minutes after application of the formulation of the present disclosure.



FIG. 3D is a photograph of the broad leaf weed shown in FIG. 3A 25 hours and 54 minutes after application of the formulation of the present disclosure.



FIG. 3E is a photograph of the broad leaf weed shown in FIG. 3A 43 hours and 18 minutes after application of the formulation of the present disclosure.



FIG. 3F is a photograph of the broad leaf weed shown in FIG. 3A 47 hours and 49 minutes after application of the formulation of the present disclosure.



FIG. 3G is a photograph of the broad leaf weed shown in FIG. 3A 48 hours and 31 minutes after application of the formulation of the present disclosure.





DETAILED DESCRIPTION

The present invention relates broadly to a formulation for weed control and fertilizer. The formulations comprise iron hydroxyl ethylenediaminetriacetic acid (iron HEDTA), fertilizer mineral supplement, feed grade urea, a natural-based wetting agent, molasses desugarized solubles (MDS), and water, and may also contain glycerin. The composition is thoroughly mixed together to form a solution that is then applied to soil, lawn, or a cultivated area in order to kill weeds and fertilize plants. The solution may be applied, for example, up to 8 times per year in tropical climates and those with mild winters, or may be applied 6 to 8 weeks apart for example, in temperate climates. In the case of rain following treatment, the solution may be re-applied one week later to ensure adequate results.


As will be understood by one skilled in the art, the formulation of the present disclosure may comprise combinations including but not limited to iron HEDTA, fertilizer mineral supplement, feed grade urea, a natural-based wetting agent, MDS, and water, and may further comprise glycerin and/or a preservative.


Table 1 below shows approximate percentage range of the ingredients of the formulation as an embodiment of the present disclosure for the control of weeds and fertilization of plants. Column 1 shows a list of the ingredients of one or more embodiments of the composition of matter of the present disclosure. Column 2 shows the approximate percentage range of each ingredient of one or more embodiments of the present disclosure.











TABLE 1






Ingredient
Approximate percentage range








Iron HEDTA
5.13% to 7.76%



Fertilizer mineral supplement
0.06% to 0.07%



Feed Grade Urea
3.77% to 4.02% % (w/v) (kg/L)



A natural-based wetting agent
0.04% to 0.05%



MDS
6.35% to 10.1%



Glycerin
0.06% to 0.07%



Water
Remaining percentage









The application of the composition to soil, lawn, or a cultivated area in accordance with the teaching of the present disclosure kills weeds as well as fertilizes plants. The composition of the present disclosure is a post emergent weed control and fertilizer made from food grade ingredients that will kill most broadleaf weeds. The ingredients in the composition of the present disclosure function as catalysts for oxygen reduction, which causes the production of unstable and highly reactive oxygen radicals, such as hydroxyl radicals. This causes cellular damage within the weed, leading to plant death. The weeds cannot handle the nutrient overload because they metabolize them too quickly causing them to die, typically within 36 to 48 hours. Weed control rates range from between 60% to 90% reduction per application depending on the weed species and time of year.


Additionally, compositions of the present disclosure will fertilize the lawn and build beneficial microbial activity in soils. The compositions of the present disclosure are considered non-toxic to pets, dogs, cats, people, and the environment.


Weeds


For purposes of the present disclosure, the term “weed” means a wild plant growing where it is not wanted and/or in competition with a cultivated area. Application of the composition of the present disclosure may kill the following weeds, but is not limited to: bindweed, black medic, broadleaf plantain, bull thistle, canada thistle, common chickweed, dandelion, false dandelion, mallow, narrow-leaved plantain, oxalis, Persian speedwell, prickly lettuce, prostrate spurge, purslane, redroot pigweed, slender speedwell, and white clover.


Table below shows the weed and the approximate percent killed using the compositions of the present disclosure. Column 1 lists the weed, column 2 shows the percentage of weeds killed, and column 3 shows the rating of weed control based on the percentage. The compositions of the present disclosure works very well on controlling dandelions and often the control rates are up to 90% or greater when lawns are treated in the spring.











TABLE 2





Weed
Percent killed
Rating







Bindweed
60% to 80%
Good


Black medic
60% to 80%
Good


Broadleaf plantain
80% to 90+%
Excellent


Bull thistle
80% to 90+%
Excellent


Canada thistle
80% to 90+%
Excellent


Dandelion
90+%
Very Excellent, especially




in the spring


False dandelion
80% to 90+%
Excellent


Mallow
60% to 80%
Good


Narrow-leaved plantain
80% to 90+%
Excellent


Oxalis
40% to 80%
Moderate


Persian speedwell
60% to 80%
Good


Prickly Lettuce
80% to 90+%
Excellent


Prostrate Spurge
40% to 80%
Moderate


Purslane
40% to 80%
Moderate


Redroot Pigweed
60% to 80%
Good


Slender speedwell
60% to 80%
Good


White clover
40% to 80%
Moderate










Fertilization


For the purposes of the present disclosure, the term “fertilizer” means any material of natural or synthetic origin that is applied to soils or to plant tissues to supply one or more plant nutrients to the growth of plants.


Iron


In an embodiment of the present disclosure, a composition of matter for weed control and fertilization of plants is provided, where an aspect of the composition comprises iron. There is an iron hydroxyl ethylenediaminetriacetic acid (iron HEDTA) in the composition of the present disclosure, which can be purchased commercially, and it is a very strong chelating agent which means it is more available to the plant for uptake. Types of iron that may be bound to a chelating agent and used in the present disclosure include, but are not limited to, ferric nitrate and iron chloride.


Descriptive examples of the concentration of iron HEDTA of the formulation are shown in Tables 1, and 3a-8b of the present disclosure. However, as will be apparent to one skilled in the art, these concentrations may encompass any percentage including but not limited to a range between 5.13% by volume and 7.76% by volume and all integers in between. Therefore, while these descriptive examples have, for example, 5.13%, 5.85%, 6.25%, 6.74%, 6.68%, 6.77%, and 7.76% by volume, it should be understood that these descriptions are applicable to any such concentration by volume including but not limited to volumes ranging between 5.13% by volume and 7.76% by volume and all integers in between, as will be understood by one skilled in the art, once they understand the principles of this invention. In some embodiments, the term “effective amount” of iron HEDTA may indicate an amount that is effective, when administered in a composition for weed control and plant fertilization as described herein.


Fertilizer Mineral Supplement


Fertilizer mineral supplement is a composition, such as MICROMATE® comprising borresol humate HA-1 (commercially available) and a chelated mix of micronutrients (commercially available, for example AXILO® Mix 5). The chelated mix of micronutrients may include, but is not limited to, for example, boron, copper, iron, mangesium, molybdenum, and zinc.


Humate is composed of organic matter that is millions of years old, that resulted from the decomposition of prehistoric plant and animal matter. Because it was once a living organism, it has many of the properties available to provide plants what they need for rapid and healthy growth. Humate also holds minerals and macro nutrients in available and soluble forms that can be assimilated and used by plants. Still further, humate provides direct plant stimulation by supplying a slow release of auxin, amino acids and organic phosphate, thus regulating hormone levels that tend to undergo rapid changes in stressed plants. In addition, humate serves as a substrate supporting the growth and proliferation of beneficial soil micro-organisms.


Humates also provide a number of physical benefits including increased water holding capacity of soil, increased aeration of soil, improved soil workability, improved seed bed, reduced soil erosion, and improved drought tolerance. Chemical benefits are also provided which include an increased percentage of total nitrogen in the soil, neutralized alkaline and acidic soils, maximized ion exchange capacity, maximized mineral uptake, and retention and release of fertilizer in root zones as needed. Still further, biological benefits are provided and include accelerated cell division thus stimulating plant growth, increased cell wall thickness thus extending shelf life, accelerated seed germination, increase of desirable micro-organisms in soil, increased vitamin content in plants, increased length wise root growth, maximized nutrient uptake, increased plant enzyme production, and enhanced photosynthesis.


Humate is primarily comprised of organic carbon in the form of humic acid and fulvic acid, but may also conatin ulmic acid and lignin, as well as many trace elements such as copper (Cu), iron (Fe), and zinc (Zn). Humic acid is a naturally occurring dark brown substance found in association with fulvic acid. Fulvic acid is a naturally occurring yellow-brown product of microbial metabolism that can be extracted from sediment, and is a powerful organic electrolyte.


As shown in FIG. 1, to generate a 2 gallon mix of fertilizer mineral supplement 103, heat 1.75 gallons of water to approximately 160 degrees Fahrenheit, then while agitating the water mix in 2.4 pounds of borresol humate HA-1 powder and 1 pound of chelated micronutrients. The mixture is allowed to cool and may be stored at room temperature until use.


Descriptive examples of the concentration of fertilizer mineral supplement of the formulation are shown in Tables 1, and 3a-8b of the present disclosure. However, as will be apparent to one skilled in the art, these concentrations may encompass any percentage including but not limited to a range between 0.06% by volume and 0.07% by volume and all integers in between. Therefore, while these descriptive examples have 0.068%, and 0.069% by volume, it should be understood that these descriptions are applicable to any such concentration by volume including but not limited to volumes ranging between 0.06% by volume and 0.07% by volume and all integers in between, as will be understood by one skilled in the art, once they understand the principles of this invention. In some embodiments, the term “effective amount” of fertilizer mineral supplement may indicate an amount that is effective, when administered in a composition for weed control and plant fertilization as described herein.


Urea


Urea serves an important role in the metabolism of nitrogen-containing compounds by animals, and is the main nitrogen-containing substance in the urine of mammals. Urea is a compound formed in the liver from ammonia produced by the deamination of amino acids and can be purchased commercially. It is the principal end product of protein catabolism and constitutes about one half of the total urinary solids. It is a colorless, odorless solid, highly soluble in water, and practically non-toxic. Dissolved in water, it is neither acidic nor alkaline. The composition of the present disclosure uses feed grade urea. Its nitrogen becomes plant-available when converted to ammonium and then nitrate.


Descriptive examples of the concentration of urea of the formulation are shown in Tables 1, and 3a-8b of the present disclosure. However, as will be apparent to one skilled in the art, these concentrations may encompass any percentage including but not limited to a range between 3.77% by weight to volume (w/v) and 4.02% by (w/v) and all integers in between. Therefore, while these descriptive examples have, for example, 3.77%, 3.97%, 3.98%, 4.00%, 4.01%, and 4.02% by weight to volume, it should be understood that these descriptions are applicable to any such concentration by weight to volume including but not limited to weight to volumes ranging between 3.77% by (w/v) and 4.02% by (w/v) and all integers in between, as will be understood by one skilled in the art, once they understand the principles of this invention. In some embodiments, the term “effective amount” of urea may indicate an amount that is effective, when administered in a composition for weed control and plant fertilization as described herein.


Natural-Based Wetting Agents


As used herein, “wetting agent” means any natural-based wetting agent, soil penetrant, and non-ionic surfactant derived from Yucca schidigera. Wetting agents can be commercially purchased, for example YUCCAH® and Therm X-70. Both of these products are derived from Yucca schidigera, a unique desert plant that produces natural surfactant compounds to help it manage water more efficiently. These surfactant compounds help improve the spreadability and soaking effect of water, even in very dry, water resistant soils. These are safe alternatives to chemical wetting agents. Other examples of wetting agents can include non-ionic surfactants derived from plants such as Yucca schidigera.


Descriptive examples of the concentration of natural-based wetting agents of the formulation are shown in Tables 1, and 3a-8b of the present disclosure. However, as will be apparent to one skilled in the art, these concentrations may encompass any percentage including but not limited to a range between 0.04% by volume and 0.05% by volume and all integers in between. Therefore, while these descriptive examples have, for example, 0.046%, and 0.045% by volume, it should be understood that these descriptions are applicable to any such concentration by volume including but not limited to volumes ranging between 0.04% by volume and 0.05% by volume and all integers in between, as will be understood by one skilled in the art, once they understand the principles of this invention. In some embodiments, the term “effective amount” of a natural-based wetting agent may indicate an amount that is effective, when administered in a composition for weed control and plant fertilization as described herein.


Molasses Desugarized Solubles


Molasses Desugarized Solubles (MDS) is produced during the exclusion separation of sucrose from beet molasses and can be purchased commercially. In the process, sucrose is recovered for granulation and the greater part of the non-sugars of the original sugar beet molasses is separated into residual molasses and concentrated to produce MDS. Major components of MDS are: water, sugar, raffinose, betaine, amino acids, nitrogen compounds, inorganic salts and organic acid salts. These all occur naturally in sugar beets. MDS is a valuable animal feed additive that has many of the properties of molasses with more protein and minerals.


Descriptive examples of the concentration of MDS of the formulation are shown in Tables 1, and 3a-8b of the present disclosure. However, as will be apparent to one skilled in the art, these concentrations may encompass any percentage including but not limited to a range between 6.35% by volume and 10.1% by volume and all integers in between. Therefore, while these descriptive examples have, for example, 6.35%, 6.68%, 6.77%, 6.69%, and 9.33% to 10.1% by volume, it should be understood that these descriptions are applicable to any such concentration by volume including but not limited to volumes ranging between 6.35% by volume and 10.1% by volume and all integers in between, as will be understood by one skilled in the art, once they understand the principles of this invention. In some embodiments, the term “effective amount” of MDS may indicate an amount that is effective, when administered in a composition for weed control and plant fertilization as described herein.


Glycerin


Descriptive examples of the concentration of glycerin of the formulation are shown in Tables 1, 3a, 4a, and 5a of the present disclosure. However, as will be apparent to one skilled in the art, these concentrations may encompass any percentage including, but not limited to, a range between 0.06% by volume and 0.07% by volume and all integers in between. Therefore, while these descriptive examples have, for example, 0.068%, and 0.069% by volume, it should be understood that these descriptions are applicable to any such concentration by volume including but not limited to volumes ranging between 0.06% by volume and 0.07% by volume and all integers in between, as will be understood by one skilled in the art, once they understand the principles of this invention. In some embodiments, the term “effective amount” of fertilizer mineral supplement may indicate an amount that is effective, when administered in a composition for weed control and plant fertilization as described herein.


Preservatives


As will be understood by one skilled in the art, the formulations of the present disclosure may further comprise a preservative to maintain the solution for several days after mixing. Examples of such preservatives include, but are not limited to, those that stabilize nitrogen. These preservatives can be commercially purchased, for example, LESCO U-PLUS®.


Mode of Application


As will be understood by one skilled in the art, once they understand the principles of the embodiments of the disclosure, the ingredients described herein for the formulation of the present disclosure may be used in a variety of preparations and applications including but not limited to injection, surface broadcast, broadcast incorporated, band application, fertigation, foliar application, sidedress, topdress, and seed placement.


Injection is used to place liquids below the soil near plant roots. It reduces losses through precise application of nutrients. Surface broadcast is method whereby fertilizer is applied across an entire field. High capacity spreaders are used to spin dry fertilizer or spray liquid fertilizer on the soil surface or on a growing crop. It is fast and economical. Broadcast incorporated improves surface application by incorporating the fertilizer through plowing or disking. Band application is also known as starter application. In the band application method, fertilizer is applied in bands near developing roots. This can be done before or during seed planting. Fertigation is the distribution of water-soluble fertilizers through an irrigation system. Foliar application is a method whereby small amounts of fertilizer are applied by directing spraying the leaves. Sidedressing is when fertilizer is applied between rows of young plants to provide a boost during periods of growth. Topdressing is when fertilizer is spread on established fields (for example, grasses and legumes). Lastly, seed placement, also known as pop-up application is when a small amount of fertilizer is placed with seeds during planting.


EXAMPLES

The following examples are provided to illustrate further the various applications of the present invention and are not intended to limit the invention beyond the limitations set forth in the appended claims.


Example 1

The flow diagram shown in FIG. 1 outlines how to mix an embodiment of the composition of the present disclosure prior to use. To make two gallons of fertilizer mineral supplement 103, first heat 1.75 gallons of water to 160 degrees Fahrenheit, then while agitating the water add 2.4 pounds of borresol humate HA-1 powder and one pound of chelated micronutrients. Allow the mixture to cool prior to use in the composition of the present disclosure. Unused fertilizer mineral supplement may stored at room temperature. As will be understood by one skilled in the art, different amounts of fertilizer mineral supplement may be generated by altering the measurements of ingredients listed above in step 103. For example, 1 gallon of fertilizer mineral supplement may be generated by heating 0.875 gallons of water and adding 1.2 pounds of borresol humate HA-1 and 0.5 pound of chelated micronutrients.


To prepare the composition of the present disclosure, mix together the appropriate amounts of water, molasses desugarized solubles, natural-based wetting agent, feed grade urea, fertilizer mineral supplement, and iron HEDTA 105. The composition may also include glycerin. Example amounts of the ingredients listed in step 105 are shown in Table 1 above and Tables 3a-8b below. As shown in step 107, apply the appropriate amount of the composition to soil, lawn, or a cultivated area. Effective amounts of composition per square foot of area are shown in Tables 3a-8b below. Application methods include, but are not limited to, injection, surface broadcast, broadcast incorporated, band application, fertigation, foliar application, sidedress, topdress, and seed placement.


Example 2

While other commercially available products may be used in the composition of the present disclosure, the natural-based wetting agent used in Tables 3a-8b below was YUCCAH®, and the chelated mix of micronutrients used in Tables 3a-8b below was AXILO® Mix 5.


In Table 3a below different measurements of the ingredients are provided to treat from 250 square feet to 100,000 square feet (SQ), column one. The total volume is shown in two units of measurement: ounces (oz) (column 2), and gallons (gal) (column 3). Columns 4 through 7 show the amount of water and MDS in two units of measurement, gallons and ounces. In column 8, the amount of natural-based wetting agent (WA) is shown in ounces. In columns 9 and 10, the amount of feed grade urea is shown in pounds (lbs) and kilograms (kg), respectively. In column 11, the amount of fertilizer mineral supplement (MT) is shown in ounces. In column 12, the amount of glycerin (GN) is shown in ounces. Lastly, in column 13, the amount of iron HEDTA is shown in ounces.

















TABLE 3a








Total Volume
H2O
MDS
WA
Urea
MT
GN
Iron



















SQ
oz
gal
gal
oz
gal
oz
oz
lbs
kg
oz
oz
oz






















250
97.09
0.76
0.65
83.11
0.05
6.5
0.04
0.25
0.11
0.07
0.07
6.5


500
194.19
1.52
1.30
166.22
0.10
13
0.09
0.50
0.23
0.13
0.13
13.0


750
291.28
2.28
1.95
249.34
0.15
19.5
0.13
0.76
0.34
0.20
0.20
19.5


1000
388.38
3.03
2.60
332.45
0.20
26
0.18
1.01
0.46
0.27
0.27
26.0


1250
485.47
3.79
3.25
415.56
0.25
32.5
0.22
1.26
0.57
0.33
0.33
32.5


1500
582.57
4.55
3.90
498.67
0.30
39
0.26
1.51
0.69
0.40
0.40
39.0


1750
680.86
5.32
4.55
582.99
0.36
45.5
0.31
1.76
0.80
0.46
0.46
45.5


2000
777.95
6.08
5.20
666.10
0.41
52
0.35
2.01
0.91
0.53
0.53
52.0


2250
875.05
6.84
5.85
749.21
0.46
58.5
0.40
2.27
1.03
0.60
0.60
58.5


2500
972.14
7.59
6.50
832.32
0.51
65
0.44
2.52
1.14
0.66
0.66
65.0


2750
1069.24
8.35
7.15
915.44
0.56
71.5
0.48
2.77
1.26
0.73
0.73
71.5


3000
1166.33
9.11
7.80
998.55
0.61
78
0.53
3.02
1.37
0.80
0.80
78.0


3250
1263.43
9.87
8.45
1081.66
0.66
84.5
0.57
3.27
1.48
0.86
0.86
84.5


3500
1360.52
10.63
9.10
1164.77
0.71
91
0.61
3.52
1.60
0.93
0.93
91.0


3750
1457.61
11.39
9.75
1247.89
0.76
97.5
0.66
3.78
1.71
0.99
0.99
97.5


4000
1554.71
12.15
10.40
1331.00
0.81
104
0.70
4.03
1.83
1.06
1.06
104.0


4250
1651.80
12.90
11.05
1414.11
0.86
110.5
0.75
4.28
1.94
1.13
1.13
110.5


4500
1748.90
13.66
11.70
1497.22
0.91
117
0.79
4.53
2.06
1.19
1.19
117.0


4750
1847.19
14.43
12.36
1581.53
0.96
123.5
0.83
4.78
2.17
1.26
1.26
123.5


5000
1944.29
15.19
13.01
1664.65
1.02
130
0.88
5.03
2.28
1.33
1.33
130.0


5250
2041.38
15.95
13.65
1747.76
1.07
136.5
0.92
5.29
2.40
1.39
1.39
136.5


5500
2138.47
16.71
14.30
1830.87
1.12
143
0.97
5.54
2.51
1.46
1.46
143.0


5750
2235.57
17.47
14.95
1913.98
1.17
149.5
1.01
5.79
2.63
1.52
1.52
149.5


6000
2332.66
18.22
15.60
1997.10
1.22
156
1.05
6.04
2.74
1.59
1.59
156.0


6250
2429.76
18.98
16.25
2080.21
1.27
162.5
1.10
6.29
2.85
1.66
1.66
162.5


6500
2526.85
19.74
16.90
2163.32
1.32
169
1.14
6.54
2.97
1.72
1.72
169.0


6750
2623.95
20.50
17.55
2246.43
1.37
175.5
1.19
6.80
3.08
1.79
1.79
175.5


7000
2721.04
21.26
18.20
2329.55
1.42
182
1.23
7.05
3.20
1.86
1.86
182.0


7250
2818.13
22.02
18.85
2412.66
1.47
188.5
1.27
7.30
3.31
1.92
1.92
188.5


7500
2915.23
22.78
19.50
2495.77
1.52
195
1.32
7.55
3.43
1.99
1.99
195.0


7750
3013.52
23.54
20.16
2580.08
1.57
201.5
1.36
7.80
3.54
2.05
2.05
201.5


8000
3110.62
24.30
20.81
2663.20
1.63
208
1.40
8.05
3.65
2.12
2.12
208.0


8250
3207.71
25.06
21.46
2746.31
1.68
214.5
1.45
8.31
3.77
2.19
2.19
214.5


8500
3304.81
25.82
22.10
2829.42
1.73
221
1.49
8.56
3.88
2.25
2.25
221.0


8750
3401.90
26.58
22.75
2912.53
1.78
227.5
1.54
8.81
4.00
2.32
2.32
227.5


9000
3498.99
27.34
23.40
2995.65
1.83
234
1.58
9.06
4.11
2.39
2.39
234.0


10000
3840
30
26
3328
2.03
260
1.76
10.07
4.57
2.65
2.65
260


50000
19456
152
130
16643
10.16
1300
8.78
50.34
22.83
13.25
13.25
1300


100000
38912
304
260
33285
20.31
2600
17.56
100.68
45.67
26.51
26.51
2600









As shown in Table 3a above, the example composition provided herein to treat approximately 1,000 square feet comprises 26 ounces of iron HEDTA, 0.27 ounces fertilizer mineral supplement, 0.46 kilograms Urea, 0.18 ounces natural-based wetting agent, and 26 ounces MDS. The composition may further comprise 0.27 ounces glycerin. As will be understood by one skilled in the art, additional preservatives may also be added to maintain the solution for few days. The total volume/square foot equates to between 0.3 ounces and 0.4 ounces per square foot. The final composition may be applied by any of the methods described above directly to the soil, lawn, or a cultivated area, for example, and may be modified accordingly to treat more or less square footage.


Table 3b below shows the percent measurements of the ingredients provided in Table 3a. The square footage is shown in column one. The total volume is shown in two units of measurement: ounces (oz) (column 2), and gallons (gal) (column 3). Columns 4 and 5 show the amount of water in gallons and ounces. In column 6, the percent iron HEDTA is shown by volume, in column 7 the percent fertilizer mineral supplement is shown by volume, in column 8 the percent feed grade urea is shown by weight to volume, column 9 shows the percent natural-based wetting agent (WA) by volume, and column 10 shows the amount of MDS by volume.
















TABLE 3b











Fertilizer









mineral






Total Volume
H2O
Iron
supplement
Urea
WA
MDS
















SQ
oz
gal
gal
oz
(oz/oz)%
(oz/oz)%
(kg/L)%
(oz/oz)%
(gal/gal)%



















250
97.09
0.76
0.65
83.11
6.6945
0.0682
3.9762
0.0452
6.69


500
194.19
1.52
1.30
166.22
6.6945
0.0682
3.9762
0.0452
6.69


750
291.28
2.28
1.95
249.34
6.6945
0.0682
3.9762
0.0452
6.69


1000
388.38
3.03
2.60
332.45
6.6945
0.0682
3.9762
0.0452
6.69


1250
485.47
3.79
3.25
415.56
6.6945
0.0682
3.9762
0.0452
6.69


1500
582.57
4.55
3.90
498.67
6.6945
0.0682
3.9762
0.0452
6.69


1750
680.86
5.32
4.55
582.99
6.6827
0.0681
3.9692
0.0451
6.68


2000
777.95
6.08
5.20
666.10
6.6842
0.0681
3.9700
0.0451
6.68


2250
875.05
6.84
5.85
749.21
6.6853
0.0682
3.9707
0.0452
6.69


2500
972.14
7.59
6.50
832.32
6.6863
0.0682
3.9713
0.0452
6.69


2750
1069.24
8.35
7.15
915.44
6.6870
0.0682
3.9717
0.0452
6.69


3000
1166.33
9.11
7.80
998.55
6.6876
0.0682
3.9721
0.0452
6.69


3250
1263.43
9.87
8.45
1081.66
6.6882
0.0682
3.9724
0.0452
6.69


3500
1360.52
10.63
9.10
1164.77
6.6886
0.0682
3.9727
0.0452
6.69


3750
1457.61
11.39
9.75
1247.89
6.6890
0.0682
3.9729
0.0452
6.69


4000
1554.71
12.15
10.40
1331.00
6.6894
0.0682
3.9731
0.0452
6.69


4250
1651.80
12.90
11.05
1414.11
6.6897
0.0682
3.9733
0.0452
6.69


4500
1748.90
13.66
11.70
1497.22
6.6899
0.0682
3.9734
0.0452
6.69


4750
1847.19
14.43
12.36
1581.53
6.6858
0.0682
3.9710
0.0452
6.69


5000
1944.29
15.19
13.01
1664.65
6.6863
0.0682
3.9713
0.0452
6.69


5250
2041.38
15.95
13.65
1747.76
6.6867
0.0682
3.9715
0.0452
6.69


5500
2138.47
16.71
14.30
1830.87
6.6870
0.0682
3.9717
0.0452
6.69


5750
2235.57
17.47
14.95
1913.98
6.6873
0.0682
3.9719
0.0452
6.69


6000
2332.66
18.22
15.60
1997.10
6.6876
0.0682
3.9721
0.0452
6.69


6250
2429.76
18.98
16.25
2080.21
6.6879
0.0682
3.9722
0.0452
6.69


6500
2526.85
19.74
16.90
2163.32
6.6882
0.0682
3.9724
0.0452
6.69


6750
2623.95
20.50
17.55
2246.43
6.6884
0.0682
3.9725
0.0452
6.69


7000
2721.04
21.26
18.20
2329.55
6.6886
0.0682
3.9727
0.0452
6.69


7250
2818.13
22.02
18.85
2412.66
6.6888
0.0682
3.9728
0.0452
6.69


7500
2915.23
22.78
19.50
2495.77
6.6890
0.0682
3.9729
0.0452
6.69


7750
3013.52
23.54
20.16
2580.08
6.6865
0.0682
3.9714
0.0452
6.69


8000
3110.62
24.30
20.81
2663.20
6.6868
0.0682
3.9716
0.0452
6.69


8250
3207.71
25.06
21.46
2746.31
6.6870
0.0682
3.9717
0.0452
6.69


8500
3304.81
25.82
22.10
2829.42
6.6872
0.0682
3.9718
0.0452
6.69


8750
3401.90
26.58
22.75
2912.53
6.6874
0.0682
3.9720
0.0452
6.69


9000
3498.99
27.34
23.40
2995.65
6.6876
0.0682
3.9721
0.0452
6.69


10000
3840
30
26
3328
6.6883
0.0682
3.9725
0.0452
6.69


50000
19456
152
130
16643
6.6875
0.0682
3.9720
0.0452
6.69


100000
38912
304
260
33285
6.6877
0.0682
3.9721
0.0452
6.69









As shown in Table 3b above, the example composition comprises between 6.68% and 6.69%/iron HEDTA (ounces of iron/total ounces), 0.07% fertilizer mineral supplement (ounces of fertilizer mineral supplement/total ounces), between 3.97% and 3.98% Urea (kilograms Urea/total liters), 0.05% natural-based wetting agent (ounces of wetting agent/total ounces), and between 6.68% and 6.69% MDS (gallons of MDS/total gallons). The composition may further comprise 0.07% glycerin (ounces of glycerin/total ounces) (not shown in Table 3b). As will be understood by one skilled in the art, the amount of water for the above formulations may be increased accordingly for formulations without glycerin or preservatives.


Example 3

In Table 4a below different measurements of the ingredients are provided to treat from 250 square feet to 9,000 square feet (SQ), column one. The total volume is shown in two units of measurement: ounces (oz) (column 2), and gallons (gal) (column 3). Columns 4 through 7 show the amount of water and MDS in two units of measurement, gallons and ounces. In column 8, the amount of natural-based wetting agent (WA) is shown in ounces. In columns 9 and 10, the amount of feed grade urea is shown in pounds (lbs) and kilograms (kg), respectively. In column 11, the amount of fertilizer mineral supplement (MT) is shown in ounces. In column 12, the amount of glycerin (GN) is shown in ounces. Lastly, in column 13, the amount of iron HEDTA is shown in ounces.

















TABLE 4a








Total Volume
H2O
MDS
WA
Urea
MT
GN
Iron



















SQ
oz
gal
gal
oz
gal
oz
oz
lbs
kg
oz
oz
oz






















250
102.4
0.8
0.6
76.8
0.051
6.5
0.04
0.25
0.11
0.07
0.07
6.0


500
192.0
1.5
1.3
166.4
0.102
13.0
0.09
0.50
0.23
0.13
0.13
12.0


750
294.4
2.3
1.9
243.2
0.152
19.5
0.13
0.76
0.34
0.20
0.20
18.0


1000
384.0
3.0
2.6
332.8
0.203
26.0
0.18
1.01
0.46
0.27
0.27
24.0


1250
486.4
3.8
3.2
409.6
0.254
32.5
0.22
1.26
0.57
0.33
0.33
30.0


1500
576.0
4.5
3.9
499.2
0.305
39.0
0.26
1.51
0.69
0.40
0.40
36.0


1750
678.4
5.3
4.6
588.8
0.355
45.5
0.31
1.76
0.80
0.46
0.46
42.0


2000
768.0
6.0
5.2
665.6
0.406
52.0
0.35
2.01
0.91
0.53
0.53
48.0


2250
870.4
6.8
5.9
755.2
0.457
58.5
0.40
2.27
1.03
0.60
0.60
54.0


2500
972.8
7.6
6.5
832.0
0.508
65.0
0.44
2.52
1.14
0.66
0.66
60.0


2750
1062.4
8.3
7.2
921.6
0.559
71.5
0.48
2.77
1.26
0.73
0.73
66.0


3000
1164.8
9.1
7.8
998.4
0.609
78.0
0.53
3.02
1.37
0.80
0.80
72.0


3250
1254.4
9.8
8.5
1088.0
0.660
84.5
0.57
3.27
1.48
0.86
0.86
78.0


3500
1356.8
10.6
9.1
1164.8
0.711
91.0
0.61
3.52
1.60
0.93
0.93
84.0


3750
1446.4
11.3
9.7
1241.6
0.762
97.5
0.66
3.78
1.71
0.99
0.99
90.0


4000
1548.8
12.1
10.4
1331.2
0.813
104.0
0.70
4.03
1.83
1.06
1.06
96.0


4250
1638.4
12.8
11.0
1408.0
0.863
110.5
0.75
4.28
1.94
1.13
1.13
102.0


4500
1740.8
13.6
11.7
1497.6
0.914
117.0
0.79
4.53
2.06
1.19
1.19
108.0


4750
1843.2
14.4
12.4
1587.2
0.965
123.5
0.83
4.78
2.17
1.26
1.26
114.0


5000
1932.8
15.1
13.0
1664.0
1.016
130.0
0.88
5.03
2.28
1.33
1.33
120.0


5250
2035.2
15.9
13.7
1753.6
1.066
136.5
0.92
5.29
2.40
1.39
1.39
126.0


5500
2124.8
16.6
14.3
1830.4
1.117
143.0
0.97
5.54
2.51
1.46
1.46
132.0


5750
2227.2
17.4
15.0
1920.0
1.168
149.5
1.01
5.79
2.63
1.52
1.52
138.0


6000
2316.8
18.1
15.6
1996.8
1.219
156.0
1.05
6.04
2.74
1.59
1.59
144.0


6250
2419.2
18.9
16.3
2086.4
1.270
162.5
1.10
6.29
2.85
1.66
1.66
150.0


6500
2508.8
19.6
16.9
2163.2
1.320
169.0
1.14
6.54
2.97
1.72
1.72
156.0


6750
2611.2
20.4
17.6
2252.8
1.371
175.5
1.19
6.80
3.08
1.79
1.79
162.0


7000
2700.8
21.1
18.2
2329.6
1.422
182.0
1.23
7.05
3.20
1.86
1.86
168.0


7250
2803.2
21.9
18.8
2406.4
1.473
188.5
1.27
7.30
3.31
1.92
1.92
174.0


7500
2905.6
22.7
19.5
2496.0
1.523
195.0
1.32
7.55
3.43
1.99
1.99
180.0


7750
2995.2
23.4
20.2
2585.6
1.574
201.5
1.36
7.80
3.54
2.05
2.05
186.0


8000
3097.6
24.2
20.8
2662.4
1.625
208.0
1.40
8.05
3.65
2.12
2.12
192.0


8250
3187.2
24.9
21.5
2752.0
1.676
214.5
1.45
8.31
3.77
2.19
2.19
198.0


8500
3289.6
25.7
22.1
2828.8
1.727
221.0
1.49
8.56
3.88
2.25
2.25
204.0


8750
3379.2
26.4
22.8
2918.4
1.777
227.5
1.54
8.81
4.00
2.32
2.32
210.0


9000
3481.6
27.2
23.4
2995.2
1.828
234.0
1.58
9.06
4.11
2.39
2.39
216.0









As shown in Table 4a above, the composition to treat approximately 1,000 square feet comprises 24 ounces of iron HEDTA, 0.27 ounces fertilizer mineral supplement, 0.46 kilograms Urea, 0.18 ounces natural-based wetting agent, and 26 ounces MDS. The composition may further comprise 0.27 ounces glycerin. As will be understood by one skilled in the art, additional preservatives may also be added to maintain the solution for a few days. The total volume/square foot equates to between 0.2 ounces and 0.3 ounces per square foot. The final composition may be applied by any of the methods described above directly to the soil, lawn, or a cultivated area, for example, and may be modified accordingly to treat more or less square footage.


Table 4b below shows the percent measurements of the ingredients provided in Table 4b. The square footage is shown in column one. The total volume is shown in two units of measurement: ounces (oz) (column 2), gallons (gal) (column 3). Columns 4 and 5 show the amount of water in gallons and ounces. In column 6, the percent iron HEDTA is shown by volume, in column 7 the percent fertilizer mineral supplement is shown by volume, in column 8 the percent feed grade urea is shown by weight to volume, column 9 shows the percent natural-based wetting agent (WA) by volume, and column 10 shows the amount of MDS by volume.
















TABLE 4b











Fertilizer









mineral






Total Volume
H2O
Iron
supplement
Urea
WA
MDS
















SQ
oz
gal
gal
oz
(oz/oz)%
(oz/oz)%
(kg/L)%
(oz/oz)%
(gal/gal)%



















250
102.4
0.8
0.6
76.8
5.8594
0.0647
3.7701
0.0429
6.3477


500
192.0
1.5
1.3
166.4
6.2500
0.0690
4.0215
0.0457
6.7708


750
294.4
2.3
1.9
243.2
6.1141
0.0675
3.9341
0.0447
6.6236


1000
384.0
3.0
2.6
332.8
6.2500
0.0690
4.0215
0.0457
6.7708


1250
486.4
3.8
3.2
409.6
6.1678
0.0681
3.9686
0.0451
6.6817


1500
576.0
4.5
3.9
499.2
6.2500
0.0690
4.0215
0.0457
6.7708


1750
678.4
5.3
4.6
588.8
6.1910
0.0684
3.9836
0.0453
6.7070


2000
768.0
6.0
5.2
665.6
6.2500
0.0690
4.0215
0.0457
6.7708


2250
870.4
6.8
5.9
755.2
6.2040
0.0685
3.9919
0.0454
6.7210


2500
972.8
7.6
6.5
832.0
6.1678
0.0681
3.9686
0.0451
6.6817


2750
1062.4
8.3
7.2
921.6
6.2123
0.0686
3.9973
0.0455
6.7300


3000
1164.8
9.1
7.8
998.4
6.1813
0.0683
3.9773
0.0452
6.6964


3250
1254.4
9.8
8.5
1088.0
6.2181
0.0687
4.0010
0.0455
6.7363


3500
1356.8
10.6
9.1
1164.8
6.1910
0.0684
3.9836
0.0453
6.7070


3750
1446.4
11.3
9.7
1241.6
6.2223
0.0687
4.0037
0.0455
6.7409


4000
1548.8
12.1
10.4
1331.2
6.1983
0.0685
3.9883
0.0454
6.7149


4250
1638.4
12.8
11.0
1408.0
6.2256
0.0688
4.0058
0.0456
6.7444


4500
1740.8
13.6
11.7
1497.6
6.2040
0.0685
3.9919
0.0454
6.7210


4750
1843.2
14.4
12.4
1587.2
6.1849
0.0683
3.9796
0.0453
6.7003


5000
1932.8
15.1
13.0
1664.0
6.2086
0.0686
3.9949
0.0454
6.7260


5250
2035.2
15.9
13.7
1753.60
6.1910
0.0684
3.9836
0.0453
6.7070


5500
2124.8
16.6
14.3
1830.40
6.2123
0.0686
3.9973
0.0455
6.7300


5750
2227.2
17.4
15.0
1920.00
6.1961
0.0684
3.9868
0.0453
6.7125


6000
2316.8
18.1
15.6
1996.80
6.2155
0.0686
3.9993
0.0455
6.7334


6250
2419.2
18.9
16.3
2086.40
6.2004
0.0685
3.9896
0.0454
6.7171


6500
2508.8
19.6
16.9
2163.20
6.2181
0.0687
4.0010
0.0455
6.7363


6750
2611.2
20.4
17.6
2252.80
6.2040
0.0685
3.9919
0.0454
6.7210


7000
2700.8
21.1
18.2
2329.60
6.2204
0.0687
4.0024
0.0455
6.7387


7250
2803.2
21.9
18.8
2406.40
6.2072
0.0686
3.9939
0.0454
6.7245


7500
2905.6
22.7
19.5
2496.00
6.1949
0.0684
3.9861
0.0453
6.7112


7750
2995.2
23.4
20.2
2585.60
6.2099
0.0686
3.9957
0.0454
6.7274


8000
3097.6
24.2
20.8
2662.40
6.1983
0.0685
3.9883
0.0454
6.7149


8250
3187.2
24.9
21.5
2752.00
6.2123
0.0686
3.9973
0.0455
6.7300


8500
3289.6
25.7
22.1
2828.80
6.2014
0.0685
3.9902
0.0454
6.7181


8750
3379.2
26.4
22.8
2918.40
6.2145
0.0686
3.9986
0.0455
6.7324


9000
3481.6
27.2
23.4
2995.20
6.2040
0.0685
3.9919
0.0454
6.7210









As shown in Table 4b above, the composition comprises between 5.86% and 6.25% iron HEDTA (ounces of iron/total ounces), between 0.06% and 0.07% fertilizer mineral supplement (ounces of fertilizer mineral supplement/total ounces), between 3.77% to 4.02% Urea (kilograms Urea/total liters), between 0.04% and 0.05% natural-based wetting agent (ounces of wetting agent/total ounces), and between 6.35% and 6.77% MDS (gallons of MDS/total gallons). As will be understood by one skilled in the art, the amount of water for the above formulations may be increased accordingly for formulations without glycerin or preservatives.


Example 4

In Table 5a below different measurements of the ingredients are provided to treat from 250 square feet to 100,000 square feet (SQ), column one. The total volume is shown in two units of measurement: ounces (oz) (column 2), and gallons (gal) (column 3). Columns 4 through 7 show the amount of water and MDS in two units of measurement, gallons and ounces. In column 8, the amount of natural-based wetting agent (WA) is shown in ounces. In columns 9 and 10, the amount of feed grade urea is shown in pounds (lbs) and kilograms (kg), respectively. In column 11, the amount of fertilizer mineral supplement (MT) is shown in ounces. In column 12, the amount of glycerin (GN) is shown in ounces. Lastly, in column 13, the amount of iron HEDTA is shown in ounces.

















TABLE 5a








Total Volume
H2O
MDS
WA
Urea
MT
GN
Iron



















SQ
oz
gal
gal
oz
gal
oz
oz
lbs
kg
oz
oz
oz






















250
96.00
0.75
0.63
80.6
0.07
9.0
0.04
0.25
0.11
0.07
0.07
6.5


500
192.00
1.50
1.25
160.0
0.15
19.2
0.09
0.50
0.23
0.13
0.13
13.0


750
289.28
2.26
1.88
240.6
0.22
28.2
0.13
0.76
0.34
0.20
0.20
19.5


1000
385.28
3.01
2.50
320.0
0.30
38.4
0.18
1.01
0.46
0.27
0.27
26.0


1250
481.28
3.76
3.13
400.6
0.37
47.4
0.22
1.26
0.57
0.33
0.33
32.5


1500
577.28
4.51
3.75
480.0
0.45
57.6
0.26
1.51
0.69
0.40
0.40
39.0


1750
674.56
5.27
4.38
560.6
0.53
67.8
0.31
1.76
0.80
0.46
0.46
45.5


2000
770.56
6.02
5.00
640.0
0.61
78.1
0.35
2.01
0.91
0.53
0.53
52.0


2250
867.84
6.78
5.63
720.6
0.68
87.0
0.40
2.27
1.03
0.60
0.60
58.5


2500
963.84
7.53
6.25
800.0
0.76
97.3
0.44
2.52
1.14
0.66
0.66
65.0


2750
1059.84
8.28
6.88
880.6
0.83
106.2
0.48
2.77
1.26
0.73
0.73
71.5


3000
1155.84
9.03
7.50
960.0
0.91
116.5
0.53
3.02
1.37
0.80
0.80
78.0


3250
1251.84
9.78
8.13
1040.6
0.98
125.4
0.57
3.27
1.48
0.86
0.86
84.5


3500
1347.84
10.53
8.75
1120.0
1.06
135.7
0.61
3.52
1.60
0.93
0.93
91.0


3750
1445.12
11.29
9.38
1200.6
1.13
144.6
0.66
3.78
1.71
0.99
0.99
97.5


4000
1541.12
12.04
10.00
1280.0
1.21
154.9
0.70
4.03
1.83
1.06
1.06
104.0


4250
1637.12
12.79
10.63
1360.6
1.28
163.8
0.75
4.28
1.94
1.13
1.13
110.5


4500
1733.12
13.54
11.25
1440.0
1.36
174.1
0.79
4.53
2.06
1.19
1.19
117.0


4750
1830.40
14.30
11.88
1520.6
1.44
184.3
0.83
4.78
2.17
1.26
1.26
123.5


5000
1926.40
15.05
12.50
1600.0
1.52
194.6
0.88
5.03
2.28
1.33
1.33
130.0


5250
2023.68
15.81
13.13
1680.6
1.59
203.5
0.92
5.29
2.40
1.39
1.39
136.5


5500
2119.68
16.56
13.75
1760.0
1.67
213.8
0.97
5.54
2.51
1.46
1.46
143.0


5750
2215.68
17.31
14.38
1840.6
1.74
222.7
1.01
5.79
2.63
1.52
1.52
149.5


6000
2311.68
18.06
15.00
1920.0
1.82
233.0
1.05
6.04
2.74
1.59
1.59
156.0


6250
2407.68
18.81
15.63
2000.6
1.89
241.9
1.10
6.29
2.85
1.66
1.66
162.5


6500
2503.68
19.56
16.25
2080.0
1.97
252.2
1.14
6.54
2.97
1.72
1.72
169.0


6750
2600.96
20.32
16.88
2160.6
2.04
261.1
1.19
6.80
3.08
1.79
1.79
175.5


7000
2696.96
21.07
17.50
2240.0
2.12
271.4
1.23
7.05
3.20
1.86
1.86
182.0


7250
2792.96
21.82
18.13
2320.6
2.19
280.3
1.27
7.30
3.31
1.92
1.92
188.5


7500
2888.96
22.57
18.76
2401.3
2.27
290.6
1.32
7.55
3.43
1.99
1.99
195.0


7750
2986.24
23.33
19.38
2480.6
2.35
300.8
1.36
7.80
3.54
2.05
2.05
201.5


8000
3082.24
24.08
20.01
2561.3
2.43
311.0
1.40
8.05
3.65
2.12
2.12
208.0


8250
3179.52
24.84
20.63
2640.6
2.50
320.0
1.45
8.31
3.77
2.19
2.19
214.5


8500
3275.52
25.59
21.26
2721.3
2.58
330.2
1.49
8.56
3.88
2.25
2.25
221.0


8750
3371.52
26.34
21.88
2800.6
2.65
339.2
1.54
8.81
4.00
2.32
2.32
227.5


9000
3467.52
27.09
22.51
2881.3
2.73
349.4
1.58
9.06
4.11
2.39
2.39
234.0


10000
3840
30
25.01
3201
3.03
387.84
1.76
10.07
4.57
2.65
2.65
260


50000
19456
152
125.03
16004
15.14
1937.92
8.78
50.34
22.83
13.25
13.25
1300


100000
38912
304
250.07
32009
30.28
3875.84
17.56
100.68
45.67
26.51
26.51
2600









As shown in Table 5a above, the composition to treat approximately 1,000 square feet comprises 26 ounces of iron HEDTA, 0.27 ounces fertilizer mineral supplement, 0.46 kilograms Urea, 0.18 ounces natural-based wetting agent, and 38.4 ounces MDS. The composition may further comprise 0.27 ounces glycerin. As will be understood by one skilled in the art, additional preservatives may also be added to maintain the solution for a few days. The total volume/square foot equates to between 0.3 ounces and 0.4 ounces per square foot. The final composition may be applied by any of the methods described above directly to the soil, lawn, or a cultivated area, for example, and may be modified accordingly to treat more or less square footage.


Table 5b below shows the percent measurements of the ingredients provided in Table 5a. The square footage is shown in column one. The total volume is shown in two units of measurement: ounces (oz) (column 2), and gallons (gal) (column 3). Columns 4 and 5 show the amount of water in gallons and ounces. In column 6, the percent iron HEDTA is shown by volume, in column 7 the percent fertilizer mineral supplement is shown by volume, in column 8 the percent feed grade urea is shown by weight to volume, column 9 shows the percent natural-based wetting agent (WA) by volume, and column 10 shows the amount of MDS by volume.
















TABLE 5b











Fertilizer









mineral






Total Volume
H2O
Iron
supplement
Urea
WA
MDS
















SQ
oz
gal
gal
oz
(oz/oz)%
(oz/oz)%
(kg/L)%
(oz/oz)%
(gal/gal)%



















250
96.00
0.75
0.63
80.6
6.7708
0.0690
4.0215
0.0457
9.3333


500
192.00
1.50
1.25
160.0
6.7708
0.0690
4.0215
0.0457
10.0000


750
289.28
2.26
1.88
240.6
6.7409
0.0687
4.0037
0.0455
9.7345


1000
385.28
3.01
2.50
320.0
6.7483
0.0688
4.0081
0.0456
9.9668


1250
481.28
3.76
3.13
400.6
6.7528
0.0688
4.0108
0.0456
9.8404


1500
577.28
4.51
3.75
480.0
6.7558
0.0689
4.0126
0.0456
9.9778


1750
674.56
5.27
4.38
560.6
6.7451
0.0688
4.0062
0.0456
10.0569


2000
770.56
6.02
5.00
640.0
6.7483
0.0688
4.0081
0.0456
10.1329


2250
867.84
6.78
5.63
720.6
6.7409
0.0687
4.0037
0.0455
10.0295


2500
963.84
7.53
6.25
800.0
6.7439
0.0687
4.0055
0.0455
10.0930


2750
1059.84
8.28
6.88
880.6
6.7463
0.0688
4.0069
0.0456
10.0242


3000
1155.84
9.03
7.50
960.0
6.7483
0.0688
4.0081
0.0456
10.0775


3250
1251.84
9.78
8.13
1040.6
6.7501
0.0688
4.0092
0.0456
10.0204


3500
1347.84
10.53
8.75
1120.0
6.7515
0.0688
4.0100
0.0456
10.0665


3750
1445.12
11.29
9.38
1200.6
6.7468
0.0688
4.0072
0.0456
10.0089


4000
1541.12
12.04
10.00
1280.0
6.7483
0.0688
4.0081
0.0456
10.0498


4250
1637.12
12.79
10.63
1360.6
6.7497
0.0688
4.0089
0.0456
10.0078


4500
1733.12
13.54
11.25
1440.0
6.7508
0.0688
4.0096
0.0456
10.0443


4750
1830.40
14.30
11.88
1520.6
6.7472
0.0688
4.0074
0.0456
10.0699


5000
1926.40
15.05
12.50
1600.0
6.7483
0.0688
4.0081
0.0456
10.0997


5250
2023.68
15.81
13.13
1680.6
6.7451
0.0688
4.0062
0.0456
10.0569


5500
2119.68
16.56
13.75
1760.0
6.7463
0.0688
4.0069
0.0456
10.0845


5750
2215.68
17.31
14.38
1840.6
6.7474
0.0688
4.0076
0.0456
10.0520


6000
2311.68
18.06
15.00
1920.0
6.7483
0.0688
4.0081
0.0456
10.0775


6250
2407.68
18.81
15.63
2000.6
6.7492
0.0688
4.0087
0.0456
10.0478


6500
2503.68
19.56
16.25
2080.0
6.7501
0.0688
4.0092
0.0456
10.0716


6750
2600.96
20.32
16.88
2160.6
6.7475
0.0688
4.0076
0.0456
10.0394


7000
2696.96
21.07
17.50
2240.0
6.7483
0.0688
4.0081
0.0456
10.0617


7250
2792.96
21.82
18.13
2320.6
6.7491
0.0688
4.0086
0.0456
10.0367


7500
2888.96
22.57
18.76
2401.3
6.7498
0.0688
4.0090
0.0456
10.0576


7750
2986.24
23.33
19.38
2480.6
6.7476
0.0688
4.0077
0.0456
10.0729


8000
3082.24
24.08
20.01
2561.3
6.7483
0.0688
4.0081
0.0456
10.0914


8250
3179.52
24.84
20.63
2640.6
6.7463
0.0688
4.0069
0.0456
10.0644


8500
3275.52
25.59
21.26
2721.3
6.7470
0.0688
4.0073
0.0456
10.0821


8750
3371.52
26.34
21.88
2800.6
6.7477
0.0688
4.0077
0.0456
10.0607


9000
3467.52
27.09
22.51
2881.3
6.7483
0.0688
4.0081
0.0456
10.0775


10000
3840
30
25.01
3201
6.6866
0.0682
3.9714
0.0452
9.97


50000
19456
152
125.03
16004
6.6879
0.0682
3.9722
0.0452
9.97


100000
38912
304
250.07
32009
6.6877
0.0682
3.9721
0.0452
9.97









As shown in Table 5b above, the composition of Example 4 comprises between 6.74% and 6.77% iron HEDTA (ounces of iron/total ounces), 0.07% fertilizer mineral supplement (ounces of fertilizer mineral supplement/total ounces), 4.00% to 4.02% Urea (kilograms Urea/total liters), 0.05% natural-based wetting agent (ounces of wetting agent/total ounces), and 9.33% to 10.1% MDS (gallons of MDS/total gallons). The composition may further comprise 0.07% glycerin (ounces of glycerin/total ounces) (not shown in Table 5b). As will be understood by one skilled in the art, the amount of water for the above formulations may be increased accordingly for formulations without glycerin or preservatives.


Example 5

In Table 6a below different measurements of the ingredients are provided to treat from 250 square feet to 9,000 square feet (SQ), column one. The total volume is shown in two units of measurement: ounces (oz) (column 2), and gallons (gal) (column 3). Columns 4 through 7 show the amount of water and MDS in two units of measurement, gallons and ounces. In column 8, the amount of natural-based wetting agent (WA) is shown in ounces. In columns 9 and 10, the amount of feed grade urea is shown in pounds (lbs) and kilograms (kg), respectively. In column 11, the amount of fertilizer mineral supplement (MT) is shown in ounces. In column 12, the amount of glycerin (GN) is shown in ounces. Lastly, in column 13, the amount of iron HEDTA is shown in ounces.
















TABLE 6a








Total Volume
H2O
MDS
WA
Urea
MT
Iron


















SQ
oz
gal
gal
oz
gal
oz
oz
lbs
kg
oz
oz





















250
97.28
0.76
0.65
83.11
0.05
6.5
0.04
0.25
0.11
0.07
6.25


500
193.28
1.51
1.30
166.22
0.10
13
0.09
0.50
0.23
0.13
12.50


750
290.56
2.27
1.95
249.34
0.15
19.5
0.13
0.76
0.34
0.20
18.75


1000
386.56
3.02
2.60
332.45
0.20
26
0.18
1.01
0.46
0.27
25.00


1250
483.84
3.78
3.25
415.56
0.25
32.5
0.22
1.26
0.57
0.33
31.25


1500
581.12
4.54
3.90
498.67
0.30
39
0.26
1.51
0.69
0.40
37.50


1750
678.40
5.30
4.55
582.99
0.36
45.5
0.31
1.76
0.80
0.46
43.75


2000
775.68
6.06
5.20
666.10
0.41
52
0.35
2.01
0.91
0.53
50.00


2250
871.68
6.81
5.85
749.21
0.46
58.5
0.40
2.27
1.03
0.60
56.25


2500
968.96
7.57
6.50
832.32
0.51
65
0.44
2.52
1.14
0.66
62.50


2750
1066.24
8.33
7.15
915.44
0.56
71.5
0.48
2.77
1.26
0.73
68.75


3000
1162.24
9.08
7.80
998.55
0.61
78
0.53
3.02
1.37
0.80
75.00


3250
1259.52
9.84
8.45
1081.66
0.66
84.5
0.57
3.27
1.48
0.86
81.25


3500
1355.52
10.59
9.10
1164.77
0.71
91
0.61
3.52
1.60
0.93
87.50


3750
1452.80
11.35
9.75
1247.89
0.76
97.5
0.66
3.78
1.71
0.99
93.75


4000
1550.08
12.11
10.40
1331.00
0.81
104
0.70
4.03
1.83
1.06
100.00


4250
1646.08
12.86
11.05
1414.11
0.86
110.5
0.75
4.28
1.94
1.13
106.25


4500
1743.36
13.62
11.70
1497.22
0.91
117
0.79
4.53
2.06
1.19
112.50


4750
1840.64
14.38
12.36
1581.53
0.96
123.5
0.83
4.78
2.17
1.26
118.75


5000
1937.92
15.14
13.01
1664.65
1.02
130
0.88
5.03
2.28
1.33
125.00


5250
2035.20
15.90
13.65
1747.76
1.07
136.5
0.92
5.29
2.40
1.39
131.25


5500
2131.20
16.65
14.30
1830.87
1.12
143
0.97
5.54
2.51
1.46
137.50


5750
2228.48
17.41
14.95
1913.98
1.17
149.5
1.01
5.79
2.63
1.52
143.75


6000
2324.48
18.16
15.60
1997.10
1.22
156
1.05
6.04
2.74
1.59
150.00


6250
2421.76
18.92
16.25
2080.21
1.27
162.5
1.10
6.29
2.85
1.66
156.25


6500
2519.04
19.68
16.90
2163.32
1.32
169
1.14
6.54
2.97
1.72
162.50


6750
2615.04
20.43
17.55
2246.43
1.37
175.5
1.19
6.80
3.08
1.79
168.75


7000
2712.32
21.19
18.20
2329.55
1.42
182
1.23
7.05
3.20
1.86
175.00


7250
2809.60
21.95
18.85
2412.66
1.47
188.5
1.27
7.30
3.31
1.92
181.25


7500
2905.60
22.70
19.50
2495.77
1.52
195
1.32
7.55
3.43
1.99
187.50


7750
3004.16
23.47
20.16
2580.08
1.57
201.5
1.36
7.80
3.54
2.05
193.75


8000
3100.16
24.22
20.81
2663.20
1.63
208
1.40
8.05
3.65
2.12
200.00


8250
3197.44
24.98
21.46
2746.31
1.68
214.5
1.45
8.31
3.77
2.19
206.25


8500
3293.44
25.73
22.10
2829.42
1.73
221
1.49
8.56
3.88
2.25
212.50


8750
3390.72
26.49
22.75
2912.53
1.78
227.5
1.54
8.81
4.00
2.32
218.75


9000
3488.00
27.25
23.40
2995.65
1.83
234
1.58
9.06
4.11
2.39
225.00









As shown in Table 6a above, the composition to treat approximately 1,000 square feet comprises 25 ounces of iron HEDTA, 0.27 ounces fertilizer mineral supplement, 0.46 kilograms Urea, 0.18 ounces natural-based wetting agent, and 26 ounces MDS. The composition may further comprise 0.27 ounces glycerin. As will be understood by one skilled in the art, additional preservatives may also be added to maintain the solution for a few days. The total volume/square foot equates to between 0.3 ounces and 0.4 ounces per square foot. The final composition may be applied by any of the methods described above directly to the soil, lawn, or a cultivated area, for example, and may be modified accordingly to treat more or less square footage.


Table 6b below shows the percent measurements of the ingredients provided in Table 6a. The square footage is shown in column one. The total volume is shown in two units of measurement: ounces (oz) (column 2), gallons (gal) (column 3). Columns 4 and 5 show the amount of water in gallons and ounces. In column 6, the percent iron HEDTA is shown by volume, in column 7 the percent fertilizer mineral supplement is shown by volume, in column 8 the percent feed grade urea is shown by weight to volume, column 9 shows the percent natural-based wetting agent (WA) by volume, and column 10 shows the amount of MDS by volume.
















TABLE 6b











Fertilizer









mineral






Total Volume
H2O
Iron
supplement
Urea
WA
MDS
















SQ
oz
gal
gal
oz
(oz/oz)%
(oz/oz)%
(kg/L)%
(oz/oz)%
(gal/gal)%



















250
97.28
0.76
0.65
83.11
6.4248
0.0720
3.9686
0.0451
6.68


500
193.28
1.51
1.30
166.22
6.4673
0.0673
3.9949
0.0454
6.73


750
290.56
2.27
1.95
249.34
6.4531
0.0688
3.9861
0.0453
6.71


1000
386.56
3.02
2.60
332.45
6.4673
0.0698
3.9949
0.0454
6.73


1250
483.84
3.78
3.25
415.56
6.4587
0.0682
3.9896
0.0454
6.72


1500
581.12
4.54
3.90
498.67
6.4531
0.0688
3.9861
0.0453
6.71


1750
678.40
5.30
4.55
582.99
6.4490
0.0678
3.9836
0.0453
6.71


2000
775.68
6.06
5.20
666.10
6.4460
0.0683
3.9817
0.0453
6.70


2250
871.68
6.81
5.85
749.21
6.4531
0.0688
3.9861
0.0453
6.71


2500
968.96
7.57
6.50
832.32
6.4502
0.0681
3.9843
0.0453
6.71


2750
1066.24
8.33
7.15
915.44
6.4479
0.0685
3.9829
0.0453
6.71


3000
1162.24
9.08
7.80
998.55
6.4531
0.0688
3.9861
0.0453
6.71


3250
1259.52
9.84
8.45
1081.66
6.4509
0.0683
3.9847
0.0453
6.71


3500
1355.52
10.59
9.10
1164.77
6.4551
0.0686
3.9873
0.0453
6.71


3750
1452.80
11.35
9.75
1247.89
6.4531
0.0681
3.9861
0.0453
6.71


4000
1550.08
12.11
10.40
1331.00
6.4513
0.0684
3.9850
0.0453
6.71


4250
1646.08
12.86
11.05
1414.11
6.4547
0.0686
3.9871
0.0453
6.71


4500
1743.36
13.62
11.70
1497.22
6.4531
0.0683
3.9861
0.0453
6.71


4750
1840.64
14.38
12.36
1581.53
6.4516
0.0685
3.9851
0.0453
6.71


5000
1937.92
15.14
13.01
1664.65
6.4502
0.0686
3.9843
0.0453
6.71


5250
2035.20
15.90
13.65
1747.76
6.4490
0.0683
3.9836
0.0453
6.71


5500
2131.20
16.65
14.30
1830.87
6.4518
0.0685
3.9853
0.0453
6.71


5750
2228.48
17.41
14.95
1913.98
6.4506
0.0682
3.9845
0.0453
6.71


6000
2324.48
18.16
15.60
1997.10
6.4531
0.0684
3.9861
0.0453
6.71


6250
2421.76
18.92
16.25
2080.21
6.4519
0.0685
3.9854
0.0453
6.71


6500
2519.04
19.68
16.90
2163.32
6.4509
0.0683
3.9847
0.0453
6.71


6750
2615.04
20.43
17.55
2246.43
6.4531
0.0685
3.9861
0.0453
6.71


7000
2712.32
21.19
18.20
2329.55
6.4520
0.0686
3.9854
0.0453
6.71


7250
2809.60
21.95
18.85
2412.66
6.4511
0.0683
3.9848
0.0453
6.71


7500
2905.60
22.70
19.50
2495.77
6.4531
0.0685
3.9861
0.0453
6.71


7750
3004.16
23.47
20.16
2580.08
6.4494
0.0682
3.9838
0.0453
6.71


8000
3100.16
24.22
20.81
2663.20
6.4513
0.0684
3.9850
0.0453
6.71


8250
3197.44
24.98
21.46
2746.31
6.4505
0.0685
3.9845
0.0453
6.71


8500
3293.44
25.73
22.10
2829.42
6.4522
0.0683
3.9855
0.0453
6.71


8750
3390.72
26.49
22.75
2912.53
6.4514
0.0684
3.9851
0.0453
6.71


9000
3488.00
27.25
23.40
2995.65
6.4507
0.0685
3.9846
0.0453
6.71









As shown in Table 6b above, the composition comprises between 6.42% and 6.45% iron HEDTA (ounces of iron/total ounces), approximately 0.07% fertilizer mineral supplement (ounces of fertilizer mineral supplement/total ounces), between 3.97% and 3.99% Urea (kilograms Urea/total liters), approximately 0.05% natural-based wetting agent (ounces of wetting agent/total ounces), and between 6.68% and 6.73% MDS (gallons of MDS/total gallons). The solution may further comprise between 0.06% and 0.07% glycerin (ounces of glycerin/total ounces, not shown in Table 6b). As will be understood by one skilled in the art, the amount of water for the above formulations may be increased accordingly for formulations without glycerin or preservatives.


Example 6

In Table 7a below different measurements of the ingredients are provided to treat from 250 square feet to 2,000 square feet (SQ), column one. The total volume is shown in two units of measurement: ounces (oz) (column 2), and gallons (gal) (column 3). Columns 4 through 7 show the amount of water and MDS in two units of measurement, gallons and ounces. In column 8, the amount of natural-based wetting agent (WA) is shown in ounces. In columns 9 and 10, the amount of feed grade urea is shown in pounds (lbs) and kilograms (kg), respectively. In column 11, the amount of fertilizer mineral supplement (MT) is shown in ounces. In column 12, the amount of glycerin (GN) is shown in ounces. Lastly, in column 13, the amount of iron HEDTA is shown in ounces.
















TABLE 7a








Total Volume
H2O
MDS
WA
Urea
MT
Iron


















SQ
oz
gal
gal
oz
gal
oz
oz
lbs
kg
oz
oz





















250
97.28
0.76
0.66
84.36
0.05
6.5
0.04
0.25
0.11
0.07
5.00


500
193.28
1.51
1.32
168.72
0.10
13
0.09
0.50
0.23
0.13
10.00


750
290.56
2.27
1.98
253.09
0.15
19.5
0.13
0.76
0.34
0.20
15.00


1000
386.56
3.02
2.64
337.45
0.20
26
0.18
1.01
0.46
0.27
20.00


1250
483.84
3.78
3.30
421.81
0.25
32.5
0.22
1.26
0.57
0.33
25.00


1500
581.12
4.54
3.96
506.37
0.30
39
0.26
1.51
0.69
0.40
29.80


1750
678.40
5.30
4.62
591.74
0.36
45.5
0.31
1.76
0.80
0.46
35.00


2000
775.68
6.06
5.28
676.10
0.41
52
0.35
2.01
0.91
0.53
40.00









As shown in Table 7a above, the composition to treat approximately 1,000 square feet comprises 20 ounces of iron HEDTA, 0.27 ounces fertilizer mineral supplement, 0.46 kilograms Urea, 0.18 ounces natural-based wetting agent, and 26 ounces MDS. The composition may further comprise 0.27 ounces glycerin. As will be understood by one skilled in the art, additional preservatives may also be added to maintain the solution for a few days. The total volume/square foot equates to between 0.3 ounces and 0.4 ounces per square foot. The final composition may be applied by any of the methods described above directly to the soil, lawn, or a cultivated area, for example, and may be modified accordingly to treat more or less square footage.


Table 7b below shows the percent measurements of the ingredients provided in Table 7a. The square footage is shown in column one. The total volume is shown in two units of measurement: ounces (oz) (column 2), gallons (gal) (column 3). Columns 4 and 5 show the amount of water in gallons and ounces. In column 6, the percent iron HEDTA is shown by volume, in column 7 the percent fertilizer mineral supplement is shown by volume, in column 8 the percent feed grade urea is shown by weight to volume, column 9 shows the percent natural-based wetting agent (WA) by volume, and column 10 shows the amount of MDS by volume.
















TABLE 7b











Fertilizer









mineral






Total Volume
H2O
Iron
supplement
Urea
WA
MDS
















SQ
oz
gal
gal
oz
(oz/oz)%
(oz/oz)%
(kg/L)%
(oz/oz)%
(gal/gal)%



















250
97.28
0.76
0.66
84.36
5.1398
0.0720
3.8235
0.0411
6.58


500
193.28
1.51
1.32
168.72
5.1738
0.0673
4.0238
0.0466
6.62


750
290.56
2.27
1.98
253.09
5.1624
0.0688
3.9568
0.0447
6.61


1000
386.56
3.02
2.64
337.45
5.1738
0.0698
4.0238
0.0466
6.62


1250
483.84
3.78
3.30
421.81
5.1670
0.0682
3.9835
0.0455
6.61


1500
581.12
4.54
3.96
506.37
5.1280
0.0688
4.0150
0.0447
6.61


1750
678.40
5.30
4.62
591.74
5.1592
0.0678
3.9875
0.0457
6.79


2000
775.68
6.06
5.28
676.10
5.1568
0.0683
3.9669
0.0451
6.77









As shown in Table 7b above, the composition comprises between 5.13% and 5.17% iron HEDTA (ounces of iron/total ounces), approximately 0.07% fertilizer mineral supplement (ounces of fertilizer mineral supplement/total ounces), 3.82% to 4.02% Urea (kilograms Urea/total liters), between 0.04% and 0.05% natural-based wetting agent (ounces of wetting agent/total ounces), and between 6.58% and 6.77% MDS (gallons of MDS/total gallons). The composition may further comprise between 0.06% and 0.07% glycerin (ounces of glycerin/total ounces, not shown in Table 7b) and preservatives. As will be understood by one skilled in the art, the amount of water for the above formulations may be increased accordingly for formulations without glycerin or preservatives.


Example 7

In Table 8a below different measurements of the ingredients are provided to treat from 250 square feet to 2,000 square feet (SQ), column one. The total volume is shown in two units of measurement: ounces (oz) (column 2), and gallons (gal) (column 3). Columns 4 through 7 show the amount of water and MDS in two units of measurement, gallons and ounces. In column 8, the amount of natural-based wetting agent (WA) is shown in ounces. In columns 9 and 10, the amount of feed grade urea is shown in pounds (lbs) and kilograms (kg), respectively. In column 11, the amount of fertilizer mineral supplement (MT) is shown in ounces. In column 12, the amount of glycerin (GN) is shown in ounces. Lastly, in column 13, the amount of iron HEDTA is shown in ounces.
















TABLE 8a








Total Volume
H2O
MDS
WA
Urea
MT
Iron


















SQ
oz
gal
gal
oz
gal
oz
oz
lbs
kg
oz
oz





















250
97.28
0.76
0.64
81.86
0.05
6.5
0.04
0.25
0.11
0.07
7.5


500
193.28
1.51
1.28
163.72
0.10
13
0.09
0.50
0.23
0.13
15


750
290.56
2.27
1.92
245.59
0.15
19.5
0.13
0.76
0.34
0.20
22.5


1000
386.56
3.02
2.56
327.45
0.20
26
0.18
1.01
0.46
0.27
30


1250
483.84
3.78
3.2
409.31
0.25
32.5
0.22
1.26
0.57
0.33
37.5


1500
581.12
4.54
3.84
491.17
0.30
39
0.26
1.51
0.69
0.40
45


1750
678.40
5.30
4.49
574.24
0.36
45.5
0.31
1.76
0.80
0.46
52.5


2000
775.68
6.06
5.13
656.1
0.41
52
0.35
2.01
0.91
0.53
60









As shown in Table 8a above, the composition to treat approximately 1,000 square feet comprises 30 ounces of iron HEDTA, 0.27 ounces fertilizer mineral supplement, 0.46 kilograms Urea, 0.18 ounces natural-based wetting agent, and 26 ounces MDS. The composition may further comprise 0.27 ounces glycerin. As will be understood by one skilled in the art, additional preservatives may also be added to maintain the solution for a few days. The total volume/square foot equates to between 0.3 ounces and 0.4 ounces per square foot. The final composition may be applied by any of the methods described above directly to the soil, lawn, or a cultivated area, for example, and may be modified accordingly to treat more or less square footage.


Table 8b below shows the percent measurements of the ingredients provided in Table 8a. The square footage is shown in column one. The total volume is shown in two units of measurement: ounces (oz) (column 2), gallons (gal) (column 3). Columns 4 and 5 show the amount of water in gallons and ounces. In column 6, the percent iron HEDTA is shown by volume, in column 7 the percent fertilizer mineral supplement is shown by volume, in column 8 the percent feed grade urea is shown by weight to volume, column 9 shows the percent natural-based wetting agent (WA) by volume, and column 10 shows the amount of MDS by volume.
















TABLE 8b











Fertilizer









mineral






Total Volume
H2O
Iron
supplement
Urea
WA
MDS
















SQ
oz
gal
gal
oz
(oz/oz)%
(oz/oz)%
(kg/L)%
(oz/oz)%
(gal/gal)%



















250
97.28
0.76
0.64
81.86
7.7097
0.0720
3.8235
0.0411
6.58


500
193.28
1.51
1.28
163.72
7.7608
0.0673
4.0238
0.0466
6.62


750
290.56
2.27
1.92
245.59
7.7437
0.0688
3.9568
0.0447
6.61


1000
386.56
3.02
2.56
327.45
7.7608
0.0698
4.0238
0.0466
6.62


1250
483.84
3.78
3.2
409.31
7.7505
0.0682
3.9835
0.0455
6.61


1500
581.12
4.54
3.84
491.17
7.7437
0.0688
4.0150
0.0447
6.61


1750
678.40
5.30
4.49
574.24
7.7388
0.0678
3.9875
0.0457
6.79


2000
775.68
6.06
5.13
656.1
7.7351
0.0683
3.9669
0.0451
6.77









As shown in Table 8b above, the composition comprises between 7.74% and 7.76% iron HEDTA (ounces of iron/total ounces), approximately 0.07% fertilizer mineral supplement (ounces of fertilizer mineral supplement/total ounces), 3.82% to 4.02% Urea (kilograms Urea/total liters), between 0.04% and 0.05% natural-based wetting agent (ounces of wetting agent/total ounces), and between 6.58% and 6.77% MDS (gallons of MDS/total gallons). The composition may further comprise between 0.06% and 0.07% glycerin (ounces of glycerin/total ounces, not shown in Table 8b) and preservatives. As will be understood by one skilled in the art, the amount of water for the above formulations may be increased accordingly for formulations without glycerin or preservatives.


In another embodiment of the present disclosure, a kit is provided to kill weeds as well as fertilize plants, comprising iron hydroxyl ethylenediaminetriacetic acid, borresol humate HA-1, a chelated mix of micronutrients, feed grade urea, a natural-based wetting agent, and molasses desugarized solubles. The kit may contain fertilizer mineral supplement, a premixed composition of borresol humate HA-1 and chelated micronutrients. The kit may further comprise glycerin and/or a preservative.


Example 7

In another embodiment of the present disclosure, the application of the composition to soil and plants in accordance with the teaching of the present disclosure kills weeds as well as fertilizes plants. The composition of the present disclosure is a post emergent weed control and fertilizer made from food grade ingredients that will kill most broadleaf weeds without damaging the surrounding cultivated area. The ingredients in the composition of the present disclosure function as catalysts for oxygen reduction, which causes the production of unstable and highly reactive oxygen radicals, such as hydroxyl radicals. This causes cellular damage within the weed, leading to plant death. The weeds cannot handle the nutrient overload because they metabolize them too quickly causing them to die.


Shown in FIGS. 2A-2F, application of the composition of the present disclosure was effective at killing a broadleaf weed. FIG. 2A shows the weed approximately one minute after application of the composition of the present disclosure. FIGS. 2B-2F shown the same weed at various time points after application. Weed death is evident approximately 2 days (48 hours) after application (FIG. 2F). The application of the composition of the present disclosure may be conducted in a variety of manners in order to allow the composition to kill weeds as well as fertilize surrounding plants. In the example shown in FIGS. 2A-2F, the composition of the present disclosure was applied evenly over the entire lawn area (blanket application, also known as surface broadcast) using a spray tank with a 2-gallon per minute cone gun nozzle. The composition was applied at a rate of 3 gallons per 1000 square feet. Other modes of application may be used, including but not limited to, injection, broadcast incorporated, band application, fertigation, foliar application, sidedress, topdress, and seed placement may be used.


Example 8

Shown in FIGS. 3A-3F, application of the composition of the present disclosure was effective at killing a broadleaf weed while the surrounding grass remains unharmed and is fertilized by the composition. FIG. 3A shows the weed approximately two minutes after application of the composition of the present disclosure. FIGS. 3B-3G shown the same weed at various time points after application. Weed death is evident approximately 2 days (48 hours) after application (FIG. 3G). The application of the composition of the present disclosure may be conducted in a variety of manners in order to allow the composition to kill weeds as well as fertilize surrounding plants. In the example shown in FIGS. 3A-3G, the composition of the present disclosure was applied evenly over the entire lawn area (blanket application, also known as surface broadcast) using a spray tank with a 2-gallon per minute cone gun nozzle. The composition was applied at a rate of 3 gallons per 1000 square feet. Other modes of application may be used, including but not limited to, injection, broadcast incorporated, band application, fertigation, foliar application, sidedress, topdress, and seed placement may be used.


The foregoing description of the invention has been presented for purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form disclosed, and other modifications and variations may be possible in light of the above teachings. The embodiment was chosen and described in order to best explain the principles of the invention and its practical application to thereby enable others skilled in the art to best utilize the invention in various embodiments and various modifications as are suited to the particular use contemplated. It is intended that the appended claims be construed to include other alternative embodiments of the invention except insofar as limited by the prior art.

Claims
  • 1. A composition for weed control and fertilizer comprising: iron hydroxyl ethylenediaminetriacetic acid, at between 5.13% and 7.76% of the total volume; fertilizer mineral supplement, at approximately between 0.06% and 0.07% of the total volume; feed grade urea, at approximately between 3.77% (kg/L) and 4.02% (kg/L); a wetting agent, at approximately between 0.04% and 0.05% of the total volume; molasses desugarized solubles, at approximately between 6.35% and 10.1% of the total volume; and water, comprising the remainder portion of said composition, wherein said composition is effective at controlling weeds.
  • 2. The composition of claim 1 further comprising glycerin, at approximately between 0.06% and 0.07% of the total volume.
  • 3. The composition of claim 1 further comprising a preservative.
  • 4. A method for weed control and fertilization comprising the steps of: providing the composition of claim 1; and applying an effective amount of the composition to soil, lawn, or a cultivated area, wherein said effective amount is between 0.3 ounces and 0.4 ounces per square foot.
  • 5. The method of claim 4, wherein said composition further comprises glycerin at approximately between 0.06% and 0.07% of the total volume.
  • 6. The method of claim 4, wherein said composition further comprises a preservative.
  • 7. The method of claim 4, wherein said composition is applied to said soil, lawn, or a cultivated area by one or more of the following methods: injection, surface broadcast, broadcast incorporated, band application, fertigation, foliar application, sidedress, topdress, and seed placement.
CROSS REFERENCE TO RELATED APPLICATIONS

This Continuation-In-Part Patent Application claims the benefit of priority from U.S. Non-Provisional patent application Ser. No. 15/085,061, filed on Mar. 30, 2016 (now U.S. Pat. No. 9,955,697, May 1, 2018), the contents of each of which are incorporated herein by reference in their entireties.

US Referenced Citations (34)
Number Name Date Kind
4519845 Ou May 1985 A
6241795 Svec et al. Jun 2001 B1
6271177 Hudetz Aug 2001 B1
6486097 Sedun et al. Nov 2002 B2
6972273 Sedun et al. Dec 2005 B2
7776124 Binder et al. Aug 2010 B2
7947104 Burnham et al. May 2011 B2
8076267 Diebold et al. Dec 2011 B2
8110017 Wells Feb 2012 B2
8557013 Burnham et al. Oct 2013 B2
8920733 Burnham et al. Dec 2014 B2
8987171 Samarajeewa et al. Mar 2015 B2
8992654 Dahms et al. Mar 2015 B2
9955697 Wolfe May 2018 B2
20010042494 Welshimer Nov 2001 A1
20060084575 Sedun et al. Apr 2006 A1
20070173409 Freire et al. Jul 2007 A1
20090004167 Boulos et al. Jan 2009 A1
20090229331 Wells Sep 2009 A1
20100154498 Valencia Jun 2010 A1
20100273656 Sedun et al. Oct 2010 A1
20110154873 Burnham et al. Jun 2011 A1
20110265532 Burnham et al. Nov 2011 A1
20120010078 Garcia-Mina et al. Jan 2012 A1
20120090365 Ersek et al. Apr 2012 A1
20120247164 Dahms et al. Oct 2012 A1
20130160506 Lynch et al. Jun 2013 A1
20140137614 Burnham et al. May 2014 A1
20150080216 Wikeley et al. Mar 2015 A1
20150101374 Burnham et al. Apr 2015 A1
20150191399 Dahms et al. Jul 2015 A1
20160157493 Sedun et al. Jun 2016 A1
20190124928 Arndt et al. May 2019 A1
20190191699 Arachchige et al. Jun 2019 A1
Foreign Referenced Citations (1)
Number Date Country
2926037 Sep 2017 CA
Non-Patent Literature Citations (11)
Entry
EPA “Scott's Lawn Pro Weed & Feed” https://www3.epa.gov/pesticides/chem_search/ppls/000538-00215-20070605.pdf, no pagination. (Year: 2007).
Agriinfotech “Super-humate” http://www.agriinfotech.com/htmls/PDF-Files/Super-Humate%20Technical%20Information.pdf, cached wayback machine Oct. 23, 2006, no pagination, 3 pages. (Year: 2006).
Andersons Products https://web.archive.org/web/20130521135300/https://andersonshumates.com/products/, cached wayback machine May 21, 2013, no pagination. (Year: 2013).
Micromate (https://humates.com/micromate/, cached google 2010) (Year: 2010).
Agsol (https://www.agsolcanada.com/products/humates), no pagination no date.
Restriction requirement and response filed Jan. 23, 2017 for U.S. Appl. No. 15/085,061, 11 pages.
Office Action and response filed Jul. 25, 2017 for U.S. Appl. No. 15/085,061, 17 pages.
Final office action and response filed Nov. 10, 2017 for U.S. Appl. No. 15/085,061, 24 pages.
Advisory action and interview summary for U.S. Appl. No. 15/085,061, 6 pages.
Pre-Appeal brief and request, and notice of appeal filed Jan. 12, 2018 and decision, 9 pages.
Neudorff product list [online] [retrieved on Mar. 3, 2020]. Retrieved from the Internet: ,URL: http://www.neudorffpro.com/index.php?id=1710>.
Related Publications (1)
Number Date Country
20180016198 A1 Jan 2018 US
Continuation in Parts (1)
Number Date Country
Parent 15085061 Mar 2016 US
Child 15718324 US