The present invention relates to joining materials by welding and more particularly, to methods apparatus and materials for joining aluminum alloy materials by electrical resistance welding.
Resistance spot welding (RSW) of steel is used in many industrial applications, e.g., in the manufacture of automobiles, often employing robotic welding equipment. RSW of steel is a fast and low-cost process, flexible for a wide range of metal gauges, easy to operate and to automate. Compared to RSW of steel, aluminum sheet of similar gauge typically requires higher welding current, for a shorter time. Attempts have been made to address this, such as cleaning, surfacing and machining the electrodes, twisting the electrodes upon contact with the stack-up, cleaning and coating the sheets with conversion coatings and the use of sacrificial inserts between the electrodes and the stack-up. Notwithstanding, it remains challenging for manufacturers who currently resistance weld steel sheet to directly substitute aluminum into their joining cells. Alternative methods and apparatus for joining aluminum sheet via RSW therefore remain of interest in the field.
The disclosed subject matter relates to a method for resistance welding, includes the steps of: (A) providing a first member composed at least partially from aluminum; (B) providing a second member composed at least partially from aluminum, each of the first member and the second member having a first outer surface with a first electrical resistance and a second outer surface with a second electrical resistance and an interior having a third electrical resistance; (C) reducing the electrical resistance of at least a portion of the first outer surface of the first member to produce a lower resistance surface, the second outer surface of the first member retaining a higher electrical resistance than the lower resistance surface and being a higher resistance surface; (D) placing the first member against the second member with the higher resistance surface abutting either the first or second outer surface of the second member producing a two-thickness stackup; (E) providing an electric resistance welder with an anode and a cathode; (F) positioning the anode against the lower resistance surface and the cathode against the second member of the stackup; and (G) passing a welding current through the stackup producing a weld between the first member and the second member at the abutting surfaces.
In another embodiment, the step of reducing is by grit blasting the first outer surface.
In another embodiment, the grit blasting is conducted with aluminum oxide grit producing a surface roughness between 30 μin to 300 μin.
In another embodiment, the step of reducing is by chemical treatment.
In another embodiment, the abutting surfaces are mill finish surfaces.
In another embodiment, the first and second outer surfaces of the first and second members include an oxide layer and wherein the oxide layer is thinned on the lower resistance surface during the step of reducing.
In another embodiment, at least one of the first member and the second member is a sheet.
In another embodiment, both the first member and the second member are sheets.
In another embodiment, further including the step of dressing the anode after the step of passing, and wherein the step of passing is conducted more than 200 times before each step of dressing is conducted.
In another embodiment, further including the step of reducing the electrical resistance of the first outer surface of the second member to produce a second lower resistance surface, the cathode being positioned against the second lower resistance surface during the step of positioning.
In another embodiment, further including the steps of providing a third member composed at least partially of aluminum, wherein the stackup of the first member and the second member is a two-thickness stackup and placing the two-thickness stackup abutting against the third member, producing a three-thickness stackup, the abutting surfaces of the two-thickness stackup with the third member each being a faying surface.
In another embodiment, a lubricant disposed on at least one of the first and second surfaces of the first or second member remains on the surface during the step of passing.
In another embodiment, at least one of the first and second surfaces of the first or second member has a conversion coating that remains on the surface during the step of passing.
In another embodiment, the anode and cathode are composed at least partially of a refractory metal.
In another embodiment, the refractory metal is tungsten.
In another embodiment, an aluminum alloy material, has: a first outer surface with a first electrical resistance; a second outer surface with a second electrical resistance; and an interior having a third electrical resistance, the electrical resistance of the first outer surface being lower than the second outer surface.
In another embodiment, the first and second outer surfaces include an oxide layer.
In another embodiment, the oxide layer of the first outer surface is thinner than the oxide layer of the second surface.
In another embodiment, the of oxide layer of the first outer surface of the first member is in the range of 3 nm to 50 nm in thickness.
In another embodiment, the first outer surface of the first member has a roughness in the range of 30 μin to 300 μin.
In another embodiment, the oxide layer of the first outer surface of the first member is at least partially composed of amorphous Al2O3.
the second outer surface of the first member is a mill finish surface.
In another embodiment, at least one of the first and second outer surfaces have lubricant thereon.
In another embodiment, A composite, has: a first member composed at least partially from aluminum; a second member composed at least partially from aluminum, each of the first member and the second member having a first outer surface with a first electrical resistance and a second outer surface with a second electrical resistance and an interior having a third electrical resistance, the electrical resistance of at least a portion of the first outer surface of the first member being lower than the electrical resistance of the second outer surface of the first member, the second outer surface being a higher resistance surface; the first member juxtaposed with the second member with the higher resistance surface abutting either the first or second outer surface of the second member; and a weld joining the abutting surfaces of the first member and the second member.
In another embodiment, the weld is a resistance spot weld.
In another embodiment, the portion of the first outer surface is a grit blasted surface.
In another embodiment, the abutting surfaces are mill finish surfaces.
In another embodiment, the first and second outer surfaces include an oxide layer and wherein the oxide layer of the first outer surface of the first member is thinner than the oxide layer of the second surface thereof.
In another embodiment, the of oxide layer of the portion of the first outer surface of the first member is in the range of 3 nm to 50 nm in thickness.
In another embodiment, the portion of the first outer surface of the first member has a roughness in the range of 30 μin to 300 μin.
In another embodiment, the oxide layer of the portion of the first outer surface of the first member is at least partially composed of amorphous Al2O3.
In another embodiment, the second outer surface of the first member is a mill finish surface.
In another embodiment, at least one of the first member and the second member is a sheet.
In another embodiment, both the first member and the second member are sheets.
In another embodiment, the composite further includes a third member composed at least partially of aluminum, the second member abutting against the third member and with a second weld joining the second member to the third member.
In another embodiment, the composite forms part of a vehicle body.
For a more complete understanding of the present disclosure, reference is made to the following detailed description of exemplary embodiments considered in conjunction with the accompanying drawings.
The figures constitute a part of this specification and include illustrative embodiments of the present disclosure and illustrate various objects and features thereof. In addition, any measurements, specifications and the like shown in the figures are intended to be illustrative, and not restrictive. Therefore, specific structural and functional details disclosed herein are not to be interpreted as limiting, but merely as a representative basis for teaching one skilled in the art to variously employ the present invention.
Among those benefits and improvements that have been disclosed, other objects and advantages of this invention will become apparent from the following description taken in conjunction with the accompanying figures. Detailed embodiments of the present invention are disclosed herein; however, it is to be understood that the disclosed embodiments are merely illustrative of the invention that may be embodied in various forms. In addition, each of the examples given in connection with the various embodiments of the invention is intended to be illustrative, and not restrictive.
Throughout the specification and claims, the following terms take the meanings explicitly associated herein, unless the context clearly dictates otherwise. The phrases “in one embodiment” and “in some embodiments” as used herein do not necessarily refer to the same embodiment(s), though it may. Furthermore, the phrases “in another embodiment” and “in some other embodiments” as used herein do not necessarily refer to a different embodiment, although it may. Thus, as described below, various embodiments of the invention may be readily combined, without departing from the scope or spirit of the invention.
In addition, as used herein, the term “or” is an inclusive “or” operator, and is equivalent to the term “and/or,” unless the context clearly dictates otherwise. The term “based on” is not exclusive and allows for being based on additional factors not described, unless the context clearly dictates otherwise. In addition, throughout the specification, the meaning of “a,” “an,” and “the” include plural references. The meaning of “in” includes “in” and “on”.
An aspect of the present disclosure is the recognition of several factors that make the process of joining aluminum and its alloys by RSW different from joining steel via RSW. (In this disclosure, “aluminum” shall include pure aluminum and its alloys.) Differences include: i) joining aluminum materials, e.g., aluminum sheets, via RSW requires higher welding current, e.g., 2-3 times that required for steel of a similar gauge; and ii) aluminum exhibits a higher shrinkage during solidification and a higher coefficient of thermal expansion during welding. The above factors require that welding parameters be kept within narrow ranges to avoid weld defects or alternatively, higher forces and currents be used for a wider process window. To mitigate these effects, frequent redressing of the electrodes is required and large-faced electrodes are preferred to mitigate electrode sticking. The higher currents require the industry to weld with direct current (DC) power supplies that operate at higher frequencies (above 800 Hz versus 50 to 60 Hz) in order to reduce the transformer size and utility line draw. Even with these measures, the anode (positive electrode in the DC weld process) starts to pick up aluminum, i.e., aluminum from the sheet adheres to the electrode, eroding the electrode and the sheet in as few as 10 welds for some alloy families, but typically after twenty-five to fifty welds. The erosion of the anode then leads to erosion of the cathode, requiring the electrodes to be refaced to ensure uniform pressure and current distribution. Anode erosion is further accelerated by the Peltier effect, which results in additional heat generation proportional to the differences in the Seebeck coefficients between copper and aluminum. As the current flows between the anode and aluminum sheet, this additional heat is locally generated at the anode-sheet interface, contributing to localized melting of the aluminum sheet proximate the interface. By comparison, the same electrodes can last longer if used in welding steel sheets. The industry addresses electrode wear by employing regular electrode dressing and/or current stepping.
Electrode dressing or refacing for RSW of steel sheets is typically done after approximately 200 to 300 welds. The number of welds between required electrode dressing for similar gauge aluminum sheet is typically to that of steel. Current stepping, which employs incrementally boosting the current after a number of welds have been completed to compensate for electrode wear, is not effective for aluminum since the current is much higher in general and is difficult to increase compared to steel.
In RSW of aluminum, a large electrical current is passed through the sheets to be welded to generate Joule heating. An aspect of the present disclosure is the recognition that the heating at the faying interface (the area of contact between the welded materials, e.g., sheets of aluminum) should be greater than in other areas of the stackup, so that the metal at the faying interface melts before other areas, merges with that of the adjacent sheet and re-solidifies as a weld before the surfaces in contact with either of the electrodes melt. This may be accomplished by selectively controlling the thickness of an oxide layer of different surface(s) of the aluminum materials to be welded, thereby controlling the electrical resistance and Joule heating in different areas of the stackup. This differs from welding sheet with a mill finish, i.e., having oxide layers of thicknesses determined by a rolling process in a rolling mill, or indiscriminately chemically cleaning or applying conversion coatings to the entire aluminum sheet to uniformly reduce the oxide as compared to a mill finish. While chemical cleaning may improve weld consistency over some mill finish flow paths, it requires an increase in welding currents by 10 to 25%, further widening the difference in welding equipment requirements compared to steel sheet RSW.
An aspect of the present disclosure is the recognition that the presence of an oxide layer of high electrical resistance on the surface of the aluminum materials to be welded that are contacted by the electrodes can cause high, localized temperatures at the electrode/sheet interface that leads to sticking and deterioration of the electrode. Further, that the weld current preferentially flows where localized asperities have been deformed, disrupting the oxide layer. In more severe cases where the combination of the electrode contact with the sheet surface topography does not uniformly break through the oxide, this localized reaction between the electrode material and aluminum can cause growth or wear of the electrode, limiting its usable life. In accordance with an embodiment of the present disclosure, this condition can be alleviated by treatment of the surfaces of the sheet(s) to be welded at the interface of the electrode(s) and the sheet(s) to control the electrical resistance through the sheet(s) surface, which reduces heat generation at the electrode interface(s). The treatment of the surface(s) of the sheet(s) in contact with the electrode(s) may be done chemically, by exposure to a plasma, a laser or a water jet, or mechanically (wire brush, scotchbrite abrasion, etc.), by exposure to a blasting media (alumina, iron, glass beads, dry ice, etc.
In accordance with another embodiment of the present disclosure, a robust and simple surface treatment promoting RSW of aluminum sheet is by grit blasting the surface of the sheets contacted by one or both of the welding electrodes, while leaving the faying surfaces of the sheets in the stackup in the untreated (mill finish) condition. Grit blasting can be applied to the entire side opposite to the faying surface side that is contacted by the electrode(s) or locally to the areas of the sheet surface that will be contacted by the electrode(s) when the sheet is welded by RSW.
In accordance with another embodiment, RSW of aluminum to aluminum can be conducted using specialized electrodes which contain physical elements or which are plated with refractory or nickel based materials. When using electrodes of this type, the welding can be conducted on mill finish aluminum sheets, chemically cleaned sheets, sheets that have been coated with a conversion coating or sheets that have their oxide layer reduced by blasting, e.g., grit blasting, on one or both surfaces of the sheets. In one embodiment, the specialized electrodes are used in combination with the differential reduction of oxide layers on at least one electrode contacting surface of a sheet of the stackup, leaving the faying surface of that sheet with a thicker oxide layer, e.g., as provided by a mill finish.
In accordance with another embodiment of the present disclosure, only one electrode contacting surface is treated by reducing the oxide layer, e.g., the anode contacting surface of the stackup is grit blasted, leaving the oxide layers of all other sheets in the stackup undisturbed or of greater thickness, even that surface in contact with the cathode. In another embodiment, all surfaces of the stackup in contact with the anode and cathode electrodes are treated, e.g., grit blasted, to reduce the thickness thereof.
In one embodiment of the present disclosure, two sheets are present in the stackup, such that the resulting weld(s) may be referred to as two thickness or 2T joints. In another embodiment, more than two sheets may be present in the stackup, giving rise to welds of a greater number of thicknesses, e.g., three thickness (3T) joints or greater. In one embodiment, the outer electrode contacting surfaces are treated to reduce the oxide thickness, such that they have a lower contact resistance than the faying surfaces, facilitating the weld joints of aluminum sheets, e.g., 2T or 3T joints or greater. In one embodiment, only the anode electrode contacting side of one sheet in the stackup is treated to reduce the thickness of the oxide layer.
In one embodiment, a stackup in accordance with the present disclosure, e.g., a stackup with one or both electrode contacting surfaces with a reduced thickness oxide layer and with faying surfaces having a thicker oxide layer is compatible with traditional lubricants used during forming/shaping operations. Typically, sheet material, such as sheet aluminum is provided with a surface lubricant that facilitates the forming of the sheet into various shapes by forming dies. For example, automotive parts, such as body panels, are formed with lubricants specially formulated to ensure the part shape can be obtained while minimizing tool (die) wear. A plurality of formed parts may then be welded without cleaning and the lubricants can impact the consistency and quality of the welds. An aspect of the present disclosure is the recognition that lubricants at the faying surfaces do not impact the weld quality as much as those that are exposed to the electrodes. At the electrode contacting surfaces of the stackup, surface lubricants typically accelerate electrode erosion and wear and contribute to weld inconsistency, porosity, cracking, electrode sticking, expulsion and small weld size. An electrode contacting surface that has the oxide layer reduced in thickness, e.g., by grit blasting in accordance with the present disclosure, reduces the amount of heat generated at the electrode interface, compensating for the detrimental influence of the lubricants.
The thickness of oxide layers 14 and 16 (
Because the oxide layers 116A, 116B have a greater thickness than the oxide layers 114A, 114B, the electrical resistance associated with oxide layers 116A, 116B is greater and the amount of heat generated by the current I passing through oxide layers 116A, 116B is correspondingly greater compared to that generated when the current I passes through oxide layers 114A, 114B. The foregoing differential in resistance and heating permits a given current I to initiate melting and welding of the central alloy portions 112A, 112B proximate the faying interface FI between the oxide layers 116A, 116B before the central alloy portions 112A, 112B proximate the oxide layers 114A, 114B and the anode 130 and cathode 132 melts.
At the small scale of the thickness of an oxide layer, e.g., 114A, it can be expected that variations of the thickness thereof will occur over a give surface area, e.g., a surface area contacted by a welding electrode. At the micro level, the central alloy portion 12 and the layers 14, 16 of aluminum oxide will not be geometrically flat but will vary dimensionally. For example, the upper surface 18 (
Weldability tests were carried out on 125×450 mm×0.9 mm thickness panels of 6022-T4 aluminum sheets. The baseline condition was mill finish and had no additional surface treatment or conversion coating applied. The improved condition was grit blasted on one side with 120 alumina grit at 60 psi, as described above. MP404 lubricant was applied to all surfaces at a coverage rate of 100 mg/square meter to represent typical industry conditions, e.g., in the fabrication of automobile bodies and panels. Each condition was tested such that the panels were welded to themselves and a total of 300 welds were consecutively run without changing the welding parameters. The panels were then assembled into a stack, like stack 105 of
All welds were good quality and no sticking of the electrodes 130, 132 (
3.1
2.5
0.0
0.0
0.0
0.0
0.0
0.0
2.8
3.1
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
2.8
3.5
0.0
0.0
3.0
0.0
2.8
3.4
0.0
2.3
0.0
2.6
0.0
3.1
3.0
0.0
3.1
0.0
2.2
0.0
0.0
2.2
2.4
3.1
2.2
0.0
0.0
0.0
0.0
0.0
0.0
0.0
2.8
0.0
0.0
3.2
0.0
3.4
The data in Table 2 was normalized to present the weld button diameter in terms of and illustrates the weld consistency achieved using the grit blasted sheet process in accordance with the present disclosure. Specifically, Table 2 shows the measured weld button diameters for 300 consecutive welds on 0.9 mm 6022-T4 (electrode side grit blast textured, faying side mill finish). Unlike the results shown in
In another embodiment of the present disclosure, only the thick oxide layer 14 on the sheet 10 in contact with the anode 130 is removed by grit blasting, i.e., at interface 1301, leaving the thick oxide layer 14 present on the sheet 10 in contact with the cathode 132, i.e., at interface 1321. An aspect of the present disclosure is the recognition that deterioration sets in earlier and grows faster at the interface 1301 between the stackup 105 and the anode 130. As a consequence, a stackup 105 having a reduced oxide thickness only on the side in contact with the anode 130, i.e., at interface 1301, will display improved, i.e., lower, dressing frequencies.
The use of electrode-contacting sheet surface(s) with reduced resistances at the electrode interface(s) 1301 also impacts the range of electrode types and/or materials that may be productively used. Copper-based electrodes exhibit high strength and conductivities approaching 80% IACS. Typical copper electrodes include RWMA Class 1 (CuZr or copper association designation C15000), Class 2 (CuCr or C18200 and CuCrZr C18150) and dispersion strengthened coppers (DSC or C15760). Class 1 electrodes are purposely selected to have exceptional electrical and thermal conductivities to keep heat generated at the contact interfaces low, preventing damage and sticking. Aluminum mill finish surfaces typically require very high conductivity copper (i.e. Class 1) to keep sticking to a minimum, whereas RSW of steel can use Class 2 electrodes. RSW of aluminum requires additional Joule heating from higher electrical currents compared to RSW of steel sheet, since the Class 1 electrodes do not provide as much secondary heat as Class 2 electrodes.
In accordance with another embodiment of the present disclosure, refractory metal electrodes including, but not limited to, materials such as tungsten (100W or C74300), tungsten-copper blends commonly referred to as elkonite (1W3/5W3 or C74450, 10W3 or C74400, 30W3 or C74350), and molybdenum (C42300) can produce welds in aluminum at significantly less current than the traditional Class 1 and 2 copper grades. The refractory metal electrodes have electrical conductivities less than 60% IACS and often range in the 30 to 50% range.
While refractory metal based electrodes offer advantages in terms of lowering the welding current required, they do not exhibit the stable, long-term performance of traditional copper electrode materials. In producing the welding results of
An aspect of the present disclosure is the recognition that the degradation/wear of the anode and the cathode attributable to welding are related. This relationship was shown in a series of 100 welds made on the same 1.1 mm 6022-T4 sheet described above in the preceding paragraphs using Class 2 copper electrodes and tungsten electrodes. In these tests, the copper anode and the tungsten anode were both dressed with 200 grit emery paper after every weld, but the cathode was not cleaned during the 100 consecutive welds. For both tungsten and copper electrodes, no wear was observed on the cathode, indicating that if the anode does not exhibit appreciable wear and erosion, then the cathode will also not exhibit wear. In an embodiment of the present disclosure, buildup on a tungsten anode can be mitigated by a low resistance interface with the stackup that is established in accordance with the teachings of the present disclosure, e.g., by grit blasting. The grit blasted anode contact surface can provide this low resistance interface, enabling use of tungsten electrodes and thereby realizing the associated advantages of using a lower welding current.
In another experiment, both surfaces of each of two 6022-T4 sheets like those used in the welding test described above were grit blasted. MP404 lubricant was applied to all sides of the sheets. Welding by RSW was conducted as described above, using the same welding settings. This experiment showed that no welding had taken place. This result was attributed to the low electrical resistance of the treated surfaces at the faying interface, which did not create enough heat for melting of the adjoining surface and their welding together.
An additional set of 300 RSW welds were conducted for a variety of other aluminum alloy sheet surfaces on 0.9 mm 6022-T4 using the same class 2 electrode materials, geometries, welding equipment and weld parameters described previously. These materials were run in both a mill condition and with Arconic 951™ pretreatment for conventional and EDT finished surfaces. These materials, which are representative of commercially available aluminum alloy sheet materials currently supplied in the auto industry, displayed electrode erosion and sticking similar to the mill finish sheet described above, i.e., electrode deterioration after 50 welds and excessive erosion after 300 welds.
Aspects of the present disclosure relate to methods to enhance the surface of an aluminum sheet that improves the consistency and repeatability of the resistance welding process to reduce the need for destructive teardowns and for improving the efficiency of the RSW process as compared to RSW welding mill finish aluminum. In accordance with an embodiment of the present disclosure, selective surface enhancement at the electrode/stack-up interface(s) results in lower resistance at the electrode/stack-up interface than at the sheet-to-sheet (or faying) surfaces, reducing the wear and erosion of the electrodes. When using conventional copper-based electrodes, electrode dressing and replacement can be extended to increase the efficiency of the process. Additionally, the selective surface enhancement enables alternative electrode materials, such as, refractory based metals and alloys and nickel-based alloys to be employed. These electrode materials provide additional heat to the weld because they have lower electrical and thermal conductivities and can only be used with the surface enhancement since conventional aluminum surfaces damage electrodes made from these materials very quickly. The approach of the present disclosure allows resistance welding at a reduced current level, enabling users to weld aluminum with the same resistance welding equipment employed to weld steel.
As shown in stackup 1405C a sheet 1410A3 with a Low Res layer 1416A can be paired with another similar sheet 1410B3. While it is preferred that Low Res layer 1416C is positioned to contact the cathode 1432 as shown in stackup 1405D to reduce wear or erosion of the cathode 1432, it can be positioned against High Res layer 1416A at the faying interface and still result in improved RSW of the layers 1410A3 and 1410B3 compared to the baseline configuration. All surfaces of the bottom sheet, e.g., 1410B3 or 1410B4 can be of the Low Res type but this will require weld currents at least 10% to 20% higher than that required for RSW of the stackup 1405D. Table 3 shows possible surface position combinations like those shown in
Sheets 2 and 3 may be conventional aluminum (mill finish) or sheets with a Low Res side. Since Low Res displays good welding performance when paired to mill finish, good welds can be obtained in a 3T joint. If a sheet with one Low Res surface is stacked adjacent to another such sheet, the adjacent faying surface is preferably a high resistance surface, such as a mill finish surface, which will provide heat to the faying interface. In general, a Low Res surface positioned adjacent a High Res surface will have better contact uniformity and will result in improved weld performance than if two High Res surfaces are juxtaposed. This improvement in the uniformity of the current transfer across the interfaces provides a significant increase in weld quality and enables 3T welding of aluminum.
While a number of embodiments of the present invention have been described, it is understood that these embodiments are illustrative only, and not restrictive, and that many modifications may become apparent to those of ordinary skill in the art. Further still, the various steps may be carried out in any desired order (and any desired steps may be added and/or any desired steps may be eliminated. All such variations and modifications are intended to be included within the scope of the present disclosure.
This application is a continuation of International Patent Application No. PCT/US2019/054914, filed Oct. 7, 2019, which claims the benefit of U.S. Provisional Patent Application No. 62/748,730 filed Oct. 22, 2018, entitled “WELDABLE ALUMINUM SHEET AND ASSOCIATED METHODS AND APPARATUS,” each of which is incorporated herein by reference in its entirety.
Number | Date | Country | |
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62748730 | Oct 2018 | US |
Number | Date | Country | |
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Parent | PCT/US2019/054914 | Oct 2019 | US |
Child | 17235598 | US |