One embodiment of the present invention relates to a welding method, a welding nozzle and a welding device, and relates to a welding method, a welding nozzle and a welding device that supply inert gas onto a surface of a metallic material.
Since tungsten inert gas (TIG) welding is high in surface quality and provides fewer defects of welding, it is used for welding of precision apparatuses and high-pressure pipes. However, the TIG welding has defects where depth of penetration of a molten pool is shallow and a welding efficiency is low. It is known that it is possible to deepen the depth of penetration by introducing oxygen into the molten pool. However, when oxygen is introduced into the molten pool, a problem where a tungsten electrode is easily consumed with that oxygen occurs. Then, in Patent Literature 1 below, a technology of double shielded TIG welding to be doubly surrounded with an inner nozzle surrounding a side of a tungsten electrode and an outer nozzle surrounding a side of the inner nozzle and to separately distribute gas to the nozzles, respectively, is disclosed. In the technology of Patent Literature 1, a dual gas supply system with Ar gas and O2 gas is prepared. Since Ar gas is distributed within the inner nozzle and mixed gas of Ar gas and O2 gas is distributed between the inner nozzle and the outer nozzle, while consumption of a tungsten electrode due to oxygen is prevented, oxygen is introduced into a molten pool and the depth of penetration is deepened.
Patent Literature 1: Japanese Patent Application Laid-Open No. 2004-298963
However, in the technology above, a dual gas supply system with Ar gas and O2 gas, and a special welding torch compatible with the dual gas supply system are required. Consequently, there are defects that the gas supply system and the welding torch become complicated and expensive. Further, since the dual gas supply system is required, there is a defect that gas for welding becomes expensive.
One embodiment of the present invention has been accomplished in light of the problem above, and the objective is to provide an arc welding method, a nozzle for arc welding and an arc welding device where oxygen is introduced into a molten pool with a simple technique to further deepen depth of penetration of the molten pool, and a welding efficiency is enhanced.
One embodiment of the present invention is a welding method, including
an inert gas supply step to supply inert gas to a surface of a metallic material from the inside of a cylindrical welding nozzle;
a heating step to heat the surface of the metallic material where the inert gas has been supplied by the welding nozzle in the inert gas supply step; and
an oxygen introduction step to introduce oxygen in the atmosphere that has been suctioned due to a reduction of pressure generated in association with a flow of the inert gas in the inert gas supply step, into a molten pool generated on the surface of the metallic material in the heating step.
According to this configuration, in the welding method where the inert gas is supplied onto the surface of the metallic material from the inside of the cylindrical welding nozzle, and the surface of the metallic material where the inert gas has been supplied by the welding nozzle is heated; oxygen in the atmosphere that has been suctioned due to a reduction in pressure generated in association with a flow of the inert gas is introduce into a molten pool generated on the surface of the metallic material. Consequently, even though a separate supply source of oxygen is not prepared as in the double shielded TIG welding, oxygen is introduced into the molten pool and depth of penetration of the molten pool is further deepened, and a weld efficiency can be enhanced.
In this case, the welding nozzle has
a nozzle inner cylinder where inert gas is distributed inside and
a nozzle outer cylinder where atmosphere that has been suctioned due to a reduction of pressure generated in association with a flow of the inert gas that is distributed within the nozzle inner cylinder in a gap with the nozzle inner cylinder while surrounding a side surface of the nozzle inner cylinder; and
in the inert gas supply step, inert gas is supplied to a metallic material from the inside of the nozzle inner cylinder; and
in the oxygen introduction step, while the atmosphere that has been suctioned due to the reduction of pressure generated in association with a flow of the inert gas that is distributed within the nozzle inner cylinder is distributed in the gap between the nozzle inner cylinder and the nozzle outer cylinder, the oxygen in the atmosphere can be introduced into the molten pool.
According to this configuration, the welding nozzle has
the nozzle inner cylinder where the inert gas is distributed inside, and
the nozzle outer cylinder where the atmosphere that has been suctioned due to a reduction of pressure generated in association with a flow of the inert gas that is distributed in the nozzle inner cylinder is distributed to the gap with the nozzle inner cylinder while surrounding the side of the nozzle inner cylinder. Further, the inert gas is supplied to the metallic material from the inside of the nozzle inner cylinder, and while the atmosphere that has been suctioned due to a reduction of pressure generated in association with a flow of the inert gas that is distributed in the nozzle inner cylinder is distributed to the gap between the nozzle inner cylinder and the nozzle outer cylinder, oxygen in the atmosphere is introduced into a molten pool. Consequently, oxygen can be introduced into the molten pool only with the welding nozzle with this simple structure having the nozzle inner cylinder and the nozzle outer cylinder.
In this case, the welding nozzle has a gap variable unit that can adjust size of the gap between the nozzle inner cylinder and the nozzle outer cylinder is adjustable; and in the oxygen introduction step, an amount of the atmosphere that is distributed in the gap between the nozzle inner cylinder and the nozzle outer cylinder is controlled by adjusting the size of the gap between the nozzle inner cylinder and the nozzle outer cylinder by the gap variable unit, and an amount of oxygen to be introduced into the molten pool can be controlled.
The amount of oxygen to be introduced in order to bring the molten pool into the ideal state varies depending upon the welding state. However, with this configuration, the welding nozzle has the gap variable unit that can adjust the size of the gap between the nozzle inner cylinder and the nozzle outer cylinder, and the amount of the atmosphere that is distributed in the gap between the nozzle inner cylinder and the nozzle outer cylinder is controlled by adjusting the size of the gap between the nozzle inner cylinder and the nozzle outer cylinder by the gap variable unit, and the amount of oxygen to be introduced into the molten pool is controlled. Consequently, the amount of oxygen to be introduced into the molten pool can be controlled by corresponding to various states of welding.
Further, the size of the gap between the nozzle inner cylinder and the nozzle outer cylinder can be greater than 1 mm but 5 mm or less.
If the size of the gap between the nozzle inner cylinder and the nozzle outer cylinder is greater than 1 mm, a reverse flow of the atmosphere that is distributed in the gap between the nozzle inner cylinder and the nozzle outer cylinder can be prevented. Further, if the size of the gap between the nozzle inner cylinder and the nozzle outer cylinder is 5 mm or less, a sufficient amount of the atmosphere can be distributed.
Further, the welding nozzle has atmosphere introduction hole parts that lead to the inside of the welding nozzle from the outside of the welding nozzle, and where the atmosphere that has been suctioned due to a reduction of pressure generated in association with a flow of the inert gas that is distributed within the welding nozzle is distributed; and in the oxygen introduction step, while the atmosphere that has been suctioned due to a reduction of pressure generated in association with a flow of the inert gas that is distributed within the welding nozzle is distributed into the atmosphere introduction hole parts, oxygen in the atmosphere can be introduced into the molten pool.
According to this configuration, the welding nozzle has the atmosphere introduction hole parts that lead to the inside of the welding nozzle from the outside of the welding nozzle, and where the atmosphere that has been suctioned due to a reduction of pressure generated in association with a flow of the inert gas that is distributed within the welding nozzle is distributed, and while the atmosphere that has been suctioned due to a reduction of pressure generated in association with a flow of the inert gas that is distributed within the welding nozzle is distributed to the atmosphere introduction hole part, oxygen in the atmosphere is introduced into the molten pool. Consequently, oxygen can be introduced into the molten pool only with the welding nozzle with this simple structure having the atmosphere introduction hole parts.
In this case, the welding nozzle has an introduction hole variable unit that can adjust size of the atmosphere introduction hole parts, and in the oxygen introduction step, the amount of the atmosphere that is distributed in the atmosphere introduction hole parts is controlled by adjusting the size of the atmosphere introduction hole parts by the introduction hole variable unit, and the amount of oxygen to be introduced into the molten pool can be controlled.
The amount of oxygen to be introduced in order to bring the molten pool to the ideal state varies depending upon a welding state. However, with this configuration, the welding nozzle has the introduction hole variable unit that can adjust the size of the atmosphere introduction hole parts, and the amount of the atmosphere that is distributed in the atmosphere introduction hole parts is controlled by adjusting the size of the atmosphere introduction hole parts by the introduction hole variable unit, and the amount of oxygen to be introduced into the molten pool is controlled.
Further, one embodiment of the present invention is a welding nozzle that supplies inert gas to a surface of a metallic material from the inside of the cylinder welding nozzle, and that is used for welding that heats the surface of the metallic material where the inert gas has been supplied by the welding nozzle, including:
a nozzle inner cylinder where the inert gas is distributed inside, and
a nozzle outer cylinder where atmosphere that has been suctioned due to a reduction of pressure generated in association with a flow of the inert gas that is distributed within the nozzle inert cylinder is distributed in the gap with the nozzle inner cylinder while surrounding the side surface of the nozzle inner cylinder, wherein
oxygen in the atmosphere is introduced into a molten pool generated on the surface of the metallic material due to heating by distributing the atmosphere that has been suctioned due to a reduction of pressure generated in association with a flow of the inert gas that is distributed within the nozzle inner cylinder in the gap between the nozzle inner cylinder and the nozzle outer cylinder.
In this case, [the welding nozzle] is equipped with a gap variable unit that can adjust size of the gap between the nozzle inner cylinder and the nozzle outer cylinder, and the amount of the atmosphere that is distributed in the gap between the nozzle inner cylinder and the nozzle outer cylinder is controlled by adjusting the size of the gap between the nozzle inner cylinder and the nozzle outer cylinder by the gap variable unit, and the amount of oxygen to be introduced into the molten pool can be controlled.
Further, in the oxygen introduction step, oxygen in the atmosphere can be introduced into the molten pool so as to be 70 ppm to 300 ppm of the amount of oxygen in the molten pool.
In the oxygen introduction step, depth of penetration can be deepened further certainly by introducing oxygen in the atmosphere into the molten pool so as to be 70 ppm to 300 ppm of the amount of oxygen in the molten pool.
Further, in the inert gas supply step, the inert gas can be supplied at 1 to 9 LM of a flow rate of inert gas.
In the inert gas supply step, the depth of penetration of the molten pool can be deepened further certainly by supplying the inert gas at 1 to 9 LM of a flow rate of the inert gas.
Further, one embodiment of the present invention is the welding nozzle that supplies inert gas to a surface of the metallic material from the inside of the cylindrical welding nozzle, and that is used for welding that heats the surface of the metallic material where the inert gas has been supplied by the welding nozzle, including: atmosphere introduction hole parts that lead to the inside of the welding nozzle from the outside of the welding nozzle, wherein
oxygen in the atmosphere is introduced into a molten pool generated on the surface of the metallic material due to heating, by distributing the atmosphere that has been suctioned due to a reduction of pressure generated in association with a flow of the inert gas that is distributed within the welding nozzle to the atmosphere introduction hole parts.
In this case, the atmosphere introduction variable that can adjust size of the atmosphere introduction hole part is included, and an amount of the atmosphere that is distributed in the atmosphere introduction hole part is controlled by adjusting the size of the atmosphere introduction hole part with the introduction hole variable unit, and an amount of oxygen to be introduced into the molten pool can be controlled.
Further, one embodiment of the present invention is welding equipment, including:
the welding nozzle of the present invention,
a thermal source to heat the surface of the metallic material where inert gas has been supplied by the welding nozzle of the present invention,
a molten pool monitoring unit that observes a molten pool, and
an oxygen introduction amount control unit that controls an amount of oxygen to be introduced into the molten pool by the gap variable unit of the welding nozzle of the present invention or the introduction hole variable unit of the welding nozzle of the present invention based upon a state of the molten pool monitored by the molten pool monitoring unit.
According to this configuration, the oxygen introduction amount control unit controls an amount of oxygen to be introduced into the molten pool by the gap variable unit of the welding nozzle of the present invention or the introduction hole variable unit of the welding nozzle of the present invention based upon a state of the molten pool monitored by the molten pool monitoring unit. Consequently, a more excellent molten pool can be obtained by controlling the amount of oxygen to be introduced into the molten pool based upon the state of the molten pool.
According to an arc welding method, an arc welding nozzle and an arc welding device in one embodiment of the present invention, it becomes possible to introduce oxygen into a molten pool with a simpler technique to further deepen depth of penetration of the molten pool, and to enhance a weld efficiency.
Hereafter, the welding method, the welding nozzle and the welding device relating to embodiments of the present invention will be explained in detail.
First, the First Embodiment of the present invention is explained. In the present embodiment, a welding nozzle relating to the present embodiment is mounted to a torch that is used for common TIG welding. Consequently, depth of penetration of a molten pool is increased by introducing oxygen, which is a surface-active element, into the molten pool. As the surface-active element, other than oxygen, sulfur, selenium and tellurium are exemplified. As a metallic material where the depth of penetration of the molten pool is increased by introducing the surface-active element into the molten pool, a metallic material containing any of, for example, Fe, Ni, an alloy of Fe and Ni and stainless steel is exemplified.
First, the torch for TIG welding is briefly explained. As shown in
Hereafter, the welding nozzle of the present embodiment is explained. As shown in
Herein, the interval g between the nozzle inner cylinder 102 and the nozzle outer cylinder 104 can be set to, for example, 1 mm to 5 mm, i.e., 3 mm, when a flow rate of the inert gas is 4 LM to 9 LM and arc length, which is the length of an arc formed between the tungsten electrode 22 and a metallic material to be welded, is 3 mm. If the arc length becomes longer, an effect to shield a molten pool 210 of the inert gas is decreased, and an amount of oxygen to be introduced to the molten pool 210 is increased. Consequently, the optimum interval g fluctuates based upon the flow rate of the inert gas and the arc length. Further, a positional relationship of a tip of the nozzle outer cylinder 104 to that of the tungsten electrode 22 is a positional relationship where the tip of the nozzle outer cylinder 104 protrudes more than the tip of the tungsten electrode 22 toward a direction of the metallic material to be welded and the entire tungsten electrode 22 is surrounded by the nozzle outer cylinder 104. However, the tip of the nozzle outer cylinder 104 can be arranged at a position recessed from the metallic material from the tip of the nozzle cylinder 102. Even in such positional relationship, an effect for suction in the atmosphere is demonstrated. Further, the tungsten electrode 22 can be arranged at a position recessed inside the welding nozzle 100a from the metallic material to be welded, and the upper limit should be a position recessed to the inside by the arc length compared to one at the side of the metallic material to be welded by the tip of either the nozzle inner cylinder 102 or the nozzle outer cylinder 104. Although it is desirable that the tip of the tungsten electrode 22 can be visually confirmed from a viewpoint of welding work, if the tungsten electrode 22 is recessed to the inside than the tip of the nozzle 100a within the range of the arc length, these are joinable.
Hereafter, action and effects of the welding nozzle 100a of the present embodiment are explained. Upon arc welding, inert gas is distributed within the nozzle inner cylinder 102, and the inert gas is supplied to a surface of a metallic material to be welded and the tungsten electrode 22 is shielded. Further, voltage is applied between the tungsten electrode 22 and the metallic material, and an arc is generated. The surface of the metallic material is heated by the arc, and a molten pool is formed. In this case, as it is known as Bernoulli's theorem, pressure is reduced in association with distribution of inert gas within the nozzle inner cylinder 102. In association with reduction of the pressure within the nozzle inner cylinder 102, as indicated with arrows in
As shown in
In the meantime, when oxygen, which is surface-active element, is introduced into the molten pool 210, as shown in
In the present embodiment, in the welding method where inert gas is supplied onto a surface of the iron material 200 from the inside of the cylindrical welding nozzle 100a and the surface of the iron material 200 where inert gas has been supplied by the welding nozzle 100a is heated, oxygen in the atmosphere that has been suctioned due to a reduction of pressure generated in association with a flow of the inert gas is introduced into the molten pool 210 generated on the surface of the iron material 200. Consequently, even though another supply source of oxygen is not prepared as with double-shielded TIG welding, oxygen is introduced into the molten pool 210 and the depth of penetration of the molten pool 210 is further deepened and a weld efficiency can be enhanced.
In the present embodiment, the welding nozzle 100a has the nozzle inner cylinder 102 where inert gas is distributed inside, and the nozzle outer cylinder 104 where the atmosphere that has been suctioned due to a reduction of pressure in association with a flow of the inert gas that is distributed in the nozzle inner cylinder 102 is distributed in the gap with the nozzle inner cylinder 102 while surrounding the side surface of the nozzle inner cylinder 102. Further, while inert gas is supplied to the iron material 200 from the inside of the nozzle inner cylinder 102 and the atmosphere that has been suctioned due to a reduction of pressure generated in association with a flow of inert gas that is distributed in the nozzle inner cylinder 102 is distributed in the gap between the nozzle inner cylinder 102 and the nozzle outer cylinder 104, oxygen in the atmosphere is introduced into the molten pool 210. Consequently, oxygen can be introduced into the molten pool 210 only with the welding nozzle 100a with this simple structure having the nozzle inner cylinder 102 and the nozzle outer cylinder 104.
Hereafter, the Second Embodiment of the present invention is explained. In the present embodiment, oxygen in the atmosphere is introduced into the molten pool 210 using a welding nozzle with different shape from that in the First Embodiment. As shown in
When inert gas is distributed within the nozzle inner cylinder 102, as similar to the First Embodiment, the atmosphere that has been suctioned from the outside of the nozzle inner cylinder 102 is distributed to the atmosphere introduction hole parts 108 due to a reduction of pressure generated in association with a flow of the inert gas. Oxygen contained in the atmosphere introduced from the atmosphere introduction hole parts 108 is then introduced into the molten pool 210.
In the present embodiment, the welding nozzle 100b has the atmosphere introduction hole parts 108 that lead to the inside of the welding nozzle 100b from the outside of the welding nozzle 100b, and where the atmosphere that has been suctioned due to a reduction of pressure generated in association with a flow of the inert gas that is distributed within the welding nozzle 100b is distributed, and while the atmosphere that has been suctioned due to a reduction of pressure generated in association with a flow of the inert gas that is distributed within the welding nozzle 100b is distributed in the atmosphere introduction hole parts 108, oxygen in the atmosphere is introduced into the molten pool 210. Consequently, oxygen can be introduced into the molten pool 210 only with the welding nozzle 100b with the simple structure having the atmosphere introduction hole parts 108.
Hereafter, the Third Embodiment of the present invention is explained. In the present embodiment, an amount of oxygen to be introduced into the molten pool 210 is controlled by controlling the gap between the nozzle inner cylinder 102 and the nozzle outer cylinder 104 in the First Embodiment. As shown in
The variable nozzle 110 is configured such that ends of a plurality of long thin nozzle pieces 112 are overlapped with each other. Ends of the nozzle pieces 112 are connected to an end of the nozzle outer cylinder 104 with hinges 113 to be flexible, respectively. Coil springs 117 are inserted between a surface of the nozzle pieces 112 and an outer surface of the nozzle inner cylinder [102], respectively. The coil spring 117 provides the force to open toward the outside of the welding nozzle 100c to the nozzle pieces 112 connected to the nozzle outer cylinder 104 with the hinges 113, respectively. Furthermore, the coil spring 117 may be an axle spring that provides force to open itself toward the outside of the welding nozzle 100c relative to the nozzle piece 112 in the hinges 113, respectively. Nozzle piece convex parts 119 that protrude toward the outside of the welding nozzle 100c are established on the outer surfaces in the vicinity of the hinges 113 of the nozzle pieces 112, respectively.
A plurality of nut concave parts 116 are established around the outer periphery of the nut 114 so as to allow an operator to easily grip them. Screw threads 115 that will be engaged with screw threads 105 are established on the outer periphery of the nozzle outer cylinder 104 on the inner periphery of the nut 114, respectively. When the nut 114 is rotated in the circumferential direction of the welding nozzle 100c due to the screw threads 105 and 115, the nut 114 slides in a direction approaching to or receding from a metallic material to be welded on the nozzle outer cylinder 104. Slopes 118 inclining toward the outside of the welding nozzle 100c are established at the end portion at the metallic material side to be welded on the inner periphery of the nut 114.
When the nut 114 is rotated in the circumferential direction of the welding nozzle 100c and the nut 114 is allowed to slide in the direction approaching to a metallic material to be welded on the nozzle outer cylinder 104, the slopes 118 slides on the nozzle piece convex parts 119 of the nozzle pieces 112 while tucking a nozzle piece convex parts 119 inward, respectively. Consequently, the variable nozzle 110 made from the nozzle pieces 112 where their end portions are overlapped with each other is pursed, and the gap g is reduced. In the meantime, the nut 114 is rotated in the reverse direction and the nut 114 is allowed to slide on the nozzle outer cylinder 104 in the direction receding from a metallic material to be welded, the distance where nozzle piece convex part 119 is tucked inward by the slope 118 becomes shorter. Consequently, the variable nozzle 110 is expanded due to spring force of the coil spring 117, and the gap g is increased.
The amount of oxygen to be introduced in order to bring the molten pool 210 to an ideal state varies depending upon the state of welding. However, in the present embodiment, the welding nozzle 100c can adjust the size of the gap g between the nozzle inner cylinder 102 and the nozzle outer cylinder 104, and the amount of atmosphere that is distributed in the gap g between the nozzle inner cylinder 102 and the nozzle outer cylinder 104 is controlled by adjusting the size of the gap g between the nozzle inner cylinder 102 and the nozzle outer cylinder 104, and the amount of oxygen to be introduced into the molten pool 210 is controlled. Consequently, the amount of oxygen to be introduced into the molten pool 210 can be controlled by responding to various statuses of welding.
Hereafter, the Fourth Embodiment of the present invention is explained. In the present embodiment, the amount of oxygen to be introduced into the molten pool 210 is controlled by controlling the size of the atmosphere introduction hole part 108 in the Second Embodiment. As shown in
A nozzle inner cylinder convex part 130 is established on the outer periphery of the nozzle inner cylinder 102. A nozzle outer cylinder concave part 131 is established on the inner periphery of the nozzle outer cylinder 120. Fitting of the nozzle inner cylinder convex part 130 into the nozzle outer cylinder concave part 131 with each other enables the nozzle inner cylinder 102 and the nozzle outer cylinder 120 to rotate in the circumferential direction of the welding nozzle 100d relative to each other while they are closely attached. An area at a site where the atmosphere introduction hole part 108 of the nozzle inner cylinder 102 is matched with the atmosphere introduction hole part 128 of the nozzle outer cylinder 120 is changed by rotating the nozzle inner cylinder 102 and the nozzle outer cylinder 120 relative to each other. Consequently, the substantial size of the atmosphere introduction hole parts 108 is adjustable, and the amount of atmosphere that is distributed in the atmosphere introduction hole part 108 by adjusting the size of the atmosphere introduction hole part 108, and the amount of oxygen to be introduced into the molten pool 210 is controlled. Consequently, the amount of oxygen to be introduced into the molten pool 210 can be controlled in response to various statuses of welding.
Hereafter, the Fifth Embodiment of the present invention is explained. In the present embodiment, a state of the molten pool 210 is monitored, and the amount of oxygen to be introduced into the molten pool [210] is controlled according to the state of the monitored molten pool 210. As shown in
The control part 70 has a D/W detecting part 71 and a gap control part 72. The D/W detecting part 71 detects D/W, which is a ratio of the depth of penetration D to the width W of the molten pool 210, based upon a detection result(s) of the photoelectric sensor 62 and the temperature sensor 64. The D/W detecting part 71 can assume, for example, the depth of penetration D to be maximal when the width D of the molten pool 210 detected by the photoelectric sensor 62 becomes minimal. Alternatively, for example, the fluidity of the molten pool 210 detected by the photoelectric sensor 62 is as shown in
According to the present embodiment, the gap control part 72 of the control part 70 controls the amount of oxygen to be introduced into the molten pool 210 based upon the status of the molten pool 210 monitored by the photoelectric sensor 62 and the temperature sensor 64. Consequently, more excellent molten pool 210 can be obtained by controlling the amount of oxygen to be introduced into the molten pool 210 based upon the status of the molten pool 210.
Furthermore, the present invention is not limited to the embodiments above, but various modified forms are applicable. For example, in the embodiments above, the modes where the welding method, the welding nozzle and the welding equipment were applied to TIG welding were mainly explained, but the present invention shall not be limited to these, but is applicable to metal inert gas (MIG) welding, laser welding and plasma welding, as well.
Hereafter, experimental examples of the present invention are explained. The welding nozzle 100a shown in
First, a flow rate at the exit of the nozzle outer cylinder 104 of the welding nozzle 100a at the time of changing the gap g (gap distance) between the nozzle inner cylinder 102 and the nozzle outer cylinder 104 of the welding nozzle 100a to 1 mm, 3 mm and 5 mm is shown in
The welding nozzle 100a shown in
According to the arc welding method, the nozzle for arc welding and the arc welding device of one embodiment of the present invention, it becomes possible to introduce oxygen into a molten pool with a simpler technique, to further deepen the depth of penetration of the molten pool, and to enhance a weld efficiency.
Number | Date | Country | Kind |
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2012-109955 | May 2012 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2013/060965 | 4/11/2013 | WO | 00 |