The invention relates to a liner for guiding welding wire with low friction.
The use of welding automated processes in many industrial applications is increasingly growing. It is common practice for such technology to feed welding wires, sometimes at significantly high speed, from large bulk containers holding up to 1000 kgs of welding consumable, from the container to the wire feeder and subsequently from the wire feeder to the welding torch.
There are some general technical problems involved when welding wire is being fed over large distances. One issue is attrition which causes the welding wire to be fed intermittently and inconsistently, with consequent spatter and in most extreme cases, torch tip burn backs. Another issue is wire surface contamination. When a large quantity of welding wire is being fed through a liner, the drawing residues and lubricant which are normally present on the wire surface as a consequence of the wire drawing process, accumulate in the liner. Further, it must be ensured that there is no excessive wire deformation and cast bending which would result in the wire being fed deformed to the welding torch, with consequent unreliable weld placements. Finally, wire surface scratching must be prevented, as otherwise the copper coating would be scraped off the wire surface which would result in inconsistent bad electrical contact at the torch tip.
There are some welding wire guides which aim at solving these issues. One example can be found in FR 2 888 825 A1 which discloses a welding wire guide which consists of two guiding bodies placed in an alternating pattern. In a first guiding body, a first set of rolling elements is arranged which guide the welding wire in a first direction. In the second guiding body, a second set of rolling elements is provided which guide the welding wire in a second direction. It is only the combination of a first and a second guiding body which defines a complete guiding channel for the welding wire. As the first set of rolling elements is spaced from the second set of rolling elements, the welding wire can touch the guiding bodies when the guiding liner is curved, resulting in increased friction and wear.
WO 2009/143917 A1 discloses a welding wire liner which consists of a plurality of liner bodies connected to each other by means of a pivot connection. Each liner body comprises a set of rolling elements which guide the wire without friction.
EP 1 974 846 A2 discloses a welding wire liner which consists of a plurality of liner bodies connected to each other by means of a ball joint. This allows the bodies to swivel in any direction with respect to the previous body. Further, the bodies can be rotated with respect to each other, which allows using the liner for feeding the welding wire to a welding torch. In view of the particular configuration of the joints between adjacent liner bodies, the ability of withstanding torsional loads has proven to be limited. Modern multiple axis welding robots move in all directions and rotate the welding torch in some cases more than 360° and must be capable of doing so without any restriction. This movement results in tension being built up, caused by the swift and sharp movements in all directions which eventually causes the wire guiding liner assemblies to snap and break apart. If the wire guiding liner is tensioned by the robot movements and cannot adequately and quickly stretch out to follow and match the robot arm rapid movements, it represents an obstacle to the continuous and correct robot performance and in most cases, when damaged, it requires the welding operator to either repair or replace it, with unwanted costly stops and losses of production.
Our earlier patent application U.S. Ser. No. 12/618,250 addresses the issue of torsional loads by using swivel connections at discrete intervals along the liner. These swivel connections allow to discharge any tension which might have resulted from the movements of the welding torch to which the liner is fitted. However, each swivel connection forms an interruption of the guiding liner.
The object of the invention is to provide a welding wire guiding liner which fulfills the requirements regarding a reliable, smooth and low-friction guiding of the welding wire, and in addition allows rotational movements of a welding torch without creating excessive torsional loads in the liner.
In order to achieve the above objects, a welding wire guiding liner is provided which has a plurality of guiding bodies connected to each other. Each of the guiding bodies contains a plurality of rolling elements defining a guiding channel for the welding wire. Each guiding body has a ring which is coaxial with the guiding channel and is freely rotatable in a peripheral direction on the body. The ring is connected to the adjacent guiding body by means of a swivel joint which allows the adjacent guiding body to swivel around a swivel axis with respect to the guiding body provided with the ring. This liner is based on the idea of combining the articulation between adjacent guiding bodies with the freedom of rotation between adjacent guiding bodies. A simple mechanical element is sufficient for achieving articulation and rotation, namely the ring which forms a swivel joint with the adjacent guiding body while being rotatably arranged on “its” guiding body.
According to a preferred embodiment, the swivel joint is formed by two connecting lugs on the ring which each have an opening into which swivel studs engage which are provided on the adjacent guiding body. This results in a reliable mechanical connection which can be easily assembled.
Preferably, each of the guiding bodies is provided with a peripheral groove which accommodates the ring. The groove is a simple means for holding the ring in a manner which allows rotation while preventing the ring from becoming disengaged from the guiding body.
According a preferred embodiment, each of the guiding bodies is provided with a holding element which accommodates the rolling elements, and a cover element in the interior of which the holding element is placed. This allows to assemble the liner with very few steps by placing the rolling elements in the holding element and then placing the cover element over the holding element whereby the rolling elements are fixed in their position in the holding element.
Preferably, the cover element has a skirt which is provided with a plurality of slots extending in parallel with the guiding channel in the interior of the guiding body, and an enlarged rim portion behind which the ring is placed. The slots allow the skirt to elastically shrink when the ring is pushed over the enlarged rim and to return to the previous condition, thereby fixing the ring on the skirt.
Preferably, the holding element is placed within the skirt so as to support the skirt in a radial direction. This prevents that the skirt unintentionally shrinks or collapses when high loads act on the ring, thereby preventing the ring from becoming detached from the skirt.
According to a preferred embodiment, an elastic ring is provided between adjacent guiding bodies. The elastic ring keeps the liner in a stretched condition which facilitates inserting the welding wire.
Preferably, each guiding body is provided with an accommodation groove for the elastic ring at one end face and an abutment surface at the opposite end face. The groove ensures that the ring is maintained at its proper location without additional measures being necessary.
The welding wire guiding liner can be provided with an outer protective hose which is made from a flexible material selected from a group comprising rubber, EPDM, silicon, cloth, polyamide, and aramid fibers. This prevents that dirt and other contamination can enter the guiding channel for the welding wire.
The invention will now be explained in detail with reference to the enclosed drawings. In the drawings,
In
The liner is composed of a plurality of guiding bodies 10 (please see in particular
Cover element 20 is generally cup-like with a generally circular plate 22 having a central opening 23, and a generally cylindrical skirt 24 which extends from plate 22. Skirt 24 defines an inner accommodation space 26 in which holding element 50 can be placed. At regularly spaced intervals, skirt 24 is provided with slots 28 which extend from the free end of skirt 24 towards plate 22, but which end at a distance before plate 24. Furthermore, skirt 24 is provided with an enlarged rim portion 30 so that a groove 32 is formed which extends around the entire skirt 24. The side of rim portion 30 which faces away from plate 22 is formed with a smooth, rounded contour (please see in particular
Groove 32 is defined in the side opposite rim portion 30 by an enlarged base portion of skirt 24, with which the skirt merges into plate 22. As can be seen in particular in
Plate 22 is provided with four swivel studs 34 which are equally distributed around the perimeter of cover element 20. Seen in a radial direction, each swivel stud 34 has a circular cross-section (please see in particular
Plate 22 features an accommodation groove 38 on its side facing away from skirt 24. As can be seen in particular in
Ring 40 has a generally rectangular cross-section (please see
Holding element 50 is formed from a plate-like base 52 from which four support blocks 54 extend. Each support block 54 is provided with two recesses 56 which are arranged such that they lie opposite each other in pairs. Between adjacent support blocks 54, an accommodation space 58 for rolling elements 70 (please see
Base 52 is provided with four positioning projections 60 which are equally spaced from each other. The width of each positioning projection 60 corresponds to the width of slots 28 in cover element 20. Furthermore, the contour of the positioning projections 60 on their side facing away from supporting blocks 54 is rounded in the same way the enlarged rim portion 60 is shaped.
Cover element 20, ring 40 and holding element 50 are formed from a plastic material, in particular from polyamide. Rolling element 70 can also be formed from plastic. In the alternative, they can be formed from metal. For mounting the rolling elements in holding element 50, short bearing pins 72 (please see
For assembling the wire guiding liner, a first step consists in placing ring 40 in groove 32 of cover element 20. To this end, the ring is simply pushed onto the skirt which elastically yields inwardly so that the ring can be pushed over rim portion 30. This is facilitated by the smooth, rounded contour of the outer edge of the rim portion and the respective edge of the ring. As soon as the ring is situated in the groove, the four sections of the skirt snap back into their original position so that ring 40 is safely held behind rim portion 30 in groove 32 (please see
In a second step, the holding element equipped with the rolling elements 70 is pushed into the accommodation space 26 of the cover element provided with ring 40. The positioning projections 60 of the holding element come to lie in slots 28 in skirt 24 so as to “close” the slots (please see
In a next step, an elastic ring 82 (please see
In a last assembly step, connecting lugs 42 of one of the so assembled guiding bodies is pushed over the swivel studs 34 of another guiding body. This is facilitated by the chamfers 36 provided on swivel studs 34. As soon as swivel studs 34 are positioned within openings 44 in connecting lugs 42 of ring 40, the connecting lugs return into their original position so that a swivel joint is formed from the swivel studs 34 engaging into openings 44. In this condition, elastic ring 82 of a “lower” guiding body 10 is held compressed against the “lower” abutment surface of the “upper” guiding body connected to the “lower” guiding body (please see
It should be clear that only two of the four swivel studs 34 of a cover element 20 are required for forming the liner. The two “unused” swivel studs 34 at the first and last guiding body 10, respectively, of the liner can be used for connecting the liner to termination 8.
Since the rolling elements 70, as viewed in a longitudinal direction, are arranged close to each other while the degree of swivel movement between adjacent guiding bodies is limited, the welding wire can easily be fed through the wire guiding liner even when it is held in a curved condition. The welding wire can travel through the liner in both directions.
Even though the skirt is shown as circular, it could also have a polygonal contour. Vice versa, the ring could also have a polygonal contour while the skirt is formed with a round contour. In any case, it must be ensured that the ring can smoothly rotate on the respective guiding body.
In practice, the guiding liner can be employed in a length of several dozen meters. The actual length can easily be adapted to the particular requirements by assembling the required number of guiding bodies. If desired, an outer protective hose can be employed, which could be formed from rubber, a plastics material or aramid fibers.
Number | Name | Date | Kind |
---|---|---|---|
318062 | Warren | May 1885 | A |
532565 | Kilmer | Jan 1895 | A |
617353 | Redmond | Jan 1899 | A |
627722 | Edwards | Jun 1899 | A |
932808 | Pelton | Aug 1909 | A |
1276117 | Riebe | Aug 1918 | A |
1468994 | Cook | Sep 1923 | A |
1640368 | Obetz | Aug 1927 | A |
1907051 | Emery | May 1933 | A |
2027670 | Broeren | Jan 1936 | A |
2027674 | Broeren | Jan 1936 | A |
2059462 | Jungmann | Nov 1936 | A |
2329369 | Haver | Sep 1943 | A |
2407746 | Johnson | Sep 1946 | A |
2457910 | McLaren et al. | Jan 1949 | A |
2477059 | Hill | Jul 1949 | A |
2483760 | Duncan | Oct 1949 | A |
2579131 | Tinsley | Dec 1951 | A |
2580900 | Epstein | Jan 1952 | A |
2694130 | Howard | Nov 1954 | A |
2713938 | Snyder | Jul 1955 | A |
2724538 | Schweich | Nov 1955 | A |
2838922 | Gift | Jun 1958 | A |
2849195 | Richardson | Aug 1958 | A |
2864565 | Whearly | Dec 1958 | A |
2869719 | Hubbard | Jan 1959 | A |
2880305 | Baird | Mar 1959 | A |
2911166 | Haugwitz | Nov 1959 | A |
2929576 | Henning | Mar 1960 | A |
2966258 | Krafft | Dec 1960 | A |
2974850 | Mayer | Mar 1961 | A |
2984596 | Franer | May 1961 | A |
3096951 | Jenson | Jul 1963 | A |
3119042 | Bond | Jan 1964 | A |
3185185 | Pfund | May 1965 | A |
3244347 | Jenk | Apr 1966 | A |
3274850 | Tascio | Sep 1966 | A |
3344682 | Bratz | Oct 1967 | A |
3352412 | Draving et al. | Nov 1967 | A |
3433504 | Hanes | Mar 1969 | A |
3463416 | Quenot | Aug 1969 | A |
3478435 | Cook | Nov 1969 | A |
3491876 | Zecchin | Jan 1970 | A |
3512635 | Lang | May 1970 | A |
3565129 | Field | Feb 1971 | A |
3567900 | Nelson | Mar 1971 | A |
3576966 | Sullivan | May 1971 | A |
3595277 | Lefever | Jul 1971 | A |
3648920 | Stump | Mar 1972 | A |
3724249 | Asbeck et al. | Apr 1973 | A |
3729092 | Marcell | Apr 1973 | A |
3730136 | Okada | May 1973 | A |
3799215 | Willems | Mar 1974 | A |
3815842 | Scrogin | Jun 1974 | A |
3823894 | Frederick et al. | Jul 1974 | A |
3939978 | Thomaswick | Feb 1976 | A |
4043331 | Martin et al. | Aug 1977 | A |
4044583 | Kinney, Jr. | Aug 1977 | A |
4074105 | Minehisa et al. | Feb 1978 | A |
4097004 | Reese | Jun 1978 | A |
4102483 | Ueyama et al. | Jul 1978 | A |
4113795 | Izawa et al. | Sep 1978 | A |
4127590 | Endo et al. | Nov 1978 | A |
4157436 | Endo et al. | Jun 1979 | A |
4161248 | Kalmanovitch | Jul 1979 | A |
4172375 | Rushforth et al. | Oct 1979 | A |
4188526 | Asano | Feb 1980 | A |
4222535 | Hosbein | Sep 1980 | A |
4254322 | Asano | Mar 1981 | A |
4274607 | Priest | Jun 1981 | A |
4280951 | Saito et al. | Jul 1981 | A |
4293103 | Tsukamoto | Oct 1981 | A |
4354487 | Oczkowski et al. | Oct 1982 | A |
4392606 | Fremion | Jul 1983 | A |
4396797 | Sakuragi et al. | Aug 1983 | A |
4429001 | Kolpin et al. | Jan 1984 | A |
4451014 | Kitt et al. | May 1984 | A |
4464919 | Labbe | Aug 1984 | A |
4500315 | Pieniak et al. | Feb 1985 | A |
4540225 | Johnson et al. | Sep 1985 | A |
4546631 | Eisinger | Oct 1985 | A |
4582198 | Ditton | Apr 1986 | A |
4585487 | Destree et al. | Apr 1986 | A |
4623063 | Balkin | Nov 1986 | A |
4737567 | Matsumoto et al. | Apr 1988 | A |
4742088 | Kim | May 1988 | A |
4826497 | Marcus et al. | May 1989 | A |
4855179 | Bourland et al. | Aug 1989 | A |
4869367 | Kawasaki et al. | Sep 1989 | A |
4891493 | Sato et al. | Jan 1990 | A |
4949567 | Corbin | Aug 1990 | A |
4974789 | Milburn | Dec 1990 | A |
5051539 | Leathers-Wiessner | Sep 1991 | A |
5061259 | Goldman et al. | Oct 1991 | A |
5078269 | Dekko et al. | Jan 1992 | A |
5100397 | Poccia et al. | Mar 1992 | A |
5105943 | Lesko et al. | Apr 1992 | A |
5109983 | Malone et al. | May 1992 | A |
5147646 | Graham | Sep 1992 | A |
5201419 | Hayes | Apr 1993 | A |
5205412 | Krieg | Apr 1993 | A |
5215338 | Kimura et al. | Jun 1993 | A |
5227314 | Brown et al. | Jul 1993 | A |
5261625 | Lanoue | Nov 1993 | A |
5277314 | Cooper et al. | Jan 1994 | A |
5314111 | Takaku et al. | May 1994 | A |
5368245 | Fore | Nov 1994 | A |
5372269 | Sutton et al. | Dec 1994 | A |
5452841 | Sibata et al. | Sep 1995 | A |
5485968 | Fujioka | Jan 1996 | A |
5494160 | Gelmetti | Feb 1996 | A |
5530088 | Sheen et al. | Jun 1996 | A |
5553810 | Bobeczko | Sep 1996 | A |
5562646 | Goldman et al. | Oct 1996 | A |
5585013 | Truty | Dec 1996 | A |
5586733 | Miura et al. | Dec 1996 | A |
5590848 | Shore et al. | Jan 1997 | A |
5629377 | Burgert et al. | May 1997 | A |
5665801 | Chang et al. | Sep 1997 | A |
5692700 | Bobeczko | Dec 1997 | A |
5714156 | Schmidt et al. | Feb 1998 | A |
5738209 | Burr et al. | Apr 1998 | A |
5739704 | Clark | Apr 1998 | A |
5746380 | Chung | May 1998 | A |
5816466 | Seufer | Oct 1998 | A |
5819934 | Cooper | Oct 1998 | A |
5845862 | Cipriani | Dec 1998 | A |
5847184 | Kleiner | Dec 1998 | A |
5865051 | Otzen et al. | Feb 1999 | A |
5921391 | Ortiz et al. | Jul 1999 | A |
5931408 | Ishii et al. | Aug 1999 | A |
5971308 | Boulton | Oct 1999 | A |
5988370 | Roemer et al. | Nov 1999 | A |
5990377 | Chen et al. | Nov 1999 | A |
6016911 | Chen | Jan 2000 | A |
6019303 | Cooper | Feb 2000 | A |
6103358 | Bruggemann et al. | Aug 2000 | A |
6159591 | Beihoffer et al. | Dec 2000 | A |
6237768 | Cipriani | May 2001 | B1 |
6245880 | Takeuchi et al. | Jun 2001 | B1 |
6255371 | Schlosser et al. | Jul 2001 | B1 |
6260781 | Cooper | Jul 2001 | B1 |
6301944 | Offer | Oct 2001 | B1 |
6322016 | Jacobsson et al. | Nov 2001 | B1 |
6340522 | Burke et al. | Jan 2002 | B1 |
6408888 | Baumer et al. | Jun 2002 | B1 |
6417425 | Whitmore et al. | Jul 2002 | B1 |
6425549 | Bae et al. | Jul 2002 | B1 |
6441067 | Chiu et al. | Aug 2002 | B1 |
6464077 | Liu | Oct 2002 | B1 |
6498227 | Horie | Dec 2002 | B1 |
6547176 | Blain et al. | Apr 2003 | B1 |
6564943 | Barton et al. | May 2003 | B2 |
6613848 | Wang et al. | Sep 2003 | B1 |
6636776 | Barton et al. | Oct 2003 | B1 |
6648141 | Land | Nov 2003 | B2 |
6649870 | Barton et al. | Nov 2003 | B1 |
6708864 | Ferguson, III et al. | Mar 2004 | B2 |
6715608 | Moore | Apr 2004 | B1 |
6745899 | Barton | Jun 2004 | B1 |
6749139 | Speck | Jun 2004 | B2 |
6750262 | Hahnle et al. | Jun 2004 | B1 |
6753454 | Smith et al. | Jun 2004 | B1 |
6821454 | Visca et al. | Nov 2004 | B2 |
6831142 | Mertens et al. | Dec 2004 | B2 |
6872275 | Ko et al. | Mar 2005 | B2 |
6889835 | Land | May 2005 | B2 |
6913145 | Barton | Jul 2005 | B2 |
6938767 | Gelmetti | Sep 2005 | B2 |
6977357 | Hsu et al. | Dec 2005 | B2 |
7004318 | Barton | Feb 2006 | B2 |
7108916 | Ehrnsperger et al. | Sep 2006 | B2 |
7147176 | Rexhaj | Dec 2006 | B2 |
7152735 | Dragoo et al. | Dec 2006 | B2 |
7156334 | Fore et al. | Jan 2007 | B1 |
7178755 | Hsu et al. | Feb 2007 | B2 |
7198152 | Barton et al. | Apr 2007 | B2 |
7220942 | Barton et al. | May 2007 | B2 |
7309038 | Carroscia | Dec 2007 | B2 |
7377388 | Hsu et al. | May 2008 | B2 |
7410111 | Carroscia | Aug 2008 | B2 |
7441657 | Gelmetti | Oct 2008 | B2 |
7441721 | Bae et al. | Oct 2008 | B2 |
7533906 | Luettgen et al. | May 2009 | B2 |
7563840 | Ye | Jul 2009 | B2 |
7950523 | Gelmetti | May 2011 | B2 |
20010014706 | Sprenger et al. | Aug 2001 | A1 |
20020000391 | Kawasai et al. | Jan 2002 | A1 |
20020003014 | Homma | Jan 2002 | A1 |
20020014477 | Lee et al. | Feb 2002 | A1 |
20020039869 | Achille | Apr 2002 | A1 |
20020120178 | Tartaglia et al. | Aug 2002 | A1 |
20030042162 | Land | Mar 2003 | A1 |
20030042163 | Cipriant | Mar 2003 | A1 |
20030052030 | Gelmetti | Mar 2003 | A1 |
20030184086 | Christianson | Oct 2003 | A1 |
20040020041 | Ferguson, III et al. | Feb 2004 | A1 |
20040050441 | Roschi | Mar 2004 | A1 |
20040133176 | Muthiah et al. | Jul 2004 | A1 |
20040155090 | B.-Jensen | Aug 2004 | A1 |
20040176557 | Mertens et al. | Sep 2004 | A1 |
20040186244 | Hatsuda et al. | Sep 2004 | A1 |
20040201117 | Anderson | Oct 2004 | A1 |
20040241333 | Cielenski et al. | Dec 2004 | A1 |
20040265387 | Hermeling et al. | Dec 2004 | A1 |
20050008776 | Chhabra et al. | Jan 2005 | A1 |
20050261461 | Maeda et al. | Nov 2005 | A1 |
20060027699 | Bae et al. | Feb 2006 | A1 |
20060074154 | Harashina et al. | Apr 2006 | A1 |
20060155254 | Sanz et al. | Jul 2006 | A1 |
20060247343 | Kishimoto et al. | Nov 2006 | A1 |
20060258824 | Oshima et al. | Nov 2006 | A1 |
20060278747 | Carroscia | Dec 2006 | A1 |
20070175786 | Nicklas | Aug 2007 | A1 |
20070272573 | Gelmetti | Nov 2007 | A1 |
20070284354 | Laymon | Dec 2007 | A1 |
20080156925 | Cooper | Jul 2008 | A1 |
20080257875 | De Keizer | Oct 2008 | A1 |
20080300349 | Fuchikami et al. | Dec 2008 | A1 |
20090014572 | Weissbrod et al. | Jan 2009 | A1 |
20090014579 | Bender et al. | Jan 2009 | A1 |
20090200284 | Sanchez | Aug 2009 | A1 |
20100116803 | Gelmetti | May 2010 | A1 |
20110073703 | Gelmetti et al. | Mar 2011 | A1 |
20110094911 | Gelmetti | Apr 2011 | A1 |
20110114523 | Gelmetti | May 2011 | A1 |
20110114617 | Gelmetti et al. | May 2011 | A1 |
20110132880 | Kossowan | Jun 2011 | A1 |
Number | Date | Country |
---|---|---|
1466469 | Feb 2004 | CN |
1626423 | Jun 2005 | CN |
1011840 | Jul 1957 | DE |
1082215 | Nov 1957 | DE |
1 154 624 | Aug 1960 | DE |
2122958 | Nov 1972 | DE |
2 148 348 | Apr 1973 | DE |
2202177 | Jul 1973 | DE |
2525938 | Dec 1976 | DE |
26 46 218 | Apr 1977 | DE |
28 16 100 | Oct 1978 | DE |
36 09 839 | Oct 1989 | DE |
19909214 | Mar 1999 | DE |
19958697 | Jun 1999 | DE |
199 10 128 | Apr 2001 | DE |
100 06 592 | Aug 2001 | DE |
10202839 | Jan 2002 | DE |
103 60 466 | Jul 2005 | DE |
102007015946 | Oct 2008 | DE |
2 267 255 | Apr 1974 | EP |
0408259 | Apr 1992 | EP |
0519424 | Dec 1992 | EP |
2 264 482 | Sep 1993 | EP |
584056 | Feb 1994 | EP |
0665 166 | Jan 1995 | EP |
0686439 | Dec 1995 | EP |
0806429 | Nov 1997 | EP |
1057751 | Dec 2000 | EP |
1 070 754 | Jan 2001 | EP |
1 275 595 | Jan 2003 | EP |
1 295 813 | Mar 2003 | EP |
1 471 024 | Oct 2004 | EP |
1 698 421 | Jun 2006 | EP |
1 974 846 | Jan 2008 | EP |
2 256 064 | Jan 2010 | EP |
2 168 706 | Mar 2010 | EP |
2 286 950 | Feb 2011 | EP |
1215111 | Apr 1960 | FR |
2055181 | May 1971 | FR |
2595674 | Mar 1988 | FR |
2 888 825 | Jan 2007 | FR |
880502 | Oct 1961 | GB |
1168928 | Oct 1969 | GB |
1229913 | Apr 1971 | GB |
1 575 157 | Sep 1980 | GB |
2059462 | Apr 1981 | GB |
2 332 451 | Jun 1999 | GB |
49-13065 | Feb 1974 | JP |
54-035842 | Mar 1979 | JP |
54-043856 | Apr 1979 | JP |
55-054295 | Apr 1980 | JP |
55-156694 | Dec 1980 | JP |
56-023376 | Mar 1981 | JP |
57-102471 | Jun 1982 | JP |
58-035068 | Mar 1983 | JP |
58-70384 | May 1983 | JP |
59-197386 | Nov 1984 | JP |
59-229287 | Dec 1984 | JP |
59-232669 | Dec 1984 | JP |
60-021181 | Feb 1985 | JP |
60-032281 | Feb 1985 | JP |
60-082275 | May 1985 | JP |
60-082276 | May 1985 | JP |
60-184422 | Sep 1985 | JP |
60-223664 | Nov 1985 | JP |
61-162541 | Jul 1986 | JP |
61-293674 | Dec 1986 | JP |
62-009774 | Jan 1987 | JP |
62-111872 | May 1987 | JP |
62-287055 | Dec 1987 | JP |
63-147781 | Jun 1988 | JP |
1-65265 | Apr 1989 | JP |
1-240222 | Sep 1989 | JP |
3-264169 | Nov 1991 | JP |
03264169 | Nov 1991 | JP |
4-112169 | Apr 1992 | JP |
04-133973 | May 1992 | JP |
4-274875 | Sep 1992 | JP |
5-178538 | Jul 1993 | JP |
7-247058 | Sep 1995 | JP |
8-40642 | Feb 1996 | JP |
08-150492 | Jun 1996 | JP |
08-267274 | Oct 1996 | JP |
2000-202630 | Jul 2000 | JP |
2000-225468 | Aug 2000 | JP |
2000-263239 | Sep 2000 | JP |
2001-26375 | Jan 2001 | JP |
2001-150187 | Jun 2001 | JP |
2001-323268 | Nov 2001 | JP |
2004-025242 | Jan 2004 | JP |
2004-025243 | Jan 2004 | JP |
2005-169499 | Jun 2005 | JP |
2007-927 | Jan 2007 | JP |
2007-29971 | Feb 2007 | JP |
2002-0077857 | Oct 2002 | KR |
793678 | Jan 1981 | RU |
1412830 | Jul 1988 | RU |
WO 8103319 | Nov 1981 | WO |
WO 8810230 | Dec 1988 | WO |
WO 94-00493 | Jan 1994 | WO |
WO 94-19258 | Sep 1994 | WO |
WO 9700878 | Jan 1997 | WO |
WO 9852844 | Nov 1998 | WO |
WO 00-50197 | Aug 2000 | WO |
WO 0127365 | Apr 2001 | WO |
WO 02094493 | Nov 2002 | WO |
WO 03-106096 | Dec 2003 | WO |
WO 2005005704 | Jan 2005 | WO |
WO 2005061168 | Jul 2005 | WO |
WO2006091075 | Aug 2006 | WO |
WO 2007010171 | Jan 2007 | WO |
WO 2007112972 | Oct 2007 | WO |
WO 2007149689 | Dec 2007 | WO |
WO 2009007845 | Jan 2009 | WO |
WO 2009143917 | Mar 2009 | WO |
Entry |
---|
U.S. Appl. No. 12/618,250, filed Nov. 13, 2009, Gelmetti et al. |
Office Action issued for related U.S. Appl. No. 12/618,250, dated Apr. 26, 2012 (11 pgs). |
“International Plastics Flammability Handbook” Jurgen Troitzsch, 2nd edition, 1990, pp. 33, 43-49 and 59. |
Chinese Official Action dated Mar. 17, 2010. |
EPO Office Action issued for related application No. 09753572.8, dated May 2, 2012 (5 pgs). |
European Office Action for corresponding application No. 10 014 553.1-2302, dated Apr. 3, 2012 (4 pgs). |
European Office Action issued for 09777298.2, dated Aug. 31, 2012 (4 pgs). |
European Search Report, dated Mar. 2, 2011 (7 pgs). |
European Search Report, dated Sep. 17, 2008. |
Hansen et al., “Water Absorption and Mechanical Properties of Electrospun Structured Hydrogels”, Journal of Applied Polymer Science, vol. 95, pp. 427-434 (2005). |
International Preliminary Report on Patentability issued for related application No. PCT/EP2009/001285, dated Nov. 30, 2010 (7 pgs). |
International Preliminary Report on Patentability, dated Sep. 16, 2010 (5 pgs). |
International Preliminary Report, PCT/IPEA/409, 7 pages. |
International Search Report and Written Opinion issued in corresponding PCT Appln. No. PCT/EP2009/005246, dated Apr. 6, 2010 (9 pgs). |
International Search Report issued in Applicants' underlying PCT Application Serial No. PCT/EP09/001285, dated Feb. 24, 2009 (3 pgs). |
International Search Report, dated Jul. 6, 2009 (3 pgs). |
Korean Official Action dated May 16, 2011, Appln. No. 2008-7005433, (3 pgs). |
PCT International Search Report, dated Nov. 6, 2008. |
Plaza et al., Preparation of ethylenebis(nitrilodimethylene)tetrakis(phenylphosphinic acid), Inorganic Synthesis, vol. 16, No. 199, abstract, one page. |
Search Report received in Applicant's counterpart European Patent Application Serial No. 08017572.2-2302. |
Search Report received in Applicant's counterpart European Patent Application Serial No. 10014216.5-1256 (8 pages), dated Apr. 14, 2011. |
Search Report received in Applicant's counterpart European Patent Application Serial No. 110008927-2302 (8 pages), dated Jul. 19, 2011. |
Search Report received in Applicant's counterpart European Patent Application Serial No. 11000236.7 (8 pages), dated Aug. 4, 2011. |
Ullmanns Encyclopedia of Industrial Chemistry, Sulfuric Acid & Sulfur Trioxide to Tetrahydrofuran, Superabsorbents, 6th Edition, vol. 35, pps. 73, 80, 86 and 89 (2003). |
US Official Action dated Feb. 13, 2012, issued in U.S. Appl. No. 12/917,320 (14 pgs). |