Welding wire guiding liner

Information

  • Patent Grant
  • 8389901
  • Patent Number
    8,389,901
  • Date Filed
    Thursday, May 27, 2010
    14 years ago
  • Date Issued
    Tuesday, March 5, 2013
    11 years ago
Abstract
A welding wire guiding liner has a plurality of guiding bodies connected to each other, each of the guiding bodies containing a plurality of rolling elements defining a guiding channel for the welding wire. Each guiding body has a ring which is coaxial with the guiding channel and is freely rotatable in a peripheral direction on the body. The ring is connected to the adjacent guiding body by means of a swivel joint which allows the adjacent guiding body to swivel around a swivel axis with respect to the guiding body provided with the ring.
Description

The invention relates to a liner for guiding welding wire with low friction.


BACKGROUND OF THE INVENTION

The use of welding automated processes in many industrial applications is increasingly growing. It is common practice for such technology to feed welding wires, sometimes at significantly high speed, from large bulk containers holding up to 1000 kgs of welding consumable, from the container to the wire feeder and subsequently from the wire feeder to the welding torch.


There are some general technical problems involved when welding wire is being fed over large distances. One issue is attrition which causes the welding wire to be fed intermittently and inconsistently, with consequent spatter and in most extreme cases, torch tip burn backs. Another issue is wire surface contamination. When a large quantity of welding wire is being fed through a liner, the drawing residues and lubricant which are normally present on the wire surface as a consequence of the wire drawing process, accumulate in the liner. Further, it must be ensured that there is no excessive wire deformation and cast bending which would result in the wire being fed deformed to the welding torch, with consequent unreliable weld placements. Finally, wire surface scratching must be prevented, as otherwise the copper coating would be scraped off the wire surface which would result in inconsistent bad electrical contact at the torch tip.


There are some welding wire guides which aim at solving these issues. One example can be found in FR 2 888 825 A1 which discloses a welding wire guide which consists of two guiding bodies placed in an alternating pattern. In a first guiding body, a first set of rolling elements is arranged which guide the welding wire in a first direction. In the second guiding body, a second set of rolling elements is provided which guide the welding wire in a second direction. It is only the combination of a first and a second guiding body which defines a complete guiding channel for the welding wire. As the first set of rolling elements is spaced from the second set of rolling elements, the welding wire can touch the guiding bodies when the guiding liner is curved, resulting in increased friction and wear.


WO 2009/143917 A1 discloses a welding wire liner which consists of a plurality of liner bodies connected to each other by means of a pivot connection. Each liner body comprises a set of rolling elements which guide the wire without friction.


EP 1 974 846 A2 discloses a welding wire liner which consists of a plurality of liner bodies connected to each other by means of a ball joint. This allows the bodies to swivel in any direction with respect to the previous body. Further, the bodies can be rotated with respect to each other, which allows using the liner for feeding the welding wire to a welding torch. In view of the particular configuration of the joints between adjacent liner bodies, the ability of withstanding torsional loads has proven to be limited. Modern multiple axis welding robots move in all directions and rotate the welding torch in some cases more than 360° and must be capable of doing so without any restriction. This movement results in tension being built up, caused by the swift and sharp movements in all directions which eventually causes the wire guiding liner assemblies to snap and break apart. If the wire guiding liner is tensioned by the robot movements and cannot adequately and quickly stretch out to follow and match the robot arm rapid movements, it represents an obstacle to the continuous and correct robot performance and in most cases, when damaged, it requires the welding operator to either repair or replace it, with unwanted costly stops and losses of production.


Our earlier patent application U.S. Ser. No. 12/618,250 addresses the issue of torsional loads by using swivel connections at discrete intervals along the liner. These swivel connections allow to discharge any tension which might have resulted from the movements of the welding torch to which the liner is fitted. However, each swivel connection forms an interruption of the guiding liner.


The object of the invention is to provide a welding wire guiding liner which fulfills the requirements regarding a reliable, smooth and low-friction guiding of the welding wire, and in addition allows rotational movements of a welding torch without creating excessive torsional loads in the liner.


BRIEF DESCRIPTION OF THE INVENTION

In order to achieve the above objects, a welding wire guiding liner is provided which has a plurality of guiding bodies connected to each other. Each of the guiding bodies contains a plurality of rolling elements defining a guiding channel for the welding wire. Each guiding body has a ring which is coaxial with the guiding channel and is freely rotatable in a peripheral direction on the body. The ring is connected to the adjacent guiding body by means of a swivel joint which allows the adjacent guiding body to swivel around a swivel axis with respect to the guiding body provided with the ring. This liner is based on the idea of combining the articulation between adjacent guiding bodies with the freedom of rotation between adjacent guiding bodies. A simple mechanical element is sufficient for achieving articulation and rotation, namely the ring which forms a swivel joint with the adjacent guiding body while being rotatably arranged on “its” guiding body.


According to a preferred embodiment, the swivel joint is formed by two connecting lugs on the ring which each have an opening into which swivel studs engage which are provided on the adjacent guiding body. This results in a reliable mechanical connection which can be easily assembled.


Preferably, each of the guiding bodies is provided with a peripheral groove which accommodates the ring. The groove is a simple means for holding the ring in a manner which allows rotation while preventing the ring from becoming disengaged from the guiding body.


According a preferred embodiment, each of the guiding bodies is provided with a holding element which accommodates the rolling elements, and a cover element in the interior of which the holding element is placed. This allows to assemble the liner with very few steps by placing the rolling elements in the holding element and then placing the cover element over the holding element whereby the rolling elements are fixed in their position in the holding element.


Preferably, the cover element has a skirt which is provided with a plurality of slots extending in parallel with the guiding channel in the interior of the guiding body, and an enlarged rim portion behind which the ring is placed. The slots allow the skirt to elastically shrink when the ring is pushed over the enlarged rim and to return to the previous condition, thereby fixing the ring on the skirt.


Preferably, the holding element is placed within the skirt so as to support the skirt in a radial direction. This prevents that the skirt unintentionally shrinks or collapses when high loads act on the ring, thereby preventing the ring from becoming detached from the skirt.


According to a preferred embodiment, an elastic ring is provided between adjacent guiding bodies. The elastic ring keeps the liner in a stretched condition which facilitates inserting the welding wire.


Preferably, each guiding body is provided with an accommodation groove for the elastic ring at one end face and an abutment surface at the opposite end face. The groove ensures that the ring is maintained at its proper location without additional measures being necessary.


The welding wire guiding liner can be provided with an outer protective hose which is made from a flexible material selected from a group comprising rubber, EPDM, silicon, cloth, polyamide, and aramid fibers. This prevents that dirt and other contamination can enter the guiding channel for the welding wire.





BRIEF DESCRIPTION OF THE DRAWINGS

The invention will now be explained in detail with reference to the enclosed drawings. In the drawings,



FIG. 1 shows a general, schematic view of the liner used for guiding welding wire to and in a welding robot;



FIG. 2 shows a perspective view of the liner;



FIG. 3 shows another, partially cut view of the liner shown in FIG. 2;



FIG. 4 shows in an enlarged scale detail IV of FIG. 3;



FIG. 5 shows a cover element used in the liner of FIG. 2 in a sectional view;



FIG. 6 shows the cover element of FIG. 5 in a top view;



FIG. 7 shows the cover element in a side view;



FIG. 8 shows the cover element in a bottom view;



FIG. 9 shows the cover element in a perspective view;



FIG. 10 shows a ring used in the liner of FIG. 2 in a side view;



FIG. 11 shows the ring of FIG. 10 in a sectional view;



FIG. 12 shows the ring in another side view;



FIG. 13 shows the ring in a perspective view;



FIG. 14 shows a holding element used in the liner of FIG. 2 in a top view;



FIG. 15 shows the holding element of FIG. 14 in a side view;



FIG. 16 shows the holding element in a bottom view;



FIG. 17 shows the holding element in a sectional view;



FIG. 18 shows the holding element in a perspective view;



FIG. 19 shows a rolling element used in the liner of FIG. 2 in a first side view;



FIG. 20 shows the rolling element of FIG. 19 in a second side view;



FIG. 21 shows the rolling element in a perspective view;



FIG. 22 shows an elastic ring used in the liner of FIG. 2 in a side view;



FIG. 23 shows the ring of FIG. 22 in a top view;



FIG. 24 shows the ring in a perspective view;



FIG. 25 shows the holding element equipped with four rolling elements in a perspective view;



FIG. 26 shows the holding element of FIG. 25 in a side view;



FIG. 27 shows the holding element of FIG. 25 in a top view;



FIG. 28 shows the cover element equipped with the ring in a perspective view;



FIG. 29 shows the cover element of FIG. 28 assembled with the holding element of FIG. 25; and



FIG. 30 shows the guiding body of FIG. 29 in a sectional view.





DETAILED DESCRIPTION OF THE INVENTION

In FIG. 1, a welding robot 1 is schematically shown, which is supplied with welding wire 2 from a container 3. Welding wire container 3 is situated in a distance from welding robot 1 at a place which is easily accessible with for example a fork lift. In order to guide welding wire 2 with low friction from container 3 to welding robot 1, a welding wire guiding liner 4 is provided which is used for guiding the welding wire from the container towards welding robot 1 and to a certain point on the welding robot, e.g. to a wire feeder 9. From this point toward a welding torch 5, a second welding wire guiding liner 6 is used. At the place where liner segment 4 is connected to welding robot 1, a termination 8 is used. Along the welding robot, the welding wire guide 6 is used which extends from a termination 8 at wire feeder 9 to a place close to welding torch 5. At the wire feeder 9, electric current, gas, etc. can be introduced into liner 6.


The liner is composed of a plurality of guiding bodies 10 (please see in particular FIGS. 2, 3 and 29, 30) which in turn each comprises a cover element 20 (please see in particular FIGS. 5 to 9), a ring 40 (please see in particular FIGS. 10 to 13) and a holding element 50 (please see in particular FIGS. 14 to 18).


Cover element 20 is generally cup-like with a generally circular plate 22 having a central opening 23, and a generally cylindrical skirt 24 which extends from plate 22. Skirt 24 defines an inner accommodation space 26 in which holding element 50 can be placed. At regularly spaced intervals, skirt 24 is provided with slots 28 which extend from the free end of skirt 24 towards plate 22, but which end at a distance before plate 24. Furthermore, skirt 24 is provided with an enlarged rim portion 30 so that a groove 32 is formed which extends around the entire skirt 24. The side of rim portion 30 which faces away from plate 22 is formed with a smooth, rounded contour (please see in particular FIG. 5).


Groove 32 is defined in the side opposite rim portion 30 by an enlarged base portion of skirt 24, with which the skirt merges into plate 22. As can be seen in particular in FIG. 7, slots 28 extend over the entire rim portion 30 and through groove 32, but end at the side of the groove which is oriented towards plate 22. Slots 28 confer to skirt 24 a certain elasticity as it allows the individual segments of the skirt to deflect inwardly.


Plate 22 is provided with four swivel studs 34 which are equally distributed around the perimeter of cover element 20. Seen in a radial direction, each swivel stud 34 has a circular cross-section (please see in particular FIG. 7). On the side facing away from rim portion 30, each swivel stud 34 is provided with a chamfer 36 which reduces the “height” of the swivel stud on the side which faces away from skirt 24.


Plate 22 features an accommodation groove 38 on its side facing away from skirt 24. As can be seen in particular in FIG. 6, accommodation groove 38 is coaxial with respect to a central axis C of the cover element.


Ring 40 has a generally rectangular cross-section (please see FIG. 11) and is provided with two connecting lugs 42 which are each provided with an opening 44. The inner edge of ring 40 on the side facing away from connecting lugs 42 is provided with a smooth, rounded contour (please see in particular FIG. 11). The inner diameter of ring 40 corresponds to the diameter of groove 32, while the height of the ring corresponds to the width of groove 32. Further, the diameter of openings 44 in connecting lugs 42 of ring 40 corresponds to the diameter of swivel studs 34 of cover element 20.


Holding element 50 is formed from a plate-like base 52 from which four support blocks 54 extend. Each support block 54 is provided with two recesses 56 which are arranged such that they lie opposite each other in pairs. Between adjacent support blocks 54, an accommodation space 58 for rolling elements 70 (please see FIGS. 19 to 21) is formed.


Base 52 is provided with four positioning projections 60 which are equally spaced from each other. The width of each positioning projection 60 corresponds to the width of slots 28 in cover element 20. Furthermore, the contour of the positioning projections 60 on their side facing away from supporting blocks 54 is rounded in the same way the enlarged rim portion 60 is shaped.


Cover element 20, ring 40 and holding element 50 are formed from a plastic material, in particular from polyamide. Rolling element 70 can also be formed from plastic. In the alternative, they can be formed from metal. For mounting the rolling elements in holding element 50, short bearing pins 72 (please see FIGS. 25 and 27) are used which extend through a central hole 74 of the respective rolling element 70. The bearing pins 72 each rest in one of the accommodation spaces 58 in support blocks 54 such that the rolling elements together form a closed guiding channel 80 for the welding wire as the rolling elements almost touch each other.


For assembling the wire guiding liner, a first step consists in placing ring 40 in groove 32 of cover element 20. To this end, the ring is simply pushed onto the skirt which elastically yields inwardly so that the ring can be pushed over rim portion 30. This is facilitated by the smooth, rounded contour of the outer edge of the rim portion and the respective edge of the ring. As soon as the ring is situated in the groove, the four sections of the skirt snap back into their original position so that ring 40 is safely held behind rim portion 30 in groove 32 (please see FIG. 28). In this condition, connecting lugs 42 project over rim portion 30 in a direction away from plate 22.


In a second step, the holding element equipped with the rolling elements 70 is pushed into the accommodation space 26 of the cover element provided with ring 40. The positioning projections 60 of the holding element come to lie in slots 28 in skirt 24 so as to “close” the slots (please see FIG. 29). Further, the support blocks 54 and the base 52 of holding element 50 have a diameter which corresponds to the diameter of accommodation space 26. Accordingly, the holding element acts as an internal support for skirt 24 which prevents the sections of the skirt from becoming deflected inwardly. This guarantees that ring 40 cannot disengage from groove 32 in cover element 20.


In a next step, an elastic ring 82 (please see FIGS. 22 to 24) is placed in accommodation groove 38 of holding element 20.


In a last assembly step, connecting lugs 42 of one of the so assembled guiding bodies is pushed over the swivel studs 34 of another guiding body. This is facilitated by the chamfers 36 provided on swivel studs 34. As soon as swivel studs 34 are positioned within openings 44 in connecting lugs 42 of ring 40, the connecting lugs return into their original position so that a swivel joint is formed from the swivel studs 34 engaging into openings 44. In this condition, elastic ring 82 of a “lower” guiding body 10 is held compressed against the “lower” abutment surface of the “upper” guiding body connected to the “lower” guiding body (please see FIG. 3). Furthermore, the “lower” guiding body 10 holds holding element 50 of the “upper” guiding body 10 in place in accommodation space 26 of cover element 20 of the “upper” guiding body 10. As the lower abutment surface of each holding element 50 is formed curved, a smooth swivel movement of the guiding bodies with respect to each other is possible, while a continuous, biasing contact between the elastic ring 82 and the respective surfaced is maintained. Elastic ring 82 both biases the wire guiding liner in a longitudinal direction and seals the guiding channel 80 in the interior from external contaminations. As ring 40 can freely turn in groove 32 of the respective guiding body, the two ends of a liner formed from a plurality of interconnected guiding bodies can be turned with respect to each other without the risk that a tensional load is being built up in the liner. In this regard, the ring serves for several purposes. First, it is part of the swivel joint which allows a swiveling movement of the respective bodies with respect to each other. Second, it allows the guiding bodies to rotate with respect to each other. Still further, the rings holds adjacent guiding bodies connected to each other while at the same time locking the holding element 50 in the interior of the respective cover element 20.


It should be clear that only two of the four swivel studs 34 of a cover element 20 are required for forming the liner. The two “unused” swivel studs 34 at the first and last guiding body 10, respectively, of the liner can be used for connecting the liner to termination 8.


Since the rolling elements 70, as viewed in a longitudinal direction, are arranged close to each other while the degree of swivel movement between adjacent guiding bodies is limited, the welding wire can easily be fed through the wire guiding liner even when it is held in a curved condition. The welding wire can travel through the liner in both directions.


Even though the skirt is shown as circular, it could also have a polygonal contour. Vice versa, the ring could also have a polygonal contour while the skirt is formed with a round contour. In any case, it must be ensured that the ring can smoothly rotate on the respective guiding body.


In practice, the guiding liner can be employed in a length of several dozen meters. The actual length can easily be adapted to the particular requirements by assembling the required number of guiding bodies. If desired, an outer protective hose can be employed, which could be formed from rubber, a plastics material or aramid fibers.

Claims
  • 1. Welding wire guiding liner, having a plurality of like guiding bodies directly connected to each other, each of the guiding bodies containing a plurality of rolling elements defining a guiding channel for the welding wire, each guiding body having a ring which is coaxial with the guiding channel and is freely rotatable in a peripheral direction on the body, the ring being connected to the adjacent guiding body by a swivel joint which allows the adjacent guiding body to swivel around a swivel axis with respect to the guiding body provided with the ring.
  • 2. The welding wire guiding liner of claim 1 wherein the swivel joint is formed by two connecting lugs on the ring which each have an opening into which swivel studs engage which are provided on the adjacent guiding body.
  • 3. The welding wire guiding liner of claim 1 wherein each of the guiding bodies is provided with a peripheral groove which accommodates the ring.
  • 4. The welding wire guiding liner of claim 1 wherein each of the guiding bodies is provided with a holding element which accommodates the rolling elements, and a cover element in the interior of which the holding element is placed.
  • 5. The welding wire guiding liner of claim 4 wherein the cover element has a skirt which is provided with a plurality of slots extending in parallel with the guiding channel in the interior of the guiding body, and an enlarged rim portion behind which the ring is placed.
  • 6. The welding wire guiding liner of claim 5 wherein the holding element is placed within the skirt so as to support the skirt in a radial direction.
  • 7. The welding wire guiding liner of claim 1 wherein an elastic ring is provided between adjacent guiding bodies.
  • 8. The welding wire guiding liner of claim 1 wherein each guiding body is provided with an accommodation groove for the elastic ring at one end face and an abutment surface at the opposite end face.
  • 9. The welding wire guiding liner of claim 1 wherein an outer protective hose is provided which is made from a flexible material selected from a group consisting of rubber, EPDM, silicon, cloth, polyamide, and aramid fibers.
US Referenced Citations (228)
Number Name Date Kind
318062 Warren May 1885 A
532565 Kilmer Jan 1895 A
617353 Redmond Jan 1899 A
627722 Edwards Jun 1899 A
932808 Pelton Aug 1909 A
1276117 Riebe Aug 1918 A
1468994 Cook Sep 1923 A
1640368 Obetz Aug 1927 A
1907051 Emery May 1933 A
2027670 Broeren Jan 1936 A
2027674 Broeren Jan 1936 A
2059462 Jungmann Nov 1936 A
2329369 Haver Sep 1943 A
2407746 Johnson Sep 1946 A
2457910 McLaren et al. Jan 1949 A
2477059 Hill Jul 1949 A
2483760 Duncan Oct 1949 A
2579131 Tinsley Dec 1951 A
2580900 Epstein Jan 1952 A
2694130 Howard Nov 1954 A
2713938 Snyder Jul 1955 A
2724538 Schweich Nov 1955 A
2838922 Gift Jun 1958 A
2849195 Richardson Aug 1958 A
2864565 Whearly Dec 1958 A
2869719 Hubbard Jan 1959 A
2880305 Baird Mar 1959 A
2911166 Haugwitz Nov 1959 A
2929576 Henning Mar 1960 A
2966258 Krafft Dec 1960 A
2974850 Mayer Mar 1961 A
2984596 Franer May 1961 A
3096951 Jenson Jul 1963 A
3119042 Bond Jan 1964 A
3185185 Pfund May 1965 A
3244347 Jenk Apr 1966 A
3274850 Tascio Sep 1966 A
3344682 Bratz Oct 1967 A
3352412 Draving et al. Nov 1967 A
3433504 Hanes Mar 1969 A
3463416 Quenot Aug 1969 A
3478435 Cook Nov 1969 A
3491876 Zecchin Jan 1970 A
3512635 Lang May 1970 A
3565129 Field Feb 1971 A
3567900 Nelson Mar 1971 A
3576966 Sullivan May 1971 A
3595277 Lefever Jul 1971 A
3648920 Stump Mar 1972 A
3724249 Asbeck et al. Apr 1973 A
3729092 Marcell Apr 1973 A
3730136 Okada May 1973 A
3799215 Willems Mar 1974 A
3815842 Scrogin Jun 1974 A
3823894 Frederick et al. Jul 1974 A
3939978 Thomaswick Feb 1976 A
4043331 Martin et al. Aug 1977 A
4044583 Kinney, Jr. Aug 1977 A
4074105 Minehisa et al. Feb 1978 A
4097004 Reese Jun 1978 A
4102483 Ueyama et al. Jul 1978 A
4113795 Izawa et al. Sep 1978 A
4127590 Endo et al. Nov 1978 A
4157436 Endo et al. Jun 1979 A
4161248 Kalmanovitch Jul 1979 A
4172375 Rushforth et al. Oct 1979 A
4188526 Asano Feb 1980 A
4222535 Hosbein Sep 1980 A
4254322 Asano Mar 1981 A
4274607 Priest Jun 1981 A
4280951 Saito et al. Jul 1981 A
4293103 Tsukamoto Oct 1981 A
4354487 Oczkowski et al. Oct 1982 A
4392606 Fremion Jul 1983 A
4396797 Sakuragi et al. Aug 1983 A
4429001 Kolpin et al. Jan 1984 A
4451014 Kitt et al. May 1984 A
4464919 Labbe Aug 1984 A
4500315 Pieniak et al. Feb 1985 A
4540225 Johnson et al. Sep 1985 A
4546631 Eisinger Oct 1985 A
4582198 Ditton Apr 1986 A
4585487 Destree et al. Apr 1986 A
4623063 Balkin Nov 1986 A
4737567 Matsumoto et al. Apr 1988 A
4742088 Kim May 1988 A
4826497 Marcus et al. May 1989 A
4855179 Bourland et al. Aug 1989 A
4869367 Kawasaki et al. Sep 1989 A
4891493 Sato et al. Jan 1990 A
4949567 Corbin Aug 1990 A
4974789 Milburn Dec 1990 A
5051539 Leathers-Wiessner Sep 1991 A
5061259 Goldman et al. Oct 1991 A
5078269 Dekko et al. Jan 1992 A
5100397 Poccia et al. Mar 1992 A
5105943 Lesko et al. Apr 1992 A
5109983 Malone et al. May 1992 A
5147646 Graham Sep 1992 A
5201419 Hayes Apr 1993 A
5205412 Krieg Apr 1993 A
5215338 Kimura et al. Jun 1993 A
5227314 Brown et al. Jul 1993 A
5261625 Lanoue Nov 1993 A
5277314 Cooper et al. Jan 1994 A
5314111 Takaku et al. May 1994 A
5368245 Fore Nov 1994 A
5372269 Sutton et al. Dec 1994 A
5452841 Sibata et al. Sep 1995 A
5485968 Fujioka Jan 1996 A
5494160 Gelmetti Feb 1996 A
5530088 Sheen et al. Jun 1996 A
5553810 Bobeczko Sep 1996 A
5562646 Goldman et al. Oct 1996 A
5585013 Truty Dec 1996 A
5586733 Miura et al. Dec 1996 A
5590848 Shore et al. Jan 1997 A
5629377 Burgert et al. May 1997 A
5665801 Chang et al. Sep 1997 A
5692700 Bobeczko Dec 1997 A
5714156 Schmidt et al. Feb 1998 A
5738209 Burr et al. Apr 1998 A
5739704 Clark Apr 1998 A
5746380 Chung May 1998 A
5816466 Seufer Oct 1998 A
5819934 Cooper Oct 1998 A
5845862 Cipriani Dec 1998 A
5847184 Kleiner Dec 1998 A
5865051 Otzen et al. Feb 1999 A
5921391 Ortiz et al. Jul 1999 A
5931408 Ishii et al. Aug 1999 A
5971308 Boulton Oct 1999 A
5988370 Roemer et al. Nov 1999 A
5990377 Chen et al. Nov 1999 A
6016911 Chen Jan 2000 A
6019303 Cooper Feb 2000 A
6103358 Bruggemann et al. Aug 2000 A
6159591 Beihoffer et al. Dec 2000 A
6237768 Cipriani May 2001 B1
6245880 Takeuchi et al. Jun 2001 B1
6255371 Schlosser et al. Jul 2001 B1
6260781 Cooper Jul 2001 B1
6301944 Offer Oct 2001 B1
6322016 Jacobsson et al. Nov 2001 B1
6340522 Burke et al. Jan 2002 B1
6408888 Baumer et al. Jun 2002 B1
6417425 Whitmore et al. Jul 2002 B1
6425549 Bae et al. Jul 2002 B1
6441067 Chiu et al. Aug 2002 B1
6464077 Liu Oct 2002 B1
6498227 Horie Dec 2002 B1
6547176 Blain et al. Apr 2003 B1
6564943 Barton et al. May 2003 B2
6613848 Wang et al. Sep 2003 B1
6636776 Barton et al. Oct 2003 B1
6648141 Land Nov 2003 B2
6649870 Barton et al. Nov 2003 B1
6708864 Ferguson, III et al. Mar 2004 B2
6715608 Moore Apr 2004 B1
6745899 Barton Jun 2004 B1
6749139 Speck Jun 2004 B2
6750262 Hahnle et al. Jun 2004 B1
6753454 Smith et al. Jun 2004 B1
6821454 Visca et al. Nov 2004 B2
6831142 Mertens et al. Dec 2004 B2
6872275 Ko et al. Mar 2005 B2
6889835 Land May 2005 B2
6913145 Barton Jul 2005 B2
6938767 Gelmetti Sep 2005 B2
6977357 Hsu et al. Dec 2005 B2
7004318 Barton Feb 2006 B2
7108916 Ehrnsperger et al. Sep 2006 B2
7147176 Rexhaj Dec 2006 B2
7152735 Dragoo et al. Dec 2006 B2
7156334 Fore et al. Jan 2007 B1
7178755 Hsu et al. Feb 2007 B2
7198152 Barton et al. Apr 2007 B2
7220942 Barton et al. May 2007 B2
7309038 Carroscia Dec 2007 B2
7377388 Hsu et al. May 2008 B2
7410111 Carroscia Aug 2008 B2
7441657 Gelmetti Oct 2008 B2
7441721 Bae et al. Oct 2008 B2
7533906 Luettgen et al. May 2009 B2
7563840 Ye Jul 2009 B2
7950523 Gelmetti May 2011 B2
20010014706 Sprenger et al. Aug 2001 A1
20020000391 Kawasai et al. Jan 2002 A1
20020003014 Homma Jan 2002 A1
20020014477 Lee et al. Feb 2002 A1
20020039869 Achille Apr 2002 A1
20020120178 Tartaglia et al. Aug 2002 A1
20030042162 Land Mar 2003 A1
20030042163 Cipriant Mar 2003 A1
20030052030 Gelmetti Mar 2003 A1
20030184086 Christianson Oct 2003 A1
20040020041 Ferguson, III et al. Feb 2004 A1
20040050441 Roschi Mar 2004 A1
20040133176 Muthiah et al. Jul 2004 A1
20040155090 B.-Jensen Aug 2004 A1
20040176557 Mertens et al. Sep 2004 A1
20040186244 Hatsuda et al. Sep 2004 A1
20040201117 Anderson Oct 2004 A1
20040241333 Cielenski et al. Dec 2004 A1
20040265387 Hermeling et al. Dec 2004 A1
20050008776 Chhabra et al. Jan 2005 A1
20050261461 Maeda et al. Nov 2005 A1
20060027699 Bae et al. Feb 2006 A1
20060074154 Harashina et al. Apr 2006 A1
20060155254 Sanz et al. Jul 2006 A1
20060247343 Kishimoto et al. Nov 2006 A1
20060258824 Oshima et al. Nov 2006 A1
20060278747 Carroscia Dec 2006 A1
20070175786 Nicklas Aug 2007 A1
20070272573 Gelmetti Nov 2007 A1
20070284354 Laymon Dec 2007 A1
20080156925 Cooper Jul 2008 A1
20080257875 De Keizer Oct 2008 A1
20080300349 Fuchikami et al. Dec 2008 A1
20090014572 Weissbrod et al. Jan 2009 A1
20090014579 Bender et al. Jan 2009 A1
20090200284 Sanchez Aug 2009 A1
20100116803 Gelmetti May 2010 A1
20110073703 Gelmetti et al. Mar 2011 A1
20110094911 Gelmetti Apr 2011 A1
20110114523 Gelmetti May 2011 A1
20110114617 Gelmetti et al. May 2011 A1
20110132880 Kossowan Jun 2011 A1
Foreign Referenced Citations (115)
Number Date Country
1466469 Feb 2004 CN
1626423 Jun 2005 CN
1011840 Jul 1957 DE
1082215 Nov 1957 DE
1 154 624 Aug 1960 DE
2122958 Nov 1972 DE
2 148 348 Apr 1973 DE
2202177 Jul 1973 DE
2525938 Dec 1976 DE
26 46 218 Apr 1977 DE
28 16 100 Oct 1978 DE
36 09 839 Oct 1989 DE
19909214 Mar 1999 DE
19958697 Jun 1999 DE
199 10 128 Apr 2001 DE
100 06 592 Aug 2001 DE
10202839 Jan 2002 DE
103 60 466 Jul 2005 DE
102007015946 Oct 2008 DE
2 267 255 Apr 1974 EP
0408259 Apr 1992 EP
0519424 Dec 1992 EP
2 264 482 Sep 1993 EP
584056 Feb 1994 EP
0665 166 Jan 1995 EP
0686439 Dec 1995 EP
0806429 Nov 1997 EP
1057751 Dec 2000 EP
1 070 754 Jan 2001 EP
1 275 595 Jan 2003 EP
1 295 813 Mar 2003 EP
1 471 024 Oct 2004 EP
1 698 421 Jun 2006 EP
1 974 846 Jan 2008 EP
2 256 064 Jan 2010 EP
2 168 706 Mar 2010 EP
2 286 950 Feb 2011 EP
1215111 Apr 1960 FR
2055181 May 1971 FR
2595674 Mar 1988 FR
2 888 825 Jan 2007 FR
880502 Oct 1961 GB
1168928 Oct 1969 GB
1229913 Apr 1971 GB
1 575 157 Sep 1980 GB
2059462 Apr 1981 GB
2 332 451 Jun 1999 GB
49-13065 Feb 1974 JP
54-035842 Mar 1979 JP
54-043856 Apr 1979 JP
55-054295 Apr 1980 JP
55-156694 Dec 1980 JP
56-023376 Mar 1981 JP
57-102471 Jun 1982 JP
58-035068 Mar 1983 JP
58-70384 May 1983 JP
59-197386 Nov 1984 JP
59-229287 Dec 1984 JP
59-232669 Dec 1984 JP
60-021181 Feb 1985 JP
60-032281 Feb 1985 JP
60-082275 May 1985 JP
60-082276 May 1985 JP
60-184422 Sep 1985 JP
60-223664 Nov 1985 JP
61-162541 Jul 1986 JP
61-293674 Dec 1986 JP
62-009774 Jan 1987 JP
62-111872 May 1987 JP
62-287055 Dec 1987 JP
63-147781 Jun 1988 JP
1-65265 Apr 1989 JP
1-240222 Sep 1989 JP
3-264169 Nov 1991 JP
03264169 Nov 1991 JP
4-112169 Apr 1992 JP
04-133973 May 1992 JP
4-274875 Sep 1992 JP
5-178538 Jul 1993 JP
7-247058 Sep 1995 JP
8-40642 Feb 1996 JP
08-150492 Jun 1996 JP
08-267274 Oct 1996 JP
2000-202630 Jul 2000 JP
2000-225468 Aug 2000 JP
2000-263239 Sep 2000 JP
2001-26375 Jan 2001 JP
2001-150187 Jun 2001 JP
2001-323268 Nov 2001 JP
2004-025242 Jan 2004 JP
2004-025243 Jan 2004 JP
2005-169499 Jun 2005 JP
2007-927 Jan 2007 JP
2007-29971 Feb 2007 JP
2002-0077857 Oct 2002 KR
793678 Jan 1981 RU
1412830 Jul 1988 RU
WO 8103319 Nov 1981 WO
WO 8810230 Dec 1988 WO
WO 94-00493 Jan 1994 WO
WO 94-19258 Sep 1994 WO
WO 9700878 Jan 1997 WO
WO 9852844 Nov 1998 WO
WO 00-50197 Aug 2000 WO
WO 0127365 Apr 2001 WO
WO 02094493 Nov 2002 WO
WO 03-106096 Dec 2003 WO
WO 2005005704 Jan 2005 WO
WO 2005061168 Jul 2005 WO
WO2006091075 Aug 2006 WO
WO 2007010171 Jan 2007 WO
WO 2007112972 Oct 2007 WO
WO 2007149689 Dec 2007 WO
WO 2009007845 Jan 2009 WO
WO 2009143917 Mar 2009 WO
Non-Patent Literature Citations (25)
Entry
U.S. Appl. No. 12/618,250, filed Nov. 13, 2009, Gelmetti et al.
Office Action issued for related U.S. Appl. No. 12/618,250, dated Apr. 26, 2012 (11 pgs).
“International Plastics Flammability Handbook” Jurgen Troitzsch, 2nd edition, 1990, pp. 33, 43-49 and 59.
Chinese Official Action dated Mar. 17, 2010.
EPO Office Action issued for related application No. 09753572.8, dated May 2, 2012 (5 pgs).
European Office Action for corresponding application No. 10 014 553.1-2302, dated Apr. 3, 2012 (4 pgs).
European Office Action issued for 09777298.2, dated Aug. 31, 2012 (4 pgs).
European Search Report, dated Mar. 2, 2011 (7 pgs).
European Search Report, dated Sep. 17, 2008.
Hansen et al., “Water Absorption and Mechanical Properties of Electrospun Structured Hydrogels”, Journal of Applied Polymer Science, vol. 95, pp. 427-434 (2005).
International Preliminary Report on Patentability issued for related application No. PCT/EP2009/001285, dated Nov. 30, 2010 (7 pgs).
International Preliminary Report on Patentability, dated Sep. 16, 2010 (5 pgs).
International Preliminary Report, PCT/IPEA/409, 7 pages.
International Search Report and Written Opinion issued in corresponding PCT Appln. No. PCT/EP2009/005246, dated Apr. 6, 2010 (9 pgs).
International Search Report issued in Applicants' underlying PCT Application Serial No. PCT/EP09/001285, dated Feb. 24, 2009 (3 pgs).
International Search Report, dated Jul. 6, 2009 (3 pgs).
Korean Official Action dated May 16, 2011, Appln. No. 2008-7005433, (3 pgs).
PCT International Search Report, dated Nov. 6, 2008.
Plaza et al., Preparation of ethylenebis(nitrilodimethylene)tetrakis(phenylphosphinic acid), Inorganic Synthesis, vol. 16, No. 199, abstract, one page.
Search Report received in Applicant's counterpart European Patent Application Serial No. 08017572.2-2302.
Search Report received in Applicant's counterpart European Patent Application Serial No. 10014216.5-1256 (8 pages), dated Apr. 14, 2011.
Search Report received in Applicant's counterpart European Patent Application Serial No. 110008927-2302 (8 pages), dated Jul. 19, 2011.
Search Report received in Applicant's counterpart European Patent Application Serial No. 11000236.7 (8 pages), dated Aug. 4, 2011.
Ullmanns Encyclopedia of Industrial Chemistry, Sulfuric Acid & Sulfur Trioxide to Tetrahydrofuran, Superabsorbents, 6th Edition, vol. 35, pps. 73, 80, 86 and 89 (2003).
US Official Action dated Feb. 13, 2012, issued in U.S. Appl. No. 12/917,320 (14 pgs).