Claims
- 1. A wholly aromatic polyester comprising the units (1)-(5) ##STR8## wherein Ar is at least one member selected from a divalent substituted mononuclear aromatic radical of the formula ##STR9## wherein X is independently hydrogen, a C.sub.1 to C.sub.5 alkyl group, a halide atom or an aryl group; with the proviso that when the valence bonds are para to each other at least one group X must be other than hydrogen; a divalent dinuclear aromatic radical of the formula ##STR10## wherein X is as previously defined and Q is at least one member selected from the group consisting of a chemical bond O, S, SO, S--S, SO.sub.2, and CO; and a divalent naphthalene radical of the formula ##STR11## or isomers thereof and wherein a+b is approximately equal to d+e; the ratio of a to b being in the range of from about 1:4:1 to about 10:1; the ratio of d to e being in the range of from about 4:1 to about 21:1; and c being in the range of from about 0.6 to about 7, based on the total number of moles of a+b.
- 2. A wholly aromatic polyester as defined in claim 1 which has a melting point of at least about 260.degree. C., a heat distortion temperature of at least about 200.degree. C. when measured under a load of 264 psi, and which yields molded articles having good surface characteristics.
- 3. A process for preparing the polyester of claim 1 which comprises reacting terephthalic acid, isophthalic acid, p-hydroxybenzoic acid, hydroquinone, and an arylene diol with an anhydride of a lower monocarboxylic acid to form a prepolymer; followed by solid state advancement of said prepolymer to the desired high molecular weight polyester.
- 4. A wholly aromatic polyester as defined in claim 1 wherein the group Ar consists essentially of biphenylene.
- 5. A wholly aromatic polyester as defined in claim 1 wherein the group Ar consists essentially of at least one member selected from ##STR12## wherein Y is methyl, chlorine, t-butyl or phenyl.
- 6. A wholly aromatic polyester as defined in claim 1 wherein the group Ar consists essentially of at least one member selected from ##STR13## wherein Q is either a chemical bond or is selected from O, S, SO, S--S, So.sub.2 --, and CO.
- 7. A wholly aromatic polyester as defined in claim 1 wherein the group Ar consists essentially of at least one member selected from ##STR14##
- 8. A wholly aromatic polyester comprising the units (1), (2), (3), (4) and (6) ##STR15## wherein a+b is approximately equal to d+f; the ratio of a to b being in the range of from about 1.4:1 to about 10:1; the ratio of d to f being in the range of from about 4:1 to about 21:1; and c being in the range of from about 0.6 to about 7 based on the total moles of a+b.
- 9. A wholly aromatic polyester consisting essentially of the units (1), (2), (3), (4), and (6) ##STR16## wherein a+b is approximately equal to d+f; the ratio of a to b being in the range of from about 1.4:1 to about 10:1; the ratio of d to f being in the range of from about 4:1 to about 21:1: and c being in the range of from about 0.6 to about 7 based on the total moles of a+b.
- 10. A molding compound formed from the copolyester of claim 1 by incorporating therein one or more reinforcing agents or fillers selected from the group consisting of glass fibers, asbestos, graphitic carbon fibers, amorphous carbon fibers, synthetic polymeric fibers, aluminum fibers, aluminum silicate fibers, oxide of aluminum fibers, titanium fibers, magnesium fibers, rock wool fibers, steel fibers, tungsten fibers, cotton, wool, and wool cellulose fibers, calcium silicate, silica, clays, talc, mica, polytetrafluoroethylene, carbon black, graphite, alumina trihydrate, sodium aluminum carbonate, barium ferrite, wollastonite and titanium dioxide.
- 11. Cookware fabricated from the molding compound as defined in claim 10.
Parent Case Info
This is a continuation of application Ser. No. 317,525, filed Mar. 1, 1989, now abandoned.
Foreign Referenced Citations (1)
Number |
Date |
Country |
3629211 |
Mar 1988 |
DEX |
Continuations (1)
|
Number |
Date |
Country |
Parent |
317525 |
Mar 1989 |
|