This invention relates to a wind power plant which is intended for connection to distribution or transmission networks, hereinafrer called power networks. The invention also relates to an electric generator for high voltage in a wind power station intended for the above-mentioned purpose. The invention further relates to a variable speed system containing the above-mentioned generator.
A wind power plant can be a single grid-connected unit but usually consists of a number of wind turbines forming a wind power farm. Each wind turbine is equipped with an electric generator located in a hub. The generator can be synchronous or of the induction type. Induction generators are more common today because they are cheaper and more robust. The synchronous generator can produce reactive power which is an advantage over the induction machine. The size of the wind turbine is today typically 100-3000 kW with many commercial turbines around 500 kw. The trend is for higher power and voltage of the generator. The voltage levels of today are from 400 V up to a few kV. In most wind farms, it is necessary to equip each wind turbine with a transformer that steps up the voltage to a local distribution voltage that may be typically 10-30 kV. Thus this transformer and the generator constitute integrated parts of a plant. Individual units are interconnected in tree branch or ring networks with high-voltage cables. The distribution network may be connected to a transmission network by a single or a couple of power transformers. The transformers entail an extra cost and also have the drawback that the total efficiency of the system is reduced. They are also a fire hazard since they contain transformer oil which can leak out in the event of failure or vandalism.
If, therefore, it were possible to manufacture electric generators for considerably higher voltages, at least the distribution transformer could be eliminated. It is possible with today's generator technology to make a 10 kV generator and thus eliminate the distribution transformer, but the cost would be far higher than a more typical 660 V machine. Furthermore today's stator winding insulation technology is sensitive to temperature variations, humidity and salt that a wind turbine generator may be exposed to. This makes it unrealistic with today's technology to dispose of the distribution transformers.
A high-voltage generator has a magnetic circuit that comprise a laminated core, e.g. of sheet steel with a welded construction. To provide ventilation and cooling the core is often divided into stacks with radial and/or axial ventilation ducts. The winding of the magnetic circuit is disposed in slots in the core, the slots generally having a cross section in the shape of a rectangle or trapezium.
In multi-phase high-voltage electric generators the windings are made as either single or double layer windings. With single layer windings there is only one coil side per slot, whereas with double layer windings there are two coil sides per slot. By “coil side” is meant one or more conductors combined vertically or horizontally and provided with a common coil insulation, i.e. an insulation designed to withstand the rated voltage of the generator to earth.
Double-layer windings are generally made as diamond windings whereas single layer windings in the present context can be made as diamond or flat windings only one (possibly two) coil width exists in diamond windings whereas flat windings are made as concentric windings, i.e. with a widely varying coil width. By “coil width” is meant the distance in arc dimension between two coil sides pertaining to the same coil.
Normally all large machines are made with doublelayer windings and coils of the same size. Each coil is placed with one side in one layer and the other side in the other layer. This means that all coils cross each other in the coil end. If there are more than two layers these crossings complicate the winding work and the coil end is less satisfactory.
It is considered that coils for rotating generators can be manufactured with good results within a voltage range of 3-20 kV.
In theory, it is known how to obtain larger voltage levels. Such generators are described, for instance, in US-A-4429244, US-A-4164672 and US-A-3743867. However, the machine designs according to the above publications do not permit optimal utilization of the electromagnetic material in the stator.
There are also wind turbines that operate at variable turbine speed. This operation mode is advantageous because the aerodynamic efficiency can be maximized. Variable speed systems employ two generators with different numbers of poles or generators with windings that can be connected for two-speed operation. Variable speed can also be obtained by means of a frequency converter. A variable speed system is simplified when a synchronous generator is used because a simple diode rectifier can be used between generator and DC-link. The two most common inverter types are line commutated and force-commutated. These two types of inverters produce different types of harmonics and hence require different line filters. The line-commutated inverter is equipped with thyristors which produces harmonic current that are turned into voltage harmonics on the grid. To eliminate these harmonics a large grid filter must be used. Another drawback is that the line-commutated inverter consumes reactive power. A force-commutated inverter can create its own three-phase voltage system and if the inverter is connected to the grid it can freely choose which power factor to use and in which direction the power should be directed. By the use of Pulse Width Modulation, PWM, the low frequency harmonics are eliminated and the first harmonics have a frequency around the switching frequency of the inverter. The most interesting valve for a PWM inverter is the insulated Gate Bipolar Transistor, IGBT. With the latest IGBT-valves, a switching frequency of from 5 to 10 kHz would be used. Today's IGBT valves are limited in voltage and power so that a single six-pulse inverter can handle about 1 MVA at 1-2 kV.
The object of the invention is thus to provide an electric generator which can be used in a wind power plant for such high voltage that the distribution transformer can be omitted, i.e. a plant in which the electric generators are intended for considerably higher voltages than conventional machines of corresponding type, in order to be able to execute direct connection to power networks at all types of high voltages, in particular exceeding the 20 kV considered as an upper limit today. Another object of the invention is to provide an electric generator that is not sensitive to salt, humidity or temperature variations, as are present known high-voltage windings. A third object of the invention is to provide a variable speed alternative for the resulting high voltage if the distribution transformer is eliminated.
By use of solid insulation in combination with the other features defined, the network can be supplied without the use of an intermediate step-up transformer even at network voltages considerably in excess of 20 kV. Furthermore, this insulation is completely insensitive to salt, humidity and temperature variations. The elimination of the transformer entails great savings and also results in several other simplifications and savings.
Wind power plants are often arranged in farmland and close to populated areas. In a conventional wind power plant the transformer must be protected from causing hazard by explosion risk or leaking oil. A concrete transformer station may have to be built at the foundation of each wind turbine unit. In future offshore locations it would be difficult and costly to repair and maintain the transformer. Thus if the transformer is eliminated, the transformer housing is eliminated and it is also possible to use thinner cables to the generator. Furthermore the reactive power consumption and the electrical losses of the transformer are eliminated. The removal of the transformer also eliminates a set of breaker units previously necessary between the transformer and the generator.
The plant according to the invention also enables several connections with different voltage levels to be arranged, i.e. the invention can be used for all auxiliary power in the power station. Another way to supply auxiliary power to each wind turbine is to have a cheap low-voltage network in parallel with the distribution network.
According to another aspect of the present invention there is provided an electric generator as claimed in the ensuing claim 25.
In a particularly preferred embodiment of the plant and generator respectively, the solid insulation system comprises at least two spaced apart layers, e.g. semiconducting layers, each layer constituting essentially an equipotential surface, and an intermediate solid insulation therebetween, at least one of the layers having substantially the same coefficient of thermal expansion as the solid insulation.
This embodiment constitutes an expedient embodiment of the solid insulation that in an optimal manner enables the windings to be directly connected to the high-voltage network and where harmonization of the coefficients of thermal expansion eliminates the risk of defects, cracks or the like upon thermal movement in the winding.
It should be evident that the windings and the insulating layers are flexible so that they can be bent. It should also be pointed out that the plant according to the invention can be constructed using either horizontal or vertical generators.
A major and essential difference between known technology and the embodiment according to the invention is that an electric generator with a magnetic circuit is arranged to be directly connected via only breakers and isolators, to a high supply voltage, typically in the vicinity of between 2 and 50 kv, preferably higher than 10 kV. The magnetic circuit comprises a laminated core having at least one winding consisting of a threaded cable with one or more permanently insulated conductors having a semiconducting layer both at the conductor and outside the insulation, the outer semiconducting layer being connected to earth potential.
To solve the problems arising with direct connection of electric machines to all types of high-voltage power networks, the generator in the plant according to the invention has a number of features as mentioned above, which differ distinctly from known technology. Additional features and further embodiments are defined in the dependent claims and are discussed in the following.
Such features mentioned above and other essential characteristics of the generator and thus of the wind-power plant according to the invention include the following:
The winding of the magnetic circuit is produced from a cable having one or more permanently insulated conductors with a semiconducting layer at both conductor and sheath. Some typical conductors of this type are XLPE cable or a cable with EP rubber insulation which, however, for the present purpose are further developed both as regards the strands in the conductor and the nature of the outer sheath.
Cables with circular cross section are preferred, but cables with some other cross section may be used in order, for instance, to obtain better packing density.
Such a cable allows the laminated core to be designed according to the invention in a new and optimal way as regards slots and teeth.
The winding is preferably manufactured with insulation in steps for best utilization of the laminated core.
The winding is preferably manufactured as a multilayered, concentric cable winding, thus enabling the number of coil-end intersections to be reduced.
The slot design is suited to the cross section of the winding cable so that the slots are in the form of a number of cylindrical openings running axially and/or radially outside each other and having an open waist running between the layers of the stator winding.
The design of the slots is adjusted to the relevant cable cross section and to the stepped insulation of the winding. The stepped insulation allows the magnetic core to have substantially constant tooth width, irrespective of the radial extension.
The above-mentioned further development as regards the strands entails the winding conductors consisting of a number of impacted strata/layers, i.e. insulated strands that from the point of view of an electric machine, are not necessarily correctly transposed, uninsulated and/or insulated from each other.
The above-mentioned further development as regards the outer sheath entails that at suitable points along the length of the conductor, the outer sheath is cut off, each cut partial length being connected directly to earth potential.
The use of a cable of the type described above allows the entire length of the outer sheath of the winding, as well as other parts of the plant, to be kept at earth potential. An important advantage is that the electric field is close to zero within the coil-end region outside the outer semiconducting layer. With earth potential on the outer sheath the electric field need not be controlled. This means that no field concentrations will occur either in the core, in the coil-end regions or in the transition between them.
The mixture of insulated and/or uninsulated impacted strands, or transposed strands, results in low stray losses. The cable for high voltage used in the magnetic circuit winding is constructed of an inner core/conductor with a plurality of strands, at least two semiconducting layers, the innermost being surrounded by an insulating layer, which is in turn surrounded by an outer semiconducting layer having an outer diameter in the order of 10-40 mm and a conductor area in the order of 10-200 mm2.
Embodiments of the invention will now be described in more detail, by way of example only, with particular reference to the accompanying drawings, in which
A wind-power plant with a magnetic circuit of the type described above is shown in
Although the generator and the plant in which this generator is included have been described and illustrated in connection with an embodiment by way of example, it should be obvious to one skilled in that art that several modifications are possible without departing from the inventive concept. The gearing may be omitted if using a low-speed generator. The generator may be earthed directly without any impedance. The auxiliary windings can be omitted, as also can other components shown. Although the invention has been exemplified with a three-phase plant, the number of phases may be more or less. The generator can be connected to the grid via a frequency convertor containing a rectifier, a DC-link and an inverter. Unlike conventional variable-speed systems, the valves of the rectifier and inverter would probably have to be series-connected because of the high voltage.
Although it is preferred that the electrical insulation system for the winding should be extruded in position, it is possible to build up an electrical insulation system from tightly wound, overlapping layers of film or sheet-like material. Both the semiconducting layers and the electrically insulating layer can be formed in this manner. An insulation system can be made of an allsynthetic film with inner and outer semiconducting layers or portions made of polymeric thin film of, for example, PP, PET, LDPE or HDPE with embedded conducting particles, such as carbon black or metallic particles and with an insulating layer or portion between the semiconducting layers or portions.
For the lapped concept a sufficiently thin film will have butt gaps smaller than the so-called Paschen minima, thus rendering liquid impregnation unnecessary. A dry, wound multilayer thin film insulation has also good thermal properties.
Another example of an electrical insulation system is similar to a conventional cellulose based cable, where a thin cellulose based or synthetic paper or non-woven material is lap wound around a conductor. In this case the semiconducting layers, on either side of an insulating layer, can be made of cellulose paper or non-woven material made from fibres of insulating material and with conducting particles embedded. The insulating layer can be made from the same base material or another material can be used.
Another example of an insulation system is obtained by combining film and fibrous insulating material, either as a laminate or as co-lapped. An example of this insulation system is the commercially available so-called paper polypropylene laminate, PPLP, but several other combinations of film and fibrous parts are possible. In these systems various impregnations such as mineral oil can be used.
In this specification “semiconducting material” means a substance which has a considerably lower conductivity than an electric conductor but which does not have such a low conductivity that it is an electric insulator. Suitably, but not essentially, the semiconducting material will have a resistivity of 1-105 ohm-cm, preferably 10-500 ohm-cm and most preferably from 10 to 100 ohm-cm, typically 20 ohm-cm.
Number | Date | Country | Kind |
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9725309 | Nov 1997 | GB | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP98/07735 | 11/30/1998 | WO | 00 | 7/11/2000 |
Publishing Document | Publishing Date | Country | Kind |
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WO99/29025 | 6/10/1999 | WO | A |
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5343139 | Gyugyi et al. | Aug 1994 | A |
5355046 | Weigelt | Oct 1994 | A |
5365132 | Hann et al. | Nov 1994 | A |
5387890 | Estop et al. | Feb 1995 | A |
5397513 | Steketee, Jr. | Mar 1995 | A |
5399941 | Grothaus et al. | Mar 1995 | A |
5400005 | Bobry | Mar 1995 | A |
5408169 | Jeanneret | Apr 1995 | A |
5449861 | Fujino et al. | Sep 1995 | A |
5452170 | Ohde et al. | Sep 1995 | A |
5468916 | Litenas et al. | Nov 1995 | A |
5499178 | Mohan | Mar 1996 | A |
5500632 | Halser, III | Mar 1996 | A |
5510942 | Bock et al. | Apr 1996 | A |
5530307 | Horst | Jun 1996 | A |
5533658 | Benedict et al. | Jul 1996 | A |
5534754 | Poumey | Jul 1996 | A |
5545853 | Hildreth | Aug 1996 | A |
5550410 | Titus | Aug 1996 | A |
5583387 | Takeuchi et al. | Dec 1996 | A |
5587126 | Steketee, Jr. | Dec 1996 | A |
5598137 | Alber et al. | Jan 1997 | A |
5607320 | Wright | Mar 1997 | A |
5612510 | Hildreth | Mar 1997 | A |
5663605 | Evans et al. | Sep 1997 | A |
5672926 | Brandes et al. | Sep 1997 | A |
5689223 | Demarmels et al. | Nov 1997 | A |
5807447 | Forrest | Sep 1998 | A |
5834699 | Buck et al. | Nov 1998 | A |
Number | Date | Country |
---|---|---|
399790 | Jul 1995 | AT |
565063 | Feb 1957 | BE |
391071 | Apr 1965 | CH |
266037 | Oct 1965 | CH |
534448 | Feb 1973 | CH |
539328 | Jul 1973 | CH |
646403 | Feb 1979 | CH |
657482 | Aug 1986 | CH |
1189322 | Oct 1986 | CH |
40414 | Aug 1887 | DE |
277012 | Jul 1914 | DE |
336418 | Jun 1920 | DE |
372390 | Mar 1923 | DE |
386561 | Dec 1923 | DE |
387973 | Jan 1924 | DE |
406371 | Nov 1924 | DE |
425551 | Feb 1926 | DE |
426793 | Mar 1926 | DE |
432169 | Jul 1926 | DE |
433749 | Sep 1926 | DE |
435608 | Oct 1926 | DE |
435609 | Oct 1926 | DE |
441717 | Mar 1927 | DE |
443011 | Apr 1927 | DE |
460124 | May 1928 | DE |
482506 | Sep 1929 | DE |
501181 | Jul 1930 | DE |
523047 | Apr 1931 | DE |
568508 | Jan 1933 | DE |
572030 | Mar 1933 | DE |
584639 | Sep 1933 | DE |
586121 | Oct 1933 | DE |
604972 | Nov 1934 | DE |
629301 | Apr 1936 | DE |
673545 | Mar 1939 | DE |
719009 | Mar 1942 | DE |
846583 | Aug 1952 | DE |
875227 | Apr 1953 | DE |
975999 | Jan 1963 | DE |
1465719 | May 1969 | DE |
1807391 | May 1970 | DE |
2050674 | May 1971 | DE |
1638176 | Jun 1971 | DE |
2155371 | May 1973 | DE |
2400698 | Jul 1975 | DE |
2520511 | Nov 1976 | DE |
2656389 | Jun 1978 | DE |
2721905 | Nov 1978 | DE |
137164 | Aug 1979 | DE |
138840 | Nov 1979 | DE |
2824951 | Dec 1979 | DE |
2835386 | Feb 1980 | DE |
2839517 | Mar 1980 | DE |
2854520 | Jun 1980 | DE |
3009102 | Sep 1980 | DE |
2913697 | Oct 1980 | DE |
2920478 | Dec 1980 | DE |
3028777 | Mar 1981 | DE |
2939004 | Apr 1981 | DE |
3006382 | Aug 1981 | DE |
3008818 | Sep 1981 | DE |
209313 | Apr 1984 | DE |
3305225 | Aug 1984 | DE |
3309051 | Sep 1984 | DE |
3441311 | May 1986 | DE |
3543106 | Jun 1987 | DE |
2917717 | Aug 1987 | DE |
3612112 | Oct 1987 | DE |
3726346 | Feb 1989 | DE |
3925337 | Feb 1991 | DE |
4023903 | Nov 1991 | DE |
4022476 | Jan 1992 | DE |
4233558 | Mar 1994 | DE |
4402184 | Aug 1995 | DE |
4409794 | Aug 1995 | DE |
4412761 | Oct 1995 | DE |
4420322 | Dec 1995 | DE |
4438186 | Jan 1996 | DE |
19620906 | Jan 1996 | DE |
19020222 | Mar 1997 | DE |
19547229 | Jun 1997 | DE |
468827 | Jul 1997 | DE |
134022 | Dec 2001 | DE |
049104 | Apr 1982 | EP |
0493704 | Apr 1982 | EP |
0056580 | Jul 1982 | EP |
078908 | May 1983 | EP |
0120154 | Oct 1984 | EP |
0130124 | Jan 1985 | EP |
0142813 | May 1985 | EP |
0155405 | Sep 1985 | EP |
0102513 | Jan 1986 | EP |
0174783 | Mar 1986 | EP |
0185788 | Jul 1986 | EP |
0277358 | Aug 1986 | EP |
0234521 | Sep 1987 | EP |
0244069 | Nov 1987 | EP |
0246377 | Nov 1987 | EP |
0265868 | May 1988 | EP |
0274691 | Jul 1988 | EP |
0280759 | Sep 1988 | EP |
0282876 | Sep 1988 | EP |
0309096 | Mar 1989 | EP |
0314860 | May 1989 | EP |
0316911 | May 1989 | EP |
0317248 | May 1989 | EP |
0335430 | Oct 1989 | EP |
0342554 | Nov 1989 | EP |
0221404 | May 1990 | EP |
0375101 | Jun 1990 | EP |
0406437 | Jan 1991 | EP |
0439410 | Jul 1991 | EP |
0440865 | Aug 1991 | EP |
0469155 | Feb 1992 | EP |
0490705 | Jun 1992 | EP |
0503817 | Sep 1992 | EP |
0571155 | Nov 1993 | EP |
0620570 | Oct 1994 | EP |
0620630 | Oct 1994 | EP |
0642027 | Mar 1995 | EP |
0671632 | Sep 1995 | EP |
0676777 | Oct 1995 | EP |
0677915 | Oct 1995 | EP |
0684679 | Nov 1995 | EP |
0684682 | Nov 1995 | EP |
0695019 | Jan 1996 | EP |
0732787 | Sep 1996 | EP |
0738034 | Oct 1996 | EP |
0739087 | Oct 1996 | EP |
0740315 | Oct 1996 | EP |
0749190 | Dec 1996 | EP |
0751605 | Jan 1997 | EP |
0739087 | Mar 1997 | EP |
0749193 | Mar 1997 | EP |
0780926 | Jun 1997 | EP |
0802542 | Oct 1997 | EP |
0913912 | May 1999 | EP |
805544 | Apr 1936 | FR |
841351 | Jan 1938 | FR |
847899 | Dec 1938 | FR |
916959 | Dec 1946 | FR |
1011924 | Apr 1949 | FR |
1126975 | Mar 1955 | FR |
1238795 | Jul 1959 | FR |
2108171 | May 1972 | FR |
2251938 | Jun 1975 | FR |
2305879 | Oct 1976 | FR |
2376542 | Jul 1978 | FR |
2467502 | Apr 1981 | FR |
2481531 | Oct 1981 | FR |
2556146 | Jun 1985 | FR |
2594271 | Aug 1987 | FR |
2708157 | Jan 1995 | FR |
268271 | Mar 1927 | GB |
293861 | Nov 1928 | GB |
292999 | Apr 1929 | GB |
319313 | Jul 1929 | GB |
518993 | Mar 1940 | GB |
537609 | Jun 1941 | GB |
540456 | Oct 1941 | GB |
589071 | Jun 1947 | GB |
666883 | Feb 1952 | GB |
685416 | Jan 1953 | GB |
702892 | Jan 1954 | GB |
715226 | Sep 1954 | GB |
723457 | Feb 1955 | GB |
739962 | Nov 1955 | GB |
763761 | Dec 1956 | GB |
805721 | Dec 1958 | GB |
827600 | Feb 1960 | GB |
854728 | Nov 1960 | GB |
870583 | Jun 1961 | GB |
913386 | Dec 1962 | GB |
965741 | Aug 1964 | GB |
992249 | May 1965 | GB |
1024583 | Mar 1966 | GB |
1053337 | Dec 1966 | GB |
1059123 | Feb 1967 | GB |
1103098 | Feb 1968 | GB |
1103099 | Feb 1968 | GB |
1117401 | Jun 1968 | GB |
1135242 | Dec 1968 | GB |
1147049 | Apr 1969 | GB |
1157885 | Jul 1969 | GB |
1174659 | Dec 1969 | GB |
1236082 | Jun 1971 | GB |
1268770 | Mar 1972 | GB |
1319257 | Jun 1973 | GB |
1322433 | Jul 1973 | GB |
1340983 | Dec 1973 | GB |
1341050 | Dec 1973 | GB |
1365191 | Aug 1974 | GB |
1395152 | May 1975 | GB |
1424982 | Feb 1976 | GB |
1426594 | Mar 1976 | GB |
1438610 | Jun 1976 | GB |
1445284 | Aug 1976 | GB |
1479904 | Jul 1977 | GB |
1493163 | Nov 1977 | GB |
1502938 | Mar 1978 | GB |
1525745 | Sep 1978 | GB |
2000625 | Jan 1979 | GB |
1548633 | Jul 1979 | GB |
2046142 | Nov 1979 | GB |
2022327 | Dec 1979 | GB |
2025150 | Jan 1980 | GB |
2034101 | May 1980 | GB |
1574796 | Sep 1980 | GB |
2070341 | Sep 1981 | GB |
2070470 | Sep 1981 | GB |
2071433 | Sep 1981 | GB |
2081523 | Feb 1982 | GB |
2099635 | Dec 1982 | GB |
2105925 | Mar 1983 | GB |
2106306 | Apr 1983 | GB |
2106721 | Apr 1983 | GB |
2136214 | Sep 1984 | GB |
2140195 | Nov 1984 | GB |
2150153 | Jun 1985 | GB |
2268337 | Jan 1994 | GB |
2273819 | Jun 1994 | GB |
2283133 | Apr 1995 | GB |
2289992 | Dec 1995 | GB |
2308490 | Jun 1997 | GB |
2332557 | Jun 1999 | GB |
123906 | Nov 2001 | GB |
175494 | Nov 1981 | HU |
60206121 | Mar 1959 | JP |
57043529 | Aug 1980 | JP |
57126117 | May 1982 | JP |
59076156 | Oct 1982 | JP |
59159642 | Feb 1983 | JP |
6264964 | Sep 1985 | JP |
1129737 | May 1989 | JP |
62320631 | Jun 1989 | JP |
2017474 | Jan 1990 | JP |
3245748 | Feb 1990 | JP |
4179107 | Nov 1990 | JP |
318253 | Jan 1991 | JP |
424909 | Jan 1992 | JP |
5290947 | Apr 1992 | JP |
6196343 | Dec 1992 | JP |
6233442 | Feb 1993 | JP |
6325629 | May 1993 | JP |
7057951 | Aug 1993 | JP |
7264789 | Mar 1994 | JP |
8167332 | Dec 1994 | JP |
7161270 | Jun 1995 | JP |
8264039 | Nov 1995 | JP |
9200989 | Jan 1996 | JP |
8036952 | Feb 1996 | JP |
8167360 | Jun 1996 | JP |
67199 | Mar 1972 | LU |
90308 | Sep 1937 | SE |
305899 | Nov 1968 | SE |
255156 | Feb 1969 | SE |
341428 | Dec 1971 | SE |
453236 | Jan 1982 | SE |
457792 | Jun 1987 | SE |
502417 | Dec 1993 | SE |
792302 | Jan 1971 | SU |
425268 | Sep 1974 | SU |
1019553 | Jan 1980 | SU |
694939 | Jan 1982 | SU |
955369 | Aug 1983 | SU |
1511810 | May 1987 | SU |
WO 8202617 | Aug 1982 | WO |
WO8502302 | May 1985 | WO |
WO9011389 | Oct 1990 | WO |
WO9012409 | Oct 1990 | WO |
PCTDE 9000279 | Nov 1990 | WO |
WO9101059 | Jan 1991 | WO |
WO9101585 | Feb 1991 | WO |
WO9107807 | Mar 1991 | WO |
PCT SE 9100077 | Apr 1991 | WO |
WO9109442 | Jun 1991 | WO |
WO 9111841 | Aug 1991 | WO |
WO8115862 | Oct 1991 | WO |
WO 9115755 | Oct 1991 | WO |
WO9201328 | Jan 1992 | WO |
WO9203870 | Mar 1992 | WO |
WO9321681 | Oct 1993 | WO |
WO9406194 | Mar 1994 | WO |
WO9518058 | Jul 1995 | WO |
WO9522153 | Aug 1995 | WO |
WO9524049 | Sep 1995 | WO |
WO9622606 | Jul 1996 | WO |
WO9622607 | Jul 1996 | WO |
PCTCN 9600010 | Oct 1996 | WO |
WO9630144 | Oct 1996 | WO |
WO9710640 | Mar 1997 | WO |
WO9711831 | Apr 1997 | WO |
WO9716881 | May 1997 | WO |
WO 9729494 | Aug 1997 | WO |
WO9745288 | Dec 1997 | WO |
WO9745847 | Dec 1997 | WO |
WO9745848 | Dec 1997 | WO |
WO9745906 | Dec 1997 | WO |
WO9745907 | Dec 1997 | WO |
WO 9745908 | Dec 1997 | WO |
WO9745908 | Dec 1997 | WO |
WO9745912 | Dec 1997 | WO |
WO9745914 | Dec 1997 | WO |
WO9745915 | Dec 1997 | WO |
WO9745916 | Dec 1997 | WO |
WO9745918 | Dec 1997 | WO |
WO9745919 | Dec 1997 | WO |
WO9745920 | Dec 1997 | WO |
WO9745921 | Dec 1997 | WO |
WO9745922 | Dec 1997 | WO |
WO9745923 | Dec 1997 | WO |
WO9745924 | Dec 1997 | WO |
WO9745925 | Dec 1997 | WO |
WO9745926 | Dec 1997 | WO |
WO9745927 | Dec 1997 | WO |
WO9745928 | Dec 1997 | WO |
WO9745929 | Dec 1997 | WO |
WO9745930 | Dec 1997 | WO |
WO9745931 | Dec 1997 | WO |
WO9745932 | Dec 1997 | WO |
WO9745933 | Dec 1997 | WO |
WO9745934 | Dec 1997 | WO |
WO9745935 | Dec 1997 | WO |
WO9745936 | Dec 1997 | WO |
WO9745937 | Dec 1997 | WO |
WO9745938 | Dec 1997 | WO |
WO9745939 | Dec 1997 | WO |
WO9747067 | Dec 1997 | WO |
WO9820595 | May 1998 | WO |
WO9820596 | May 1998 | WO |
WO9820597 | May 1998 | WO |
WO 9820598 | May 1998 | WO |
WO9820600 | May 1998 | WO |
WO 9820602 | May 1998 | WO |
WO9821385 | May 1998 | WO |
PCTFR 9800468 | Jun 1998 | WO |
WO9827634 | Jun 1998 | WO |
WO9827635 | Jun 1998 | WO |
WO9827636 | Jun 1998 | WO |
WO9829928 | Jul 1998 | WO |
WO9829929 | Jul 1998 | WO |
WO9829930 | Jul 1998 | WO |
WO9829931 | Jul 1998 | WO |
WO9829932 | Jul 1998 | WO |
WO9833731 | Aug 1998 | WO |
WO9833736 | Aug 1998 | WO |
WO9833737 | Aug 1998 | WO |
WO9834238 | Aug 1998 | WO |
WO 9834239 | Aug 1998 | WO |
WO9834240 | Aug 1998 | WO |
WO9834241 | Aug 1998 | WO |
WO9834242 | Aug 1998 | WO |
WO9834243 | Aug 1998 | WO |
WO9834244 | Aug 1998 | WO |
WO9834245 | Aug 1998 | WO |
WO9834246 | Aug 1998 | WO |
WO9834247 | Aug 1998 | WO |
WO9834248 | Aug 1998 | WO |
WO9834249 | Aug 1998 | WO |
WO9834250 | Aug 1998 | WO |
WO9834309 | Aug 1998 | WO |
WO9834312 | Aug 1998 | WO |
WO9834315 | Aug 1998 | WO |
WO9834321 | Aug 1998 | WO |
WO9834322 | Aug 1998 | WO |
WO9834323 | Aug 1998 | WO |
WO9834325 | Aug 1998 | WO |
WO9834326 | Aug 1998 | WO |
WO9834327 | Aug 1998 | WO |
WO9834328 | Aug 1998 | WO |
WO9834329 | Aug 1998 | WO |
WO9834330 | Aug 1998 | WO |
WO9834331 | Aug 1998 | WO |
WO9829927 | Sep 1998 | WO |
WO 9840627 | Sep 1998 | WO |
WO 9843336 | Oct 1998 | WO |
WO9917309 | Apr 1999 | WO |
WO9917311 | Apr 1999 | WO |
WO9917312 | Apr 1999 | WO |
WO9917313 | Apr 1999 | WO |
WO9917314 | Apr 1999 | WO |
WO9917315 | Apr 1999 | WO |
WO9917316 | Apr 1999 | WO |
WO9917422 | Apr 1999 | WO |
WO9917424 | Apr 1999 | WO |
WO9917425 | Apr 1999 | WO |
WO9917426 | Apr 1999 | WO |
WO9917427 | Apr 1999 | WO |
WO9917428 | Apr 1999 | WO |
WO9917429 | Apr 1999 | WO |
WO9917432 | Apr 1999 | WO |
WO9917433 | Apr 1999 | WO |
WO9919963 | Apr 1999 | WO |
WO9919969 | Apr 1999 | WO |
WO9919970 | Apr 1999 | WO |
PCTSE 9802148 | Jun 1999 | WO |
WO9927546 | Jun 1999 | WO |
WO9928919 | Jun 1999 | WO |
WO9928921 | Jun 1999 | WO |
WO 9928922 | Jun 1999 | WO |
WO9928923 | Jun 1999 | WO |
WO9928924 | Jun 1999 | WO |
WO9928925 | Jun 1999 | WO |
WO9928926 | Jun 1999 | WO |
WO9928927 | Jun 1999 | WO |
WO9928928 | Jun 1999 | WO |
WO9928929 | Jun 1999 | WO |
WO9928930 | Jun 1999 | WO |
WO9928931 | Jun 1999 | WO |
WO9928934 | Jun 1999 | WO |
WO9928994 | Jun 1999 | WO |
WO 9929005 | Jun 1999 | WO |
WO9929005 | Jun 1999 | WO |
WO9929008 | Jun 1999 | WO |
WO9929011 | Jun 1999 | WO |
WO9929012 | Jun 1999 | WO |
WO9929013 | Jun 1999 | WO |
WO9929014 | Jun 1999 | WO |
WO9929015 | Jun 1999 | WO |
WO9929016 | Jun 1999 | WO |
WO9929017 | Jun 1999 | WO |
WO9929018 | Jun 1999 | WO |
WO9929019 | Jun 1999 | WO |
WO9929020 | Jun 1999 | WO |
WO9929021 | Jun 1999 | WO |
WO9929022 | Jun 1999 | WO |
WO 9929023 | Jun 1999 | WO |
WO9929024 | Jun 1999 | WO |
WO 9929025 | Jun 1999 | WO |
WO9929026 | Jun 1999 | WO |
WO9929029 | Jun 1999 | WO |
WO9929034 | Jun 1999 | WO |