Certain embodiments of this invention relates to a writable window, where an image (e.g., advertisement, logo, design, picture, pattern, and/or word) can be selectively written into the window and is/are designed to be viewed by humans and/or animals. For example, the images may be designed to be viewed by humans, and/or may be designed to be viewed by animals such as birds so that birds can more easily see the window(s) in order to prevent or reduce bird collisions with windows. In certain example embodiments, the window may comprise an insulating glass (IG) window unit, or alternatively a monolithic window. At least one substrate (e.g., glass substrate) of the window supports a solar coating such as a low-emissivity (low-E) coating. The solar coating (e.g., low-E coating) in IG and monolithic embodiments may include at least one infrared (IR) reflecting layer comprising or consisting essentially of silver, where the silver inclusive layer may be located on and directly contacting a contact/seed layer comprising or consisting essentially of a material such as zinc oxide and/or zinc stannate. A radiation source(s) such as a laser(s) and/or lamp(s) may be used to selectively expose certain areas of the coating to radiation (e.g., UV radiation). The exposed area(s) of the coating have different optical characteristic(s) (e.g., reduced visible reflectance and/or higher visible transmission) than the area(s) of the coating not exposed to the radiation, so that following the radiation exposure the exposed area(s) form an image(s) designed to be viewed by humans and/or animals. In such a manner, images may be selectively written onto coated glass to be used in windows such as architectural windows for office buildings and/or apartment buildings, windows for homes, windows for freezer doors, and/or vehicle windows.
IG window units are known in the art. For example, see U.S. Pat. Nos. 6,632,491, 6,014,872; 5,800,933; 5,784,853; 5,557,462; 5,514,476; 5,308,662; 5,306,547; and 5,156,894, all of which are hereby incorporated herein by reference. An IG window unit typically includes at least first and second substrates spaced apart from one another by at least one spacer and/or seal. The gap or space between the spaced apart substrates may or may not be filled with a gas (e.g., argon) and/or evacuated to a pressure less than atmospheric pressure in different instances.
Many conventional IG window units include a solar management coating (e.g., multi-layer coating for reflecting at least some infrared radiation) on an interior surface of one of the two substrates. Such IG units enable significant amounts of infrared (IR) radiation to be blocked so that it does not reach the interior of the building (apartment, house, office building, or the like).
It would be desirable to be able to form images on windows in an efficient manner, that one or more of: (i) does not significant affect the durability of the coating, (ii) allows advertisements and/or logos to be selectively formed on windows in an aesthetically pleasing manner not necessarily requiring stickers, (iii) enables animals such as birds to more easily see the windows so as to reduce bird collisions with windows, and/or (iv) allows customizable images to be formed on windows for buildings.
For instance, in Chicago certain buildings (e.g., skyscrapers) are located in migratory bird paths. Birds flying along these paths repeatedly run into these buildings because they cannot see the windows of the building. This results in thousands of bird deaths, especially during seasons of bird migration.
In view of the above, it will be appreciated that there exists a need in the art for improved windows which can prevent or reduce bird collisions therewith.
Certain embodiments of this invention relates to a writable window, where an image (e.g., advertisement, logo, design, picture, pattern, and/or word) can be selectively written into the window and is/are designed to be viewed by humans and/or animals. For example, the images may be designed to be viewed by humans, and/or may be designed to be viewed by animals such as birds so that birds can more easily see the window(s) in order to prevent or reduce bird collisions with windows. In certain example embodiments, the window may comprise an insulating glass (IG) window unit, or alternatively a monolithic window. In IG window unit embodiments, the IG window unit includes first and second substrates (e.g., glass substrates) spaced apart from one another, wherein at least one of the substrates supports a solar coating such as a low-emissivity (low-E) coating. In monolithic window embodiments, a substrate (e.g., glass substrate) supports a solar coating such as a low-E coating. The low-E coating in IG and monolithic embodiments may include at least one infrared (IR) reflecting layer of or including silver, where the silver inclusive layer may be located on and directly contacting a contact/seed layer of or including a material such as zinc oxide and/or zinc stannate. A radiation source(s) such as a laser(s) and/or lamp(s) may be used to selectively expose certain areas of the coating to radiation such as ultraviolet (UV) radiation. The exposed area(s) of the coating have different optical characteristic(s) (e.g., reduced visible reflectance and/or higher visible transmission) than the area(s) of the coating not exposed to the radiation, so that following the exposure the exposed area(s) form an image(s) designed to be viewed by humans and/or animals. For example, UV exposure causes the contact/seed layer and/or silver based layer to heat up in exposed areas. For instance, heating of the contact/seed layer causes the adjacent silver layer to also heat up in the exposed areas thereby physically changing the silver layer in those areas so as to densify and cause the silver layer to become more conductive and more transparent to visible light in the exposed areas. Thus, the physical and optical properties of the IR reflecting layer(s) (e.g., silver layer(s)) are changed in the exposed areas. In such a manner, images may be selectively written onto coated glass to be used in windows such as architectural windows for office buildings and/or apartment buildings, windows for homes, windows for freezer doors, and/or vehicle windows.
In certain example embodiments of this invention, the image may be designed to be seen by birds so that birds can more easily see the window so as to prevent or reduce bird collisions therewith. By making the window more visible to birds in such a manner, bird collisions and thus bird deaths can be reduced.
In certain example embodiments, there is provided a method of making a coated article for use in a window, the method comprising: having a coated article including a coating supported by a substrate; directing ultraviolet (UV) radiation toward the coating and exposing only part of the coating to UV radiation in order to form an image in the coating that can be seen by a human eye.
In the method of the immediately preceding paragraph, the image may comprise a logo.
In the method of any of the preceding two paragraphs, the image may comprise at least one word.
In the method of any of the preceding three paragraphs, the coating may comprise at least one layer comprising silver that is located over and directly contacting a layer comprising metal oxide that absorbs UV radiation. The layer comprising metal oxide may have a bandgap of from about 3.15 to 3.4 eV, and/or may comprise zinc oxide and/or zinc stannate. And the layer comprising silver may have a higher visible transmission and/or reduced visible reflectance in area(s) exposed to the UV radiation compared to area(s) of the coating not exposed to the UV radiation so that a shape of the image is substantially defined by area(s) exposed to the UV radiation.
In the method of any of the preceding four paragraphs, the coating may have a sheet resistance (Rs) of no greater than 10 ohms/square, more preferably no greater than 8 or 6 ohms/square.
In the method of any of the preceding five paragraphs, the coating may be a low-E coating.
In the method of any of the preceding six paragraphs, the coated article may have a visible transmission of at least about 50% (more preferably at least about 60%) before and/or after said exposing.
In the method of any of the preceding seven paragraphs, the substrate may be a glass substrate.
In the method of any of the preceding eight paragraphs, the method may further comprise, after said exposing, coupling the substrate with the coating thereon to another substrate in making an insulating glass (IG) window unit.
In the method of any of the preceding nine paragraphs, said UV radiation may be directed toward the coating from at least one source of UV radiation. The source may comprise a UV emitting lamp and/or a UV emitting laser. The method may further include providing a mask between the coating and the source of UV radiation so that opening(s) defined in the mask determine which part of the coating is exposed to UV radiation from the source. Radiation emitted from the source may consist essentially of UV radiation.
In the method of any of the preceding ten paragraphs, the coating may comprise at least one layer comprising silver located between at least first and second dielectric layers.
In certain example embodiments of this invention, there is provided an IG window unit comprising: a first glass substrate; a second glass substrate spaced apart from the first glass substrate; a low-E coating having sheet resistance (Rs) of no greater than 10 ohms/square, the low-E coating supported by at least one of the glass substrates so as to face a gap located between the substrates; wherein the low-E coating comprises at least one layer comprising silver that is located over and directly contacting a layer comprising metal oxide that can absorb ultraviolet (UV) radiation, wherein an image viewable by a human eye is formed in the low-E coating.
In the IG window unit of the immediately preceding paragraph, the layer comprising silver may have a higher visible transmission and/or reduced visible reflectance in certain area(s) compared to other area(s) of the coating so that a shape of the image is substantially defined by the area(s) having the higher visible transmission and/or reduced visible reflectance.
In the IG window unit of the immediately preceding paragraph, the area(s) having the higher visible transmission and/or reduced visible reflectance may be area(s) that were exposed to UV radiation from a UV source (e.g., UV emitting laser or lamp), and the area(s) not having the higher visible transmission and/or reduced visible reflectance may be area(s) that were not so exposed.
In the IG window unit of any of the preceding three paragraphs, the layer comprising metal oxide may have a bandgap of from about 3.15 to 3.4 eV.
In the IG window unit of any of the preceding four paragraphs, the layer comprising metal oxide may comprise zinc oxide and/or zinc stannate.
Referring now more particularly to the accompanying drawings in which like reference numerals indicate like parts throughout the several views.
Referring to
A low-E coating typically includes at least one IR reflecting layer of or including silver 11 sandwiched between at least a lower dielectric 7 and an upper dielectric 15. The example low-E coating 5 in
One or more radiation source(s) 20 is/are provided in order to selective expose only certain portions of the coated article to radiation such as UV radiation. For example, in the
The contact/seed layer 9 (e.g., of or including zinc oxide and/or zinc stannate) may have a bandgap of from about 3.0 to 3.4 eV, more preferably from about 3.15 to 3.4 eV, and most preferably about 3.2 eV, and because of this bandgap the contact/seed layer 9 absorbs UV radiation 21 from the source 20 (e.g., about 355 nm and/or about 308 nm) and heats up. The seed layer 9 may be a semiconductor or dielectric. At least the silver in layer 11 in the exposed areas next to the heated portions of layer 9 is in turn heated and physically changes in the heated area(s) by densifying and becoming more transparent to visible light and/or differently colored, and also by become more conductive. Thus, the characteristics of the layer stack are introduced as the UV is absorbed by the seed/contact layer 9 with a subsequent release of thermal energy to at least the adjacent silver (or gold) based layer 11 and possible to other layer(s) in the stack. Accordingly, the physical and optical properties of the IR reflecting silver layer 11 are changed in the UV exposed areas. The exposed area(s) will then have a different visible transmission and/or visible reflectance than non-exposed area(s), and therefore the image(s) generally indicated by the exposed area can then be seen by human eyes and/or animal eyes due to the contrast in visible reflectance and/or transmission between the exposed area(s) and the non-exposed area(s).
In such a manner, various images 12 may be selectively written onto coated glass to be used in windows (e.g., with the outline of “LOGO” in
The
In view of the presence of both IR blocking/reflecting coating (i.e., solar management coating) 5, IG window units according to certain example embodiments of this invention as shown in
>=50%
>= 60%
>= 68%
It is noted that certain parameters can be tuned by adjusting layer thicknesses. For example, sheet resistance can be decreased and visible transmission decreased by increasing the thickness of the silver based layer 11 and/or by providing the coating with additional silver based layer(s). In certain example embodiments, the coating 5 in the
As used herein, the terms “on,” “supported by,” and the like should not be interpreted to mean that two elements are directly adjacent to one another unless explicitly stated. In other words, a first layer may be said to be “on” or “supported by” a second layer, even if there are one or more layers there between.
While the invention has been described in connection with what is presently considered to be the most practical and preferred embodiment, it is to be understood that the invention is not to be limited to the disclosed embodiment, but on the contrary, is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the appended claims.
This application is a division of application Ser. No. 13/484,844, filed May 31, 2012, the entire disclosure of which is hereby incorporated herein by reference in this application.
Number | Name | Date | Kind |
---|---|---|---|
5028759 | Finley | Jul 1991 | A |
5147125 | Austin | Sep 1992 | A |
5156894 | Hood et al. | Oct 1992 | A |
5306547 | Hood et al. | Apr 1994 | A |
5308662 | Woodard et al. | May 1994 | A |
5480722 | Tomonaga | Jan 1996 | A |
5514476 | Hartig et al. | May 1996 | A |
5557462 | Hartig et al. | Sep 1996 | A |
5784853 | Hood et al. | Jul 1998 | A |
5800933 | Hartig et al. | Sep 1998 | A |
6014872 | Hartig et al. | Jan 2000 | A |
6238847 | Axtell, III | May 2001 | B1 |
6632491 | Thomsen et al. | Oct 2003 | B1 |
6899953 | O'Shaughnessy | May 2005 | B1 |
7940606 | Nakaoki | May 2011 | B2 |
8101278 | Laird | Jan 2012 | B2 |
8114488 | Alvarez | Feb 2012 | B2 |
8124237 | Nunez-Regueiro et al. | Feb 2012 | B2 |
8142622 | Ferreira et al. | Mar 2012 | B2 |
8173263 | Lingle et al. | May 2012 | B2 |
8221833 | Veerasamy et al. | Jul 2012 | B2 |
9422189 | Walp | Aug 2016 | B2 |
9469565 | Krasnov | Oct 2016 | B2 |
9487437 | Walp | Nov 2016 | B2 |
9919959 | Krasnov | Mar 2018 | B2 |
10207951 | Krasnov | Feb 2019 | B2 |
20030121764 | Yang | Jul 2003 | A1 |
20030129813 | Lu | Jul 2003 | A1 |
20070116967 | Medwick et al. | May 2007 | A1 |
20080008829 | Blacker et al. | Jan 2008 | A1 |
20080145661 | Medwick | Jun 2008 | A1 |
20090074997 | Stark | Mar 2009 | A1 |
20090104436 | Berg et al. | Apr 2009 | A1 |
20100032008 | Adekore | Feb 2010 | A1 |
20100071810 | Nadaud et al. | Mar 2010 | A1 |
20110195360 | Flemming | Aug 2011 | A1 |
20120048722 | McLean et al. | Mar 2012 | A1 |
20120186635 | Eastman | Jul 2012 | A1 |
20130099196 | Wu | Apr 2013 | A1 |
20180186692 | Krasnov | Jul 2018 | A1 |
20190039947 | Fisher | Feb 2019 | A1 |
20190169069 | Krasnov | Jun 2019 | A1 |
Number | Date | Country |
---|---|---|
0377444 | Feb 1990 | EP |
0 391 848 | Oct 1990 | EP |
2003-012345 | Jan 2003 | JP |
Entry |
---|
Machine translation of JP 2003-012345 A by Yazawa Tetsuo, published Jan. 15, 2003. |
Machine translation of EP 0391848 A1 by Herren et al., published Oct. 10, 1990. |
Paul A. Tipler; Physics; Worth Publishers, Inc.; New York, NY; 1976 (no month) excerpt section 42-2, on pp. 957-960. |
S. Peter Poppa's, PhD, editor; UV Curing: Science and Technology; chapter “light sources” by Vincent D McGinniss; technology marketing Corporation; Stamford, Connecticut, USA; 1978 (no month); pp. 96-129. |
U.S. Appl. No. 13/484,844, filed May 31, 2012; Krasnov. |
U.S. Appl. No. 13/484,894, filed May 31, 2012; Krasnov et al. |
International Search Report dated Sep. 23, 2013. |
Baruah et al., “Zinc Stannate Nanostructures: Hydrothermal Synthesis” Science and Technology of Advanced Materials, vol. 12, Published Mar. 11, 2011; pp. 013004-1 to 013004-18. |
Number | Date | Country | |
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20170022097 A1 | Jan 2017 | US |
Number | Date | Country | |
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Parent | 13484844 | May 2012 | US |
Child | 15285848 | US |