1. Field of the Invention
The present invention relates to vehicle windshield defrosters and wipers using heated washer fluid.
2. Description of Related Art
Defrosting and deicing of motor vehicle windshields and wipers have been served by conventional warm air defrosters for many decades. There continues to be much driver dissatisfaction with the slow and otherwise poor performance of these defrosters for providing quick and safe driving visibility. Government mandated vehicle safety standards (e.g. FMVSS103 based on 1960s warm air automotive defroster minimal technology) set minimum defrosting performance requirements, yet still allow 30 minutes from cold engine start to clear a preset standard amount of frost at 0° F. Even modern (27.5 miles per gallon CAFE—Corporate Average Fuel Economy) vehicles still typically take 15-25 minutes to defrost the windshield on this test.
Consequently, in commonplace operation drivers often have to scrape ice from the windshield and knock ice off wiper blades or waste fuel and time waiting for the engine to warm up so the defrosters can work. Windshields are especially difficult to access effectively with ice scrapers, and the situation is exacerbated in the U.S.A. with the coming wave of 78 million elderly “baby boomers” having reduced agility to scrape ice from windshields. Also, evidence indicates global warming may be generating more intense storms including during winter.
Much better defroster performance is deemed necessary by many winter weather drivers, especially in light of better available technology such as electrically heated windshields and the even more effective emerging heated washer systems. Substantially intensifying this need for better defrosting systems is the rapidly emerging class of high fuel efficiency internal combustion engine, hybrid, plug-in hybrid electric, full battery electric and fuel cell electric vehicles to achieve the very challenging newly legislated 35.5 mpg CAFE requirement by 2015, a less oil dependent national economy (witness skyrocketing fuel prices) and more environmentally friendly vehicles.
Because of the high fuel efficiency of these coming new vehicles there is inherently much less “waste heat” energy available to enable traditional engine coolant heat based warm air defrosters and heaters to perform well. Automakers and their suppliers are now actively researching and developing new defroster and heater technologies such as heat storage, heat pumps, electrical heating, viscous friction heaters, coolant turbulence heaters and fuel fired heaters to meet the new needs of these highly fuel efficient vehicles. Present day conventional type vehicles of lesser fuel efficiency and greater “waste heat” will largely become obsolete. The common practice of warming up the engine for extended periods of time to defrost the windshield before driving is contrary to the now common goals of reducing pollution and energy dependence on foreign oil.
Remote start feature has been available on the aftermarket for many years and is recently becoming popular as an original equipment feature to enhance defrosting, heating and air conditioning performance. However anti-idling laws of many states and countries, in the interest of reducing air pollution and improving fuel economy, increasingly limit allowable idle time (now typically down to 5 minutes) and the remote start feature will tend to have corresponding idle time restrictions.
Electrically heated windshields can substantially reduce defrost time but have had limited use because of cost, complexity, poor reliability, and technical problems such as interference with electronic communications devices. Electric heated windshield replacement cost is many times more (examples of 5 times more have been discovered) than a conventional windshield and replacement data indicate the average vehicle has about 1½ windshields during its lifetime. Visible heating wires and heating films can also be distracting and degrade windshield clarity and transparency.
Electrically heated washer fluid systems spraying through conventional nozzles have had limited success in the aftermarket but have recently emerged on the original equipment market to augment windshield and wiper deicing performance of warm air defroster systems. Electrical overheating failure has resulted in at least one major product recall. One of the world's largest automakers has recently offered a heated washer system feature available on numerous models, and other automakers have also been planning to offer this feature. Still, even these systems exhibit poor performance, functionality and reliability in the opinion of many users. Although these heated washer systems can reduce the FMVSS103 defrost time from typically 15-25 minutes down to 5-10 minutes, drivers still desire much faster defrosting. Also, when driving in winter icing and blizzard conditions in which visibility becomes poor from iced up wipers and windshield, even with the aid of the warm air defroster on maximum output, available heated washer systems fail to quickly and effectively clear ice and often the driver still has to manually deice the wipers and windshield to achieve safe driving visibility. These heated washer systems commonly do not respond instantly upon driver demand to spray heated washer fluid. Fluid spray is delayed for 30-45 seconds while a small amount of fluid, e.g. 2 ounces, heats up to provide only a 2-3 second spray after which time there is another long delay to heat another small amount of fluid. This process typically takes about 2½ minutes to complete one deice cycle, with repeat cycles often needed. Confusing heated washer driver operated switch controls, along with already and increasingly complex modern instrument panel controls and displays, further add to the complexity and cost of these systems.
Heated washer systems using heat from engine coolant have long been available but also have had little success in the marketplace largely due to slow time to warm up upon engine cold start, low heat transfer rates, issues with washer heater freeze up damage and the heater purging its fluid from boiling of the high vapor pressure alcohol antifreeze laden washer fluid (about 158° F. boiling temperature) in the presence of 200+° F. engine coolant temperatures. Purging not only can waste washer fluid but, more importantly, causes significant delay in spray time from the resulting empty washer fluid heater having to become refilled, and the cold fluid then entering the heater does not have sufficient time to fully heat up as it quickly passes through the heater to get sprayed to the windshield. This limited fluid heat up from quick passage through the heater is largely due the commonly known heat transfer phenomenon of fluid boundary layer thickness (basically defined as the distance of the zero velocity fluid immediately adjacent the flow channel wall to the point at which there is 99% of the maximum flow velocity). In either laminar or turbulent flow, just a modestly thick boundary layer (e.g. 0.10 inches typical of tubular heaters) can prevent very high heat transfer flux in even otherwise well designed heat exchangers. Fortunately, because of relatively low required flow rate and pumping time of the washer fluid pump, and relatively low flow rate requirement of engine coolant (or heat pump fluid or other lower flow rate heating fluid) in the cabin heater circuit, it is possible to construct a very simple compact heat exchanger having an unusually high heat transfer rate. This heater concept, described as the object of this patent application, will have rather high, yet acceptable, flow restriction, with extremely low liquid volume relative to the area of the heat transfer fluid chambers, and with the extremely low liquid volume will therefore be inherently freeze protected because of the small freeze expansion of the small amount of fluid. Its heat transfer flux will be very high by virtue of the forced ultra thin, and therefore extremely low thermal resistance, boundary layers simply by virtue of uniformly and extremely thin flow channel construction, e.g. 0.010 inches (resulting in less than 0.005 inches thick boundary layer), of the washer fluid to be heated flow chamber and engine coolant heating fluid flow chamber. After extensively researching related subject matter this inventor has discovered no prior art of washer fluid heater or other multi liquid heat exchanger construction to make advantage this concept.
To avoid a contributing cause of windshield cracking automakers are known to limit heated washer fluid temperature contacting the windshield to no more than about 125° F. The concentrated thermal shock from hotter fluid than this coming from fluid concentrating conventional nozzles onto sensitive areas of the windshield, such as a small stone crack, scratch or subtle stress concentration at the windshield mounting edge, can readily propagate a large crack in the glass.
Heated washer fluid spray concentrating, and therefore high windshield thermal shocking, conventional nozzles, even of the wider spraying fluidic and spray fanning types, fail to provide the very high degree of broad and uniform heated fluid distribution needed to bring out the great deicing and bug clearing performance capability of an otherwise well engineered heated washer system. Only well designed heated fluid delivering wiper blades provide “close proximity to glass” fluid delivery and near perfectly uniform broad distribution that maximizes defrosting, deicing and bug cleaning performance, while minimizing washer fluid usage, and prove to be the most effective washing means. This broad and uniform distribution enables much higher temperature (e.g. 150° F.-175° F.) fluid to be safely delivered with minimal thermal shock for improved deicing and cleaning and without risk of windshield cracking or scalding of persons.
Another deficiency of available heated washer systems is that they cause the heated fluid to lose a large part of its heat energy through rapid wind chill evaporative cooling of the contained high vapor pressure alcohol antifreeze as the fluid sprays from the nozzles a foot or two through the cold air before reaching the mid and upper reaches of the windshield. The resulting large amount of midair condensing visible steam on actual tests by this inventor is clear evidence of this energy loss. This sudden cloud of steam can also cause momentary reduction of driver visibility, e.g. while making a left turn in the presence of oncoming traffic on a sunny day. Actual testing of my well designed fluid delivering squeegee wiper blade, as subsequently described herein, demonstrates almost total absence of this evaporative energy loss, with a resulting 50% or greater reduction in windshield deice time and fluid usage as compared with using heated fluid through conventional nozzles.
Often washer systems will be filled with water based fluid having insufficient antifreeze which subsequently freezes solid and causes washer heater permanent damage from ice expansion pressure. Washer heater design features to provide freeze protection typically add cost, and the increased complexity can run counter to increasing reliability.
Another shortcoming of available washer fluid heaters is that their effectiveness is inherently limited because, in between the short electronically programmed heated fluid squirts, the remaining heat of the fluid on the windshield and the now slightly warmed glass is quickly dissipated by evaporation and wind chill during the frequent and long fluid reheating delays between these short squirts. The result is delayed defrosting and even partial windshield refreezing while awaiting subsequent programmed heated short squirts which have to reheat the remaining ice to its melting point. This results in extended defrost times best measured in minutes. However actual testing of proof of concept working models of my invention demonstrates if the total heat energy required to melt and clear the ice is delivered in one relatively quick, continuous and very evenly distributed amount of heated fluid directly from the wiper blade rubber squeegee onto the windshield the time for complete defrosting is dramatically reduced to seconds.
Another deficiency of available washer fluid heaters is that they are prone to building up calcium scale and other mineral deposits from the long term heating of washer fluid continuously stored within the heating chamber. This is the same mechanism that causes heavy lime scale buildup in a teapot simmering water over a long period of time. These deposits can choke fluid passage, cause loss of heat transfer efficiency and break loose and clog washer nozzles.
A new heated washer system is needed which will fulfill the following requirements:
The present invention provides a windshield washer fluid heater which overcomes the above-mentioned disadvantages of the previously known systems and fulfills the above stated nine requirements.
In brief, in a first preferred embodiment of the present invention, the heater includes an elongated housing which defines an elongated housing chamber. A subhousing is disposed in the housing chamber which divides the housing chamber into an outer housing chamber between the housing and the subhousing, and an inner housing chamber inside the subhousing. The subhousing is constructed of a thermally conductive material and the inner and outer housing chambers are fluidly isolated from each other.
A core is disposed inside the inner housing chamber thus forming an annular chamber between the core and the subhousing. Preferably, the core is dimensioned so that the ratio of the (area of the core)/(volume of the annular chamber) for the annular chamber exceeds 700 meters2/meters3. Consequently, the width of the annular chamber in the transverse direction is very small compared to the transverse size of the core.
A washer fluid inlet is open to the subhousing on one end of the annular chamber while a washer fluid outlet is open to the subhousing at the other end of the annular chamber. Similarly, an engine coolant inlet is open to the outer housing chamber while an engine coolant outlet is also open to the outer chamber at a position spaced from the inlet. Consequently, engine coolant flow into the engine coolant inlet flows through the outer housing chamber and to the engine coolant outlet.
In operation, the engine coolant rapidly warms washer fluid flowing through the annular chamber which is then expelled onto the engine windshield.
As an alternative to a coolant housed chamber, an electric heater can be utilized to heat the subhousing.
Even though the heated windshield wiper fluid can be sprayed directly onto the windshield from the automotive body, preferably the heated windshield wiper fluid is fluidly connected to a conduit in a windshield wiper blade. That windshield wiper blade, in turn, includes apertures provided through it to spray the heated wiper fluid onto the windshield.
A better understanding of the present invention will be had upon reference to the following detailed description when read in conjunction with the accompanying drawing, wherein like reference characters refer to like parts throughout the several views, and in which:
Warm engine coolant flows from the off center inlet hose barb 1 through an outer housing chamber 2 to the opposite end 22 of the heater then crosses over to the opposite side outer finned annulus half circular heat transfer chamber 3 and returns to the outlet hose off center barb 4. Outer finned half annuli 2 and 3 are sealingly separated at linear contact points 18 for the full length of the finned annuli and at coolant barb end dam 18a. Cold washer fluid 5 enters at its on-center inlet barb 6 on one end of the heater and flows very evenly distributed through the inner finned heat transfer chamber 7 with matching male finned and very closely and evenly spaced—approximately 0.010 inch constant clearance—center core 8, to opposite end on-center heated fluid outlet barb 9. The intermediate outer fined/inner finned member 10 is typically of aluminum extrusion construction having high heat conductivity and partially defines the heated fluid (e.g. washer fluid) flow heat transfer chamber 7 and is fluidly disposed in series between the source of a cleaning fluid to be heated, washer pump and reservoir 11 and a check valve 12 and a fluid nozzle 13 or 13a (re.
The outer surface 17 of the intermediate outer finned/inner finned member 10 forms a second fluid flow chamber 33 for engine coolant in conjunction with an outer housing 21 sealingly enclosing the washer fluid inner chamber enclosure 10 plus barbed end caps 6 and 9 with O-ring seals 15a and 16a. The outer surface 17 of the intermediate outer finned/inner finned member 10 is shaped with a plurality of closely and uniformly spaced heat conducting fins, all of which maintain a close fin tip clearance 31 or having contact with the inner wall 32 of the outer housing 21, except for two opposing fins which are always in longitudinally sealing contact at points 18 with the inner surface of the outside housing 21 to form the finned half annulus flow channels 2 and 3 in connection with dam 18a for the coolant to flow from the inlet hose barb 6 through one half 2 of the outer housing chamber to the opposite end 22 then cross over to flow back outwardly through the opposite half 3 of the outer housing chamber to the coolant outlet hose barb 4. The outside housing 21 is typically constructed of low heat conductivity high strength proven automotive cooling system material such as fiberglass filled nylon or polyphenylene sulfide (PPS) and can have integral fins 23 mimicking with close clearance (e.g. 0.010 in.-0.020 in.) to the outer fins of the aluminum intermediate member 10. The outer housing 21 may be constructed of a higher strength metal if necessary as might be required with the heater being applied in a higher pressure and hotter heat source system. In the case of a very high pressure, high temperature heat source such as a CO2 heat pump, in order to better contain the pressure the inner finned flow chamber may be used for the heating (CO2) fluid and the outer finned chamber for the lower pressure (washer) fluid to be heated. The outer housing coolant inlet barb 1 and outlet barb 4 are for connection with the engine coolant line preferably in series with the cabin heater line coming from, or returning to the engine, re.
Aluminum parts are anodized or coated as needed for corrosion protection with minimal degradation to heat transfer characteristic.
The heater is preferably mounted in a vertical position with the washer fluid inlet on top and washer fluid outlet on the bottom to facilitate fluid thermal purging back to the reservoir instead of out the nozzles or fluid delivering wiper blades. Also the coolant inlet and outlet barbs are preferably mounted vertically to avoid air entrapment.
Other similarly effective configurations could also be done, such as planar rather than circular which could also provide for three or more fluids, or by switching heating fluid to the inner flow chamber, and the fluid(s) to be heated to the outer flow chamber(s). Also, the outer flow chamber(s) could have the inlet and outlet at opposite ends of the heat exchanger.
Upon activation of the conventional washer/wiper switch the washer fluid quickly (in less than 1 second) fills the very small volume inner washer fluid heating chamber 7 which is often in an empty state, having been purged empty from the alcohol laden low boiling point, about 158° F., washer fluid being heated by the higher thermostatically controlled, about 200° F., engine coolant. The substantially heated fluid emerges instantly from the either conventional nozzles 13 or the preferred wiper squeegee integral nozzles 13a, to provide instantly delivered continuous on demand heated fluid deicing and cleaning action to the windshield and wiper blades.
Because the heater has a very high heat transfer rate, heat recovery time is virtually instantaneous when closely repeated deice/wash cycles are desired. Upon washer shutdown the residual fluid between the heater and the nozzles remains in the washer lines by virtue of check valve 12 while the very small amount of washer fluid in the washer heater might soon purge—because of low alcohol laden washer fluid boiling temperature—back toward the washer reservoir thereby conserving the purged fluid, and stopping calcium/mineral buildup and any significant thermal energy drain from the cabin heater coolant circuit.
Upon engine shutdown in freezing temperatures thermal contraction from cooling may cause washer fluid to be drawn back into the very small washer fluid heating chamber 7. Any subsequent freeze up due to lack of antifreeze solution will leave the fluid heater undamaged primarily by virtue of the very small amount of freeze expansion of the preceding very small amount of contained liquid.
Other preferred embodiments below include electric heating elements as a heat source for more rapid deicing at cold engine start conditions and for use in electric powered vehicles. Similarities in construction and function to the above described embodiment will become apparent.
With reference now to
Preferably, the housing 102 is formed from two housing shells 106 and 108, each of which is substantially cylindrical in shape and having an open end 110 and 112, respectively. The open ends 110 and 112 of the housing shells 106 and 108, respectively, are secured together in any conventional fashion, such as by spin welding.
A generally tubular and cylindrical subhousing 114 is disposed within the housing chamber 104 and divides the housing chamber 104 into an annular outer housing chamber 116 formed between the subhousing 114 and the housing 102, and an inner housing chamber 118 formed within the subhousing 114. The subhousing 114, furthermore, is constructed of a thermally conductive material, preferably a metal such as aluminum, and has a plurality of circumferentially spaced fins 120 (
Referring now to
The annular chamber 126 shown in
The core 122 is made of a thermally conductive material, such as aluminum. As such, the core 122 not only rapidly heats up, but also stores the heat energy.
The height of the standoffs 124 defines the radial thickness of the annular chamber 126. As best shown in
As best shown in
Referring now to
Optionally, a filter may be associated with the washer fluid inlet 130 to prevent debris from entering into the interior of the subhousing 114.
In operation, the windshield wiper fluid inlet 130 is connected to a source of pressurized windshield washer fluid, such as the windshield washer fluid pump found on most vehicles. The windshield washer fluid outlet 134 is then fluidly connected to either spray jets mounted on the vehicle and directed to the vehicle windshield or to a windshield wiper blade such as the type already previously described. Consequently, upon activation of the windshield washer fluid pump, windshield washer fluid is pumped into the inlet 130, through the annular chamber 126 and out through the washer fluid outlet 134.
Simultaneously, heated engine coolant fluid flows into the coolant inlet 150, through the outer housing chamber 104 and out through the coolant outlet 152. Although some leakage of engine coolant may flow directly from the inlet 150 and to the outlet 152 without flowing longitudinally along the length of the housing 102, a majority of the coolant flow through the housing 102 is channeled by the fins 116 on the subhousing 114 from one end 133 of the housing 102 and to its other end 132 as shown by arrows 154. A fluid dam 155 (
In order to channel the engine coolant entirely through the outer housing chamber 104 and minimize leakage directly from the coolant inlet 150 to the coolant outlet 152, preferably an interference fit is created between the fins 120 and the housing 102.
In operation, the heat from the engine coolant is conducted by the subhousing 114 to heat the windshield washer fluid in the annular chamber 126. Since the ratio of the wetted area of the annular chamber 126 to the volume of the chamber 126 is so high, the heating of the windshield washer fluid in the annular chamber 126 is not only rapid, but nearly complete. Indeed, the temperature of the windshield washer fluid from the outlet 134 approximates the temperature of the engine coolant.
As a practical matter, after use of the windshield washer system, any windshield washer fluid contained within the annular chamber 126 will simply boil off back to the reservoir.
Having described my invention, it can be seen that the present invention provides a simple and yet highly effective heated windshield wash fluid system which both quickly and effectively deices and defrosts an automotive vehicle windshield and wiper. Having described my invention, however, many modifications thereto will become apparent to those skilled in the art to which it pertains without deviation from the spirit of the invention as defined by the scope of the appended claims.
This application claims priority of U.S. Provisional Patent Application Ser. No. 61/089,577 filed Aug. 18, 2008, which is incorporated herein by reference.
Number | Name | Date | Kind |
---|---|---|---|
1153095 | Martin | Sep 1915 | A |
1228482 | Schonger | Jun 1917 | A |
1410487 | McCarty | Mar 1922 | A |
1465292 | Wessig | Aug 1923 | A |
1490168 | Ford | Apr 1924 | A |
1556030 | Redshaw | Oct 1925 | A |
1650922 | Worthington | Nov 1927 | A |
1733408 | Herber | Oct 1929 | A |
1835833 | Williams | Dec 1931 | A |
1917141 | Middleton | Jul 1933 | A |
1933220 | Petree | Oct 1933 | A |
2002426 | Allyne | May 1935 | A |
2032998 | Mickadelt | Mar 1936 | A |
2056776 | Evans et al. | Oct 1936 | A |
2125154 | Dillon | Jul 1938 | A |
2258922 | Albee | Oct 1941 | A |
2260904 | Horton | Oct 1941 | A |
2357426 | Patterson | Jan 1945 | A |
2576198 | Stuart | Nov 1951 | A |
2662154 | Cochran | Dec 1953 | A |
2738408 | Cheviron | Mar 1956 | A |
2839773 | McMillen | Jun 1958 | A |
2847193 | Carter | Aug 1958 | A |
2894730 | Agule | Jul 1959 | A |
2900168 | Nyborg | Aug 1959 | A |
2947020 | Wilfert | Aug 1960 | A |
2968071 | Di Perna | Jan 1961 | A |
3135004 | Naigraw | Jun 1964 | A |
3243119 | Merkle | Mar 1966 | A |
3292866 | Benner | Dec 1966 | A |
3319891 | Campbell | May 1967 | A |
3321792 | Senkewich | May 1967 | A |
3366336 | Neuschwanger et al. | Jan 1968 | A |
3371368 | Walker | Mar 1968 | A |
3408678 | Linker | Nov 1968 | A |
3416428 | Heller | Dec 1968 | A |
3427675 | Tibbet | Feb 1969 | A |
3447186 | Senkewich | Jun 1969 | A |
3473348 | Bottum | Oct 1969 | A |
3479689 | Kurzke et al. | Nov 1969 | A |
3489884 | Waseleski, Jr. | Jan 1970 | A |
3493041 | Hourwitz et al. | Feb 1970 | A |
3560706 | Fonseca | Feb 1971 | A |
3568766 | Thomas | Mar 1971 | A |
3574881 | Temple | Apr 1971 | A |
3591887 | Keddie | Jul 1971 | A |
3632042 | Goulish et al. | Jan 1972 | A |
3688081 | Speich | Aug 1972 | A |
3738252 | Cardinale | Jun 1973 | A |
3756510 | Nitterl et al. | Sep 1973 | A |
3757088 | Osborn | Sep 1973 | A |
3835294 | Krohn et al. | Sep 1974 | A |
3868492 | Taylor | Feb 1975 | A |
3887004 | Beck | Jun 1975 | A |
3888412 | Lindo | Jun 1975 | A |
3935425 | Weissberger et al. | Jan 1976 | A |
4037286 | Medearis et al. | Jul 1977 | A |
4059882 | Wunder | Nov 1977 | A |
4085308 | Youngquist | Apr 1978 | A |
4088269 | Schlick | May 1978 | A |
4090668 | Kochenour | May 1978 | A |
4096616 | Coffinberry | Jun 1978 | A |
4096910 | Coffinberry et al. | Jun 1978 | A |
4109133 | Hanle et al. | Aug 1978 | A |
4127763 | Roselli | Nov 1978 | A |
4132881 | Ciarniello et al. | Jan 1979 | A |
4139761 | Obrowski | Feb 1979 | A |
4145788 | Ferrarelli | Mar 1979 | A |
4177928 | Bergkvist | Dec 1979 | A |
4180723 | Szupillo | Dec 1979 | A |
4212425 | Schlick | Jul 1980 | A |
4236548 | Howard | Dec 1980 | A |
4276501 | Fanz | Jun 1981 | A |
4285540 | Harada et al. | Aug 1981 | A |
4354548 | Carlsson | Oct 1982 | A |
4387290 | Yasuda | Jun 1983 | A |
4508957 | Rocchitelli | Apr 1985 | A |
4575003 | Linker et al. | Mar 1986 | A |
4665351 | Nyberg | May 1987 | A |
4700424 | Hagen | Oct 1987 | A |
4763381 | Williams | Aug 1988 | A |
4821363 | Delluc | Apr 1989 | A |
4821797 | Allgauer et al. | Apr 1989 | A |
4832262 | Robertson | May 1989 | A |
4834172 | Duran | May 1989 | A |
4862951 | Muller et al. | Sep 1989 | A |
4895203 | McLaren | Jan 1990 | A |
4910380 | Reiss et al. | Mar 1990 | A |
4967437 | Morse | Nov 1990 | A |
5010289 | Takada | Apr 1991 | A |
5046216 | Baungarter et al. | Sep 1991 | A |
5065471 | Laplante | Nov 1991 | A |
5099909 | Barigelli et al. | Mar 1992 | A |
5118040 | Abe | Jun 1992 | A |
5221828 | Basheer et al. | Jun 1993 | A |
5264962 | Kho | Nov 1993 | A |
5325561 | Kotlar | Jul 1994 | A |
5327614 | Egner-Walter et al. | Jul 1994 | A |
5354965 | Lee | Oct 1994 | A |
5383247 | Nickel | Jan 1995 | A |
5426814 | Minnick | Jun 1995 | A |
5509606 | Breithaupt et al. | Apr 1996 | A |
5522453 | Green | Jun 1996 | A |
RE35890 | So | Sep 1998 | E |
5881428 | Simmons | Mar 1999 | A |
6032324 | Lansinger | Mar 2000 | A |
20040118939 | Shank et al. | Jun 2004 | A1 |
20070295825 | McNaughton | Dec 2007 | A1 |
Number | Date | Country |
---|---|---|
197803 | Apr 1908 | DE |
2011695 | Sep 1971 | DE |
2914183 | Apr 1979 | DE |
1194037 | Nov 1959 | FR |
2191390 | Dec 1987 | GB |
2001-171487 | Jun 2001 | JP |
WO 2005104690 | Nov 2005 | WO |
Entry |
---|
International Search Report and Written Opinion dated Feb. 8, 3012 in relation to PCT/US12/067822. |
Number | Date | Country | |
---|---|---|---|
20100037415 A1 | Feb 2010 | US |
Number | Date | Country | |
---|---|---|---|
61089577 | Aug 2008 | US |