Field of the Invention
This invention relates to semiconductor devices, and in particular to light emitting devices capable of wire bond free fabrication and operation.
Description of the Related Art
Light emitting diodes (LED or LEDs) are solid state devices that convert electric energy to light, and generally comprise one or more active layers of semiconductor material sandwiched between oppositely doped layers. When a bias is applied across the doped layers, holes and electrons are injected into the active layer where they recombine to generate light. Light from the active layer is emitted from all surfaces of the LED.
There has been a great deal of recent interest in LEDs formed of Group-III nitride based material systems because of their unique combination of material characteristics including high breakdown fields, wide bandgaps (3.36 eV for GaN at room temperature), large conduction band offset, and high saturated electron drift velocity. The efficient extraction of light from LEDs is a major concern in the fabrication of high efficiency LEDs. For conventional LEDs with a single out-coupling surface, the external quantum efficiency is limited by total internal reflection (TIR) of light from the LED's emission region that passes through the substrate. TIR can be caused by the difference in the refractive index between the LED semiconductor and surrounding ambient, as predicted by Snell's Law. This difference results in a small escape cone from which light rays from the active area can transmit from the LED surfaces into the surrounding material and ultimately escape from the LED package.
Different approaches have been developed to reduce TIR and improve overall light extraction, with one of the more popular being surface texturing. Surface texturing increases the escape probability of the light by providing a varying surface that allows photons multiple opportunities to find an escape cone. Light that does not find an escape cone continues to experience TIR, and reflects off the textured surface at different angles until it finds an escape cone. The benefits of surface texturing have been discussed in several articles. [See Windisch et al., Impact of Texture-Enhanced Transmission on High-Efficiency Surface Textured Light Emitting Diodes, Appl. Phys. Lett., Vol. 79, No. 15, October 2001, Pgs. 2316-2317; Schnitzer et al. 30% External Quantum Efficiency From Surface Textured, Thin Film Light Emitting Diodes, Appl. Phys. Lett., Vol. 64, No. 16, October 1993, Pgs. 2174-2176; Windisch et al. Light Extraction Mechanisms in High-Efficiency Surface Textured Light Emitting Diodes, IEEE Journal on Selected Topics in Quantum Electronics, Vol. 8, No. 2, March/April 2002, Pgs. 248-255; Streubel et al. High Brightness AlGaNInP Light Emitting Diodes, IEEE Journal on Selected Topics in Quantum Electronics, Vol. 8, No. March/April 2002].
U.S. Pat. No. 6,657,236, assigned to Cree Inc., discloses structures for enhancing light extraction in LEDs through the use of internal and external optical elements formed in an array. The optical elements have many different shapes, such as hemispheres and pyramids, and may be located on the surface of, or within, various layers of the LED. The elements provide surfaces from which light refracts or scatters. Also, a reflective material may be used to coat one or more of the layers of the device to enhance light extraction by reflecting light emitted from the active layers away from the substrate or other photon absorbing materials.
Another method used to fabricate more efficient semiconductor devices is called flip-chip mounting. Flip-chip mounting of LEDs involves mounting the LED onto a submount substrate-side up. Light is then extracted and emitted through the transparent substrate, or the substrate may be removed altogether. Flip-chip mounting is an especially desirable technique for mounting SiC-based LEDs. Since SiC has a higher index of refraction than GaN, light generated in the active region does not internally reflect (i.e. reflect back into the GaN-based layers) at the GaN/SiC interface. Flip-chip mounting of SiC-based LEDs offers improved light extraction when employing certain chip-shaping techniques known in the art. Flip-chip packaging of SiC LEDs has other benefits as well, such as improved heat extraction/dissipation, which may be desirable depending on the particular application for the chip.
Significant effort has been invested in developing a white light LED. Conventional LEDs cannot generate white light, i.e., a broad spectrum, directly from their active layers. Light from a blue emitting LED has been converted to white light by surrounding the LED with a yellow emitting phosphor, polymer or dye, with a typical phosphor being cerium-doped yttrium aluminum garnet (Ce:YAG). [See Nichia Corp. white LED, Part No. NSPW300BS, NSPW312BS, etc.; See also U.S. Pat. No. 5,959,316 to Lowrey, “Multiple Encapsulation of Phosphor-LED Devices”]. The surrounding phosphor material “downconverts” the wavelength of some of the blue light, changing its color to yellow. Some of the blue light passes through the phosphor without being changed while a substantial portion of the light is downconverted to yellow. The LED emits both blue and yellow light, which combine to provide a white light. In another approach light from a violet or ultraviolet emitting LED has been converted to white light by surrounding the LED with multicolor phosphors or dyes.
LED devices are often described as having a vertical geometry or a lateral geometry as shown in
In response to an applied bias, current and charge carriers move through the device 100 vertically with respect to the semiconductor surfaces. Radiative recombination occurs in the active region 102 and light is emitted. Some of the emitted light has its wavelength downconverted in the phosphor layer, resulting in a desired emission spectrum.
The bias is applied to the device 200 through electrodes 212, 214. Current and charge carriers move laterally through the device between the electrodes 212, 214. A percentage of the carriers recombine in the active region 202, causing light to be emitted. Some of the emitted light has its wavelength downconverted in the phosphor layer 220, enabling the device to emit light with desired wavelength spectrum.
One disadvantage inherent to all of these exemplary configurations is that their design prevents package level components such as, for example, a phosphor layer or an encapsulation structure from being applied until after the device is singulated and mounted in a conventional LED package. In some cases the constraint is caused by the need to connect the device to an outside voltage source using a wire bond or other similar means of connection. In other cases the constraint is caused by the need to coat the sides of the substrate with phosphor to prevent too much blue light from escaping without being downconverted.
The invention as embodied in the claims discloses a new semiconductor device, such as an LED chip, that has two bottom-side electrical contacts, allowing for wire bond free fabrication. One embodiment of a semiconductor device according to the present invention comprises an active region interposed between an n-type semiconductor layer and a p-type semiconductor layer. A p-electrode is disposed such that a lead is accessible from a point on the surface of the device opposite the primary emission surface. The p-electrode is electrically connected to the p-type layer. An n-electrode is also disposed such that a lead is accessible from a point on the surface of the device opposite the primary emission surface. The n-electrode is electrically connected to the n type layer. The p-electrode and the n-electrode are thick enough to provide primary mechanical support for the semiconductor device.
Another embodiment of a semiconductor device having top and bottom surfaces and first and second edge surfaces comprises a base element thick enough to provide structural support for said semiconductor device. An active region is interposed between a first semiconductor layer and a second semiconductor layer such that the second semiconductor layer is disposed on the base element. A first electrode electrically contacts the first semiconductor layer and has a lead that is accessible from the bottom surface. The first electrode is disposed substantially perpendicular to the bottom surface and constitutes at least a portion of the first edge surface. A first spacer layer is disposed to isolate the first electrode from the second semiconductor layer and the base element.
A method for fabricating semiconductor devices according to the present invention is also disclosed. First and second semiconductor layers and an active region are grown on a growth substrate. A portion of the surface of the first semiconductor layer opposite the growth substrate is exposed. A spacer layer is formed on the second semiconductor layer and the exposed portion of the first semiconductor layer. A portion of the spacer layer is removed such that a portion of the first and second semiconductor layers is exposed. An electrode layer is formed on the remaining portions of the spacer layer and the exposed portions of the first and second semiconductor layers. The growth substrate is removed. A portion of the electrode layer is removed to form first and second electrodes such that the first electrode is electrically contacting the first semiconductor layer and the second electrode is electrically contacting the second semiconductor layer. The first and second electrodes are disposed to be electrically isolated from one another.
Another embodiment of a semiconductor device comprises an n-type semiconductor layer, a p-type semiconductor layer having at least one via, and an active region interposed between the n-type and p-type layers. The active region has at least one via corresponding to the at least one via in the p-type layer, such that a portion of the n-type layer adjacent to the active region is exposed. The at least one p-electrode has a lead that is accessible on a surface opposite of a primary emission surface of the semiconductor device. The at least one p-electrode is electrically connected to the p-type layer. The at least one n-electrode has a lead that is accessible on a surface opposite of the primary emission surface. The at least one n-electrode is electrically connected to the n-type layer. The at least one p-electrode and the at least one n-electrode are thick enough to provide primary mechanical support for the semiconductor device.
These and other aspects and advantages of the invention will become apparent from the following detailed description and the accompanying drawings which illustrate by way of example the features of the invention.
The present invention as embodied in the claims enables wafer-level packaging of semiconductor devices, such as high efficiency light emitting diode (LED) devices, for example. The claims also teach a method for fabricating these devices. Similarly, as in other semiconductor devices, a bias voltage is applied across the device and light is emitted as a result of radiative recombination in the active region of the device. Various elements and procedures can be used to increase the light output of the device. For example, layers of materials functioning as mirrors or refractors can be formed at certain locations within the device to redirect emitted light away from photon absorbing materials such as the substrate. Another method often employed in the art is to roughen or texture one or more of the layers to prevent total internal reflection. Such features are typically added at the wafer level of fabrication.
It is sometimes desirable to alter the emission spectrum of an LED device by shifting the frequency of a portion of the emitted light using a layer of material with wavelength conversion properties, such as phosphor, for example. In order to shape an optical beam or otherwise alter the properties of the emitted light, an encapsulant may be added over the device. These encapsulants typically have characteristics that affect the emitted light in some intended fashion. For example, an encapsulant may function as a lens, focusing or collimating the emitted light to achieve a particular beam profile. Features such as conversion layers and encapsulants, often referred to as packaging elements, are typically added to the device after a device has been mounted and wire bonded in a conventional LED package. Wire bonds are lead wires that provide electrical paths from an outside voltage/current source to the internal semiconductor layers, allowing a voltage bias to be applied to the device. Because the structures and methods disclosed in the claims obviate the need for wire bonds, packaging elements may be added to the device at the wafer level, i.e., prior to being mounted and wired bonded in a conventional LED package. The new design provides additional flexibility, permitting customers to specify additional features that may be realized at the wafer level. Also, because the features may be added to the chip at the wafer level rather than at a later packaging level, the cost to produce the chip is significantly reduced.
It is understood that when an element such as a layer, region or substrate is referred to as being “on” another element, it can be directly on the other element Or intervening elements may also be present. Furthermore, relative terms such as “inner”, “outer”, “upper”, “above”, “lower”, “beneath”, and “below”, and similar terms, may be used herein to describe a relationship of one element to another. It is understood that these terms are intended to encompass different orientations of the device in addition to the orientation depicted in the figures. Additionally, terms such as “bottom” and “top” are used to describe the spatial relationship of elements to one another as they appear in a particular exemplary figure that is being discussed. Such terms are used only for the convenience of the reader and not for the purpose of limiting the device to a particular orientation during fabrication, operation or otherwise.
Although the terms first, second, etc. may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections should not be limited by these terms. These terms are only used to distinguish one element, component, region, layer or section from another region, layer or section. Thus, a first element, component, region, layer or section discussed below could be termed a second element, component, region, layer or section without departing from the teachings of the present invention.
It is noted that the terms “layer” and “layers” are used interchangeably throughout the application. A person of ordinary skill in the art will understand that a single “layer” of semiconductor material may actually comprise several individual layers of material. Likewise, several “layers” of material may be considered functionally as a single layer. In other words, the term “layer” does not denote an homogenous layer of semiconductor material. A single “layer” may contain various dopant concentrations and alloy compositions that are localized in sub-layers. Such sub-layers may function as buffer layers, contact layers or etch-stop layers, for example. These sub-layers may be formed in a single formation step or in multiple steps. Unless specifically stated otherwise, the Applicant does not intend to limit the scope of the invention as embodied in the claims by describing an element as comprising a “layer” or “layers” of material.
Embodiments of the invention are described herein with reference to cross-sectional view illustrations that are schematic illustrations of idealized embodiments of the invention. As such, variations from the shapes of the illustrations as a result, for example, of manufacturing techniques and/or tolerances are expected. Embodiments of the invention should not be construed as limited to the particular shapes of the regions illustrated herein but are to include deviations in shapes that result, for example, from manufacturing. A region illustrated or described as square or rectangular will typically have rounded or curved features due to normal manufacturing tolerances. Thus, the regions illustrated in the figures are schematic in nature and their shapes are not intended to illustrate the precise shape of a region of a device and are not intended to limit the scope of the invention.
The substrate 402 can be made of many materials such as sapphire, silicon carbide, aluminum nitride (AlN), GaN, with a suitable substrate being a 4H polytype of silicon carbide, although other silicon carbide polytypes can also be used including 3C, 6H and 15R polytypes. Silicon carbide (SiC) has certain advantages, such as a closer crystal lattice match to Group III nitrides than sapphire and results in Group III nitride films of higher quality. SiC substrates are available from Cree Research, Inc., of Durham, N.C. and methods for producing them are set forth in the scientific literature as well as in U.S. Pat. No. Re. 34,861; U.S. Pat. No. 4,946,547; and U.S. Pat. No. 5,200,022.
Although it is possible to grow either n-type or p-type layers first on a growth substrate, it may be preferable to grow the n-type layers first. This is the case for several reasons that are known in the art. One reason for growing the n-type layers first is that they are grown at higher temperatures than the p-type layers; n-type layers are grown at temperatures around 1100° C., and p-type layers are grown around 900° C. When p-type layers are subjected to temperatures in excess of 900° C., the dopant material (often magnesium) can diffuse into adjacent layers, reducing the quality of the layer. Thus, once the n-type layers have been grown on the substrate, subsequent p-type layers can be grown at lower temperatures that do not substantially affect the n type layers that have already been formed. Another reason for growing n-type layers first is that layers grown on the substrate must be grown for longer periods of time to overcome the lattice mismatch at the substrate interface. Layers grown longer are grown thicker. Because p-type layers are more light-absorbent than n-type layers, it is desirable to have a thicker n-type layer so that less emitted light is absorbed.
In
A portion of the n-type layer 404 is exposed using a known etching process, chlorine reactive ion etching for example, or another process that is known in the art. A conductive n-pad 410 is formed on an exposed portion of the n-type layer 404 which is shown extending laterally beyond the edges of the active region 408 and the p-type layer 406. A p-pad 412 is formed on the exposed surface of the p-type layer 406. The n-pad 410 and p-pad 412 function as contacts that will facilitate an electrical connection between the semiconductor layers 404, 406 and leads that will be added at a later stage in the fabrication process as discussed below. The pads 410, 412 may comprise a conductive metal material such as gold, silver or copper, for example.
In the configuration shown, p-pad 412 may be formed from a reflective material, such as aluminum, silver, gold, rhodium, platinum, palladium, gold tin or combinations thereof. These reflective materials can be deposited on the surface of p-type layer 406 using conventional methods, such as sputtering. Using a reflective material to form the p-pad 412 may increase the light extraction efficiency of the device 400 by redirecting light emitted from the active region 408 that might otherwise be absorbed by layers and elements below the p-pad, such as spacer elements or electrodes, both of which are discussed in detail below.
In
The spacing material is then patterned using a known process to expose a portion of both the n-pad 410 and the p-pad 412, leaving some of the spacing material 414 to remain, as shown in
In
The substrate 402 may be removed and the top surface of the n-type layer 404 may be modified as shown in
Once the n-type layer 404 is exposed, it may be processed in several different ways. It may be desirable to modify (e.g., texture or roughen) various surfaces on or within the device to provide a multitude of angled surfaces and increase light extraction. A modified surface improves light extraction by providing a varying surface that allows light that would otherwise be trapped in the LED, by total internal reflection (TIR), to escape as emitted light. The variations in the modified surface increase the chances that the light will reach an emission surface within the critical angle (as defined by Snell's law) and will be emitted. For light that does not escape through the modified surface, the variations of the modified surface reflect the light at different angles, increasing the chances that the light will escape on the next pass after reflecting off the p-pad.
There are several known methods by which a semiconductor surface may be modified. The surface may have portions removed by processes such as etching, grinding or ablation. It is also possible to add material, such as nanoparticles or light extraction elements for example, to the surface in order to give it a non-uniform texture. Adding light extraction structures to a surface within the device is discussed at length in U.S. Pat. No. 6,657,236 assigned to Cree, Inc. A combination of any of these processes may also achieve the desired surface modifications.
Although the modified surface 420 is shown as a surface of the n-type layer 404 opposite the active region 408 in
A portion of the thick metal layer 418 is then etched away using a known method such that two separate metal electrodes are defined as shown in
In other embodiments, different process steps may be used to achieve a device configuration similar to that shown in
In
The new arrangement, one embodiment of which is shown in
In another embodiment, the n-electrode 422 and the spacer elements 416 that are shown on the right side of
Although the embodiment shown in
A phosphor layer 718 can be formed on the top surface of the current spreading layer 710. The phosphor layer may cover other surfaces as well, such as the side surfaces of the device 700. As discussed above, the phosphor layer 718 performs a wavelength conversion function and may be provided in a number of known binders such as, for example, epoxy, silicone or low-temperature glass. The phosphor layer 718 may be formed by, for example, dispensing, screen printing, jet printing, molding, spin coating, or by mounting a previously made component.
A reflective layer 720 may be added to the device 700 to improve the external quantum efficiency. In the embodiment shown in
In other embodiments, the substrate 707 may comprise a conductive material such as n-type SiC, allowing for an electrical connection to the bottom semiconductor layer and obviating the need for the n-electrode. In this case, n-electrode 712 and spacer element 716 would be unnecessary and reflective layer 720 and substrate 707 would extend such that their right edge would be flush with or even beyond the right edges of the semiconductor layers 702, 704, 706. The electrical connection to the n-type layer 706 would run from the bottom surface of the device 700 up through the conductive substrate and reflective layer up to the layer 706.
The opening created by the removal of the substrate 707 can be filled to create a base element 806 comprising a material such as polyimide, for example. Base element 806 adds structural support to the device 800. In other embodiments, the base element may comprise a conductive material such as aluminum or copper, for example, allowing for an electrical connection to the bottom semiconductor layer and obviating the need for the n-electrode. In this case, n-electrode 712 and spacer element 716 would be unnecessary and reflective layer 804 and base element 806 would extend such that their right edge would be flush with or even beyond the right edges of the semiconductor layers 702, 704, 706. The electrical connection to the n-type layer 706 would run from the bottom surface of the device 700 up through the conductive base element and reflective layer up to the layer 706.
Another embodiment of a semiconductor device 900 according to the claims of the present invention is shown in
The n-electrode 908 is disposed using a known process vertically along the outer edge of the device 900, providing an electrical connection from a lead accessible from the bottom surface of the device 900 to the n-type layer 904. In this embodiment a current spreading layer 910 is shown on the top surface of the n-type layer 904. However, in another embodiment the current spreading layer 910 may be disposed on only a portion of the n-type layer or even omitted as current typically spreads very well through n-type materials. A thin semi-transparent current spreading layer 912 is disposed on the p-type layer 906. A p-electrode 914 extends vertically down from the current spreading layer 912 along the outside of the device 900 such that a lead is accessible from the bottom side of the device 900. As discussed above, because the leads of the electrodes 908, 914 are accessible from the bottom side of the device 900, there is no need for a wire bond to connect the device 900 to an external voltage source.
A reflective layer 916 is disposed on the bottom surface of the current spreading layer 912. The reflective layer 916 may comprise a material that is both reflective and conductive such as mixture of platinum and silver, for example. In another embodiment, the reflective layer may comprise a multilayer stack of dielectric materials such as SiO2/Ta2O5, for example, that comprise a distributed Bragg reflector. A base element 918 that provides structural support is formed below the reflective layer 916. The base element 918 may comprise a thermally conductive material such as copper, for example, and is disposed on the bottom of the reflective layer 916 between the spacer elements 714, 716. The modified surface 920 of the n-type layer 904 enhances the light extraction of the device 900 as discussed above. A phosphor layer 718 is disposed over the current spreading layer 910. The phosphor layer 718 covers all or part of the spreading layer 910. The phosphor layer 718 may also cover the entire top side of the device as well as the sides of the device as shown in
Because current spreads better through n type semiconductor materials, the n-pads 1108 can be much smaller than the p-pads 1110 as shown in
The embodiment shown in
In
In
The p-pad 1312 is then deposited with holes that correspond to the vias, allowing access to the n-type layer 1304. A spacer layer 1316 is then deposited and patterned to expose the p-pad 1312 in some regions and the n-type layer 1304 inside the vias. An n-pad 1310 is then deposited, contacting the n-type layer 1304 in the vias. The n-pad 1310 contacts the n-type layer 1304 in multiple locations and is interconnected throughout the device 1300. In order to provide the interconnectivity, part of the n-pad 1310 overlaps the p-pad 1312. The spacer layer 1316 keeps the n- and p-pads 1310, 1312 electrically isolated. The n- and p-electrodes 1318, 1320 are then formed and the growth substrate removed as discussed above. In another embodiment, the growth substrate may be removed earlier in the fabrication process.
The device 1300 allows for the size and geometry of the electrodes 1318, 1320 to be tailored independently of the n-pad 1310 and the vias through the active layer 1308. This can potentially make packaging the device 1300 simpler and more cost effective. Furthermore, because of the interconnected n-pad 1310 and the large p-pad 1312, current spreading in the semiconductor layers is improved which leads to increased light extraction over the entire active region 1308.
Although the present invention has been described in detail with reference to certain preferred configurations thereof, other versions are possible. Therefore, the spirit and scope of the invention should not be limited to the versions described above.
This application is a continuation of and claims the benefit of U.S. patent application Ser. No. 11/985,410, filed Nov. 14, 2007.
This invention was made with Government support under Contract No. 70NANB4H3037 of the Department of Commerce. The Government has certain rights in this invention.
Number | Name | Date | Kind |
---|---|---|---|
4824767 | Chambers et al. | Apr 1989 | A |
5563079 | Shin et al. | Oct 1996 | A |
5712175 | Yoshida | Jan 1998 | A |
5803579 | Turnbull et al. | Sep 1998 | A |
5959316 | Lowry et al. | Sep 1999 | A |
6132072 | Turnbull et al. | Oct 2000 | A |
6212213 | Weber et al. | Apr 2001 | B1 |
6234648 | Borner et al. | May 2001 | B1 |
6375340 | Biebl | Apr 2002 | B1 |
6395572 | Tsutsui et al. | May 2002 | B1 |
6480389 | Shin | Nov 2002 | B1 |
6486499 | Krames | Nov 2002 | B1 |
6489637 | Sakamoto | Dec 2002 | B1 |
6513949 | Marshall et al. | Feb 2003 | B1 |
6538371 | Duggal et al. | Mar 2003 | B1 |
6547249 | Collins et al. | Apr 2003 | B2 |
6550949 | Bauer et al. | Apr 2003 | B1 |
6552495 | Chang et al. | Apr 2003 | B1 |
6577073 | Shimizu et al. | Jun 2003 | B2 |
6614172 | Chiu | Sep 2003 | B2 |
6642652 | Collins | Nov 2003 | B2 |
6646292 | Steigerwald | Nov 2003 | B2 |
6650044 | Lowery | Nov 2003 | B1 |
6657236 | Thibeault et al. | Dec 2003 | B1 |
6692136 | Marshall et al. | Feb 2004 | B2 |
6784463 | Camras et al. | Aug 2004 | B2 |
6791259 | Stokes | Sep 2004 | B1 |
6809347 | Tasch et al. | Oct 2004 | B2 |
6817735 | Shimizu et al. | Nov 2004 | B2 |
6828596 | Steigerwald et al. | Dec 2004 | B2 |
6841804 | Chen et al. | Jan 2005 | B1 |
6869812 | Heng | Mar 2005 | B1 |
6914267 | Fukasawa et al. | Jul 2005 | B2 |
6936857 | Doxsee et al. | Aug 2005 | B2 |
6946309 | Camras et al. | Sep 2005 | B2 |
6972436 | Li et al. | Dec 2005 | B2 |
7005679 | Tarsa et al. | Feb 2006 | B2 |
7008078 | Shimizu et al. | Mar 2006 | B2 |
7014336 | Ducharme et al. | Mar 2006 | B1 |
7066623 | Lee et al. | Jun 2006 | B2 |
7095056 | Vitta et al. | Aug 2006 | B2 |
7141825 | Horio et al. | Nov 2006 | B2 |
7154125 | Koide et al. | Dec 2006 | B2 |
7160744 | Park et al. | Jan 2007 | B2 |
7213940 | Van de Ven et al. | May 2007 | B1 |
7341878 | Krames | Mar 2008 | B2 |
7388232 | Suehiro et al. | Jun 2008 | B2 |
7439166 | Milosavljevic et al. | Oct 2008 | B1 |
7453092 | Suehiro | Nov 2008 | B2 |
7521862 | Mueller et al. | Apr 2009 | B2 |
7622742 | Kim et al. | Nov 2009 | B2 |
7683377 | Nagai | Mar 2010 | B2 |
7709282 | Fukshima | May 2010 | B2 |
7714342 | Lee et al. | May 2010 | B2 |
7755095 | Nagai | Jul 2010 | B2 |
8106417 | Yoo | Jan 2012 | B2 |
9129977 | Marchand | Sep 2015 | B2 |
9178121 | Edmond | Nov 2015 | B2 |
9219200 | Erchak | Dec 2015 | B2 |
20020125485 | Steigerwald | Sep 2002 | A1 |
20020139987 | Collins et al. | Oct 2002 | A1 |
20020180351 | McNulty et al. | Dec 2002 | A1 |
20020185965 | Collins | Dec 2002 | A1 |
20020190260 | Shen | Dec 2002 | A1 |
20030030063 | Sosniak et al. | Feb 2003 | A1 |
20030124752 | Wei et al. | Jul 2003 | A1 |
20030146411 | Srivastava et al. | Aug 2003 | A1 |
20030218183 | Micovic et al. | Nov 2003 | A1 |
20040105261 | Ducharme et al. | Jun 2004 | A1 |
20040217364 | Tarsa et al. | Nov 2004 | A1 |
20050077531 | Kim | Apr 2005 | A1 |
20050082562 | Ou et al. | Apr 2005 | A1 |
20050082974 | Fukasawa et al. | Apr 2005 | A1 |
20050104080 | Ichihara et al. | May 2005 | A1 |
20050139252 | Shim | Jun 2005 | A1 |
20050149323 | Sawada | Jul 2005 | A1 |
20050211989 | Horio et al. | Sep 2005 | A1 |
20050221527 | Yeh | Oct 2005 | A1 |
20050224821 | Sakano | Oct 2005 | A1 |
20060038190 | Park | Mar 2006 | A1 |
20060043402 | Suehiro | Mar 2006 | A1 |
20060054907 | Lai | Mar 2006 | A1 |
20060063289 | Negley | Mar 2006 | A1 |
20060081869 | Lu et al. | Apr 2006 | A1 |
20060105482 | Alferink et al. | May 2006 | A1 |
20060169994 | Tu | Aug 2006 | A1 |
20060202105 | Krames | Sep 2006 | A1 |
20060273333 | Wu et al. | Dec 2006 | A1 |
20060273335 | Ashara et al. | Dec 2006 | A1 |
20070018182 | Beeson et al. | Jan 2007 | A1 |
20070018184 | Beeson et al. | Jan 2007 | A1 |
20070057271 | Schiaffino et al. | Mar 2007 | A1 |
20070063215 | Kohda | Mar 2007 | A1 |
20070065960 | Fukshima | Mar 2007 | A1 |
20070102693 | Nagai | May 2007 | A1 |
20070102715 | Ko et al. | May 2007 | A1 |
20070111473 | Furukawa et al. | May 2007 | A1 |
20070181895 | Nagai | Aug 2007 | A1 |
20070200127 | Andrews et al. | Aug 2007 | A1 |
20070202624 | Yoon et al. | Aug 2007 | A1 |
20070262338 | Higashi et al. | Nov 2007 | A1 |
20080157115 | Chuang et al. | Jul 2008 | A1 |
20080179602 | Negley et al. | Jul 2008 | A1 |
20080182369 | Jeong et al. | Jul 2008 | A1 |
20080211416 | Negley et al. | Sep 2008 | A1 |
20080217635 | Emerson et al. | Sep 2008 | A1 |
20080230799 | Wang et al. | Sep 2008 | A1 |
20080237640 | Mishra et al. | Oct 2008 | A1 |
20080241757 | Xu et al. | Oct 2008 | A1 |
20080251858 | Ahn et al. | Oct 2008 | A1 |
20090008654 | Nagai et al. | Jan 2009 | A1 |
20090096386 | Yeh et al. | Apr 2009 | A1 |
20090109151 | Kim et al. | Apr 2009 | A1 |
20090121241 | Keller et al. | May 2009 | A1 |
20090129085 | Alzar et al. | May 2009 | A1 |
20090140272 | Beason et al. | Jun 2009 | A1 |
20090261356 | Lee et al. | Oct 2009 | A1 |
20090267085 | Lee et al. | Oct 2009 | A1 |
20090283787 | Donofrio et al. | Nov 2009 | A1 |
20100059733 | Shei et al. | Mar 2010 | A1 |
20100155746 | Ibbetson et al. | Jun 2010 | A1 |
Number | Date | Country |
---|---|---|
1871713 | Nov 2006 | CN |
101027795 | Aug 2007 | CN |
4284620 | Oct 1992 | JP |
08111544 | Apr 1996 | JP |
9129532 | May 1997 | JP |
09008403 | Oct 1997 | JP |
10-163535 | Jun 1998 | JP |
2000311704 | Jul 2000 | JP |
2001-308380 | Nov 2001 | JP |
2003-515956 | May 2003 | JP |
2003-209286 | Jul 2003 | JP |
2003-529889 | Oct 2003 | JP |
2004-080046 | Mar 2004 | JP |
2004-103443 | Apr 2004 | JP |
2004-266240 | Sep 2004 | JP |
2004-356116 | Dec 2004 | JP |
2005-142311 | Jun 2005 | JP |
2005527102 | Aug 2005 | JP |
2005286291 | Oct 2005 | JP |
2006-032779 | Feb 2006 | JP |
2006100787 | Apr 2006 | JP |
2006216933 | Aug 2006 | JP |
2006352085 | Dec 2006 | JP |
2007-511065 | Apr 2007 | JP |
2007511065 | Apr 2007 | JP |
2002-77135 | Oct 2002 | KR |
WO 8300408 | Feb 1983 | WO |
WO 03032397 | Apr 2003 | WO |
WO 05048361 | May 2005 | WO |
WO 2005124877 | Dec 2005 | WO |
WO 06035664 | Apr 2006 | WO |
WO 2007141763 | Dec 2007 | WO |
WO 2009039805 | Apr 2009 | WO |
Entry |
---|
First Office Action from Chinese Patent Application No. 200910137491.3; dated Apr. 14, 2010. |
Notice of Issuance for Chinese Paten Application No. 201180060870.2. |
Second Office Action for Chinese Application No. 201180060870.2; dated Nov. 11, 2015. |
Decision of Dismissal of Amendment for Japanese Appl. 2012-212830; dated Nov. 13, 2014. |
Notice of Allowance from Korean Appl. No. 10-2010-7013082; dated Jan. 30, 2015. |
Decision of Rejection from Chinese Patent Appl. No. 200980149197.2; dated Mar. 25, 2015. |
Decision of Patent Grant from Japanese Appl. No. 2012-212830; dated May 19, 2015. |
First Office Action from Chinese Appl. No. 2011800608702; dated Jul. 1, 2015. |
Third Office Action from Chinese Appl. No. 2009801491972; dated Sep. 2, 2014. |
Second Office Action from Chinese Appl. No. 200880124595.4; dated Jan. 6, 2013. |
Notice of Reasons for Rejection for Japanese Patent Appl. 2009-132243; dated Dec. 16, 2011. |
Office Action from U.S. Appl. No. 12/432,478; dated Nov. 17, 2010. |
Office Action from U.S. Appl. No. 11/904,064; dated Apr. 22, 2011. |
Office Action from U.S. Appl. No. 12/432,478; dated May 16, 2011. |
Office Action from U.S. Appl. No. 12/012,376; dated Jul. 8, 2010. |
Office Action from U.S. Appl. No. 12/012,376; dated Dec. 3, 2010. |
Office Action from U.S. Appl. No. 12/012,376; dated Feb. 22, 2011. |
Grundbacher et al., “Utilization of an Electron Beam Resist Process to Examine the Effects of Asymmetric Gate Recess on the Device Characteristics of AlGas/InGaAs PHEMT's” vol. 44 Dec. 1997. |
Notice of Allowance for U.S. Appl. No. 12/012,376; dated May 13, 2011. |
Office Action for U.S. Appl. No. 12/416,816; dated Oct. 29, 2010. |
Office Action for U.S. Appl. No. 12/418,416; dated Aug. 20, 2010. |
Office Action for U.S. Appl. No. 12/329,713; dated Feb. 15, 2012. |
Office Action for U.S. Appl. No. 12/821,069; dated Dec. 28, 2010. |
Office Action for U.S. Appl. No. 12/002;429; dated Jan. 28, 2011. |
International Search Report for PCT Appl. No. PCT/US2010/024980; dated Oct. 6, 2010. |
Office Action for U.S. Appl. No. 12/012,376; dated Jul. 8, 2010. |
Office Action for U.S. Appl. No. 12/012,376; dated Dec. 3, 2010. |
Notice of Rejection from Japanese Application No. 2012-212830; dated Jan. 21, 2014. |
Second Office Action for Chinese Application No. 200980149197.2; dated Dec. 30, 2013. |
Reasons for Rejection from Japanese Application No. 2012-212830; dated Aug. 27, 2013. |
International Search Report and Written Opinion for Application No. PCT/US2011/001741; dated Feb. 14, 2012. |
Office Action for German Application No. 102008029318.0; dated Dec. 13, 2010. |
European Search Report for Application No. 1018578.4; dated Dec. 2, 2010. |
Office Action for U.S. Appl. No. 12/905,995; dated Jan. 11, 2013. |
Office Action for U.S. Appl. No. 12/329,713; dated Feb. 27, 2013. |
Office Action for U.S. Appl. No. 12/329,713; dated Oct. 15, 2012. |
Notice of Reasons for Rejection from Japanese Application No. 2010-534010; dated Jun. 26, 2012. |
Written Opinion for International Search for PCT Application No. PCT/US2009/066743; dated Dec. 14, 2009. |
Decision of Rejection for Japanese Application No. 2010-534010; dated Apr. 16, 2013. |
Office Action for Chinese Application No. 200980149197.2; dated Nov. 15, 2012. |
Office Action for Korean Application No. 10-2005-7020463; dated Dec. 21, 2010. |
Decision of Rejection for Japanese Application No. 2009-132243; dated Oct. 2, 2012. |
George Crawford, Philips Lumileds Lighting Company, “Light Extraction From LEDs”, Session J3: Emerging Science of Solid State Lighting—Current State of the Art in High Brightness LEDs, p. 7 2007 American Physical Society March Meeting, vol. 52, No. 1 (Mar. 6, 2007). |
LEDs Magazzine—Lumileds Introduces Thin Film Flip Chips to Boost LED Brightness, Jul. 11, 2007, available at http://ledsmagazine.com/news/4/7/16. |
Windisch et al. “Impact of Texture-Enhanced Transmission of High-Efficiency Surface-Textured Light-Emitting Diodes”, Applied Physics Letters vol. 79, No. 15, Oct. 2001, pp. 2315-2317. |
Schnitzer et al. “30% External Quantum Efficiency from Surface Textured, thin-filmed Light-emitting diodes”, Applied Physics Letters vol. 16, No. 64, Oct. 1993, pp. 2174-2176. |
Windisch et al. “Light-Extraction Mechanism of High-Efficiency Surface-Textured Light-Emitting Diodes”, IEEE Journal on Selected Topics in Quantum Electronics vol. 8, No. 2, Mar./Apr. 2002, pp. 248-255. |
Streubelet al. “High Brightness A l GlnP Light-Emitting Diodes”, IEEE Journal on Selected Topics in Quantum Electronics vol. 8, No. 2, Mar./Apr. 2002, pp. 321-332. |
Nichia Corp. White LED, Part No. NSPW300BS and NSPW312BS. |
Van de Ven, et al., “Warm White Illumination with High CRI and High Efficiency by Combining 455nm Excited Yellowish Phosphor LEDs and Red AlInGaP LEDs”, First International Conference on White LEDs and Solid State Lighting. |
Notice Requesting Submission of Opinion. |
European Examination European Application No. 05781972.8-1235. |
International Preliminary Report PCT/US05/20603; dated Mar. 27, 2008. |
Cree XLamp 7090 XR-E Series LED Binning and Labeling. |
Korean Office Action—Patent Application No. 10-2010-7013082. |
Office Action for U.S. Appl. No. 12/329,713; dated Feb. 11, 2011. |
Office Action for U.S. Appl. No. 12/329,713; dated Aug. 3, 2011. |
Office Action for U.S. Appl. No. 12/321,059; dated Feb. 11, 2011. |
Office Action for U.S. Appl. No. 12/328,713; dated Sep. 1, 2010. |
Office Action for U.S. Appl. No. 12/418,816; dated Jun. 16, 2010. |
Office Action for U.S. Appl. No. 12/185,031; dated Jun. 14, 2011. |
Office Action for U.S. Appl. No. 12/321,059; dated Sep. 24, 2010. |
Number | Date | Country | |
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20170179088 A1 | Jun 2017 | US |
Number | Date | Country | |
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Parent | 11985410 | Nov 2007 | US |
Child | 15449510 | US |