The field to which the disclosure generally relates includes drying process for wood based materials and greenhouse.
Greenhouses have been used extensively for growing agricultural products including vegetables, fruits, flowers and other indoor plants where a narrow range of desired temperature is required for the viable biological processes of plants. When the interior temperature of the greenhouse is outside the range, the plants can suffer from irreversible loss or die. It is not critical, however, to control the relative humidity inside an agricultural greenhouse as long as sufficient moisture is supplied to the soil. It is undesirable to remove much moisture from an agricultural greenhouse because extra water would be provided to the soil or the plant would be dehydrated.
Wood drying is normally achieved by using a kiln apparatus, which is heated by steam or direct heating sources including wood or gas furnaces. A kiln apparatus consumes significant amount of fuel or electricity, and thus expensive to operate. Relative high temperature in a kiln apparatus can also cause internal stresses in a wood product, resulting in deformation or cracks. Wood can be air dried by putting wood under covered spaces with adequate air circulations. Air-drying requires extended drying time and is less controllable due to natural variation of weather conditions.
A method of drying comprises placing a moist material inside a substantially enclosed solar greenhouse. The greenhouse comprises at least one light transmission roof and/or wall panel that is substantially transparent to solar radiation, but resistant to convective and conductive heat transfer. The temperature and relative humidity inside the greenhouse are maintained within their pre-determined ranges while the moist material is allowed to dry. A wood based material manufactured using the drying method exhibits improved properties.
A solar greenhouse for product drying comprises a plurality of roof and wall panels that are substantially transparent to solar radiation and resistant to convective and conductive heat transfer. The greenhouse also comprises a humidity measuring device and a humidity control mechanism for effective removal of interior moisture while maintaining the interior relative humidity within a pre-determined range.
Other exemplary embodiments of the present invention will become apparent from the detailed description provided hereinafter. It should be understood that the detailed description and specific examples, while disclosing exemplary embodiments of the invention, are intended for purposes of illustration only and are not intended to limit the scope of the invention.
Exemplary embodiments of the present invention will become more fully understood from the detailed description and the accompanying drawings, wherein:
The following description of the embodiment(s) is merely exemplary in nature and is in no way intended to limit the invention, its application, or uses. Unless specifically stated, the process embodiments described herein are not constrained to a particular order or sequence. Additionally, some of the described embodiments or elements thereof can occur or be performed at the same point in time.
Any moist materials may be dried using the drying method and greenhouse described below. Wood based materials effectively dried using the method exhibit improved properties.
The term wood based material herein includes any solid materials that comprise fibers of cellulose and/or hemicellulose. The wood based material may comprise any wood species in any geometric shapes. Suitable wood species may include, but not limited to, soft wood, hard wood (maple, oak, as examples), pressure treated wood, bamboo, corn stalk, sugar cane bagasse, straw stalks (such as rice straw and wheat straw), seed flax stalk and any hybrid wood materials. Specific examples of wood species may include Radiata Pine, Scots Pine, Red Pine, Yellow Pine, Maple, Alder, Birch, Aspen, Balsawood, and Beech. The wood based material may be a wood sheet, wood fibers, green lumber, pre-treated lumber, beam, plank, wood chip, wood powder, dimensional lumber, veneer, panels, engineered wood such as plywood, laminated veneer lumber (LVL) and wafer boards veneer.
The wood based material may include voids in at least a portion of the material. Typical voids are cell voids formed during the formation of the wood as part of a tree. The voids may be interconnected to form channels. Water, or aqueous solutions may be able to fill the voids and transport through the channels. Soft wood materials tend to include larger size channels, and higher volume fraction of voids. Voids may also be created artificially by any known chemical or mechanical processes, such as etching and incising. The size of the voids may range from nanometers to millimeters in terms of the maximal linear dimension of the void cross-section.
A wood based product may be treated by impregnation with a treatment composition through the voids and channels of the material structure. Various treatment compositions and solutions may be used. Typical treatment composition may include aqueous or non-aqueous mixtures containing preservatives, insecticides, flame retardants, colorants, wood hardeners, water and UV protectors, and the like. Examples of components in a typical treatment composition may include one or more of chromated copper arsenate, alkaline copper quaternary (ACQ), acid copper chromate, copper azole, copper-HDO (Bis-(N-Cyclohexyldiazeniumdioxy)-copper), copper chromate, copper citrate, micronized copper, boric acid, boric oxides, borate salts, sodium silicate, potassium silicate, bifenthrin, permethrin, copper naphthenate, copper dimethyidithiocarbamate (CDDC), reactive wood hardening resins, and copper oxide. The treatment composition may be applied to the wood based material through a pressure process or non-pressure process. Non-pressure processes may include brushing, spraying, dipping, soaking, steeping or by means of hot and cold bath. Pressure processes are typically carried out in closed cylinders with applied pressure and/or a vacuum. The use of elevated pressure allows deeper and more uniform penetration and a higher absorption of a treatment composition. Additionally, the treatment conditions(such as pressure, temperature, duration, number of treatment cycles, and composition) may be controlled so that retention and penetration can be varied. The wood based material may be loaded onto special tram cars, so called “buggies,” and into the cylinder. These cylinders are then set under pressure, optionally with the addition of higher temperature. In a subsequent step, a vacuum may be used to extract excess treatment composition. These cycles of pressure and vacuum can be repeated to achieve better penetration if desired. After the pressure or nonpressure treatment process, the void and channels of the wood based material are typically filled with the treatment composition to a significant extent. Since an aqueous composition is typically used in the processes, water content in the treated wood material at this stage may range from about 30% to about 300% based on the weight the dry material. After the treatment process, the moisture inside the material needs to be reduced to a lower level.
The wood based material may contain water absorbed by the cellulose or hemicellulose fibers, and liquid water contained inside the voids and channels. The maximal percentage of absorbed water by the cellulosic fibers in the wood based material is referred to as fiber saturation point. A fiber saturation point may range from 20% to 30% by weight. When moisture content of a wood based material is beyond its fiber saturation point, there is liquid water or aqueous composition inside the voids and/or channels. The water inside the voids and channels can be desirably removed by drying, preferably without adversely affecting the mechanical or chemical properties of the material. A high temperature kiln oven may be used to dry the wood based material. High temperature drying, however, may cause excessive expansion or gasification of liquid water inside the wood channels in addition to uneven temperature distribution across the material, resulting in internal stresses, deformation and cracks.
A moist wood based material may be dried inside the greenhouse described below, powered substantially by solar radiation configured to remove moisture under controlled conditions. The moist wood material may be stacked together to form a drying unit that is configured to be lifted and moved by a forklift truck or other transportation or lifting tools.
The doors of the solar greenhouse may comprise a light transmission panel or any other door material. A curtain type door or clear plastic flaps may also be used as the door material. The greenhouse may include a plurality of doors to allow easy transportation of wood based materials in and out of the greenhouse. The width of the door may be large enough for forklift trucks or other transportation or lifting equipments to pass through. In addition, the spacing between two neighboring doors may be at least two times the width of the drying unit containing a transportable package of the wood based material. As shown in
The greenhouse includes a means for controlling ventilation (such as air exchange between the interior and exterior of the greenhouse). The means for controlling ventilation may include a simple adjustable opening, a door, a vent fan, thermostat controlled vent fans, an adjustable roof vent, a shutter, a window, and any equivalent thereof. The means for controlling ventilation may be included in the roof and/or wall sections of the greenhouse. As illustrated in
The greenhouse may include a means for controlling exposure to solar radiation. The means for controlling solar radiation may include a shade screen (retractable manually or automatically controlled by an electric motor), a switchable smart glass panel, and any equivalent thereof. The means for controlling solar radiation is capable of adjusting the amount of solar radiation exposure for an effective rate of heating inside the greenhouse. A shade screen may be a cloth, a film, or a laminated or coated sheet material. The shade screen may comprise an incorporated solar radiation absorbing and/or reflecting colorant (dye and/or pigment). The shade screen may be provided in the form of a roller shade that can be pulled out to cover at least a portion of the roof or retracted back into the core of the roller to expose the roof to the solar radiation. The operation of the roller shade may be conducted manually or by an electromechanical device such as an electric motor. As shown in
The greenhouse may optionally include a solar panel that is capable of storing, collecting and/or converting solar energy. The solar panel may comprise a photovoltaic device capable of collecting and converting solar radiation into electricity. The solar panel may be used to supply electricity to a circulation fan, a ventilation fan, an electromechanical device for controlling the adjustment of shade screen or ventilation opening or switchable smart glass, a rechargeable battery, a dehumidifier, or a supplemental heating unit inside the greenhouse. The solar panel may be positioned next to the greenhouse, or attached to the wall or roof structure of the greenhouse.
The greenhouse may optionally include a supplemental heating unit. A heat exchanger with external steam, hot water, hot oil, or electricity as its energy supply may be used to provide additional heat when solar radiation is not sufficient to generate the desired condition for drying the wood based material.
The greenhouse may desirably include a humidity measuring device and a humidity control mechanism. Wet and dry bulb temperature measurements, relative humidity sensors (including capacitive sensors and resistive sensors), dewcells, infra-red humidity sensors and/or a psychrometer or hygrometer may be used to monitor the humidity inside and outside the greenhouse. Moisture content (also called humidity ratio) of air is herein defined as a ratio of kilograms of water vapor per kilogram of dry air at a given pressure. Moisture content does not change with temperature except when the air cools below its dewpoint. Moisture content or humidity ratio may be calculated or measured based on relative humidity, wet/dry bulb temperature, and/or other measurements using psychrometrics. Information on psychrometric charts and calculation can be found in “Handbook of Psychrometric Charts—Humidity diagrams for engineers,” by David Shallcross, published by Springer; 1st edition, Aug. 31, 1997. A psychromatric chart is provided in
The method of drying and configuration of the solar greenhouse described above may utilize the psychrometric information and measurements to set proper venting program, temperature and humidity adjustments. When the moisture content inside the greenhouse is greater than the moisture content of air outside the greenhouse, the interior air may be vented or exchanged with outside air at a controlled rate regardless of the temperature difference between the outside and inside of the greenhouse. A desired and pre-determined interior temperature range and humidity range may be chosen depending on the nature of the particular batch of wood based material to be dried and its moisture content. The venting schedule and rate of venting is then controlled by the humidity control mechanism such that the moisture inside the greenhouse can be partially removed based on the moisture content differential between the interior and exterior air, while the interior temperature and humidity are maintained within their pre-determined ranges. Venting can typically be carried out unless the moisture content of interior air is not higher than that of exterior air, or the interior air temperature or relative humidity drifts outside their pre-determined ranges. The humidity control mechanism may allow the interior moisture content to rise significantly higher than the moisture content of exterior air before means for controlling ventilation is open, especially when this is a significant temperature difference between inside and outside air. A wide range of temperature and interior relative humidity may be allowed for various wood based materials. A typical temperature range may be 20° C. to 65° C. or 30° C. to 50° C., and relative humidity range of about 30% to about 95% or about 50% to about 80%. The wood based material can be dried to a moisture content below, near or above its fiber saturation point using this method. The moisture content of a dried wood based material may range from about 10% to about 50%. The above method and configuration result in consistent removal of moisture inside the greenhouse and a controlled drying of the wood based material inside the greenhouse. A wood based material dried by the above method exhibits a relative uniform moisture distribution throughout the material structure and less internal stress that may contribute to cracking, deformation or dimension changes.
Any combinations of wood based materials, treatment processes, greenhouse configurations and greenhouse-drying processes, may be used to achieve a desired result. For example, a wood based material is first pressure treated with an aqueous composition comprising at least one of a preservative, an insecticide, a UV stabilizer, a flame retardant and a wood hardener. The treated wood based material, having a moisture content between about 30% and about 300%, or between about 50% and about 200%, may be placed inside the solar greenhouse having an interior temperature between about 20° C. and 60° C. The pre-determined interior relative humidity ranges from about 30% to 80%. When the moisture inside the material evaporates, the interior moisture content of the greenhouse will rise. A schedule of venting the high moisture content interior air is carried out while maintaining the interior temperature and relative humidity within their pre-determined ranges by the means of ventilation and solar exposure control until the wood based material reaches its target moisture content.
The method of drying and the solar greenhouse according to this invention may be used to manufacture various products such as wood veneer, wood floor, interior and exterior wood furniture, wood beams, wood boards, plywood and wood laminates.
The greenhouse and the process described above may also be used to condition a wood based material to reach a target moisture content, remove internal stresses or reach a stable dimension or physical configuration.
The above description of embodiments of the invention is merely exemplary in nature and, thus, variations thereof are not to be regarded as a departure from the spirit and scope of the invention.
This application claims the benefit of U.S. Provisional Application No. 60/949,860, filed on Jul. 15, 2007.
Number | Name | Date | Kind |
---|---|---|---|
487965 | Piver | Dec 1892 | A |
1328655 | Fish, Jr. | Jan 1920 | A |
1482972 | Chandler | Feb 1924 | A |
1556865 | Muller | Oct 1925 | A |
1918682 | Altenkirch | Jul 1933 | A |
1926035 | Chesley | Sep 1933 | A |
1926036 | Chesley | Sep 1933 | A |
1946814 | Varley | Feb 1934 | A |
1954674 | Lager | Apr 1934 | A |
2027894 | Alcorn et al. | Jan 1936 | A |
2038008 | Shodron | Apr 1936 | A |
2121495 | Fitzalan | Jun 1938 | A |
2138690 | Altenkirch | Nov 1938 | A |
2185760 | Altenkirch | Jan 1940 | A |
2292337 | Ford | Aug 1942 | A |
2343345 | Touton | Mar 1944 | A |
2343346 | Touton | Mar 1944 | A |
2479526 | Touton | Aug 1949 | A |
2529621 | Mayo | Nov 1950 | A |
2543618 | Wood | Feb 1951 | A |
2567983 | Wood | Sep 1951 | A |
2688476 | Mayo | Sep 1954 | A |
2810208 | Sadler | Oct 1957 | A |
2831268 | Cox | Apr 1958 | A |
2895400 | Topf | Jul 1959 | A |
2935009 | Cloud et al. | May 1960 | A |
3097077 | Melikian | Jul 1963 | A |
3103227 | Long | Sep 1963 | A |
3314862 | Hay | Apr 1967 | A |
3412728 | Thomason | Nov 1968 | A |
3450192 | Hay | Jun 1969 | A |
3571943 | Sipple | Mar 1971 | A |
3727345 | Smith | Apr 1973 | A |
3811198 | Baltes | May 1974 | A |
3852891 | Stephan | Dec 1974 | A |
3866334 | Huang | Feb 1975 | A |
3896558 | Lovgren | Jul 1975 | A |
3943842 | Bills et al. | Mar 1976 | A |
4015366 | Hall, III | Apr 1977 | A |
4020565 | Steffen | May 1977 | A |
4029081 | Strong | Jun 1977 | A |
4045880 | Steffen | Sep 1977 | A |
4069593 | Huang | Jan 1978 | A |
4077134 | Steffen | Mar 1978 | A |
4099338 | Mullin et al. | Jul 1978 | A |
4122828 | DiPeri | Oct 1978 | A |
4123003 | Winston | Oct 1978 | A |
4128948 | Wood | Dec 1978 | A |
4129177 | Adcock | Dec 1978 | A |
4148147 | Steffen | Apr 1979 | A |
4160523 | Stevens | Jul 1979 | A |
4165966 | Whelan et al. | Aug 1979 | A |
4223666 | Wasserman | Sep 1980 | A |
4236063 | Glucksman | Nov 1980 | A |
4246887 | Christiansen | Jan 1981 | A |
4253244 | Kranzler | Mar 1981 | A |
4279082 | Commander | Jul 1981 | A |
4305235 | Roston | Dec 1981 | A |
4307519 | Szucs et al. | Dec 1981 | A |
4321775 | Emerson | Mar 1982 | A |
4323113 | Troyer | Apr 1982 | A |
4329789 | Erickson | May 1982 | A |
RE31023 | Hall, III | Sep 1982 | E |
4347671 | Dias et al. | Sep 1982 | A |
4387533 | Green et al. | Jun 1983 | A |
4407078 | Takeyama et al. | Oct 1983 | A |
4430828 | Oglevee et al. | Feb 1984 | A |
4438680 | Esposito | Mar 1984 | A |
4446853 | Adcock | May 1984 | A |
4471424 | Persson | Sep 1984 | A |
4490926 | Stokes | Jan 1985 | A |
4498526 | Arenas | Feb 1985 | A |
4505260 | Metzger | Mar 1985 | A |
4510921 | Yano et al. | Apr 1985 | A |
4524528 | Ehlers | Jun 1985 | A |
4527247 | Kaiser et al. | Jul 1985 | A |
4567732 | Landstrom et al. | Feb 1986 | A |
4583300 | Mast | Apr 1986 | A |
4596093 | Esposito | Jun 1986 | A |
4597310 | Panttila | Jul 1986 | A |
4598752 | Esposito | Jul 1986 | A |
4606157 | Esposito | Aug 1986 | A |
4607567 | Esposito | Aug 1986 | A |
4609346 | Siccardi | Sep 1986 | A |
4616560 | Esposito | Oct 1986 | A |
4624084 | Esposito | Nov 1986 | A |
4627202 | Esposito | Dec 1986 | A |
4627208 | Esposito | Dec 1986 | A |
4678019 | Esposito | Jul 1987 | A |
4679350 | Banta | Jul 1987 | A |
4702018 | Hastings | Oct 1987 | A |
4737103 | Siccardi | Apr 1988 | A |
4800653 | Steffen | Jan 1989 | A |
4830276 | Sprung | May 1989 | A |
4864783 | Esposito | Sep 1989 | A |
4916642 | Kaiser et al. | Apr 1990 | A |
4981021 | Assaf | Jan 1991 | A |
4999927 | Durst et al. | Mar 1991 | A |
5001859 | Sprung | Mar 1991 | A |
5014770 | Palmer | May 1991 | A |
5065528 | Kaneko et al. | Nov 1991 | A |
5078881 | Augustine et al. | Jan 1992 | A |
5097895 | Assaf | Mar 1992 | A |
5168640 | Becerra | Dec 1992 | A |
5194147 | Augustine et al. | Mar 1993 | A |
5269829 | Meyer | Dec 1993 | A |
5271225 | Adamides | Dec 1993 | A |
5335447 | Bee | Aug 1994 | A |
5368092 | Rearden et al. | Nov 1994 | A |
5392611 | Assaf et al. | Feb 1995 | A |
5417736 | Meyer | May 1995 | A |
5435377 | Kratochvil | Jul 1995 | A |
5485685 | Hashimoto | Jan 1996 | A |
5517767 | Schechinger et al. | May 1996 | A |
5524381 | Chahroudi | Jun 1996 | A |
5540521 | Biggs | Jul 1996 | A |
5589599 | McMullen et al. | Dec 1996 | A |
5619806 | Warren | Apr 1997 | A |
5632798 | Funk et al. | May 1997 | A |
5678324 | Viitaniemi et al. | Oct 1997 | A |
5680712 | Kiyokawa et al. | Oct 1997 | A |
5705140 | Johansing, Jr. | Jan 1998 | A |
5711819 | Miyasaki | Jan 1998 | A |
5727388 | Adamides | Mar 1998 | A |
5746653 | Palmer et al. | May 1998 | A |
5784805 | Hashimoto | Jul 1998 | A |
5813168 | Clendening | Sep 1998 | A |
5836085 | Ben-Ezra | Nov 1998 | A |
5866752 | Goozner | Feb 1999 | A |
5873178 | Johnson | Feb 1999 | A |
5873181 | Miyasaki | Feb 1999 | A |
5931001 | Watanabe et al. | Aug 1999 | A |
5940150 | Faris et al. | Aug 1999 | A |
5950326 | Scott | Sep 1999 | A |
5979074 | Brunner et al. | Nov 1999 | A |
5979170 | Thorpe | Nov 1999 | A |
5992048 | DeVore et al. | Nov 1999 | A |
6039774 | McMullen et al. | Mar 2000 | A |
6110429 | Johansing, Jr. | Aug 2000 | A |
6170264 | Viteri et al. | Jan 2001 | B1 |
6199214 | Campbell | Mar 2001 | B1 |
6202321 | Soucy | Mar 2001 | B1 |
6230421 | Reed et al. | May 2001 | B1 |
6230480 | Rollins, III | May 2001 | B1 |
6230501 | Bailey et al. | May 2001 | B1 |
6233841 | Beach | May 2001 | B1 |
6243968 | Conrad et al. | Jun 2001 | B1 |
6293121 | Labrador | Sep 2001 | B1 |
6389772 | Gleckman et al. | May 2002 | B2 |
6389814 | Viteri et al. | May 2002 | B2 |
6399359 | Hofstede | Jun 2002 | B1 |
6438862 | Soucy | Aug 2002 | B1 |
6501014 | Kubota et al. | Dec 2002 | B1 |
6530160 | Gookins | Mar 2003 | B1 |
6531230 | Weber et al. | Mar 2003 | B1 |
6559903 | Faris et al. | May 2003 | B2 |
6583827 | Faris et al. | Jun 2003 | B2 |
6598398 | Viteri et al. | Jul 2003 | B2 |
6671008 | Li et al. | Dec 2003 | B1 |
6688018 | Soucy | Feb 2004 | B2 |
6691427 | Fernandes et al. | Feb 2004 | B1 |
6695692 | York | Feb 2004 | B1 |
6705043 | Opdam et al. | Mar 2004 | B1 |
6710823 | Faris et al. | Mar 2004 | B2 |
6725598 | Yoneda et al. | Apr 2004 | B2 |
6758211 | Schmidt | Jul 2004 | B1 |
6772535 | Koslow | Aug 2004 | B2 |
6782947 | de Rouffignac et al. | Aug 2004 | B2 |
6797366 | Hanson et al. | Sep 2004 | B2 |
6845569 | Kim | Jan 2005 | B1 |
6865825 | Bailey et al. | Mar 2005 | B2 |
6868621 | Grimm et al. | Mar 2005 | B1 |
6877555 | Karanikas et al. | Apr 2005 | B2 |
6880633 | Wellington et al. | Apr 2005 | B2 |
6883251 | Terrell et al. | Apr 2005 | B2 |
6897936 | Li et al. | May 2005 | B1 |
6912018 | Faris et al. | Jun 2005 | B2 |
6915850 | Vinegar et al. | Jul 2005 | B2 |
6918442 | Wellington et al. | Jul 2005 | B2 |
6918443 | Wellington et al. | Jul 2005 | B2 |
6922911 | Lam | Aug 2005 | B2 |
6923257 | Wellington et al. | Aug 2005 | B2 |
6929067 | Vinegar et al. | Aug 2005 | B2 |
6932155 | Vinegar et al. | Aug 2005 | B2 |
6941677 | Adrian | Sep 2005 | B2 |
6948562 | Wellington et al. | Sep 2005 | B2 |
6951247 | de Rouffignac et al. | Oct 2005 | B2 |
6964300 | Vinegar et al. | Nov 2005 | B2 |
6965816 | Walker | Nov 2005 | B2 |
6966374 | Vinegar et al. | Nov 2005 | B2 |
6969123 | Vinegar et al. | Nov 2005 | B2 |
6981548 | Wellington et al. | Jan 2006 | B2 |
6991032 | Berchenko et al. | Jan 2006 | B2 |
6991033 | Wellington et al. | Jan 2006 | B2 |
6991036 | Sumnu-Dindoruk et al. | Jan 2006 | B2 |
6991045 | Vinegar et al. | Jan 2006 | B2 |
6994169 | Zhang et al. | Feb 2006 | B2 |
6997518 | Vinegar et al. | Feb 2006 | B2 |
7004247 | Cole et al. | Feb 2006 | B2 |
7004251 | Ward et al. | Feb 2006 | B2 |
7009665 | Li et al. | Mar 2006 | B2 |
7011154 | Maher et al. | Mar 2006 | B2 |
7013972 | Vinegar et al. | Mar 2006 | B2 |
7024796 | Carin et al. | Apr 2006 | B2 |
7024799 | Perret | Apr 2006 | B2 |
7024800 | Carin et al. | Apr 2006 | B2 |
7028478 | Prentice, III | Apr 2006 | B2 |
7032660 | Vinegar et al. | Apr 2006 | B2 |
7033781 | Short | Apr 2006 | B1 |
7040397 | de Rouffignac et al. | May 2006 | B2 |
7040398 | Wellington et al. | May 2006 | B2 |
7040399 | Wellington et al. | May 2006 | B2 |
7040400 | de Rouffignac et al. | May 2006 | B2 |
7043920 | Viteri et al. | May 2006 | B2 |
7051807 | Vinegar et al. | May 2006 | B2 |
7051808 | Vinegar et al. | May 2006 | B1 |
7051811 | de Rouffignac et al. | May 2006 | B2 |
7055600 | Messier et al. | Jun 2006 | B2 |
7063145 | Veenstra et al. | Jun 2006 | B2 |
7066254 | Vinegar et al. | Jun 2006 | B2 |
7066257 | Wellington et al. | Jun 2006 | B2 |
7077198 | Vinegar et al. | Jul 2006 | B2 |
7077199 | Vinegar et al. | Jul 2006 | B2 |
7086465 | Wellington et al. | Aug 2006 | B2 |
7090013 | Wellington | Aug 2006 | B2 |
7096942 | de Rouffignac et al. | Aug 2006 | B1 |
7100994 | Vinegar et al. | Sep 2006 | B2 |
7104319 | Vinegar et al. | Sep 2006 | B2 |
7107706 | Bailey et al. | Sep 2006 | B1 |
7114566 | Vinegar et al. | Oct 2006 | B2 |
7118852 | Purdum | Oct 2006 | B2 |
7128153 | Vinegar et al. | Oct 2006 | B2 |
7135332 | Ouellette | Nov 2006 | B2 |
7138173 | Wheatley et al. | Nov 2006 | B2 |
7156176 | Vinegar et al. | Jan 2007 | B2 |
7165615 | Vinegar et al. | Jan 2007 | B2 |
7169489 | Redmond | Jan 2007 | B2 |
7181865 | Kolega et al. | Feb 2007 | B2 |
7182268 | Kawahara | Feb 2007 | B2 |
7204041 | Bailey et al. | Apr 2007 | B1 |
7220365 | Qu et al. | May 2007 | B2 |
7225866 | Berchenko et al. | Jun 2007 | B2 |
7240440 | Delons | Jul 2007 | B2 |
7275569 | Hobbs | Oct 2007 | B2 |
7287558 | Hobbs | Oct 2007 | B2 |
7340845 | Kneebone | Mar 2008 | B2 |
7381550 | Hallberg et al. | Jun 2008 | B2 |
7382332 | Essig et al. | Jun 2008 | B2 |
7434332 | Morton et al. | Oct 2008 | B2 |
7438261 | Porter | Oct 2008 | B2 |
7461691 | Vinegar et al. | Dec 2008 | B2 |
7487601 | Carin et al. | Feb 2009 | B2 |
7498398 | Di et al. | Mar 2009 | B2 |
7591505 | Onizawa et al. | Sep 2009 | B2 |
7597855 | Trentacosta et al. | Oct 2009 | B2 |
7610692 | Carin et al. | Nov 2009 | B2 |
7612735 | Essig et al. | Nov 2009 | B2 |
7617617 | Gorbell et al. | Nov 2009 | B2 |
7624801 | Zubrin et al. | Dec 2009 | B2 |
7625624 | Trentacosta et al. | Dec 2009 | B2 |
7629400 | Hyman | Dec 2009 | B2 |
7650939 | Zubrin et al. | Jan 2010 | B2 |
20010015061 | Viteri et al. | Aug 2001 | A1 |
20010045104 | Bailey et al. | Nov 2001 | A1 |
20020041346 | Faris et al. | Apr 2002 | A1 |
20020085151 | Faris et al. | Jul 2002 | A1 |
20020100836 | Hunt | Aug 2002 | A1 |
20020118328 | Faris et al. | Aug 2002 | A1 |
20020124431 | Duhaut et al. | Sep 2002 | A1 |
20020144506 | Viteri et al. | Oct 2002 | A1 |
20030005626 | Yoneda et al. | Jan 2003 | A1 |
20030024686 | Ouellette | Feb 2003 | A1 |
20030029185 | Kopko | Feb 2003 | A1 |
20030035917 | Hyman | Feb 2003 | A1 |
20030035972 | Hanson et al. | Feb 2003 | A1 |
20030056390 | Adrian | Mar 2003 | A1 |
20030066638 | Qu et al. | Apr 2003 | A1 |
20030066830 | Reed et al. | Apr 2003 | A1 |
20030079363 | Soucy | May 2003 | A1 |
20030079877 | Wellington et al. | May 2003 | A1 |
20030080604 | Vinegar et al. | May 2003 | A1 |
20030093187 | Walker | May 2003 | A1 |
20030098149 | Wellington et al. | May 2003 | A1 |
20030098605 | Vinegar et al. | May 2003 | A1 |
20030100451 | Messier et al. | May 2003 | A1 |
20030102124 | Vinegar et al. | Jun 2003 | A1 |
20030102125 | Wellington et al. | Jun 2003 | A1 |
20030102126 | Sumnu-Dindoruk et al. | Jun 2003 | A1 |
20030102130 | Vinegar et al. | Jun 2003 | A1 |
20030111223 | Rouffignac et al. | Jun 2003 | A1 |
20030116315 | Wellington et al. | Jun 2003 | A1 |
20030130136 | Rouffignac et al. | Jul 2003 | A1 |
20030131993 | Zhang et al. | Jul 2003 | A1 |
20030131994 | Vinegar et al. | Jul 2003 | A1 |
20030131995 | de Rouffignac et al. | Jul 2003 | A1 |
20030131996 | Vinegar et al. | Jul 2003 | A1 |
20030136558 | Wellington et al. | Jul 2003 | A1 |
20030136559 | Wellington et al. | Jul 2003 | A1 |
20030137181 | Wellington et al. | Jul 2003 | A1 |
20030141066 | Karanikas et al. | Jul 2003 | A1 |
20030141067 | Rouffignac et al. | Jul 2003 | A1 |
20030141068 | Rouffignac et al. | Jul 2003 | A1 |
20030142964 | Wellington et al. | Jul 2003 | A1 |
20030146002 | Vinegar et al. | Aug 2003 | A1 |
20030148894 | Vinegar et al. | Aug 2003 | A1 |
20030155111 | Vinegar et al. | Aug 2003 | A1 |
20030164239 | Wellington et al. | Sep 2003 | A1 |
20030173072 | Vinegar et al. | Sep 2003 | A1 |
20030173078 | Wellington et al. | Sep 2003 | A1 |
20030173080 | Berchenko et al. | Sep 2003 | A1 |
20030173081 | Vinegar et al. | Sep 2003 | A1 |
20030173082 | Vinegar et al. | Sep 2003 | A1 |
20030173085 | Vinegar et al. | Sep 2003 | A1 |
20030178191 | Maher et al. | Sep 2003 | A1 |
20030183390 | Veenstra et al. | Oct 2003 | A1 |
20030192691 | Vinegar et al. | Oct 2003 | A1 |
20030192693 | Wellington | Oct 2003 | A1 |
20030194692 | Purdum | Oct 2003 | A1 |
20030196788 | Vinegar et al. | Oct 2003 | A1 |
20030196789 | Wellington et al. | Oct 2003 | A1 |
20030196801 | Vinegar et al. | Oct 2003 | A1 |
20030196810 | Vinegar et al. | Oct 2003 | A1 |
20030201098 | Karanikas et al. | Oct 2003 | A1 |
20030205378 | Wellington et al. | Nov 2003 | A1 |
20030208923 | Lewis | Nov 2003 | A1 |
20030209348 | Ward et al. | Nov 2003 | A1 |
20030221333 | Lam | Dec 2003 | A1 |
20040003592 | Viteri et al. | Jan 2004 | A1 |
20040016769 | Redmond | Jan 2004 | A1 |
20040020642 | Vinegar et al. | Feb 2004 | A1 |
20040023087 | Redmond | Feb 2004 | A1 |
20040025366 | Soucy | Feb 2004 | A1 |
20040031282 | Kopko | Feb 2004 | A1 |
20040040715 | Wellington et al. | Mar 2004 | A1 |
20040061819 | Faris et al. | Apr 2004 | A1 |
20040077090 | Short | Apr 2004 | A1 |
20040160538 | Li et al. | Aug 2004 | A1 |
20040194335 | Perret | Oct 2004 | A1 |
20040194371 | Kinnis | Oct 2004 | A1 |
20040207566 | Essig et al. | Oct 2004 | A1 |
20040210056 | Wood et al. | Oct 2004 | A1 |
20040211554 | Vinegar et al. | Oct 2004 | A1 |
20040211557 | Cole et al. | Oct 2004 | A1 |
20040211569 | Vinegar et al. | Oct 2004 | A1 |
20050000802 | Hobbs | Jan 2005 | A1 |
20050007505 | Faris et al. | Jan 2005 | A1 |
20050007506 | Faris et al. | Jan 2005 | A1 |
20050039388 | Wehner | Feb 2005 | A1 |
20050079333 | Wheatley et al. | Apr 2005 | A1 |
20050092483 | Vinegar et al. | May 2005 | A1 |
20050153410 | Hallberg et al. | Jul 2005 | A1 |
20050160617 | Fouts | Jul 2005 | A1 |
20050187677 | Walker | Aug 2005 | A1 |
20050241174 | Kolega et al. | Nov 2005 | A1 |
20050246919 | Delons | Nov 2005 | A1 |
20050249917 | Trentacosta et al. | Nov 2005 | A1 |
20050274067 | Morton et al. | Dec 2005 | A1 |
20050274293 | Morton et al. | Dec 2005 | A1 |
20050284167 | Morgan et al. | Dec 2005 | A1 |
20060010712 | Carin et al. | Jan 2006 | A1 |
20060010714 | Carin et al. | Jan 2006 | A1 |
20060026017 | Walker | Feb 2006 | A1 |
20060033674 | Essig et al. | Feb 2006 | A1 |
20060049305 | Porter | Mar 2006 | A1 |
20060053791 | Prentice | Mar 2006 | A1 |
20060101665 | Carin et al. | May 2006 | A1 |
20060101881 | Carin et al. | May 2006 | A1 |
20060131928 | Onizawa et al. | Jun 2006 | A1 |
20060174965 | Hobbs | Aug 2006 | A1 |
20060178445 | Mcintyre et al. | Aug 2006 | A1 |
20060201024 | Carin et al. | Sep 2006 | A1 |
20060206246 | Walker | Sep 2006 | A1 |
20060213657 | Berchenko et al. | Sep 2006 | A1 |
20060254079 | Gorbell et al. | Nov 2006 | A1 |
20060254080 | Carin et al. | Nov 2006 | A1 |
20060254081 | Carin et al. | Nov 2006 | A1 |
20060273223 | Haaland et al. | Dec 2006 | A1 |
20060280906 | Trentacosta et al. | Dec 2006 | A1 |
20070061946 | Webb | Mar 2007 | A1 |
20070062105 | Stevens | Mar 2007 | A1 |
20070074420 | Eriksson et al. | Apr 2007 | A1 |
20070082187 | Wang et al. | Apr 2007 | A1 |
20070098602 | Haueter et al. | May 2007 | A1 |
20070100122 | Crawford et al. | May 2007 | A1 |
20070100125 | Crawford et al. | May 2007 | A1 |
20070105993 | Germroth et al. | May 2007 | A1 |
20070106054 | Crawford et al. | May 2007 | A1 |
20070119602 | Haaland et al. | May 2007 | A1 |
20070119603 | Haaland et al. | May 2007 | A1 |
20070129531 | Germroth et al. | Jun 2007 | A1 |
20070151262 | Bailey | Jul 2007 | A1 |
20070163142 | Carin et al. | Jul 2007 | A1 |
20070175063 | Morgan et al. | Aug 2007 | A1 |
20070184238 | Hockaday et al. | Aug 2007 | A1 |
20070184274 | Wheatley et al. | Aug 2007 | A1 |
20070209799 | Vinegar et al. | Sep 2007 | A1 |
20070225470 | Di et al. | Sep 2007 | A1 |
20070256318 | Sugawara et al. | Nov 2007 | A1 |
20070259220 | Redmond | Nov 2007 | A1 |
20070266623 | Paoluccio | Nov 2007 | A1 |
20070271810 | Kelley et al. | Nov 2007 | A1 |
20070271814 | Bae et al. | Nov 2007 | A1 |
20080041364 | Brock | Feb 2008 | A1 |
20080047502 | Morse | Feb 2008 | A1 |
20080072450 | Kim et al. | Mar 2008 | A1 |
20080078100 | Kim et al. | Apr 2008 | A1 |
20080104858 | Carin et al. | May 2008 | A1 |
20080105019 | Carin et al. | May 2008 | A1 |
20080110043 | Carin et al. | May 2008 | A1 |
20080115950 | Haaland et al. | May 2008 | A1 |
20080138265 | Lackner et al. | Jun 2008 | A1 |
20080148592 | Kim et al. | Jun 2008 | A1 |
20080148597 | Kim et al. | Jun 2008 | A1 |
20080172899 | Carin et al. | Jul 2008 | A1 |
20080178819 | Sia et al. | Jul 2008 | A1 |
20080189979 | Carin et al. | Aug 2008 | A1 |
20080223269 | Paoluccio | Sep 2008 | A1 |
20080250715 | Cooper et al. | Oct 2008 | A1 |
20080263890 | Picard | Oct 2008 | A1 |
20080283247 | Zubrin et al. | Nov 2008 | A1 |
20080293857 | Crawford et al. | Nov 2008 | A1 |
20080293882 | Germroth et al. | Nov 2008 | A1 |
20080295220 | Webb | Dec 2008 | A1 |
20080296018 | Zubrin et al. | Dec 2008 | A1 |
20080314058 | Jones et al. | Dec 2008 | A1 |
20080314593 | Vinegar et al. | Dec 2008 | A1 |
20090008089 | Zubrin et al. | Jan 2009 | A1 |
20090013596 | Wang | Jan 2009 | A1 |
20090014170 | Zubrin et al. | Jan 2009 | A1 |
20090049763 | Blundell et al. | Feb 2009 | A1 |
20090061267 | Monzyk et al. | Mar 2009 | A1 |
20090062581 | Appel et al. | Mar 2009 | A1 |
20090093573 | Germroth et al. | Apr 2009 | A1 |
20090093574 | Crawford et al. | Apr 2009 | A1 |
20090145999 | Porter | Jun 2009 | A1 |
20090181434 | Aikens et al. | Jul 2009 | A1 |
20090183424 | Gorbell et al. | Jul 2009 | A1 |
20090186966 | Gallucci et al. | Jul 2009 | A1 |
20090188127 | Gorbell et al. | Jul 2009 | A1 |
20090189445 | Strizki | Jul 2009 | A1 |
20090205363 | de Strulle | Aug 2009 | A1 |
20090226308 | Vandor | Sep 2009 | A1 |
20090227003 | Blotsky et al. | Sep 2009 | A1 |
20090230040 | Limcaco | Sep 2009 | A1 |
20090230686 | Catlin | Sep 2009 | A1 |
20090255144 | Gorbell et al. | Oct 2009 | A1 |
20090323180 | Weber et al. | Dec 2009 | A1 |
20100000444 | Constantz et al. | Jan 2010 | A1 |
20100018113 | Bohlig et al. | Jan 2010 | A1 |
20100018228 | Flammang et al. | Jan 2010 | A1 |
20100031560 | Calabrese et al. | Feb 2010 | A1 |
20100086480 | Williams | Apr 2010 | A1 |
20100087574 | Crawford et al. | Apr 2010 | A1 |
Number | Date | Country |
---|---|---|
641743 | Mar 1984 | CH |
641743 | Mar 1984 | CH |
03156282 | Jul 1991 | JP |
04317697 | Nov 1992 | JP |
06159934 | Jun 1994 | JP |
WO 2007002733 | Jan 2007 | WO |
Number | Date | Country | |
---|---|---|---|
20090013596 A1 | Jan 2009 | US |
Number | Date | Country | |
---|---|---|---|
60949860 | Jul 2007 | US |