Patent Grant
10179959
This application is a national stage of international application no. PCT/JP2013/069797, filed on Jul. 22, 2013, which is incorporated herein by reference.
The present invention relates to a yarn producing apparatus for producing carbon nanotube yarn from carbon nanotube fibers.
An example of the yarn producing apparatus as described above includes a drawing unit that continuously draws carbon nanotube fibers from a carbon nanotube forming substrate and a yarn producing unit that twists the carbon nanotube fibers drawn by the drawing unit to produce yarn (for example, see Patent Literature 1).
[Patent Literature 1] Japanese Patent Application Laid-Open Publication No. 2010-116632
In the yarn producing apparatus as described above, when the carbon nanotube fibers on the carbon nanotube forming substrate run out, it is necessary to replace the carbon nanotube forming substrate. For example, Patent Literature 1 does not disclose a specific mechanism for replacing the carbon nanotube forming substrate. As described above, in the field of yarn producing apparatus, there is a demand for yarn producing apparatus capable of replacing the carbon nanotube forming substrate.
It is therefore an object of the present invention to provide a yarn producing apparatus capable of replacing the carbon nanotube forming substrate.
A yarn producing apparatus according to an aspect of the present invention produces carbon nanotube yarn by aggregating carbon nanotube fibers. The yarn producing apparatus includes a substrate support, a continuous drawing unit, a yarn producing unit, and a substrate replacing mechanism. The substrate support supports a carbon nanotube forming substrate. The continuous drawing unit continuously draws the carbon nanotube fibers from the carbon nanotube forming substrate. The yarn producing unit aggregates the carbon nanotube fibers drawn by the continuous drawing unit. The substrate replacing mechanism replaces the carbon nanotube forming substrate supported on the substrate support with another carbon nanotube forming substrate.
In this yarn producing apparatus, the substrate replacing mechanism enables replacement of the carbon nanotube forming substrate. As described above, for example, when the carbon nanotube fibers on the carbon nanotube forming substrate run out, the substrate replacing mechanism can replace it with a new carbon nanotube forming substrate. The carbon nanotube yarn thus can be continuously produced.
The substrate support may include a plurality of substrate supports. In this case, carbon nanotube yarn can be produced using the carbon nanotube fibers drawn from the plurality of carbon nanotube forming substrates. For example, a standby carbon nanotube forming substrate from which carbon nanotube fibers have not yet been drawn may be placed on a substrate support. When any carbon nanotube forming substrate runs out of carbon nanotube fibers, carbon nanotube fibers can be drawn from the standby carbon nanotube forming substrate to enable the continued production of carbon nanotube yarn.
The substrate replacing mechanism may be movable in the direction of a row of a plurality of the carbon nanotube forming substrates each supported by the substrate support. In this case, the substrate replacing mechanism can be moved to the position where the carbon nanotube forming substrate is easily replaced. This configuration facilitates replacement of the carbon nanotube forming substrate.
The substrate replacing mechanism may include a substrate replacing unit configured to replace the carbon nanotube forming substrate supported on the substrate support with another carbon nanotube forming substrate and a controller configured to control the substrate replacing unit such that the carbon nanotube forming substrate supported on the substrate support is replaced with another carbon nanotube forming substrate. In this case, the substrate replacing mechanism can automatically replace the carbon nanotube forming substrate. The carbon nanotube yarn thus can be produced efficiently.
The substrate replacing mechanism may further include a remaining amount monitor configured to monitor the remaining amount of the carbon nanotube fibers in the carbon nanotube forming substrate supported by the substrate support. The controller may control the substrate replacing unit such that the carbon nanotube forming substrate supported on the substrate support is replaced with another carbon nanotube forming substrate, based on a result of monitoring by the remaining amount monitor. In this case, the carbon nanotube forming substrate can be replaced at appropriate timing, based on the result of monitoring by the remaining amount monitor.
The substrate replacing unit may include a holder capable of holding the carbon nanotube forming substrate and a movement mechanism configured to move the holder between a hold position where the holder is allowed to hold the carbon nanotube forming substrate supported by the substrate support and a substrate storage accommodating the carbon nanotube forming substrate. The movement mechanism moves the holder as described above, so that the carbon nanotube forming substrate can be moved between the substrate support and the substrate storage.
The hold position may be a position where the holder is opposed to a rear surface of the carbon nanotube forming substrate supported by the substrate support. The holder may have a suction port at a section thereof opposed to the rear surface of the carbon nanotube forming substrate. The holder may hold the carbon nanotube forming substrate by suction force from the suction port. In this case, the carbon nanotube forming substrate can be easily held using suction force from the suction port provided in the holder.
The substrate support may have a suction port on a surface thereof opposed to the rear surface of the carbon nanotube forming substrate. The substrate support may hold the carbon nanotube forming substrate by suction force from the suction port. In this case, the carbon nanotube forming substrate can be easily held using suction force from the suction port provided in the substrate support.
The present invention enables replacement of the carbon nanotube forming substrate.
An embodiment of the present invention will be described in detail below with reference to the drawings. It should be noted that the same or corresponding elements are denoted with the same reference signs in the description of the drawings and an overlapping description will be omitted.
As shown in
The fiber supply unit 2 holds a carbon nanotube forming substrate (hereinafter referred to as “CNT forming substrate”) S from which CNT fibers F are drawn. The CNT forming substrate S is called a carbon nanotube forest or a vertically aligned carbon nanotube structure in which high-density and highly-oriented carbon nanotubes (for example, single-wall carbon nanotubes, double-wall carbon nanotubes, or multi-wall carbon nanotubes) are formed on a substrate by chemical vapor deposition or any other process. Examples of the substrate include a glass substrate, a silicon substrate, and a metal substrate.
The fiber supply unit 2 includes a substrate support 10, a supply state changing mechanism 20, and a substrate replacing mechanism 30. In the present embodiment, the fiber supply unit 2 includes five substrate supports 10. Each substrate support 10 removably supports a CNT forming substrate S from which CNT fibers F are drawn. The supply state changing mechanism 20 changes a supply state of CNT fibers F drawn from the CNT forming substrate S and supplied to the yarn producing unit 4. The substrate replacing mechanism 30 replaces the CNT forming substrate S supported by the substrate support 10 with another CNT forming substrate S. The details of the substrate support 10, the supply state changing mechanism 20, and the substrate replacing mechanism 30 will be described later.
The yarn producing unit 4 false-twists the CNT fibers F drawn by the nip roller unit 5 described later. The yarn producing unit 4 blows the supplied air around the CNT fibers F to false-twist CNT fibers F with the airflow to produce CNT yarn Y.
The nip roller unit 5 includes a pair of rollers for drawing the CNT fibers F. The CNT yarn Y twisted by the yarn producing unit 4 is sandwiched between the rollers in the nip roller unit 5, and the CNT yarn Y is sent to the winding unit 7 with rotation of the rollers. Although the CNT yarn Y flaps immediately after being output from the yarn producing unit 4, the rollers in the nip roller unit 5 sandwich the CNT yarn Y to eliminate or minimize the flap.
The status monitor 6 monitors the state of the CNT yarn Y, here, detects the thickness of the CNT yarn Y. Examples of the status monitor 6 include optical, contact, and capacitive sensors. Any sensor can be used as long as it can detect the thickness of the CNT yarn Y. The result of detection by the status monitor 6 is output to the supply controller 250.
The winding unit 7 includes a winding tube 7a. The CNT yarn Y is wound onto the winding tube 7a. The CNT yarn Y is wound onto the winding tube 7a whereby CNT fibers F are continuously drawn from the CNT forming substrate S.
The details of the substrate support 10 will now be described. As shown in, for example,
Each substrate support 10 includes a rear surface supporting portion 11 and an end portion supporting portion 12, as shown in
The rear surface supporting portion 11 stands from the end portion supporting portion 12 and abuts on the rear surface of a CNT forming substrate S. The rear surface of the CNT forming substrate S is that surface of the CNT forming substrate S on which carbon nanotubes are not formed. The rear surface supporting portion 11 is opposed to the vicinity of the lower end of the CNT forming substrate S to be supported. The rear surface supporting portion 11 has a notch 11b cut downward from the upper edge. The rear surface supporting portion 11 has suction ports 11a at a section thereof opposed to the rear surface of the CNT forming substrate S. The suction force from the suction ports 11a allows the CNT forming substrate S to stick to the rear surface supporting portion 11 and allows the CNT forming substrate S to be supported on the rear surface supporting portion 11 and the end portion supporting portion 12.
The details of the supply state changing mechanism 20 will now be described. The supply state changing mechanism 20 includes an initial drawing unit 200 and a supply controller 250 as shown in
The base plate 201 is attached to the base plate 2a of the fiber supply unit 2 in a swingable manner. In the present embodiment, as shown in
The base plate 201 has a through hole 201a. The suction tube 210 is passed through the through hole 201a. With this configuration, when the suction tube 210 is advanced to and retracted from the CNT forming substrate S, the suction tube 210 does not interfere with the base plate 201.
The roller support 202 is fixed to the top surface of the base plate 201. On one surface of the roller support 202, the driving roller 203, the first driven roller 204, and the second driven roller 205 are rotatably attached. The driving roller 203 is arranged closer to the substrate support 10 than are the first driven roller 204 and the second driven roller 205. The suction tube 210 is supported between the driving roller 203, and the first driven roller 204 and the second driven roller 205. The rotation of the driving roller 203 is driven by the driving motor 206. The rotation of the driving roller 203 allows the suction tube 210 to advance to and retract from the CNT forming substrate S. The first driven roller 204 and the second driven roller 205 are driven to rotate with the advancement and retraction of the suction tube 210.
The driving roller 203 has a recess 203a on the circumferential surface thereof. The recess 203a extends in the circumferential direction. The recess 203a holds the side surfaces of a guide 212 provided on the suction tube 210. The bottom of the recess 203a abuts on the end portion of the guide 212 of the suction tube 210 to allow the suction tube 210 to advance to and retract from the CNT forming substrate S with the rotation of the driving roller 203. The recess 203a of the driving roller 203 holds the guide 212 of the suction tube 210 to restrict the rotation of the suction tube 210.
A recess 204a and a recess 205a extending in the circumferential direction are provided on the circumferential surface of the first driven roller 204 and the circumferential surface of the second driven roller 205, respectively. The recesses 204a and 205a each have an arc-shaped cross section fitted on the outer shape of the tube portion 211 of the suction tube 210.
The recess 204a in the first driven roller 204 and the recess 205a in the second driven roller 205 are engaged with the tube portion 211 of the suction tube 210, and the recess 203a in the driving roller 203 is engaged with the guide 212 of the suction tube 210, thereby preventing disengagement of the suction tube 210 from the driving roller 203, the first driven roller 204, and the second driven roller 205.
The suction tube 210 includes the tube portion 211 and the guide 212. The tube portion 211 is a tubular member having an arc shape. The tube portion 211 has a suction port 213 at one end thereof. The suction port 213 is an opening formed like a slit. The opening is oriented in the outer circumferential direction of the arc-shaped tube portion 211. The other end of the tube portion 211 is connected to a suction device. The tube portion 211 is opposed to the first driven roller 204 and the second driven roller 205 on the outer circumferential surface of the arc shape and is opposed to the driving roller 203 on the inner circumferential surface of the arc shape.
The guide 212 is provided on the surface of the tube portion 211 that is opposed to the driving roller 203. The guide 212 is shaped like a thin plate and extends in the direction in which the tube portion 211 extends. The guide 212 is held in the recess 203a provided on the circumferential surface of the driving roller 203. In this configuration, the inner circumferential side of the arc shape of the suction tube 210 faces the substrate support 10.
The configuration of the initial drawing unit 200 drawing CNT fibers F from a CNT forming substrate S will now be described. CNT fibers F are drawn by the initial drawing unit 200, for example, when a new CNT forming substrate S is placed on a substrate support 10 and the drawing of the new CNT fibers F is started.
As shown in
The suction tube 210 has an arc shape. When the suction tube 210 retracted on the bottom surface side of the base plate 2a as shown in
As shown in
While the suction force from the suction port 213 draws CNT fibers F from the CNT forming substrate S, the initial drawing unit 200 allows the suction tube 210 to retract. As shown in
As described above, the initial drawing unit 200 advances the suction tube 210 to draw CNT fibers F from a CNT forming substrate S and then retracts the suction tube 210, so that the newly drawn CNT fibers F aggregate and adhere to other CNT fibers F and are sent together with other CNT fibers F to the yarn producing unit 4.
The control of the initial drawing unit 200 by the supply controller 250 will now be described. The supply controller 250 controls the initial drawing unit 200 based on the result of detection by the status monitor 6 to draw CNT fibers F from a CNT forming substrate S. As shown in
When a CNT forming substrate S other than the standby CNT forming substrate S (at the front) runs out of carbon nanotubes (carbon nanotubes have been completely drawn), or when the amount of CNT fibers F drawn from a CNT forming substrate S other than the standby CNT forming substrate S decreases due to a drawing failure or other reasons, the supply controller 250 draws CNT fibers F from the standby CNT forming substrate S and sends the drawn CNT fibers F together with the CNT fibers F drawn from other CNT forming substrates S to the yarn producing unit 4.
More specifically, the supply controller 250 controls the driving of the driving source for swinging the base plate 201 of the initial drawing unit 200 and the driving motor 206 for advancing and retracting the suction port 213 to allow the initial drawing unit 200 to draw CNT yarn Y from the standby CNT forming substrate S. For example, if the status monitor 6 detects that the thickness of the CNT yarn Y becomes smaller than the lower limit in a predetermined range, the supply controller 250 controls the initial drawing unit 200 such that the suction tube 210 advances toward the standby CNT forming substrate S to draw CNT fibers F as described above. The supply controller 250 then controls the initial drawing unit 200 such that the suction tube 210 retracts and the drawn CNT fibers F aggregate and adhere to other CNT fibers F.
As described above, the supply controller 250 controls the initial drawing unit 200 based on the detection result from the status monitor 6, and adds a CNT forming substrate S to draw CNT fibers F or changes the number of substrates to control the amount of CNT fibers F supplied to the yarn producing unit 4 (control the supply state of CNT fibers F). The amount of CNT fibers F supplied to the yarn producing unit 4 may be controlled by changing the amount of CNT fibers F drawn from one CNT forming substrate S.
The details of the substrate replacing mechanism 30 will now be described. The substrate replacing mechanism 30 replaces the CNT forming substrate S supported on a substrate support 10 with another CNT forming substrate S. In the present embodiment, the substrate replacing mechanism 30 replaces the CNT forming substrate S supported on a substrate support 10 with a CNT forming substrate S stored in a substrate storage W provided in the vicinity of the fiber supply unit 2. The substrate replacing mechanism 30 can also move the CNT forming substrate S supported on one substrate support 10 to another substrate support 10.
The substrate replacing mechanism 30 is configured to include a substrate replacing unit 300, a replacement controller 350, and a remaining amount monitor 370, as shown in
The arm driver 302 is mounted on the upper surface of the body 303 and turns about a vertical straight line relative to the body 303. The base end of the arm 301 is joined to a side surface of the arm driver 302. The arm driver 302 allows the arm 301 to swing about the joint with the arm 301 such that the front end of the arm 301 (the side having the holder 304) moves closer to and away from the base plate 2a. The arm driver 302 also allows the connection portion with the arm 301 to move in the vertical direction. That is, the arm driver 302 can move the entire arm 301 in the vertical direction.
The holder 304 is provided on the front end of the arm 301 (the end opposite to the end connected with the arm driver 302). The holder 304 is brought into abutment with the rear surface of a CNT forming substrate S. As shown in
Since the extension 304b also has the suction port 304a, the entire CNT forming substrate S can be sucked by the suction ports 304a, rather than sucking a localized area of the CNT forming substrate S by the suction ports 304a. With this configuration, the CNT forming substrate S can be stably and reliably held by the holder 304.
When a CNT forming substrate S is received from a substrate support 10 or when a CNT forming substrate S is delivered to a substrate support 10, the substrate replacing unit 300 allows the holder 304 to move such that the surface of the rear surface supporting portion 11 of the substrate support 10 of interest that comes into abutment with the CNT forming substrate S is matched with the surface of the holder 304 that comes into abutment with the CNT forming substrate S. The extension 304b is then put into the notch 11b. The position where the holder 304 is located when receiving a CNT forming substrate S from a substrate support 10 or when delivering a CNT forming substrate S to a substrate support 10 is referred to as a “hold position”. The hold position is set for each substrate support 10. In the substrate replacing unit 300, the holder 304 can move to the hold position set for each substrate support 10.
The substrate replacing unit 300 allows the holder 304 to move between a hold position and the substrate storage W or between a hold position and another hold position. Specifically, the substrate replacing unit 300 replaces the CNT forming substrate S supported on the substrate support 10 by moving the body 303 along the rail 305, turning the arm driver 302 relative to the body 303, moving the entire arm 301 upward and downward, and swinging the arm 301 to move the holder 304 between the hold position and, for example, the substrate storage W.
The remaining amount monitor 370 monitors the remaining amount of CNT fibers F on the CNT forming substrate S supported on each substrate support 10. The remaining amount monitor 370 can determine the amount of CNT fibers F left on the CNT forming substrate S, for example, by measuring the weight of the CNT forming substrate S supported on the substrate support 10. Alternatively, the remaining amount monitor 370 can determine the amount of CNT fibers F left on the CNT forming substrate S by capturing an image of the CNT forming substrate S with a camera and processing the captured image. A failure in drawing CNT fibers F can be recognized based on temporal changes in the amount of CNT fibers F left on the CNT forming substrate S.
Alternatively, the remaining amount monitor 370 can determine the amount of CNT fibers F left on the CNT forming substrate S, based on whether CNT fibers F are being drawn from the CNT forming substrate S. In this case, for example, an image of the region where CNT fibers F drawn from the CNT forming substrate S run is captured with a camera, and whether CNT fibers F are being drawn from the CNT forming substrate S can be grasped based on the captured image. For example, if CNT fibers F are not being drawn from the CNT forming substrate S, it can be determined that the CNT forming substrate S is empty of CNT fibers F. The remaining amount monitor 370 can monitor the remaining amount by any method other than the methods described above for monitoring the remaining amount of CNT fibers F.
The control of the substrate replacing unit 300 by the replacement controller 350 will now be described. The replacement controller 350 controls the substrate replacing unit 300 such that the CNT forming substrate S empty of CNT fibers F or having a drawing failure is replaced with a new CNT forming substrate S stored in the substrate storage W, based on the monitoring result of the remaining amount of CNT fibers F by the remaining amount monitor 370.
Specifically, if the remaining amount monitor 370 detects a CNT forming substrate S empty of CNT fibers F, the replacement controller 350 controls the substrate replacing unit 300 such that the empty CNT forming substrate S is received from the substrate support 10. The replacement controller 350 then controls the substrate replacing unit 300 such that the received empty CNT forming substrate S is stored into the substrate storage W. The replacement controller 350 then controls the substrate replacing unit 300 such that a new CNT forming substrate S is received from the substrate storage W and the new CNT forming substrate S is passed to a substrate support 10 that does not bear a CNT forming substrate S thereon. As described above, the replacement controller 350 controls the substrate replacing unit 300 based on the monitoring result from the remaining amount monitor 370 to replace the CNT forming substrate S.
The present embodiment is configured as described above. In the yarn producing apparatus 1, the substrate replacing mechanism 30 enables replacement of the CNT forming substrate S. With this configuration, for example, when the CNT fibers F on the CNT forming substrate S run out, the substrate replacing mechanism 30 can replace it with a new CNT forming substrate S. The CNT yarn Y thus can be continuously produced.
Since a plurality of substrate supports 10 are provided, CNT yarn Y can be produced using CNT fibers F drawn from a plurality of CNT forming substrates S. A standby CNT forming substrate S from which CNT fibers F have not yet been drawn may be placed on the substrate support 10. For example, when any CNT forming substrate S runs out of CNT fibers F, CNT fibers F can be drawn from the standby CNT forming substrate S to enable the continued production of CNT yarn Y.
The substrate replacing unit 300 is movable in the direction of a row of a plurality of CNT forming substrates S supported on the substrate supports 10, whereby the operation of replacing the CNT forming substrate S is facilitated.
The substrate replacing mechanism 30 includes the replacement controller 350 controlling the substrate replacing unit 300 such that the CNT forming substrate S supported on the substrate support 10 is replaced with another CNT forming substrate S. In this case, the substrate replacing mechanism 30 can automatically replace the CNT forming substrate S. CNT yarn Y thus can be produced efficiently.
The replacement controller 350 allows replacement of the CNT forming substrate S based on the result of monitoring by the remaining amount monitor 370. In this case, the CNT forming substrate S can be replaced at an appropriate timing, based on the result of monitoring by the remaining amount monitor 370.
The substrate replacing unit 300 moves the holder 304 between the hold position and the substrate storage W. With this configuration, the substrate replacing unit 300 can move the CNT forming substrate S between the substrate support 10 and the substrate storage W.
The holder 304 has the suction ports 304a and holds the CNT forming substrate S by suction force from the suction ports 304a. In this case, the holder 304 can easily hold the CNT forming substrate S using the suction force from the suction port 304a.
The substrate support 10 has the suction ports 11a and holds the CNT forming substrate S by suction force from the suction ports 11a. In this case, the substrate support 10 can easily hold the CNT forming substrate S using the suction force from the suction ports 11a.
Although an embodiment and modifications of the present invention have been described above, the present invention is not intended to be limited to the foregoing embodiment. For example, in the foregoing embodiment, the status monitor 6 is used to detect the thickness of CNT yarn Y. However, in place of the status monitor 6, an image of the CNT fibers F drawn from a CNT forming substrate S may be captured with a camera, and the captured image may be processed to allow monitoring of the amount of CNT fibers F drawn from the CNT forming substrate S or as to whether CNT fibers F are being drawn. In this case, the supply controller 250 can control the initial drawing unit 200 based on the amount of CNT fibers F obtained based on the captured image or whether CNT fibers F are being drawn.
In the embodiment, the suction force from the suction port 213 is used to draw CNT fibers F from the CNT forming substrate S. However, CNT fibers F can be drawn by any method other than the suction force. For example, CNT fibers F can be drawn from the CNT forming substrate S using a tool called a microdrill. Alternatively, CNT fibers F may be drawn with an adhesive tape, a hook-like member, or any other means.
In the embodiment, the suction tube 210 is provided with the guide 212, and the guide 212 is engaged in the recess 203a of the driving roller 203. However, the guide 212 may be provided on the first driven roller 204 side in the suction tube 210, and the guide 212 may be engaged with the first driven roller 204 or the second driven roller 205. Alternatively, the guide 212 may be provided on both of the driving roller 203 side and the first driven roller 204 side in the suction tube 210 to be engaged in the recess 203a of the driving roller 203 and, for example, the recess 204a of the first driven roller 204. The use of a rack gear as the guide 212 and a pinion gear as the driving roller 203 can ensure reliable operation of the suction tube 210.
In place of the CNT forming substrate S, for example, a device that continuously synthesizes carbon nanotubes to supply CNT fibers F may be used as the supply source of CNT fibers F. In the embodiment, the yarn producing unit 4 twists CNT fibers F with airflow. However, the yarn producing unit may twist CNT fibers F by any method other than using airflow. The yarn producing unit 4 and the winding unit 7 may be replaced by, for example, a device that winds CNT yarn Y while twisting (genuine-twisting) CNT fibers F to produce CNT yarn Y. Alternatively, non-twisted aggregated yarn may be produced using a thin tube. In this case, there is no twisting propagation point G, and a roller or a guide may be employed for concentrating CNT fibers F at the position corresponding to the propagation point G.
The present invention enables replacement of the carbon nanotube forming substrate.
1 . . . yarn producing apparatus, 4 . . . yarn producing unit, 6 . . . status monitor, 7 . . . winding unit (continuous drawing unit), 10 . . . substrate support, 11a . . . suction port (suction port in the substrate support), 20 . . . supply state changing mechanism, 30 . . . substrate replacing mechanism, 200 . . . initial drawing unit, 203 . . . driving roller, 203a . . . recess, 204 . . . first driven roller (driven roller), 204a . . . recess, 205 . . . second driven roller (driven roller), 205a . . . recess, 210 . . . suction tube, 206 . . . driving motor (driver), 212 . . . guide, 213 . . . suction port, 250 . . . supply controller (controller of the supply state changing mechanism), 300 . . . substrate replacing unit, 301 . . . arm (movement mechanism), 302 . . . arm driver (movement mechanism), 303 . . . body (movement mechanism), 304 . . . holder, 304a . . . suction port (suction port in the holder), 350 . . . replacement controller (controller of the substrate replacing mechanism), 370 . . . remaining amount monitor, F . . . CNT fibers, S . . . CNT forming substrate, Y . . . CNT yarn, W . . . substrate storage.
| Filing Document | Filing Date | Country | Kind |
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| PCT/JP2013/069797 | 7/22/2013 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
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| WO2015/011760 | 1/29/2015 | WO | A |
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