Patent Application
20200063296
The present invention relates, most generally, to yarns and yarn producing methods, and more particularly to yarns with stretchable conductive elastomeric cores and sheath coverings, and to fabrics and garments produced with such yarns. The invention also relates to systems including conductive elastic yarns and a processor connected to said conductive yarns.
Stretch type fabrics with elastomeric yarns have become very popular and useful in today's garment producing industry. There are many methods used to form elastomeric yarns and stretch type fabrics. The garments formed with such yarns, are very popular in sportswear and athletic uniforms and apparel, but also find application in various other types of fashion clothing because these stretch type fabrics produce form-fitting garments, provide additional comfort and are very useful where a tight fitting garment is needed or desirable.
Even though there are many stretch type fabrics and garments available, many of them lack good elasticity. In many cases, the fabrics and the garments are not sufficiently resilient. Various other materials lose their elasticity in time and tend to sag and crack and become nonfunctional. As such, better elastic materials for garments are needed.
Turning to today's rapidly advancing electronics industry, many sensing devices are being developed and utilized to monitor various body functions, conditions, activities and movements, and athletic performance. For example, these devices may be used to monitor the number of steps a wearer takes, the speed at which the wearer walks or runs and they may be used to sense various other body movements. In other examples, these sensing devices may be used to monitor various metabolic conditions. These sensing devices find particular application in the fields of orthopedics and athletics such as in athletic training where various aspects of a wearer's athletic performance can be measured and evaluated.
Conventional devices of this nature are often bulky and uncomfortable to wear. Conventional devices typically contain metal components that must be worn by the user and are generally uncomfortable. These devices are often strapped onto the user's body over or underneath the user's clothing and may include rigid portions. In many examples, the devices themselves limit the dexterity of the user or otherwise adversely affect the performance of the user.
An example of this type of device is disclosed in WO2003/060449. This document relates to a general-purpose effect-emitting strain gauge device, comprising a stretchable, electrically conductive fabric whose electrical properties change upon stretching, a regulating electrical circuit that generates a signal in response to stretching or relaxing the stretchable fabric of the device. There was an attempt to make this device wearable by using electrically conductive, conjugated polymer-coated fibers and fabrics, typically using polypyrrole and polyaniline as conjugated polymers, however the device was not compatible with textiles.
Conductive elastic yarns are known. EP 1749301 discloses a fiber having an electrically conductive elastomeric structure comprising an elastomeric polymer which is made conductive by addition of antimony-doped tin oxide or carbon nanotubes dispersed in the polymer matrix. WO2015150682 discloses elastic conductive yarns in which the conductive properties are obtained by twisting a synthetic yarn around a metal core yarn, and subsequently twisting the yarn thus obtained around an elastic core yarn. Again, the resulting yarn is poorly suitable to be used in a fabric for garments. Conductive yarns may be used in the textile field as sensors, or part of sensors, connected to a processor to detect a change in the electrical properties of the conductive yarns. The change in electrical properties may come from e.g. a change in the length and/or section area of the conductive portion of the yarn.
There is therefore the need to provide stretch type yarns and fabrics that retain their elasticity through time and use. It would also be desirable to provide electronic monitoring devices that are comfortably worn by a user. There also is the need to provide conductive stretch/elastic yarns that retain substantially unchanged electrical properties after many work cycles. As an example, an electrical property to be maintained substantially unchanged is the electric resistance of a yarn and the way the resistance changes during a loading-unloading cycle. A loading-unloading cycle typically is carried out when the elastic conductive fiber is stretched.
The above problems are solved by the present invention that provides a stretchable conductive yarn with a core that has conductive and elastic properties, and a non-conductive sheath covering the core, according to claim 1. Preferably, the core has first elastic fibers and second less elastic fibers to control the return movement of the conductive elastic fibers. Another object of the present invention is a fabric comprising the above discussed yarns and a garment made of the fabric, according to claim 13. A further object of the invention is a method for forming an elastic conductive yarn, according to claim 23. Another aspect of the invention is a system according to claim 20, including the fabric formed with the conductive elastic yarns, and a processor coupled to the conductive yarns of the fabric.
The present disclosure relates to conductive elastic yarns and the production of the same using various yarn manufacturing processes that produce stretchable conductive yarns for sensing and other applications. The conductive elastic yarns include a conductive core of one or more conductive elastic fibers and an insulating sheath that covers the conductive core. One or more of the conductive fibers may be an elastomeric material into which or onto which conductive particles have been added or onto which a conductive coating has been applied. Various methods may be used to form the conductive cores and the insulating sheaths that cover the cores.
The disclosure also provides fabrics formed with the conductive elastic yarns and various garments formed using the fabrics with the conductive elastic yarns. The conductive elastic yarns can be used in both warp and weft directions in woven and knitted fabric constructions. The fabrics and garments serve as sensors or other electronic components.
Another aspect of the disclosure is a system including the fabric formed with the conductive elastic yarns, and a processor coupled to the fabric. The processor detects body movements of a user wearing a garment formed of the fabric, as a function of change in length or width due to stretching or bending of the fabric.
The present invention is best understood from the following detailed description when read in conjunction with the accompanying non-limiting drawings. It is emphasized that, according to common practice, the various features of the drawing are not necessarily to scale. On the contrary, the dimensions of the various features may be arbitrarily expanded or reduced for clarity. Like numerals denote like features throughout the specification and drawing.
The present disclosure relates to conductive elastic yarns and the production of such yarns using various yarn manufacturing processes. The conductive elastic yarns include a conductive core of one or more elastic fibers and an insulating sheath that covers the conductive core. The conductive elastic yarns are used to produce stretchable conductive fabrics used for various sensing applications in various types of garments and other wearable appliances and devices. The conductive elastic yarns can be used in both warp and weft directions in woven and knitted fabric constructions. The garments formed of the stretchable conductive fabric include various types of shirts, pants, tights, caps, shorts, socks and various other types of apparel. The stretchable conductive fabric may also be used to form a sleeve, a compression sock, or various bands or other appliances or devices worn on various locations on a wearer's body.
The stretchable conductive fabric forms a sensing device and is coupled to appropriate electronics and may be used as an electrical sensor to measure or monitor various bodily functions, conditions and actions for various applications in the medical, orthopedic, athletic, and other fields.
In some embodiments, the conductive elastic yarns are formed using known materials for elastic fibers such as thermoplastic elastomers and thermoplastic elastic polyurethanes (TPU) having a well-combined structure of soft and hard building segments that provides exceptional elasticity. Various elastic polyurethane materials, collectively referred to as elastanes, may be used. In such embodiments, the two segments may be advantageously based on polyethers having low glass transition temperatures, Tg and aromatic isocyanates capable of π-π stacking respectively. These materials are known in the art and commercially available. In various other embodiments, other elastomeric materials and other arrangements are used to form the conductive elastic core fibers of the yarn. Suitable materials for the elastic fibers are: polyurethane such as that used to produce elastane (e.g. Lycra, dorlastan), spandex (RadicciSpandex Co), Lastol (Dow Chemical XLA). The first elastic fibers are preferably in the form of a filament or a bundle of filaments.
Still various other types of commercially available elastic fibers, and other elastic materials being developed, may be used as the elastic fibers according to the disclosure. In some embodiments, the elastic core of the inventive yarn includes a first fiber that is highly elastic and at least a second fiber that is less elastic than the first fiber and has good recovery properties. The first fiber can be stretched by at least 300%, preferably at least by 400%, as measured according to ASTM D3107 or BISFA (The International Bureau for Standardisation of Man-made Fibers), DIN 53835-2, and standards.
Suitable materials for the second fiber, i.e. the less elastic, control, fiber, include polyamides such as nylon (e.g., nylon 6, nylon 6,6, nylon 6,12 and the like), polyester, polyolefins such as polypropylene and polyethylene, mixtures and copolymers of the same, PBT and bicomponent filaments namely elastomultiesters such as PBT/PET and PTT/PET filaments such as T400 ® by Invista®. The second less elastic fiber is usually textured, or crimped, in its relaxed state; the second fiber may be tensioned to a substantially linear condition and when the tension is removed, it returns to the initial crimped condition. The second fiber is preferably in the form of a filament or of a bundle of filaments.
According to the disclosure, the first elastic and conductive fibers and the second, less elastic fibers are combined together in a tensioned condition and arranged in the core of the yarn in such a way that the second fiber can act onto the first fiber, when stretched and thus elongated, to help the first fiber returning to the initial length that the first fiber had before being stretched with the fabric. There are known different ways of obtaining such an effect. US 2008/0318485 discloses to combine elastic (elastane) and less elastic (polyester) fibers and twisting them together, possibly with the cotton sliver, to provide an elastic yarn. Reference is made in particular to paragraphs 24, 28 and 29 of US'485. Another disclosure of how to combine elastic and less elastic fibers is available from US 2010/0281842, e.g. from paragraphs 22-25 and 35, where the less elastic fiber combined with the elastic fiber is referred to as a “control filament”. WO 2012/062480, in the name of the present applicant, discloses a method of combining the first and second fibers in which the fibers are connected together to act as a single fiber during the tensioning and relaxing steps (i.e. during loading-unloading processes). Possible connecting methods disclosed in WO'480 are intermingling, twisting at a high number of twists per meter and coextrusion.
In the present description, coextrusion is intended to indicate any process according to which at least two types of fibers (e.g. conductive elastomer and polyester or other less elastic fiber), are mechanically connected together by compressing them together, preferably in a stretched condition of at least one of the fibers. As in the other connecting methods of WO'480, also “coextrusion” is carried out on fibers that are moving along an apparatus for treating fibers. The fibers are passed together through a device where they are coextruded in the sense of being forced and passed into a same space of reduced volume, so that they are compressed together. An exemplary device for coextrusion-connecting fibers is a roll having a “V” shape; the fibers are forced into the bottom of the roll “V”, where the fibers are compressed together and thus connected to form a single bundle of fibers.
In another embodiment, the tensioned bundle of fibers to be connected may be fed to a same location of a couple of rollers, e.g. in a groove, where they are compressed together and thus connected together. At least some fibers may have been treated with chemicals during their production said chemicals may improve adhesion of the fibers of the two bundles to each other.
The thus obtained bundle of first and second fibers is then fed to the sheath forming apparatus, generally a ring spinning machine, that will impart some twisting also to the single bundle of connected fibers, during the ring spinning process, as is known in the art. In a preferred embodiment, the device for connecting the fibers of the two bundles is located close to the apparatus for covering the multi-fiber elastic and conductive core, such as e.g. a ring spinning apparatus; in this way the fibers connected by coextrusion are not accidentally separated before they are fed to the ring spinner.
The present disclosure provides for forming electrically conductive yarns from materials that are per se electrically insulating, such as TPU's or other elastomeric materials, by adding conductive materials to the originally electrically insulating elastomeric materials. This may be via addition of at least one of the following: carbon nanomaterials, nanoparticles of metal or metal oxides, other metallic and non-metallic particles, and mixtures thereof. Suitable materials are ZnS, Ag, and carbon nanomaterials, in particular carbon nano-powders. The dimensions of the conductive material may advantageously lie in the range of 0.1 nm to about 250 nm. In the advantageous embodiment in which TPU is the elastomeric material, a conductive TPU (c-TPU) is formed by incorporating the conductive impurities within the TPU material. In other embodiments of electrically conductive yarns, the conductive materials are variously dispersed in the elastomeric fibers in various manners within the matrix of the elastomeric material.
The amount of conductive impurities in the fibers may depend on the type of material; as a general rule, conductive impurities are present in the fibers in the range of about 1% by weight to about 50% by weight of the fiber, but other formulations such as 25-50% by weight, may be used in other embodiments.
In each of the aforementioned examples, conductive impurities may be introduced to the elastomeric fiber using various techniques. In some embodiments, the conductivity is produced by the addition of conductive additives above the percolation threshold of the elastomeric material followed by dry or wet spinning processes as will be described further below. The percolation threshold is the critical value of the occupation probability p, or more generally a critical surface for a group of parameters p1, p2, . . . , such that infinite connectivity, i.e. percolation, first occurs. In other embodiments, other methods for impregnating the elastomeric fiber with conductive dopants may be used. In some embodiments, mechanical mixing is used. In still other embodiments, the conductive impurities are coated externally on the surface of the elastomeric fiber. The coating may be a coating that includes the conductive nanoparticles described above or it may be any other suitable conductive coating.
The elastomeric conductive material may be cast into mono-filaments (preferably) and/or into staple fibers and may be utilized as-is or together with other fibers in a yarn. The conductive stretch core includes one or multiple fibers, i.e., a bundle of fibers. One or more of the core fibers has elastic properties. One or more of the core fibers has conductive properties. The conductive elastomeric core is characterized by excellent recovery and resiliency properties provided by one or more of the core fibers. The conductive elastomeric core is completely covered by an insulating sheath to form a stretch yarn. The insulating, i.e. a sheath may be a cotton fiber sheath, preferably a cotton staple fiber, but other materials are used in other embodiments. In some embodiments, the insulating sheath completely covers the core so that none of the core surfaces through the fibers of the sheath at any time, including after use. Other insulating sheath coverings are used in other embodiments. The stretch yarn may be used alone or within a fabric construction, woven or knit.
The c-TPU or other conductive elastomeric materials provide new and advanced applications for yarn and further the applications for current yarns by providing a stretchable sensing material that is wearable and finds various applications in the electronics industry as referred to above. Typically, conductivity of the elastic fibers is 1.00×101 to 1.00×104 S/cm (Siemens/centimeter) measured by ASTM D 257 and ESD STM11.11 standards.
The conductive elastomeric materials may function as various types of sensors based on their resistive, inductive, and capacitive characteristics. The conductive stretchable fabric may be used for sensing body movements as a function of dimensional (e.g. diameter of the conductive core) change induced stretching (e.g. elbow and knee regions), i.e. a strain sensor. In some embodiments, the conductive stretchable fabric functions as an electrode, signal path, a heater or various electromagnetic insulating materials. The sensing devices find application in the medical, orthopedic, athletic and other fields. In some embodiments, the stretchable conductive fabric is used to monitor the number of steps a user takes or the speed at which the wearer walks or runs and the stretchable conductive fabric may be used to sense various other body movements. In other embodiments, the sensing devices are used to monitor various metabolic conditions such as body temperature, heart rate, blood pressure and various other conditions. Various processors and other electronic components and devices may be suitably coupled to the conductive fabric so that the c-TPU or other conductive fabric may be used as sensing platform in the wearable electronics field. An example of processor that is part of a garment is disclosed in WO 2017/017260. The coupling with the processor may be through a wire or wirelessly.
As previously discussed, the elastic conductive fibers (generally in the form of filaments) are combined with the second fibers to provide the core of an elastic yarn. It was found that the presence of the second, less elastic, usually textured, fibers results in a core where after each elongation of the yarn by stretching it, the elastic fibers are brought back to their initial length (or to substantially their initial length), notwithstanding the presence of conductive elements in the elastic fibers. Because the elastic component of the core goes back to (substantially) its initial length, the elastic conductive portion of the yarn of the invention will always have (substantially) the same geometry in a relaxed, i.e. not tensioned, condition. This same geometrical initial condition of the elastic fibers results in the fact that the values of the parameters depending upon the geometry of the elastic part of the core are (substantially) the same at the beginning of a loading-unloading (stretch-relax) cycle, i.e. when the yarn is not stretched, or tensioned. Any detected change of said values will be caused by the change of the geometry of the elastic fibers during the deformation that is being detected.
Now referring to the figures, each of
The fibers i.e. first fiber 4, second fiber 5, and third fiber 6, that make up core 2 may be connected together as previously discussed, e.g. by twisting, intermingling or co-extrusion. In some embodiments in which the fibers are intertwined, they can be intertwined to various degrees. The respective fibers may be connected together to various degrees and in many manners. In various embodiments, multiple conductive elastic fibers may be co-extruded with man-made fibers, intermingled with man-made fibers, twisted single ply or two ply with man-made fibers or twisted single ply or two ply with natural fibers, or air jet texturized (AJT) with man-made fibers.
In the embodiments of
First fiber 4, second fiber 5, and third fiber 6 may be formed of the same or different material and at least one has a different degree of elasticity. In one embodiment, one of the fibers may be stretchable to a length of 400% of its original length and one of the other fibers may be less elastic but stretchable to about 20% of its original length. In some embodiments, before connecting the core fibers, at least one elastic core fiber, e.g., first fiber 4, second fiber 5 or third fiber 6, is stretched, combined with other fibers and then released, so that after interconnection with the other fiber or fibers, the stretched and released fiber will recover and reduce its length. This will result in an amount, or length, of one or two of the other fibers being available for stretching of the core, multicomponent, yarn. In this manner, the composite yarn can be significantly stretched even if one or more of the other fibers is less or much less elastic than the other fiber or fibers. In various embodiments, the interconnected fibers of the core of the disclosed yarn act substantially as a single fiber. In embodiments in which a first fiber is stretched, as described above, the high recovery properties of the second and/or third fibers will result in the yarn, and, more particularly, the final fabric, being at the same time stretchable and having excellent recovery properties.
Because of the structure of the elastic conductive core having first and second fibers and its excellent recovery properties, an advantage of the claimed yarn is that the electric properties of the elastic and conductive yarn are maintained through its use and through the life of the fabric incorporating the invention yarn. In fact, after elongation, when the force stretching the fiber is released, the elastic fiber will recover substantially entirely the dimensions that the fiber had before it was stretched. The elastic properties that depend on the dimensions of the fiber or yarn will thus be maintained substantially constant, notwithstanding the repeated and frequent use of the fabric. This recovery may be obtained by means of the presence of the second fiber (or by the presence of the second and third fiber). In some embodiments, a bare elastane fiber may be one of the fibers so as to maintain original dimensions of the elastic yarn.
In the present description, “co-extrusion” is intended to indicate any process according to which at least two fibers e.g. a conductive elastomer fiber and a polyester fiber, are mechanically connected together by compressing them together, with one or both fibers advantageously in a stretched condition prior to being mechanically connected. The connecting of the fibers by mechanical means may include compacting by compression. Similar to the other methods for joining the core fibers, “co-extrusion” is carried out on fibers that are moving along an apparatus for treating fibers. The fibers may advantageously be in a stretched state prior to being joined. In some embodiments, one of the fibers may be stretched to 2-4 times its original length and the other fiber may be stretched to 1.1 to 1.5 times its original length, but other degrees of stretching may be used in other embodiments. The fibers may additionally or alternatively include a chemical coating to help adhesion, prior to being joined. The fibers are passed together through a device where they are forced together into a space of reduced volume, so that they are mechanically compressed together. An exemplary device for connecting fibers is a roll having a “V” shape, where the fibers are forced into the bottom of the “V” part of the roll, where the fibers are compressed together and thus connected to form a single bundle of fibers such as fibers 4, 5, 6 of core 2 of
In another embodiment, two or more fibers to be connected together, are fed to the same location of a pair of rollers, e.g. a groove, where they are compressed together and thus mechanically compressed together. At least some fibers may have been treated with chemicals during their production and prior to being joined together by co-extrusion. The chemicals may improve adhesion of the fibers of the two bundles to each other.
The bundle of core 2 fibers 4, 5, 6 obtained by co-extrusion through a narrow space as above discussed, may then be fed to the sheath forming apparatuses (e.g. ring-spinning apparatus) such as will be shown in
In view of the above, it is clear to the skilled person that co-extrusion as used herein with reference to core fibers, signifies a process of connecting two or more fibers by mechanical compression. This mechanical compression, or compacting by compression, takes place before the joined fibers are provided with an insulating sheath, usually a sheath of staple fibers that are spun onto the conductive elastic core. The fibers joined by co-extrusion may advantageously be in a stretched state when joined together. It is also clear to the skilled person that co-extruded fibers as used herein, describe two or more fibers joined together by co-extrusion, such fibers initially being mechanically joined together and substantially parallel with minimal or no twisting as formed, before being fed to a ring-spinning apparatus to provide the core with a sheath.
A T-400 yarn package is loaded on the creel (not shown). The T-400 yarn is guided to a feeding roller and wound around the roller five times. An elastomer, e.g. elastane yarn package is loaded on draft rollers to be provided a draft, and the elastane yarn is guided through a sensor and combined with 1-400 yarn at a feeding roller. From the feeding roller the combined fibers are guided to an Intermingling Air Jet 18, e.g. a Sincro Jet intermingling device from Fadis, Italy.
Subsequently, the intermingled fibers are guided to a lubricating station and are eventually wound on composite yarn package 206 that will be shown in
In the various illustrative embodiments, the fibers, i.e. first fiber 4, second fiber 5 and third fiber 6, may be of the same diameter or they may have different diameters.
When more than one of the first fiber 4, second fiber 5 and third fiber 6 are conductive, they may include different degrees of conductivity and may be formed of the same or different conductive additives.
One or more of first fiber 4, second fiber 5 and third fiber 6 may be formed of c-TPU or the various other thermoplastic elastomers, as described above. In addition to c-TPU and the other elastomeric materials listed above, suitable materials for one or more of first fiber 4, second fiber 5 and third fiber 6 include polyurethane fibers such as elastane, spandex and those fibers that have similar elastic properties. In some embodiments, at least one of first fiber 4, second fiber 5 and third fiber 6 in chosen to be a fiber that can stretch to 400% of their initial length (e.g. as elongation at break) or greater. In particular embodiments, one or more of the first fiber 4, second fiber 5 and third fiber 6 may be formed of T162C, T178C, T136C, 1902C and polyolefin elastomers such as XLA. T162C, T178C, T136C T902 are types of Spandex products by Invista and mainly consist of copolyether-based soft segments and 4,4′-Methylene diphenyl diisocyanate (MDI) based hard segments as building blocks. XLA is a crosslinked, homogeneously branched ethylene polymer developed by DOW chemical company. Other commercial examples of elastomeric fibers used for one or more of first fiber 4, second fiber 5 and third fiber 6 include but are not limited to, Dowxla, Dorlastan (Bayer, Germany), Lycra (Dupont, USA), Clerrspan (Globe Mfg. Co., USA), Glospan (Globe Mfg. Co., USA), Spandaven (Gomelast C. A, Venezuela), Roica (Asahi Chemical Ind., Japan), Fujibo Spandex (Fuji Spinning, Japan), Kanebo LooBell 15 (Kanebo Ltd., Japan), Spantel (Kuraray, Japan), Mobilon (Nisshinbo Industries), Opelon (Toray-DuPont Co. Ltd.), Espa (Toyoba Co.), Acelan (Teakwang Industries), Texlon (Tongkook Synthetic), Toplon (Hyosung), Yantai (Yantai Spandex), Linel, Linetex (Fillatice SpA). These and other fibers may be chosen for providing generally good elastic properties and are high stretchability. Polyolefin fibers may also be used.
In each of the aforementioned examples, one or more of the fibers of first fiber 4, second fiber 5 and third fiber 6 includes conductive impurities as described above. Preferably, the elastomeric (elastic) fibers are conductive and the less elastic (control) fibers are not conductive.
In
In other embodiments, different numbers of fibers may combine to form conductive elastomeric core 2.
Referring once again to
The materials of sheath 3 surround conductive elastomeric core 2. In various embodiments, sheath 3 completely covers elastomeric conductive core 2. Any suitable process used to cover elastomeric conductive core 2 with the cotton or other fibers to produce sheath 3, may be used. Core-spun and ring spun technologies are known and widely used processes in the textile industry, and involve combining two or more yarns with different features, to form one yarn member. These and various other methods for spinning fibers to produce a yarn may be used. Any spinning method to produce a yarn 1 having a core disposed within sheath 3 lies within the scope of the present disclosure. Ring spinning is a method of spinning fibers, such as cotton, flax or wool, to make a yarn, and may be used in various embodiments. The disclosure also provides for the yarn including sheath 3 and elastic conductive core 2 to be formed using core spinning with elastic conductive core 2 fed into the cotton or other material that forms sheath 3. Along with core-spinning and ring spinning, the texturizing of cotton, polyester, or polyamide with thermoplastic elastomers or TPUs, are among the methods used to achieve elastic yarns and fabrics of the disclosure.
Various methods for forming a yarn by combining a stretchable core including one or multiple fibers that have elastic properties with an insulating sheath covering, are provided in WO2012/062480, referred to above and the various processes provided therein may be used according to the present disclosure, to produce novel conductive elastic yarns for sensing and various other applications.
In some embodiments, the elastomer forms about a 20-50 wt % in the solution and in some embodiments, the elastomer material forms about 20-30 wt % of the solution, but other weight percentages and other solvent solutions may be used in other embodiments.
The process also provides for combining the elastomer/TPU solution with a desired conductive material, step 102. In various embodiments, a continuous conductive core may be made by adding conductive additives to an elastomer such as but not limited to the elastomeric materials provided herein. Conductive additives such as described above, may be used and according to the embodiment in which the elastomeric material is TPU, the addition of the conductive additives forms c-TPU. The conductive additives may be introduced into the matrix of the elastomer material via mechanical mixing of the additives and/or surface coating. The mixing may involve adding the conductive additives to the elastomeric material-containing solution to exceed the percolation threshold of the elastomeric material in the solution. The addition of the conductive additives in the solution forms a dispersed solution via diffusion in a controlled manner. Such addition may be advantageously done in a controlled manner to avoid bulky and gummy particle accumulations. Conductive additives may be mixed with compatibilizers prior to mixing with elastomeric material containing solution in various embodiments.
At step 104, the solution of elastomer/TPU with conductive additives may be used in a wet spinning or dry-spinning process to form the conductive fibers described above, which can serve as elastomeric conductive core 2. Embodiments of dry and wet spinning apparatuses are shown in
At step 106, the process provides for combining the conductive elastomeric fibers formed at step 104, with second fibers, to form an elastomeric (elastic) conductive core 2 such as by twisting, intermingling or co-extrusion. According to embodiments in which the elastomeric conductive core includes multiple fibers, they may be combined in various manners as described above. Step 106 also provides for ring spinning or core spinning of the elastic conductive core, with further materials such as various conventional and other natural and man-made fibers such as described above, to form an insulating sheath that covers the elastomeric conductive core. The elastic conductive core may include one or multiple core fibers such as described above. Various methods for forming a yarn with a stretchable core including one or multiple fibers that have elastic properties and covered by an insulating sheath, are provided in above-identified US Patent Application Publ. No. 2013/0260129, for example and are shown in
A homogenous solution of elastomeric material including conductive additives may be pressurized through a nozzle, or spinneret, to form multiple fine fibers having diameters between 1-50 μm in some embodiments. Depending on the type of spinning process used, the solvent may be removed either via warm air evaporation, or by washing in a water bath followed thin layer evaporation to collect the solvent for reuse. In some embodiments, various methods may be used to coat the elastic fiber with a conductive coating during or after the dry or wet spinning process. Some coating methods include spraying, kiss roll, dipping and padding but other coating methods are used in other embodiments. Suitable coating materials include but are not limited to conductive metal oxides, in-situ nanoparticle forming solutions, carbon nanomaterials.
The solution of elastomeric material including conductive additives is pressurized through spinning nozzle 24 to form multiple fine fibers 28 which may have diameters ranging from about 1-50 μm in some embodiments but other diameters are achieved in other embodiments. Multiple fine fibers 28 are formed within chamber 30. Chamber 30 includes inlet 32 through which air may be introduced as indicated by arrows 34. Chamber 30 also includes outlet 36 through which evaporated solvent may be exhausted. Multiple fine fibers 28 may be conductive elastic fibers and may be combined to form fiber 38 by winding unit 40 which includes rollers 42 that draw and stretch the fiber 38.
In some embodiments, the above-disclosed elastomeric conductive core 2 may be comprised of T400 and elastane, in which the T400 fibers are bicomponent fibers and have 75 denier and elastane fibers have 40 or 70 denier. The yarn count of this composite core is 81.5 or 90 denier which is 2.25-7 times thicker than regular corespun elastane yarns. “Denier” is a unit of weight for measuring the fineness of threads of silk, rayon, nylon, etc. . . . . Suitable conductive additives are included, such as described above.
Due to the dimensions of a T400+Elasthane elastomeric conductive core 2, the relevant bobbin may be much bigger than a bobbin of elastane; therefore, as shown in
T400 and elastane or another arrangement of elastomeric conductive core 2, is guided between two tension bars 210 that are used to give a low pre-tension to the yarn, just to align and straighten conductive core 2. This is useful in view of the nature of elastomeric composite core “yarn” 2, especially when the composite yarn is obtained by intermingling of two fibers, namely T400 and elastane. From pre-tension bars 210, elastomeric conductive core yarn 2 is fed to two driving rollers 211 on which a weight 212 is placed. Elastomeric conductive core 2 is guided between the driving rollers and the weight 212 to avoid free movement of the core yarn with respect to the rollers 211, however, other suitable means for imparting a controlled speed to elastomeric conductive core yarn 2 may be used instead of the combination of rollers 211 and weight 212 in other embodiments, e.g. means such as draft rollers known in the art.
One advantage of the above disclosed arrangement is that the same apparatus can be used also to prepare a standard elastane core yarn. In this embodiment, the elastane fiber is loaded in a package that is placed on the rollers 211 in the place of weight 212.
From the first drafting arrangement 211, 212, elastomeric conductive core 2 is guided to a rolling guide 213 and from it to draft rollers 214, that are the foremost couple of a plurality of drafting rollers for the cotton roving 208, such as may be available in the art. Cotton roving 208 is guided from spool 207 in front of pre-tension rollers 210, driving rollers 211, into a first guide 215 and a second guide 216. As can be seen in
From guide 216, cotton roving 208 is sent to draft rollers 220, 222 and 214. Draft rollers 214 are in common between elastomeric conductive core 2 and roving 208.
According to the invention, elastomeric conductive core 2 is tensioned before being coupled with the cotton roving, the tensioning or stretching is obtained by means of the speed difference between rollers 211 and rollers 214, i.e. the speed difference between rollers 211 and the last draft roller 214 create the draft ratio in composite core “yarn”. As mentioned, the draft ratio of the composite core may be within the range of 1.05 to 1.16, preferably in the range of 1.10 to 1.14 and most preferably from 1.12 to 1.14. The above draft ratio is calculated as the ratio of the speed of rollers 214 versus the speed of rollers 211, where the speed is the angular speed on the surface of the rollers.
Pre-tensioning bars 210 contribute to obtaining the required draft ratio. The additional pretension bars 210 are useful in increasing the draft ratio from 1.05 to 1.14 because they provide an alignment and slight tension of the elastomeric conductive core 2, thus helping in the further stretch step. This results in the extreme accuracy with which the elastomeric conductive core 2 is kept in the center of the final yarn 1.
Use of additional guide 215 and its staggered position with respect of guide 216 also allows the cotton roving to be fed always at the same position and prevents the moving of cotton roving during the long run production. The combination of a better control in keeping the position of cotton roving 208 and a high tension on elastomeric conductive core 2 makes it possible to keep elastomeric conductive core 2 centered in the final yarn 1 and to perfectly cover the core with the staple fibers 3. The two portions of final yarn 1 leaving draft rollers 214 are fed through guide 217 and spun together at spinning device 218, known in the art and comprising in one embodiment ring, traveler and spindle.
Any spinning method to produce a yarn 1 having a elastomeric conductive core 2 centered in a sheath 3 is within the scope of the present invention. Such methods include e.g. covered yarn system (using machinery by JCBT, Menegato, OMM, RATTI, RPR, Jschikawa) or twisting machines (using machinery by Hamel, 2 for 1 by Volkman, SiroSpin by COGNETEX or Zinser).
The elastic yarn produced as big weft packages as above described with reference to
The obtained fabric may then be treated with finishing processes, e.g. additional processes can be carried out such as a thermal treatment of the stretched fabric to set the required stretch value for the fabric itself. These treatments are known in art and are carried out in function of the final characteristics required for the fabric.
Produced is a novel product of a yarn with an elastic conductive core of one or more fibers, at least one of which is a conductive fiber and in which the conductive core is an elastic material and is covered with an insulating sheath such as described above. The core-spun/ring-spun yarns having the continuous conductive elastomeric core can be used for sensing and monitoring applications. The yarns may be used in the weft or warp direction to form various stretch fabrics such as denim fabrics. The stretch denim fabrics may be used to form various garments or other apparel to be worn on various body parts of a wearer.
In one embodiment such as shown in
In other embodiments, the yarns are used to form various other garments or other apparel or wearable devices. The garments may be worn tightly on the wearer's body. The garments may be suitable as fashion attire or they may be garments with a dedicated used in athletic orthopedic or other medical fields. The conductive fabric may serve as an electrode, a signal path, a strain sensor, a heater or various electromagnetic insulating materials.
The stretchable conductive fabric is coupled to suitable circuitry such as electrical components 76 shown in
The preceding merely illustrates the principles of embodiments of the disclosure. It will thus be appreciated that those skilled in the art will be able to devise various arrangements which, although not explicitly described or shown herein, embody the principles of the disclosure and are included within its spirit and scope. Furthermore, all examples and conditional language recited herein are principally intended expressly to be only for pedagogical purposes and to aid in understanding the principles of the invention and the concepts contributed by the inventors to furthering the art, and are to be construed as being without limitation to such specifically recited examples and conditions. Moreover, all statements herein reciting principles, aspects, and embodiments of the disclosure, as well as specific examples thereof, are intended to encompass both structural and functional equivalents thereof. Additionally, it is intended that such equivalents include both currently known equivalents and equivalents developed in the future, i.e., any elements developed that perform the same function, regardless of structure.
This description of the embodiments is intended to be read in connection with the figures of the accompanying drawing, which are to be considered part of the entire written description. In the description, relative terms such as “lower,” “upper,” “horizontal,” “vertical,” “above,” “below,” “up,” “down,” “top” and “bottom” as well as derivatives thereof (e.g., “horizontally,” “downwardly,” “upwardly,” etc.) should be construed to refer to the orientation as then described or as shown in the drawing under discussion. These relative terms are for convenience of description and do not require that the apparatus be constructed or operated in a particular orientation. Terms concerning attachments, coupling and the like, such as “connected” and “interconnected,” refer to a relationship wherein structures are secured or attached to one another either directly or indirectly through intervening structures, as well as both movable or rigid attachments or relationships, unless expressly described otherwise.
Although the invention has been described in terms of embodiments, it is not limited thereto. Rather, the appended claims should be construed broadly, to include other variants and embodiments of the invention, which may be made by those skilled in the art without departing from the scope and range of equivalents of the invention.
| Number | Date | Country | Kind |
|---|---|---|---|
| 17169397.1 | May 2017 | EP | regional |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2018/061625 | 5/4/2018 | WO | 00 |
