The present invention concerns a three-dimensional thermoformed element.
Many lining elements, typically an inner lining, as in a vehicle, such as an aircraft, train, ship or automobile, are already used for protection purposes, typically thermal and/or acoustic protection, or as a fire barrier element.
For this type of elements, which are typically molded, problems still exist both in terms of structural realization and conditions of use. For example, there are elements with compounds in powder and/or porous form, which pose problems of dispersion and/or handling. Structural problems may also arise, for example, in the context of compromises to be made between requirements for protection (e.g. thermal and/or acoustic and/or fire barrier as mentioned above) on the one hand and volume and/or weight on the other, especially when mounting in cramped and/or difficult-to-access locations. Special shape requirements may also be established.
For example, in an automobile, the floor and walls connecting the passenger compartment to the boot space and the passenger compartment to the engine space are lined with insulating molded parts. These molded parts must be adapted to chassis parts that are sometimes complex, irregular in mechanical strength and/or protective capacity.
Some three-dimensional molded parts, e.g. for sound insulation, may be produced from PU foam (polyurethane). However, this is relatively expensive. In addition, PU foam is also difficult to recycle. Molded parts made from conventional fiber mats, which are manufactured from fibrous material by rollers, are only suitable to a limited degree. Fiber mats may only be used for slightly deformed parts. In addition, due to the lamination method, they do not have a uniform density distribution. Consequently, they often do not meet the geometric and acoustic requirements imposed on these special molded parts.
Within this framework, and in order to provide an adaptable solution for different demanding environments, an assembly is proposed here comprising:
Thus, thermal insulation and acoustic insulation are usefully coupled.
The expression “inner lining element” has the meaning:
In fact, and in a conventional way, the porous structure will be interposed between two major surfaces of said barrier wall.
“Major surface” is to be understood in conjunction with “minor (or marginal) surface”, which is the area where the sheets (or portions of sheets) forming the barrier wall are interbonded and sealed together to close the envelope. Complementarily, the two “major surfaces” together form the area (the larger: major) of the envelope bounded by this sealing zone and which forms the active (thermally insulating) part of the envelope.
“Porous” (porous) refers to a material (or structure) having interstices allowing the passage of air. Porous, open-cell materials therefore include foams but also fibrous materials (such as glass or rock wool). The passage interstices, which may be described as pores, have sizes smaller than 1 or 2 mm so that good thermal insulation may be guaranteed, and preferably smaller than 10 microns.
The porous structure may include or be made of polymeric fibers, mineral fibers or natural fibers. The term fibers is to be understood in a conventional way. These are elongated elements with a length L (which corresponds to its largest dimension) and, transverse to this length, a section where the fibre has a main dimension d (such as a width or a diameter), with a ratio such as L≥5d, and preferably L≥10d.
The porous structure may be of a textile nature, which would provide a structuring effect, resulting in a fairly light element with a wide variety of shapes.
The thermoformable barrier wall may be similar to a film, with a thickness between 50 and 200 microns. But it could be thicker.
According to the conventional definition, the envelope will then be a flexible object whose shape (like its material: the film) and the shape of the porous structure it surrounds will adapt to each other. A synonym would then be: bag or pocket.
Of course, the envelope surrounds the porous structure by covering it completely.
It is also proposed:
If this is the case, the thermoformed barrier wall will have a double effect: that of increasing the thermal protection of the said element, due to the depression created in the envelope, and that of mechanically maintaining (or freezing) the 3D shape.
It is also proposed that the envelope, with a porous structure in three dimensions, as the said at least one thermal insulating element :
Thus, an adaptation to local configurations by associating a 3D shape to such configurations will be reached.
To maintain(freeze) its shape, once deformed, the three-dimensional porous structure (thus non-planar) may or may not contain a binder (chemical implication).
The combination in particular between a film as mentioned above and the porous structure will make it possible both to achieve and to maintain over time a 3D shape that is both light, with interesting thermal and/or acoustic characteristics, or even mechanically solid, depending on the density(s) of the porous structure selected.
In particular with a thermoformable barrier wall such as a film, it is recommended that the thermoformed wall has a breaking strength greater than 1 MPa, and preferably between 10 MPa and 300 MPa.
Thus, especially in the absence of a binder, the wall will be able to impose on the porous structure the expected 3D shape, forcing it to deform from its initial raw shape, typically a 2D shape.
In particular with a porous structure comprising or consisting of fibers, and to complete the compromise between lightness/structuring/ease of fabrication/functionalization(s) possible within the envelope, it is however also proposed that the porous structure may include a binder, so that, in the case of fibers, a matrix is formed where said fibers will be bonded together at their contact or crossing areas. However, this is not mandatory. Both hypotheses are discussed in more detail below.
If present, and for the same purpose as above, the binder will preferably comprise a glue and/or adhesive.
In addition, such an element will easily lend itself to targeted functional applications, in particular due to the structuring provided by the porous structure.
Therefore, it is proposed that the said thermoformed element may additionally comprise, in the envelope, a thermal insulation, so that at ambient temperature and pressure, the thermoformed element has, through the barrier wall, a coefficient of thermal conductivity (A) lower than 30 mW/m·K.
In the application, ambient temperature and pressure mean 20° C. and 105 Pa, respectively, +/−10%.
It may be relevant that (at least) a phase change material (PCM) is provided in the envelope.
The combined use of a porous structure and dispersed particles for the PCM(s) and/or the thermal insulation will make it possible to obtain, in an industrially feasible way in series, a variable concentration of these components that the binder will fix and unite.
With a porous structure as above, and whether or not there is thermal insulation and/or MCP, the said element will favorably present, +/−5%, a thickness between 0.8 and 20 mm, and a density between 5 and 350 Kg/m3.
Preferably, the pore volume (void space) will be between 80 and 99% (by volume).
With or without binder, another aspect provides that the invention allows the said element to be adapted to its operational environment, and in particular to obtain:
In this way, it is easy to vary the thermal conductivity and/or mechanical strength in the direction of thickness, albeit to a limited extent, but without necessarily having to add fillers in the textile structure (MCP or thermal insulating material such as aerogel; see below).
In particular, for example to thermally manage a vehicle battery pack (electric accumulators), it is also proposed:
And, to ensure an efficient compromise between the thermal management of this battery pack, for example, and the mechanical constraints (protection and resistance) and available space, it is still proposed:
In another application, it is proposed that in the assembly:
This will improve insulation without penalizing either weight or bulk.
Another relevant application, with comparable advantages, is where:
Another relevant application, again with comparable advantages, is where:
Another relevant application, again with comparable advantages, is one in which the structural element would include:
To facilitate handling, storage and safety, it is also proposed that the thermal insulating element and the second porous structure be enclosed together in a second envelope which will typically be a film (thickness less than 1/10 mm) and which may be a fire wall (meeting the following specifications: UL94 V0 and/or FAR 25.856; then with further enhanced safety).
For compactness and mechanical/energy performance, the second porous structure may be bent-shaped and/or may have reliefs and/or depressions.
The thermal insulating element and the second porous structure will typically be interposed between two said major surfaces of said wall, which will then be thermoformed at the location of said two major surfaces.
The invention will if necessary be better understood and other details, characteristics and advantages of the invention may appear when reading the following description made as a non-limiting example with reference to the appended drawings in which:
We have thus represented, in
This set includes:
It will have been understood that the expression “in three dimensions” (3D) is equivalent, as in the common sense, to not (integrally) plane. The thermoformed set 1, like thus the fibrous textile structure 5, is represented bended; but they could also present common local reliefs and/or depressions, as for example in zones respectively 25, 27 in
The porous structure 5 will be advantageously based on powder or a fibrous textile structure and thus will include polymeric fibers, mineral fibers (glass, basalt for example) or natural fibers (cellulose, flax, hemp for example). The fibrous textile structure 5 is then a woven or non-woven fabric. A felt will be interesting for its intrinsic compression (felt is a compressed, non-woven structure obtained by pressing and agglutinating fibers). In addition to this intrinsic compression, the felt would advantageously be compressed later in the shaping mould (30a or 30b below;
Felt, or more generally the fibrous textile structure 5, may be presented as a slab (see
Wall 7a is thermoformable, in the sense that it then comprises a polymer film that has been thermoformed: polymer alone or metal lined, such as a complex or composite film: metallized PET film where PET has been sprayed with aluminum.
The polymer film (alone or thus metal-backed) 7a will have been thermoformed at the location of the two major (or main) surfaces, S1 and S2
Envelope 7 contains in a closed manner the porous structure 5; and its wall 7a follows the shape of this porous structure, where it faces it (major surfaces S1 and S2).
As shown in
As mentioned above, the sealing of the wall 7a on itself may have consisted of gluing or welding. This confirms that, in the set 1 formed in three dimensions, the porous structure 5 and the envelope 7 retain, as initially, their respective structural identities. They are not fused together. They remain distinctly identifiable; they are structurally independent of each other: It is possible to cut the envelope 7 and remove it from its position around the fibrous structure 5 without having to tear it off. It is therefore not a coating or surface layer (coating as in U.S. Pat. No. 4,035,215).
If it is a “film”, material 7a will have a favorable thickness between 30 and 800 microns, preferably between 50 and 150 microns.
In the case of a porous structure 5, e.g. fibers 3 without binder (see below and
This tensile strength (“tensile strength”, often abbreviated as (TS), or “ultimate strength”, Ftu) of a typical 7a film, whether in a version after the above-mentioned thermoforming step, or before (state of this film as marketed before its implementation in accordance with the present invention), will be favorably higher than 1 MPa, and preferably between 10 MPa and 300 MPa and even more preferably between 50 MPa and 100 MPa.
If these characteristics are not respected, the relatively free character of the porous structure 5 and the mechanical resistance of the envelope 7, whose thermoforming will thus have fixed a common “3D” shape by constraint of the said structure and softening of the film 7a, will not be able to ensure that the thermoformed assembly 1 maintains(freezes) its 3D shape over time:
Hence a possible preference for a slightly thicker metal 7a wall.
As will also be seen in connection with
If the porous structure 5 is free of binder 9, the respective densities of porous material 3 in the first zones 10a1 and second zones 10b1 will each be uniform (equal) throughout the respective thicknesses e1, e2. These density variations between zones such as 10a1, 10b1 may be achieved by starting from different thicknesses of these zones from each other (respectively e1+X and e2+X). The globally uniform compression on the outer surface of the porous structure 5, created during the thermoforming of the barrier wall 7a, will allow the above-mentioned thicknesses, e1 and e2 respectively, to be achieved.
As a second hypothesis, it is therefore possible that a chemical binder is present in the porous structure 5. Once compressed/formed in 3D, the porous material 3 will then keep this state by itself. The manufacturing technique may be that of EP-A-2903800, a fibrous structure and a manufacturing process are known from the documents DE 103 24 735. Epoxy or phenolic resin may be used as binder 9.
In this case, it may be assumed that the formed unit 1 has a maximum thickness e,e2,e3 of more than 3 mm. Binder 9 is used both to shape the porous structure 5 (during thermoforming) and to maintain its shape integrity over time.
When using a heat-reactive binder 9, such as polypropylene or phenolic resin, the porous material should be heated so that the porous material melts and a rigid, non-deformable molded part is formed.
With or without binder 9, the forming of set 1 may be done in a forming mold 30a or 30b (
Although an all-metal 7a wall of a few tenths of a mm thickness may be suitable, it may be preferable, in step a), to choose a thermoformable wall and then, in step d), to heat this wall so that the two heated major surfaces S1,S2 soften. This ductility is then used to shape the wall 7a and the material of structure 5 under pressure by means of casting, after which it is allowed to cool.
If the polymer film option 7a is chosen, it may be a polyimide or PEEK film, or polyethylene, or polypropylene.
In step d), the molding may include a casting between a male element 340a and a female element 340b of a mold 30a, for bending and/or embossing, as shown in
However, to facilitate the making of the shapes, it may be proposed a deformation by pressure against a mold 30b including:
The deformable membrane 340c may be made of flexible plastic or rubber-based material that can withstand a temperature of 140 to 200° C.
To the above assembly 1, at least one thermal insulator 11 may be usefully added in the envelope 7, so that at ambient temperature and pressure, assembly 1 presents, through the film 7a, a coefficient of thermal conductivity (A) lower than 40 mW/m·K, and preferably lower than 20 mW/m·K; see
In addition, with the protective wall 7a, the thermal insulation 11 may then be usefully dispersed in structure 5.
With thermal insulation 11 in the form of particles, a variable concentration may be achieved at different locations.
This is also possible if at least one phase-change material (PCM) is also present in the envelope 7, which may be dispersed in structure 5 (
In the example in
In the example in
In the example shown in
In zone(s) 10d the structure 5 is (over)loaded with MCP 13, where part 1 has one or more heat exchange zone(s) with a refrigerant or heat transfer fluid 19. Thus, the areas of (over)densification or (over)concentration of particles and/or fibers may be precisely and appropriately located where required.
As already mentioned, a notable field of application of the invention is that of vehicles. The three-dimensional assembly formed 1 may in particular define there an internal lining element of a structural element, said structural element separating between them an outside environment and an internal volume to be insulated or thermally and/or acoustically protected from this outside environment, this with constraints of exiguous volume, particular shapes and/or weight to be limited as much as possible.
Thus one can see
The lining element 39 is thus interposed between volumes 35 and 37.
The structural element 33 may be a door panel, made of metal, of composite (i.e. composed of several materials; for example a mixture of synthetic resin and mineral, natural or synthetic fibers) or of plastic. It defines in the example the structural frame of a car door. At the exterior side, a door panel metal sheet 41 may be attached to it, for defining the exterior body of the door. At the interior side (passenger side), an interior trim panel 43 may be attached to it, so that assembly 1 is interposed between the metal sheet 41 and the interior trim 43.
The bending and/or reliefs 21 and/or recesses 23 of element 1 are engaged at least in part with the complementary curved shape and/or recesses 231 and/or reliefs 211 of the structural element 33, so that they respectively substantially conform to at least part of the contour thereof; see
In the totally closed envelope 7 of this element 1 may be found, as shown in
These attachments to structural element 33 may include screwing, riveting or other fasteners, for example, via rods 17.
And the envelope 7 will then also contain at least one of:
Rather than, as shown in
In
The environment is that of part of the body 44 of an all-electric or hybrid motor vehicle 45 or of a protective plate 33a fixed to the battery compartment 36 and/or the body 44 of the vehicle (body and chassis of the vehicle may be confused). An electric battery pack 47 for the electrical supply of the vehicle, contained in the closed compartment 36, is to be installed:
The above-mentioned structural element 33 may therefore be defined by a protective plate 33a. The metal plate 33a extends like a floor (or is a part of it) and provides protection against, for example, scratches. A part of it can be seen in
The above-mentioned inner lining element 39 is in the example defined by one or more trays 390 comprising one or more elements 1, with a 3D shape (here partly bent-shaped), interposed between the outside environment 35 and a cooling plate 41 of the battery pack 47.
The cooling plate 41 comprises channels 49 for the circulation of a cooling fluid arranged in heat exchange with the battery pack 47. In communication with a heat exchanger 51 located further in the vehicle, the coolant flows through channels 49 via an inlet 49a and outlet 49b that communicate with channels 49. The underside of the support plate 53, on which the electric battery pack 47 rests, forms a cover for the channels 49, which rest tightly against it by their edges. In addition or alternatively the support plate 53 may be part of the battery compartment in which the battery pack 47 is enclosed. To form a thermal barrier to the outside environment 35, especially for battery pack 47, the (each) thermally insulating element 1 is sandwiched between plate 33a and cooling plate 41.
With its lower side 41a and upper side 41b being the mirror image of each other, plate 41 has reliefs and depressions, at least some of which are defined by channels 49 on the upper side. The protective plate 33a also has reliefs 330 and depressions 331.
And element(s) 1 itself has, as already indicated, said reliefs 210 and depressions 230, here on the two major surfaces (lower and upper) of the thermoformed barrier wall; but these reliefs and depressions are different on the lower and upper faces, since, facing each other, the reliefs and depressions of plate 33a and plate 41 are different from each other, but complementary to those of element(s) 1.
Therefore, on the said major surfaces of the barrier wall (7a):
It must also be understood that the solutions that may be associated between the modes of realization, as well as between the figures, are transferable from one realization to another and may thus be associated between them.
Another efficient aspect has been schematized in
This solution proposes in fact to obtain a reinforced thermal insulation and a relevant acoustic insulation, by associating:
More precisely, it is first proposed to use the above-mentioned assembly, with the said at least one thermally insulating element 1 comprising its porous structure 5 in its envelope 7 formed by the barrier wall 7a, as for example in
However, in this solution it is furthermore provided :
The second density is lower than the first density, and the first porous structure 5 is superimposed with the second porous structure 50. Superimposed here means that we have a double thickness: the cumulative thickness of the porous structures 5.50 between zones 35 and 37. Together, superimposed, the two structures may be presented as in
The superposition of these structures is not necessarily in a horizontal plane; it may be for example in a vertical plane, as in the example of a car door in
This being said, one should also note:
It will have been understood that the two major surfaces S10,S20 are the image on envelope 70 and its wall 70a of the two major surfaces S1,S2 on envelope 7 and its wall 7a. The minor/marginal peripheral zone in terms of surface, here 70b image of 7b, remains.
The second envelope 70 is not necessarily under vacuum. The second porous structure 50 may be in a third vacuum envelope, itself then housed, together with the first envelope 70, in the second envelope 70.
Typically less compressed than the first porous structure 5, the second porous structure 50 will have a thickness e20 greater than the thickness e10 of the first porous structure 5, this being to be considered everywhere or on most of at least the larger of the surfaces of the two porous structures 5.50.
The thickness e20 may be from 3 to 15 mm. Thickness e10 may be from 0.5 to 2.5 mm. The first density may be from more than 100 to 800 kg/m3; the second density may be from 5 to less than 100 kg/m3.
The first porous structure 5 provides relevant thermal and acoustic insulation. The second porous structure 50 ensures a reinforced thermal insulation and a more limited acoustic insulation in low frequencies, but good in high frequencies. We thus obtain a hybrid solution with a heavy assembly (mass effect) which absorbs in low frequencies (20 to 200 Hz) through the first porous structure 5 and in high frequencies (above 200 Hz) through the second porous structure 50.
Several other applications are still presented below, with reference to
(a) Firstly, the applications relative:
The uprights or the body and their trim in the passenger compartment are therefore concerned.
The term passenger compartment is to be understood as “space receiving occupants to be transported” and an aircraft is a “vehicle”; therefore an aircraft fuselage is also concerned.
In the example in
The foam layer 69 and the liner 67 may be 2 to 5 mm thick, together, element 1 thermal insulation 3 to 6 mm, structural element 33 4 to 10 mm.
The structural element 33 (which may be composite) actually forms a second part of the so-called “structural element”, the first part being formed by the outer body 63.
An approximate top view of the roof part 60 of the vehicle, which is lined by the structure shown below, is shown in
Following the XVII-XVII cross section line, roof part 60 is rounded off laterally, in 60a (idem on the opposite side, in 60b), in particular. Thus, the porous structure 5, which is three-dimensional, is at least bent-shaped, as shown in
(b) Next (see
As shown in
Still in the direction of thickness, one may also prefer:
To further strengthen the insulation, a so-called second layer 85 of thermal and acoustic insulation may be interposed between sheets 77 and the air layer 79.
Typical thickness of the sheets 77 is 1.5 to 3 mm; the first and second layers 81,85 are 15 to 30 mm thick.
Apart from the plates 77, at least part of the above-mentioned elements (thus forming the set 75
As for the part of the roof 60, following a cutting line parallel to the thickness of the overall fuselage wall 75, this wall has a curved shape, as illustrated in
(c) Then again (see
In a conventional way, the most structuring structures are the spars 93 which, like the rails 91, extend parallel to the longitudinal axis (aircraft axis) X2. Frames 89 extend circumferentially, around the X2 axis.
In this case, the said “structural element” of the insulation assembly already presented is considered to be the assembly formed by the outer body (defined by sheet metal 77) and the frames, or rails or stringers, fixed with radially inward. As shown in the diagram, the proposed solution is to equip at least part of this assembly by insulating individually the frames in the example, each with an inner lining element comprising at least one said three-dimensional, vacuum thermal insulating element 1, the thermal insulating element 1 still comprising:
Thermal insulating element 1 may be covered with an aesthetic coating 99 (such as a liner) which may be found in 101 as an inner lining of the outer body/sheet 77.
In the example, the insulated parts (frames 89) protrude radially inward from the sheets 77. Each thermal insulating element 1 extends around the accessible part of the frame concerned. It may be conformed to the shape of the frame because the barrier wall 7a (and/or 7b; not shown) has been thermoformed and the porous structure 5 (idem) is three-dimensional and has been shaped by compression. The two elements 1 and 89 are then engaged one within the other.
The result is a solution that combines efficient insulation, light weight, small dimensions, ease of installation and maintenance.
Between the insulated part (frame 89) considered and the thermal insulation element 1 that extends around it, one may even interpose a layer of traditional insulation 97 (such as glass wool) whose maintenance in place is facilitated/assured by the fixed shape of the thermal insulation element 1, which may be fixed to the said insulated part (frame 89), by gluing or other means.
In terms of fixing or holding, the cohesion between the elements of the roof part 60 or the fuselage structure 75 may for example be ensured by gluing and/or screwing, with the presence of spacers if necessary.
The assembly is made up of two layered structures wrapped or not in a bag 70:
The combination of these materials allows a good compromise of thermo-acoustic insulation.
It should be noted that the solution described in connection with
In the application to the passenger compartment wall as shown in
Although not shown, element 1 for the thermal insulation of the solutions shown in connection with
Number | Date | Country | Kind |
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1857600 | Aug 2018 | FR | national |
Filing Document | Filing Date | Country | Kind |
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PCT/FR2019/051949 | 8/22/2019 | WO | 00 |