The present invention relates to an accumulator injection system for the intermittent injection of high-pressure fuel into combustion spaces of an internal combustion engine.
An accumulator injection system of this type is known from DE 102 10 282 A1. Conveying assemblies convey fuel out of a fuel reservoir in order to feed at least one high-pressure line to the cylinders of the combustion engine. A number of fuel injectors are fed via the at least one high-pressure line and in each case contain injector nozzles feeding fuel to a combustion space of the internal combustion engine. The at least one high-pressure line comprises line segments, by means of which the individual fuel injectors are connected to one another. The injector bodies of the fuel injectors comprise an integrated accumulator space. The accumulator spaces are used instead of a common-rail component, and each accumulator space has a volume which corresponds to 50 times to 80 times the maximum injection quantity of a fuel injector per injection operation. Each accumulator space is acted upon by means of an inflow throttle with fuel which is under high pressure. These inflow throttles are designed in such a way that multiple successive injection operations are possible, without pressure pulsations arising in the line segments. The influencing of other fuel injectors is avoided.
A fuel injection system disclosed in DE 32 27 742 employs injection valves which are equipped with an accumulator space. During the injection operation, the fuel which is under high pressure in the accumulator space is partially expanded, at the same time with a pressure drop, in the accumulator space. As a result, the law of injection, that is to say the time profile of the injection operation, has a characteristic falling from the start toward the end, this having an adverse effect on the combustion process of the internal combustion engine. Each accumulator space is connected to the high-pressure fuel conveying line via a narrowed orifice or a throttle passage. On account of the small flow cross-section area, the throttle passage prevents the occurrence of appreciable pressure waves in the fuel conveying lines during each injection operation. Such pressure waves would influence inadmissibly the uniform fuel distribution in a multi-cylinder engine and the stability of the injection operations of an individual injection valve from stroke to stroke.
EP 0 228 578 A proposes similar fuel injection valves to those in DE 32 27 742. In a design variant of these injection valves, a spring-loaded nonreturn valve is located between an annular bore around a guide element of the injection valve member and the accumulator space of the injection valve. The annular bore is connected to the fuel supply bore of the injection valve, and a bore connects the accumulator space to the rear side of the nonreturn valve, that is to say downstream of the nonreturn valve seat in the flow direction. The pressure in the accumulator space is therefore constantly lower than the pressure in the fuel supply bore, in particular at the commencement of each injection operation. As result, in the injection valve according to EP 0 228 578 A, the injection valve member can be closed reliably, even if the injection quantity is small.
The accumulator spaces of the injection valves known from DE 32 27 742 and from EP 0 228 578 A are located below a guide piston and a hydraulic control space of the injection valve member. A guide piston and control space belong to a hydraulic control device for controlling the movement of the injection valve member, and, in most operating states of the injection valve, it is necessary for the pressure below the guide piston to be lower than the pressure in the fuel supply bore during injection or even already at the commencement of injection, in order to ensure a sufficiently rapid closing of the injection valve member. The result of this, in many instances, is that the injection valve member becomes very long and is costly to produce. Moreover, this arrangement seriously restricts the freedom for accommodating the accumulator chamber in structural terms.
EP 0 264 640 A shows how, by shifting the volume of each individual injector accumulator into the line system, the overall system volume can be optimized and the disadvantages of the fuel injection systems known from DE 32 27 742 and EP 0 228 578 A can be overcome, while preserving the stability of the injection operations. In practice, according to EP 0 264 640 A, a line segment preceding all the injectors was designed with a larger internal cross section than the cross section of the remaining lines, so that this segment has a higher accumulator action than the remaining lines. This line segment was designated by the name of common rail, and the injection system was consequently called a “common-rail injection system”. Reference may be made for comparison, for example, to the specialist article “Das Common Rail-Einspritzsystem—ein neues Kapitel der Dieseleinspritztechnik” [“The common-rail injection system—a new chapter in diesel injection technology”] from the Motortechnische Zeitschrift MTZ No. 58, October 1997.
DE 31 19 050 shows an injection valve with an accumulator chamber likewise integrated in the housing. The accumulator chamber is connected, unthrottled, to a feed pressure line which is connected to a fuel pump. This system, in which in each case an injection valve with a pressure line and a pump is shown as a unit, is suitable for very large diesel engines.
The injection systems according to DE 102 10 282 A1 and DE 32 27 742 have the essential disadvantage of the falling injection characteristic. In order to mitigate this, a very large accumulator chamber could be integrated in the injection valve here, but this has the disadvantage that the injection valve becomes bulky.
Injection valves both according to DE 32 27 742 and according to EP 0 228 578 A have the essential disadvantages of a long injection valve member and of the great restriction in the spatial arrangement of the accumulator space.
The practical implementation of the system according to EP 0 264 640 A has the line segment with a larger cross section. For example, in engines of the performance class above about 350 kW and up to 20,000 kW and above, this line segment is likewise highly bulky and costly. Furthermore, in numerous applications, for safety reasons, the common rail and the pressure lines must have a double-walled design for the event where a crack occurs. This further increases the outlay and costs for the common rail. Moreover, if the latter is fastened to the engine block, the problem arises that the different thermal expansion between the engine and the common rail gives rise to undesirable mechanical stresses. Sometimes, therefore, the line segment is subdivided into a plurality of shorter segments which are designed with a short line in each case to an injection valve, even amounting to the configuration of an individual accumulator. These individual accumulators are not accommodated in the housing of the injection valve, since the conditions of space in the engine cylinder head usually make it possible only to accommodate an injector accumulator which is too small. The commercial implementation of such a system can be read about, for example, in the specialist article “Das Akkumulator-Common-Rail-Einspritzsystem für die MTU-Baureihe 8000 mit 1800 bar Systemdruck” [“The accumulator common-rail injection system for the MTU construction series 8000 with a system pressure of 1800 bar”], published in the Motortechnische Zeitschrift MTZ No. 61, October 2000.
The design according to DE 31 19 050 makes it possible to have only the unit of an injection valve with integrated accumulator chamber, together with a pump and with the associated connecting line, since, when a plurality of injection valves are connected to an underdimensioned accumulator chamber via a relatively thin pressure line to a multi-cylinder pump, excessive dynamic pressure fluctuations arise which cannot be brought into phase with the injection operations and which inadmissibly influence the accuracy of the injection operations.
The object of the present invention is to develop an accumulator injection system of the type initially mentioned, in such a way that an optimal injection operation becomes possible even with smaller accumulator chambers.
This object is achieved by means of an accumulator injection system for the intermittent injection of high-pressure fuel into combustion spaces of an internal combustion engine, with a high-pressure conveying device which feeds high-pressure fuel to a number of injection units having in each case an injection valve, a discrete accumulator chamber assigned to the each injection valve and a throttling device, the injection units being connected to one another and to the high-pressure conveying device by means of hydraulic line means, and each injection valve having an injection valve member actuated by means of an actuator arrangement and a hydraulic control device for controlling the operation of injecting high-pressure fuel through nozzle injection orifices of a nozzle of the injection valve. The hydraulic line means have too low an accumulator action to ensure the required, reproducibly identical injection operations of the injection valves, and the throttling device permits, at least approximately unimpeded, the flow of the high-pressure fuel in the direction of the injection valve and throttles the flow in the opposite direction in such a way that high-pressure fuel flows to each injection valve during its injection operation both from the assigned accumulator chamber as well as from the accumulator chamber of other injection units and from the high-pressure conveying device.
A line segment of larger cross section, known as a common rail, is absent. It becomes possible to employ discrete accumulator chambers of such small volume that they can be integrated, as required, into the construction space of the injection valve housing. Each injection valve of the accumulator injection system is assigned such a discrete accumulator chamber. The spatial arrangement of the discrete accumulator chambers can be selected optimally with great freedom of configuration, since the accumulator chambers do not have to be located below the guide piston of the injection valve, as disclosed in DE 32 27 742 and EP 0 228 578 A. Furthermore, these discrete accumulator chambers are connected solely by means of pressure lines of relatively small cross section to one another and to a high-pressure conveying device common to all the injection valves. The cross section of these lines is such that they form, overall, a volume having too low an accumulator action to be capable alone of generating the required reproducibly identical injection operations of the injection valves. These line cross sections may be equal or else even unequal.
By a throttling device which permits the flow of the high-pressure fuel in the direction of the injection valve and throttles the flow in the opposite direction being assigned to each injection unit, it is possible, on the one hand, despite the utmost small discrete accumulator chambers, to control the pressure profile during the injection operation for all the injection valves of an internal combustion engine exactly and without a disturbing pressure drop, for which purpose the action of dynamic pressure waves is utilized. On the other hand, it is also possible to damp the dynamic pressure waves from an injection operation of one injection valve to the injection operation of the next injection valve or to make the dynamic pressure waves equal for each injection valve, to an extent such that all the injection operations take place under virtually identical conditions. Consequently, even the exact arrangement of the hydraulic line means - pressure lines - in the injection system no longer plays a major role, and this arrangement can be configured with a high degree of freedom geometrically and optimally in terms of cost.
The accumulator injection system according to the invention is suitable particularly for diesel engines, preferably of medium to higher performance. It may, however, also be employed in smaller diesel engines, such as are used, for example, in automobile construction.
The present invention is explained in more detail by means of preferred exemplary embodiments which are illustrated in the drawing and are described below. In the drawing, purely diagrammatically,
In each injection valve 18, in each case a fuel line 16 issues, in the direction of the longitudinal axis 20 of the respective injection valve, into an accumulator chamber 22 assigned to the injection valve 18 (see also
The description of the embodiments shown in
In the longitudinal section of the injection valve 18 of
The functioning of the injection valve 18 is summarized as follows: current is applied to the actuator arrangement 42 and the hydraulic control device 40 responds. This causes a movement of the injection valve member 36 away from a nozzle seat 44 of the nozzle 34, with the result that fuel under high pressure flows from the accumulator chamber 22 via the bore 28 and the further bore 32 to the nozzle injection orifices 46 of the nozzle 34 and the injection operation commences. When the current is removed from the actuator arrangement 42, the injection valve member 36 moves in the direction of the nozzle seat 44 via the hydraulic control device 40, until the injection operation is interrupted. For the exact description of the set-up and of functioning, reference is made to the prior art, for example to CH patent application 00676/05 and the corresponding WO application PCT/CH2006/000191 which describe this part of the injection valve 18 exactly. The actuator arrangement 42, shown to be offset axially with respect to the longitudinal axis 20, could also be arranged on the longitudinal axis 20.
The underside 35a of the control piston 35 of the injection valve member 36, the guide sleeve 37 and the control space 39 are located below the accumulator chamber 22. The accumulator chamber 22 of the injection valve 18 is hydraulically connected, virtually without resistance, to the nozzle prespace 41 via the bore 28 and a further bore 32. The passages, not shown in detail (for details, reference is made once again to CH patent application 00676/05 and WO application PCT/CH2006/000191), for the flow of fuel from the nozzle prespace 41 to the region 43 directly upstream of the nozzle seat 44 are also dimensioned such that as low a pressure drop as possible occurs between the nozzle prespace 41 and the region 43 during the injection operation.
Reference is made purely illustratively to the volume capacity of the accumulator chamber 22 which, in the injection unit 27 according to
During each injection of an injection valve 18, the high-pressure fuel from the fuel line 16 flows through the accumulator chamber 22, in order to arrive via the bore 28 and the further bore 32 at the nozzle prespace 41 and consequently at the nozzle 34. The fuel stream flows through the accumulator chamber 22 which is therefore a throughflow accumulator chamber 22′. Purely illustratively, the diameters of the fuel lines 14 and 16 (
According to
It is known that the kinetic energy of the flow through a throttle is largely lost and converted into heat, as is the case with the bypass throttle 56. The bypass throttle 56 has an effective flow cross section which is preferably somewhat smaller than the overall effective flow cross section of the nozzle injection orifices 46 (the design range is between 0.3 and 3 times, depending on the specific version and on the number of injection valves 18 of the injection system 10). The nonreturn valve spring 54 is preferably not very strong and allows an opening of the nonreturn valve 24a, that is to say the movement of the ball 50 in the flow direction 48 away from the nonreturn valve seat 52, in the case of a pressure difference of, for example, 20 bar (the design range is between about 2 bar and somewhat above 50 bar, depending on the prestress of the spring 54).
In an alternative design variant of the accumulator injection system 10 of
The functioning of the fuel accumulator injection system 10 of
At the commencement of the injection operation, with the nonreturn valve 24a initially being closed, fuel flows out of the accumulator chamber 22 through the bore 28 and a further bore 32 and is injected through the nozzle injection orifices 46 into the combustion space of the internal combustion engine (the combustion space and internal combustion engine are not shown). As a result, the fuel expands, along with a slight pressure drop, in the accumulator chamber 22. The bypass throttle 56 cannot continue to convey sufficient fuel, thus causing the ball 50 to lift off from the nonreturn valve seat 52 in the direction of the flow 48, with the result that the follow-up of fuel from the fuel line 16 into the accumulator chamber 22 through which the fuel flows commences. This operation causes a dynamic lowering of pressure in the fuel line 16 which is propagated at sound velocity into the fuel line system. As the injection operation continues, the pressure in the accumulator chamber 22 falls further. On account of the reduced dimensions of the accumulator chamber 22, this lowering of pressure may amount, in the case of an initial pressure of, for example, 1600 bar, to up to a few hundred bar (for example, 100-400 bar), and, in turn, it is propagated dynamically into the fuel line 16 and into the fuel line system. Since the fuel line 16 communicates with the accumulator chamber 22 via the open nonreturn valve 24a, however, the lowering of pressure in the accumulator chamber 22 is smaller than if, with the same accumulator chamber volume, only the bypass throttle 56 were connected between, that is to say smaller than, for example, in an injection system according to DE 32 27 742. Furthermore, since the accumulator chamber 22 is advanced near to the nozzle seat 44, but, by means of the bore 28 and the further bore 32, above the control piston 35 of the injection valve member 36, the amplitude of the dynamic lowering of pressure in the fuel line 16 is smaller than in an injection system disclosed in EP 0 264 640 A, where there is no accumulator chamber 22 assigned to each injection valve 18.
During an injection operation which corresponds to a full-load injection of the associated internal combustion engine, the pressure lowering phase in the accumulator chamber 22 lasts for up to about half the overall injection duration. This value is purely indicative and may vary upward or downward, depending on the application. The dynamic lowering of pressure in the fuel line 16 then also covers the fuel feed line 14, the fuel lines 16 of the other, in particular adjacent fuel injection valves 18 and, via the bypass throttles 56, also the respective accumulator chambers 22. All these elements with high-pressure fuel have an accumulator action. However, the flow direction from the accumulator chambers 22 of the adjacent and, at most, further fuel injection valves 18 is opposite to the flow direction 48 of the injection valve 18 where injection takes place. Consequently, the nonreturn valves 52 of the adjacent and, at most, further injection valves 18 remain closed, and the follow-up of fuel from the assigned accumulator chambers 22 takes place solely through the bypass throttles 56, which, in the adjacent, and at most, further accumulator chambers 22, causes only a lower pressure drop than in the accumulator chamber 22 of the injection valve 18 which is just operating.
However, since there can be a high-pressure fuel follow-up from a plurality of accumulator chambers 22 via their bypass throttles 56, the overall fuel follow-up, taking place in the accumulator injection system 10, in the fuel line 16 and in the accumulator chamber 22 of the injecting injection valve 18 causes an advantageous recovery of the injection pressure in the second half of the injection operation, this recovery continuing up to the end of the full-load injection duration. The injection pressure in this phase rises at the nozzle injection orifices 46 and reaches a desirably high value toward the end of the injection operation; see, in this respect, also
If, then, the injection operation is ended rapidly, a dynamic pressure rise takes place in the bore 28 and the further bore 32 on account of the abrupt braking of the liquid column at the nozzle seat 44. This dynamic pressure rise is propagated as far as the assigned accumulator chamber 22 and is damped by the accumulator chamber volume. Furthermore, the remaining pressure rise can be propagated, likewise only damped, from the accumulator chamber 22 via the bypass throttle 56, and opposite to the flow direction 48, in the remaining part of the accumulator injection system 10, since the nonreturn valve 52 does not allow a throughflow opposite the flow direction 48. The bypass throttle 56 nullifies a substantial part of the energy carried along by the flow through the bypass throttle 56 and does not allow the occurrence in the accumulator injection system 10 of any pressure amplitudes which are difficult to control.
The arrangement of the nonreturn valve with bypass throttle 24 of the accumulator injection system 10 of
it damps the pressure fluctuation in the accumulator chambers 22 of noninjecting fuel injection valves 18 during the injection of any desired injection valve 18,
it damps the pressure fluctuation between the injecting injection valve 18 and the rest of the accumulator injection system 10 at the end of injection, and
it brings about an advantageously rising characteristic of the injection pressure in the second half of a full-load injection operation of any desired injection valve 18.
After the end of any injection operation, in the accumulator injection system 10 pressure differences remain in the accumulator chambers 22 and residual oscillations remain in the fuel feedline 14 and fuel lines 16. By virtue of a suitable design of the volume of the accumulator chambers 22, the properties of the nonreturn valves with the bypass throttles 24 (as mentioned above) and of the fuel feed line 14 and fuel lines 16 of a specific injection system 10, a virtually identical wave pattern ever-recurring for all the injection valves 18 is generated in it, so that all the injection valves 18 of the injection system 10 acquire virtually identical conditions for injection in terms of the pressure profile (see, in this respect,
In
This arrangement leads to a different behavior of the injection valve 78 in the overall accumulator injection system 10, as compared with the injection unit 27 according to
At the commencement of the injection operation, the fuel will flow for the most part out of the fuel line 16 through the bores 70, 28 and 32 to the nozzle injection orifices 46. It can be determined from the design of the cross section of the bypass throttle 56 and the force of the spring 54 (see
If, then, the dynamic lowering of pressure in an injection valve 78 arrives via the fuel feedline 14 and fuel line 16 at the nonreturn valve with bypass throttle 24 of an adjacent injection valve 78, the nonreturn valve 24a of the latter may also open and, in addition to the assigned bypass throttle 56, follow up with fuel from the accumulator chamber 22 dynamically to the injecting injection unit 27. If the dynamic pressure recovery wave arrives at the injecting injection valve 78, the nonreturn valve 24a of this injecting injection valve 78 will then, when the pressure recovery wave reaches the closing side of the nonreturn valve 24a, shut off the passage of the pressure recovery wave to the accumulator chamber 22 of this injecting injection valve 78, and therefore almost the entire pressure wave amplitude arrives, virtually undamped, as a pressure rise at the nozzle injection orifices 46 (reduced by the amount of that fraction which can pass via the bypass throttle 24b into the accumulator chamber 22 of this injecting injection valve 78).
The different switching behavior of the nonreturn valves 24a in the second half of the injection operation, as compared with the arrangement of
This arrangement is highly effective even with only two injection valves 78 having two assigned accumulator chambers 22, two assigned nonreturn valves with bypass throttles 24 and the associated fuel feed and fuel lines 14, 16. In fuel injection systems 10 with more than two injection valves 78, an additional reduction in the overall volume of accumulated high-pressure fuel can be achieved, as compared with the arrangement of
The second essential difference from the arrangement of
In a design variant, not shown, of an injection valve according to the present invention, the injection valve has a cul-de-sac accumulator chamber 22″, and the nonreturn valve with bypass throttle 24 is located at the inlet of the lateral high-pressure inflow 70 of the injection valve. This version has virtually the same behavior as the injection valve 18 of
A first separating line 74, shown by a line of dashes in
In a further alternative embodiment, not shown, of the injection valves 18, 78, 88, the accumulator chamber 22 is arranged laterally, either offset axially parallel to the longitudinal axis 20 or at an angle (of, for example, 90°) to the longitudinal axis 20. Here, too, the housing of the accumulator chamber 22 may be formed in one piece with the injection valve housing 30 (for example, this structural unit is produced as a forging) or as two components screwed to one another.
In
However, in an accumulator injection system 10 with the design of the injection units 27 according to
In the embodiment, shown in
For the sake of completeness, it may be mentioned that even injection units, such as those shown in
In a design variant, the distributor block 96 is assigned an accumulator chamber 97, as indicated in
The high-pressure fuel passes via the fuel feedline 100 into a distributor block 99 symmetrical to an axis 101 and, via fuel lines 102a, 102b, 102c and 102d, to four injection units 27. Further possible fuel lines in the case of an extension, shown by dashes at 116, of the distributor block 99 are indicated by dashes at 102′. The valve body 106 of each throughflow limiting valve 104 is of double-acting design. During each injection operation, the valve body 106 moves in the direction of the fuel line 102 which leads to the injection unit 27 having the injecting injection valve. When the accumulator injection system 90 is functioning normally, the valve body 106 does not move so far that the conical end 110 reaches as far as the shut-off seat 112. In the intermissions between injection operations, the valve body 106 is brought into its central position of rest by the force of a spring 108. By contrast, if too much fuel is unintentionally demanded if an injection operation lasts for too long a time, the conical end 110 reaches the shut-off seat 112 and closes off the further flow of fuel. Slightly throttling annular passage surfaces between the valve body 106 and the body of the distributor block 99 are designated by 114. They lie between the fuel inlet through the fuel feedline 100 and a prespace 116 to a fuel line 102. Furthermore, the valve bodies 106 have in the middle a narrowed region 118, in order to ensure the unimpeded throughflow of fuel from the fuel line 100 and through a bore 120 to all the throughflow limiting valves 104.
The advantage of this solution is that a double-acting throughflow limiting valve 104 serves at least two injection valves 18 and therefore the number of throughflow limiting valves 104 for a specific engine is at least halved, as compared with the prior art.
In design variants, a throttle 121a is arranged in the fuel inflow to the distributor block 99, as depicted by dashes. Instead of this throttle 121a, a throttle 121b may be present in the fuel inflow segment in each case between two chambers 124 receiving a double-acting throughflow limiting valve 104. It is also conceivable, however, to install both throttles 121a and 121b. Furthermore, the distributor block 99 may be assigned an accumulator chamber 97 in a similar way to the distributor block 96. The purpose of these elements is the same as was described in connection with the design variant of the distributor block 96. In this case, too, the outlay in structural terms increases.
In the embodiment shown in
An accumulator injection system of this type is suitable particularly for a retrofit on an existing internal combustion engine, in which case the high-pressure pumps 12′ of the original conventional injection system can be preserved and therefore only new injection units 27 and new hydraulic line means 13 have to be retrofitted.
In all the exemplary embodiments shown, the accumulator chambers 22 and the nonreturn valve with bypass throttle 24—the throttling device 25—and also the issue of the bore 32 are mounted above the underside 35a of the control piston 35 of the injection valve member 36, thus allowing a particularly compact configuration of the operating elements in the nozzle 34. The accumulator chamber 22 and/or the nonreturn valve with bypass throttle 24 may also be installed such that they are accommodated below the underside 35a of the control piston 35, in a similar way to known injection valve versions, and, if appropriate, allowing for a long injection valve member. The design could also be such that only the bore 32 issues below the underside 35a of the control piston 35 of the injection valve member 36.
In all the exemplary embodiments, the accumulator injection system has no accumulator space common to all the injection valves, in the manner of a common rail. This is reflected in that the hydraulic connection means of an accumulator injection system according to the invention have too a low an accumulator action to generate alone the required, reproducibly identical injection operations of the injection valves. The connection means may preferably all have at least approximately the same cross section. Any small chambers or spaces, such as are necessary, for example, for throughflow limiting valves, or any throttles are also to be included. It is important, however, that, during each full-load injection operation, fuel is also supplied from accumulator chambers other than the accumulator chamber assigned to the injection valve just injecting and from the high-pressure conveying device.
The throttling device 25 may also be designed, for example, in the form of a “hydraulic circular diode”.
An accumulator injection system according to the invention preferably has at least three injection units 27.
For diesel engines with a performance of the order of 250 KW per cylinder, flow cross sections in the fuel line system corresponding to a diameter of about 6 mm are recommended. Diameters of 2-4 mm are recommended for performances of about 50-100 KW.
An accumulator injection system 10 according to the invention, as shown in
For comparison, an accumulator injection system with a common rail was also simulated. In this case, the exactly identical stipulations were taken into account. The only difference was that the fuel was supplied directly to the injection valves 18 by means of the fuel lines 16, and that a volume of 800 cm3, corresponding to the eight accumulator chambers 22, was shifted into the line pieces 14′ in the manner of a common rail, with their cross section being assumed to be enlarged correspondingly. The injection valves 18 were therefore not assigned any individual accumulator chamber 22 or any throttling device 25. Results of this simulation are shown in the graphs of
In all the graphs, the abscissa is the time axis, the time being given in seconds. In
It may be gathered from
In comparison with this, as shown in
Number | Date | Country | Kind |
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1195/05 | Jul 2005 | CH | national |
1365/05 | Aug 2005 | CH | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/CH2006/000364 | 7/10/2006 | WO | 00 | 1/9/2008 |
Publishing Document | Publishing Date | Country | Kind |
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WO2007/009279 | 1/25/2007 | WO | A |
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31 19 050 | Nov 1982 | DE |
32 27 742 | May 1983 | DE |
197 06 694 | Sep 1998 | DE |
198 42 067 | Mar 2000 | DE |
101 12 154 | Sep 2002 | DE |
102 10 282 | Sep 2003 | DE |
102 38 951 | Mar 2004 | DE |
103 07 871 | Sep 2004 | DE |
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0 264 640 | Apr 1988 | EP |
0 657 642 | Jun 1995 | EP |
0 921 302 | Jun 1999 | EP |
1 002 948 | May 2000 | EP |
WO2006108309 | Oct 2006 | WO |
Number | Date | Country | |
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20080296413 A1 | Dec 2008 | US |