Information
-
Patent Grant
-
6437422
-
Patent Number
6,437,422
-
Date Filed
Wednesday, May 9, 200124 years ago
-
Date Issued
Tuesday, August 20, 200223 years ago
-
Inventors
-
Original Assignees
-
Examiners
Agents
- Ohlandt, Greeley, Ruggiero & Perle, L.L.P.
- Underweiser; Marian
-
CPC
-
US Classifications
Field of Search
US
- 257 618
- 257 40
- 428 383
- 357 25
-
International Classifications
-
Abstract
Active devices that have either a thread or a ribbon geometry. The thread geometry includes single thread active devices and multiple thread devices. Single thread devices have a central core that may contain different materials depending upon whether the active device is responsive to electrical, light, mechanical, heat, or chemical energy. Single thread active devices include FETs, electro-optical devices, stress transducers, and the like. The active devices include a semiconductor body that for the single thread devices is a layer about the core of the thread. For the multiple thread devices, the semiconductor body is either a layer on one or more of the threads or an elongated body disposed between two of the threads. For example, a FET is formed of three threads, one of which carries a gate insulator layer and a semiconductor layer and the other two of which are electrically conductive and serve as the source and drain. The substrates or threads are preferably flexible and can be formed in a fabric.
Description
FIELD OF THE INVENTION
This invention relates to active devices and, more particularly to active devices formed with threads.
BACKGROUND OF THE INVENTION
Active devices generally have electrical impedance between two electrodes that varies as a function of a change of energy. For example, active devices include transistors, diodes, strain gauges, electrical optical devices and the like. One form of transistor is the well-known field effect transistor (FET). One known FET is a metal oxide semiconductor FET(MOSFET), which has been widely used as a switching element for high-speed electronic applications. The MOSFET specifically refers to SiO
2
/bulk silicon transistors. A more general FET is a metal insulator semiconductor FET (MISFET). A thin film transistor (TFT) is a MISFET in which the active semiconductor material is deposited as a thin film.
It is known to fabricate active devices with either crystalline silicon or amorphous silicon. Amorphous silicon is a cheaper alternative to crystalline silicon, but its applications are limited to slower speed devices as its mobility is about 10
−1
cm
2
/N*sec, which is about 15,000 times smaller than that of crystalline silicon.
Currently, there is much work directed to developing alternative materials, such as organic and organic-inorganic semiconductor materials that may be deposited by low cost and low temperature processes. Lower processing costs may lead to low cost logic and display devices. Lower temperature processing opens up the possibility of depositing these materials on a wider range of substrates, including plastic, paper and fabrics for flexible electronic devices.
An example of a FET made with organic materials is disclosed in U.S. Pat. No. 5,347,144 to Garnier et al., entitled “Thin-Layer Field Effect Transistors With MIS Structure Whose Insulator and Semiconductor Are Made of Organic Materials.” Organic materials may provide a less expensive alternative to inorganic materials for TFT structures, as they are cheaper to manufacture by methods, such as spin coating or dip coating from solution, thermal evaporation, or screen printing. Such organic materials include small molecules (e.g., pentacene, metal-phthalocyanines and the like), short-chain oligomers (e.g., n-thiophenes, where n=3-8 thiophene units) and polymers (e.g., polyalkylthiophenes, poly-phenylenevinylenes and the like).
An example of a FET made with organic-inorganic materials is described in U.S. Pat. No. 6,180,956 to Chondroudis et al., entitled “Thin Film Transistors With Organic-Inorganic Hybrid Materials as Semiconducting Channels.” Again, TFTs made with organic-inorganic materials can use the cheaper manufacturing processes, such as spin coating or dip coating from solution, thermal evaporation, or screen printing.
Conventional active devices are generally formed on planar substrates. Thus, current efforts to make flexible devices are focussed on deposition of the semiconductor devices on large area flexible substrates. These efforts have not yet provided a commercial flexible electronic device.
Accordingly, there is a need for an active device that can be fabricated with low cost and low temperature processing.
There is also a need for an assembly of and a method for forming a plurality of active devices on a flexible substrate.
There is also a need for a method of forming a large area assembly of such active devices.
SUMMARY OF THE INVENTION
An active device of the present invention is formed of a thread with a semiconductor body extending axially along the thread. First and second electrical conductors extend axially along the thread and are disposed in electrical contact at spaced apart locations with the semiconductor body. The carrier concentration in the semiconductor body varies with energy that affects the thread, thereby also varying the impedance between the first and second electrical conductors.
According to an aspect of the invention, the thread has an optical fiber core upon which the semiconductor body is disposed and the energy is light energy. According to another aspect of the invention, the thread has a piezo-electric core upon which the semiconductor body is disposed and the energy is mechanical. According to another aspect of the invention, the thread has an electrically conductive core with a layer of electrical insulation upon which the semiconductor body is disposed and the energy is electrical. According to further aspects of the present invention, the energy can be heat or chemical with a suitable core.
According to other aspects of the invention, the active device is formed of a plurality of threads and the semiconductor body that extends axially of one of the threads. Two of the threads are electrically conductive and a third thread is responsive to applied energy to modulate the carrier concentration of the semiconductor body. The third thread can have either an optical fiber core or an electrically conductive core. The semiconductor body can be either a layer that is disposed on the third thread or an elongated body that is disposed in a region between the three threads. When the third thread has an electrically conductive core with a layer of electrical insulation, the active device is a field effect transistor. In these devices current flow is in a path that includes the first and third threads and the semiconductor body. That is, current flow is perpendicular or radial with respect to the axes of the first and second threads.
The threads used to form the various active devices of the present invention are formed of one or more filaments that are flexible or bendable. Thus, the need for a flexible substrate and flexible active device is met by the present invention.
The semiconductor body includes a semiconductor that can be disposed on a thread core that has a layer of electrical insulation disposed thereon, or that is an optical fiber or a piezo-electric material. Preferably, the semiconductor body includes an organic semiconductor or a hybrid organic/inorganic semiconductor or other semiconductor types that can be formed on the thread cores with low cost and low temperature processes, such as spin coating or dip coating from solution, thermal evaporation, or screen printing. Thus, the active devices of the present invention can be made with low cost and low temperature processes, thereby satisfying the aforementioned needs.
According to still another aspect of the present invention, an electrical circuit includes a plurality of threads and at least one semiconductor body with the threads forming two or more active devices. In some of these embodiments, each thread is an active device. In other embodiments, two or more active devices can share an electrically conductive thread.
According to still further aspects of the present invention, a fabric includes a plurality of threads in which at least one of the threads forms an active device.
BRIEF DESCRIPTION OF THE DRAWINGS
Other and further objects, advantages and features of the present invention will be understood by reference to the following specification in conjunction with the accompanying drawings, in which like reference characters denote like elements of structure and:
FIG. 1
is a perspective view of a segment of an active field effect transistor of the present invention;
FIG. 2
is a blown up cross-sectional view of
FIG. 1
;
FIGS. 3-7
are cross-sectional views of alternative field effect transistors of the present invention;
FIG. 8
is a cross-sectional view of an active device of the present invention;
FIG. 9
is a cross-sectional view of an alternative active device of the present invention;
FIG. 10
is a diagram of a prior art circuit;
FIG. 11
is an assembly of the present invention for the FETs of
FIG. 10
;
FIG. 12
is a diagram of a prior art circuit;
FIG. 13
is an assembly of the present invention for the FETs of
FIG. 12
;
FIG. 14
depicts a fabric that contains active device threads of the present invention;
FIG. 15
is a sampling circuit for the active device threads of
FIG. 14
; and
FIG. 16
is a perspective view of an alternate active device of the present invention.
DESCRIPTION OF THE PREFERRED EMBODIMENT
Referring to
FIGS. 1 and 2
, a FET
50
includes a sheath
53
, a bundle
52
of threads
54
,
56
,
58
and
60
. Threads
54
and
56
form a pair of gates of FET
50
and threads
58
and
60
form the source and drain, respectively, of FET
50
. Gate thread
54
has a core
62
and gate thread
56
has a core
64
. Source thread
58
has a core
66
and drain thread
60
has a core
68
. Sheath
53
may be any suitable electrically insulative material, known currently or in the future. Sheath
53
is omitted from FIG.
2
. Cores
62
,
64
,
66
and
68
comprise one or more filaments of an electrically conductive and flexible material, such as a metal or a conductive polymer. Alternatively, the filaments may be a non-conductive plastic with a coating of electrically conductive material, such as metal or conductive plastic. The filaments may be solid or hollow and may have any suitable cross-section, symmetrical, asymmetrical, curved or uncurved or any combination thereof.
Gate thread
54
includes a layer
70
of insulator material disposed adjacent to core
62
and a layer
72
of semiconductor material disposed adjacent to insulator layer
70
. Gate thread
56
includes a layer
74
of insulator material disposed adjacent to core
64
and a layer
76
of semiconductor material disposed adjacent to insulator layer
74
. Source thread
58
includes a contact layer
78
disposed adjacent to core
66
and drain thread
60
includes a contact layer
80
disposed adjacent to core
68
. Contact layers
76
and
78
are disposed in electrical contact with semiconductor layers
70
and
72
and function to enhance carrier mobility at the interfaces of electrical contact with semiconductor layers
72
and
76
.
Semiconductor layers
72
and
76
and contact layers
78
and
80
may be any suitable organic, inorganic, or hybrid semiconductor material that can be disposed on the core material, known presently or in the future. Organic semiconductors include, for example, semiconducting small molecules, oligomers and polymers. For, example, semiconductor layers
72
and
76
may be formed with organic semiconductors, such as polythiophene derivatives, oligothiophene derivatives and pentacene. A hybrid semiconductor, for example, may be phenethyl ammonium tin iodide. Contact layers
78
and
80
may be formed of highly conductive materials, such as doped semiconductors, metallic hybrids, or metals, such as Au, Cu, Mg, Ca, and the like. The doped semiconductors include, for example, polythiophene with iodine, polyaniline with camphor sulfonic acid, polyacetylene, polypyrrole, and the like. These materials may be applied by any suitable process, such as electrodeposition, electroless plating, extrusion, spraying, stamping, molding, powder coating, melting, spin coating, and the like.
Gate insulation layers
70
and
74
may be any suitable electrical insulation material that can be used for FETs, known presently or in the future. For example, the insulation material may be organic insulators, such as polymethylmethacrylate (PMMA), polyimide, epoxies, and the like; inorganic insulators, such as silicon dioxide, silicon nitride, barium strontium titanates, and the like; or organic/inorganic hybrids, such as sol gel and silicates. Gate insulation layers
70
and
74
may be applied to cores
62
and
64
by any suitable process, such as electrodeposition, electroless plating, extrusion, spraying, stamping, molding, powder coating, melting, spin coating, and the like.
Current flow in FET
50
is from thread to thread. For example, current flow is in a path that includes source thread
58
, semiconductor layers
72
and
76
of threads
54
and
56
and drain thread
60
. That is, current flow is perpendicular or radial with respect to the axes of the source and drain threads
58
and
60
.
FET
50
has a width that is in the length direction of bundle
52
. The width depends on the application. For example, if FET
50
were embedded in a five inch shirt pocket of a garment, the width would be about five inches. If the power rating is about 10mW, (suitable for activating a light emitting diode) and the current rating is about 1mA, FET
50
would have a width of about 12 cm (the length of the pocket) and a thread diameter in the range of about 10 microns to about 100 microns.
Gate threads
54
and
56
, source thread
58
and drain thread
60
are twisted together in bundle
52
so as to impart a mechanical force to hold them together in a manner that assures good electrical contact at the interfaces of source thread
58
and drain thread
60
with semiconductor layers
72
and
76
. Other techniques may be used to impart the necessary mechanical force, such as ties, a sleeve, a sheath and the like. The sheath
53
also prevents shorting between threads.
Because of its flexibility and thread geometry, FET
50
has the significant capability of integration into a woven fabric. Due to the large width of FET
50
, its current rating can be high enough to drive substantial loads, even with low mobility organic semiconductor layers
72
and
76
.
In a specific example of FET
50
, gate cores
62
and
64
are each copper wires with a diameter of about 25 microns. Gate insulator layers
72
and
74
are enamel coatings of about 0.5 micron thickness. Semiconductor layers
72
and
76
are formed by dipping the enamel coated wires in a solution of an organic semiconductor dissolved in chloroform and then removing and drying. The organic semiconductor is regioregular poly-3-hexyl-thiophene (P3HT).
The source and drain cores
58
and
60
are also copper wires with a diameter of about 25 microns that are coated with chromium to prevent corrosion. Contact layers
78
and
80
are formed by dipping the wires in P3HT solution that has been doped with Ferric Chloride. The contact layer thickness is about 0.2 microns.
Gate threads
54
and
56
, source thread
58
and drain thread
60
are each wound on spools. Gate threads
54
and
56
, source thread
58
and drain thread
60
are then unspooled and wound together to form the twisted thread structure of FIG.
1
. Sheath
53
is then formed by dipping the twisted threads in a solution of PMMA dissolved in acetone, which does not affect semiconductor layers
72
,
76
,
78
and
80
.
Referring to
FIG. 3
, a FET
90
is substantially the same as FET
50
, except that gate thread
56
is replaced with a spacer thread
92
. Spacer thread
92
may comprise a single filament or multiple filaments of an electrical insulation material, such as nylon, PMMA, polyvinylchloride (PVC), polyesters, and the like. The filaments may be solid or hollow and may have any suitable cross-section. Insulation thread
92
keeps source thread
58
and drain thread
60
separated so that they do not contact one another. Like FET
50
, FET
90
has a mechanical force imparted to gate thread
54
, source thread
58
, drain thread
60
and insulation thread
92
to hold them together as a bundle in a manner that keeps source thread
58
and drain thread
60
separated.
Referring to
FIG. 4
, a FET
100
has a gate thread
102
, a gate thread
104
, a source thread
106
, a drain thread
108
and a semiconductor body
110
. Source thread
106
and drain thread
108
are substantially identical to source thread
58
and drain thread
60
of FET
50
of
FIGS. 1 and 2
. Gate thread
102
has a core
112
upon which is disposed an insulator layer
114
. Gate thread
104
has a core
116
upon which is disposed an insulator layer
118
. Cores
1
112
and
116
are substantially identical to cores
62
and
64
of FET
50
of
FIGS. 1 and 2
. Insulation layers
114
and
118
are substantially identical to insulation layers
70
and
74
of FET
50
of
FIGS. 1 and 2
. Semiconductor body
110
has an elongated shape and is disposed in the space or void between threads
102
,
104
,
106
and
108
. Like FET
50
, FET
100
has a mechanical force imparted to gate threads
102
and
104
, source thread
106
, drain thread
108
and semiconductor thread
110
to hold them together as a bundle in a manner that keeps source thread
58
and drain thread
60
separated.
Semiconductor body
110
may be fabricated of any suitable semiconductor material that is formable in an elongated threadlike shape and that has a pliability that adjusts to the surfaces of gate threads
102
and
104
, source thread
106
and drain thread
108
when a mechanical force is applied. For example, semiconductor body
110
may be formed of a permeable thread that is saturated with an organic semiconductor, such as P3HT or of a hybrid organic/inorganic semiconductor, such as phenephyl ammonium tin iodide.
Alternatively, semiconductor body
110
may be formed of a semiconductor paste or gel that is applied to the surface of one or more of the threads
102
,
104
,
106
and
108
in an amount sufficient to provide a continuous body therebetween. For example, the semiconductor paste may be formed of an organic semiconductor combined with a binder chosen for its mechanical properties, such as toughness, strength, pliability, adhesive and thermal properties. The binder, for example, may be polystyrene.
Referring to
FIG. 5
, a FET
120
includes a gate thread
122
, a source thread
124
, a drain thread
126
, a spacer thread
128
, a semiconductor body
130
and a pair of contact threads
132
and
134
. Gate thread
122
is substantially identical to gate thread
102
of FET of FET
100
in FIG.
4
. Spacer thread
128
is substantially identical to spacer thread
92
of FIG.
3
. Semiconductor body
130
is substantially identical to semiconductor body
110
of FET
100
of FIG.
4
. Source thread
124
and drain thread
126
are each formed of one or more filaments of an electrically conductive and flexible material, such as a metal or a conductive polymer. Alternatively, the filaments may be a non-conductive plastic with a coating of electrically conductive material, such as metal or conductive plastic. The filaments may be solid or hollow and may have any suitable cross-section.
Contact thread
132
is disposed in electrical contact with semiconductor thread
110
and in electrical contact with source thread
124
. Contact thread
134
is disposed in electrical contact with semiconductor thread
130
and drain thread
126
. Contact threads
132
and
134
are formed with any suitable semiconductor material that enhances carrier mobility at the interfaces to semiconductor thread
130
. For example, contact threads
132
and
134
may be formed of a doped semiconductor through controlled diffusion of a dopant from the source and drain.
It will be appreciated by those skilled in the art that the contact thread arrangement of FET
120
can be used in place of the contact layer arrangement of FETs
50
,
90
and
100
. For example, contact layers
78
and
80
of source and drain threads
58
and
60
of FET
50
(
FIGS. 1 and 2
) can be replaced by a pair of spaced apart contact threads that are in electrical contact with semiconductor layers
72
and
76
and with source and drain cores
66
and
68
.
In a specific example of FET
120
, semiconductor body
130
is formed by soaking a permeable thread, which may be formed of multiple filaments, in P3HT dissolved in chloroform solution, withdrawing and drying. Contact threads
132
and
134
may be a high function Pd coated copper. Contact threads
132
and
134
with semiconductor body therebetween are fused to form a three thread assembly and spooled. The three thread assembly is then dipped in a solution of P3HT dissolved in chloroform, and, while still wet, wound with spacer thread
128
, source thread
124
and drain thread
126
to harden in position and form FET
120
.
Referring to
FIG. 6
, a FET
140
is substantially identical to FET
100
of
FIG. 4
, except that an optical thread
142
replaces gate thread
104
. Alternatively, optical thread
142
may replace both gate threads
102
and
104
. Optical thread
142
is an optical fiber that is disposed adjacent to semiconductor body
110
and between source thread
106
and drain thread
108
. Optical energy applied to optical thread
142
is coupled into semiconductor body
110
and modulates the carrier concentration therein so as to cause a change in the impedance thereof between the source thread
106
and the drain thread
108
.
Referring to
FIG. 7
, a FET
150
has a single thread
152
. Thread
152
has a core
154
, an insulating layer
156
, a semiconductor layer
158
, a source layer
160
and a drain layer
162
. Core
154
comprises one or more filaments of an electrically conductive and flexible material, such as a metal or a conductive polymer. Alternatively, the filaments may be a non-conductive plastic with a coating of an electrically conductive material, such as metal or conductive plastic. The filaments may be solid or hollow and may have any suitable cross-section. Insulating layer
156
is disposed on the surface of core
154
and semiconductor layer
158
is disposed on the surface of insulating layer
156
. Source layer
160
and drain layer
162
are disposed on the surface of semiconductor layer
158
as stripes along the length or axial direction of thread
152
.
Referring to
FIG. 8
, an active device
170
has a single thread
172
. Thread
172
has a core
174
, a semiconductor layer
176
, and a pair of electrodes
178
and
180
. Core
174
is comprised of an optical fiber. Semiconductor layer
176
is disposed on the surface of optical fiber core
174
. Electrodes
178
and
180
are disposed on the surface of semiconductor layer
176
as stripes along the length or axial direction of thread
172
. Optical energy applied to optical fiber core
174
modulates the carrier concentration in semiconductor layer
176
and, hence, varies the impedance between electrodes
178
and
180
. An important application of active device
170
is to convert light energy to electrical energy.
Referring to
FIG. 9
, an active device
190
has a single thread
192
. Thread
192
has a core
194
, a semiconductor layer
196
, and three electrodes
198
,
200
and
202
. Core
194
is comprised of a piezo-electric material. Semiconductor layer
196
is disposed on the surface of piezo-electric core
194
. Electrodes
198
,
200
and
202
are disposed on the surface of semiconductor layer
196
as stripes along the length or axial direction of thread
192
. Mechanical stress applied to piezo-electric core
194
modulates the carrier concentration in semiconductor layer
196
and, hence, varies the impedance between electrode
198
and electrodes
200
and
202
and between electrodes
200
and
202
. An important application of active device
190
is to convert mechanical energy to electrical energy.
The optical fiber
174
of active device
170
or the piezo-electric core
194
of active device
190
can be replaced by with other suitable materials for the conversion of heat energy or chemical energy to electrical energy. It is also possible to use light, mechanical stress, heat or chemical energy to generate electrical power that could replace batteries in low power applications.
Referring to
FIG. 10
, a prior art FET circuit
210
includes a pair of FETs
212
and
214
. FET
212
has a gate G
1
, a source
216
and a drain
218
. FET
214
has a gate G
2
, a source
220
and a drain
222
. FETs
212
and
214
have their source/drain channels connected in series, i.e., source
218
is connected to drain
220
.
Referring to
FIG. 11
, circuit
210
is shown in a thread assembly
224
. FET
212
is formed with a source thread
225
., a gate thread
227
and a common thread
226
. FET
214
is formed with a gate thread
228
, a drain thread
229
and common thread
226
. Thus, gates G
1
and G
2
are implemented with gate threads
227
and
229
; source
216
, with source thread
225
; drain
222
, with drain thread
229
; and drain
218
and source
220
, with common thread
226
.
Referring to
FIG. 12
, a prior art circuit
230
includes two FETs
232
and
234
. FET
232
has a gate G
1
, a source
236
and a drain
238
. FET
234
has a gate G
2
, a source
240
and a drain
242
. FETs
232
and
234
have their source/drain channels connected in parallel, i.e., source
236
is connected to source
240
and drain
238
is connected to drain
242
.
Referring to
FIG. 13
, circuit
230
is shown in a thread assembly
224
. FETs
232
and
234
are formed with a common source thread
246
and a common drain thread
248
and with separate gate threads
245
and
247
. Thus sources
236
and
240
(
FIG. 12
) are implemented with common source thread
246
; drains
238
and
242
(FIG.
12
), with common drain thread
248
; and gates G
1
and G
2
, with gate threads
245
and
247
.
Referring to
FIG. 14
, a fabric
300
has a plurality of threads
302
A and
302
B that are woven together. Threads
302
A are cloth threads and threads
302
B are active device threads, such as FETs
50
,
90
,
100
,
120
or
140
or active devices
150
,
170
or
190
. Applications for fabric
300
include any application in which an electrical, optical, mechanical stress, heat, or chemical activity is needed.
Referring to
FIG. 15
, by way of example, threads
302
B may each be a piezo-electric thread of the type shown in FIG.
9
. The electrodes
198
,
200
and
202
are connected to a sampling device
304
. During a sampling period, sampling device
304
connects voltages between across electrodes
198
and
200
,
198
and
202
, and
200
and
202
and measures the currents therethrough for comparison with reference values. Dashed lines
306
are for connections to others of the active device lines
302
B. For example, all of the active device threads
302
B could be sampled together or at separate sampling periods.
Referring to
FIG. 16
, an active device
320
has a flexible ribbon substrate
322
, a layer
324
, a layer
326
, a pair of electrical conductors
328
and
330
and a semiconductor body
332
. Flexible substrate
322
may be formed of any plastic or metallic material having the characteristics of being pliable or bendable.
For a FET, substrate
322
is electrically conductive and layer
324
is also electrically conductive and forms the gate. Layer
326
is an electrical insulator. Electrical conductors
328
and
330
are the source and drain, respectively. For an optical active device, gate layer
324
is omitted and layer
326
is a light transmissive element, such as a light transmissive waveguide, a prism and the like that transmits light to semiconductor body
332
.
For a FET, flexible substrate
322
is preferably a flexible insulated material, such as insulated metal foil, plastics, anodized aluminum, kapton, mylar, cloth, rubber and the like. Layer
324
is any metal that is suitable for a FET gate, such as: aluminum, gold, chrome, and the like. Layer
326
is any suitable gate organic insulator, such as polymethylmethacrylate (PMMA), polyimide, epoxies, and the like; inorganic insulator, such as silicon dioxide, silicon nitride, barium strontium titanates, and the like; or organic/inorganic hybrid, such as sol gel and silicates.
For an optically active device, the flexible substrate is preferably a light transmissive material, such as epoxy, polyimide, polystyrene, mylar, plexiglass, PMMA and the like. Layer
326
is preferably an insulating light transmissive material, such as silicon dioxide, PMMA, and the like. Metal gate layer
326
is preferably a transparent metal, such as indium tin oxide.
For either the FET or the optically active device case, semiconductor body
332
is a layer of organic semiconductor or of a hybrid organic/inorganic material. Suitable organic semiconductor materials include, for example, semiconducting small molecules, oligomers and polymers. For, example, semiconductor body
332
may be formed: with organic semiconductors, such as polythiophene derivatives, oligothiophene derivatives and pentacene. A hybrid semiconductor, for example, may be phenethyl ammonium tin iodide. Electrical conductors
328
and
330
may be any suitable metal or conductive plastic.
These semiconductor material, gate material, gate insulator material and electrical conductors may be applied, by any suitable process, such as coating, dip coating from solution, thermal evaporation, screen printing, extrusion, electrodeposition, stamping, molding and the like.
It should be apparent to those skilled in the art that the FETs described herein can use a hybrid semiconductor, such as, phenethyl ammonium tin iodide, without doping in the channel regions or with doping of tin or antimony in contact regions.
The present invention having been thus described with particular reference to the preferred forms thereof, it will be obvious that various changes and modifications may be made therein without departing from the spirit and scope of the present invention as defined in the appended claims.
Claims
- 1. An active device comprising a thread, a semiconductor body extending axially along said thread, first and second electrical conductors extending axially along said thread and disposed in electrical contact at spaced apart locations with said semiconductor body, wherein the impedance between the first and second electrical conductors is varied by energy that affects said thread.
- 2. The active device of claim 1, wherein said thread has a core, and wherein said semiconductor body is a layer that surrounds said core.
- 3. The active device of claim 2, wherein said core is an optical fiber.
- 4. The active device of claim 2, wherein said core is a piezo-electric material.
- 5. The active device of claim 2, further comprising a layer of insulation material disposed between said core and said semiconductor layer, and wherein said core and said first and second electrical conductors are a gate, a source and a drain of a field effect transistor.
- 6. The active device of claim 1, wherein said thread is a first thread of a plurality of threads, wherein said first and second electrical conductors are second and third ones of said threads.
- 7. The active device of claim 6, wherein said first thread is an optical fiber.
- 8. The active device of claim 6, wherein said first thread includes a core that is electrically conductive, and wherein a layer of electrical insulation material is disposed on said core.
- 9. The active device of claim 8, wherein said semiconductor body is a layer that is disposed on said layer of electrical insulation material.
- 10. The active device of claim 8, wherein a fourth one of said plurality of threads extends axially of said first thread.
- 11. The active device of claim 10, wherein said fourth thread is a spacer of insulation material interposed between said second and third threads.
- 12. The active device of claim 10, wherein said fourth thread includes an electrically conductive core and a layer of electrical insulation material disposed on said core.
- 13. The active device of claim 10, wherein another semiconductor layer is disposed on the electrical insulation layer of said fourth thread.
- 14. The active device of claim 6, further comprising first and second contact bodies that have a carrier enhancing capability and that extend axially of said first thread, wherein said first contact body is disposed between and in electrical contact with said semiconductor body and said second thread, and wherein said second contact body is disposed between and in electrical contact with said semiconductor body and said third thread.
- 15. The active device of claim 14, wherein said second and third threads include first and second cores, respectively, and wherein said first and second contact bodies are disposed on said first and second cores, respectively.
- 16. The active device of claim 14, wherein said first and second contact bodies are fourth and fifth ones of said plurality of threads.
- 17. The active device of claim 1, wherein said semiconductor body includes organic semiconductor material.
- 18. The active device of claim 17, wherein said organic material is a member of the group consisting of: semiconducting small molecules, oligomer and polymers.
- 19. The active device of claim 17, wherein said organic material is a member of the group consisting of: pentacene, oligothiophene and polythiophene.
- 20. The active device of claim 1, wherein said semiconductor body includes a hybrid organic/inorganic semiconductor material.
- 21. The active device of claim 20, wherein said hybrid organic/inorganic semiconductor material is phenethyl ammonium tin iodide.
- 22. The active device of claim 2, wherein said core includes one or more filaments.
- 23. The active device of claim 22, wherein said one or more filaments are electrically conductive.
- 24. The active device of claim 1, wherein said thread is flexible.
- 25. The active device of claim 6, wherein said plurality of threads is twisted.
- 26. The active device of claim 6, further comprising means for holding said plurality of threads together.
- 27. The active device of claim 6, wherein current flow is in a path that includes said semiconductor body and said second and third threads.
- 28. The active device of claim 1, wherein said core is electrically conductive.
- 29. A field effect transistor comprising a thread having an electrically conductive core, a layer of electrical insulation disposed axially along said core, a semiconductor body extending axially along said core and disposed adjacent to said layer of electrical insulation, first and second electrical conductors extending axially along said core and disposed in electrical contact with said semiconductor material at spaced apart locations thereof, wherein the electrical impedance between said first and second electrical conductors varies as a function of energy applied to said electrically conductive core.
- 30. The field effect transistor of claim 29, wherein said thread is a first one of a plurality of threads, wherein said first thread is a gate with said layer of electrical insulation being disposed on the core thereof, wherein a second one and a third one of said threads include said first and second electrical conductors, respectively, and wherein said second and third threads are a source and a drain, respectively.
- 31. The field effect transistor of claim 30, wherein at least one of said plurality of threads is flexible.
- 32. The field effect transistor of claim 30, wherein said plurality of threads is twisted into a bundle, and wherein said bundle is flexible.
- 33. The field effect transistor of claim 30, wherein said semiconductor body includes organic semiconductor material.
- 34. The field effect transistor of claim 33, wherein said organic material is a member of the group consisting of: semiconducting small molecules, oligomer and polymers.
- 35. The active device of claim 33, wherein said organic material is a member of the group consisting of: pentacene, oligothiophene and polythiophene.
- 36. The active device of claim 29, wherein said semiconductor body includes a hybrid organic/inorganic semiconductor material.
- 37. The active device of claim 36, wherein said hybrid organic/inorganic semiconductor material is phenethyl ammonium tin iodide.
- 38. The field effect transistor of claim 29, wherein said core includes one or more filaments.
- 39. The field effect transistor of claim 38, wherein said one or more filaments are electrically conductive.
- 40. The field effect transistor of claim 30, wherein current flow is in a path that includes said semiconductor body and said second and third threads.
- 41. An electrical circuit comprising a plurality of threads and at least one body of semiconductor material, wherein said plurality of threads form two or more electrically interconnected active devices.
- 42. The electrical circuit of claim 41, wherein said semiconductor body is disposed axially of a first one of said plurality of threads, and wherein second and third ones of said plurality of threads are electrically conductive.
- 43. The electrical circuit of claim 42, wherein said semiconductor body is a first semiconductor body, wherein a second semiconductor body is disposed axially of a fourth one of said plurality of threads, and wherein one of said second and third threads is in electrical contact with both of said semiconductor bodies.
- 44. The electrical circuit of claim 42, wherein said semiconductor body is a first semiconductor body that extends axially of a first one of said plurality of threads, and wherein a second semiconductor body is disposed axially of a second one of said plurality of threads, wherein each of said threads includes at least one electrical conductor that extends axially thereof, and wherein said first and second threads comprise said two or more active devices.
- 45. An active device comprising a semiconductor body, a first electrode and a second electrode disposed at spaced apart locations in electrical contact with said semiconductor body, and a substantially planar and flexible substrate that carries said first and second electrodes and said semiconductor body.
- 46. The active device of claim 45, further comprising a gate electrode and a gate insulator, wherein said flexible substrate also carries said gate electrode and said gate insulator.
- 47. The active device of claim 45, wherein said semiconductor body is an organic semiconductor, and wherein said organic material is a member of the group consisting of: semiconducting small molecules, oligomer and polymers.
- 48. The active device of claim 45, wherein said semiconductor body includes an organic semiconductor, and wherein said organic material is-a member of the group consisting of: pentacene, oligothiophene and polythiophene.
- 49. The active device of claim 45, wherein said semiconductor body includes a hybrid organic/inorganic semiconductor material.
- 50. The active device of claim 49, wherein said hybrid organic/inorganic semiconductor material is phenethyl ammonium tin iodide.
- 51. The active device of claim 46, wherein said flexible substrate is a member of the group consisting of metal, electrically conductive polymer and polymer coated with an electrically conductive material.
- 52. The active device of claim 45, further comprising a light transmissive body that is also carried by said flexible substrate.
- 53. The active device of claim 45, wherein said flexible substrate is a light transmissive body.
- 54. A fabric comprising a plurality of threads, wherein at least one of said threads forms an active device that exhibits a change in electrical impedance when subjected to a change in energy.
- 55. The fabric of claim 54, wherein said energy is electrical energy.
- 56. The fabric of claim 54, wherein said energy is light energy.
- 57. The fabric of claim 54, wherein said energy is mechanical energy.
- 58. The fabric of claim 54, wherein said active device is formed by first, second and third ones of said plurality of threads.
- 59. The fabric of claim 58, further comprising a semiconductor body extending axially of said first thread and disposed between said second and third threads.
- 60. The fabric of claim 59, wherein said active device is a first active device, wherein a second active device is formed of fourth and fifth ones of said plurality of threads and of one of said second and third threads, and wherein another semiconductor body extends axially of said fourth thread.
- 61. The field effect transistor of claim 32, further comprising a sheath of electrically insulating material, wherein said bundle is disposed in said sheath.
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