Adhesively bonded engine intake manifold assembly

Information

  • Patent Grant
  • 7475664
  • Patent Number
    7,475,664
  • Date Filed
    Monday, April 2, 2007
    17 years ago
  • Date Issued
    Tuesday, January 13, 2009
    15 years ago
Abstract
An engine intake manifold assembly (10), including a first component (12) having a first mating surface (14) and a second molded plastic component (16) having a second mating surface (18). The second molded plastic component (16) is adhesively bonded to the first component (12) with an adhesive (20). The adhesive bond strength exceeds the strength of the second molded plastic component (16).
Description
TECHNICAL FIELD

The present invention relates to adhesively bonded engine component assemblies and more particularly to adhesively bonded intake manifold assemblies. The invention also relates to an intake manifold assembly employing a cure-on-demand adhesive.


BACKGROUND OF THE INVENTION

Historically, fabrication techniques have involved the fabrication of separate metal components and joining the components using fasteners, with an intermediate disposed gasket. This tends to require many parts and therefore is labor intensive.


Plastic engine intake manifold assemblies (such as for automotive vehicle engines) have been fabricated by near net shape manufacturing processes, such as lost core processes. While these tend to result in desirable near net shape products, the shapes of which may be complex, they typically are expensive.


In another popular process, two or more plastic intake manifold components are made, each with a planar mating surface. The components are joined at each of their respective mating surfaces by vibration welding. This process also tends to be time, energy and labor intensive. Further, there is a potential that any warpage of respective components or other surface irregularities will result in undesirable gaps at the mating surface upon welding. Thus, it is imperative that opposing mating surfaces are planar, which constrains design flexibility.


Accordingly, there is a need to provide a method of manufacture and resulting assembly, pursuant to which multiple components of an engine intake manifold assembly are joined together with an adhesive bond. There is a further need for respective components to be attached to each other in the optional absence of fasteners, a gasket or both. There is still a further need for a high integrity joint be achieved opposing mating surfaces that are non-planar, thereby enabling intricate plastic component shapes (with or without additional integrated components) to be molded by conventional molding processes.


SUMMARY OF THE INVENTION

The present invention meets the above needs and others by providing an engine intake manifold assembly including a first component having a first mating surface, and a second component having a second mating surface. A layer of adhesive is provided between the first and second components in contact with the respective mating surfaces for joining the first and second components to define an engine intake manifold assembly.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a perspective view of an intake manifold assembly in accordance with the present invention.



FIG. 2 is a sectional view of a joint formed in accordance with the present invention.



FIGS. 3
a-3c are sectional views of examples of integrated mechanical attachments in the components of the assembly of the present invention.





DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

Referring to FIGS. 1, 2, 3a-3c there is shown an intake manifold assembly 10 of the present invention including a first component 12 having a first mating surface 14. A second component 16 having a second mating surface 18 is bonded to the first component with an intermediate layer of adhesive 20. Either or both of the first or second mating surfaces can include one or more additional coatings, layers or components. Thus, it is contemplated that the mating surfaces of either or both of the first or second components may not necessarily be integrally formed on the components.


Optionally, either or both of the first component 12 or second component 16 has a member for facilitating joinder or location of the components relative to each other or to the engine. Referring more specifically to FIGS. 2 and 3a-3c (where like parts are denoted by like reference numerals), there are shown examples of different members. Typically, a first member 22 associated with the first component 12 will engage a second opposing structural member 24 associated with the second component 16. Such engagement can be about the periphery of a component, on an interior portion (not shown) or both. Any suitable coating structure may be employed. For instance, a friction fit, an interference fit or some other interlock fit may be used. Examples of suitable joints include butt joints, lap joints, tongue in groove joints or the like. In one embodiment, shown in FIG. 3a, a snap fit connection 26 results from a tang 28 on the first member 22, engaging an opposing wall 30 formed on the second member 24. In another embodiment, in FIG. 3b, one of the components has a flange 32 having an inner wall surface 34 for increasing the surface area available for bonding and for engaging the other component. FIG. 3c is a magnified view of the joints shown in FIG. 2, and illustrates a detent 36 for achieving a snap fit and a rib 38 that penetrates a groove 40 about at least a portion of the mating surface for increasing surface area for contacting adhesive, and effectively forming a tongue-in-groove joint, snap fit or both. As will be appreciated, optionally, a tang or other like structure may be formed for assisting in achieving a snap fit or for providing an audible locator for facilitating assembly. Combinations of the above types of joints are also contemplated as possible within a single assembly. Further examples are illustrated in commonly owned, co-pending U.S. application Ser. No. 09/825,721 (filed contemporaneously herewith; entitled “Adhesively Bonded Radiator Assembly”). Further, other suitable structures or surface treatments may be employed for providing an increase in the amount of surface area of the mating surfaces of the joint, or the overlap between the respect mating surfaces of the components.


The adhesive preferably is provided over at least a portion of the surfaces to be joined, and preferably sufficiently about the periphery so that there are no appreciable gaps that result between the first and second components. In one embodiment, a bead of adhesive is placed (e.g., by pumping) on the respective mating surface of at least one of the components and the opposing mating surface is brought into contact with it. The assembly is then cured. In another embodiment, the adhesive is precoated (e.g., by spraying, dipping, brushing, swabbing, or the like) on one or both of the mating surfaces of the respective components and then the components are joined and cured. Any other suitable joining technique may likewise be employed. Preferably the amount of adhesive employed is sufficient to achieve the desired performance characteristics of the assembly. Such amount will vary from application to application.


In one embodiment the invention is an engine intake manifold having disposed on the mating surfaces of its respective components a continuous bead or film of adhesive. As used herein continuous bead or film of adhesive means a bead or film of adhesive that is disposed around the periphery of the mating surface and the end of the adhesive bead or film connects with the beginning of the adhesive bead or film. The continuous bead or film of adhesive upon cure is capable all of forming an air and liquid tight seal between the components. This function allows the adhesive bead or film to replace gaskets as the sealing means. The adhesive may be applied to the intake manifold components in the immediate vicinity of the location where the components are to be contacted with each other or it may be applied in a location remote from where or when the components are to be contacted. Remote as used herein refers can refer to one or both of time and location. In the embodiment where the adhesive is applied to one or more of the components remote from the place wherein the components are joined together a cure-on-demand adhesive is used.


In a preferred embodiment of the present invention, either or both of the first or second components is fabricated from a plastic material, i.e., a thermoset material, a thermoplastic material, or a mixture thereof. Among preferred high-performance thermoplastic materials are polybutylene terephthalate, polyetherimides, polyphenylene ether/polyamide resins, polyether sulfone resins, polyether ether ketone resins, liquid crystal polymers, polyarylsulfone resins, polyamideimide resins, polyphthalimide resins, nylon 6, 6, polyamide resins, syndiotactic polystyrene, and blends thereof. In a particular preferred embodiment, the material is a thermoplastic selected from polyamides, polystyrenes, polyolefins, polycarbonates, or mixtures thereof. More preferably, the material is selected from polyamides (e.g., nylon 6,6), polystyrenes or mixtures thereof. In one preferred embodiment, the material is a blend of polyamides and syndiotactic polystyrenes, and more preferably a blend of nylon 6,6 and syndiotactic polystyrene. Among useful thermoset materials are epoxy resins.


The plastics used for preparing the components typically will also include other ingredients, such as reinforcements, property modifiers (e.g., impact modifiers, flame retardants, UV protectants or the like) or other suitable fillers (e.g., chopped glass, mineral, talc, calcium carbonate, or the like). For instance, in one embodiment, the plastic is glass filled in an amount of about 10 to about 50 volume percent and more preferably about 35 volume percent. Preferably, the material selected exhibits a tensile strength of at least about 175 MPa and more preferably at least about 225 MPa, and an elongation of about 1 to about 10%, and more preferably about 3 to about 5%. The material is also thermal resistant and will withstand without degradation temperatures of at least about 135° C. (about 275° F.) and more preferably 177° C. (350° F.) for at least about 144 hours and more preferably 168 hours.


Of course, one or more of the components might be a metal (e.g., cast iron, steel, magnesium, aluminum, titanium or the like), a composite, a ceramic (e.g., a carbide, a nitride, a boronitride, or the like), or some other material. The components are preferably injection molded using conventional techniques and processing conditions. Alternatively, they may be prepared in another suitable manner, such as by compression molding, thermoforming, blow molding or the like.


Either or both of the component materials or the adhesive may be suitably treated (uniformly or locally) as desired to improve corrosion resistance, oxidation resistance, thermal resistance, or another characteristic of the final product. For instance, they might be admixed, impregnated or coated with suitable additives for achieving a desired property. In some instances, bond strengths might be enhanced by further contacting the adhesive with a suitable primer.


The adhesive of the present invention is a structural adhesive and more preferably is a curable on demand material. Any adhesive that after cure can withstand the conditions of use of an engine (e.g., for an automotive vehicle) can be used. Preferably such adhesive does not decompose or delaminate at temperatures of up to about 138° C. (280° F.), more preferably up to about 143° C. (290° F.), even more preferably up to about 160° C. (320° F.) and most preferably up to about 191° C. (375° F.).


Furthermore, the adhesive is able to withstand exposure to hydrocarbon materials, calcium chloride, brake fluid, glycol coolants, windshield washer solvents and the like, at the above-mentioned temperatures and the pressures to which the internal combustion engine reaches internally. In an optional embodiment, the adhesive is able to bond to other engine components, which may be metallic, ceramic, composite, plastic, or the like. The adhesive used may be curable via a variety of known mechanisms including heat cure, infrared cure, ultraviolet cure, chemical cure, radio frequency cure, solvent loss, and moisture cure.


In another embodiment the adhesive is a cure-on-demand adhesive which requires a separate operation to cause the adhesive to begin to cure. In one embodiment this is achieved by using an encapsulated curing agent which is ruptured during assembly. In another embodiment this is achieved by removing a protective coating to expose the adhesive to ambient conditions. Cure can be initiated by exposing the adhesive to heat, infrared or ultraviolet light sources, or to shearing forces and the like.


While other adhesive families are contemplated as well (e.g., urethanes, acrylics, silanes, or the like), preferably the adhesive is a high temperature epoxy resin, a polyimide, a hi-bred polyimide/epoxy resin adhesive or an epoxy novolac/nitrile rubber adhesive. Preferred adhesives are the high temperature epoxy resin adhesives. High temperature epoxy resin adhesive means an adhesive wherein the primary component is an epoxy resin which when cured can withstand exposure to the temperatures mentioned above without decomposing or delaminating from the substrate.


In a particularly preferred embodiment, the adhesive is a mineral filled catalyzed adhesive that includes one or more regular or modified epoxy components, a suitable curing agent and a suitable thixotropic agent for maintaining a room temperature Brookfield viscosity (in uncured state) on the order of about 500 cps.


It should be recognized that the use of the term adhesive herein is not intended to foreclose primers or other bonding agents from the scope of the present invention.


The present invention offers considerable design flexibility. Though mating surfaces can be planar, they need not be. In a preferred embodiment, either or both of the mating surfaces is generally non planar (e.g., contoured, stepped, corrugated, or the like). The employment of molded plastic components also enables the formation of intricately shaped structures. In this regard, the intake manifold can have molded or otherwise fabricated in or on one of its surfaces one or more components such as brackets, connectors, cable guides, hose guides, harnesses, clips or the like. Further, conduits, ports or other like passages can be cored or machined into a molded component to enable integration of multiple components into the intake manifold assembly.


As will be appreciated by the skilled artisan, among the many advantages of the present invention are that assemblies can be made that are substantially free of a sealing gasket, mechanical fasteners or both. However, the scope of the present invention does not foreclose the use of gaskets or fasteners. Indeed, it is contemplated that a gasket might be made from (e.g., by die cutting a gasket) from the adhesive or incorporate as a component thereof (e.g. as an impregnant or coating), the adhesive of the present invention. The resulting structure seals much like a gasket would, but also exhibits the desirable mechanical characteristics of the structural adhesive.


With specific reference to FIGS. 3a-3c, it can be seen that the joint has a transverse cross section thickness (t) at the joint. Though larger section thicknesses may be used and remain within the scope of the present invention, in certain highly preferred embodiments, the section thickness is less than about 7 mm, and still more preferably is less than about 5 mm (e.g., about 3 to about 4 mm). This further renders the present invention more advantageous than previous assemblies, which typically have employed larger section thicknesses.


Another advantage of the present invention relative to vibration welded assemblies is that substantially the entirety of the first and second mating surfaces in contact with the adhesive is capable of continuously bonding to the adhesive across the joint and thereby reinforcing the joint strength. In contrast, where filled or reinforced plastics are vibration welded, the filler or reinforcement (e.g., glass) will not weld at the weld interface. Thus, across the interface, there are discontinuities that inhibit achievement of high weld strengths.


Though the present invention has been described in the context of automotive vehicle engine intake manifolds, the use of the invention is not intended to be limited thereby. Any motorized object employing an intake manifold subject to operating conditions milder than or comparable to those experienced by an automotive vehicle engine may employ the present technology.


In preparation of the present assembly, the adhesive is applied to the by contacting the adhesive in a conventional fashion with one or more mating surface to form a continuous bead or film. The adhesive may be coated, extruded brushed or the like onto the surface. The adhesive can be applied immediately before joining components or it can be applied in remote location from the location where the components are bonded together, or the engine. The preferred cure-on-demand adhesive is exposed to conditions such that it will cure and thereby bond the components together and form a seal between them. Such conditions can be applied prior to or after bringing components together for joining. It is well within the average level of skill in the art to determine which operation may be used to cure the adhesive and when it should be performed. In one embodiment the operation may be an operation that is inherent in the assembly or operation of an automotive vehicle.


In another embodiment the intake manifold assembly may include an integrated acoustic management system designed to prevent the noise inherent in the operation of an internal combustion engine from escaping the engine compartment. In one embodiment the assembly may include an outer shell and an inner shell adapted such that the inner shall is located within the outer shell and there is a gap between the two. The gap may simply contain air which can attenuate certain sound waves thereby reducing the noise that can be heard outside the engine. Alternatively the gap can be filled with a sound deadening material such as elastomeric material or foam material. In another embodiment the valve cover may have bound to its inner surface a sound attenuating material such as the elastomer or foam.


In another embodiment the assembly of the invention can include a coating or film on the exterior or interior which functions to improve the barrier properties of the valve cover to hydrocarbons. Such a coating of film can reduce the fugitive hydrocarbon emission from an automotive vehicle. Any coating or film which prevents the transmission of hydrocarbons through the assembly may be used. A preferred coating is a carbon-silica based plasma deposited coating as described in U.S. Pat. Nos. 5,298,587; 5,320,875; 5,433,786 and 5,494,712 incorporated herein by reference.


The assembly of the present invention is capable of withstanding a temperature of about 163° C. (about 325° F.) for at least about 2500, and more preferably about 3000 hours and about 177° C. (about 350° F.) for at least about 75 and more preferably about 100 hours. The assembly exhibits substantially no detectable degradation in the presence of automotive vehicle fluids, such as brake fluid, windshield washer fluid, power steering fluid, engine coolant (standard and lifetime), engine oil (standard, synthetic and sour), gasoline, diesel fuel, ethanol, methanol, starter fluids or the like. The assembly also exhibits no detectable degradation due to exposure to environmentally encountered compounds such as calcium chloride, sodium chloride, exhaust gas (e.g. type) or the like. In a particularly preferred embodiment, the resulting tensile strength of the adhesive of the joint in the assembly is at least about 4000 psi (28 MPa), more preferably at least about 6500 psi (45 MPa), and still more preferably at least about 9000 psi (62 MPa). Further preferably the strength of the joint is greater than the strength of at least one, and preferably more than one, of the individual molded components.


The present intake manifold assembly can be employed in combination with other adhesively bonded engine components, such as described in commonly owned co-pending application Ser. No. 10/051,417 (“Adhesively Bonded Valve Cover Cylinder Head Assembly”), hereby incorporated by reference, and that disclosed in commonly owned co-pending application Ser. No. 09/825,721 (“Adhesively Bonded Radiator Assembly”), hereby incorporated by reference.

Claims
  • 1. A method for making an automotive vehicle engine intake manifold assembly, comprising the steps of: a) providing a first component having an associated first mating surface for defining a joint;b) molding a second component having an associated second mating surface for opposing the first mating surface and defining the joint;c) applying an epoxy structural adhesive to at least one of the first component or the second component;d) joining the first component together with the second component with the epoxy structural adhesive therebetween for forming a joint section with a thickness less than about 7 mm;e) snap-fitting the first component together with the second component;f) curing the structural adhesive for bonding the first component with the second component; wherein at least one of the first or the second component includes a flange having an inner wall surface adapted for receiving the adhesive on at least one of the first component or the second component.
  • 2. The method of claim 1, wherein the snap-fitting includes audibly locating the first component relative to the second component.
  • 3. The method of claim 2, wherein the epoxy structural adhesive is a high temperature structural adhesive.
  • 4. The method of claim 1, wherein the second component is a plastic that includes a material selected from polyamides, polystyrenes or mixtures thereof.
  • 5. The method of claim 3, further including a step of exposing the adhesive to heat for initiating curing of the epoxy structural adhesive.
  • 6. The method of claim 1, further including a step of contacting the structural adhesive with a primer.
  • 7. The method of claim 1, wherein at least one of the first component or the second component includes a glass filled plastic.
  • 8. A method for making an automotive vehicle engine intake manifold assembly, comprising the steps of: a) providing a first component having an associated first mating surface for defining a tongue-in-groove joint having a section thickness less than about 5 mm;b) injection molding a second component having an associated second mating surface for opposing the first mating surface and defining the tongue-in-groove joint;c) applying a high temperature epoxy structural adhesive to at least one of the first component or the second component;d) applying a primer to at least one of the first component or the second component;e) joining the first component together with the second component with the high temperature epoxy structural adhesive therebetween;f) snap-fitting the first component together with the second component;g) exposing the adhesive to heat for initiating curing of the structural adhesive; andh) curing the structural adhesive for bonding the first component with the second component; wherein at least one of the first or the second component includes a flange having an inner wall surface adapted for receiving the adhesive on at least one of the first component or the second component.
  • 9. The method of claim 8, wherein each of the first component and the second component are plastic.
  • 10. The method of claim 9, further including a step of forming a flange having an inner wall surface adapted for receiving the adhesive on at least one of the first component or the second component.
  • 11. The method of claim 10, wherein the second component is a plastic that includes a material selected from polyamides, polystyrenes or mixtures thereof.
CLAIM OF PRIORITY

This application is a continuation of Ser. No. 10/796,404, filed on Mar. 9, 2004 now U.S. Pat. No. 7,213,560, which is a continuation of Ser. No. 10/318,926, filed on Dec. 13, 2002 now U.S. Pat. No. 6,739,302, which is a continuation of Ser. No. 09/826,477 filed on Apr. 4, 2001 now U.S. Pat. No. 6,543,404.

US Referenced Citations (111)
Number Name Date Kind
3724599 Heidacker Apr 1973 A
3903350 Baird Sep 1975 A
3926904 Scola Dec 1975 A
3993126 Taylor Nov 1976 A
4101003 Timour et al. Jul 1978 A
4266604 Sumikawa et al. May 1981 A
4301775 Smart et al. Nov 1981 A
4345552 Kasting et al. Aug 1982 A
4374717 Drauglis et al. Feb 1983 A
4402518 Locacius Sep 1983 A
4471731 Kasting et al. Sep 1984 A
4480609 Hayashi Nov 1984 A
4492267 Cadars Jan 1985 A
4495020 Nakabayashi et al. Jan 1985 A
4498433 Ogawa Feb 1985 A
4522165 Ogawa Jun 1985 A
4531578 Stay et al. Jul 1985 A
4540044 Lenz Sep 1985 A
4544432 Foister et al. Oct 1985 A
4546822 Tamura Oct 1985 A
4576223 Humpolik et al. Mar 1986 A
4586566 Kern et al. May 1986 A
4600051 Wehrman Jul 1986 A
4608950 Payne et al. Sep 1986 A
4677947 Bousquet Jul 1987 A
4678026 Lenz et al. Jul 1987 A
4682672 Berger et al. Jul 1987 A
4708105 Leydorf et al. Nov 1987 A
4709670 Ampferer Dec 1987 A
4709689 Simcox Dec 1987 A
4709757 Bly Dec 1987 A
4735261 Huebner Apr 1988 A
4741352 Gray May 1988 A
4898261 Winberg et al. Feb 1990 A
4930469 Kamprath et al. Jun 1990 A
4938314 Sitzier et al. Jul 1990 A
4939923 Sharp Jul 1990 A
4940086 Stay Jul 1990 A
4941936 Wilkinson et al. Jul 1990 A
4951783 Kamprath et al. Aug 1990 A
4961967 Pluddemann Oct 1990 A
4985523 Mochizuki et al. Jan 1991 A
5058542 Grayson et al. Oct 1991 A
5083537 Onofrio et al. Jan 1992 A
5098743 Juday Mar 1992 A
5107924 Herbert et al. Apr 1992 A
5158045 Arthur et al. Oct 1992 A
5188078 Tamaki Feb 1993 A
5195581 Puntambekar et al. Mar 1993 A
5223684 Li et al. Jun 1993 A
5250629 Tani et al. Oct 1993 A
5265566 Arnold et al. Nov 1993 A
5284203 Dauvergne Feb 1994 A
5285754 Bell Feb 1994 A
5298587 Hu et al. Mar 1994 A
5320875 Hu et al. Jun 1994 A
5323740 Daily et al. Jun 1994 A
5323745 Sato et al. Jun 1994 A
5329903 Mueller et al. Jul 1994 A
5364914 Choate et al. Nov 1994 A
5365901 Kiczek Nov 1994 A
5375569 Santella Dec 1994 A
5376428 Palazzotto et al. Dec 1994 A
5412024 Okada et al. May 1995 A
5424371 Frihart et al. Jun 1995 A
5433786 Hu et al. Jul 1995 A
5476237 Clarke Dec 1995 A
5492086 Kuhns Feb 1996 A
5494712 Hu et al. Feb 1996 A
5511518 Jain et al. Apr 1996 A
5531196 Clark Jul 1996 A
5548026 Jorissen et al. Aug 1996 A
5569734 Petschel et al. Oct 1996 A
5575256 Peters et al. Nov 1996 A
5617825 Altmann et al. Apr 1997 A
5636605 Nomizo et al. Jun 1997 A
5636607 Sattler et al. Jun 1997 A
5636759 Brummer Jun 1997 A
5642697 Jahrens et al. Jul 1997 A
5663284 Kominami et al. Sep 1997 A
5669350 Altmann et al. Sep 1997 A
5704325 Sattler et al. Jan 1998 A
5704335 Akutagawa et al. Jan 1998 A
5715782 Elder Feb 1998 A
5717009 Matsushita et al. Feb 1998 A
5743011 Dickerson et al. Apr 1998 A
5746168 Lochbrunner et al. May 1998 A
5746177 Criss et al. May 1998 A
5791312 Sattler et al. Aug 1998 A
5794591 Kalebjian et al. Aug 1998 A
5797589 Kalebjian et al. Aug 1998 A
5837958 Fornsel Nov 1998 A
5865244 Moser Feb 1999 A
5875758 Fujita Mar 1999 A
5877236 Roesch et al. Mar 1999 A
5878715 Hernandez et al. Mar 1999 A
5883192 Natori et al. Mar 1999 A
5947073 Chaffin et al. Sep 1999 A
5957100 Frohwerk et al. Sep 1999 A
6013709 Masuyama et al. Jan 2000 A
6021753 Chaffin et al. Feb 2000 A
6069219 McCormick et al. May 2000 A
6131543 Achenbach et al. Oct 2000 A
6167855 Mammarella et al. Jan 2001 B1
6267093 Lohr Jul 2001 B1
6302074 Bolsover et al. Oct 2001 B1
6497413 Schmatz Dec 2002 B1
6543404 Jones et al. Apr 2003 B2
20020144808 Jones Oct 2002 A1
20030165305 Dallas et al. Sep 2003 A1
20040266925 Shiono Dec 2004 A1
Foreign Referenced Citations (23)
Number Date Country
2355052 Jul 2000 CA
3720483 Jan 1988 DE
3809944 Oct 1989 DE
3927955 Feb 1991 DE
41 03 685 Aug 1992 DE
19735 445 Jan 1999 DE
199 02817 Jul 2000 DE
0512678 Nov 1992 EP
0823455 Feb 1998 EP
0872632 Oct 1998 EP
0992674 Dec 2000 EP
1045948 Oct 1966 GB
2 245 931 Jan 1992 GB
362003155 Jan 1987 JP
407027016 Jan 1995 JP
8-132529 May 1996 JP
11207826 Mar 1999 JP
11-302480 Nov 1999 JP
2000210947 Feb 2000 JP
WO 99 14273 Mar 1999 WO
WO 0043644 Jul 2000 WO
WO0144311 Jun 2001 WO
PCTUS0146503 Dec 2001 WO
Related Publications (1)
Number Date Country
20070251483 A1 Nov 2007 US
Continuations (3)
Number Date Country
Parent 10796404 Mar 2004 US
Child 11695332 US
Parent 10318926 Dec 2002 US
Child 10796404 US
Parent 09826477 Apr 2001 US
Child 10318926 US