The present disclosure is directed to an apparatus, a method of servicing, and a method of measuring for a coating process.
Line of sight measurements, such as temperature measurements using a pyrometer, are known for use with controlled atmosphere processes, such as sputtering. Such measurements are made through viewports that provide line of sight viewability of a workpiece or other component within the controlled atmosphere.
Generally, in certain coating processes (for example, vapor deposition), a solid material from a vapor is deposited on exposed surfaces of an article within the vapor deposition chamber. The deposition also occurs on other surfaces. The surfaces can include chamber walls, viewports, or other exposed surfaces. Over time, the coating can build up on the chamber walls, viewports, or other exposed surfaces. When buildup occurs on the viewports, measurements through the viewport can become unreliable. Conventional systems require shutdown of the process in order to service the viewport.
An apparatus and method that provides reduced buildup of coating on a viewport and permits servicing of the viewport without taking the process offline, wherein the apparatus and method may be used in conjunction with the formation of a photovoltaic module would be desired in the art.
In an exemplary embodiment, a shutter apparatus having a viewport, a device positioned for selectively isolating the viewport from a process chamber, and a second chamber positioned between the viewport and the device. The device includes a first position to selectively isolate the viewport from a process chamber and to selectively maintain a predetermined process pressure in the process chamber. The device includes a second position to selectively permit line of sight measurement of the process chamber from the viewport. The second chamber maintains the predetermined process pressure in the process chamber when the device is in the second position.
In another exemplary embodiment, a method for servicing a coating apparatus having an isolatable viewport including providing a shutter apparatus, venting the second chamber, and maintaining the predetermined process pressure in the process chamber during servicing of the coating apparatus. The shutter apparatus includes a viewport, a device positioned for selectively isolating the viewport from a process chamber and a second chamber positioned between the viewport and the device. The device includes a first position to selectively isolate the viewport from a process chamber and to selectively maintain a predetermined process pressure in the process chamber. The device includes a second position to selectively permit line of sight measurement of the process chamber from the viewport. The second chamber maintains the predetermined process pressure in the process chamber when the device is in the second position.
In another exemplary embodiment, a method of measuring a process parameter for a coating process having an isolatable viewport includes providing a shutter apparatus, adjusting pressure in the second chamber, and actuating the device. The shutter apparatus includes a viewport, a device positioned for selectively isolating the viewport from a process chamber; and a second chamber positioned between the viewport and the device. The device includes a first position to selectively isolate the viewport from a process chamber and to selectively maintain a predetermined process pressure in the process chamber. The device includes a second position to selectively permit line of sight measurement of the process chamber from the viewport. The second chamber maintains the predetermined process pressure in the process chamber when the device is in the second position. The process parameter is measured for the coating process when the device is in the second position.
Wherever possible, the same reference numbers will be used throughout the drawings to represent the same parts.
Provided is an apparatus and method that provides reduced buildup of coating on a viewport and permits servicing (for example, cleaning, replacing, etc.) of the viewport without taking the process offline. The apparatus and method may be used in conjunction with the formation of a photovoltaic module.
Embodiments of the present disclosure may reduce buildup of coating on viewports, may increase operational capacity by having less downtime for cleaning viewports, may decrease the effect on temperature measurements within a coating chamber, and/or may provide a simple and low cost solution for monitoring and thereby controlling temperature and pressure within a coating chamber.
In the disclosure, when a layer is being described as “adjacent,” “on,” or “over” another layer or substrate, it is to be understood that the layer can either be directly in contact or that another layer or feature can intervene.
Superstrate 201 is a sheet of high transmission glass onto which thin films are grown. Superstrate 201 receives light 105 (see e.g.,
After light 105 passes through superstrate 201, light passes through first conductive layer 203. First conductive layer 203 may be a transparent conductive oxide (TCO), which permits transmission of light 105 with little or no absorption. First conductive layer 203 is also electrically conductive, permitting electrical conduction to provide the series arrangement of cells 107. In one embodiment, the first conductive layer 203 is about 0.3 pm of stoichiometric cadmium stannate (nominally Cd2SnO4).
Other suitable conductive layers may include fluorine-doped tin oxide, aluminum-doped zinc oxide, indium tin oxide. First conductive layer 203 may permit passage of light 105 through to the semiconductor layers (e.g., first semiconductor layer 207 and second semiconductor layer 209) while also functioning as an ohmic electrode to transport photogenerated charge carriers away from the light absorbing material.
A buffer layer 205 is adjacent to first conductive layer 203. Buffer layer 205 is more electrically resistive and protects the layers of cell 107 from chemical interactions from the glass and/or interactions which might be incurred from subsequent processing. Inclusion of buffer layer 205 reduces or prevents electrical or other losses that may take place across cell 107 and across module 100. Suitable materials for buffer layer 205 may include zinc oxide containing materials and/or any other suitable barrier material having more electrical resistivity than first conductive layer 203 and capable of protecting the layers of the cell from interactions from the glass or interactions from subsequent processing. In addition, the inclusion of buffer layer 205 permits the formation of a first semiconductor layer 207 which permits photon passage while maintaining a high quality junction capable of generating electricity. In certain embodiments, buffer layer 205 may be omitted or substituted by another material or layer. In one embodiment, buffer layer 205 includes a combination of ZnO and SnO2. For example, buffer layer 205 may be formed to a thickness of about 0.1 μm thick or less and may include ZnO and SnO2 in about a one to two (1:2) stoichiometric ratio.
As shown in
First semiconductor layer 207 forms the junction with second semiconductor layer 209 to create the photovoltaic effect in cell 107, allowing electricity to be generated from light 105. Second semiconductor layer 209 may include Cd, CdTe or other p-type semiconductor material when provided with first semiconductor layer 207 provides a photovoltaic effect when exposed to light 105.
As shown in
Second conductive layer 211 may be fabricated from any suitable conductive material and combinations thereof. For example, suitable materials include materials including, but not limited to, graphite, metallic silver, nickel, copper, aluminum, titanium, palladium, chrome, molybdenum alloys of metallic silver, nickel, copper, aluminum, titanium, palladium, chrome, and molybdenum and any combination thereof. In one embodiment, second conductive layer 211 may be a combination of graphite, nickel and aluminum alloys.
An encapsulating glass 213 may be adhered adjacent to second conductive layer 211. Encapsulating glass 213 may be a rigid structure suitable for use with the thin films of cell 107. Encapsulating glass 213 may be the same material as superstrate 201 or may be different. In addition, although not shown in
Module 100 and individual cells 107 may include other layers and structures not shown in
As shown in the flow diagram of
Subsequent to providing superstrate 201, first conductive layer 203 is deposited onto superstrate 201 (box 303). First conductive layer 203 is electrically conductive, which permits electrical conduction to provide the series arrangement of cells 107. In one embodiment, first conductive layer 203 is about 0.3 μm of stoichiometric cadmium stannate (nominally Cd2SnO4). Other suitable conductive layers may include fluorine-doped tin oxide, aluminum-doped zinc oxide, and/or indium tin oxide. First conductive layer 203 can be formed, for example by direct current (DC) or radio refrequency (RF) sputtering. In one embodiment, first conductive layer 203 is a layer of substantially amorphous Cd2SnO4 that is sputtered onto superstrate 201. Such sputtering can be performed from a hot-pressed target containing stoichiometric amounts of SnO2 and CdO onto superstrate 201 in a ratio of 1 to 2. The cadmium stannate can alternately be prepared using cadmium acetate and tin (II) chloride precursors by spray pyrolysis.
Once first conductive layer 203 is applied, buffer layer 205 may be applied to first conductive layer 203 (box 305). In one embodiment, buffer layer 205 may be formed, for example, by sputtering. In one example, buffer layer 205 may be formed by sputtering from a hot-pressed target containing stoichiometric amounts of about 67 mol % SnO2 and about 33 mol % ZnO onto first conductive layer 203. As deposited by sputtering, the zinc tin oxide material for buffer layer 205 may be substantially amorphous. Layer 205 may have a thickness between about 200 and 3,000 Angstroms, or between about 800 and 1,500 Angstroms, to have desirable mechanical, optical, and electrical properties. Buffer layer 205 may have a wide optical bandgap, for example about 3.3 eV or more, in order to permit the transmission of light 105.
First semiconductor layer 207 is deposited on buffer layer 205 (box 307). In one embodiment, first semiconductor layer 207 may be formed, for example, by chemical bath deposition or sputtering. First semiconductor layer 207 may be deposited to a thickness of from about 0.01 to 0.1 μm. One suitable material for use as first semiconductor layer 207 is CdS. A suitable thickness for a CdS layer may be from about 500 and 800 Angstroms. First semiconductor layer 207 forms the junction with second semiconductor layer 209 to create the photovoltaic effect in cell 107, allowing it to generate electricity from light 105.
After the formation of first semiconductor layer 207, second semiconductor layer 209 is deposited on first semiconductor layer 207 (box 309). Second semiconductor layer 209 may include Cd, CdTe or other p-type semiconductor material. Second semiconductor layer 209 may be deposited by diffusive transport deposit, sputtering or other suitable deposition method for depositing p-type semiconductor thin film material.
Subsequent to the formation of second semiconductor layer 209, second conductive layer 211 is formed (box 311). Second conductive layer 211 may be fabricated from any suitable conductive material. Second conductive layer 211 may be formed by sputtering, electrodeposition, screen printing, physical vapor deposition (PVD), chemical vapor deposition (CVD) or spraying. In one embodiment, second conductive layer 209 is a combination of graphite that is screen printed onto the surface and nickel and aluminum alloy that is sputtered thereon.
All the sputtering steps described above are suitably magnetron sputtering at ambient temperature under highly pure atmospheres. However, other deposition processes may be used, including higher temperature sputtering, electrodeposition, screen printing, physical vapor deposition (PVD), chemical vapor deposition (CVD) or spraying. In addition, the processing may be provided in a continuous line or may be a series of batch operations. When the process is a continuous process, the sputtering or deposition chambers are individually isolated and brought to coating conditions during each coating cycle and repeated.
Once second conductive layer 211 is formed, encapsulating glass 213 is adhered to second conductive layer 211 (box 313). Encapsulating glass 213 may be a rigid material suitable for use with thin film structures and may be the same material or different material than superstrate 201. Encapsulating glass 213 may be adhered to second conductive layer 211 using any suitable method. For example, encapsulating glass 213 may be adhered to second conductive layer 211 using an adhesive or other bonding composition.
Although not shown in
Scribing may be utilized to form the interconnections between the layers and isolate cells and/or layers of the thin film stack. Scribing may be accomplished using any known techniques for scribing and/or interconnecting the thin film layers. In one embodiment, scribing is accomplished using a laser directed at one or more layers from one or more directions. One or more laser scribes may be utilized to selectively remove thin film layers and to provide interconnectivity and/or isolation of cells 107. In one embodiment, the scribes and layer deposition are accomplished to interconnect and/or isolate cells 107 to provide a PV circuit having cells 107 in a series electrical arrangement.
In one embodiment, chamber 406 may have an entrance and an exit permitting articles to enter and exit chamber 406 at predetermined times during the vapor deposition. For example, chamber 406 may be an in-line chamber as part of a substantially continuous manufacturing line. The entrance and the exit may positioned inline before, after, and/or adjacent to heat chambers 417. Heat chambers 417 may include features for maintaining a vacuum before, after, and/or within process chamber 406 during some or all periods of the vapor deposition. In another embodiment, process chamber 406 may be a batch chamber having a fixed volume of space available for application of coating.
Shutter apparatus 400 includes a viewport 402, a device 404 positioned for selectively isolating viewport 402 from process chamber 406, and a second chamber 408 positioned between viewport 402 and device 404, second chamber 408 having a port 410 (as further described below with reference to
The process can involve monitoring and controlling of various parameters. For example, the duration of the deposition process may be controlled, the amount of vapor provided may be controlled, and the properties of the vapor provided may be controlled. The properties of the vapor provided may include the temperature and pressure. Within process chamber 406, multiple vapors of different temperatures may be provided and/or vapors provided may change temperature upon entering the atmosphere of process chamber 406. Monitoring the temperature within process chamber 406 may be performed by measuring temperature through one or more shutter apparatuses 400 positioned along the walls or other portions of process chamber 406. Generally, chamber 406 may be exposed to pressure from about 10−10 torr to about 5000 torr, 10−10 torr to 1 torr, or 10−4 torr to about 10−3 torr and temperatures between about 100° C. and about 800° C.
Viewport 402 may be any suitable viewport for measuring temperature within process chamber 406 with pyrometer 412. Viewport 402 is formed of a material that includes optical properties that do not modify the temperature measurement. For example, viewport 402 may be a calcium fluoride window. To measure temperature within process chamber 406, viewport 402 may be subjected to high temperatures and low pressures associated with coating processes. It is desirable that the temperature of viewport 402 be maintained at a predetermined temperature below a detection limit of measurement device 412 to avoid modifying the temperature measurement of article 403.
When measurements are being taken, viewport 402 and/or second chamber 408 may be exposed to vapor from within process chamber 406 thereby contacting and potentially coating viewport 402 and/or second chamber 408. Thus, it is desirable that viewport 402 and second chamber 408 be inert and chemically resistant. To remove coating 405 that builds up on viewport 402 or second chamber 408, viewport 402 and/or second chamber 408 may be removed and cleaned after device 404 is closed (as shown in
Referring to
Device 404 further includes a second position (open) to selectively permit line of sight measurement of process chamber 406 from viewport 402. Device 404 may move from the first position to the second position by any suitable mechanism. For example, device 404 may move from the first position to the second position by a rod 409 actuated by any suitable mechanism for adjusting the position of device 404. As device 404 is actuated from the second position (open) to the first position (closed) by rod 409, a cam feature 416 may force seal(s) 407 to be compressed outwardly toward sealing surface. In the second position (open), cam feature 416 may be adjusted by moving rod 409, thereby permitting an open path between process chamber 406 and viewport 402.
It is desirable for the shutter apparatus 400 to be in the second position for a short duration because vapor within process chamber 406 may be traveling into second chamber 408 and to viewport 402 while the device is in the second position. It is further desirable that device 404 open quickly to decrease the duration of time between the shutter apparatus 400 being in the first position (where little or no vapor is likely to travel from process chamber 406 into second chamber 408) and the shutter apparatus 400 being in the second position (where temperature measurements of process chamber 406 may be performed with the pyrometer 412).
In one embodiment, differential pumping may be performed by one or more ports 414 positioned in a region 413 selectively fluidly separated from second chamber 408 and process chamber 406 by device 404. Differential pumping may permit operation of process chamber 406 at lower pressures. Port(s) 414 may reduce or eliminate air (or other gas) entering process chamber 406 by removing the air (or other gas) in region 413 prior to the air (or other gas) traveling to process chamber 406. Port(s) 414 may be vacuum pumped when device 404 is in the first position (closed). In another embodiment, seal(s) 407 may be utilized (along with differential pumping on port(s) 414) to selectively reduce or eliminate traveling of vapor between process chamber 406, into region 413, and second chamber 408. Also, prior to actuating device 404 to the second position (open), pressure within region 413 may be adjusted (for example, to substantially equalize the pressure) in second chamber 408 and process chamber 406. Other suitable methods of differential pumping may additionally or alternatively be used.
Referring to
While the disclosure has been described with reference to a preferred embodiment, it will be understood by those skilled in the art that various adjustments may be made and equivalents may be substituted for elements thereof without departing from the scope of the disclosure. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the disclosure without departing from the essential scope thereof. Therefore, it is intended that the disclosure not be limited to the particular embodiment disclosed as the best mode contemplated for carrying out this disclosure, but that the disclosure will include all embodiments falling within the scope of the appended claims.