The present invention is related to real-time industrial and municipal water and liquid quality monitoring. This type of device is used in a variety of applications such as monitoring quality of plant effluent, industrial process control, and security monitoring of drinking water distribution systems.
Recently, industry and government have begun to realize the value of continuous monitoring of process parameters for a variety of applications. It is now understood that being able to monitor process variables in real-time allows operators to adjust the process parameters without delay so that the process can be continuously optimized. This can have wide ranging benefits such as cost reduction, improved quality, faster production and reduced waste. An example this kind of thinking is the recent push for process analytical technology (PAT) in the pharmaceutical industry.
Real-time transmittance and absorbance monitoring devices are some of the most applicable technologies for continuous monitoring of a variety of water quality parameters. This is partially due to their versatility since so many parameters can be determined with the use of certain wavelengths of light.
However, current transmittance monitoring technologies require improvement. One of the main issues affecting the accuracy, cost and maintenance of current transmittance monitoring devices is a lack of stability of the output of the light sources. This lack of stability manifests as sudden output fluctuations over the short term, medium term drift due to temperature and humidity effects on the lamp and power supply electronics, and long term drift due to aging of the light source.
Several methods commonly used to deal with the light source stability issue are: use of very high quality lamp and power supply electronics; use of complicated optics to split the light path to two sensors such that one sensor looks at the transmittance and the other sensor looks at the lamp output such that compensation is made for light source instability; use of beam splitting optics with a light beam chopper to allow the use of a single sensor by alternating transmittance and lamp output measurements for stability compensation; use of multiple path-length technologies for stability compensation which require either the use of multiple sensors; use of wetted moving parts, or place practical upper and lower limits on effective path-length; use of a reference wavelength outside the absorbance spectrum of the particular agent being monitored which assumes lamp fluctuations occur identically at all wavelengths emitted by the lamp and assumes that there is in fact a wavelength that is outside the absorbance spectrum of the particular agent being monitored.
Therefore, there is a need for a transmittance measuring device which avoids the aforementioned limitations.
The present invention provides a device that monitors light transmittance using an inexpensive light source and power supply by compensating for light source drift and fluctuations using only one light sensor and one light beam without an expensive optical system, without practical limitations on path-length, and without the errors caused by using reference wavelengths.
In an aspect of the present invention there is provided an apparatus for measuring a transmittance of light through a target substance, the apparatus comprising: a light source for emitting light; a light detector for detecting an intensity of light; a support mechanism on which the light source and the light detector are mounted in a spaced apart relationship thereby defining a straight light path from the light source to the light detector, an actuator for engendering relative motion between the support mechanism and the target substance to at least a first position and a second position, where in the first position the target substance substantially intersects the light path and in the second position the target substance does not substantially intersect the light path. Preferably, the support mechanism is movable to at least a first and a second position with respect to the target, where in the first position the target substance substantially intersects the straight light path and in the second position the target substance does not substantially intersect the straight light path.
The target substance may be a solid, or it may be a fluid, and wherein the apparatus further comprises a structure capable of containing the fluid. Preferably, the apparatus includes a digital computer capable of controlling the actuator and receiving light intensity signals from the light detector. Even more preferably, the digital computer is a microprocessor connected to the light detector and to the actuator.
In a further embodiment of the present invention, the actuator may be a rotational actuator; wherein in the first position the support mechanism and the target are at a first angle with respect to each other, and in the second position the support mechanism and the target are at a second angle with respect to each other. In this embodiment, the rotational actuator preferably rotates along an axis of rotation that does not intersect the target substance.
In a further embodiment of the present invention, the target substance is a fluid; the apparatus further comprises a structure enclosing the support mechanism, the light source, and the light detector; the structure including at least one orifice and least one translucent region; the translucent region substantially intersects the straight light path when in the second position; the orifice allows for fluid to flow into and out of the structure; and the orifice substantially intersects the straight path when in the first position. In this embodiment, the actuator is preferably a linear actuator. Preferably, the translucent region is a cell containing one of vacuum and air. Even more preferably, the structure includes a first and second region, the light source contained in the first region, and the light detector contained in the second region; and the straight light path intersects at least a portion of the structure when in one or both of the first position and the second position. Preferably, the first and second region are tubular in shape, and the first translucent region is a tube that substantially intersects the straight light path when in the first position, and the second translucent region is a pair of opposing windows that substantially intersects the straight light path when in the second position.
In a further aspect of the present invention, there is provided a method for measuring a transmittance of light through a target substance, the method comprising: providing an apparatus comprising: a light source for emitting light; a light detector for detecting an intensity of light; a support mechanism on which the light source and the light detector are mounted in a spaced apart relationship thereby defining a straight light path from the light source to the light detector, the support mechanism being movable to at least a first and a second position with respect to the target, where in the first position the target substance substantially intersects the straight light path and in the second position the target substance does not substantially intersect the straight light path; and an actuator for moving the support mechanism into the first position and the second position with respect to the target; performing a first measurement step and a second measurement step in either order, the first measurement step including signaling the actuator to move the support mechanism to the first position and subsequently storing in memory a first value corresponding to a first signal received from the light detector; and the second measurement step including signaling the actuator to move the support mechanism to the second position and subsequently storing in memory a second value corresponding to a second signal received from the light detector. Preferably, the method further comprises the step of: computing a ratio of the first value and the second value.
In a further aspect of the present invention there is provided an apparatus for measuring a transmittance of light through a target substance comprising: a light source capable of emitting light; a light detector capable of detecting an intensity of light; a support mechanism on which the light source and the light detector are mounted in a spaced apart relationship thereby defining a path of light from the light source to the light detector; and an actuator for engendering relative motion between the support mechanism and the target substance to at least a first position and a second position; wherein in the first position the target substance substantially intersects the path of light and in the second position the substance does not substantially intersect the path of light.
In a further aspect of the present invention there is provided a method for measuring a transmittance of light through a target substance using the apparatus provided in the invention, the method comprising: performing a first measurement step and a second measurement step in either order, wherein the first measurement step includes signaling the actuator to engender relative motion between the support mechanism and the target substance to the first position and subsequently storing in memory a first value corresponding to a first signal received from the light detector; and wherein the second measurement step includes signaling the actuator to engender relative motion between the support mechanism and the target substance to the second position and subsequently storing in memory a second value corresponding to a second signal received from the light detector. Further, one may additionally perform the step of: computing a ratio of the first value and the second value.
A further understanding of the functional and advantageous aspects of the present invention can be realized by reference to the following detailed description and drawings.
The invention will be more fully understood from the following detailed description thereof taken in connection with the accompanying drawings, which form a part of this application, and in which:
Without limitation, the majority of the systems described herein are directed to an apparatus and method of measuring optical properties of water. As required, embodiments of the present invention are disclosed herein. However, the disclosed embodiments are merely exemplary, and it should be understood that the invention may be embodied in many various and alternative forms.
The figures are not to scale and some features may be exaggerated or minimized to show details of particular elements while related elements may have been eliminated to prevent obscuring novel aspects. Therefore, specific structural and functional details disclosed herein are not to be interpreted as limiting but merely as a basis for the claims and as a representative basis for teaching one skilled in the art to variously employ the present invention. For purposes of teaching and not limitation, the illustrated embodiments are directed to real-time industrial and municipal water and liquid quality monitoring.
As used herein, the term “about” or “approximately”, when used in conjunction with ranges of dimensions, temperatures or other physical properties or characteristics is meant to cover slight variations that may exist in the upper and lower limits of the ranges of dimensions as to not exclude embodiments where on average most of the dimensions are satisfied but where statistically dimensions may exist outside this region. For example, in embodiments of the present invention dimensions of components of an apparatus and method of measuring optical properties of water are given but it will be understood that these are non-limiting.
As used herein, the coordinating conjunction “and/or” is meant to be a selection between a logical disjunction and a logical conjunction of the adjacent words, phrases, or clauses. Specifically, the phrase “X and/or Y” is meant to be interpreted as “one or both of X and Y” wherein X and Y are any word, phrase, or clause.
As used herein, the term “fluid” refers to any liquid, gas, or substance that continually deforms under an applied shear stress.
As used herein, the term “light” refers to any electromagnetic radiation, and is not limited to wavelengths of visible light. For example, “light” may refer to radio waves, microwaves, infrared radiation, visible light, ultraviolet radiation, X-rays, or gamma rays.
Referring to
Generally speaking, a preferred embodiment of the present invention operates by comparing the transmittance of light through a test substance to the transmittance of light in the ambient environment. In a preferred embodiment, the test substance is a liquid, though the test substance may be any substance of interest. Referring to
When test substance is a fluid, apparatus 100 preferably includes structure 4 which surrounds test substance 7 and is designed to allow light to transmit through both structure 4 and test substance 7. As shown in
As shown in
Microprocessor 12 is connected to both actuator 11 and light detector 6. Microprocessor 12 synchronizes the movement of the moveable support mechanism 10 via the actuator 11 with the sampling of the signal produced by light detector 6. When apparatus 100 is undergoing normal operation, the microprocessor 12 first signals actuator 11 to move moveable support mechanism 10 into the first position (
Additionally, computed ratios for liquids containing known levels of light transmittance may be stored in memory. This allows future ratios of liquids containing unknown levels of light absorbing matter to be compared with the stored values to allow correlations between the measured transmittance of light through the test substance and the actual level of light absorbing matter in the test substance.
It will be appreciated that windowed apertures 5 could be designed such that these apertures help to direct the light through the structure in a narrow beam for the purpose of reducing stray light. Further, a lens (not shown) transparent to a desired wavelength of light could be fixed in front of light source 3 to focus the light into a narrow beam towards the light detector 6 with a purpose of reducing stray light. Further, a lens transparent to a wavelength of light could be positioned in the light path 9 in front of the light detector 6 in order to collect and focus the light that is transmitted from light source 3.
Those skilled in the art will appreciate that light source 3 may be any source of electromagnetic radiation emitting any range of wavelengths, including but not limited to a mercury lamp, a deuterium lamp, a xenon lamp, a tungsten lamp, a halogen lamp, and an LED light source. Light detector 6 may be any electromagnetic radiation detector capable of detecting an intensity of light of the wavelength or set of wavelengths that can be transmitted by the type of matter in the test substance 7, such as a solid state light detector. Preferably, light source 3 and light detector 6 are connected to microprocessor 12 via conductive wires; though they may be connected with other means such wireless receiver and transmitter.
It is often desirable to emit specific wavelengths from light source 3 by either filtering the light output (filter not shown) or by using a plurality of light sources, each emitting set wavelengths of light, collectively forming a light source. These specific wavelengths can be any arbitrary preselected wavelength spectrum, or can be a narrow band of wavelengths. Further, it is often desirable to have the light source 3 emit different light wavelength spectra at different times, which can be controlled by the microcontroller 12. In this configuration, it is further desirable to have the detector be able to resolve the intensity of the different wavelength components of the incoming light signal, i.e. an intensity spectrum. Given such a detector that can resolve the range of wavelengths of light into substantially individual wavelengths of light, a light transmittance spectrum can be calculated.
The accuracy and range of the apparatus is directly affected by the length of light path 9 the thickness of test substance 7. The distance between the windowed apertures 5 can be any distance in theory, though practical constraints limit this distance to be generally but not limited to between about 1 mm and about 600 mm. A longer light transmittance distance through the test substance can improve performance when measuring the light transmittance of liquid with high purity, yet this can decrease performance when measuring the light transmittance of liquid with low purity. A shorter light transmittance distance through the test substance can reduce performance when measuring the light transmittance of liquid with high purity, yet this can increase performance when measuring the light transmittance of liquid with low purity. The final computed light transmittance value can be scaled in software to provide a measurement relative to a particular light transmittance distance through the test substance.
The structure 4 can be a flow cell including an influent or inlet port and an effluent or outlet port to allow the test substance 7 to flow through the structure 4 at a particular flow rate via tubing designed to carry the test substance 7 to and from the structure 4. Alternatively, the structure 4 can be part of the external walls of the apparatus such that the test substance 7 surrounds the apparatus and is able to freely flow between the opposed windowed apertures 5 embedded in the structure 4 (
Those skilled in the art would appreciate that actuator 11 may be any device that engenders relative motion between moveable support mechanism 10 and test substance 7. Some non-limiting examples include: linear solenoid, linear stepper actuator, stepper motor, servo motor, rack and pinion connected to a DC motor, and cam mechanism connected to a DC motor. Actuator 11 can make use of absolute or relative positioning techniques. For example, if a stepper motor is used the positions can be determined by counting the number of steps from one position to the next and recording this by microprocessor 12. Alternatively, if the actuator 11 is a simple DC motor, the microprocessor 12 may make use of additional sensors such as photodiodes or micro-switches to allow signals to be produced when the moveable support mechanism 10 reaches a particular position. The actuator may also make use of mechanical stops to allow proper positioning of the moveable support mechanism 10.
When the light source 3 is first turned on it is allowed to reach a stable operating output characterized by a manageable amount of light intensity drift over time, as measured by the light detector 6, before normal operation is begun. Microprocessor 12 can be programmed to determine when the intensity of light from of light source 3 has become stable enough by measuring and comparing the light source intensity using the light detector 6 at predetermined time intervals.
The accuracy of light detector 6 readings, whether they measure light source intensity directly or the amount of light transmitted through the test substance 7, can be improved by using signal conditioning electronics and/or by using various software averaging algorithms. In the preferred embodiment of the invention, signal conditioning electronics is used to improve light detector 6 reading accuracy. Such signal conditioning electronics include but are not limited to trans-impedance amplifiers, signal gain amplifiers, and analog to digital converters (ADCs).
Software running on microprocessor 12 can be implemented to average sample sets read from the light detector 6, thereby smoothing out the measured signal. This can further improve the accuracy and increase the signal to noise ratio.
For applications desiring the light absorbance of the test substance 7, the microprocessor 12 can calculate the light absorbance by evaluating a negative logarithm of the measured light transmittance.
The apparatus may be configured to further include a second light detector to measure the light intensity of light source 3 directly at all times. The purpose of the second light detector is to allow the microprocessor 12 to correct for changes in light intensity that occur between the times when the light detector 6 is read in first position 1 and in second position 2. This allows the device to automatically correct for any light source intensity fluctuations that occur during this short interval.
Another way to reduce errors caused by changes in light source output that occur between the times when the light detector 6 is read in first position 1 and in second position 2, is to use a software trending algorithm. Microprocessor 12 may use a software trending algorithm to allow the light source intensity to be approximately predicted from previous readings from the light detector 6, in the attempt to predict and therefore correct for any changes in light source intensity that occur during this short interval.
Such a trending algorithm may be a linear trend, which computes the average local rate of change and assumes that the local rate of change is constant. An alternative trending algorithm is polynomial interpolation where software running on microprocessor 12 fits a polynomial to past data points and evaluates the polynomial to estimate present and future data points. A further possible trending algorithm is evaluation of a statistical model where past data points form the basis for calibration of the statistical model. Those skilled in the art will appreciate that there are other algorithms for processing the signals received from light detector 6. The above examples are not intended to exclude other signal processing methods.
A further embodiment of the present invention is shown in
Referring to
It would be appreciated by those skilled in the art that other embodiments of the present invention may be used. For example, the actuator 11 may move structure 4 instead of the support mechanism 10, thereby achieving the same relative motion as illustrated in
As used herein, the terms “comprises”, “comprising”, “including” and “includes” are to be construed as being inclusive and open ended, and not exclusive. Specifically, when used in this specification including claims, the terms “comprises”, “comprising”, “including” and “includes” and variations thereof mean the specified features, steps or components are included. These terms are not to be interpreted to exclude the presence of other features, steps, or components.
The foregoing description of the preferred embodiments of the invention has been presented to illustrate the principles of the invention and not to limit the invention to the particular embodiment illustrated. It is intended that the scope of the invention be defined by all of the embodiments encompassed within the following claims and their equivalents.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/CA10/01061 | 6/29/2010 | WO | 00 | 3/19/2012 |
Number | Date | Country | |
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61221458 | Jun 2009 | US |