1. Field of the Invention
Embodiments of the invention generally relate to apparatus and methods for processing semiconductor substrates. More particularly, embodiments of the present invention relate to apparatus and methods for processing a substrate near an edge region.
2. Description of the Related Art
During a chemical vapor deposition (CVD) or plasma enhanced chemical vapor deposition (PECVD), it is desirable to have a uniform thickness profile across a substrate and no deposition near an edge area of the substrate. The area near the edge where deposition is not desired is generally referred to as the “edge exclusion.”
To prevent the formation of the deposition film at the edge of the substrate,
While the use of the shadow ring 105 can currently achieve thickness uniformity up to a 3.5 mm-wide edge exclusion area, the requirement for thickness non-uniformity has to be reduced to a 2 mm-wide edge exclusion area owing to increasingly shrinking device dimensions. As a result of the smaller edge exclusion area, the conventional approach using the shadow ring 105 to prevent deposition at the edge area may not provide satisfactory result.
Therefore, there is a need for an apparatus and method that can provide a desired profile of deposition film at the substrate edge region without using a shadow ring, and at least overcome the issues addressed above.
The present application describes apparatuses and methods for processing a substrate edge region. In one embodiment, an apparatus adapted for etching at a substrate edge region is disclosed. The apparatus comprises a chamber body having a process volume, a substrate support arranged inside the process volume and having a substrate support surface, a plasma generator configured to supply an etching agent in a plasma phase to a peripheral region of the substrate support surface, and a gas delivery assembly coupled to a gas source for generating a radial gas flow over the substrate support surface from an approximately central region of the substrate support surface toward the peripheral region of the substrate support surface.
In another embodiment, a method of etching at a substrate edge region is disclosed. The method comprises placing a substrate on a substrate support inside a process chamber, wherein the substrate has a top surface, a central region and an edge region, providing an etching agent in a plasma phase at the edge region of the substrate, and forming a radial gas flow on the top surface of the substrate from the central region toward the edge region.
So that the manner in which the above recited features of the present invention can be understood in detail, a more particular description of the invention, briefly summarized above, may be had by reference to embodiments, some of which are illustrated in the appended drawings. It is to be noted, however, that the appended drawings illustrate only typical embodiments of this invention and are therefore not to be considered limiting of its scope, for the invention may admit to other equally effective embodiments.
To facilitate understanding, identical reference numerals have been used, where possible, to designate identical elements that are common to the figures. It is contemplated that elements disclosed in one embodiment may be beneficially utilized on other embodiments without specific recitation.
Embodiments described herein relate to an apparatus and method for processing a substrate edge region that are applicable for various chamber systems configured to process a substrate. Examples of chamber systems include, without limitations, loadlock chambers, testing chambers, deposition chambers, etching chambers, and thermal treatment chambers.
A substrate support assembly 230 may be centrally disposed within the process chamber 202. In one embodiment, the support assembly 230 may be temperature controlled. The support assembly 230 may support a substrate 220 during processing. In one embodiment, the support assembly 230 comprises a support base 232 made of aluminum that may encapsulate at least one embedded heater 234 operable to controllably heat the support assembly 230 and the substrate 220 positioned thereon to a predetermined temperature. In one embodiment, the support assembly 230 may operate to maintain the substrate 220 at a temperature between about 150 degrees Celsius to about 1000 degrees Celsius, depending on the processing parameters for the material being processed.
The support base 232 may have an upper side 236A and a lower side 236B. The upper side 236A that supports the substrate 220 has a surface area smaller than the substrate 220, so that a peripheral edge region of the substrate 220 remains free of contact with the support base 232 to facilitate its processing, such as etching, or cleaning. The lower side 236B may have a stem 238 coupled thereto. The stem 238 couples the support assembly 230 to a lift system 240 that moves the support assembly 230 vertically between an elevated processing position and a lowered position that facilitates substrate transfer to and from the process chamber 202. The stem 238 additionally provides a conduit for electrical and thermocouple leads between the support assembly 230 and other components of the system 200. A bellows 242 may be coupled between the stem 238 and the bottom 214 of the process chamber 202. The bellows 242 provides a vacuum seal between the process volume 216 and the atmosphere outside the process chamber 202 while facilitating vertical movement of the support assembly 230.
To facilitate the transfer of the substrate 220, the support base 232 also includes a plurality of openings 246 through which lift pins 248 are movably mounted. The lift pins 248 are operable to move between a first position and a second position. The first position, shown in
The support assembly 230 may also comprise a centering mechanism 260 operable to center the substrate 220 relative to a vertical reference axis Z perpendicular to the substrate support plane of the support base 232. The centering mechanism 260 comprises three or more movable centering fingers 262 positioned at a periphery of the support base 232, and an opposing plate 264 placed below the fingers 262. Each finger 262 is pivotally mounted on the support base 232 via a shaft 266. The opposing plate 264 and the support base 232 are relatively movable so that the opposing plate 264 may contact and pivot the fingers 262 in a release position and stay free from the fingers 262 in a centering position.
In one embodiment, the opposing plate 264 may be stationary and the relative movement between the support base 232 and the opposing plate 264 is due to the vertical movement of the support base 232. The fingers 262 engage on the peripheral edge of the substrate 220 to center the substrate 220 when the support assembly 230 is in an elevated position as shown in
The lid assembly 222 provides an upper boundary to the process volume 216. The lid assembly 222 may be removed or opened to service the process chamber 202. In one embodiment, the lid assembly 222 may be fabricated from aluminum.
A gas delivery assembly 270 is coupled to an interior side of the lid assembly 222. The gas delivery assembly 270 includes a gas bowl 272 that has an outer wall 274, inner wall 276 and bottom 278. The shape of the bottom 278 may be configured to substantially follow the profile of the substrate 220. The gas bowl 272 includes a first gas distribution circuit coupled to the first entry port 206, and a second gas distribution circuit coupled to the second entry port 210.
The first gas distribution circuit includes a plenum 280A partially delimited between the outer wall 274, inner wall 276 and bottom 278, and a plurality of slits 282 formed through a peripheral region of the bottom 278 and connected to the plenum 280A. In one embodiment, the slits 282 may be angled outwards to avoid gas flow toward a center portion of the substrate.
The second gas distribution circuit includes a gas conduit 280B that is delimited by the inner walls 276 and has an end opened to a central region of the process volume 216. The gas flow provided along the second gas distribution circuit is configured from center to edge to protect unprocessed region.
To remove a portion of a deposition film at an edge region of the substrate 220, the remote plasma source 204 provides an etching agent in a plasma phase that flows into the plenum 280A via the first entry port 206, and applied on the edge region of the substrate 220 through the slits 282. The etching agent may be selectively chosen according to the material of the deposition film to etch. Examples of etching agents may include, without limitation, ionized NF3, O2, F2, or SF6. To prevent the diffusion of the etching agent toward a central region of the substrate 220, the purge gas source 208 provides an inert gas that enters the process volume 216 via the second entry port 210 and gas conduit 280B, and then flows radially on the top surface of the substrate 220 from its central region toward its peripheral edge region. Suitable inert gases may include, without limitation, Ar or He. The radial flow of the inert gas acts to limit the action area of the etching agent to the peripheral region of the substrate 220.
A person skilled in the art will appreciate that various embodiments may be implemented for the gas bowl 272.
Though the foregoing illustrates an implementation in which a remote plasma source is externally coupled to the process chamber, alternate embodiments may integrate a plasma generator in the process chamber. More specifically, some variant embodiments may define a plasma volume inside the process chamber, but away from the substrate edge. The plasma volume receives a flow of processing gas, which is excited as it passes between ground and RF electrodes placed in the plasma volume. In other embodiments, the plasma may be struck in-situ at the substrate edge region, where an RF electrode is placed adjacent to the peripheral area of the substrate support used as ground electrode. More details of the embodiments integrating a plasma generator in the process chamber are described below in conjunction with
Like the embodiment shown in
A gas delivery assembly 360 is coupled to an interior side of the lid assembly 322. The gas delivery assembly 360 includes a gas bowl 362 that is connected to a switchable power source 364 operable to selectively apply various potential biases to the gas bowl 362, including an RF potential bias, DC potential bias, AC potential bias, or a ground potential.
The gas bowl 362 has an outer wall 365, an inner wall 366 and a bottom 368. The shape of the bottom 368 may be configured to substantially follow the profile of the substrate 320 that rests between the support assembly 330 and the gas delivery assembly 360. The gas bowl 362 includes a first gas distribution circuit coupled to the first entry port 306, and a second gas distribution circuit coupled to the second entry port 310.
The first gas distribution circuit includes a plasma generation volume 370A partially delimited between the outer wall 365, inner wall 366 and a peripheral portion of the bottom 368, and a plurality of slits 372 formed through the peripheral portion of the bottom 368 and connected to the plasma generation volume 370A. The plasma generation volume 370A, which is connected to the first entry port 306, includes an electrode 373 that is coupled to a RF power source 375. The electrode 373 is sandwiched between isolator materials 377, and has an exposed surface 380 that is spaced apart from a facing inner side 382 of the outer wall 365. The outer wall 356 serves as a counter electrode to the electrode 373 during plasma generation. The distance between the counter electrode and the electrode 373 varies at different locations which make it easy to strike a plasma therebetween.
The second gas distribution circuit includes a plenum 370B that is surrounded by the plasma generation volume 370A. The plenum 370B, which is connected to the second entry port 310, is partially delimited between the inner wall 366 and a perforated portion 384 of the bottom 368. The perforated portion 384 includes a plurality of apertures 386 through which gases received in the plenum 370B flow into the process volume 316.
In a PECVD mode of operation, the plenum 370B receives a process gas from the deposition gas source 311, and the substrate 320 is heated. While the support assembly 330 is grounded, the switchable power source 364 applies an RF potential bias to the gas bowl 362, such as the bottom 368, such that a plasma is generated from the process gas present in the process volume 316 between the support assembly 330 and the gas delivery assembly 360. The entire substrate is exposed to the plasma and being processed, for example a film may be deposited on the substrate. The RF power from the switchable power source 364, the composition of the process gas, and the thermal conditions applied to the substrate 320 may be set in accordance with the type of deposition film to form on the substrate 320.
In one embodiment, the deposition film may include an advanced patterning film (“APF”) including amorphous carbon. The APF may be deposited at a substrate temperature between about 200° C. and 1500° C., while a process gas including propylene (C3H6) as carbon source is introduced in the process volume 316. Optionally, the process gas may include additional chemical elements to include in the APF, such as a nitrogen (N2) and doping elements. RF power from about 500 W to about 1500 W may be applied in the chamber at a frequency of about 13.56 MHz. A more detailed description of conditions for forming the APF by PECVD and its use is described in U.S. Pat. No. 7,262,106, entitled “Absorber Layer for DSA Processing”, which is incorporated herein by reference.
Once the formation of the deposition film is completed, the etching function may be used to remove undesirable portions of the deposition film in the edge region of the substrate 320. In an edge processing mode of operation, the plasma generation volume 370A receives an etching gas from the etching gas source 304 via the first entry port 306. In the meantime, the gas bowl 362 may be grounded,such that RF power supplied by the RF power source 375 to the electrode 373 excites the etching gas present in the plasma generation volume 370A between the exposed surface 380 of the electrode 373 and the inner side 382 of the outer wall 365. To facilitate the ionization of the etching gas, the inner side 382 may include a slant portion 388 that is inclined relative to the exposed surface 380 of the electrode 373. An etching agent in a plasma phase is thereby formed from the etching gas in the plasma generation volume 370A. The etching agent then is flowed via the slits 372 into the process volume 316 to etch a portion of the deposition film at the peripheral edge region of the substrate 320.
In one embodiment, a bias potential may be applied to the counter electrode, i.e. the gas bowl 362 with a DC or AC potential bias from the switchable power 364. By adjusting the bias potential, the bombarding strength of the plasma may be adjusted to a desirable level. In another embodiment, the support assembly 330 may be biased with a DC or AC potential to adjust the bombarding strength of the plasma.
While the etching agent is delivered via the slits 372, the plenum 370B receives a purge gas from the purge gas source 308, which may include any inert gases such as Ar or He. The purge gas enters the process volume 316 through the apertures 386, and then flows radially on the top surface of the substrate 320 toward its peripheral edge region to limit the diffusion of the etching agent supplied via the slits 372.
While the examples shown in
The gas delivery assembly 430 includes a gas bowl 442 that has an outer wall 444, inner wall 446 and a bottom 448. The gas bowl 442 is coupled to a switchable power source 443. The shape of the bottom 448 may be configured to substantially follow the profile of the substrate 434. The gas bowl 442 includes a first gas distribution circuit coupled to the first entry port 406, and a second gas distribution circuit coupled to the second entry port 410.
The first gas distribution circuit includes a plenum 450A partially delimited between the outer wall 444, inner wall 446 and the bottom 448, and a plurality of slits 452 formed through a peripheral region of the bottom 448 and connected to the plenum 450A.
The second gas distribution circuit includes a gas conduit 450B that is surrounded by the inner wall 446 and has an end opened approximately at a central region of the process volume 416.
The plasma generator includes an electrode 460 sandwiched between isolator materials 462, which are arranged adjacent to the outer wall 444 of the gas bowl 442. The electrode 460 is coupled to a RF power source 464, and includes a slant end 466 positioned proximate to the outer wall 444 and a peripheral portion of the support base 432.
In an etching mode of operation, the etching gas source 404 provides an etching gas that flows through the first entry port 406 into the plenum 450A, and then passes through the slits 452 into the peripheral region of the process volume 416 where the slant end 466 of the electrode 460 is positioned. In the meantime, the gas bowl 442 and the support base 432 are grounded or applied with an AC or DC potential bias, such that RF power applied to the electrode 460 excites the etching gas present between the slant end 466, the support base 432 and the gas bowl 442. An etching agent in a plasma phase is thereby formed in the vicinity of the edge region of the substrate 434.
To prevent the diffusion of the etching agent toward the central region of the substrate 434, the purge gas source 408 provides an inert gas that is delivered along the gas conduit 450B, and flows radially on the top surface of the substrate 434 from its central region toward its peripheral edge region. The radial flow of the inert gas allows to limit the action area of the etching agent to the peripheral region of the substrate 434.
To prevent the diffusion of the etching agent toward a central region of the substrate 434, the purge gas source 408 provides an inert gas that enters a central region of the process volume 416 via the second entry port 410 and aligned holes 498 formed through the upper and lower plate 484 and 486, and then flows radially on the top surface of the substrate 434 from its central region toward its peripheral region. The radial flow of the inert gas allows to limit the action area of the etching agent to the peripheral region of the substrate 434.
As has been described above, the apparatus and method provided herein are thus able to process an edge region of a substrate, for example etching a deposition film on a substrate edge region in an effective manner, without using a shadow ring.
The apparatus and method for processing an edge region may be used in stand alone edge processing chambers, incorporated with a processing chamber that capable of process the entire substrate, or incorporated in other chambers, such as a load lock chamber.
While the foregoing is directed to certain embodiments of the present invention, other and further embodiments of the invention may be devised without departing from the basic scope thereof, and the scope thereof is determined by the claims that follow.
This application claims benefit of U.S. Provisional Patent Application Ser. No. 60/949,397 (Attorney Docket No. 011997L), filed Jul. 12, 2007, U.S. Provisional Patent Application Ser. No. 60/982,961 (Attorney Docket No. 011997L02), filed Oct. 26, 2007, and U.S. Provisional Patent Application Ser. No. 60/982,993 (Attorney Docket No. 011997L03), filed Oct. 26, 2007. Each of the aforementioned patent applications is herein incorporated by reference.
Number | Date | Country | |
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60949397 | Jul 2007 | US | |
60982961 | Oct 2007 | US | |
60982993 | Oct 2007 | US |