Azo moiety containing metal complexes in toners

Abstract

A symmetric 2:1 metal complex represented by the general formula: ##STR1## where R is a hydrogen atom, an alkyl group having from 1 to 10 carbon atoms, an alkoxy group having from 1 to 4 carbon atoms, an alkoxycarbonyl group having from 2 to 5 carbon atoms, an acyl group having from 2 to 5 carbon atoms, an aminocarbonyl group, an alklyaminocarbonyl group having from 2 to 5 carbon atoms, an alkylsulfonyl group having from 1 to 3 carbon atoms, an aminosulfonyl group, an acylamino group having from 2 to 5 carbon atoms, a nitro group, a cyano group or a halogen atom, m is an integer of from 1 to 4, when m is 2 or more, the plurality of R may be the same or different substituents, Q is --NHCO--Y--Z or --CONH--Y--Z (where Y is an alkylene group having from 1 to 4 carbon atoms, and Z is a quaternary ammonium group), M is a chromium atom or a cobalt atom, and X.sup..crclbar. is an anion.

Description

The present invention relates to a metal complex and an electrophotographic toner containing the metal complex.

In electrophotography, it is common to employ a method which comprises forming an electrostatic latent image on a photoconductor made of e.g. a photoconductive material, then developing the latent image with a powder developer to form a visible image, and further fixing the image by heat or a solvent.

As the developer for such electrophotography, it is common to use a mixture comprising fine powder composed of a resin and a coloring agent, which is generally called a toner, and fine glass beads or iron powder, which is generally called a carrier.

The present invention relates to this developing powder called a toner and a novel metal complex useful for the toner.

A photoconductive layer can be positively or negatively charged, and a positively or negatively charged electrostatic latent image can be formed in the photoconductive layer by exposing it with an original overlaid thereon. When a negatively charged electrostatic latent image is developed with a positively charged toner, a positive-positive image corresponding to the original will be formed. However, when a positively charged electrostatic latent image is developed with a negatively charged toner, a negative image of the original, i.e. a positive-negative image, where the black and white tones are reversed, will be obtained. Thus, as electrophotographic toners, there are two types of toners, i.e. one being a positively charged toner and the other being a negatively charged toner.

The present invention relates to a positively chargeable toner.

In general, such a toner is fine powder obtained by mixing a coloring agent such as a dyestuff or a pigment, to a synthetic resin.

In order to positively charge the toner, the electrostatic characteristics of the dyestuff play an important role so that the dyestuff serves not only as a coloring agent but also as an electric charge-controlling agent.

As a positive charge-controlling agent, basic dyestuffs such as Nigrosine have been employed. However, the conventional dyestuffs such as Nigrosine have drawbacks such that there is a substantial variation in the electric chargeability among production lots, and when formed into a toner the durability of the toner for continuous repeated use for photocopying is not good.

The present inventors have conducted extensive researches to solve the above problems, and have found certain metal complexes having a positive charge-controlling ability and good compatibility with resins. It is thereby possible to obtain excellent toners free from the above-mentioned problems.

Namely, the present invention provides a symmetric 2:1 metal complex represented by the general formula: ##STR2## where R is a hydrogen atom, an alkyl group having from 1 to 10 carbon atoms, an alkoxy group having from 1 to 4 carbon atoms, an alkoxycarbonyl group having from 2 to 5 carbon atoms, an acyl group having from 2 to 5 carbon atoms, an aminocarbonyl group, an alkylaminocarbonyl group having from 2 to 5 carbon atoms, an alkylsulfonyl group having from 1 to 3 carbon atoms, an aminosulfonyl group, an acylamino group having from 2 to 5 carbon atoms, a nitro group, a cyano group or a halogen atom, m is an integer of from 1 to 4, when m is 2 or more, the plurality of R may be the same or different substituents, Q is --NHCO--Y--Z or --CONH--Y--Z (where Y is an alkylene group having from 1 to 4 carbon atoms, and Z is a quaternary ammonium group), M is a chromium atom or a cobalt atom, and X.sup..crclbar. is an anion.

The present invention also provides an electrophotographic toner containing the metal complex of the formula I as an electric charge-controlling agent or a coloring agent.

Now, the present invention will be described in detail with reference to the preferred embodiments.

The metal complex of the formula I of the present invention may be prepared in good yield by diazotizing a diazo component represented by the general formula: ##STR3## where R and m are as defined above, by a conventional method, then coupling the resulting diazo compound with a coupling component represented by the general formula: ##STR4## where X.sup..crclbar. and Q are as defined above, by a conventional method, to obtain a monoazo compound represented by the general formula: ##STR5## where R, m, X.sup..crclbar. and Q are as defined above, and then heat-treating this monoazo compound with a chromium-introducing agent or a cobalt-introducing agent in water or in an organic solvent by a conventional method. As the diazo component of the formula II which may be used in the present invention, there may be mentioned, for instance, 3-chloro-2-aminophenol, 4-chloro-2-aminophenol, 4-bromo-2-aminophenol, 5-bromo-2-aminophenol, 4-iodo-2-aminophenol, 3,5-dichloro-2-aminophenol, 4,6-dichloro-2-aminophenol, 3,4,6-trichloro-2-aminophenol, 4-nitro-2-aminophenol, 5-nitro-2-aminophenol, 6-chloro-4-nitro-2-aminophenol, 4-chloro-5-nitro-2-aminophenol, 4-chloro-6-nitro-2-aminophenol, 6-bromo-4-nitro-2-aminophenol, 4-methyl-2-aminophenol, 4-t-butyl-2-aminophenol, 4-t-octyl-2-aminophenol, 4,5-dimethyl-2-aminophenol, 4-methoxy-2-aminophenol, 4-methyl-5-nitro-2-aminophenol, 4-bromo-5-methyl-2-aminophenol, 4-cyano-2-aminophenol, 4-acetyl-2-aminophenol, 4-methoxycarbonyl-2-aminophenol, 4-aminocarbonyl-2-aminophenol, 4-ethylaminocarbonyl-2-aminophenol, 4-aminosulfonyl-2-aminophenol and 4-propylsulfonyl-2-aminophenol.

As the coupling component of the formula III where Q is --NHCO--Y--Z, there may be mentioned N,N,N-trimethyl-N-[N'-(7-hydroxy-1-naphthyl)carbamoyl]methylammonium chloride, N,N,N-trimethyl-N-[N'-(6-hydroxy-1-naphthyl)carbamoyl]methylammonium chloride, N,N,N-triethyl-N-[N'-(7-hydroxy-1-naphthyl)carbamoyl]methylammonium chloride, N,N-dimethyl-N-ethyl-N-[N'-(7-hydroxy-1-naphthyl)carbamoyl]methylammonium iodide, N,N-dimethyl-N-n-butyl-N-[N'-(7-hydroxy-1-naphthyl)carbamoyl]methylammonium bromide, N,N-dimethyl-N-n-butyl-N-[N'-(6-hydroxy-1-naphthyl)carbamoyl]methylammonium chloride, N,N,N-trimethyl-N-[N'-(7-hydroxy-1-naphthyl)carbamoyl]propylammonium chloride, N,N,N-trimethyl-N-[N'-(6-hydroxy-1-naphthyl)carbamoyl]propylammonium chloride, N,N-dimethyl-N-benzyl-N-[N'-(7-hydroxy-1-naphthyl)carbamoyl]methylammonium chloride, N-methyl-N-[N'-(7-hydroxy-1-naphthyl)carbamoyl]propylpiperidinium bromide, N-methyl-N-[N'-(7-hydroxy-1-naphthyl)carbamoyl]methylmorpholinium chloride, N-[N'-(7-hydroxy-1-naphthyl)carbamoyl]methylpyridinium chloride, and N-[N'-(6-hydroxy-1-naphthyl)carbamoyl]methylpyridinium chloride.

Further, as the coupling component of the formula III where Q is --CONH--Y--Z, there may be mentioned N,N,N-trimethyl-N-2-(3-hydroxy-2-naphthamido)ethylammonium chloride, N,N,N-triethyl-N-2-(3-hydroxy-2-naphthamido)ethylammonium chloride, N,N,N-trimethyl-N-3-(3-hydroxy-2-naphthamido)propylammonium bromide, N,N-dimethyl-N-ethyl-N-3-(3-hydroxy-2-naphthamido)propylammonium chloride, N,N,N-trimethyl-N-4-(3-hydroxy-2-naphthamido)butylammonium chloride, N,N-dibutyl-N-methyl-N-3-(3-hydroxy-2-naphthamido)propylammonium chloride, N-methyl-N-3-(3-hydroxy-2-naphthamido)propylpiperidinium bromide, N-methyl-N-3-(3-hydroxy-2-naphthamido)propylmorpholinium chloride and N-2-(3-hydroxy-2-naphthamido)ethylpyridinium chloride.

The metal complex of the formula I of the present invention thus obtained, has a positive chargeability and excellent compatibility with resins, for example, a polymer of styrene or a substituted styrene such as polystyrene or polyvinyl toluene, a styrene-substituted styrene copolymer, a styrene-acrylate copolymer, a styrene-methacrylate copolymer, a styrene-acrylonitrile copolymer, a polyvinyl chloride resin, a polyethylene, a silicone resin, a polyester, a polyurethane, a polyamide, an epoxy resin, a modified rosin or a phenol resin. Thus, the metal complex can uniformly be dispersed in such a resin and further pulverized into fine powder. Such a fine powder also has positive chargeability.

On the other hand, the metal complex of the present invention has little solubility in water, and scarcely affected by the environmental humidity, thus being capable of maintaining the positive chargeability for a long period of time.

In the formula I, X.sup..crclbar. is preferably a halogen ion such as a chlorine, bromine, fluorine or iodine ion.

The toner of the present invention may be prepared by melt-mixing from 1 to 50% by weight of the metal complex of the formula I with 50 to 99% by weight of a synthetic resin, and after the solidification, pulverizing the solidified product by means of a ball mill or other pulverizer. Alternatively, it may be prepared by adding a polymerization initiator to a synthetic resin monomer, incorporating from 1 to 50%, by weight of the monomer, of the metal complex of the formula I thereto, and polymerizing the mixture is a suspended state in water. Other coloring agents or carbon black may also be incorporated. The toner thus obtained will provide an electric charge in a quantity suitable for the development of an electrostatic image due to the friction with the carrier, whereby the quantity of the electric charge can be maintained at a constant level during repeated development operations. The distribution of the electric charge is uniform and can be maintained in a stabilized condition for a long period of time. Accordingly, an image developed by means of this toner, is uniform and has a constant image density, and it is very sharp as compared with the image where a conventional positive toner is used.

Now, the present invention will be described in further detail with reference to Examples. However, it should be understood that the present invention is by no means restricted by these specific Examples.

In the Examples, "parts" means "parts by weight".

EXAMPLE 1

14.4 Parts of 4-chloro-2-aminophenol was mixed with 26 parts of concentrated hydrochloric acid and 400 parts of water, and the mixture was cooled with ice to a temperature of from 0.degree. to 5.degree. C. After an addition of 6.9 parts of sodium nitrite, the mixture was stirred at the same temperature for 2 hours for diazotization. The diazo compound thus obtained was subjected to a coupling reaction by pouring it into a solution of a mixture comprising 300 parts of water, 10 parts of sodium hydroxide and 29.3 parts of N,N,N-trimethyl-N-[N'-(7-hydroxy-1-naphthyl)carbamoyl]methylammonium chloride at a temperature of from 0.degree. to 5.degree. C. Then, a monoazo compound having the following structure was isolated. ##STR6##

This monoazo compound was dissolved in 120 parts of ethylene glycol, and 17.4 parts of sodium chromium salicylate was added thereto. The mixture was stirred at a temperature of from 85.degree. to 90.degree. C. for a chromium-introducing reaction. Then, the mixture was cooled to 30.degree. C., and hydrochloric acid was added to acidify the mixture to an acidity confirmed by Congo Red. Then, the product was isolated at room temperature, and dried under reduced pressure at 50.degree. to 60.degree. C. to obtain 45 parts of chromium complex of the following formula as a blackish blue fine powder: ##STR7## The wavelength at the maximum absorption by this chromium complex was 581 nm as measured in a dimethylformamide solvent.

The coupling component used in this Example was prepared by chloroacetylating 8-amino-2-naphthol in glacial acetic acid with chloroacetic acid chloride by using sodium acetate as an acid binding agent, to obtain 8-chloroacetylamino-2-naphthol, dissolving isolated 8-chloroacetylamino-2-naphthol in acetone, and then blowing gaseous trimethylamine into the solution.

EXAMPLE 2

53.8 Parts of a monoazo dyestuff represented by the formula: ##STR8## obtained in the same manner as in Example 1, was dissolved in 200 parts of methyl cellosolve, and after an addition of 18.2 parts of sodium chromium salicylate, the mixture was stirred at a temperature of from 100.degree. to 105.degree. C. for 2 hours for a chromium-introducing reaction. Then, the mixture was cooled to 20.degree. C., and then treated in the same manner as in Example 1 to obtain 51.2 parts of a chromium complex of the following formula as a black powder: ##STR9##

The wavelength at the maximum absorption by this chromium complex was 594 nm as measured in a dimethylformamide solvent.

The coupling component used in this Example was readily prepared by heating 5-chloroacetylamino-2-naphthol in pyridine.

EXAMPLES 3 to 32

In the same manner as in Examples 1 and 2, symmetric 2:1 metal complexes were obtained. The structures, the wavelengths at the maximum absorption (in dimethylformamide) and outer appearance are shown in Table 1.

TABLE 1__________________________________________________________________________ Examples Monoazo compound ##STR10## metalCentral solventComplexing (nm)absorptionmaximumat theWavelength anceappear-Outer__________________________________________________________________________ ##STR11## B: CH.sub.2.sup..sym.N(CH.sub.3).sub.3Cl.sup..crclbar. 1 Cr Ethylene glycol 576 Black powder4 ##STR12## B: CH.sub.2.sup..sym.N(CH.sub.3).sub.3Cl.sup..crclbar. 3 Cr Dimethylformamide 583 Blackish purple powder5 ##STR13## B: CH.sub.2.sup..sym.N(C.sub.2 H.sub.5).sub.3Cl.sup..c rclbar. Cr Ethylene glycol 592 Black powder6 ##STR14## ##STR15## Cr Water 597 Blackish purple powder7 ##STR16## B: C.sub.2 H.sub.4.sup..sym.N(CH.sub.3).sub.3Cl.sup..c rclbar. Co Water 562 Black powder8 ##STR17## ##STR18## Cr Methyl cellosolve 585 Black powder9 ##STR19## B: CH.sub.2.sup..sym.N(CH.sub.3).sub.3Cl.sup..crclbar. Co n-Butanol 560 Black powder10 ##STR20## ##STR21## Cr Dimethyl sulfoxide 592 Black powder11 ##STR22## B: CH.sub.2.sup..sym.N(CH.sub.3).sub.3Cl.sup..crclbar. Cr Formamide Water 612 Black powder12 ##STR23## ##STR24## Cr Ethylene glycol 587 Blackish purple powder13 ##STR25## ##STR26## Cr Ethylene glycol 613 Black powder14 ##STR27## B: CH.sub.2.sup..sym.N(CH.sub.3).sub.3Cl.sup..crclbar. Cr Water Dimethylformamide 608 Black powder15 ##STR28## ##STR29## Cr Ethylene glycol 589 Black powder16 ##STR30## B: CH.sub.2.sup..sym.N(CH.sub.3).sub.3Cl.sup..crclbar. Cr Ethylene glycol 590 Blackish purple powder17 ##STR31## ##STR32## Cr Water 593 Blackish blue powder18 ##STR33## B: C.sub.3 H.sub.6.sup..sym.N(CH.sub.3).sub.3Cl.sup..c rclbar. Co Ethylene glycol 559 Blackish purple powder19 ##STR34## ##STR35## Cr Methyl cellosolve 592 Black powder20 ##STR36## B: CH.sub.2.sup. .sym.N(CH.sub.3).sub.3Cl.sup..crclbar . Cr Diethylene glycol 588 Blackish blue powder21 ##STR37## ##STR38## Cr Ethylene glycol 596 Blackish purple powder22 ##STR39## B: C.sub.4 H.sub.8.sup..sym.N(CH.sub.3).sub.3Br.sup..c rclbar. Cr Methyl cellosolve 592 Black powder23 ##STR40## B: CH.sub.2.sup..sym.N(CH.sub.3).sub.3Cl.sup..crclbar. Cr Triethanolamine 582 Black powder24 ##STR41## ##STR42## Cr n-Butanol 587 Blackish blue powder25 ##STR43## B: CH.sub.2.sup..sym.N(CH.sub.3).sub.3CH.sub.3 SO.sub.4.sup..crclbar. Cr Ethylene glycol 594 Black powder26 ##STR44## B: CH.sub.2.sup..sym.N(CH.sub.3).sub.3Cl.sup..crclbar. Cr Ethylene glycol 593 Black powder27 ##STR45## B: CH.sub.2.sup..sym.N(CH.sub.3).sub.3Cl.sup..crclbar. Cr n-Butanol 592 Black powder28 ##STR46## ##STR47## Cr Ethylene glycol 586 Blackish purple powder29 ##STR48## ##STR49## Cr Methyl cellosolve 590 Blackish blue powder30 ##STR50## B: CH.sub.2.sup..sym.N(CH.sub.3).sub.3I.sup..crclbar. Cr Methyl cellosolve 593 Black powder31 ##STR51## B: C.sub.3 H.sub.6.sup..sym.N(CH.sub.3).sub.3Cl.sup..c rclbar. Cr Ethylene glycol 585 Black powder32 ##STR52## B: CH.sub.2.sup..sym.N(C.sub.2 H.sub.5).sub. 3Br.sup..crclbar. Cr Dimethylformamide 616 Black powder__________________________________________________________________________

EXAMPLE 33

15.4 Parts of 5-nitro-2-aminophenol was mixed with 26 parts of concentrated hydrochloric acid and 250 parts of water, and the mixture was cooled with ice to a temperature of from 0.degree. to 5.degree. C. After an addition of 6.9 parts of sodium nitrite, the mixture was stirred at the same temperature for 1.5 hours for diazotization. The diazo compound thus obtained was subjected to a coupling reaction by pouring it into a solution comprising 400 parts of water, 10 parts of sodium hydroxide and 39.9 parts of N,N,N-trimethyl-N-3-(3-hydroxy-2-naphthamido)propylammonium methylsulfate at a temperature of from 0.degree. to 5.degree. C. Then, a monoazo compound represented by the formula: ##STR53## was isolated. This monoazo compound was dissolved in 150 parts of methyl cellosolve, and 17.5 parts of sodium chromium salicylate was added thereto. The mixture was stirred at from 90.degree. to 95.degree. C. for 2 hours for a chromium-introducing reaction. Then, the reaction mixture was cooled to 25.degree. C., and hydrochloric acid was added to acidify the mixture. Then, the product was isolated and dried under reduced pressure at a temperature of from 50.degree. to 60.degree. C. to obtain 56 parts of a chromium complex having the following formula as a blackish purple powder: ##STR54## The visible ray absorption spectrum of this chromium complex was measured in a dimethylformamide solvent, whereby the wavelength at the maximum absorption was 599 nm.

The coupling component used in this Example was obtained by reacting methyl 2-hydroxy-3-naphthoate with dimethylamino propylamine in toluene to obtain N,N-dimethyl-N-3-(3-hydroxy-2-naphthamido)propylamine, and converting the amide compound isolated by filtration, with dimethylsufuric acid in methanol, to a quaternary ammonium form. Further, the amide compound may also be readily prepared via 2-hydroxy-3-napthoic acid chloride.

EXAMPLE 34

62.8 Parts of a monoazo dyestuff of the formula: ##STR55## obtained in the same manner as in Example 33, was dissolved in 200 parts of dimethylformamide, and after an addition of 30.5 parts of chromium acetate (45% solution), the mixture was stirred at a temperature of from 100.degree. to 105.degree. C. for 3 hours for a chromium-introducing reaction. Then, the mixture was treated in the same manner as in Example 33 to obtain 54.3 parts of a chromium complex of the following formula as a blackish purple fine powder: ##STR56## The visible ray absorption spectrum of this chromium complex was measured in a dimethylformamide solvent, whereby the wavelength at the maximum absorption was 602 nm.

EXAMPLES 35 to 58

In the same manner as in Examples 33 and 34, metal complexes were prepared. The structures, the wavelengths at the maximum absorption and the outer appearances of these metal complexes are shown in Table 2.

TABLE 2__________________________________________________________________________ Examples Monoazo compound ##STR57## metalCentral Complexing solvent (nm)absorptionmaximuma t theWavelength anceappear-Oute r__________________________________________________________________________35 ##STR58## ##STR59## Cr Ethylene glycol 595 Black powder36 ##STR60## ##STR61## Cr Ethylene glycol 591 Blackish blue powder37 ##STR62## ##STR63## Cr Dimethylformamide 601 Blackish purple owder38 ##STR64## ##STR65## Cr Ethylene glycol 587 Black powder39 ##STR66## ##STR67## Cr Water Ethylene 598col Blackish blue powder40 ##STR68## ##STR69## Co Ethylene glycol 572 Blackish blue powder41 ##STR70## ##STR71## Cr n-Butanol 587 Black powder42 ##STR72## ##STR73## Cr Ethylene glycol 586 Black powder43 ##STR74## ##STR75## Cr Ethylene glycol 593 Blackish blue powder44 ##STR76## ##STR77## Co Methyl cellosolve 571 Blackish purple owder45 ##STR78## ##STR79## Cr n-Butanol 590 Black powder46 ##STR80## ##STR81## Cr Ethylene glycol 610 Black powder47 ##STR82## ##STR83## Cr Ethylene glycol 587 Black powder48 ##STR84## ##STR85## Cr Ethylene glycol 592 Blackish blue powder49 ##STR86## ##STR87## Cr Dimethylformamide 595 Blackish blue powder50 ##STR88## ##STR89## Co Triethanolamine 568 Blackish purple owder51 ##STR90## ##STR91## Cr Water 590 Black powder52 ##STR92## ##STR93## Cr Ethylene glycol 598 Black powder53 ##STR94## ##STR95## Cr Diethylene glycol 586 Blackish purple owder54 ##STR96## ##STR97## Cr Ethylene glycol 593 Black powder55 ##STR98## ##STR99## Cr Dimethylformamide 588 Black powder56 ##STR100## ##STR101## Cr Water 592 Black powder57 ##STR102## ##STR103## Cr Dimethylformamide 600 Black powder58 ##STR104## ##STR105## Cr Ethylene glycol 594 Blackish blue powder__________________________________________________________________________

Now, the following Application Examples are given to illustrate the toners of the present invention.

Application Example 1

To 5 parts of the chromium complex obtained in Example 1, 100 parts of a styrene-n-butyl methacrylate copolymer and 5 parts of carbon black were added and thoroughly mixed. Then, the mixture was kneaded while heating and melting it. After cooling, the mixture was roughly pulverized in a mixer, and then finely pulverized by a high speed centrifugal pulverizer to obtain a positively chargeable fine toner. The toner was mixed with iron powder having a particle size of from 100 to 150 .mu.m in a weight ratio of 5:100, and the mixture was used for a commercially available copying machine employing a zinc oxide photosensitive material, whereby a clear image free from fogging was obtained. The quantity of the electric charge of the toner was 22 .mu.c/g on an average as measured by a blow off method, and the electric charge distribution was substantially uniform at a level of from 22 to 23 .mu.c/g.

Application Examples 2 to 13

In the same manner as in Application Example 1, toners containing metal complexes and having compositions as identified in Table 3 were prepared. The electric chargeability of these toners was measured. The results are also shown in Table 3.

TABLE 3__________________________________________________________________________ Elec-Appli- triccation charge-Exam- Composition of the developer abiltyples Metal complex Other components (.mu.c/g)__________________________________________________________________________ ##STR106## Styrene-n-butyl methacrylate copolymer Carbon black Iron powder carrier 20 parts 1 part 500 parts 18.3 0.2 part3 ##STR107## Phenol resin Polyester resin Carbon black Iron powder carrier 12 parts 9 parts 1.5 parts 500 16.8s 0.5 part4 ##STR108## Polyethylene wax Ethylene-vinyl cetate copolymer Magnetite 50 parts 40 parts 50 17.3s 1 part5 ##STR109## Styrene-ethylhexyl methacrylate copolymer Polyester resin Silicone wax Carbon black Silicone resin-coated iron powder carrier 40 parts 5 parts 4 parts 0.1 part 700 parts 10.3 0.1 part6 ##STR110## Styrene-acryl copolymer Carbon black Glass beads 20 parts 2 parts 1000 parts 15.4 0.2 part7 ##STR111## Styrene-ethyl methacrylate copolymer Iron powder 100 parts 2000 parts 13.2 5 parts8 ##STR112## Styrene-butadiene copolymer Carbon black Iron powder carrier 50 parts 5 parts 1500 parts 18.9 2 parts9 ##STR113## Styrene-n-butyl methacrylate copolymer C.I. pigment blue-15 Iron powder carrier 12 parts 0.1 part 500 17.4s 0.5 part10 ##STR114## Polyester resin Carbon black Iron powder carrier 50 parts 5 parts 1500 parts 12.1 1 part11 ##STR115## Styrene-methyl acrylate copolymer C.I. pigment black 1 Iron powder carrier 50 parts 3 parts 1500 parts 12.8 1 part12 ##STR116## Epoxy resin Carbon black Iron powder carrier 30 parts 3 parts 1000 parts 11.1 0.5 part13 ##STR117## Polyvinyl butyral resin Carbon black Iron powder 10 parts 1 part 250 parts 14.2 0.5 part__________________________________________________________________________

Appliction Example 14

To 1 part of a chromium complex represented by the formula: ##STR118## 100 parts of a styrene-n-butyl methacrylate copolymer and 8 parts of carbon black were added and thoroughly mixed. The mixture was then kneaded while heating and melting it. After cooling, the mixture was roughly pulverized in a mixer, and then finely pulverized by a high speed centrifugal pulverizer to obtain a positively chargeable fine toner. The toner was mixed with iron powder having a particle size of from 100 to 150 .mu.m in a weight ratio of 5:100, and the mixture was used for a commercially available copying machine employing a zinc oxide photosensitive material, whereby a clear image free from fogging was obtained. The quantity of the electric charge of the toner was 17.5 .mu.c/g on an average as measured by a blow off method, and the electric charge distribution was substantially uniform at a level of from 17.0 to 18.3 .mu.c/g.

Application Examples 15 to 29

In the same manner as in Example 14, toners containing metal complexes and having compositions as identified in Table 4 were obtained. The electric chargeability of these toners were measured. The results are also shown in the Table 4.

TABLE 4__________________________________________________________________________ Elec-Appli- triccation charge-Exam- Composition of the developer abilityples Metal complex Other components (.mu.c/g)__________________________________________________________________________15 ##STR119## Styrene-ethyl- hexyl metha- crylate Polyester resin Silicone wax Carbon black Iron powder carrier 40 parts 5 parts 3 parts 2 parts 1000 parts 14.8 0.2 part16 ##STR120## Styrene-acryl copolymer Carbon black Glass beads carrier 30 parts 3 parts 1000 18.9s 0.5 part17 ##STR121## Styrene-methyl methacrylate copolymer Silicone resin- coated iron powder 50 parts 1500 16.3s 10 parts18 ##STR122## Polyvinyl butyral resin Carbon black Iron powder carrier 200 parts 10 parts 2000 17.4s 2 parts19 ##STR123## Bisphenol type epoxy resin Carbon black Iron powder carrier 50 parts 2 parts 1000 18.6s 0.5 part20 ##STR124## Styrene resin Carbon black Iron powder carrier 50 parts 2 parts 1000 14.0s 0.5 part21 ##STR125## Styrene-butyl methacrylate copolymer Carbon black Iron powder carrier 30 parts 2 parts 800 parts 15.0 0.2 part22 ##STR126## Phenol resin Polyester resin arbon black Silicon resin- coated iron powder 15 parts 8 parts 2 parts 700 21.3s 0.5 part23 ##STR127## Polyethylene wax Ethylene- vinyl acetate copolymer Magnetite 50 parts 40 parts 30 parts 18.5 1 part24 ##STR128## Styrene-ethyl- hexyl metha- acrylate copolymer Carbon black Ironpowder carrier 20 parts 1 part 600 parts 23.2 0.5 part25 ##STR129## Maleic acid resin Carbon black Iron 50 parts 5 parts 1000 16.4s 0.2 part26 ##STR130## Styrene-ethyl methacrylate copolymer Carbon black Iron powder carrier 30 parts 3 parts 500 parts 18.3 0.1 part27 ##STR131## Styrene-buta- diene co- polymer Carbon black Iron powder carrier 50 parts 5 parts 1500 16.7s 1 part28 ##STR132## Polyester resin C.I. pigment lue-15 Silicone resin- coated iron powder 12 parts 0.2 part 400 18.5s 0.4 part29 ##STR133## Styrene-butyl methacrylate copolymer Carbon black Iron powder carrier 100 parts 5 parts 300 17.2s 2 parts__________________________________________________________________________

Claims

1. A symmetric 2:1 metal complex represented by the general formula: ##STR134## where R is a hydrogen atom, an alkyl group having from 1 to 10 carbon atoms, an alkoxy group having from 1 to 4 carbon atoms, an alkoxycarbonyl group having from 2 to 5 carbon atoms, an acyl group having from 2 to 5 carbon atoms, an aminocarbonyl group, an alkylaminocarbonyl group having from 2 to 5 carbon atoms, an alkylsulfonyl group having from 1 to 3 carbon atoms, an aminosulfonyl group, an acylamino group having from 2 to 5 carbon atoms, a nitro group, a cyano group or a halogen atom, m is an integer of from 1 to 4, when m is 2 or more, the plurality of R may be the same or different substituents, Q is --NHCO--Y--Z or --CONH--Y--Z (where Y is an alkylene group having from 1 to 4 carbon atoms, and Z is a quaternary ammonium group), M is a chromium atom or a cobalt atom, and X.sup..crclbar. is an anion.

2. The metal complex according to claim 1, wherein X.sup..crclbar. is a halogen ion.

3. An electrophotographic toner containing from 1 to 50% by weight of the metal complex of the formula I as defined in claim 1, and from 50 to 99% by weight of a resin.

4. The electrophotographic toner according to claim 3, wherein the resin is a styrene polymer, a substituted styrene polymer, a styrene-substituted styrene copolymer, a styrene-acrylate copolymer, a styrene-methacrylate copolymer, a styrene-acrylonitrile copolymer, a polyvinyl chloride resin, a polyethylene resin, a silicone resin, a polyester resin, a polyurethane resin, a polyamide resin, an epoxy resin, a modified rosin or a phenol resin.