The invention relates to a battery element having at least one electrode stack, which is surrounded by an outer, electrical insulation and having at least one heat-conducting element.
Battery cells, in particular lithium-ion cells, are known, which, owing to their high energy density and their low weight, are regarded as advantageous cell types for use in motor vehicles. Such battery cells comprise stacked or folded electrochemically active layers which are separated from one another by nonwoven plastic separators in order to prevent short circuits.
Said electrode stacks are enclosed by a flexible outer film. This outer film is closed except for one edge and the film bag thus formed is filled with an organic electrolyte. The film bag is then closed and sealed, wherein contact tabs protrude from the film bag as connections of the electrodes. These battery cells do not have a rigid outer envelope, which makes them flexible but also sensitive to mechanical stresses.
From the German document DE 10 201 0 055 599 A1, it is known to clamp the flexible battery cells between two adjacent frames and to combine a plurality of such framed battery cells to form a battery module. Cooling plates are provided on the upper side of the battery module, said plates being in heat-conducting contact with the individual battery cells, namely with the end face thereof. When such battery cells are charged, in particular during rapid charging, heating occurs, as a result of which the electrolyte is heated and an excess pressure is produced in the battery cell. In the event of overheating, the electrolyte can evaporate and the battery cell can be destroyed. In the above-mentioned frames, oval openings for the pressure reduction in such short circuits are provided, so that the electrolyte vapor can escape. It is desirable to prevent such overheating.
The document DE 10 201 1 002 666 A1 describes the cooling of a pouch cell in an energy storage device. Here, during assembly, the each pouch cell is brought into heat-conducting contact with one cooling element on two opposite lateral surfaces. The heat generated in the pouch cell is transferred to the cooling elements by heat conduction and is then dissipated by a cooling fluid which flows through at least one flow channel of the respective cooling elements. The cooling elements are fastened to a carrier plate of the energy storage device at a predetermined distance by means of sliding shoes. Good heat dissipation is only achieved if the pouch cell is in contact with the two cooling bodies over a large area on both sides. Manufacturing tolerances can, however, result in air gaps being formed between the cooling elements and the pouch cell, said air gaps impairing the heat dissipation. The cooling elements shown are relatively thick and thus also have an undesirably high weight.
The document DE 10 201 1 107 716 A1 shows better cooling. A battery element is shown here, which has an insulation element on one side surface and a cooling element on the other side. The cooling element consists of two metal sheets with a polymer coating. A web structure, which can consist of aluminum or a polymer, is arranged between the metal sheets. In order to obtain a one-piece battery element having an integrated cooling element, the cooling element is flattened at its ends or is connected to the insulation element by means of an additional insulation body to form a jacket of the main body of the battery cell. The plurality of cooling passages ensures the dissipation of the heat generated in the battery cell. The multi-layer construction of the cooling element is disadvantageous.
The aim of the invention is to provide an improved battery element with more efficient cooling. The battery element is intended to be used in particular for battery modules of motor vehicles and should have as low a weight as possible for this purpose.
This object is achieved by a battery element having the features of claim 1. The dependent claims describe advantageous embodiments. The new battery element represents an improvement of the known pouch cell. In addition to one or more battery cells, in particular lithium-ion cells, a heat-conducting element in the form of one or more multi-chamber hollow profiles is also integrated in the battery element. This multi-chamber hollow profile serving for cooling or optionally also the heating of the battery cell is of flat design, has two opposite broad sides and, in the interior, a plurality of chambers which are arranged adjacent to one another and run parallel through the multi-chamber hollow profile. A temperature-control medium flows through the chambers, for example for cooling a cooling liquid, a coolant or gaseous media, such as, for example, air in order to transport away the heat generated in the battery cell. A cooling of the battery cell is described below. Even if the multi-chamber hollow profile can also serve to heat the battery cell, the heat transport is optimal, since a wide side surface of the multi-chamber hollow profile is in planar contact with the side surface of at least one insulated electrode stack of a battery cell. For the sake of simplicity, the term electrode stack is subsequently used for the inner components of the battery cell, namely the two electrodes with the separators and the electrolyte. The two electrodes can be flat or can be folded several times.
For example, an electrode stack is located on the upper side and a further electrode stack lies flat against the underside of the multi-chamber hollow profile. In this case, the multi-chamber hollow profile is integrated centrally between the two electrode stacks in the battery element.
In an advantageous embodiment, a side wall of the multi-chamber hollow profile forms a wall of the battery cell, i.e. the multi-chamber hollow profile and an outer sealable film together enclose an electrode stack with the separators and the electrolyte. The multi-chamber hollow profile has an electrically insulating plastic coating for the connection to the sealable film. Owing to this electrically insulating plastic coating, the multi-chamber hollow profile is, on the one hand, electrically insulated with respect to the electrode stack and, on the other hand, this coating, consisting of thermoplastic plastics, on the outer surface of the multi-chamber hollow profile allows a connection to the sealable film covering the electrode stack in the provided connection regions. For such a connection of the film to the multi-chamber hollow profile, the latter is preferably of such a width that connecting regions can be provided on the longitudinal edges of the multi-chamber hollow profile. Since the longitudinal edges of the multi-chamber hollow profile are loaded by pressure forces and heat during such a sealing operation, no chambers are provided at these longitudinal edges in an advantageous embodiment such that, in the event of a connection of the sealable outer film to the longitudinal edges of the multi-chamber hollow profile, stability losses on the multi-chamber hollow profile do not occur despite a heat input and mechanical loads.
In a further embodiment, the electrode stack, as in a known pouch cell, is completely surrounded by an outer, electrically insulating, sealable film. In this new battery element, the multi-chamber hollow profile together with one or more known battery cells then form a unit, i.e. an integral component. In the simplest embodiment, the battery cell is pressed against the multi-chamber hollow profile and mechanically clamped thereto. Examples of such elastic tensioning elements are a film or a fabric. In a further embodiment, at least one known battery cell, i.e. an electrode stack having an outer, electrically insulating, sealable film, is arranged adjacent to the wide side surfaces of the multi-chamber hollow profile and is surrounded by a further outer film and is thereby pressed against the multi-chamber hollow profile and held flat against the multi-chamber hollow profile. Such an additional outer film can, for example, also be drawn in the form of a tube via such an arrangement, namely the battery cells and the multi-chamber hollow profile arranged therebetween, the ends of the tube being connected to the coated multi-chamber profile. The invention further relates to a winding comprising a film.
In a further embodiment, the battery cell is connected to the multi-chamber hollow profile via the outer, sealable film thereof. For this purpose, the multi-chamber hollow profile has the electrically insulating, thermoplastic coating. Said plastic coating of the multi-chamber hollow profile and the sealable film of the battery cell are connected to each other in order to form the new battery element. The cohesive connection is produced by welding or sealing the thermoplastic material of the multi-chamber hollow profile with the thermoplastic material of the outer film of the battery cell is obtained.
In a further embodiment, a connection between the film of the battery cell and the multi-chamber hollow profile is achieved in that a sealable intermediate film is arranged between the two. This intermediate film is connected to the multi-chamber hollow profile and, in desired connecting regions, forms a cohesive connection to the film of the battery cell.
A simple connection possibility between the multi-chamber hollow profile and the outer film of the battery cell is also an adhesive connection. The surface of the multi-chamber hollow profile is pretreated for good adhesion to the multi-chamber hollow profile. Such a pretreatment consists, for example, of a plasma treatment, a fibre treatment, an anodization, a mechanical surface treatment or special coatings in order to improve the adhesion of the surface of the multi-chamber hollow profile. Conversion layers or galvanization of the outer surfaces of the multi-chamber hollow profile produced by arc welding can be used as coatings. In the case of a large-area adhesive connection between the outer film of the battery cell and the multi-chamber hollow profile, it is to be taken into account that the battery cell expands due to the development of heat during charging and discharging. This is to be taken into account by providing an expansion joint. Thus, for example, an adhesive-free region is provided between the battery cell and the multi-chamber hollow profile, preferably this region is arranged in the transverse direction of the multi-chamber hollow profile.
In the above-described manner, at least one electrode stack is connected to a lateral surface of the multi-chamber hollow profile. Said electrode stacks are each covered by an outer sealable film or surrounded by an outer film. In this way, the multi-chamber hollow profile is an integral component of the new battery element, wherein the electrode stacks arranged on one side or on both sides rest on the multi-chamber hollow profile over a large area.
In this case, it is also possible for a plurality of electrode stacks or battery cells arranged next to one another to be connected to the upper side and/or lower side of the multi-chamber hollow profile. In the case of an arrangement of a plurality of electrode stacks or a plurality of battery cells both on the upper side and on the underside of the multi-chamber hollow profile, these can be arranged opposite one another or else offset with respect to one another. Furthermore, it is also possible to fasten the electrode stacks, which are arranged on the underside of the first multi-chamber profile, with their opposite broad side to a further multi-chamber hollow profile, with the result that a battery element is produced from five layers arranged one above the other, namely electrode stack, multi-chamber hollow profile, electrode stack, multi-chamber hollow profile, electrode stack.
In a further embodiment, a connection between the battery cell and the multi-chamber hollow profile is achieved by wrapping. Here, the battery cell is very flat, and has flat elongate electrodes which are separated by separators and are surrounded by a film bag. This flat battery cell has a comparatively large bag length starting from one end, at which the contact tabs extend out of the film bag to the other end, the bag bottom. This long bag-like battery cell is wound around the multi-chamber hollow profile and held on the multi-chamber hollow profile.
In an advantageous manner, a multi-chamber hollow profile is provided as an integral component of the battery cell for controlling the temperature of the battery cell. The multi-chamber hollow profile serves, on the one hand, for heating or, on the other hand, to heat away the heat produced in the battery element and, for this purpose, flows through a cooling medium. Said multi-chamber hollow profile is preferably an extruded profile made of aluminum or an aluminum alloy. This material has, on the one hand, good heat conduction properties and can furthermore be produced in an advantageous manner as an extruded profile at a very low height. The height H of the multi-chamber hollow profile is 0.3 mm to 10 mm, preferably 0.8 to 3 mm. Thus, a battery element of low construction height and low weight can be produced. If, for example, two electrode stacks each having a height HB of approximately only 8 mm and a multi-chamber hollow profile having a height H of 3 mm are used for a battery element, such a battery element having an integrated heat-conducting element has a construction height of less than 20 mm. The length of the battery element, ie the length of the multi-chamber hollow profile, can be selected as desired for the purpose of application. The width of the battery element is preferably provided in such widths which can be optimally extruded, for example up to a width of 200 mm.
Alternatively, the multi-chamber hollow profile can also be made of sheet metal, for example made of a folded sheet metal or by a roll-bond-process.
In all the aforementioned embodiments, the electrode stacks are in surface contact with the multi-chamber hollow profile, that is the heat transport during rapid charging of such a battery cell takes place over the shortest path from the electrochemically active layer of the electrode stack arranged furthest away in the battery cell to the surface of the multi-chamber hollow profile. This advantage of the new battery element is expressed in a geometry factor G, namely
G=H
B
/H
the ratio of the body height of the battery cell HB to the height H of the multi-chamber hollow profile. In the case of the new battery elements, this geometry factor G is between values of 1.3 and at most 25, preferably between 3 and 7. These values illustrate that the entire electrode stack is well tempered, namely in particular also the electrochemically active layer of the electrode stack in the battery cell arranged furthest away from the multi-chamber hollow profile.
The heat is conducted out of the battery element via the chambers of the multi-chamber hollow profile through which cooling medium flows. For this purpose, the chambers on the end faces of the multi-chamber hollow profile are connected to a cooling system or a collector via connections. In the case of very long battery elements, in particular in the case of a plurality of battery cells provided in the longitudinal direction of the multi-chamber hollow profile, the cooling medium flows through the multi-chamber hollow profile, for example in a w-shape or z-shape. The connections are only arranged on one end face of the multi-chamber hollow profile. This has the advantage that the temperature differences of the cooling medium in the battery element are minimized.
The new battery element advantageously ensures a good thermal connection of the electrode stacks to the multi-chamber hollow profile, which can be expressed by a thermal characteristic number TK. This thermal characteristic number TK expresses how large the tempered area of the multi-chamber hollow profile is in relation to the contact area of the electrode stack on the multi-chamber hollow profile.
TK=ΣB
K1-n/(BE)
BE is the width of the contact region of an electrode stack on the multi-chamber hollow profile. BK is the width of a chamber of the multi-chamber hollow profile, which chamber is temperature-controlled by a fluid. The sum of all chamber widths is related to the width of the contact region. The new battery elements exhibit very good thermal characteristic numbers TK of greater than 0.8.
In each application described above, an outer sealable film is used. This can be a composite film, as is used for known battery cells. Such foils have a sealable, thermoplastic layer on one side, an intermediate layer in the form of an aluminum foil as a diffusion barrier and, in turn, a plastic layer on the outer side. The inner layer of these composite films consists in particular of thermoplastic material, such as polyolefins, preferably of polypropylene, which melts through the application of heat and can be connected to the surface of the multi-chamber hollow profile with an electrically insulating, thermoplastic plastic coating. This plastic coating on the multi-chamber hollow profile is also a sealable, i.e. heat-weldable plastic, such as polyester or polyolefins. Here too, for example polypropylene is used, which can be applied in the form of powder by a powder coating on the multi-chamber hollow profile. In addition, a wet paint coating is also possible or a plastic film is applied to the surface of the multi-chamber hollow profile, for example by film lamination. This thermoplastic synthetic coating is preferably provided over the entire surface on the surface of the multi-chamber hollow profile, in particular to ensure appropriate electrical insulation from the electrode stack and on the other hand to connect to the outer film along the longitudinal edges but also at any point across the width of the multi-chamber hollow profile, namely for extensive inclusion of an electrode stack. Only the contact lugs of the electrodes are led out of such a covering of the electrode stack. In addition, the end faces of the multi-chamber hollow profile can protrude beyond the foil-covered electrode stacks in order to connect the inner chambers more easily to corresponding connections for cooling or to collectors.
Advantageously, by means of the integrated cooling or heating in the form of the multi-chamber hollow profile, the battery element also provides its own stability and can be inserted in this stable form without a frame into a housing in order to form a battery module, wherein the weight advantage over known battery elements with framed battery cells is not lost due to the thin and light multi-chamber hollow profile.
Furthermore, the electrode stacks or battery cells are fastened with their surface to the multi-chamber hollow profile in a potential-free manner at a very short distance, wherein the multi-chamber hollow profile is connected to the contact surfaces in order to form an electrode stack in the battery element by means of a plastic insulation, for example. It is electrically insulated by means of a plastic coating.
The drawing shows an exemplary embodiment. The invention is not limited to this exemplary embodiment. In this drawing:
In the figures, the same reference numerals are used for identical components in the different embodiments.
The new battery element 10 shown in
In this case, two films 40, 40′ were used. It is also possible to use a single foil which surrounds the entire battery cell and, for example, is connected to the plastic coating 27 of the multi-chamber hollow profile 20 by foil edges at a trapping edge 23 of the multi-chamber hollow profile 20.
In addition, it is possible to use known battery cells, to arrange these on both sides of the multi-chamber hollow profile 20 and to enclose them with a polypropylene film as an outer layer and to connect them to the multi-chamber hollow profile 20 and thus to provide them with cooling. In this case, for example, for two battery cells, a common foil is provided, which is fastened only to a catchment edge 23 or one film tube can be drawn over the arrangement, which is connected at its end sides to the multi-chamber hollow profile 20 over the width of the multi-chamber hollow profile.
If known battery cells are provided on their outer side with a sealable foil, it is also possible to connect these battery cells to the multi-chamber hollow profile 20 via their outer envelope.
A cooling or heating in the form of a multi-chamber profile 20 is provided for such a new battery element 10. This multi-chamber profile 20 is shown once again in
As can be seen in
TK=ΣB
K1-n/(BE)
This results in a width BE of 87 mm in this example, namely the width of the contact zone of the electrode stacks 30, 30′ on the multi-chamber hollow profile 20, see
The advantage of the new battery element 10 is also expressed in the geometry factor G, which represents the ratio of the body height HB of the battery cell to the height H of the multi-chamber hollow profile 20. The body height HB of the battery cell is shown in
In the example of
If required, a longitudinal edge 23, 24 can be connected to a thermocouple in order to monitor the development of heat in the battery element or a battery module.
As shown in particular in
A plurality of battery elements 10 can be assembled to form a battery module of corresponding size, for example can be used on edge, as shown in
Number | Date | Country | Kind |
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10 2017 130 068.6 | Dec 2017 | DE | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2018/084528 | 12/12/2018 | WO | 00 |