The present invention relates to a battery module having a structure in which failure such as heat generation occurring in a battery cell does not affect other cells, and a battery module assembly using the battery module.
Recently, from the viewpoint of resource savings and energy savings, secondary batteries such as nickel hydrogen secondary battery, nickel cadmium secondary battery and lithium ion secondary battery, which can be used repeatedly, are increasingly demanded. Among them, the lithium ion secondary battery has light weight, high electromotive force, and large energy density. Therefore, demand for lithium ion secondary batteries is increased as driving power sources for various portable electronic apparatuses and mobile telecommunication apparatuses such as portable telephones, digital cameras, video cameras, notebook-sized personal computers and the like.
On the other hand, in order to reduce the amount of fossil fuel to be used and amount of CO2 emissions, a battery pack as a power source for driving a motor of an automobile or the like is increasingly expected. The battery pack is configured by using a plurality of battery units each including one or more battery cells in order to obtain a desired voltage or capacity.
In a battery module, as the number of battery units to be mounted is increased, space for routing power lines and control wiring is required. This makes it difficult to reduce the size of the battery module.
Thus, a configuration of a battery unit is disclosed including a plurality of battery cells, in which connecting lines between the cells and wiring for detecting a voltage, a temperature, and the like, are connected by pattern wirings formed on a printed circuit board (see, for example, Patent Literature 1). Similarly, a power source device is disclosed in which a plurality of power source modules are stored in a holder case and connected to each other via an end plate (for example, Patent Literature 2). The end plate is provided with a power source lead and a sensor lead for connecting power source modules. This configuration can reduce connection failure and reduce the size of the power source device.
Furthermore, as the capacity of battery cells to be stored in a battery module is increased, each battery cell itself may generate heat to high temperatures depending on the mode of use. Therefore, in addition to the safety of the cell itself, the safety of the battery module combining a plurality of battery units each of which assembles the cells becomes more important. That is to say, in a cell, an internal pressure rises due to gas generated by overcharge, overdischarge, or internal short-circuit or external short-circuit, and occasionally, an external case of the cell may rupture. Therefore, in general, the cell is provided with a vent mechanism, a safety valve, or the like, for extracting gas, so that internal gas is released when unexpected circumstances occur. At this time the exhausted gas may ignite, so that the gas may produce smoke, or, although rarely, catch fire.
Then, a power source device is disclosed in which a plurality of cells are stored in a battery chamber in a case, and an open part is provided in a separation wall facing a safety valve of each cell (see, for example, Patent Literature 3). In this power source device, gas ejected from the cell at an abnormal state is exhausted from an exhaust port via the exhaust chamber.
However, in the battery modules described in Patent Literatures 1 and 2, when one cell abnormally generates heat and a safety valve works, an amount of heat of the cell that generates heat or the influence on the surrounding batteries by ignition to the ejected gas cannot be suppressed. Therefore, the battery units may be deteriorated one after another. In particular, a battery module in which battery units are mounted has a problem of how to suppress and minimize the expansion of the influence of the battery unit in an abnormal state to the surrounding battery units.
Furthermore, in the power source device disclosed in Patent Literature 3, an open part is provided in a separation wall of a case so as to face the safety valve of the battery, thereby exhausting the ejected gas to the outside so that the gas do not fill the battery chamber. However, similar to Patent Literatures 1 and 2, when one cell abnormally generates heat before the safety valve works, the surrounding cells are heated one after another by emission, radiation, or the like, of the heat of the cell that generates heat. Since the amount of heat generation is increased synergistically as the number of the cells stored in the battery chamber is increased, it is not possible to minimize the influence on the surrounding cells. Although a circuit board incorporated in resin is disclosed, connection to a cell, a control method and the like are neither disclosed nor suggested. Furthermore, since the circuit board is incorporated in resin, reduction in size of the battery module is limited.
[Patent Literature]
The present invention provides a battery module capable of reducing space for wiring and of minimizing the influence of abnormal heat generation of a battery cell with failure on the surrounding battery cells, and a battery module assembly using the battery module.
The battery module of the present invention includes a plurality of battery units, a housing, a wiring board, and a lid. Each of the battery units is composed of one or more battery cells each having a vent mechanism. At least one surface of the housing is an open end. The housing has a plurality of storage parts partitioned by one or more partition walls. Each battery unit is stored in each storage part. The wiring board covers the open end of the housing, is disposed at the vent mechanism side of the battery cells, and has a connection terminal connected to the battery units. The lid covers the open end of the housing and the wiring board, and has an open part. Through holes are provided in positions facing the battery units and in a different region from that of the connection terminals in the wiring board.
With this configuration, it is possible to store the battery unit in the storage part of the housing with at least the wiring board and the partition wall in a sealed state. Therefore, even if a battery unit is in an abnormal state, gas, which is ejected by opening of a vent mechanism of a cell, is not supplied with oxygen from the outside, and is exhausted to the outside of the battery module in a state of gas via the through hole of the wiring board. Furthermore, since each battery unit is stored in a partitioned storage part in the housing, heat transfer to the surrounding battery units is suppressed and an influence of the heat can be minimized. Moreover, space necessary for routing power supply wiring, control wiring, or the like, can be considerably reduced by the wiring board. As a result, a battery module having a small size, high safety, and excellent reliability can be achieved.
The battery module assembly of the present invention has a configuration in which a plurality of the battery modules are combined at least one of in series and in parallel. With this configuration, depending on the intended use, a battery module assembly having any voltage or capacity can be achieved.
According to the present invention, a battery module capable of reducing space for wiring and of minimizing the influence of abnormal heat generation of a battery unit with failure on the surrounding battery units, and a battery module assembly using the battery module can be achieved.
Hereinafter, exemplary embodiments of the present invention are described with reference to drawings in which the same reference numerals are given to the same components. Note here that the present invention is not limited to the contents mentioned below as long as it is based on the basic features described in this specification. Furthermore, in the below description, a non-aqueous electrolyte secondary battery such as a lithium ion battery (hereinafter, referred to as a “battery”) is described as an example of a battery cell. However, the present invention is not limited to this example.
As shown in
On the top and bottom of electrode group 4, insulating plates 10A and 10B are placed. In this state, electrode group 4 is inserted into battery case 5. The other end of positive electrode lead 8 is welded to sealing plate 6, and the other end of negative electrode lead 9 is welded to the bottom of battery case 5. Furthermore, a non-aqueous electrolyte (not shown) conducting lithium ion is filled in battery case 5. An open end of battery case 5 is caulked to positive electrode cap 16, current blocking member 18 such as a PTC element, and sealing plate 6 via gasket 7.
Vent mechanism 19 such as a safety valve is opened when failure occurs in electrode group 4. Positive electrode cap 16 is provided with vent hole 17 for extracting gas generated when vent mechanism 19 is opened.
Positive electrode 1 includes positive electrode current collector 1A and positive electrode layer 1B containing positive electrode active material. Positive electrode layer 1B includes a lithium-containing composite oxide such as LiCoO2, LiNiO2, and Li2MnO4 or a mixture or a composite compound thereof, as the positive electrode active material. Furthermore, positive electrode layer 1B further includes a conductive agent and a binder. Examples of the conductive agent include graphites such as natural graphites and artificial graphites; and carbon blacks such as acetylene black, Ketjen black, channel black, furnace black, lampblack, thermal black, and the like. Furthermore, examples of the binder include PVDF, polytetrafluoroethylene, polyethylene, polypropylene, aramid resin, polyamide, polyimide, and the like. As positive electrode current collector 1A, aluminum (Al), carbon (C), conductive resin, and the like, can be used.
As the non-aqueous electrolyte, an electrolyte solution obtained by dissolving a solute in an organic solvent, or a so-called a polymer electrolyte layer including the electrolyte solution and immobilized by a polymer can be used. Examples of the solute of the nonaqueous electrolyte may include LiPF6, LiBF4, LiClO4, LiAlCl4, LiSbF6, LiSCN, LiCF3SO3, LiN(CF3CO2), LiN(CF3SO2)2, and the like. Furthermore, examples of the organic solvent may include ethylene carbonate (EC), propylene carbonate, butylene carbonate, vinylene carbonate, dimethyl carbonate (DMC), diethyl carbonate, ethyl methyl carbonate (EMC), and the like.
Negative electrode 2 includes negative electrode current collector 11 and negative electrode layer 15 containing negative electrode active material. As negative current collector 11, a metal foil of, for example, stainless steel, nickel, copper, and titanium, and a thin film of carbon and conductive resin are used. As negative electrode layer 15, negative electrode active materials capable of reversibly absorbing and releasing lithium ions can be used. For example, carbon materials such as graphite, silicon (Si), tin (Sn), or the like having a theoretical capacity density of more than 833 mAh/cm3, can be used.
Hereinafter, a battery module in accordance with this exemplary embodiment is described in detail with reference to
As shown in
Hereinafter, with reference to the drawings, each component constituting battery module 100 is described. As shown in
Lid 20 covers the open end of housing 50 and wiring board 30. As shown in
Wiring board 30 covers the open end of housing 50 and disposed at a vent mechanism side of each battery unit 40. Furthermore, as shown in
Each through hole 36 formed in wiring board 30 is provided in a position facing each battery unit 40 and in a different region from that of the connection terminals 32. As shown in
Thus, since battery units 40 can be connected to each other via wiring board 30, space necessary for routing power supply wiring, control wiring, or the like can be considerably reduced. Therefore, it is not necessary to provide a clearance space or a through hole in partition wall 52 of housing 50 forming storage part 54 for storing each battery unit 40. Consequently, each battery unit 40 can be stored in storage part 54 formed by partition walls 52 and wiring board 30 so as to be sealed. As a result, gas ejected from a battery unit in an abnormal state cannot enter the storage part of the neighboring battery unit. Therefore, even if the gas ignites and catches fire, entry of flame is prevented, and the influence thereof can be inhibited reliably.
Hereinafter, in battery module 100, an operation and an effect of battery module 100 when abnormal heat generation and the like occurs in one of battery units 40 are described with reference to
As shown in
As shown in
When gas 45 is rapidly ejected from battery unit 40, the risk that gas 45 ignites and catches fire is generally increased. However, in battery module 100 having the above-mentioned configuration, an amount of oxygen in storage part 54 is limited, and oxygen is not supplied from the outside because storage part 54 is a sealed space. Therefore, the possibility that the gas ignites is extremely low, and the gas is exhausted from through hole 36 of wiring board 30 in a state of gas 45. Thus, since explosive expansion of gas 45 due to ignition does not occur, battery module 100 does not rupture at all. Furthermore, partition walls 52 of housing 50 can prevent heat of battery unit 40 that abnormally generates heat from being transferred to the neighboring battery unit. As a result, an influence of heat transfer from the storage part storing the battery unit that abnormally generates heat to a battery unit stored in another storage part can be considerably suppressed.
According to this exemplary embodiment, battery unit 40 can be stored in storage part 54 of housing 50 with at least wiring board 30 and partition walls 52 in a sealed state. Therefore, since gas 45 ejected when battery unit 40 is in an abnormal state is not supplied with oxygen from the outside, it can be exhausted to the outside of battery module 100 in a state of gas from through hole 36 of wiring board 30. Therefore, it is possible to achieve a battery module having an excellent safety in which fire or smoke due to ignition of gas 45 do not occur.
Furthermore, since each battery unit 40 is stored in storage part 54 partitioned by partition walls 52 in housing 50, an amount of heat transferred to the surrounding battery units is suppressed, thus enabling the influence thereof to be minimized. In addition, space necessary for routing power supply wiring, control wiring, or the like, can be considerably reduced by wiring board 30. As a result, a battery module having a smaller size, higher safety and an excellent reliability can be achieved.
This exemplary embodiment describes a glass-epoxy substrate as an example of wiring board 30, but not limited to this. For example, as shown in a sectional view of
As shown in
As reinforcing member 64, polyphenylene sulfide (PPS) resin, polycarbonate (PC) resin, polyether ether ketone (PEEK) resin, phenol resin, UNILATE, glass epoxy resin, ceramic, and the like can be used. Note here that the above-mentioned resin may contain filler such as carbon fiber and glass fiber. Furthermore, as wiring board 60, a bus bar and the like may be formed in the same material as that of reinforcing member 64 by insert molding. Thus, it is possible to enhance the mechanical strength of wiring board 60, and to improve deformation resistance or heat resistance of wiring board 60 with respect to the pressure of the ejected gas. Therefore, it is possible to enhance the reliability and safety. In this way, use of flexible substrate 62 enhances the workability and facilitates handling, and reinforcement of flexible substrate 62 with reinforcing member 64 improves the sealing degree of storage part 54.
Furthermore, this exemplary embodiment describes an example of a structure in which housing 50 and lid 20 are fitted with each other, and thereby peripheral wall 22 of lid 20 and partition walls 52 of housing 50 hold wiring board 30. However, the present invention is not limited to this. For example, as shown in a battery module shown in an exploded perspective view of
Alternatively, instead of providing supporting member 65, as shown in
Furthermore, this exemplary embodiment describes an example in which power supply wiring is formed on wiring board 30. However, the present invention is not limited to this. For example, voltage detection wiring for detecting a voltage of each battery unit 40 and temperature detection wiring for detecting a temperature of each battery unit 40 may be provided on wiring board 30. In such a case, a temperature detector such as a thermistor is connected to the temperature detection wiring, and each of such temperature detectors can be brought into contact with each battery unit 40 to detect a temperature. Thus, voltages and temperatures of a plurality of battery units 40 can be detected and controlled individually. As a result, since the voltages and temperatures can be controlled by taking property variation or change over time of battery units 40 into consideration, reliability and safety can be further enhanced. Note here that since a large amount of electric current flows in the power supply wiring, it is necessary to reduce electric loss due to wiring resistance. However, voltage detection wiring and the temperature detection wiring can carry out detection with a small amount of electric current. Therefore, the pattern width of the voltage detection wiring or the temperature detection wiring on wiring board 30 can be considerably narrow as compared with the pattern width of the power supply wiring. As a result, the power supply wiring and a plurality of pairs of the voltage detection wiring and the temperature detection wiring can be disposed efficiently to form wiring board 30. Therefore, space necessary for wiring can be reduced considerably.
Furthermore, this exemplary embodiment describes an example in which the open end is provided on one side of housing 50. However, the present invention is not limited to this. For example, as shown in
Furthermore, this exemplary embodiment describes an example in which a plurality of battery units 40 are disposed with vent mechanisms aligned in the same direction. However, the present invention is not limited to this.
As shown in
As shown in
Wiring board 70 formed of, for example, a glass-epoxy substrate includes connection terminals 72, connection plates (not shown), through holes 76, and power supply wiring (power line: not shown) connecting between at least neighboring connection terminal 72 and the connection plate to each other. Connection terminal 72 is connected to a first electrode (for example, a positive electrode) at the vent mechanism side of battery unit 40. The connection plate is connected to a second electrode (for example, a negative electrode). Each through hole 76 is provided in a position facing each battery unit 40 and in a different region from that of the connection terminals 72.
Connection terminal 72 has a C-shaped cross-section having a bottom surface as shown in
Also in this configuration, gas ejected from a battery unit in an abnormal state cannot enter a storage part of an adjacent battery unit. Therefore, if the gas ignites and catches fire, entry of flame is prevented, and the influence thereof can be inhibited reliably. In particular, as described in detail in the below-mentioned another example of the battery module, in a case that a battery unit including a plurality of battery cells is stored in storage part 54 of housing 50, the effect is large. This is because even if a cell that is not disposed in the vicinity of through hole 76 of wiring board 70 is in an abnormal state, space in which the gas ejected from a vent hole of this cell is exhausted can be secured by the predetermined space of connection terminal 72, the gas can be exhausted from through hole 76 easily. As can be understood, space T may be appropriately adjusted according to an amount of gas to be emitted from battery unit 40. A hole may be formed on, for example, the side surface of a folding portion of connection terminal 72, so that the hole has the same function as through hole 76. Thus, exhausting efficiency of gas can be improved.
According to this exemplary embodiment, the same effect as that of the first exemplary embodiment can be obtained. Furthermore, by providing a predetermined space between wiring board 70 and battery unit 40 by connection terminals 72, exhaust resistance of gas to be ejected can be reduced and the gas can be exhausted efficiently and reliably. Furthermore, with a simple structure in which connection terminal 72 is allowed to protrude from wiring board 70, the predetermined spaces between wiring board 70 and battery units 40 can be formed uniformly.
This exemplary embodiment describes an example of connection terminal 72 having a C-shaped cross-section. However, the present invention is not limited to this example. For example, as shown in
Furthermore, as shown in
Next, another example of a battery module in this exemplary embodiment is described with reference to
In battery module 300, battery units 340 each including, for example, three cells connected in parallel are used. Then, each battery unit 340 is stored in storage part 354 partitioned by partition walls 352 of housing 350. Battery module 300 is different from battery module 200 in this point.
More specifically, firstly, the vent mechanism sides of three cells are aligned, and first electrodes of the three cells are connected to each other and second electrodes are connected to each other to form battery unit 340. Then, a first electrode of each battery unit 340 is connected to connection terminal 332 of wiring board 330, and a second electrode is connected to a connection plate (not shown). Then, battery units 340 are stored in storage part 354 of housing 350. Similar to the configuration described with reference to
Thus, in battery unit 340 including a plurality of battery cells, even if at least one cell is in an abnormal state and ejects gas, the gas can be reliably exhausted from through hole 336 efficiently. Furthermore, for example, by providing an open part around the peripheral portion (periphery) by using connection terminal 332 having a C-shaped cross-section, gas can be exhausted more efficiently.
This exemplary embodiment describes an example in which a battery unit is configured by using three cells. However, the present invention is not limited to this example. For example, according to the required electric capacity, three or more cells may be connected in parallel to form a battery unit. At this time, it is preferable that a plurality of through holes 336 are provided in wiring board 330 as the number of batteries to constitute the battery unit is increased.
According to this exemplary embodiment, depending upon the applications of use, highly versatile battery module assemblies 400 and 500 having arrangement space and necessary voltage and capacity can be configured by arbitrarily combining battery modules 100. Note here that instead of battery module 100, any of battery modules 150, 200, and 300, which are described in the first and second exemplary embodiments, may be used.
Next, another example of a battery module assembly is described with reference to
That is to say, battery module assembly 600 includes housing 650, a plurality of battery units 640, wiring boards 630 and lid 620. Housing 650 includes a plurality of storage parts 654 partitioned by partition walls 652 two-dimensionally in the first direction and the second direction. Battery units 640 are stored in storage parts 654, respectively. Wiring board 630 connects a group of battery units 640 disposed along the first direction among battery units 640 in single-dimensional arrangement. Lid 620 is fitted with housing 650 in which battery units 640 are stored in a sealed state.
Wiring boards 630 are connected in parallel or in series or combination thereof by ECU (Electric Control Unit) 660. That is to say, ECU 660 is a connection member for connecting wiring boards 630. As described above, battery module assembly 600 can be regarded as a battery module in which battery units 640 are arranged two-dimensionally and they are connected by using a plurality of wiring boards 630 and ECU 660.
Wiring board 630 can detect and control temperatures and/or voltages of the battery cells, and can transmit/receive such information to/from the external apparatus. Lid 620 is provided with an exhaust chamber (not shown) and an open part (not shown) for exhausting the ejected gas such that they correspond to, for example, each wiring board 630. This configuration is similar to the configuration of peripheral wall 22 shown in
In this configuration, by using an integrated housing 650, further smaller battery module assembly 600 can be achieved.
Note here that in the exemplary embodiments, a control circuit for detecting and controlling charge and discharge of the battery module, a temperature, or a voltage are not particularly described. However, it is needless to say that a control circuit may be provided in the outside or inside of the battery module.
Furthermore, each exemplary embodiment describes an example of a cylindrical cell as a battery unit. However, the present invention is not limited to this. For example, a rectangular cell may be employed. Furthermore, a cell having a positive electrode terminal, a negative electrode terminal and a vent mechanism at the same side may be employed. Thus, assembly property or workability of each battery unit and a wiring board are considerably improved. Furthermore, a configuration specific to each exemplary embodiment may be combined as possible.
The present invention is useful as a battery module and a battery module assembly, which require high reliability and high safety in, for example, automobiles, bicycles, machine tools, and the like.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2009/006740 | 12/10/2009 | WO | 00 | 4/6/2011 |