Patent Application
20250183420
The present invention relates to a battery pack having a venting duct integrally formed in an upper cover of a pack case to directs high temperature gases or flames discharged from a venting device provided on the upper surface of prismatic cells aligned in a row to a predetermined discharge direction.
This application claims the benefit of priority based on Korean Patent Application No. 10-2022-0168749, filed on Dec. 6, 2022, the disclosure of which is incorporated herein by reference in its entirety.
Unlike primary batteries, secondary batteries can be recharged, and they have been heavily researched and developed in recent years due to their potential for miniaturization and large capacity. The demand for secondary batteries as an energy source is increasing rapidly due to the technological development and increasing demand for mobile devices, electric vehicles, and energy storage systems, which are emerging in response to the need for environmental protection.
Secondary batteries are categorized into coin-type cells, cylindrical cells, prismatic cells, and pouch-type cells based on the shape of the battery case. In a secondary battery, an electrode assembly mounted inside the battery case is a chargeable/dischargeable power generator consisting of a laminated structure of electrodes and separators.
Secondary batteries take the form of a battery pack, which can be a grouping of a plurality of battery cells. Battery packs increase energy density and can be used in devices that require high energy, such as electric vehicles. A battery pack electrically connects multiple battery cells to output a specified power, cools the battery cells as their temperature rises during operation, and has various safety devices to respond to emergencies such as ignition.
Particularly, since secondary batteries are required to be used continuously for a long period of time, it is necessary to effectively control the heat generated during the charging and discharging process. If the secondary battery is not properly cooled, the increase in temperature causes an increase in current, which causes an increase in temperature, and the increase in current causes the temperature to rise again, triggering a feedback chain reaction that eventually leads to the catastrophic condition of thermal runaway.
Moreover, when secondary batteries are grouped together in the form of modules or packs, the thermal runaway of one secondary battery can cause the thermal propagation phenomenon that continuously overheats other neighboring secondary batteries. Furthermore, there is a high risk of fire due to ignition sources such as flammable gases and heated electrodes emitted from overheated secondary batteries, so it is necessary to suppress the risk of ignition.
In order to prepare for emergencies such as thermal runaway and thermal propagation, secondary batteries are often equipped with a venting device as a safety valve. In the event of an excessive increase in the internal pressure of the secondary battery, the venting device reacts by opening itself to relieve the internal pressure, thereby preventing the structural collapse of the secondary battery.
However, when the venting device is operated, flammable gases and ignition sources such as heated electrodes are ejected in a random direction through the outlet of this pressure relief, so it is necessary to control and guide the direction of the ejection properly. For this purpose, a venting duct is sometimes installed in the module to form an induction passage for the venting device.
The present invention aims to provide a battery pack that can collectively form an induction passage for a venting device with a simple assembly process for all secondary batteries included in a battery block and battery module comprising the battery pack.
However, the technical problem the present invention aims to solve is not limited to the problems mentioned above, and other problems not mentioned will be apparent to those of ordinary skill in the art from the description of the invention set forth below.
The present invention relates to a battery pack that, in one example, includes: a battery block including a cell array in which a plurality of prismatic cells provided with a venting device on the upper surface is arranged in a row, a pair of side plates disposed on each of both sides of the cell array, and a pair of end plates disposed on each of front and rear surfaces of the cell array, wherein both ends of the end plates in the width direction are fixed to side brackets provided at both ends of the side plates in the longitudinal direction of the side plates, so that the cell array is constrained as a single block; and a pack case in which a plurality of the battery blocks are mounted, wherein the upper cover of the pack case is integrally formed with a venting duct having a flow path communicating with a plurality of venting devices arranged in a row on the upper surface of the cell array.
Here, it may be preferable that the venting duct is integrally formed by plastically processing the upper cover.
In an exemplary embodiment of the present invention, the venting duct includes: a concave part that coupled to the upper surface of the prismatic cell around the venting device, and a convex part that forms a space surrounding the venting device.
In addition, a contact surface of the concave part of the venting duct and the upper surface of the prismatic cell may be provided with an insulating sheet.
In addition, the convex part forms a duct outlet on one side facing the side frame of the pack case, while the opposite side may form a closed surface.
Additionally, an electrode terminal is disposed on the upper surface of the prismatic cell on each side of the venting device, and a wiring duct forming a space for surrounding the electrode terminal on each side of the venting duct may be integrally formed by plastically processing the upper cover.
Here, it may be preferable that the wiring duct is isolated from the duct outlet.
In addition, the duct outlet may communicate with a venting outlet provided in the side frame of the pack case.
Meanwhile, in an exemplary embodiment of the present invention, the cell array includes a heat-absorbing/venting pouch disposed between the prismatic cells to contact the front and rear surfaces of the prismatic cell, wherein the heat-absorbing/venting pouch seals and stores a liquid-impregnated absorbent material, wherein the heat-absorbing/venting pouch is provided with a heat-fused sealing part along its edge, and the heat-fused sealing part may be provided with a vulnerable part having a relatively low bursting strength.
In addition, the vulnerable part of the heat-absorbing/venting pouch is disposed at the upper end edge, wherein the insulating sheet may be provided with a venting slit corresponding to the vulnerable part in the space formed by the convex part of the venting duct.
Additionally, the side plate is made from a single plate bent in a “U” shape with an open upper end to form an internal space, wherein a heat-absorbing/venting pouch sealing and storing an absorbent impregnated with liquid may be built into the internal space.
According to an embodiment, the side plate is provided with a concave surface on both sides of the bent plate, at least one bonding rib is provided along a longitudinal direction that the concave surfaces facing each other bonded to each other along the longitudinal direction thereof, wherein the heat-absorbing/venting pouch may be inserted into the internal space compartmentalized by the bonding rib.
According to the battery pack of the present invention having the above-described configuration, a venting duct compartmentalized for each battery block is installed for all cell arrays simply by mounting a battery block in the pack case and sealing the pack case with an upper cover. Thus, the assembly and disassembly process of the battery pack is simplified since it is not necessary to install a venting duct for each battery block, and since the upper cover acts as a venting duct, the material is reduced, resulting in cost savings.
In addition, the upper cover having an integrally curved venting duct has a curved cross-sectional shape, which improves the mechanical rigidity compared to a conventional upper cover having a simple flat plate shape, and can more effectively protect the battery block inside the pack case.
However, the technical effects obtainable through the present invention are not limited to the effects described above, and other effects not mentioned here will be clearly understood by those skilled in the art from the description of the invention provided below.
The following diagrams accompanying this specification illustrate preferred embodiments of the present invention and, together with the detailed description of the present invention that follows, serve to further illustrate the technical ideas of the present invention, and the present invention is not to be construed as limited to what is shown in such diagrams.
The present invention is subject to various modifications and can have many embodiments, certain of which are described in detail below.
However, this is not intended to limit the present invention to any particular embodiment and is to be understood to include all modifications, equivalents, or substitutions that fall within the scope of the thought and technology of the present invention.
The terms “comprise” or “have” are used herein to designate the presence of characteristics, numbers, steps, actions, components or members described in the specification or a combination thereof, and it should be understood that the possibility of the presence or addition of one or more other characteristics, numbers, steps, actions, components, members or a combination thereof is not excluded in advance.
In addition, when a part of a layer, a film, a region or a plate is disposed “on” another part, this includes not only a case in which one part is disposed “directly on” another part, but a case in which a third part is interposed there between. In contrast, when a part of a layer, a film, a region or a plate is disposed “under” another part, this includes not only a case in which one part is disposed “directly under” another part, but a case in which a third part is interposed there between. In addition, in this application, “on” may include not only a case of disposed on an upper part but also a case of disposed on a lower part.
The present invention relates to a battery pack, which in one example includes: a battery block including a cell array in which a plurality of prismatic cells provided with a venting device on the upper surface is arranged in a row, a pair of side plates disposed on each of both sides of the cell array, and a pair of end plates disposed on each of front and rear surfaces of the cell array, wherein both ends of the end plates in the width direction are fixed to side brackets provided at both ends of the side plates in the longitudinal direction of the side plates, so that the cell array is constrained as a single block; and a pack case in which a plurality of the battery blocks are mounted.
Here, the upper cover of the pack case is integrally formed with a venting duct forming an integral flow path for a plurality of venting devices arranged in a row on the upper surface of the cell array, and preferably, the venting duct is integrally formed by plastically processing the upper cover.
According to the battery pack of the present invention, a venting duct for every cell array compartmentalized for each battery block is installed by simply mounting the battery block inside the pack case and sealing the pack case with the upper cover.
This simplifies the assembly and disassembly of the battery pack by eliminating the need to install a venting duct for each individual battery block, and reduces the amount of material required as the upper cover acts as a venting duct, resulting in cost savings.
In addition, the upper cover with an integrally curved venting duct has a curved cross-sectional shape, which improves mechanical rigidity compared to a conventional upper cover with a simple flat plate shape, and can more effectively protect the battery block inside the pack case.
Specific embodiments of the present invention will now be described in detail with reference to the accompanying drawings. As used in the following description, relative positioning designations such as front to back, up and down, left and right are intended to aid in understanding the invention and refer to the orientation shown in the drawings unless otherwise defined.
A first embodiment of the present invention briefly describes a battery block 10, and a configuration in which a plurality of battery blocks 10 are connected together to form a single battery module 500. The venting duct 632 provided in the battery pack 600 of the present invention is arranged in parallel, one for each battery block 10 that constrains a single cell array 100 in block form, with the battery blocks 10 described in
The cell array 100 refers to a population of cells comprising a plurality of prismatic cells 110 arranged in a row. Each prismatic cell 110 is a finished prismatic secondary battery capable of being independently charged and discharged, and in the embodiment shown, 12 prismatic cells 110 are shown together to form a single cell array 100. All of the prismatic cells 110 are typically constructed to the same specifications, and the prismatic cells 110 aligned in a row collectively form a parallelepiped shape.
Here, the illustrated prismatic cell 110 corresponds to a unidirectional prismatic cell 110 having both positive and negative electrode terminals 112 disposed on its upper surface, and further having a venting device 114 between the pair of electrode terminals 112. The venting device 114 provided on the upper surface of the plurality of prismatic cells 110 arranged in the cell array 100 is also aligned in a row.
The venting device 114 is a device corresponding to a safety valve that ruptures to relieve the pressure inside the prismatic cell 110 when an exceed level of pressure is applied, and may include, for example, a notched rupture disk made of a thin plate-like member of a metal material. When the pressure inside the sealed prismatic cell 110 rises, the pressure causes tensile strain across the thin plate and tears the weaker notch part to release the pressure inside the prismatic cell 110.
A pair of side plates 200 are disposed on each of both sides of the cell array 100, and a pair of end plates 300 are disposed on each of the front and rear surfaces of the cell array 100. Both ends of the end plate 300 in the width direction W are fixed to side bracket 210 provided at both ends in the longitudinal direction L of the side plate 200, and the interconnection of the end plate 300 and the side plate 200 via the side bracket 210 constrains the cell array 100 as a single block.
Here, the side plate 200 and the end plate 300, and the side bracket 210 connecting them are all made of a thermally conductive material, for example, a metal material with good thermal conductivity, such as aluminum or stainless steel (SUS), through which the side plate 200 and the end plate 300 are thermally connected.
In other words, for any prismatic cell 110 in the cell array 100, the side plate 200 and end plate 300 that contact the cell array 100, as well as other neighboring prismatic cells 110, form a single thermal mass that is thermally connected to each other. In this way, the entire battery block 10 forms a single thermal mass, which provides the basis for a passive cooling structure that not only mitigates the rapid temperature rise of the prismatic cells 110 during charging and discharging, but also quickly disperses heat in the event of an emergency such as thermal runaway, thermal propagation, and the like.
Meanwhile, the upper end of the side plate 200 has a bent upper flange 230 that contacts the upper surface of the cell array 100. The upper flange 230 creates a downward fixing force that presses the cell array 100 to the bottom when the side plate 200 and end plate 300 of the battery block 10 are mounted to the mounting part 640 of the pack case 602.
Referring again to
A weld bolt 310 provided on a pair of end plates 300 disposed on the front and rear surfaces of the cell array 100, respectively, provide a fastening point for the side bracket 210, and fastening grooves 212 are engaged in the weld bolt 310 to primarily align the assembly position of the side plate 200 and end plate 300. For a stable and robust coupling of the side plate 200 and the end plate 300, and for strong constraint to the cell array 100, the weld bolts 310 and the fastening grooves 212 may be provided in an up-down pair relative to the center in the height direction H of the cell array 100.
In addition, the end plate 300 includes an end bracket 400 that is fixed to the pack case 602. Additionally, the side bracket 210 also includes end bracket 400 that is fixed to the pack case 602.
An end bracket 400 provided on the end plate 300 and the side plate 200 has a fastening surface 410 aligned with the width direction W, and one or more fastening holes 412 are formed on the fastening surface 410 of the end bracket 400. The fastening surface 410 of the end bracket 400 is seated on a mounting part 640 provided in the pack case 602 (see
Further, the end bracket 400 may include reinforcing ribs 420, such as in the form of a right triangle perpendicular to the fastening surface 410, to reinforce rigidity to a load in the height direction. For reference, to reinforce the rigidity of the end plate 300 itself, one or more concave surfaces 320, similar to the concave surface 222 of the side plate 200, may be bent and formed, and the upper end of the end plate 300 may also be provided with an upper flange 330 for stable fixation of the cell array 100.
Meanwhile,
Referring to
Another cell array 100 arranged along the width direction W share a single side plate 200 in the center, and a plurality of cell arrays 100 extend along the width direction W by means of a weld bolt 310 provided in a pair of end plates 300 disposed at the front and rear surfaces of another array of cells 100, respectively, fixed to the fastening grooves 212 of the side bracket 210.
In this way, as the side bracket 210 is provided with fastening grooves 212 on both the left and right sides, respectively, it becomes possible to couple one end plate 300 with each side of one side plate 200, and as neighboring cell arrays 100 share one side plate 200, the total number of side plates 200 is only one more than the number of cell arrays 100 in a structure in which a plurality of battery blocks 10 are connected. Thus, the space efficiency of the battery pack 600 mounting the battery block 10 of the present invention is further improved.
The pack case 602, in which the plurality of battery blocks 10 is mounted, includes a base plate 610 forming a bottom surface, a side frame 620 forming walls along all sides of the base plate 610, and an upper cover 630 sealing the upper surface of the pack case 602. The pack case 602 shown illustrates an example of two battery modules 500 with the side plate 200 and end plate 300 coupled together in a grid configuration to form a row of three cell arrays 100 (as used herein, an assembly of a plurality of battery blocks connected together via side plates will be referred to as a battery module).
A single battery module 500 with three cell arrays 100 arranged in a row has an end bracket 400 exposed along the end plate 300 at the front and rear surfaces, and one end bracket 400 also exposed on the side bracket 210 between the end plates 300. The pack case 602 is also provided with a rail-like mounting part 640 corresponding to the fastening surface 410 of the end bracket 400 that protrude from the front and rear surfaces of the battery module 500. The mounting part 640 includes a pair of side mounting parts 642 coupled to or integrally formed with the side frame 620, and a center mounting part 644 arranged side by side across the center of the base plate 610.
When the battery module 500 is inserted into the space between the side mounting part 642 and the center mounting part 644, the fastening surface 410 of the end bracket 400 faces the mounting part 640 of the pack case 602, and all of the battery blocks 10 are fixed to the pack case 602 by bonding or uniting the end bracket 400 to the mounting part 640 of the pack case 602 via the fastening holes 412.
And, when the end brackets 400 of each battery block 10 are coupled and fixed to the mounting part 640 of the pack case 602, the side plates 200, and furthermore, the upper flange 330, 230 that is bent and formed on the upper end of the end plate 300 naturally generates a downward fixing force that presses the cell array 100 against the base plate 610, thereby ensuring that the cell array 100 is firmly coupled to the base plate 610.
In the embodiment shown, the base plate 610 includes a heat sink 612 provided with a cooling flow path 614 through which cooling medium flows therein. The heat sink 612 includes a lower plate with the cooling flow path 614 formed therein, and an upper plate that fluidly seals by bonding to the lower plate, the upper plate having a pair of flow adapters 616 that form inlets and outlets for cooling medium to be distributed to the cooling flow path 614.
Further, the contact surface between the heat sink 612 of the base plate 610 and the battery block 10, a thermally conductive thermal interface material (TIM) 618 may be interposed. The thermally conductive thermal interface material 618 refers to an air-permeable material that has a significantly higher thermal conductivity than metallic materials such as aluminum, and the thermally conductive thermal interface material 618 contributes to rapidly transferring heat generated by the battery block 10 to the heat sink 612 with a high thermal conductivity and by acting as a filler to smooth out microscopic irregularities in the contact surface.
The battery modules 500 mounted within the pack case 602 are sealed by an upper cover 630 that couples to the upper end corner of the side frame 620, as shown in
Preferably, the venting duct 632 is formed integrally with the upper cover 630 by plastic processing, such as press processing. To integrally form the venting duct 632, the upper cover 630 is bent to form a curved cross-sectional shape, which provides the upper cover 630 with increased mechanical rigidity and better protection of the battery block 10 inside the pack case 602 compared to a conventional upper cover that is simply a flat plate.
The concave parts 634 on either side of the convex part 633 coupled to the upper surface of the prismatic cell 110, thereby isolating the space inside the convex part 633 surrounding the venting device 114 from the outside. Furthermore, the contact surface of the concave part 634 of the venting duct 632 and the upper surface of the prismatic cell 110 may be interposed with a heat-resistant insulating sheet 636, such as a mica sheet, to prevent the venting device 114 from being covered. The insulating sheet 636 thermally protects the contact surface of the concave part 634 and the prismatic cell 110 when high temperature gases, flames, particles, etc. are ejected by the rupture of the venting device 114, and allows the airtightness to be maintained longer.
The flow space inside the convex part 633 formed by the venting duct 632 forms a pathway for the combustion products ejected from the venting device 114 to travel, and each cell array 100 has one venting duct 632. That is, the plurality of prismatic cells 110 comprising the cell array 100 share one venting duct 632, and the venting duct 632 assigned to each cell array 100 is separate from each other. In this way, thermal runaway generated in any one battery block 10 is inhibited from propagating to the surrounding area, thereby preventing or delaying it from spreading to thermal propagation.
Further, the convex part 633 of the venting duct 632 has one side facing the side frame 620 of the pack case 602 forming a duct outlet 635, while the opposite side forms a closed surface. Referring to
Meanwhile, in the embodiment shown, the upper surface of the prismatic cell 110 has electrode terminals 112 on each side of the venting device 114. Since the electrical wiring between the plurality of prismatic cells 110 comprising the cell array 100 and the battery block 10 originates from the electrode terminals 112, it is necessary to secure the space required for the electrical wiring around the electrode terminals 112. To this end, the upper cover 630 is provided with a wiring duct 638 on either side of the venting duct 632 to form a space surrounding the electrode terminals 112 of the cell array 100, and the wiring duct 638 is preferably formed integrally by plastically processing the upper cover 630.
Here, as shown in
Referring to
In addition, the side plate 200 has concave surfaces 222 on either side of the bent plate, and the facing concave surfaces 222 are bonded to each other to form bonding ribs 220. These bonding ribs 220 are provided at least one along the longitudinal direction L of the side plate 200, and in the embodiment shown, a total of three bonding ribs 220 are formed at each end and in the center of the side plate 200.
A single plate bent in a “U” shape may have excellent durability and strength against compression and tension in the longitudinal direction L due to the bending structure, but may be relatively weak against forces in the height direction H. The bonding ribs 220 improve the rigidity of the side plate 200 to the force in the height direction H by connecting the concave surface 222 on both sides of the side plate 200 together by bonding through welding, riveting, or the like.
By such a structure of the side plate 200, i.e., a single plate structure bent in a “U” shape and a structure of the concave surface 222 bonded to each other, the side plate 200 is lightweight and has strong mechanical rigidity. Accordingly, in the battery block 10 of the present invention, the side plate 200 replaces the configuration of the cross beam conventionally provided in the battery pack 600, and the simplified structure of the battery pack 600 enables the space utilization rate of the battery pack 600 to be improved, further increasing the energy density in the same volume, and reducing the cost.
And, as shown in
The heat-absorbing/venting pouch 240 seals and stores an absorbent material 242 impregnated with a large amount of liquid, and the liquid impregnated with the absorbent material 242 absorbs the heat of the prismatic cell 110 transferred through the side plate 200. In other words, the heat-absorbing/venting pouch 240 has a heat capacity corresponding to the absorbed heat of the liquid impregnated with the absorbent material 242 and the latent heat that the liquid absorbs as it vaporizes when it exceeds its boiling point. The absorbed heat and latent heat of the liquid adds significant heat capacity to the side plate 200, allowing it to absorb more heat from the prismatic cell 110, further delaying the temperature rise of the prismatic cell 110.
The body of the heat-absorbing/venting pouch 240 may be manufactured using a flexible laminate sheet, which may be a three-or-more layer structure including an aluminum thin film layer, an inner resin layer formed on the inner side of the aluminum thin film layer, and an outer resin layer formed on the outer side of the aluminum thin film layer. For example, the inner resin layer may be unstretched casted polypropylene (CPP) or polypropylene (PP), and the outer resin layer may be polyethylene terephthalate (PET) or nylon.
And, when the liquid impregnated in a large amount in the absorbent material 242 contained in the heat-absorbing/venting pouch 240 absorbs the heat generated by the prismatic cell 110 and its temperature exceeds the boiling point and vaporizes, the rapid increase in volume due to the phase change from liquid to gas causes the heat-absorbing/venting pouch 240, which seals the absorbent material 242, to be under pressure. If the internal pressure exceeds the bursting strength of the heat-absorbing/venting pouch 240, a portion of the heat-absorbing/venting pouch 240 tears, releasing vapor. This discharge(venting) of the vapor allows the high-temperature prismatic cell 110 to cool once again.
Here, the heat-absorbing/venting pouch 240 may be configured such that the vapor that is discharged is appropriately directed so that it performs an effective cooling action. To accomplish this, a portion of the heat-fused sealing part 244 formed along the edge of the heat-absorbing/venting pouch 240 may be provided with a vulnerable part 246. The vulnerable part 246 is configured to preferentially fracture under increased pressure due to vaporization of the liquid by locally reducing the seal strength of the heat-fused sealing part 244. That is, the vulnerable part 246 may be formed in a manner that makes the heat fusion strength of the heat-fused sealing part 244 lower than the surrounding area. For example, the vulnerable part 246 can be made relatively thinner in thickness than the surrounding area or notched to reduce its strength, or it can be formed by locally removing the aluminum thin film layer that maintains the durability of the laminate sheet.
Meanwhile, in a first embodiment of the present invention, the absorbent material 242 may be an absorbent material 242 including a superabsorbent matrix, such as a superabsorbent polymer (SAP) or a superabsorbent fiber (SAF). Superabsorbent matrices can be porous or fibrous, capable of absorbing large amounts of liquid by exhibiting capillary action, while superabsorbent fibers can be manufactured in the form of fibers, such as nonwoven fabrics, by processing superabsorbent resins. The superabsorbent matrix can significantly increase the heat capacity of the side plate 200 as it can hold a large amount of liquid.
The specific types of superabsorbent resins and superabsorbent fibers made therefrom are not particularly limited in the present invention, but can be used without limitation as long as they have a high absorption capacity for fluids, in particular water. Examples of superabsorbent resins in the present invention include one or more selected from the group consisting of polyacrylic acid, polyacrylate, polyacrylate graft polymers, starch, cross-linked carboxymethylated cellulose, acrylic acid copolymers, hydrolyzed starch-acrylonitrile graft copolymers, starch-acrylic acid graft copolymers, saponified vinyl acetate-acrylic acid ester copolymer, hydrolyzed acrylonitrile copolymer, hydrolyzed acrylamide copolymer, ethylene-maleic anhydride copolymer, isobutylene-maleic anhydride copolymer, polyvinylsulfonic acid, polyvinylphosphonic acid, polyvinyl phosphoric acid, polyvinyl sulfonic acid, sulfonated polystyrene, polyvinylamine, polydialkylaminoalkyl (meth)acrylamide, polyethyleneimine, polyarylamine, polyarylguanidine, polydimethyldialylammonium hydroxide, quaternized polystyrene derivatives, guanidine-modified polystyrene, quaternized poly(meth)acrylamide, polyvinylguanidine and mixtures thereof, preferably crosslinked polyacrylic acid salts, crosslinked polyacrylic acid, and crosslinked acrylic acid copolymers, but it is not limited thereto.
The type of acrylic acid copolymer used as a superabsorbent resin in the present invention is not particularly limited, but may preferably be a copolymer including one or more comonomers selected from the group consisting of acrylic acid monomer and maleic acid, itaconic acid, acrylamide, 2-acrylamide-2-methylpropanesulfonic acid, 2-(meth)acryloylethanesulfonic acid, 2-hydroxyethyl(meth)acrylate, and styrenesulfonic acid.
In the present invention, the superabsorbent resin may have an absorption capacity for water of 10 g/g to 500 g/g, preferably 50 g/g to 200 g/g, but is not limited thereto. That is, each gram of the superabsorbent resin may absorb 10 g to 500 g of water, preferably 50 g to 200 g of water.
In the present invention, the greater the amount of water absorption of the superabsorbent resin, the better the duration of the cooling effect, but when the amount exceeds 500 g/g, the fluidity of the superabsorbent resin increases and it is difficult to maintain its shape, so that effective cooling cannot be exerted, and when the amount is less than 10 g/g, the duration of the cooling effect is too short to be effective.
And, in a first embodiment of the present invention, the liquid impregnated in the absorbent material 242 may be water. Water has the largest specific heat and latent heat of any readily available liquid. Therefore, water impregnated in the absorbent material 242 is suitable for application in the heat-absorbing/venting pouch 240 of the present invention because it absorbs a large amount of heat during its phase change to a gas, beginning even before it is vaporized.
Additionally, as shown in
The configuration of the heat-absorbing/venting pouch 240 disposed between the prismatic cells 110 follows the same as described above, except that the location of the vulnerable part 246 on the heat-fused sealing part 244 can be limited to the upper end edge. By disposing the vulnerable part 246 at the upper end edge of the heat-absorbing/venting pouch 240, in the event of a rupture of the vulnerable part 246, vapor can be ejected into the convex part 633 of the venting duct 632, and contact with the vapor can significantly reduce the risk of ignition or fire by reducing the temperature of the high temperature combustion products below their combustion point.
And, correspondingly, the insulating sheet 636 may have a venting slit 637 penetrated at a location corresponding to the vulnerable part 246 of the heat-absorbing/venting pouch 240. The venting slit 637 is intended to provide a flow path for vapor ejected through the vulnerable part 246, and for effective cooling of the combustion products, the vulnerable part 246 and the corresponding venting slit 637 need to be located within the flow space formed by the convex part 633 of the venting duct 632.
The present invention has been described in more detail above with reference to the drawings and embodiments. However, it is to be understood that the configurations shown in the drawings or embodiments described herein are only one embodiment of the invention and do not represent all of the technical ideas of the present invention, and that there may be various equivalents and modifications that may replace them at the time of filing the present disclosure.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2022-0168749 | Dec 2022 | KR | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/KR2023/019191 | 11/27/2023 | WO |
