The present disclosure relates to a method for synthesizing nominally-aligned arrays of carbon nanotubes (CNTs) to obtain a foam structure and to a method for controlling mechanical properties of the foam structure during a synthesis process. Moreover, the present disclosure relates to carbon nanotube foams with controllable mechanical properties.
Nominally-aligned arrays of carbon nanotubes (CNTs) are known to behave as low-density energy dissipative foams under compression. The material can be readily synthesized using standard thermal chemical vapor deposition techniques, resulting in a foam-like bulk material consisting of trillions of CNTs per square centimeter. However, these systems have remained largely unused in practical applications due to large variations in properties that result from the synthesis process.
According to a first aspect of the present disclosure, a method for synthesizing nominally-aligned arrays of carbon nanotubes (CNTs) is described, the method comprising determining synthesis parameters for synthesizing the CNTs; determining a relationship between at least one of the synthesis parameters and a diameter of the CNTs, wherein variation of the at least one of the synthesis parameters affects the diameter of the CNTs; establishing at least one operative value of the at least one of the synthesis parameters based on said relationship and with respect to the diameter to be obtained; and synthesizing the CNTs by applying the at least one operative value of the at least one of the synthesis parameters to obtain a foam structure of the nominally-aligned arrays of carbon nanotubes (CNTs).
According to a second aspect of the present disclosure, a method for controlling mechanical properties in a carbon nanotube foam structure is described, the method comprising synthesizing the carbon nanotube foam structure by carrying a precursor solution comprising a catalyst and a carbon source in a reaction zone by way of a carrier gas; and controlling or varying a concentration of the carrier gas to affect the mechanical properties of the carbon nanotube foam structure.
According to a third aspect of the disclosure, a method for controlling mechanical properties in a carbon nanotube foam structure is described, the method comprising synthesizing the carbon nanotube foam structure by carrying a precursor solution comprising a catalyst and a carbon source in a reaction zone by way of a carrier gas; and controlling or varying an input of precursor solution to affect the mechanical properties of the carbon nanotube foam structure.
According to a fourth aspect of the disclosure, a method for controlling mechanical properties in a carbon nanotube foam structure is described, the method comprising synthesizing the carbon nanotube foam structure by carrying a precursor solution comprising a catalyst and a carbon source in a reaction zone by way of a carrier gas including hydrogen to obtain the carbon nanotube foam structure; and controlling or varying a concentration of hydrogen in the carrier gas to affect the carbon nanotube foam structure and to control the mechanical properties of the carbon nanotube foam structure; and controlling or varying an input rate of the precursor solution to affect an average carbon nanotube diameter in the foam structure and to control the mechanical properties of the carbon nanotube foam structure.
According to a fifth aspect of the present disclosure, a method for synthesizing nominally-aligned arrays of carbon nanotubes (CNTs) is described, the method comprising synthesizing a foam structure of nominally-aligned arrays of carbon nanotubes (CNTs) by carrying a precursor solution comprising a catalyst and a carbon source in a reaction zone by way of a carrier gas to obtain the foam structure; and determining a relationship between a flow direction of the carrier gas carrying the precursor solution and a density of the foam structure; and synthesizing the CNTs by controlling the flow direction rate of the carrier gas in relation to a growth of the nominally-aligned arrays of carbon nanotubes to alter a density of the foam structure.
Further aspects of the disclosure are shown in the specification, drawings and claims of the present application.
Various embodiments of the present disclosure will now be described more fully with reference to the accompanying drawings. The words and phrases used in the present disclosure should be understood and interpreted to have a meaning consistent with the understanding of those words and phrases by those skilled in the relevant art. For example, in the present disclosure, the expression “nominally-aligned arrays of carbon nanotubes” can mean ordered structures or arrangements of nanotubes which naturally align themselves and are held together by van der Waals forces and lateral entanglement of the CNTs, which are not perfectly parallel (hence “nominally-aligned”). The alignment refers to “bundles” or “groups” of CNTs, and not specifically on the alignment of the individual tubes in the arrangement. In addition, the term “synthesis”, which is, for example, included in the expressions “synthesis process”, “synthesis parameters” or “method for synthesizing”, can mean a process in which volatile or gas-phase precursors including a carbon source react on a substrate, leading to nanotube growth. In some embodiments of the present disclosure, the synthesis is a process based on chemical vapor deposition (CVD). In particular, according to some embodiments of the present disclosure, CVD synthesis is achieved by taking carbon species in the gas phase and using an energy source, such as a plasma, a resistively heated coil or heat in general, such as the heat of a heated furnace, to impart energy to a gaseous carbon molecule. Commonly used gaseous carbon sources can include toluene, methane, carbon monoxide, and acetylene. The energy source can be used to “crack” the carbon molecule into a reactive radical species. These radical reactive species can then diffuse down to the substrate, which is heated and coated in a catalyst (usually a first row transition metal such as Ni, Fe, or Co) where it will bond. According to some embodiments, the synthesis of nominally-aligned CNTs can include a floating catalyst thermal chemical vapor deposition (TCVD) system that can include a reaction zone (furnace), a precursor solution including a catalyst and a carbon source, and a carrier gas to move the solution into the reaction zone. The synthesis of the CNTs can take place on a thermally oxidized surface, for example Si surface, placed inside the furnace prior to the reaction.
Elastomeric open cell foams are usually constructed out of polymeric materials and exhibit a hysteretic, energy-dissipative response under compression (
The remarkable electrical, thermal, and mechanical properties of nominally aligned carbon nanotubes (CNTs), including possessing the lowest strength-to-weight ratio of any known material have received much attention as researchers have endeavored to obtain benefits at the macro scale level from these promising objects [see reference 5, incorporated herein by reference in its entirety]. To this end, it has been observed that aligned arrays of multiwall CNTs synthesized in certain ways behave similar to elastomeric open cell foams, with the same three-regime deformation behavior and recovery from large strains [see references 3 and 4, incorporated herein by reference in their entirety]. Moreover, in comparing the performance of this material to that of typical polymeric foams of comparable density (0.1-0.3 g cm−3), it has been observed that the CNT foams dissipate at least 200 times the amount of energy in quasistatic compression tests conducted to 0.8 strain [see reference 1, incorporated herein by reference in its entirety]. Despite these promising characteristics, the typical CNT synthesis processes have resulted in enormous variability in the material properties, preventing their practical use.
According to some embodiments of the present disclosure, a process for synthesizing nominally-aligned arrays of carbon nanotubes (CNTs) is schematically shown in
The synthesis of the CNTs can take place on a thermally oxidized Si surface placed inside the furnace prior to the reaction. According to some aspects of the present disclosure, this setup can have many variables that could affect the resulting CNT arrays, including flow rate and composition of carrier gas, flow rate and composition of precursor solution, and temperature.
In particular, according to some embodiments of the present disclosure, general processes to control the resulting material properties both at a microstructural level (e.g., the average CNT diameter) as well as the bulk level (e.g., the foam's stiffness and energy-dissipation properties) are provided. These processes enable reproducibility in the manufacturing process and customizability toward applications by the tuning of the foam's mechanical properties. The result of one of these processes is also a new foam-like material with a customizable heterogeneous microstructure resulting in improved impact protection.
More in particular, according to a first aspect of the present disclosure, method for synthesizing CNTs can include a first controlling phase wherein the hydrogen concentration can be regulated by the flow rates to uniformly control the microstructure and mechanical properties of the resulting CNT foam. This first controlling phase is designated in
A relationship between the quantity of hydrogen gas used in the method for synthesizing the foam and the resulting mechanical properties of the foam can be established. The hydrogen concentration can determine the microstructure of the foam, specifically the average CNT diameter. Higher hydrogen concentrations produce smaller CNT diameters, resulting in softer material. This mechanism can act to affect the microstructure uniformly. It follows that according to some aspects of the present disclosure, the first controlling phase can be based on the effect of using different hydrogen concentrations in the carrier gas.
In particular, controlling the amount of hydrogen during floating catalyst chemical vapor deposition of vertically aligned arrays of carbon nanotubes can have significant structural and mechanical effects. Using a lower hydrogen concentration in the furnace feedstock can lead to the growth of stiffer CNT arrays with higher average bulk density, less uniform diameter distribution, and larger average CNT diameters (e.g., due to the growth of individual CNTs with a larger number of walls). A lower hydrogen concentration can also lead to the synthesis of CNT arrays that can reach significantly higher peak stresses at maximum strain, and that can absorb increased amounts of energy during compression. Both the overall height of the arrays and their strain recovery after compression have been found to be independent of hydrogen concentration during growth. The stress-strain curves for samples synthesized without hydrogen do not present the clear three-regime deformation behavior characteristic of CNT foams, which can likely be a result of the non-uniformity of the associated CNTs. In contrast, samples synthesized with higher amounts of hydrogen better conform to the stress-strain behavior exhibited by ideal foams. This study shows that using different concentrations of hydrogen during synthesis allows for the tuning of microstructural properties of (vertically aligned CNTs) VACNTs, including the ability to control the distribution of CNT diameters and the number of CNT walls, and consequently their mechanical response. This contributes to an understanding of the tunability of CNT-based materials, at microstructural and bulk levels, and it is expected to facilitate the design of new materials with tunable mechanical properties for many potential applications, such as protective foams and novel laminar structural composites.
According to further embodiments of the present disclosure, the alteration of carrier gas can have a direct effect on the microstructure of the CNT array by changing the average CNT diameter as evident when using scanning electron microscopy (SEM) and transmission electron microscopy (TEM) as shown in
In particular,
A detailed study of the first controlling phase is disclosed in [6] (Raney J R, et al. “Tailoring the microstructure and mechanical properties of arrays of aligned multiwall carbon nanotubes by utilizing different hydrogen concentrations during synthesis”, Carbon 2011; 49: 3631-3638), the disclosure of which is incorporated by reference in its entirety in the present application and partially reported in the following paragraphs under the section “Example of the first controlling phase”.
According to a second aspect of the present disclosure, a method for synthesizing CNTs can include a second controlling phase, wherein a syringe pump can control the injection rate of the liquid phase precursor solution and thereby controlling the heterogeneous density distribution of the material. This second controlling phase is designated in
The second controlling phase allows one to introduce non-uniform structural changes in such foams. By varying the input rate of the carbon/catalyst solution during synthesis, softer, lower density regions can be formed along the height of the structure, which correspond to areas of lower average CNT diameters. Higher precursor input rates can result in the softer regions, and lower input rates can correspond to stiffer regions. In contrast to the first controlling phase, the second controlling phase therefore can affect the desired regions of the foam, resulting in the ability to construct a heterogeneous foam with stiffer or softer regions along the height where desired. In other words, the second process can tailor compressive strain localization along the height of an array and thereby improve impact energy dissipation through the introduction of micro scale heterogeneities during the synthesis process by variations in the input rate of catalyst and carbon precursors.
The result of the second controlling phase can be a new material with controllable soft regions. When the foam is compressed after synthesis, the softer regions are observed to buckle earlier than the rest of the foam, displaying strain localization. This effect can be used to create new light-weight foams with heterogeneous density distributions that improve the performance of the material under low velocity impact. This material can be further used as a thin protective layer designed to protect critical systems from low energy collisions.
In particular, the input rate of the catalyst solution, as controlled by the programmable syringe pump shown in the diagram in
In particular,
Comparing
More in particular, in
Additionally, region II can be lengthened or shortened in order to increase or decrease, respectively, the thickness of the low density region. However, this does affect the mechanical properties which will be discussed later in the following paragraphs.
In particular,
A detailed study of the second controlling phase, and study of a resulting new foam-like heterogeneous material, is disclosed in Raney J R, et al. “Control of microstructural heterogeneities in arrays of aligned carbon nanotubes for tailored strain localization and improved impact energy dissipation”, which is part of the U.S. provisional application 61/512,318 for “Carbon Nanotube Foams with Controllable Mechanical Properties” filed on Jul. 27, 2011, (mentioned above) and also described in the following paragraphs under section “Example of the second controlling phase”.
According to a third aspect of the present disclosure, a method for synthesizing CNTs can include a third controlling phase which relates to a control on a position of CNTs sections on a growth substrate with respect of the carrier gas flow directions. In particular, CNT arrays grown in the substrate's sections closer to the gas inlet could have higher densities. A study on the effect of the carrier gas flow carrying the precursor on the structural and mechanical properties of vertically aligned CNT arrays, and on the effects of non-covalent functionalization of the CNT surfaces on the bulk mechanical response of the arrays in compression is disclosed in [22], Misra A, Raney J R, Craig A E, and Daraio C, Nanotechnol. 22, 425705 (2011), for “Effect of density variation and non-covalent functionalization on the compressive behavior of carbon nanotube arrays”, the disclosure of which is also incorporated herein by reference in its entirety. An embodiment of the present disclosure relating to the third controlling phase is also described in the following paragraphs under section “Example of the third controlling phase”.
According to further embodiments of the present disclosure, a method for synthesizing nominally-aligned arrays of carbon nanotubes (CNTs) and for controlling the mechanical properties of a foam structure of CNTs can include a combination of any one of the controlling phases of the group including the first controlling phase and/or the second controlling phase and/or the third controlling phase.
It can be noted each of the procedures outlined in the present disclosure and/or a combination of these procedures allow for one to tune the material over a wide variety of compressive responses, with the stress level of the plateau able to be altered by a factor of about 10. This means that these procedures could be used for a wide variety of applications over a comparable range of protective thresholds.
In addition, it can be noted that all of the procedures outlined above involve the tuning of parameters during CNT synthesis to alter the final structural and mechanical properties of the system. In combination with the first controlling phase and/or the second controlling phase and/or the third controlling phase, additional parameters can be utilized during CNT synthesis to tune the diameters of the CNTs. Because a relationship between average CNT diameter and the resulting bulk mechanical response of CNT arrays has been established, these other parameters are expected to have similar effects to those of the hydrogen concentration (i.e., the first controlling phase) and therefore can be combined with the first controlling phase or to the other controlling phases. For example, changing the temperature can affect the CNT diameters. Similarly, the concentration of catalysts can also affect CNT diameter, with more catalysts leading to larger CNT diameters, in general. It follows that these parameters are therefore an additional way in combination with the first controlling phase and/or the second controlling phase and/or the third controlling phase to tune the structure of the system, and thereby the mechanical response.
Vertically aligned arrays of multiwall CNTs (VACNTs) were synthesized by floating catalyst thermal chemical vapor deposition at atmospheric pressure. The system utilized a long quartz furnace tube with a 4.1 cm internal diameter and a 15 cm heating zone. The temperature of the heating zone was 825° C. A thermally oxidized Si wafer was used as the substrate for CNT growth. A solution of ferrocene (the Fe catalyst precursor) and toluene (the carbon source) were mixed at a ratio of 0.02 g ml−1. A total of 50 ml of this solution was injected into the furnace at ˜1 ml min−1. Synthesis cycles were performed with different quantities of hydrogen, varying from 0 to 400 sccm in 80 sccm increments (corresponding to concentrations from 0% to 50% of the total gas flow), with argon flow adjusted correspondingly from 800 to 400 sccm to maintain a total combined gas flow rate of 800 sccm. The amount of hydrogen used was fixed during each synthesis cycle. In other words, a carrier gas composition was therefore altered from 100% argon, 0% hydrogen to 50% argon, 50% hydrogen while keeping the total gas flow rate constant. The result of this process was arrays of VACNTs with total thickness (e.g., height along the CNT axis) of ˜1 mm. The thick VACNT arrays were resilient against handling and could be physically manipulated. Prior to any mechanical testing, VACNTs on their growth substrate were sectioned into square areas of ˜16 mm2. The VACNTs were subsequently removed from the growth substrate, to which they were only weakly bonded, with a razor blade. The mass of each sample was measured with a microbalance. The sample height (along the long CNT axis) was determined using a commercial materials tester (INSTRON® E3000). A small preload of about 0.2 N (˜0.12 MPa for the present samples) was used on all samples to ensure uniform contact. The apparatus measures displacement in 1 μm increments, resulting in an uncertainty of ˜0.1% for the present samples (˜1 mm thick). The volume of each sample was obtained by multiplying the sample height by the corresponding cross-sectional area. Bulk density was then calculated by dividing the mass by the corresponding volume of each sample. The average bulk density of samples grown with no hydrogen in the feedstock was 0.229 g cm−3. However the bulk density was observed to vary with the sample's spatial position in the growth substrate. Higher densities were observed for CNTs grown on substrate areas closer to the entrance of the flowing gases, as reported in [22] and which is the subject of the third controlling phase.
Quasistatic cyclic axial compression was performed with the same apparatus (INSTRON® E3000), along the axis of the VACNTs. The stress-strain response was measured up to a set maximum compressive strain of 0.8 (chosen to avoid exceeding the force capacity of the apparatus), with a constant strain rate of 0.01 s−1 for both loading and unloading.
Scanning electron microscopy (SEM) was conducted with a FEI Sirion at 15 kV on as-grown samples that had been removed from the growth substrate. Transmission electron microscopy (TEM) was performed using a FEI TF30UT at 300 kV. Samples were prepared for TEM by placing a small amount of the VACNTs into isopropyl alcohol and sonicating until the CNTs were dispersed. A small drop of this solution was placed on a TEM grid and the isopropyl alcohol was evaporated. Raman spectroscopy was performed with a RENISHAW® M1000 Micro Raman Spectrometer System using an Argon ion laser of wavelength 514.5 nm on samples removed from the substrate.
After completing synthesis of VACNTs using six different hydrogen concentrations (0-50% in 10% increments) the resulting samples were characterized by SEM and TEM, as shown in
At the macro scale level, the average height of the VACNTs does not change significantly with variations in the hydrogen concentration. However, their bulk density presents visible changes when the amount of hydrogen is varied in the feedstock (
A similar effect was observed in studies of floating catalyst systems with other additives instead of hydrogen (see reference [5]), and also in studies of the effects of hydrogen in plasma-enhanced CVD systems [see reference [11], incorporated herein by reference in its entirety]. The decline in the CNTs' outer diameters, from an average of ˜46 nm for 0% hydrogen to ˜19 nm for 50% hydrogen, corresponds to a change in the number of walls from ˜56 for 0% hydrogen to ˜18 for 50% hydrogen. The observed trend in the decline of CNTs' diameters is in agreement with earlier reports for CNTs grown in a CVD system with a predeposited catalyst (see references [12], [13], [14], incorporated herein by reference in their entirety). It has been shown that introducing hydrogen into thermal CVD systems narrows Fe catalyst particles [12] and that this results in CNTs of smaller diameters (see again reference [12], and see references [15], [16], [17], incorporated herein by reference in their entirety). This effect was expected to be the primary reason why the present CNTs become narrower with increasing hydrogen concentration in the furnace. In order to rule out the possibility of hydrogen-induced etching as the cause of the observed smaller diameters, already-synthesized CNTs were placed back in the presence of hydrogen in synthesis conditions. Any perceptible etching or narrowing of the CNTs were not observed. Thus, the hydrogen can alter the CNT diameters when it is present during synthesis, affecting the catalyst. It was a concern that increasing hydrogen concentrations could cause defects in the CNT walls (see reference [18] incorporated herein by reference in its entirety). Raman spectroscopy measurements were performed to provide more quantitative information on the possible formation of defects induced by hydrogen (e.g.,
Quasistatic cyclic compression tests were performed to characterize variations in the mechanical properties of the VACNTs induced by the presence of hydrogen during the synthesis process (and by the related microstructural changes). All samples tested were of similar size and geometry, though it should be noted that VACNTs appear to exhibit compressive behavior that is independent of the geometry of the array (see reference [21] incorporated herein by reference in its entirety). Results for a loading and unloading cycle obtained from a sample grown with 0% hydrogen are shown in
If the CNTs are approximated as Euler columns (as they can be when their length greatly exceeds their radius (see reference [9], incorporated herein by reference in its entirety)), their critical buckling stress can be expected to be proportional to the square of the radius. An array of Euler columns of different diameters will not buckle at a single stress value. As a consequence, CNTs that are synthesized with a large amount of hydrogen with small diameter variations within the array (e.g., a diameter distribution with a standard deviation of less than 5 nm for the 50% hydrogen case) should buckle more uniformly compared to those synthesized without hydrogen (e.g., with a much wider diameter distribution, with a standard deviation of 17 nm). This analysis is in qualitative agreement with the results displayed in
As described earlier, the density of the VACNT arrays taken from a given substrate varies with position. Higher densities are measured for samples taken from areas of the growth substrate closer to the entrance of the gases in the furnace. For any given hydrogen concentration, the energy absorption of each VACNT array depends nearly linearly on this density variation. A similar relationship has been observed for VACNTs in the variation of peak stress with density (see reference [26]). However, it is interesting to note that two VACNT samples with the same bulk density, but synthesized with different concentrations of hydrogen, will typically absorb slightly different amounts of energy in compression, revealing that bulk density alone is not a sufficient predictor of mechanical properties. In other words, a separate linear relationship between bulk density and energy absorption exists for each hydrogen concentration utilized.
According to further aspects of the present disclosure, the process of synthesizing can include establishing a relation between an input rate of the catalyst solution and the diameter of the CNTs.
Specifically, millimeter-scale arrays of CNTs on thermally oxidized Si substrates can be synthesized using a floating catalyst CVD system in a flow of argon at 825° C. In contrast with fixed catalyst systems, in which a catalyst layer is deposited on the growth substrate prior to CNT synthesis, floating catalyst systems continuously input catalyst along with the carbon source. As reported in detail in reference [6], the disclosure of which is incorporated herein by reference in its entirety in the present disclosure, a solution of ferrocene has been used (Fe catalyst precursor) and toluene (carbon source). Non-constant input rates for the precursor solution has been used, controlled by a programmable syringe pump. When high injection rates (e.g., several ml min−1) are used in bursts of a few minutes or less, it has been observed that a corresponding softer region results in the final CNT structure. Using high resolution scanning electron microscopy (SEM), it has been observed that the CNTs in these softer regions have a lower average diameter than the CNTs in regions synthesized with slower injection rates (e.g., ˜30 nm for the former and ˜43 nm for the latter), but statistically similar areal densities as estimated by a count of the number of CNTs per unit length across the structure. This may be related to the “lengthening-thickening” two stage growth process that CNTs have been previously observed to undergo (see reference [26]).
According to this understanding, in the initial stages of synthesis, CNTs lengthen rapidly but remain of narrow diameter. Later in the process, the diameter begins to rapidly increase, with the rate of lengthening concomitantly declining (see reference [26]). At the other extreme, the precursor input rate can be set to zero by pausing the injection system, depriving the heating zone simultaneously of any new carbon or catalyst. If the system is starved of precursor solution in this way, higher density regions of lateral entanglement (poor CNT alignment) arise (see references [7], [8]). An input rate profile corresponding to a particular CNT growth cycle is shown in
As is typical for arrays of CNTs synthesized using floating catalyst techniques (see references [3], [23], [6], and reference [27] incorporated herein by reference in its entirety), arrays synthesized with a constant input rate and those synthesized with varying input rates recover to most of their original height after large compressive strains. In order to observe the manner of collapse in the system under compression, a steel vise was used to hold the arrays in a compressed state to allow for SEM imaging.
Additional samples were synthesized with different carbon/catalyst solution input rate profiles. For the simplest cases, samples were synthesized with only one of the low density “dark bands” described above. This was accomplished by using a three-part input rate profile using the programmable syringe pump. The three steps (I-III) are depicted in
By changing the relative times for step I and step III (e.g., the “normal” synthesis rate before and after the low density band, respectively), the ultimate location of the low density region could be adjusted along the height of the CNT array. This allowed for the control of strain localization under compression.
Other input rate profiles were used to construct samples with multiple low density bands by repeating steps II and III in the above scheme multiple times, samples with low density bands of different thicknesses by varying the length of time for step II above, and samples with increased discreteness between low-density and normal-density regions by varying the amount of time that the input rate was paused between steps I/II and between steps II/III above. In addition to the quasistatic observations (e.g., the SEM images in
Though samples of a wider range of heights (0.6-1.4 mm) and bulk densities (0.15-0.35 g cm−3) were synthesized, only those samples near the desired height and density were used so that additional variables were not introduced. The testing apparatus was activated with a switch that simultaneously triggered a solenoid to release the striker and started a PHANTOM® high speed camera recording at 20 kHz. The falling striker was imaged by the camera before, during, and after impact, allowing the calculation of the striker's trajectory and the associated restitution coefficient (e.g., the ratio of the incoming and outgoing striker velocities). The apparatus includes a force sensor (e.g., PCB Piezotronics) underneath the sample, activated by the onset of dynamic force as a result of the striker's impact. This gives a force-time profile for each test. With the restitution coefficient readily calculated for each test using the images from the high speed camera, energy conservation principles allowed a value to be calculated for the amount of energy dissipated during each collision. The percent of incoming striker kinetic energy that was dissipated in each test was used as a figure of merit for the different types of samples.
Although
The data for force as a function of time is approximated as the instantaneous force on the impacting sphere, ignoring the effects of stress-wave propagation as a first order approximation. Striker velocity as a function of time is determined by integrating this data in Newton's second law, using the incoming velocity of the striker as determined by the high speed camera as the integration constant corresponding to the initial velocity. Finally, this is integrated once more to obtain displacement as a function of time, with the initial position (onset of force) defined as zero position. The striker displacement into the samples is ˜20-30% higher for the samples with bands than for those without bands (
A second contribution to energy dissipation that results from the low density bands is an increase in permanent deformation in samples containing them. Control samples without these bands show less damage after impact. This was confirmed with SEM imaging after the impact tests. It was also confirmed by repeated impact events in the same location for each sample, which revealed that after the first one or two impact events, the sample performance quickly declines as defined by decreased energy dissipation and increased peak force, thus becoming approximately the same as the control samples. It is important to note that this compaction is highly localized. If the striker impacts a portion of the sample even a couple millimeters from a previous impact site then dissipation proceeds as if the sample had not been impacted previously.
The softer region appears to become somewhat compacted, losing its benefit after a few strikes. Accordingly, the trend for energy dissipation (
In addition to the effect on impact energy dissipation that arises from increased striker displacement and sample permanent deformation, a third effect due to resulting changes in stress wave propagation was also expected from the bands. It has been observed in other systems with layers of varying densities that these can greatly affect stress-wave propagation in high (e.g., blast loading) (see reference [29], incorporated herein by reference in its entirety) and moderate (low kinetic energy impact tests such as the tests of the present disclosure) (see reference [30], incorporated herein by reference in its entirety) strain rate conditions. Depending on how the stress wave amplitude compares to the local yield stress, the variations in density can result in changes to both the shape of the stress wave as well as the net energy dissipated (see reference [31], incorporated herein by reference in its entirety).
Other groups have synthesized banded CNT arrays by starting and stopping the injection of the solution of carbon source and catalyst. This may be a factor in the present systems but it requires further study to understand its relative importance, as little has been reported regarding stress wave propagation in aligned CNTs (see reference [32], incorporated herein by reference in its entirety) or by dropwise synthesis (see reference [32], and reference [33] incorporated herein by reference in its entirety). With both approaches, however, the layers were found to separate easily [32].
In the present case, it was found that there is much better continuity and adhesion between layers (similar to a study for a fixed catalyst system in which acetylene gas was used as a pulsed carbon source to synthesize sub-micron size bands (see reference [24], incorporated herein by reference in its entirety)) for both the present “discrete” and “continuous” cases. This was quantified by testing the samples in tension. Two factors are likely to promote improved continuity and adhesion even in the present “discrete” case. First, rather than abruptly shutting off the injection of precursor solution, some residual evaporation of precursor continues for roughly half a minute due to the buildup of a small pool of precursor in the present system directly in front of the heating zone of the furnace. Second, rather than pausing the system for 10-15 minutes (see references [8], [32]) or even longer (see reference [25], incorporated herein by reference in its entirety), the precursor flow has been kept off for a few minutes at a time. If the input of the precursors completely stopped for more than 10-15 minutes, then the layers readily separated even with light handling. Thus, the continuity of the CNTs between layers and, as a result, the interlayer strength appears to depend on the time that the structure is deprived of precursor solution.
Since mechanical performance such as dissipation of impact energy was actually superior in the “continuous” case relative to the “discrete” case, there is little reason to not synthesize samples of the “continuous” type, which, with their more gradual boundaries between layers would be expected to have even better interlayer adhesion. It has been also studied how the height of the band affects the mechanical performance by changing the amount of time during synthesis that the high input rate of precursor solution was used. The resulting samples were tested under impact, and the band sizes were determined using SEM. All samples were of “discrete” type in order to facilitate accurate measurement of band height. The results are shown in
Moreover, since mechanical performance such as dissipation of impact energy was actually superior in the “continuous” case relative to the “discrete” case, there is little reason to not synthesize samples of the “continuous” type, which with their more gradual boundaries between layers would be expected to have even better interlayer adhesion (see reference [31]). It is also worth noting that some samples of the “continuous” type performed better than the maximum performance shown in
By varying the input rate of the precursor solution (containing both the carbon source and the catalyst precursor necessary for CNT synthesis) into a CVD furnace, CNT arrays can be synthesized with a heterogeneous structure. Higher precursor input rates lead to softer regions with lower average CNT diameter, which are observed to buckle earlier than higher density regions when the structure is subject to compression. As a result, strain can be controllably localized in a compressed CNT array.
Vertically aligned arrays of carbon nanotubes were grown using a floating catalyst TCVD method. The microstructure of the resulting arrays was highly hierarchical: at the mesoscale, CNT bundles grew vertically away from the substrates; at the micro-scale (within these bundles), the individual CNTs grew highly entangled with their neighbors. The TCVD system used included a single furnace utilizing a quartz tube through which the precursor vapors passed into the heating zone. Source precursors (0.02 g ferrocene per milliliter of toluene) were fed directly into the quartz tube before entering the heating zone. The growth substrates consisted of silicon wafers with a 1 μm thick thermal oxide layer (area ˜3×2 cm2), and were placed at the center of a high temperature (825° C.) zone in the furnace. After the growth was completed, small sections of the CNT arrays (˜7×7 mm2) were separated from the substrates using a razor blade, to obtain freestanding samples for the testing. The bulk densities of the freestanding samples were calculated by dividing the measured mass of each sample by its measured volume. The density of the CNT samples was found to vary between 0.12 and 0.28 g cm−3, depending on the position of the CNT sections on the growth substrate with respect to the carrier gas flow direction (CNT arrays grown in the substrate's sections closer to the gas inlet had higher densities). The CNT arrays were functionalized by two methods: in the first one, the CNT arrays were first separated from the growth substrate and then they were wetted in 15 ml of volatile acetone containing 0.02 g of dispersed silica nanoparticles (with diameters ˜10-20 nm); in the second one, the CNT arrays were also first separated from the growth substrate and then they were immersed in acetone containing sodium dodecyl sulfate (SDS) instead of the silica (SiO2) particles. The solutions containing acetone and nanoparticles or surfactant were ultrasonicated for 30 min to obtain uniform dispersions. The freestanding CNT samples were soaked in the ultrasonicated solutions for 24 h and they were dried for the next 24 h. The schematic diagrams in
With reference to
An example of a fourth controlling phase includes a combination of any one of the examples of the first controlling phase and/or the second controlling phase and/or the third controlling phase disclosed in the paragraphs reported above.
The examples set forth above are provided to give those of ordinary skill in the art a complete disclosure and description of how to make and use the embodiments of the disclosure, and are not intended to limit the scope of what the inventors regard as their disclosure. Modifications of the above-described modes for carrying out the disclosure may be used by persons of skill in the art, and are intended to be within the scope of the following claims. All patents and publications mentioned in the specification may be indicative of the levels of skill of those skilled in the art to which the disclosure pertains. All references cited in this disclosure are incorporated by reference to the same extent as if each reference had been incorporated by reference in its entirety individually.
It is to be understood that the disclosure is not limited to particular methods or systems, which can, of course, vary. It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments only, and is not intended to be limiting. As used in this specification and the appended claims, the singular forms “a,” “an,” and “the” include plural referents unless the content clearly dictates otherwise. The term “plurality” includes two or more referents unless the content clearly dictates otherwise. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which the disclosure pertains.
A number of embodiments of the disclosure have been described. Nevertheless, it will be understood that various modifications may be made without departing from the spirit and scope of the present disclosure. Accordingly, other embodiments are within the scope of the following claims.
The present application is a Divisional of U.S. application Ser. No. 13/491,014 filed on Jun. 7, 2012, which is incorporated herein by reference in its entirety, which, in turn claims priority to U.S. provisional application 61/512,318 for “Carbon Nanotube Foams with Controllable Mechanical Properties” filed on Jul. 27, 2011, which is incorporated herein by reference in its entirety.
This invention was made with government support under W911NF-09-D-0001 awarded by United States Army. The government has certain rights in the invention.
Number | Date | Country | |
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61512318 | Jul 2011 | US |
Number | Date | Country | |
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Parent | 13491014 | Jun 2012 | US |
Child | 14700035 | US |