Catalytic composition for photopolymerization and a photopolymerizable composition containing the same

Abstract

The present invention relates to a catalytic composition for photopolymerization, which comprises an alpha-diketone and a hydrazone or a silane compound which has a silicon atom carrying a hydrogen, and also relates to a photopolymerizable composition which comprises a vinyl compound capable of radical polymerization and the above catalytic composition. The catalytic composition is markedly improved in photopolymerization activity and the photopolymerizable composition uniformly cures.

Description

This invention relates to a catalytic composition for photopolymerization, which comprises an alpha-diketone and a hydrazone or a specific silane compound, and also relates to a photopolymerizable composition which contains the above catalytic composition. The photopolymerizable composition can be used for adhesion, fastening or sealing of metal, ceramic or plastic parts, fixation of joints of such parts, or the like.

Photopolymerizable compositions are compositions which are stable in unhardened state for a long time while light is being shielded, but polymerize and cure in use by exposure to ultraviolet or visible light. As photopolymerizable compositions, conventionally known are those which mainly comprise vinyl compounds capable of radical polymerization and to which photopolymerization catalysts are added.

However, since photopolymerization reaction progresses from the surface which is directly irradiated with light, photopolymerizable compositions harden well on the irradiated surface but tend to insufficiently harden in the deep inside so that unevenness in physical properties occurs in hardened bodies. This tendency is especially pronounced in the case of dental treatment in which visible light, which is minimal in beam energy, is used in view of safety for human body. As a result, vinyl compounds often remain unpolymerized at the boundary between an adherend and a photopolymerizable composition remote from the surface irradiated with light, and thus adequate adhesion to the adherend cannot be obtained, or upon an environmental test, unpolymerized vinyl compounds bleed to cause adhesion strength to gradually decrease.

There are various photopolymerization catalysts, for example, benzoin compounds such as benzoin, benzoin methyl ether and benzoin ethyl ether; carbonyl compounds such as camphorquinone, benzil, benzophenone, acetophenone and Michler's ketone; azo compounds such as azobisisobutyronitrile and azodibenzoyl; sulfur compounds such as dibenzothiazolyl sulfide and tetraethyl thiuram disulfide; and the like. However, since these catalysts are all low in sensitivity, they have not solved the aforementioned problems.

It is an object of the present invention to provide a catalytic composition for photopolymerization and a photopolymerizable composition comprising a vinyl compound capable of radical polymerization, which can solve the aforementioned problems because hardening reaction progresses not only on the directly-irradiated surface but also into the deep inside, upon exposure to ultraviolet or visible light.

As a result of intensive researches to solve the aforementioned problems, the present inventors found that when a composition comprising an alpha-diketone and a hydrazone or a specific silane compound is added to a vinyl compound capable of radical polymerization, hardening reaction rapidly takes place with light irradiation and progresses into the deep inside.

That is, the present invention relates to a catalytic composition for photopolymerization, which comprises an alpha-diketone, a hydrazone or a silane compound in which a silicon atom is linked with a hydrogen atom, and to a photopolymerizable composition which comprises the above catalytic composition and a radical-polymerizable vinyl compound.

Hereinafter, a detailed explanation is given of each ingredient of the present catalytic composition for photopolymerization and of the present photopolymerizable composition containing that catalytic composition.

Alpha-diketones

Alpha-diketones used as a component of the present catalytic composition for photopolymerization are those which function as a photopolymerization initiator absorbing a light within the near-ultraviolet through visible range. Preferred are the compounds shown in the following general formula (A): ##STR1## wherein X and Y, which may be identical with or different from each other, represent a substituted or unsubstituted alkyl, alkenyl or aryl group, having 1 to 24 carbon atoms, and X and Y may form a ring structure by linking with each other.

Specific examples of the alpha-diketones used in the present invention are camphorquinone, benzil, 1,2-(1-naphtyl)-1,2-ethanedione, acenaphthene quinone; benzil substituted with halogen or alkoxy such as p,p'-dimethoxybenzil and p,p'-dichlorobenzil; biacetyl, pentanedione, 1,2-phenanthrenequinone, 3,4-phenanthrenequinone, 9,10-phenanthrenequinone, and 1,2-naphthoquinone. Among them, especially preferred is camphorquinone. However, the alpha-diketone used in the present invention is not limited only to the above-listed compounds. These compounds may be used singly or in combination with two or more of them.

Hydrazones

Hydrazones are compounds containing in molecule the structure denoted by --NH--N.dbd.C<, and are used as a component of the present catalytic composition for photopolymerization in combination with alpha-diketones.

Hydrazones, which contain in molecule the structure denoted by --NH--N.dbd.C<, can readily be obtained by dehydration-condensation of a carbonyl compound having 1-24 carbon atoms and hydrazine or a substituted compound thereof denoted by Z--NH--NH.sub.2 wherein Z is a substituted or unsubstituted alkyl, alkenyl, alkylsulfonyl, aryl or arylsulfonyl group, having 1-20 carbon atoms.

The carbonyl compound which is used in synthesis of hydrazones includes camphorquinone, benzil, 1,2-(1-naphtyl)-1,2-ethanedione, acenaphthene quinone; benzil substituted with halogen or alkoxy such as p,p'-dimethoxybenzil and p,p'-dichlorobenzil; biacetyl, 1,2-phenanthrenequinone, 1,4-phenanthrenequinone, 3,4-phenanthrenequinone, 9,10-phenanthrenequinone, naphthoquinone, 2,3-butanedione, 2,3-pentanedione, 1,2-cyclohexanedione, 1,3-cyclohexanedione, acetone, acetaldehyde, butyraldehyde, benzaldehyde, acetophenone, chloroacetophenone, trifluoroacetophenone, benzophenone, benzoin, benzoin methyl ether, and benzoin isopropyl ether. However, these compounds are merely examples.

Examples of hydrazine or its substituted compounds are p-toluenesulfonylhydrazide, 4,4'-oxybis(benzenesulfonylhydrazide), benzenesulfonylhydrazide, benzoic hydrazide, succinic dihydrazide, oxamic hydrazide, methylhydrazine, and phenylhydrazine. However, these compounds are merely examples.

In the present invention, any of the reaction products of such carbonyl compounds and hydrazine or substituted compounds thereof as mentioned above may be used as a hydrazone. However, preferred are camphorquinone p-toluenesulfonylhydrazone which is a reaction product of camphorquinone and p-toluenesulfonylhydrazide, and the following reaction products of carbonyl compounds and substituted compounds of hydrazine: a reaction product of camphorquinone as carbonyl compound and 4,4'-oxybis(benzenesulfonylhydrazide), benzoic hydrazide or benzenesulfonylhydrazide as substituted hydrazine; a reaction product of benzil as carbonyl compound and p-toluenesulfonylhydrazide, oxamic hydrazide, benzoic hydrazide or 4,4'-oxybis(benzenesulfonylhydrazide) as substituted hydrazine; a reaction product of acetone as carbonyl compound and p-toluenesulfonylhydrazide or oxamic hydrazide as substituted hydrazine; a reaction product of acetaldehyde, benzaldehyde, acetophenone, chloroacetophenone, trifluoroacetophenone or the like as carbonyl compound and p-toluenesulfonylhydrazide as substituted hydrazine; a reaction product of 2,3-pentanedione as carbonyl compound and p-toluenesulfonylhydrazide as substituted hydrazine; and a reaction product of 2,3-butanedione as carbonyl compound and p-toluenesulfonylhydrazide as substituted hydrazine.

In the present invention, the above-mentioned compounds may be used alone or in combination with two or more thereof.

Silane compounds

Silane compounds having a silicon atom which carries a hydrogen atom are used as a component of the present catalytic composition for photopolymerization in combination with alpha-diketones. The silane compounds have, in molecule, a structure of --SiHRaRb or --SiHRc-- wherein Ra, Rb and Rc, which may be identical with or different from each other, represent a hydrogen or a substituted or unsubstituted alkyl, alkenyl, aryl, alkoxy, acyloxy or amino group, having 1-22 carbon atoms.

For example, a silane compound which contains in molecule two or more silicon atoms possesses a linkage such as --Si--Si-- and --Si--Z--Si-- wherein Z is a di- or more valent residue such as of oxygen, nitrogen, an alkyl group and an aryl group. In this case, the present invention requires such a silane compound to be one in which at least one of their silicon atoms have the structure of "--SiHRaRb" or "--SiHRc--".

In addition to Ra, Rb and Rc, silicon atoms may carry any element in the silane compounds. However, a silane compound in which a silicon atom carries a halogen atom such as chlorine is not preferred because the halogen atom tends to deteriorate the effect of photopolymerization acceleration.

The number of the silicon atoms contained in one molecule of the silane compound is not limited. In the present invention, preferred examples of the silane compounds are methyl silane, ethyl silane, butyl silane, hexyl silane, ethyldimethyl silane, diethyl silane, trimethyl silane, triethyl silane, hexyl silane, octadecyl silane, phenyl silane, diphenyl silane, triphenyl silane, methylphenyl silane, phenyldimethyl silane, diphenylmethyl silane, phenyldiethyl silane, phenyldipropyl silane, benzyldimethyl silane, p-bis(dimethylsilyl)benzene, 1,1,1-trimethyldisilane, tris(dimethylsilyl)amine, diethyl(dimethylsilyl)amine, methyldiacetoxy silane, hexamethyl-1,5-dihydrotrisiloxyane, methyldimethoxy silane, dimethylethoxy silane, diethoxy silane and triethoxy silane. However, these compounds are merely examples.

Silane coupling agents, which are used to enhance adhesion between organic substances and inorganic substances, are similar in structure to the silane compounds of the present invention. However, the silane coupling agents cannot be used in the present invention nor expected to achieve the effect of the present invention because they do not have any silicon atom which carries a hydrogen atom.

In the present invention, silane compounds as listed above may be used singly or in combination with two or more thereof.

Composition ratio

Composition ratio of the alpha-diketone and the hydrazone or the silane compound, which constitute the present catalytic composition for photopolymerization, depends upon conditions in use. Preferably, the present catalytic composition comprises 1-99% by weight of alpha-diketone and 99-1% by weight of hydrazone or silane compound. More preferably, it comprises 2-90% by weight of alpha-diketone and 98-10% by weight of hydrazone or silane compound.

When the present catalytic composition is employed for photopolymerization of a vinyl compound capable of radical polymerization, the amount of the former to be added to the latter depends on conditions in use. Usually, the present catalytic composition for photopolymerization is added in an amount of preferably 0.01-30 parts by weight, more preferably 0.05-20 parts by weight, most preferably 0.05-10 parts by weight based on 100 parts by weight of the vinyl compound.

It is not clear how the photopolymerization accelerators used in the present invention function upon polymerization. It is, however, assumed that the photopolymerization accelerators promote radical initiation caused by dehydrogenation or decomposition of alpha-diketones excited by absorption of light within the near-ultraviolet to visible range.

Vinyl compounds capable of radical polymerization

Any vinyl compound can be used in the present invention as long as it can be radical-polymerized by addition of the present catalytic composition for photopolymerization and irradiation of light. Specific examples of the vinyl compounds are shown below:

Vinyl compounds (1)

(Meth)acrylates shown by the following formula (1). ##STR2## wherein R.sup.1 is hydrogen or --CH.sub.3, R.sup.2 is a straight- or branched-chain alkyl group of 2-4 carbon atoms in which at least one hydrogen atom is substituted with --OH group and/or halogen atom.

Examples of the (meth)acrylates of the formula (1) are 2-hydroxyethyl(meth)acrylate, 2-hydroxypropyl(meth)acrylate, 1,2-dihydroxyethyl(meth)acrylate, 3-chloro-2-hydroxypropyl(meth)acrylate and the like.

Vinyl compounds (2)

(Meth)acrylates shown by the following formula (2). ##STR3## wherein R.sup.3 is hydrogen, --CH.sub.3, --C.sub.2 H.sub.5, CH.sub.2 OH or ##STR4## R.sup.4 is hydrogen, OH, ##STR5## m is an integer of 1-8, n is an integer of 1-20, and p is 0 or 1.

Examples of the (meth)acrylates of the formula (2) are diethyleneglycol di(meth)acrylate, triethyleneglycol di(meth)acrylate, tetraethyleneglycol di(meth)acrylate, 1,2-propyleneglycol di(meth)acrylate, dipropyleneglycol di(meth)acrylate, polyethyleneglycol di(meth)acrylate, glycerol di(meth)acrylate, glycerolacrylate methacrylate, diglycerol di(meth)acrylate, glycerin tri(meth)acrylate, trimethylolpropane tri(meth)acrylate, di-glycerol tetra(meth)acrylate and the like.

Vinyl compounds (3)

(Meth)acrylates shown by the following formula (3). ##STR6## wherein R.sup.5 and R.sup.6 are hydrogen, an alkyl group having 1-8 carbon atoms, R.sup.7 and R.sup.8 are a hydrocarbon residue having 2-8 carbon atoms, and m is an integer of 1-10.

Examples of the (meth)acrylates of the formula (3) are 2,2-bis(4-methacryloxydiethoxyphenyl)propane, 2,2-bis(4-acryloxydiethoxyphenyl)propane, 2,2-bis(4-methacryloxytriethoxyphenyl)propane, 2,2-bis(4-acryloxypentaethoxyphenyl)propane, 2,2-bis(4-methacryloxyhexaethoxyphenyl)propane, 2,2-bis(4-acryloxyheptaethoxyphenyl)propane, 2,2-bis(4-methacryloxyoctaethoxyphenyl)propane, 2,2-bis(4-acryloxydipropoxyphenyl)propane, 2,2-bis(4-methacryloxytripropoxyphenyl)propane, 2,2-bis(4-acryloxydibutoxyphenyl)propane, 2,2-bis(4-methacryloxyoctabutoxyphenyl)propane, 2-(4-methacryloxydiethoxyphenyl)-2-(4-methacryloxytriethoxyphenyl)propane, 2-(4-acryloxydipropoxyphenyl)-2-(4-acryloxytriethoxyphenyl)propane, and the like.

Vinyl compounds (4)

(Meth) acrylates shown by the following formula (4). ##STR7## wherein R.sup.9 is hydrogen or a hydrocarbon residue having 1-4 carbon atoms, and n is 0 or an integer of 1-10.

Examples of the (meth)acrylates of the formula (4) are dicyclopentenyl (meth)acrylate, dicyclopentenyloxymethyl (meth)acrylate, dicyclopentenyloxyethyl (meth)acrylate, dicyclopentenyloxypropyl (meth)acrylate, and the like.

Vinyl compounds (5)

(Meth)acrylates shown by the following formula (5). ##STR8## wherein R.sup.10 is hydrogen, an alkyl group having 1-18 carbon atoms, a cycloalkyl group having 5-20 carbon atoms, a phenyl group, a tetrahydrofurfurly group, or an alkyl group of 5-20 carbon atoms which contains a phenyl or tetrahydrofurfurly group.

Examples of the (meth)acrylates of the formula (5) are methacrylic acid, acrylic acid, methyl (meth)acrylate, cyclohexyl (meth)acrylate, tetrahydrofurfurly (meth)acrylate, 2-ethylhexyl (meth)acrylate, phenyl (meth)acrylate, benzyl (meth)acrylate, and the like.

Vinyl compounds (6)

(Meth)acrylates shown by the following formula (6). ##STR9## wherein R.sup.11 is a hydrocarbon residue having 2-18 carbon atoms, and R.sup.12 is a hydrocarbon residue having 1-18 carbon atoms.

Examples of the (meth)acrylates of the formula (6) are 2-hydroxy-3-phenoxypropyl (meth)acrylate, cyclohexanoxy-.beta.-hydroxypropyl (meth)acrylate, tetrahydrofurfurloxy-.beta.-hydroxypropyl (meth)acrylate, nonyloxy-.beta.-hydroxypropyl (meth)acrylate, and the like.

Vinyl compounds (7)

(Meth)acrylates shown by the following formula (7). ##STR10## wherein R.sup.13 is an alkyl group having 1-20 carbon atoms, a vinyl group, an aryl group and an alkoxyalkyl group.

Examples of the (meth)acrylates of the formula (7) are methoxycarbonylmethyl (meth)acrylate, ethoxycarbonylmethyl (meth)acrylate, heptoxycarbonylmethyl (meth)acrylate, isopropoxycarbonylmethyl (meth)acrylate, and the like.

Vinyl compounds (8)

(Meth)acrylates shown by the following formula (8). ##STR11## wherein R.sup.14 is a hydrocarbon residue of 1-20 carbon atoms, m is an integer of 1-10, and n is 1 or 2.

Vinyl compounds (9)

(Meth)acrylates shown in the following formula (9). ##STR12## wherein m is an integer of 1-10, and n is 1 or 2.

Examples of the (meth)acrylates of the formulas (8) and (9) are acidphosphoxyethyl (meth)acrylate, 3-chloro-2-acidphosphoxypropyl (meth)acrylate, acidphosphoxypropyl (meth)acrylate, and the like.

Vinyl compounds (10)

Urethane prepolymers having a (meth)acryloyloxy group, as mentioned in (10-1) and (10-2) below:

(10-1): An urethane prepolymer having a (meth)acryloyloxy group, which is a reaction product of a (meth)acrylate having a hydroxy group and an organic polyisocyanate. (10-2): An urethane prepolymer having a (meth)acryloyloxy group, which is a reaction product of a (meth)acrylate having a hydroxy group, an organic polyisocyanate and a tri- or more- valent polyol and/or diol.

Other vinyl compounds

Aside from the aforementioned vinyl compounds, the catalytic composition for photopolymerization of the present invention can be combined with various other vinyl compounds, for example, a vinyl ester such as vinyl acetate and vinyl propionate; a vinyl ether such as methyl vinyl ether, ethyl vinyl ether and cyclohexyl vinyl ether; and alkenyl benzene such as styrene, vinyltoluene, alpha-methyl styrene, chloromethyl styrene and stilbenzene; N-vinyl pyrrolidone; and a carboxylic acid such as maleic acid, maleic acid anhydride. However, these compounds are merely examples.

The above-mentioned vinyl compounds capable of radical polymerization may be used singly or in combination with two or more thereof.

Additives

Besides the aforementioned components, various substances may be added to the present composition for different purposes. For example, a nitro compound, a nitroso compound or a quinone such as hydroquinone and hydroquinone monomethyl ether may be added for improving stability; a dye or pigment may be added for coloring; a thixotropic agent such as silica may be added for imparting thixotropic property; a chelating agent such as ethylenediaminetetraacetic acid and its salt; and an acrylic, urethane or epoxy resin or silica may be added for increasing viscosity and volume.

In addition, an organic peroxide can be added to impart thermal polymerization property or anaerobic polymerization property.

The present photopolymerizable composition can readily be prepared by mixing and dissolving the aforementioned components under room temperature or elevated temperature.

Curing methods

The present photopolymerizable composition to which the present catalytic composition for photopolymerization is added may be cured in the same manner as conventionally employed. Light source may be high-pressure mercury lamp, metal halide lamp, xenon lamp halogen lamp, fluorescent lamp, or incandescent lamp.

EXAMPLES AND COMPARATIVE EXAMPLES

Hereinafter, the present invention will be set forth in more detail by way of the following examples and comparative examples, but the present invention is not limited to these examples.

Firstly, hydrazones were synthesized in the following ways.

SYNTHESIS EXAMPLE 1

A 100 ml pear-shaped flask was charged with 50 ml of ethanol, 0.03 mol of p-toluenesulfonylhydrazide and 0.03 mol of camphorquinone. In addition, a rotator was placed in the flask, and the flask was equipped with a condenser. While the raw materials were stirred with a magnetic stirrer, the reaction liquid was heated with a water bath until ethanol was boiled and refluxed, and then, under this condition, the reaction liquid was allowed to react for about 8 hours.

After ethanol was removed from the reaction liquid under vacuum, a viscous substance was obtained at 60.degree. C. In GPC analysis, this substance (camphorquinone p-toluenesulfonylhydrazone) showed substantially two peaks on the side of molecular weight higher than the two raw materials.

In NMR analysis, the broad peak near 5.5 ppm of p-toluenesulfonylhydrazide disappeared, but instead a sharp quadruple line of the hydrazone compounds appeared at 3.6 ppm to 3.8 ppm.

SYNTHESIS EXAMPLE 2

A 100 ml pear-shaped flask was charged with 40 ml of ethanol, 0.03 mol of p-toluenesulfonylhydrazide and 0.15 mol of acetone. In addition, a rotator was place in the flask, and the flask was equipped with a condenser. While the raw materials were stirred with a magnetic stirrer, the reaction liquid was heated with a water bath until ethanol was boiled and refluxed, and then under this condition, the reaction liquid was allowed to react for about 8 hours.

After ethanol and excess acetone were removed from the reaction liquid by vacuum, a powdery substance (4,4'-oxybis(benzenesulfonylhydrazono acetone)) was obtained at room temperature. In GPC analysis, this substance showed a substantially single peak on the side of molecular weight higher than the two raw materials.

In NMR analysis, the broad peak near 5.5 ppm of p-toluenesulfonylhydrazide disappeared, but instead a sharp double line of the hydrazone compounds appeared at 2.16 ppm to 2.22 ppm.

SYNTHESIS EXAMPLE 3

A 100 ml pear-shaped flask was charged with 40 ml of ethanol, 0.01 mol of 4,4'-oxybenzenesulfonylhydrazide and 0.01 mol of camphorquinone. In addition, a rotator was placed in the flask, and the flask was equipped with a condenser. While the raw materials were stirred with a magnetic stirrer, the reaction liquid was heated with a water bath until ethanol was boiled and refluxed, and then, under this condition, the reaction liquid was allowed to react for about 8 hours.

After ethanol was removed from the reaction liquid under vacuum, a yellow semi-solid substance (4,4'-oxybis(benzenesulfonylhydrazono camphorquinone)) was obtained at room temperature. In GPC analysis, this substance showed a substantially single peak on the side of molecular weight higher than the two raw materials.

In IR analysis, the peak of C.dbd.O of camphorquinone at 5.75 .mu.m was partially shifted to 5.9 .mu.m.

SYNTHESIS EXAMPLE 4

A 100 ml pear-shaped flask was charged with 50 ml of ethanol, 0.03 mol of p-toluenesulfonylhydrazide and 0.015 mol of 2,3-butanedione. In addition, a rotator was placed in the flask, and the flask was equipped with a condenser. While the raw materials were stirred with a magnetic stirrer, the reaction liquid was heated with a water bath until ethanol was boiled and refluxed, and then, under this condition, the reaction liquid was allowed to react for about 8 hours.

After ethanol was removed from the reaction liquid under vacuum, a powdery substance (butanedione p-toluenesulfonyl hydrazone) was obtained at room temperature. In GPC analysis, this substance showed a substantially single peak on the side of molecular weight higher than the two raw materials.

In NMR analysis, the broad peak near 5.5 ppm of p-toluenesulfonylhydrazide disappeared, but instead a single sharp peak of the hydrazone compounds appeared at 8.52 ppm.

SYNTHESIS EXAMPLE 5

A 100 ml pear-shaped flask shielded with covering of aluminum foil was charged with 50 ml of ethanol, 0.055 mol of p-toluenesulfonylhydrazide and 0.055 mol of benzaldehyde. In addition, a rotator was placed in the flask, and the flask was equipped with a condenser. While the raw materials were stirred with a magnetic stirrer, the reaction liquid was heated with a water bath until ethanol was boiled and refluxed, and then, under this condition, the reaction liquid was allowed to react for about 8 hours. After the reaction liquid was cooled to room temperature and 200 ml of petroleum ether was added thereto, white precipitate was obtained at room temperature.

The precipitate was filtered with a glass filter and dried to obtain a white powder. In GPC analysis, this substance showed a substantially single peak on the side of molecular weight higher than the two raw materials.

SYNTHESIS EXAMPLE 6

A 200 ml pear-shaped flask shielded with covering of aluminum foil was charged with 100 ml of ethanol, 0.019 mol of 4,4'-oxybis(benzenesulfonylhydrazide) and 0.038 mol of benzoin ethyl ether. In addition, a rotator was placed in the flask, and the flask was equipped with a condenser. While the raw materials were stirred with a magnetic stirrer, the reaction liquid was heated with a water bath until ethanol was boiled and refluxed, and then, under this condition, the reaction liquid was allowed to react for about 8 hours.

After ethanol was removed from the reaction liquid under vacuum, a pale yellow solid substance was obtained at room temperature. In GPC analysis, this substance showed a substantially single peak on the side of molecular weight higher than the two raw materials.

SYNTHESIS EXAMPLE 7

A 200 ml pear-shaped flask shielded with covering of aluminum foil was charged with 100 ml of ethanol, 0.019 mol of 4,4'-oxybis(benzenesulfonylhydrazide) and 0.038 mol of benzoin isobutyl ether. In addition, a rotator was placed in the flask, and the flask was equipped with a condenser. While the raw materials were stirred with a magnetic stirrer, the reaction liquid was heated with a water bath until ethanol was boiled and refluxed, and then, under this condition, the reaction liquid was allowed to react for about 8 hours.

After ethanol was removed from the reaction liquid under vacuum, a pale yellow solid substance was obtained at room temperature. In GPC analysis, this substance showed a substantially single peak on the side of molecular weight higher than the two raw materials.

SYNTHESIS EXAMPLE 8

A 200 ml pear-shaped flask was charged with 50 ml of ethanol, 0.047 mol of benzenesulfonylhydrazide and 0.047 mol of camphorquinone. In addition, a rotator was placed in the flask, and the flask was equipped with a condenser. While the raw materials were stirred with a magnetic stirrer, the reaction liquid was heated with a water bath until ethanol was boiled and refluxed, and then, under this condition, the reaction liquid was allowed to react for about 8 hours.

After ethanol was removed from the reaction liquid under vacuum, a highly-viscous, orange-colored liquid substance was obtained at room temperature. In GPC analysis, this substance showed substantially two peaks on the side of molecular weight higher than the two raw materials.

EXAMPLES 1-9 AND COMPARATIVE EXAMPLE 1

Photopolymerizable compositions were prepared by covering the outside of containers with aluminum foil to shield light as mentioned below, putting therein 100 parts by weight of trimethylolpropane triacrylate and prescribed photopolymerization catalysts as shown in Table 1, and mixing them under stirring at a heated temperature of 80.degree. C. to obtain uniform liquid mixtures. The photopolymerizable compositions thus obtained were subjected to a test for thick film cureability and a measurement of hardness of hardened bodies in order to evaluate photopolymerizable property.

Evaluation of photopolymerization property

Test method for thick film cureability

(1) Preparing a polyethylene tube which is 5 mm in inner diameter and 40 mm in length and which is open at the top end and is closed at the bottom end by a cap. Covering the outside of the polyethylene tube with aluminum foil to shield light.

(2) Putting a photopolymerizable composition into the tube up to the top end.

(3) Irradiating with light at a location of 2 mm above the surface of the photopolymerizable composition for 10 seconds, and then measuring a thickness of the hardened photopolymerizable composition.

As a light irradiating apparatus, the following was used:

Manufacturer: SHOFU Unit type: Daylight lamp 2, optical fiber type Lamp used: Sylvania EFR/15 V-150 W having the following specification of illuminance at the three different wavelengths; 0.08 mw/cm.sup.2 at 365 nm, 251 mw/cm.sup.2 at 405 nm, 41 mw/cm.sup.2 at 436 nm.

Method for evaluating hardness of hardened bodies

(1) Preparing a polyethylene tube which is 5 mm in inner diameter and 4 mm in depth and which is open at the top end and closed at the bottom end by a cap.

(2) Putting a photopolymerizable composition into the tube up to the top end.

(3) Irradiating with light at a location of 2 mm above the surface of the photopolymerizable composition for 10 seconds, taking the hardened body of the photopolymerizable composition out of the tube, and then measuring the hardness of the upper surface (which was the side irradiated with light) of the hardened body and the hardness of the lower surface of the hardened body by use of a Shore hardness gauge. The light irradiating apparatus is the same as used in the above test method for thick film cureability. The hardness gauge used is the following:

Manufacturer: Ueshima Seisakusho Model: HD-104N Type: SHORE D Standard: ASTM D 2240

The results of the evaluation of the photopolymerizable compositions are shown in Table 2.

TABLE 1__________________________________________________________________________ Photopolymerizable compositions Comparative Example Nos. Example No. 1 2 3 4 5 6 7 8 9 1__________________________________________________________________________Camphorquinone 0.3 0.1 0.3 0.1 0.3 0.1 0.3 0.1 0.3 0.8Hydrazone obtained 3 3 0 0 0 0 0 0 0 0in Synthesis Example 1Hydrazone obtained 0 0 3 3 0 0 0 0 0 0in Synthesis Example 2Hydrazone obtained 0 0 0 0 3 3 0 0 0 0in Synthesis Example 3Hydrazone obtained 0 0 0 0 0 0 3 3 1 0in Synthesis Example 4Trimethylolpropane 100 100 100 100 100 100 100 100 100 100triacrylate__________________________________________________________________________ TABLE 2__________________________________________________________________________ Photopolymerizable compositions ComparativeItems of evaluation of Example Nos. Example No.Photopolymerizability 1 2 3 4 5 6 7 8 9 1__________________________________________________________________________Thickness of cured films (mm) 10 11 15 18 40 40 14 11 11 3Shore hardness of the upper 93 96 88 86 89 90 91 95 96 93surface of hardened bodiesShore hardness of the lower 79 94 70 75 86 83 86 83 90 8surface of hardened bodies__________________________________________________________________________

EXAMPLES 10-27 AND COMPARATIVE EXAMPLES 1-2

Photopolymerizable compositions were prepared using camphorquinone as alpha-diketone in the same manner as in Example 1 except that various silane compounds were used as shown in Table 3. These photopolymerizable compositions were subjected to the same tests of thick film cureability and hardness of hardened bodies as in Example 1, to evaluate photopolymerization property. The results of the evaluation are shown in Table 4.

TABLE 3__________________________________________________________________________ Photopolymerizable compositionsComponent (I) or Example Nos.Component (II) 10 11 12 13 14 15 16 17 18 19__________________________________________________________________________Camphorquinone 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8 0.8Triphenyl silane 0.5 2 5 10 0 0 0 0 0 0Triethyl silane 0 0 0 0 0.5 2 0 0 0 0Phenyldimethyl silane 0 0 0 0 0 0 0.5 2 0 0Phenyl silane 0 0 0 0 0 0 0 0 0.5 2Diethyl silane 0 0 0 0 0 0 0 0 0 0P-BDS-B*.sup.1 0 0 0 0 0 0 0 0 0 0n-hexyl silane 0 0 0 0 0 0 0 0 0 0n-octadecyl silane 0 0 0 0 0 0 0 0 0 0tris(dimethylsilyl)amine 0 0 0 0 0 0 0 0 0 0HM-DH-TS*.sup.2 0 0 0 0 0 0 0 0 0 0Methyldiacetoxy silane 0 0 0 0 0 0 0 0 0 0Triethoxy silane 0 0 0 0 0 0 0 0 0 0Trimethylolpropane 100 100 100 100 100 100 100 100 100 100triacrylate__________________________________________________________________________ Photopolymerizable compositions ComparativeComponent (I) or Example Nos. Example No.Component (II) 20 21 22 23 24 25 26 27 1 2__________________________________________________________________________Camphorquinone 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.8 0.4Triphenyl silane 0 0 0 0 0 0 0 0 0 0Triethyl silane 0 0 0 0 0 0 0 0 0 0Phenyldimethyl silane 0 0 0 0 0 0 0 0 0 0Phenyl silane 0 0 0 0 0 0 0 0 0 0Diethyl silane 1.0 0 0 0 0 0 0 0 0 0P-BDS-B*.sup.1 0 1.0 0 0 0 0 0 0 0 0n-hexyl silane 0 0 1.0 0 0 0 0 0 0 0n-octadecyl silane 0 0 0 1.0 0 0 0 0 0 0tris(dimethylsilyl)amine 0 0 0 0 1.0 0 0 0 0 0HM-DH-TS*.sup.2 0 0 0 0 0 1.0 0 0 0 0Methyldiacetoxy silane 0 0 0 0 0 0 1.0 0 0 0Triethoxy silane 0 0 0 0 0 0 0 1.0 0 0Trimethylolpropane 100 100 100 100 100 100 100 100 100 100triacrylate__________________________________________________________________________ *.sup.1 PBDS-B: pbis(dimethylsilyl)benzene *.sup.2 HMDH-TS: hexamethyl1,5-dihydrotrisiloxyane TABLE 4__________________________________________________________________________ Photopolymerizable compositions ComparativeItems of evaluation of Example Nos. Example No.photopolymerizability 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 1 2__________________________________________________________________________Thickness of cured 6 14 8 9 9 9 14 14 10 12 13 12 12 10 8 11 10 10 3 6films (mm)Shore hardness of the 90 90 94 92 93 93 90 91 96 96 90 91 93 88 90 92 91 90 93 79upper surface ofhardened bodiesShore hardness of the 60 85 80 84 72 88 75 84 90 92 88 88 89 86 87 82 80 62 8 11lower surface ofhardened bodies__________________________________________________________________________

EXAMPLES 28-39

Photopolymerizable compositions containing two different alpha-diketones were prepared in the same manner as in Example 1 except that the components shown in Table 5 were used.

These photopolymerizable compositions were subjected to the same tests of thick film cureability and hardness of hardened bodies as in Example 1, to evaluate photopolymerization property. The results of the evaluation are also shown in Table 5.

EXAMPLES 40-43 AND COMPARATIVE EXAMPLES 3-6

Photopolymerizable compositions were prepared in the same manner as in Example 10 except that alpha-diketones and/or silane compounds and various radical-polymerizable vinyl compounds were used as shown in Table 6.

These photopolymerizable compositions were subjected to the same tests of thick film cureability and hardness of hardened bodies as in Example 1, to evaluate photopolymerization property. The results of the evaluation are also shown in Table 6.

EXAMPLES 44-45 AND COMPARATIVE EXAMPLES 7-11

Photopolymerizable compositions were prepared in the same manner as in Example 10 except that alpha-diketones and/or hydrazones and various radical-polymerizable vinyl compounds were used as shown in Table 7.

These photopolymerizable compositions were subjected to the same tests of thick film cureability and hardness of hardened bodies as in Example 1, to evaluate photopolymerization property. The results of the evaluation are also shown in Table 7.

EXAMPLES 56-59 AND COMPARATIVE EXAMPLES 12-14

Photopolymerizable compositions containing alpha-diketones and hydrazones, silane compounds or known amine compounds were prepared by blending together the components shown in Table 8.

These photopolymerizable compositions were subjected to the same tests of thick film cureability and hardness of hardened bodies as in Example 1, to compare the present photopolymerization catalysts with the known catalysts in terms of photopolymerization property. The results of the evaluation are also shown in Table 8.

TABLE 5__________________________________________________________________________ Example Nos. 28 29 30 31 32 33 34 35 36 37 38 39__________________________________________________________________________Components of compositionsCamphorquinone 0.3 0.2 0.3 0.2 0.3 0.2 0.3 0.2 0.3 0.2 0.3 0.2Benzil 0.1 0.2 0 0 0.1 0.2 0 0 0 0 0 0Acenaphthenequinone 0 0 0.1 0.2 0 0 0.1 0.2 0 0 0 03-Methyl-1,2-cyclo- 0 0 0 0 0 0 0 0 0.1 0.2 0.1 0.2pentanedioneTriphenyl silane 2 2 2 2 0 0 0 0 2 2 0 0Hydrazone of synthesis ex. 5 0 0 0 0 3 3 3 3 0 0 3 3Trimethylolpropane triacrylate 100 100 100 100 100 100 100 100 100 100 100 100Properties of hardened bodiesThickness of cured films (mm) 12 10 11 12 15 15 11 11 12 13 15 17Shore hardness of the upper 92 91 91 90 94 96 91 94 92 90 90 94surface of hardened bodiesShore hardness of the lower 85 82 87 88 88 83 87 88 88 86 85 97surface of hardened bodies__________________________________________________________________________ TABLE 6__________________________________________________________________________ Example No. Comparative Example No. 40 41 42 43 3 4 5 6__________________________________________________________________________Components of compositionsCamphorquinone 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4Triphenyl silane 1 1 1 1 0 0 0 0Hydrogenated dicyclopenta- 100 0 0 0 100 0 0 0dienyl diacrylate (DCP-A)Pentaerythritol triacrylate 0 100 0 0 0 100 0 0PO-modified trimethylolpropane 0 0 100 0 0 0 100 0triacrylate (Aronix M-310)2,2-bis(4-acryloxydiethoxy- 0 0 0 100 0 0 0 100phenyl)propaneProperties of hardened bodiesThickness of cured films (mm) 9 9 9 11 8 8 4 8Shore hardness of the upper 76 69 44 44 40 37 17 12surface of hardened bodiesShore hardness of the lower 74 55 60 38 41 43 55 12surface of hardened bodies__________________________________________________________________________ Notes: Aronix M310 is a trademark of Toagosei Chemical Industry Co., Ltd. DCPA is a commercial product of Kyoeisha Chemical Co., Ltd. TABLE 7__________________________________________________________________________ Example Nos. Comparative Example Nos. 44 45 46 47 48 49 50 51 52 53 54 55 7 8 9 10 11__________________________________________________________________________Components ofcompositionsCamphorquinone 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4 0.4Hydrazone of synthesis 3 0 0 3 0 0 0 3 0 0 0 0 0 0 0 0 0ex. 6Hydrazone of synthesis 0 3 0 0 3 0 0 0 0 3 0 0 0 0 0 0 0ex. 7Hydrazone of synthesis 0 0 0 0 0 0 3 0 0 0 0 0 0 0 0 0 0ex. 8Hydrazone of synthesis 0 0 3 0 0 3 0 0 3 0 3 3 0 0 0 0 0ex. 12,2-bis(4-acryloxydi- 100 100 100 0 0 0 0 0 0 0 0 0 100 0 0 0 0ethoxyphenyl)propanePO-modified trimethylol- 0 0 0 100 100 100 0 0 0 0 0 0 0 100 0 0 0propane triacrylate(Aronix M-310)Trimethylolpropane 0 0 0 0 0 0 100 50 50 0 0 0 0 0 50 0 0triacrylateTris(acryloxyethyl)iso- 0 0 0 0 0 0 0 50 50 0 0 0 0 0 50 0 0cyanurateHydrogenated dicyclo- 0 0 0 0 0 0 0 0 0 100 100 0 0 0 0 100 0pentadienyl diacrylateDipentaerythritol 0 0 0 0 0 0 0 0 0 0 0 100 0 0 0 0 100hexaacrylateProperties of hardenedbodiesThickness of cured 15 13 13 13 13 12 7 40 40 15 11 19 8 4 7 8 7films (mm)Shore hardness of the 74 83 85 59 81 70 95 89 90 94 95 93 12 17 11 40 35upper surface ofhardened bodiesShore hardness of the 52 78 80 60 79 70 91 64 91 90 87 84 12 55 11 40 31lower surface ofhardened bodies__________________________________________________________________________ TABLE 8______________________________________ Comparative Example Nos. Example Nos. 56 57 58 59 12 13 14______________________________________Components ofcompositionsCamphorquinone 0.4 0.4 0.4 0.4 0.4 0.4 0.4Hydrazone of 1 0 0 0 0 0 0synthesis ex. 5Hydrazone of 0 3 0 0 0 0 0synthesis ex. 6Triphenyl silane 0 0 1 0 0 0 0Trihexyl silane 0 0 0 1 0 0 0Dimethylaminoethyl 0 0 0 0 1 0 0methacrylicTriethylamine 0 0 0 0 0 1 0Tri-n-butylamine 0 0 0 0 0 0 1Trimethylolpropane 100 100 100 100 100 100 100triacrylateProperties ofhardened bodiesDisconfort odor none none none none exist exist existThickness of cured 9 40 9 10 15 17 13films (mm)Shore hardness of 91 89 92 91 92 45 29the upper surface ofhardened bodiesShore hardness of 90 87 70 90 88 60 25the lower surface ofhardened bodies______________________________________

The present photopolymerizable composition which is obtained by blending the present catalytic composition for photopolymerization with a radical-polymerizable vinyl compound exhibits excellent thick film cureability with light irradiation, and the hardened body of the photopolymerizable composition is high in hardness.

In other words, the present catalytic composition for photopolymerization is markedly improved in photopolymerization activity, compared with conventional catalysts. The present photopolymerizable composition containing the present catalytic composition for photopolymerization is very useful as a coating, an adhesive, a filler, a sealing agent, a material for shaped articles, and the like.

Claims

1. A catalytic composition for photopolymerization, which comprises an alpha-diketone and a hydrazone, said hydrazone being obtained by dehydration-condensation of a carbonyl compound and an arylsulfonyl hydrazide represented by the formula Z--NHNH.sub.2 wherein Z is an arylsulfonyl group containing up to 20 carbon atoms.

2. A catalytic composition according to claim 1, in which said alpha-diketone is a compound having the following formula (A): ##STR13## wherein X and Y, which may be identical with or different from each other, represent a substituted or unsubstituted alkyl, alkenyl or aryl group, or X and Y may form a ring structure by linkage with each other.

3. A catalytic composition according to claim 1, which comprises 1-99% by weight of said alpha-diketone and 99-1% by weight of said hydrazone.

4. A catalytic composition according to claim 1, which comprises 2-90% by weight of said alpha-diketone and 98-10% by weight of said hydrazone.

5. A photopolymerizable composition which comprises a vinyl compound capable of radical polymerization and a catalytic composition which comprises an alpha-diketone and a hydrazone, said hydrazone being obtained by dehydration-condensation of a carbonyl compound and an arylsulfonyl hydrazide represented by the formula Z--NHNH.sub.2 wherein Z is an arylsulfonyl group containing up to 20 carbon atoms.

6. A photopolymerizable composition according to claim 5, which comprises 100 parts by weight of said vinyl compound and 0.01-30 parts by weight of said catalytic composition.

7. A photopolymerizable composition according to claim 5, which comprises 100 parts by weight of said vinyl compound and 0.05-20 parts by weight of said catalytic composition.

8. A photopolymerizable composition according to claim 5, which comprises 100 parts by weight of said vinyl compound and 0.05-10 parts by weight of said catalytic composition.