This invention relates to a ceramic heat exchanger and a method of producing same, and particularly, a ceramic micro-channel counter-flow heat exchanger and a method of producing same.
Ceramic is a material suitable for heat exchangers because of its light weight compared with metals and good thermal conductance. Particularly because of its good heat resistance, ceramic is regarded as a promising material for use in recovery of heat from high-temperature gases above 800° C., such as exhaust gases from gas turbines or others. Commonly used in high-temperature applications are metallic plate-fin heat exchangers, which exhibit high effectiveness, but have a drawback that complicated fin shapes lead to high costs. Ceramic is, however, a material difficult to work into complicated shapes because of its high hardness and brittleness. Heat exchangers using ceramic having such properties have already proposed, as seen in patent documents 1 to 3, for example.
The ceramic heat exchanger disclosed in patent document 1 is an integrally-fired ceramic product comprising an outer frame and walls defining a plurality of channels inside the frame, intended to force a high-temperature fluid and a low-temperature fluid to flow through the channels in opposite directions to transfer heat from the high-temperature fluid to the low-temperature fluid via the walls.
The ceramic heat exchanger disclosed in patent document 2 is a sintered product produced by forming a plurality of grooved plate-form shapes from a mixture of silicon carbide powder, carbon powder and a binder, then forming a stack of the grooved plate-form shapes by provisionally bonding them with a bonding agent, the stack having minute holes formed of the grooves, then degreasing, or removing the binder from the stack, then heating, then impregnating the stack with molten silicon, and then reaction-sintering the stack.
The ceramic heat exchanger disclosed in patent document 3 comprises a casing for exhaust gases to flow through, and a plurality of tubes fitted to the casing to extend through the opposite end walls of the casing and across the interior of the casing, the tubes being intended to contain and circulate a heat medium in the direction from an exhaust gases outlet side to an exhaust gases inlet side, wherein spaces between the tubes and the end walls of the casing are filled with a liquid-form ceramic material which is matured into a ceramic, or filled with a solid-form ceramic material which is impregnated with a liquid-form ceramic material and matured into a ceramic.
The ceramic heat exchanger disclosed in patent document 1 has channels in a grid array for high-temperature and low-temperature fluids to flow in the opposite directions. How to introduce the high-temperature and low-temperature fluids into the channels in the ceramic heat exchanger is however not described specifically. The ceramic heat exchanger disclosed in patent document 2 is produced by stacking and joining a plurality of grooved plate-form shapes together, wherein channels are formed of grooves of the grooved plate-form shapes. This ceramic heat exchanger has a lot of joints, and thus, requires a lot of production steps and has a high likelihood of leakage. The ceramic tube heat exchanger disclosed in patent document 3 contains complicated joints between the casing and the tubes, and thus, requires a lot of production steps and has a high likelihood of leakage.
The present invention has been made in consideration of the above problems. An object of the present invention is to provide a ceramic heat exchanger which has reduced joints, and thus, is easy to produce and less likely to leak, and a method of producing same.
The present invention provides a ceramic heat exchanger made of ceramic, for forcing a first medium and a second medium, different in temperature, to flow in opposite directions to transfer heat between the first and second media, comprising: a body having first channels for the first medium to flow and second channels for the second medium to flow, and lids each having openings, joined to the body at opposite ends with the openings connected to the first channels, the body further having inlet channels formed in a first channel outlet-side end portion to allow the second medium to enter the body at a side thereof and flow into the second channels, and outlet channels formed in a first channel inlet-side end portion to allow the second medium to flow out of the second channels and leave the body at the side thereof.
The first and second channels may form alternating rows. The first and second channels may form a grid or honeycomb structure. The first and second channels may have a cross-section shape consisting of long and short sides. The ratio of the long side to the short side of the cross-section shape is desirably between 1.2 and 3.0.
The inlet channels as well as the outlet channels may be grooves formed in the body and delimited by an inner side of the lid, the grooves extending transversely across the body and connecting to the second channels. The outlet channels may be greater in capacity than the inlet channels.
The ceramic heat exchanger may further comprise a cylindrical member arranged over the body, the cylindrical member providing an inlet chamber connecting to the inlet channels and having an inlet for the second medium to flow in, and an outlet chamber connecting to the outlet channels and having an outlet for the second medium to flow out.
The present invention also provides a method of producing a ceramic heat exchanger made of ceramic for forcing a first medium and a second medium, different in temperature, to flow in opposite directions to transfer heat between the first and second media, comprising: a forming step of forming a body-forming shape having first channels for the first medium to flow and second channels for the second medium to flow, and lid-forming shapes each having openings to be connected to the first channels, a sintering step of sintering the body-forming shape and the lid-forming shapes, thereby producing a body-forming sintered block and lid-forming sintered blocks, a working step of creating grooves connecting to the second channels, in opposite end portions of the body-forming sintered block, transversely across the body-forming sintered block, an application step of applying a bonding agent to joint surfaces of at least either the body-forming sintered block or the lid-forming sintered blocks, and a heat treatment step of heat-treating the body-forming sintered block with the lid-forming sintered blocks placed on opposite ends thereof, with the openings in agreement with the first channels, thereby integrating the body-forming sintered block and the lid-forming sintered blocks by virtue of the bonding agent.
In the ceramic heat exchanger and the method of producing same according to the present invention, the ceramic heat exchanger is composed of a body and lids, and produced by joining only the body and the lids. Such ceramic heat exchanger has reduced joints, and thus, is easy to produce and less likely to leak.
With reference to
The ceramic heat exchanger 1 shown in
The body 2 is intended to force the high-temperature medium and the low-temperature medium to flow through in opposite directions. Specifically, as seen in
The sintered ceramic block forming the body 2 may be made using oxide ceramics such as alumina and zirconia, or non-oxide ceramics such as silicon carbide. Oxide ceramics are superior in oxidation resistance at high temperatures, while non-oxide ceramics are superior in mechanical properties at high temperatures because of their low coefficients of thermal expansion. In order to improve the ceramic heat exchanger performance, it is desirable to make the body 2 using silicon carbide which has high thermal conductivity and high high-temperature strength.
As seen in
As seen in
The inlet channels 23 and the outlet channels 24 are grooves 23a, 24a formed in the body 2 and delimited by an inner side 3a of the lid 3, the grooves extending transversely across the body and connecting to the second channels 22. As seen from
As seen from
The lids 3 are joined to the body 2 at the opposite ends. The lids 3 have a function of separating the first channels 21 from second channels 22. Specifically, as seen in
The openings 31 are provided in the lids 3 to connect to their associated rows of the first channels 1 and connect to no second cannel 22, no inlet channel 23 and no outlet channel 24. In
Next, the method of producing the ceramic heat exchanger 1, according to the present invention will be described.
The method of producing the ceramic heat exchanger 1, made of ceramic and intended to force a high-temperature medium and a low-temperature medium different in temperature to flow in opposite directions to transfer heat from the high-temperature medium to the low-temperature medium, according to the present invention, comprises a forming step of forming a body 2-forming shape having first channels 21 for the high-temperature medium to flow and second channels 22 for the low-temperature medium to flow, and lid-forming shapes each having openings 31 to be connected to the first channels 21, a sintering step of sintering the body 2-forming shape and the lid 3-forming shapes, thereby producing a body 2-forming sintered block 20 and lid 3-forming sintered blocks 30, a working step of creating grooves 23a, 24a connecting to the second channels 22, in opposite end portions 2a, 2b of the body 2-forming sintered block 20, transversely across the body 2-forming sintered block 20, an application step of applying a bonding agent 4 to joint surfaces of at least either the body 2-forming sintered block 20 or the lid 3-forming sintered blocks 30, and a heat treatment step of heat-treating the body 2-forming sintered block 20 with the lid 3-forming sintered blocks 30 placed on opposite ends thereof, with the openings 31 in agreement with the first channels 21, thereby integrating the body 2-forming sintered block 20 and the lid 3-forming sintered blocks 30 by virtue of the bonding agent 4.
The forming step is a step of forming a body 2-forming shape and lid 3-forming shapes. Specifically, the body 2-forming shape is created by preparing a clay by mixing ceramic powder, a binder and water by means of an agitation mixer such as a kneader, and extruding the clay through a die for forming a cylindrical shape having through-holes (first and second channels 21 and 22) in a grid array as shown in
The case in which the ceramic material used is silicon carbide will be taken as an example. For the body 2, a clay suitable for extrusion is prepared by adding, to a silicon carbide primary material with 0.5 to 10 μm average particle size and 99 to 99.8% purity, carbon (C), boron (B) and sintering aids such as alumina (Al2O3), yttria (Y2O3) and magnesia (MgO), putting an appropriate amount of this material in an agitation mixer such as a kneader, together with a binder such as polyethyleneglycol or polyethylene oxide and water, and mixing. The body 2-forming shape is obtained by extruding the clay thus prepared, through the aforementioned die.
For the lid 3, a slurry is prepared by adding, to a silicon carbide primary material with 0.5 to 10 μm average particle size and 99 to 99.8% purity, carbon (C), boron (B) and sintering aids such as alumina (Al2O3), yttria (Y2O3) and magnesia (MgO), and also adding an appropriated amount of a binder such as polyethyleneglycol or polyethylene oxide. The slurry thus prepared is made into granules by spray drying granulation. The lid 3-forming shape is obtained by packing the granules into the aforementioned die and applying pressure to the die under predetermined conditions.
The sintering step is a step of sintering the body 2-forming shape and the lid 3-forming shapes, thereby producing a body 2-forming sintered block 20 and lid 3-forming sintered blocks 30. Specifically, by sintering the body 2-forming shape and the lid 3-forming shapes in a sintering furnace, with an atmosphere, a temperature and a retention time predetermined to be suitable for the ceramic powder used, there are obtained a body 2-forming cylinder-shaped sintered block 20 having through-holes (first and second channels 21 and 22) in a grid array as shown in
The working step is a step of creating grooves 23a, 24a providing inlet and outlet channels 23 and 24. Specifically, the grooves 23a, 24a are created in the end portions 2a, 2b of the body 2 to each connect to its associated row of the second channels 22. The grooves 23a, 24a in the end portions 2a, 2b of the body 2 have depths Da, Db as seen in
The application step is a step of applying a bonding agent 4 to joint surfaces of at least either the body 2-forming sintered block 20 or the lid 3-forming sintered blocks 30. The bonding agent 4 is a glassy glaze, for example. The bonding agent 4 is applied to the opposite ends, or joint surfaces of the body 2-forming sintered block 20, by using a brush or other means. The body 2-forming sintered block 20 after the application step has an end portion 2a-side end shown in
The heat treatment step is a step of integrating the body 2-forming sintered block 20 and the lid 3-forming sintered blocks 30 into a ceramic heat exchanger 1 shown in
The joints made by heat treatment are liable to leak. The ceramic heat exchanger 1 produced by the above-described method according to the present invention has, however, a reduced number of joints made by heat treatment, namely only two of such joints at the opposite ends of the body 2, resulting in a reduced likelihood of leakage. Further, the body 2-forming sintered block 20 and the lid 3-forming sintered blocks 3 can be joined together easily by a reduced number of work steps, namely applying the bonding agent 4 to at least either the opposite ends of the body-2 forming sintered block 20 or the inner side 3a of each lid-3 forming sintered block 30, placing the lid 3-forming sintered blocks 30 on the opposite ends of the body 2-forming sintered block 20, with the openings 31 in agreement with the rows of the first channels 21, and heat-treating the blocks 20 and 30 thus assembled. Furthermore, the inlet and outlet channels 23, 24 for forcing the low-temperature medium to flow into and out of the second channels 22 are provided simply by creating the grooves 23a, 24a in the opposite end portions 2a, 2b of the body 2-forming sintered block 20 and joining the lid 3-forming sintered blocks 30 to the opposite ends of the block 20. The inlet and outlet channels 23, 24 can therefore be easily created employing only the techniques applicable to ceramic which is high in brittleness and thus difficult to work.
Next, exemplary applications of the ceramic heat exchanger 1 according to the present invention will be described.
In the applications of the ceramic heat exchanger 1 shown in
In the first application shown in
The cylindrical member 5 has an annular raised portion 53 inside, which delimits the inlet chamber 51 and the outlet chamber 52. The inside diameter of the annular raised portion 53 is slightly greater than the outside diameter of the body 2 of the ceramic heat exchanger 1, to ensure a space for allowing difference in thermal expansion between the ceramic heat exchanger 1 and the cylindrical member 5. The annular raised portion 53 has, for example a width, or axial length Dc ensuring that the annular raised portion does not overlap the inlet channels 23 or the outlet channels 24, as seen in
In the above-described first application, the high-temperature medium axially enters the first channels 21 in the ceramic heat exchanger 1, at the end portion 2b-side, or outlet channel 24-side end, and leaves the ceramic heat exchanger 1 at the end portion 2a-side, or inlet channel 23-side end. The low-temperature medium, on the other hand, enters the inlet chamber 51 through the inlet 51a in the cylindrical member 5, then enters the inlet channels 23 open at the side of the ceramic heat exchanger 1, then enters the second channels 22 and absorbs heat from the high-temperature medium while flowing in the second channels 2, and then leaves the ceramic heat exchanger 1 through the outlet channels 24, the outlet chamber 52 and the outlet 52a. The high-temperature medium is exhaust gases of 800° C. or above, for example, while the low-temperature medium is compressed air of approximately 150 to 200° C. to be supplied to an engine such as an internal combustion engine, for example. Through the ceramic heat exchanger 1 according to the present invention, the low-temperature medium, or compressed air is heated to approximately 500° C., for example.
In the second application shown in
As in the first application, the cylindrical member 5 with an annular raised portion 53 provides an inlet chamber 51 with an inlet 51a, and an outlet chamber 52 with an outlet 52a. In the second application, the cylindrical member 5 also provides a low-temperature medium flow-in passage 54 outside the inlet chamber 51 and the outlet chamber 52. Specifically, the cylinder member 55 is a double-walled member defining an inner and an outer spaces, where the outer space serves as a low-temperature medium flow-in passage 54, while the inner space holds the ceramic heat exchanger 1 and provides a low-temperature medium flow-out passage (outlet chamber 52). The cylindrical member 5 also has an annular inward projection 55 at the high-temperature medium inlet-side end. In this annular projection 55, an axially-oriented entry 54a to the flow-in passage 54 and an axially-oriented exit 52a from the flow-out passage 52 are formed. The annular projection 55 and the flange 91 of the adapter 9 are joined with an elastic member 7 inserted between, and the high-temperature medium inlet-side conduit 6 is joined integrally to the annular projection 55. This configuration allows the ceramic heat exchanger 1 to be fitted between the high-temperature medium conduits 6 only by inserting the ceramic heat exchanger 1 in the cylindrical member 5 from the high-temperature medium outlet-side until it butts against the annular projection 55, and fastening the conduit 6 and the cylindrical member 5 together using fastening members 8.
In the above-described second application, the high-temperature medium axially enters the first channels 21 in the ceramic heat exchanger 1 via the adapter 9, and leaves the ceramic heat exchanger 1 at the end portion 2a-side, or inlet channel 23-side end. The low-temperature medium, on the other hand, enters the flow-in passage 54 through the entry 54a, then enters the inlet chamber 51 through the inlet 51a, then enters the inlet channels 23 open at the side of the ceramic heat exchanger 1, then enters the second channels 22, and while flowing in the second channels 22, absorbs heat from the high-temperature medium, and leaves the ceramic heat exchanger through the outlet channels 24, the outlet chamber 52 and the outlet 52a.
The above-described first and second applications are examples in which the low-temperature medium flows in and out of the cylindrical member 5 at the side thereof, transversely, or at the high-temperature medium inlet-side end thereof, axially. The present invention is however not restricted to such examples. For example, it may be arranged such that the low-temperature medium flows in and out at the high-temperature medium outlet-side end of the cylindrical member, axially, or flows in at the side of the cylindrical member transversely and flows out at an end of the cylindrical member axially or vice versa, or flows in at the high-temperature medium outlet-side end of the cylindrical member and flows out at the high-temperature medium inlet-side end thereof, axially.
Next, variants of the ceramic heat exchanger 1 according to the present invention will be described.
In the first variant shown in
The cross-sectional view of the second variant shown in
In the third variant shown in
As shown in
Further variants of the ceramic heat exchanger 1 according to the present invention will be described.
In the fourth variant shown in
As seen in the Figure, the first and second channels 21, 22 have a rectangular cross-section shape with a long side X and a short side Y, where the ratio of the long side X to the short side Y (X/Y) is set between 1.2 and 3.0. The cross-section shape with a ratio X/Y less than 1.2 is difficult to create due to great working resistance. The cross-section shape with a ratio X/Y greater than 3.0 is susceptible to deformation, because of high likelihood of shrinkage of the long side X compared with the short side Y. Although in the described example, the first and second channels 21, 22 are identical in cross-section shape, the first and second channels 21, 22 may have different X/Y ratios. The first and second channels 21, 22 may be square and rectangular in cross-section shape, respectively, or vice versa.
In the fifth variant shown in
The present invention is not restricted to the above-described embodiments. Each embodiment is modified in various ways without departing from the scope and spirit of the present invention. For example, the third variant may be modified by introducing features of the first or second variant.
Number | Date | Country | Kind |
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2009-069965 | Mar 2009 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2010/054924 | 3/23/2010 | WO | 00 | 11/7/2011 |
Publishing Document | Publishing Date | Country | Kind |
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WO2010/110238 | 9/30/2010 | WO | A |
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