Patent Application
20070213201
1. Field of the Invention
This invention relates to a ceramic powder to be used for forming dielectric ceramic layers in a multilayer ceramic electronic component resulting from alternately stacking dielectric ceramic layers and internal electrode layers, and particularly relates to a ceramic powder useful for enhancing the dielectric property of the multilayer ceramic electronic component. This invention further relates to a dielectric paste using the ceramic powder, a multilayer ceramic electronic component, and a method for the production thereof.
2. Description of the Prior Art
The multilayer ceramic capacitor that is a typical example of multilayer ceramic electronic components possesses a structure resulting from alternately stacking a plurality of pairs of dielectric ceramic layers and internal electrode layers and has been extensively used as an electronic part having a small size, a large capacity, and high reliability. Not infrequently, a great number of multilayer ceramic capacitors are used in one electronic device, for example.
In recent years, electronic devices have been undergoing reduction in size and addition to performance. This trend has been urging the multilayer ceramic capacitor with increasingly more severity to acquire reduction in size, addition to capacity, decrease in price, enhancement of reliability, and the like. For the purpose of enabling the multilayer ceramic capacitor to secure reduction in size and addition to capacity in response to the harsh demand, the dielectric ceramic layers are required to decrease the layer thickness and increase the number of component layers. The dielectric ceramic layer is otherwise required to use a dielectric material having a high dielectric constant.
As the situation now stands, an effort is being directed toward thinning the component layers untill an interlayer of about 2 μm (the thickness of each of the component layers about 2 μm). The thinning of the dielectric ceramic layers, however, entails such problems as intensifying the electric field applied to the dielectric ceramic layers in consequence of the application of voltage, markedly aggravating the dielectric loss, and degrading the capacitance temperature characteristic as well.
The present inventors, therefore, have proposed to suppress the dielectric loss and enhance the capacitance temperature characteristic by optimizing barium titanate for use in the dielectric ceramic layers based on the results of the X-ray diffraction (refer to JP-A 2001-345230). To be specific, the invention disclosed in JP-A 2001-345230, in producing a multilayer ceramic chip capacitor possessing a capacitor chip piece of a structure resulting from alternately stacking dielectric layers and internal electrode layers, contemplates using as the raw material powder for barium titanate destined to form the dielectric layers a raw material powder whose ratio of the peak intensity (I(200)) of the diffraction line of the (200) face to the intensity (Ib) at the intermediate point between the angle of the peak point of the diffraction line of the (002) face and the angle of the peak point of the diffraction line of the (200) face, (I(200)/Ib), is in the range of 4 to 16. The invention, consequently, has succeeded in enhancing relative permittivity, decreasing dielectric loss, and realizing a multilayer ceramic chip capacitor that excels in capacity temperature capacity even when the dielectric layers have a small thickness.
In the invention disclosed in JP-A 2001-345230 mentioned above, however, the specific surface area of the raw material powder of barium titanate that has been actually studied barely reaches 3.6 m2/g. The invention has given no study to the raw material powder having a larger specific surface area than the limit mentioned above. In consideration of the trend of dielectric ceramic layers toward further decrease in thickness, the study may be inevitably judged as insufficient. As a result of the study performed by the present inventors, it has been found that the analysis merely by X-ray diffraction cannot be necessarily rated as satisfactory.
This invention has been proposed in view of the the actual state of related art mentioned above and is aimed at providing a ceramic powder and a dielectric paste that, when used in a multilayer ceramic electronic component, enable enhancing relative permittivity and decreasing dielectric loss as well and, even when the decrease of layer thickness is further promoted, enable retention of sufficient capacitance temperature characteristic. This invention is also aimed at realizing a multilayer ceramic electronic component possessing a high dielectric property and excelling in temperature properties owing to the provision of the ceramic powder and the dielectric paste mentioned above and is further aimed at providing a method for the production thereof.
The present inventors have carried out many studies over a long time with a view to accomplishing the object mentioned above. To be specific, they have performed a further detailed analysis on the ceramic powder possessing a perovskite-type structure. As a result, they have eventually acquired a knowledge that the ceramic powder possessing the perovskite-type crystal structure mentioned above contains a tetragonal phase and a cubic phase and the optimization of the ratio (weight ratio) of the tetragonal phase and the cubic phase is effective for the purpose of enhancing the dielectric property of a multilayer ceramic capacitor.
This invention has been accomplished based on this knowledge. That is, the ceramic powder of this invention is a ceramic powder that is intended to form dielectric ceramic layers in a multilayer ceramic electronic component resulting from alternately stacking the dielectric ceramic layers and internal electrode layers and is characterized by possessing a perovskite-type crystal structure and satisfying an expression X≧3, wherein X denotes the weight ratio Wt/Wc of the tetragonal phase content Wt and the cubic phase content Wc.
The dielectric paste of this invention is a dielectric paste that is intended to form dielectric ceramic layers in a multilayer ceramic electronic component resulting from alternately stacking the dielectric ceramic layers and internal electrode layers and is characterized by containing the aforementioned ceramic powder as a ceramic powder. The multilayer ceramic electronic component of this invention is a multilayer ceramic electronic component that is resulting from alternately stacking dielectric ceramic layers and internal electrode layers and is characterized by the fact that the dielectric ceramic layers resulting from shaping dielectric green sheets with the dielectric paste and firing these sheets. The method for producing the multilayer ceramic electronic component of this invention, in the process of obtaining the multilayer ceramic electronic component by alternately stacking dielectric green sheets and electrode precursory layers respectively with a dielectric paste and an electroconductive paste and subsequently firing the resultant multilayer body, is characterized by using the dielectric paste mentioned above.
The ceramic powder for use in a dielectric ceramic layer has been heretofore analyzed by X-ray diffraction, for example, and based on the results of the analysis the ceramic powder about to be used has been tried to optimize. In the case of barium titanate, for example, though the X-ray chart is varied in consequence of the variation of the specific surface area, the idea of comprehending this variation of the X-ray diffraction chart as a variation of the lattice constant of a tetragonal phase and setting a range for the variation accordingly may be cited. The conventional method as mentioned above, however, has not always brought a satisfactory effect.
The present inventors, therefore, inferred that the variation of the X-ray diffraction chart mentioned above was caused by the mixed phase consisting of a tetragonal phase and a cubic phase. When they subjected the X-ray diffraction chart to polyphasic analysis (such as the biphasic analysis presuming the two phases, ie a tetragonal phase and a cubic phase) by the Rietveld method, the results concurred satisfactorily with the inference and endorsed the correctness of the inference. When the analysis was further advanced, it was found that the ratio of the tetragonal phase and the cubic phase was varied as by the conditions of production of barium titanate and this variation affected characteristic properties. Specifically, when the ceramic powder possessing the perovskite-type crystal structure satisfies the expression X≧3, wherein X denotes the weight ratio Wt/Wc of the tetragonal phase content Wt and the cubic phase content Wc, it is rendered possible to enhance the relative permittivity, suppress the dielectric loss, and maintain the sufficient capacitance temperature characteristic attainable by further advancing the thinning of layers.
This invention, as the index of the selection of raw material (ceramic powder), adopts the weight ratio Wt/Wc (=X) of the tetragonal phase content Wt and the cubic phase content Wc. By using the ceramic powder that is selected based on this index, it is rendered possible to enhance the relative permittivity and moreover depress the dielectric loss even when the dielectric ceramic layers forming the multilayer ceramic capacitor are required to incur decrease in thickness and increase in the number of layers in consequence of a reduction in size or a large addition to capacity, for example. It is further made possible to realize a multilayer ceramic electronic component (multilayer ceramic capacitor) excelling in capacitance temperature characteristic even when the dielectric ceramic layers happen to have a small thickness (not more than 3 μm, for example).
Now, the ceramic powder and the dielectric paste that make use of this invention and further the multilayer ceramic electronic component (specifically a multilayer ceramic capacitor herein) and the method for production thereof will be described in detail below.
First, to explain the multilayer ceramic capacitor that uses the ceramic powder of this invention, the main body of device is configured in a multilayer ceramic capacitor 1 by alternately stacking a plurality of pairs of dielectric ceramic layers and internal electrode layers as illustrated in
Though the shape of the main body does not need to be particularly restricted, it is generally in the shape of a rectangular body. The size of the main body does not need to be particularly restricted but may be properly set to suit the purpose of use. For example, it may approximately measure 0.6 mm to 5.6 mm (preferably 0.6 mm to 3.2 mm) in length×0.3 mm to 5.0 mm (preferably 0.3 mm to 1.6 mm) in width×0.1 mm to 1.9 mm (preferably 0.3 mm to 1.9 mm (preferably 0.3 mm to 1.6 mm) in thickness.
The dielectric ceramic layers 2 mentioned above are made of a dielectric ceramic composition and formed by sintering the powder of the dielectric ceramic composition (ceramic powder). This invention contemplates causing the dielectric ceramic composition to contain as a main ingredient a dielectric oxide possessing a perovskite-type crystal structure represented by the constitutional formula, ABO3 (wherein A site is formed of at least one element selected from the group consisting of Sr, Ca, and Ba and B site is formed of at least one element selected from the group consisting of Ti and Zr). Here, the amount of oxygen (O) may deviate to a certain extent from the stoichiometric composition of the aforementioned constitutional formula. Of all the dielectric oxides answering the constitutional formula, barium titanate that is obtained by forming the A site mainly of Ba and the B site mainly of Ti proves to be favorable. More favorably, the dielectric oxide is barium titanate represented by the constitutional formula, BamTiO2+m (wherein 0.995≦m≦1.010 and 0.995≦Ba/Ti≦1.010 are satisfied).
Besides the main ingredient, the dielectric ceramic composition may contain various kind of accessory ingredient. As the accessory ingredient, at least one oxide selected from the group consisting of oxides of Sr, Zr, Y, Gd, Tb, Dy, V, Mo, Zn, Cd, Ti, Sn, W, Ba, Ca, Mn, Mg, Cr, Si, and P may be cited. The addition of such an accessory ingredient results in enabling the sintering to proceed at a low temperature without degrading the dielectric property of the main ingredient. It also results in suppressing the inferior reliability taking place when the dielectric ceramic layers 2 are given a decreased thickness and as well allowing addition to the service life.
The conditions of the dielectric ceramic layers 2 such as the number of layers and the thickness of each layer may be properly decided to suit the purpose of use. The thickness of the dielectric ceramic layers 2 is about 1 μm to 50 μm and preferably not more than 5 μm. From the viewpoint of enabling the multilayer ceramic capacitor to acquire a decreased size and an increased capacity, the dielectric ceramic layers 2 prefer to have a thickness of not more than 3 μm and the dielectric ceramic layers 2 prefer to be stacked up to a total of not less than 150 layers.
Though the electroconductive material to be contained in the internal electrode layers 3 is not particularly restricted, such a base metal as, for example, Ni, Cu, Ni alloy, or Cu alloy may be used. The thickness of the internal electrode layers 3 may be properly decided to suit the purpose of use. It is, for example, about 0.5 μm to 5 μm and preferably not more than 1.5 μm.
Though the electroconductive material contained in the external electrodes 4 and 5 is not particularly restricted, generally Cu, Cu alloy, Ni, Ni alloy, Ag, or Ag—Pd alloy are used. Cu, Cu alloy, Ni, and Ni alloy prove to be advantageous because they are inexpensive materials. While the thickness of the external electrodes 4, 5 may be properly decided to suit the purpose of use, it is about 10 μm to 50 μm, for example.
In the multilayer ceramic capacitor 1 possessing the structure mentioned above, the dielectric ceramic composition (body material) that is used for the dielectric ceramic layers 2 exerts a great influence on the characteristic properties. This invention realizes enhancement of the dielectric property by rendering appropriate the ceramic powder destined to serve as the body material. Specifically, this invention subjects a ceramic powder possessing a perovskite-type crystal structure to powder X-ray diffraction analysis, performs polyphasic analysis by the Rietveld method on the results of the powder X-ray diffraction analysis, and selects a ceramic powder that satisfies the expression X≧3, wherein X denotes the weight ratio Wt/Wc of the tetragonal phase content Wt and the cubic phase content Wc.
Now, the polyphasic analysis by the Rietveld method mentioned above will be described below. In the powder X-ray diffraction analysis, for example, the lattice constant can be derived from the peak position, the crystal structure parameters (polarization coordinates, population, atomic displacement parameter, etc.) from the area (integrated intensity) of the diffraction profile, the lattice strain and the crystallite size from the broadening of profile, and the mass fractions of the component phases of a mixture. In the powder neutron diffraction analysis, the magnetic moments of various magnetic atomic sites can be derived further from the integrated intensity.
The Rietveld method mentioned above is a general-purpose technique for powder diffraction data analysis that can be simultaneously determining fundamentally important physical quantities in solid-state physics, chemistry, and materials chemistry and serves as a tool for comprehending physical phenomena and chemical properties manifested by polycrystalline materials from the structural aspect. The important object of the Rietveld method is to refine crystal structure parameters included in crystal structure factors Fk and serves the purpose of directly precising the structural parameters and the lattice constants with respect to the whole of powder X-ray diffraction patterns and powder neutron diffraction patterns. That is, this method implements the fitting of a diffraction pattern computed based on an approximate structure model in order that the computed diffraction pattern may agree as closely with the actually measured pattern as possible. As the salient advantages of the Rietveld method, the ability to determine not only the crystal structure parameters but also the lattice constant with high accuracy and precision and also the ability to determine the lattice strain, the crystallite size, and the contents of components in a mixture may be cited in respect of the fact the method admits all the analysis patterns as the objects of fitting and pays due respect to the presence of K α2 reflection in the case of the X-ray characteristic.
In the ceramic powder possessing a Perovskite-type crystal structure such as barium titanate, the presence of a tetragonal phase and a cubic phase has been known. The X-ray diffraction pattern of this ceramic powder is varied in concert with variation of the mean particle diameter (specific area) thereof.
Heretofore, it has been proposed to grasp a variation of the X-ray diffraction chart as a variation of the lattice constant and use it as an index of the ceramic powder to be used. When a=b is presumed in the lattice constants a, b, and c in the tetragonal phase as shown in
The rule set forth above, however, makes no great difference from defining the mean particle diameter or the specific surface area of the ceramic powder to be used and consequently acquire no sufficient result. The present inventors, therefore, have tried a detailed analysis of the X-ray diffraction chart. Specifically, the present inventors, by assuming that the state varying from
The results of the biphasic analysis mentioned above suggest firstly that the analysis excelling in precising ability has been implemented accurately. This fact may be safely regarded as endorsing the correctness of the aforementioned assumption (purporting the mixed phase between the tetragonal phase and the cubic phase) and has led the inventors to the comprehension that the ceramic powder having a relatively small mean particle diameter (a large specific surface area) is the mixed phase of a tetragonal phase and a cubic phase. To date, the barium titanate powder has never been recognized as the mixed phase of a tetragonal phase and a cubic phase.
Secondly, it has been ascertained that, when the ceramic powder is used as the body material for the dielectric ceramic layers 2 of the multilayer ceramic capacitor 2, the ratio of the tetragonal phase and the cubic phase exerts an influence on the characteristic properties and, particularly when importance is attached to the electrical characteristics, satisfaction of the expression X≧3, wherein X denotes the weight ratio Wt/Wc of the tetragonal phase content Wt and the cubic phase content Wc, is advantageous. By satisfying this expression X≧3, it is rendered possible to enhance the relative permittivity and moreover suppress the dielectric loss even when the dielectric ceramic layers 2 forming the multilayer ceramic capacitor 1 are given a reduced thickness or the number of component layers is increased. It is also made possible to realize a multilayer ceramic capacitor 1 excelling in capacitance temperature characteristic even when the dielectric ceramic layers 2 have a small thickness (not more than 3 μm, for example).
The weight ratio X mentioned above varies with the conditions for the production of the ceramic powder, for example. The X-ray diffraction chart, notwithstanding an unchanged appearance, possibly produces a value different from the weight ratio X mentioned above when it is actually subjected to polyphasic analysis by the Rietveld method mentioned above. Since this difference defies comprehension by the conventional X-ray diffraction analysis, it becomes necessary to find the value by the polyphasic analysis according to the Rietveld method mentioned above and select what satisfies the aforementioned condition.
As regards the aforementioned weight ratio Wt/Wc (=X) of the tetragonal phase content Wt and the cubic phase content Wc, the expression X≧3 constitutes the basis for the selection of the ceramic powder possessing the perovskite-type crystal structure as already pointed out. In this case, the fact that the ceramic powder is the mixed phase between a tetragonal phase and a cubic phase serves as a prerequisite and the ceramic powder consisting solely of a tetragonal phase (the value of X is infinitely large) is not included. If the value of the X mentioned above continues to increase, the possibility that the mean particle diameter will no longer be decreased in spite of contriving conditions of production, for example, will ensue and the possibility that the specific surface area will no longer be increased will also ensue. When the thinning of the dielectric ceramic layers 2 is taken into consideration, therefore, the value of X prefers to be 5 at most (namely X≦5).
This invention aims to maintain high dielectric properties while thinning the dielectric ceramic layers 2 and, therefore, prefers to give the component dielectric ceramic layers 2 a thickness of not more than 3 μm as described above. Abreast with the thickness, the specific surface area SSA of the ceramic powder to be used prefers to exceed 4 m2/g (mean particle diameter not more than 0.25 μm) and more favorable fall in the range of 4 m2/g to 10 m2/g. When the specific surface area SSA is 10 m2/g, the mean particle diameter is approximately 0.1 μm.
By using for the multilayer ceramic capacitor 1 the raw material (ceramic powder) selected by the method of selection of raw material based on the polyphasic analysis in accordance with the Rietveld method, it is rendered possible to realize further reduction in size and further addition to capacity of the multilayer ceramic capacitor 1. Thus, the multilayer ceramic capacitor contemplated by this invention is most suitable for uses requiring high dielectric properties. Now, the method for producing the multilayer ceramic capacitor using the aforementioned ceramic powder will be explained below.
To produce the multilayer ceramic capacitor possessing the aforementioned configuration, dielectric green sheets destined to form dielectric ceramic layers 2, electrode precursory layers destined to form internal electrode layers 3 subsequent to firing, and external cladding green sheets destined to form external cladding dielectric layers 6 are prepared and they are stacked to complete a multilayer body.
The dielectric green sheets can be obtained by preparing a dielectric paste containing a ceramic powder, applying this dielectric paste to carrier sheets as base materials by the doctor blade method, and drying the resultant coated carrier sheets. The dielectric paste is prepared by kneading the ceramic powder destined to serve as a body material and an organic vehicle or a water-based vehicle. For the preparation of the dielectric paste, the ceramic powder selected by the method of selection of raw material based on the polyphasic analysis in accordance with the Rietveld method is used. Then, the mean particle diameter and the specific surface area thereof are selected in conformity with the thickness of the dielectric ceramic layers 2 within the range mentioned above.
Incidentally, the expression “the organic vehicle that is used for the preparation of the dielectric paste mentioned above” refers to what results from dissolving a binder in an organic solvent. The binder to be used for the organic vehicle is not particularly restricted but may be properly selected from among various ordinary binders such as ethyl cellulose and polyvinyl butyral. The organic solvent to be used for the organic vehicle also is not particularly restricted but may be properly selected from among various organic solvents such as terpineol, diethylene glycol monobutyl ether, acetone, and toluene. The term “water-based vehicle” refers to what results from dissolving a water-soluble binder or dispersant in water. The water-soluble binder is not particularly restricted. The use of polyvinyl alcohol, cellulose, water-soluble acrylic resin, or the like suffices.
Then, the electrode precursory layer is formed by having the prescribed region of the dielectric green sheet mentioned above printed with an electroconductive paste containing an electroconductive material. The electroconductive paste is prepared by causing the electroconductive material and a common material (ceramic powder) to be kneaded with the organic vehicle.
After the multilayer body is formed, the sinter (main body of device) is obtained by performing a treatment for the removal of binder, a firing work, and a heat treatment adapted to re-oxidize the dielectric ceramic layers 2 and the external cladding dielectric layers 6. The treatment for the removal of binder, the firing work, and the heat treatment for the sake of re-oxidization may be performed continuously or independently.
The treatment for the removal of binder may be performed under ordinary conditions. When such a base metal as Ni or Ni alloy is used in the electroconductive material for the internal electrode layers 3, however, this treatment prefers to be carried out under the following conditions. The rate of temperature increase is in the range of 5 to 300° C./hour, particularly 10 to 50° C./hour, the standing temperature is in the range of 200 to 400° C., particularly 250 to 340° C., the standing time is in the range of 0.5 to 20 hours, particularly 1 to 10 hours, and the atmosphere is a heated mixed gas of N2 and H2.
As the firing conditions, the rate of temperature increase is in the range of 50 to 500° C./hour, particularly 200 to 300° C./hour, the standing temperature is in the range of 1100 to 1300° C., particularly 1150 to 1250° C., the standing time is in the range of 0.5 to 8 hours, articularly 1 to 3 hours, and the atmosphere is preferably a humidified mixed gas of N2 and H2.
During the firing, the oxygen partial pressure in the atmosphere prefers to be not more than 10−2 Pa. If the oxygen partial pressure exceeds the upper limit mentioned above, the excess will possibly result in oxidizing the internal electrode layers 3. If the oxygen partial pressure is unduly low, the shortage will tend to induce abnormal sintering of the electrode material and inflict a break on the internal electrode layers 3. The oxygen partial pressure of the firing atmosphere, therefore, prefers to be in the range of 10−2 Pa to 10−8 Pa.
The heat treatment after the firing is carried out with the holding temperature or the highest temperature set generally at not less than 1000° C. and preferably in the range of 1000° C. to 1100° C. If the holding temperature or the highest temperature mentioned above falls short of 1000° C., the shortage will possibly result in oxidizing the electroconductive material (Ni) in the internal electrode layers 3 and exerting an adverse effect on the capacity and the service life of the multilayer ceramic capacitor.
The atmosphere for the heat treatment mentioned above is given a higher oxygen partial pressure than that of the firing, preferably in the range of 10−3 Pa to 1 Pa and more preferably in the range of 10−2 Pa to 1 Pa. If the oxygen partial pressure of the atmosphere for the heat treatment falls short of the range, the shortage will render the re-oxidation of the dielectric layers difficult. Conversely, if it exceeds the range, the excess will possibly result in re-oxidizing the internal electrode layers 3. As the conditions of the heat treatment, the holding time is in the range of 0 to 6 hours, particularly 2 to 5 hours, the rate of temperature decrease is in the range of 50 to 500° C./hour, particularly 100 to 300° C./hour, and the atmosphere is humidified N2 gas, for example.
Finally, the multilayer ceramic capacitor 1 illustrated in
Now, a working example embodying this invention will be explained below based on the results of an experiment.
XRD (Powder X-Ray Diffraction) Measurement
The powder X-ray diffraction (XRD) measurement was performed by the use of a powder X-ray diffraction device (made by Rigaku K.K. and sold under the product name of Rint2000), and measurement range of 2θ is from 10 to 130°. As a result, XRD profile data for the Rietveld analysis was obtained. In this measurement, the electrical current and the electrical voltage were so set that the step width would reach 0.01° and the largest peak count about 10000 counts.
Rietveld Analysis
The XRD profile data consequently obtained was analyzed by the use of the software, RIETAN-2000 (Rev. 2.4.1) (for Windows), intended for Rietveld analysis. For the determination of the mass fractions of the component phases, the Microabsorption with due correction was adopted.
Study on Reliability of Polyphasic Analysis by Rietveld Method
Analysis of a barium titanate powder possessing a perovskite-type crystal structure (specific surface area SSA 6.16 m2/g and mean particle diameter 0.16 μm determined by a scanning electron microscope) was tried by the Rietveld method. The Rietveld analysis was executed in three modes, ie the monophasic analysis of a tetragonal phase (tetragonal crystal), the monophasic analysis of a cubic phase (cubic crystal), and the biphasic analysis of the tetragonal phase (tetragonal crystal)+the cubic phase (cubic crystal). The reliability factors in these analyses are shown in Table 1.
[Table 1]
Of the indexes for evaluating the condition of progress of the Rietveld analysis and the degree of agreement between the actual intensity and the calculated intensity, the most important R factor is Rwp. Since Rwp is prone to the influences of diffraction intensity and background intensity, however, the index S value (=Rwp/Re) destined to compare Re equaling the smallest statistically expected Rwp with Rwp serves as a substantial yardstick for indicating good fitness of analysis. S=1 signifies perfection of precision. So long as S is smaller than 1.3, the results of analysis may well be regarded as satisfactory. A review of Table 1 from this point of view reveals that the s value resulting from the biphasic analysis of the tetragonal phase and the cubic phase is not more than 1.3, namely a smaller s value than is the s value obtained by the monophasic analysis. This fact indicates properness of conclusion that the analyzed ceramic powder consists of the two, one tetragonal and one cubic, phases.
Study Regarding the Weight Ratio Wt/Wc (=X) of Tetragonal Phase Content Wt and Cubic Phase Content Wc in Ceramic Powder
Multilayer ceramic capacitors were manufactured by following the method of production described above while using varying kinds of ceramic powders (barium titanate powders) (Examples 1 to 3 and Comparative Examples 1, 2). The multilayer ceramic capacitors so manufactured had a size of 1.0 mm×0.5 mm×0.5 mm, the number of stacked dielectric ceramic layers was 160, the thickness of each of the component dielectric ceramic layers was 1.6 μm, and the thickness of each of the internal electrodes was 1.0 μm. The specific surface area SSA of the ceramic powder used, the mean particle diameter determined with the scanning electronic microscope SEM (SEM diameter), the content Wt of the tetragonal phase, the content Wc of the cubic phase, the weight ratio Wt/Wc (=X) of the contents, the lattice constants of the tetragonal phase and the cubic phase, the relative permittivity of the manufactured multilayer ceramic capacitor, the dielectric loss, and the rate of change of capacity ΔC/C (−25° C. and 85° C.) are show in Table 2.
[Table 2]
It is clear from Table 2 that in the ceramic powder to be used, the increase of the relative permittivity and the decrease of the dielectric loss are realized by satisfying the weight ratio Wt/Wc (=X)≧3 of the tetragonal phase and the cubic phase. This satisfaction brings a comparable result in the ratio of change of capacity.
Study Regarding Specific Surface Area of Ceramic Powder
Ceramic powders differing in specific surface area SSA were compared with respect to their characteristic properties exhibited when the weight ratio of the tetragonal phase and the cubic phase was not less than 3, ie Wt/Wc≧3, and when it was less than 3, ie Wt/Wc≦3. The results are shown in Table 3.
[Table 3]
It is clear from Table 3 that whenever the specific surface area SSA of the ceramic powder is in the range of 4 m2/g to 10 m2/g, the relative permittivity can be enhanced and the dielectric loss can be decreased so long as the weight ratio, Wt/Wc, of the tetragonal phase and the cubic phase satisfies the expression Wt/Wc≧3. When the ceramic powder to be used has a specific surface area SSA in the range of 4 m2/g to 10 m2/g and a weight ratio of the tetragonal phase and the cubic phase, Wt/Wc, of not less than 3, therefore, it is rendered possible to manufacture a multilayer ceramic capacitor that excels in terms of relative permittivity and dielectric loss.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2006-065944 | Mar 2006 | JP | national |
