Patent Grant
11370191
The present disclosure relates generally to nanofiber sheet fabrication. Specifically, the present disclosure relates to changing a density of a nanofiber sheet using an edged surface.
Nanofiber forests, composed of both single wall and multiwalled nanotubes, can be drawn into nanofiber ribbons or sheets. In its pre-drawn state, the nanofiber forest comprises a layer (or several stacked layers) of nanofibers that are parallel to one another and perpendicular to a surface of a growth substrate. When drawn into a nanofiber sheet, the orientation of the nanofibers changes from perpendicular to parallel relative to the surface of the growth substrate. The nanotubes in the drawn nanofiber sheet connect to one another in an end-to-end configuration to form a continuous sheet in which a longitudinal axis of the nanofibers is parallel to a plane of the sheet (i.e., parallel to both of the first and second major surfaces of the nanofiber sheet). The nanofiber sheet can be treated in any of a variety of ways, including spinning the nanofiber sheet into a nanofiber yarn.
Example 1 is a nanofiber sheet drawn from a nanofiber sheet source by a drawing mechanism and densified using an edged surface, the nanofiber sheet comprising: a first section of the nanofiber sheet disposed between the nanofiber sheet source and a first side of the edged surface, the first section having a first density; a second section of the nanofiber sheet disposed between the first side of the edged surface and the drawing mechanism, the second section have a second density different from the first density; and a transition section of the nanofiber sheet disposed between the first section and the first side of the edged surface.
Example 2 includes the subject matter of Example 1, wherein the second density of the second section is greater than the first density of the first section.
Example 3 includes the subject matter of Example 2, wherein the first section has a first width and the second section has a second width less than the first width.
Example 4 includes the subject matter of Example 1, wherein the second density of the second section is less than the first density of the first section.
Example 5 includes the subject matter of Example 4, wherein the first section has a first width and the second section has a second width that is greater than the first width.
Example 6 is a system for densifying a nanofiber sheet comprising: a nanofiber sheet source; a drawing mechanism configured for applying a tensile force to a nanofiber sheet drawn from the nanofiber sheet source; and at least one arcuate edge disposed between the nanofiber sheet source and the drawing mechanism.
Example 7 includes the subject matter of Example 6, wherein the at least one arcuate edge is concave and has a radius that is oriented 90°+/−30° relative to at least one of a plane of the nanofiber sheet, an axis of aligned nanofibers comprising the nanofiber sheet, or a direction in which the nanofiber sheet is drawn.
Example 8 includes the subject matter of Example 6, wherein the at least one arcuate edge is convex and has a radius that is oriented 90°+/−30° relative to at least one of a plane of the nanofiber sheet, an axis of aligned nanofibers comprising the nanofiber sheet, or a direction of draw.
Example 9 includes the subject matter of any of Examples 6-8, wherein the nanofiber sheet source further comprises: a substrate; and a nanofiber forest disposed on the substrate.
Example 10 includes the subject matter of any of Examples 6-9, wherein the drawing mechanism comprises a bobbin.
Example 11 includes the subject matter of any of Examples 6-10, wherein the at least one arcuate edge comprises a fracture surface of a cleaved silicon wafer.
Example 12 includes the subject matter of any of Examples 6-10, wherein the at least one arcuate edge comprises a blade.
Example 13 includes the subject matter of Example 12, wherein the blade is coated with polytetrafluorethylene.
Example 14 includes the subject matter of Example 13, wherein the blade is coated with polytetrafluorethylene.
Example 15 includes the subject matter of any of Examples 6-14, comprising: a first arcuate edge disposed to be in contact with a first major surface of the nanofiber sheet; and a second arcuate edge disposed to be in contact with a second major surface of the nanofiber sheet.
Example 16 includes the subject matter of any of Examples 6-15, wherein the first arcuate edge and the second arcuate edge are not coplanar with one another.
Example 17 includes the subject matter of any of Examples 6-16, wherein at least one of the first arcuate edge and the second arcuate edge are not coplanar with the drawing mechanism.
Example 18 includes the subject matter of any of Examples 6-17, wherein at least one of the first arcuate edge and the second arcuate edge are not coplanar with the nanofiber sheet source.
Example 19 includes the subject matter of any of Examples 6-18, wherein the arcuate edge transcribes a curve selected from a portion of a circle, a parabola or an ellipse.
Example 20 includes the subject matter of any of Examples 6-19, wherein the arcuate edge transcribes a curve along a radius extending from the nanofiber sheet source or from the drawing mechanism.
Example 21 includes the subject matter of any of Examples 6-20, wherein the arcuate edge transcribes a curve having a radius that perpendicular to a major surface of the nanofiber sheet.
Example 22 includes the subject matter of any of Examples 6-21, wherein the arcuate edge is curved in two different planes.
Example 23 includes the subject matter of any of Examples 6-22, wherein a curvature of the arcuate edge is adjustable.
Example 24 is a method for densifying a nanofiber sheet comprising: providing a nanofiber sheet having: a first density; a first major surface; and a second major surface opposite the first major surface; drawing the nanofiber sheet having the first density in a first direction so that at least one of the first major surface and the second major surface is drawn over and in contact with a corresponding at least one arcuate edge; and responsive to drawing the nanofiber sheet over and in contact with the at least one arcuate edge, changing the first density of the nanofiber sheet to a second density.
Example 25 includes the subject matter of Example 24, wherein changing the first density to the second density occurs at a location proximate to a line of contact between the nanofiber sheet and the at least one arcuate edge.
Example 26 includes the subject matter of Example 25, wherein the location proximate to the line of contact comprises a transition section.
Example 27 includes the subject matter of any of Examples 24-26, wherein the nanofiber sheet is a carbon nanotube nanofiber sheet.
The figures depict various embodiments of the present disclosure for purposes of illustration only. Numerous variations, configurations, and other embodiments will be apparent from the following detailed discussion.
Overview
There are a variety of methods that can be used to densify a nanofiber sheet. In some examples, a nanofiber sheet can be exposed to a solvent or other liquid. Upon removal of the solvent or other liquid, the nanofibers are drawn together thus increasing a density of the nanofiber sheet (whether measured in nanofibers per unit volume or mass per unit volume).
While liquid-based densification is effective and convenient, it does have some drawbacks. For example, nanofibers in an as-drawn, undensified sheet are often entangled. Also, nanofibers in an as-drawn, undensified sheet are not generally completely straight, but rather each nanofiber includes a variety of curves and changes in conformation or orientation along its length. The entanglements between nanofibers and the non-linear conformation of the nanofibers limits the degree to which a nanofiber sheet can be densified. While application and subsequent removal of a solvent from a nanofiber sheet does cause the nanofibers to draw closer together (in others words, densify), removal of the solvent is typically insufficient to disentangle and straighten the nanofibers en masse. Because the mechanical and electrical properties of nanofibers are highly anisotropic in a direction along a longitudinal axis of a nanofiber, nanofiber sheets, yarns, and other assemblies of nanofibers that retain nanofiber entanglements and non-linear conformations have mechanical and electrical properties that could be improved by disentangling and straightening the nanofibers.
“Microcombing” nanofiber sheets is one technique to disentangle and straighten the nanofibers. In this technique, a nanofiber sheet is drawn across an edge of a metallic, a using straight (i.e., having an edge that is a straight line) blade, such as a razor blade. The micron-scale irregularities in the edge of the blade act as a comb that helps to disentangle and straighten the nanofiber in a sheet. Once this microcombing is complete, the sheet can be densified using a solvent.
However, the combination of microcombing and liquid-densification is inefficient because it requires a two-step process to fully process a nanofiber sheet. Furthermore, the final density of a liquid-densified nanofiber sheet is partially a function of the density of the nanofiber sheet prior to being exposed to the liquid used in the liquid-based densification. In other words, the denser a nanofiber sheet is prior to liquid-based densification, the denser the nanofiber sheet will be after liquid-based densification.
Thus, in accordance with an embodiment of the present disclosure, techniques are described for changing a density of a nanofiber sheet using an edged surface, and in particular an arcuate edged surface. As described herein, a nanofiber sheet is drawn over (and in contact with) an arcuate edged surface. Depending on whether the arcuate surface is convex or concave (relative to the drawing direction of the nanofiber sheet) determines whether the nanofiber sheet density is increased relative to the as-drawn sheet or decreased relative to the as-drawn sheet.
Embodiments described herein produce many benefits. One benefit is the ability to straighten and align nanofibers within a nanofiber sheet, thus improving properties of the sheet (or yarn produced therefrom) and the ability to increase or decrease a density of the nanofiber sheet. Another benefit, for example, is the ability to tailor a width of a nanofiber sheet based on the dimensions and curvature of an edge surface that the nanofiber sheet is drawn over and in contact with. This enables a nanofiber sheet of a desired width to be produced, without removing material, regardless of a width of the as-provided nanofiber sheet. Another benefit, for example, is the ability to change a density of a nanofiber sheet both in terms of a number of nanofibers (or related parameter nanofiber mass) per unit of sheet width or sheet surface area and per unit of sheet volume. Changing the density of nanofibers per unit volume can, in turn, change an amount of a solvent and/or infiltration material imbibed by the sheet. In one example, a nanofiber sheet can be drawn so as to reduce its volumetric density, increasing a volume of interstitial spaces between fibers of the sheet and thus increasing an amount of infiltration material than can be imbibed by the sheet. Analogously, if a nanofiber sheet is drawn so as to increase its volumetric density, the interstitial spaces between fibers are decreased in size, thus reducing an amount of infiltration material than can be imbibed by the sheet. In another example, a nanofiber sheet can be drawn so as to increase its volumetric density, decreasing a volume of interstitial spaces between fibers of the sheet and thus decreasing an amount of infiltration material than can be imbibed by the sheet. In some embodiments, sheet density can be increased by greater than 50%, greater than 100% or greater than 200%. In other embodiments, sheet density can be decreased by greater than 10%, greater than 20% or greater than 50%. Similarly, the areal density of a nanofiber sheet can be increased or decreased, and in some cases the areal density may be increased by more than 10%, more than 20% or more than 50%. In other embodiments, the areal density may be decreased by more than 10%, more than 20% or more than 50%.
Applications of nanofiber sheets fabricated according to embodiments of the present disclosure can be used in a variety of applications, some of which include a sheet having a freestanding portion (i.e., a portion not in direct contact with a substrate). Example applications include, but are not limited to, filters, pellicles, electromagnetic interference (EMI) shields, and thermoacoustic speakers. In other applications, a freestanding portion of a nanofiber sheet (e.g., a sheet that has an unsupported center and a perimeter attached to a peripheral frame) may be used as a support for one or more other CNT sheets or materials including ceramics, metals, polymers, and films thereof.
A description of nanofiber forests and sheets precedes a description of techniques for densifying a nanofiber sheet using an edged surface.
Nanofiber Forests
As used herein, the term “nanofiber” means a fiber having a diameter less than 1 μm. While the embodiments herein are primarily described as fabricated from carbon nanotubes, it will be appreciated that other carbon allotropes, whether graphene, micron or nano-scale graphite fibers and/or plates, and even other compositions of nano-scale fibers such as boron nitride may be densified using the techniques described below. As used herein, the terms “nanofiber” and “carbon nanotube” encompass both single walled carbon nanotubes and/or multi-walled carbon nanotubes in which carbon atoms are linked together to form a cylindrical structure. In some embodiments, carbon nanotubes as referenced herein have between 4 and 10 walls. As used herein, a “nanofiber sheet” or simply “sheet” refers to a sheet of nanofibers aligned via a drawing process (as described in PCT Publication No. WO 2007/015710, and incorporated by reference herein in its entirety) so that a longitudinal axis of a nanofiber of the sheet is parallel to a major surface of the sheet, rather than perpendicular to the major surface of the sheet (i.e., in the as-deposited form of the sheet, often referred to as a “forest”). This is illustrated and shown in
The dimensions of carbon nanotubes can vary greatly depending on production methods used. For example, the diameter of a carbon nanotube may be from 0.4 nm to 100 nm and its length may range from 10 μm to greater than 55.5 cm. Carbon nanotubes are also capable of having very high aspect ratios (ratio of length to diameter) with some as high as 132,000,000:1 or more. Given the wide range of dimensional possibilities, the properties of carbon nanotubes are highly adjustable, or “tunable.” While many intriguing properties of carbon nanotubes have been identified, harnessing the properties of carbon nanotubes in practical applications requires scalable and controllable production methods that allow the features of the carbon nanotubes to be maintained or enhanced.
Due to their unique structure, carbon nanotubes possess particular mechanical, electrical, chemical, thermal and optical properties that make them well-suited for certain applications. In particular, carbon nanotubes exhibit superior electrical conductivity, high mechanical strength, good thermal stability and are also hydrophobic. In addition to these properties, carbon nanotubes may also exhibit useful optical properties. For example, carbon nanotubes may be used in light-emitting diodes (LEDs) and photo-detectors to emit or detect light at narrowly selected wavelengths. Carbon nanotubes may also prove useful for photon transport and/or phonon transport.
In accordance with various embodiments of the subject disclosure, nanofibers (including but not limited to carbon nanotubes) can be arranged in various configurations, including in a configuration referred to herein as a “forest.” As used herein, a “forest” of nanofibers or carbon nanotubes refers to an array of nanofibers having approximately equivalent dimensions that are arranged substantially parallel to one another on a substrate.
Some embodiments of nanofiber forests include nanofibers that have two portions in their as-deposited form. With reference to
Nanofiber forests as disclosed herein may be relatively dense. Specifically, the disclosed nanofiber forests may have a density of at least 1 billion nanofibers/cm2. In some specific embodiments, a nanofiber forest as described herein may have a density of between 10 billion/cm2 and 30 billion/cm2. In other examples, the nanofiber forest as described herein may have a density in the range of 90 billion nanofibers/cm2. The forest may include areas of high density or low density and specific areas may be void of nanofibers. The nanofibers within a forest may also exhibit inter-fiber connectivity. For example, neighboring nanofibers within a nanofiber forest may be attracted to one another by van der Waals forces. Regardless, a density of nanofibers within a forest can be increased by applying techniques described herein.
Methods of fabricating a nanofiber forest are described in, for example, PCT No. WO2007/015710, which is incorporated herein by reference in its entirety.
Various methods can be used to produce nanofiber precursor forests. For example, in some embodiments nanofibers may be grown in a high-temperature furnace. In some embodiments, catalyst may be deposited on a substrate, placed in a reactor and then may be exposed to a fuel compound that is supplied to the reactor. Substrates can withstand temperatures of greater than 800° C. or even 1000° C. and may be inert materials. The substrate may comprise stainless steel or aluminum disposed on an underlying silicon (Si) wafer, although other ceramic substrates may be used in place of the Si wafer (e.g., alumina, zirconia, SiO2, glass ceramics). In examples where the nanofibers of the precursor forest are carbon nanotubes, carbon-based compounds, such as acetylene may be used as fuel compounds. After being introduced to the reactor, the fuel compound(s) may then begin to accumulate on the catalyst and may assemble by growing upward from the substrate to form a forest of nanofibers. The reactor also may include a gas inlet where fuel compound(s) and carrier gasses may be supplied to the reactor and a gas outlet where expended fuel compounds and carrier gases may be released from the reactor. Examples of carrier gases include hydrogen, argon, and helium. These gases, in particular hydrogen, may also be introduced to the reactor to facilitate growth of the nanofiber forest. Additionally, dopants to be incorporated in the nanofibers may be added to the gas stream.
In a process used to fabricate a multilayered nanofiber forest, one nanofiber forest is formed on a substrate followed by the growth of a second nanofiber forest in contact with the first nanofiber forest. Multi-layered nanofiber forests can be formed by numerous suitable methods, such as by forming a first nanofiber forest on the substrate, depositing catalyst on the first nanofiber forest and then introducing additional fuel compound to the reactor to encourage growth of a second nanofiber forest from the catalyst positioned on the first nanofiber forest. Depending on the growth methodology applied, the type of catalyst, and the location of the catalyst, the second nanofiber layer may either grow on top of the first nanofiber layer or, after refreshing the catalyst, for example with hydrogen gas, grow directly on the substrate thus growing under the first nanofiber layer. Regardless, the second nanofiber forest can be aligned approximately end-to-end with the nanofibers of the first nanofiber forest although there is a readily detectable interface between the first and second forest. Multi-layered nanofiber forests may include any number of forests. For example, a multi-layered precursor forest may include two, three, four, five or more forests.
Nanofiber Sheets
In addition to arrangement in a forest configuration, the nanofibers of the subject application may also be arranged in a sheet configuration. As used herein, the term “nanofiber sheet,” “nanotube sheet,” or simply “sheet” refers to an arrangement of nanofibers where the nanofibers are aligned end to end in a plane. An illustration of an example nanofiber sheet is shown in
As can be seen in
Nanofiber sheets may be assembled using any type of suitable process capable of producing the sheet. In some example embodiments, nanofiber sheets may be drawn from a nanofiber forest. An example of a nanofiber sheet being drawn from a nanofiber forest is shown in
As can be seen in
Nanofiber sheets have many properties that can be exploited for various applications. For example, nanofiber sheets may have tunable opacity, high mechanical strength and flexibility, thermal and electrical conductivity, and may also exhibit hydrophobicity. Given the high degree of alignment of the nanofibers within a sheet, a nanofiber sheet may be extremely thin. In some examples, a nanofiber sheet is on the order of approximately 10 nm thick (as measured within normal measurement tolerances), rendering it nearly two-dimensional. In other examples, the thickness of a nanofiber sheet can be as high as 200 nm or 300 nm. As such, nanofiber sheets may add minimal additional thickness to a component.
As with nanofiber forests, the nanofibers in a nanofibers sheet may be functionalized by a treatment agent by adding chemical groups or elements to a surface of the nanofibers of the sheet and that provide a different chemical activity than the nanofibers alone. Functionalization of a nanofiber sheet can be performed on previously functionalized nanofibers or can be performed on previously unfunctionalized nanofibers. Functionalization can be performed using any of the techniques described herein including, but not limited to CVD, and various doping techniques.
Nanofiber sheets, as drawn from a nanofiber forest, may also have high purity, wherein more than 90%, more than 95% or more than 99% of the weight percent of the nanofiber sheet is attributable to nanofibers, in some instances. Similarly, the nanofiber sheet may comprise more than 90%, more than 95%, more than 99% or more than 99.9% by weight of carbon.
Mechanically Changing Nanofiber Sheet Density
As described above, embodiments disclosed herein mechanically alter a density of a nanofiber sheet (or ribbon) while also disentangling and straightening the nanofibers therein. As described in more detail below, this is accomplished by drawing a nanofiber sheet over and in contact with an edged surface. Examples of edged surfaces include, but are not limited to, surgical blades, surgical blades coating with polytetrafluoroethylene (PTFE), and a fracture surface of a cleaved silicon wafer. In various embodiments, the contact surface of the edge can have a length of contact (in the direction of the axis of draw) with the nanofiber sheet of less than 5 mm, less than 1 mm, less than 500 μm, less than 250 μm or less than 100 μm. The contact surface can be smooth and, along the edge, may exhibit an absence of peaks or valleys of greater than, for example, 1 μm, 2 μm, 5 μm, 10 μm, 50 μm or 100 μm that are otherwise present in conventional razor blades. The aligned nanofibers of the nanofiber sheet may be oriented along the same axis as is the direction of draw which is also typically the same direction as the nanofiber sheet is pulled over the edged surface.
In particular, the PTFE coated surgical blades and the fracture surface of a cleaved silicon wafer can be used because of their uniform edged surfaces which produce uniform nanofiber sheets. This is distinct from the microcombing techniques described above, which rely on inhomogeneities and defects in an edge of a blade to straighten nanofibers in the sheet. Unlike embodiments of the present disclosure, the defects in a blade used in a traditional microcombing technique produce nanofiber sheets that vary in nanofiber density and defect density. These variations in the traditional technique include longitudinal tears in a major surface of the nanofiber sheet caused by some of the defects in the blade. While non-torn portions of the nanofiber sheet can be denser, longitudinal tears reduce the usefulness of a nanofiber sheet.
Embodiments herein also include using an edge of an arcuate surface. Vectors normal to points on the arcuate surface are parallel to major surfaces of nanofiber sheet. In other words, the direction of curvature of the arcuate surface can be thought of as a portion of a surface of a cylinder, in which a longitudinal axis of the cylinder is perpendicular to the major surfaces of the nanofiber sheet. The edge of the arcuate surface can, in embodiments, be partially or completely coplanar with a major surface of the nanofiber sheet. In one embodiment, by using an edged surface having a convex surface that faces the drawing direction of the nanofiber sheet, the nanofiber sheet expands in width. While the nanofibers in the sheet are straightened and disentangled, the number of nanofibers per unit volume of nanofiber sheet decreases because the width of the sheet increases. This can be useful for nanofiber sheets for any number of reasons. For example, a less dense nanofiber sheet with straight and disentangled nanofibers may be desired to be infiltrated with another material in a greater proportion than possible with a denser nanofiber sheet.
In another embodiment, by causing the edged surface to have a concave surface that faces the drawing direction of the nanofiber sheet, the nanofiber sheet, when drawn in contact with this surface contracts in width. This not only straightens and disentangles the nanofibers in the sheet, it also increases the number of nanofibers per unit volume of the sheet by decreasing the width of the sheet. This can lead to denser nanofiber yarns spun from the nanofiber sheet.
The curvature of the arcuate surface may be consistent or may vary along the length of the edge of the surface. In various embodiments, the curvature may be formed from portions of a circle, parabola or an ellipse, for example. In some cases the curvature is fixed while in others it may be adjustable. For example, a flexible curved blade can be kept in compression by two opposed clamp surfaces. The amount of curvature can be adjusted by reducing or expanding the distance between the clamp surfaces. Adjustments may be warranted for different sources of nanofiber sheets or by different properties in the finished sheet, such as variations in density. The curvature can also be adjusted in real time to assure quality and may be responsive to upstream or downstream analytical input, such as a measurement of downstream or upstream sheet density.
As shown in
The nanofiber forest 516, described above, is disposed on the substrate 520. The substrate 520 can be growth substrate, like those described above or it can be a transfer substrate on which the nanofiber forest has been disposed after having been grown on the growth substrate. Regardless, the nanofiber forest is drawn into the nanofiber sheet 524. Techniques for growing and drawing nanofiber forests into a nanofiber sheet are described in PCT in Publication No. WO 2007/015710, which is incorporated by reference herein in its entirely.
In the example system 500, the nanofiber sheet 524 is passed over, and in contact with, an arcuate edge of the blade 504 (example arcuate shapes of which are shown in
As described above, each of the blades 504 and 508 can be, for instance, a surgical blade, a PTFE coated surgical blade, a fracture surface of a cleaved silicon wafer, or combinations thereof. All of these options provide an edged surface against which the nanofiber sheet 524 can be drawn, thus altering the structure of the sheet through, for example, straightening and disentangling the nanofibers therein. Other types of blades 504, 508 that provide a uniform, edged surface may also be used in place of those specifically identified above.
The sharp edges of the blades 504, 508 are also helpful for at least another reason. Nanofiber sheets, like the nanofiber sheet 524, stick to most surfaces that they come into contact with. However, the nanofiber sheet 524 does not stick to the sharp edges of the blades 504, 508 because of their minimal surface area. This can be particularly true for those edge materials with low surface energy, like PTFE coated surfaces. Low surface energy materials can be those exhibiting large water drop angles, such as greater than 100°, greater than 105° or greater than 110° or having a low coefficient of friction, such as less than 0.3, less than 0.2, or less than 0.1.
Using a PTFE coated surgical blade (or other PTFE coated sharp edge) and the fracture surface of a cleaved silicon wafer have another benefit. In both of these embodiments, the edge placed in contact with the nanofiber sheet 524 is uniform, lacking the dents, chips, inhomogeneities and topical variation found in, for example, a standard blade or other sharp metallic surface. These topical variations can introduce a longitudinal tear or local density variation in the nanofiber sheet 524 as the sheet 524 is drawn over the topical variation. Tears and variations produce a less uniform nanofiber sheet 524 that has location-dependent variation in mechanical and electrical properties. As a result, providing an edge that is more uniform than a conventional steel edge is preferable.
The orientation and placement of the blades 504, 508 is selected to improve the ability of the edged surfaces of the blades 504, 508 to disentangle and straighten the nanofibers within the nanofiber sheet 524. This improvement is accomplished in two ways. First, the blades 504, 508 are placed so that a corresponding edged surface (or the blade itself) is at an angle to the corresponding major surface of the nanofiber sheet 524. The angle may be orthogonal or non-orthogonal. These angles are indicated in
Second, the blades 504, 508 are placed relative to one another to apply an additional tensile stress (or simply “tension”) to a section of the nanofiber sheet 524 disposed between the blades 504, 508 beyond the tensile force provided by the drawing mechanism 512 (such as a motorized bobbin or other drawing mechanism). This added tension facilitates straightening and disentangling of the nanofibers in the nanofiber sheet 524, in addition to the straightening and disentangling provided by the edged surface of the blades 504, 508 alone. In some examples, the tensile stress is on the order of from 0.1 MPa to 1 MPa. In the example system 500, the placement of blade 504 relative to the blade 508 is indicated by angle χ. Similarly, tension is added by the placement of the blade 508 relative to the drawing mechanism 512, which is indicated by angle δ. The angle χ is the angle between the section of the nanofiber sheet 524 between the blade 504 and the blade 508 relative to the section of the nanofiber sheet 524 between the nanofiber forest 516 and the blade 504. Similarly, the angle δ is the angle between the section of the nanofiber sheet 524 between the blade 508 and the draw mechanism 512 relative to the section of the nanofiber sheet 524 between the blade 504 and the blade 508. In various embodiments, angles χ and δ can be, for example, greater than 1°, greater than 5θ, greater than 10°, greater than 20°, greater than 45°, less than 120°, less than 90° or less than 45°.
Turning briefly to
Returning to the example system 500, the drawing mechanism 512 applies a tensile force to the nanofiber forest 516, thus drawing the nanofiber sheet 524 from the nanofiber forest 516 on the substrate 520. Examples of the drawing mechanism 512 include a motorized rotary mechanism, such as a bobbin. The drawing mechanism can provide a tensile or pulling force throughout an entire length of the nanofiber sheet, thus drawing the nanofiber sheet from the sheet source. In some examples, the tensile force is sufficient to draw the nanofiber sheet directly from a nanofiber forest on a substrate so that nanofibers from the nanofiber forest are removed from the substrate and progressively processed by the nanofiber sheet densification system. The tensile force can be constant or be varied by varying a torque applied to the drawing mechanism by a motor, spring, or other mechanism. The magnitude of the tensile force can also be used to influence an alignment between nanofibers of the yarn. Generally speaking, the greater the magnitude of the tensile force the higher a degree of alignment between nanofibers, between nanofibers and nanoparticles, and between nanoparticles. The tensile force applied by the drawing mechanism can be selected in coordination with the relative location of the blades 504, 508, as described above.
Arcuate Edged Surface
The effect on the nanofiber sheet of an arcuate edged surface of is described below in the context of
The result of mechanically changing the width of the nanofiber sheet from the width W1 at the as-supplied section 600 to the greater width W2 at the second section 624 has the effect of reducing the density of the second section to a density less than the density of the as-supplied section 600.
The result of mechanically changing the width of the nanofiber sheet from the width W1 at the as-supplied section 600 to the narrow width W3 at the section 644 also has the effect of increasing the density of the section 644 to a density greater than the density of the as-supplied section 600.
In an embodiment, a nanofiber sheet drawn from a nanofiber forest (or other nanofiber sheet source) and processed according to embodiments described herein can be thought of as having three sections. The first section (e.g., section 600) has a density corresponding to the nanofiber sheet as drawn from a nanofiber forest or as provided from a nanofiber sheet source (e.g., a spool of nanofiber sheet). This first section is disposed between the source of the nanofiber sheet (not shown in
Example Method
Further Considerations
The foregoing description of the embodiments of the disclosure has been presented for the purpose of illustration; it is not intended to be exhaustive or to limit the claims to the precise forms disclosed. Persons skilled in the relevant art can appreciate that many modifications and variations are possible in light of the above disclosure.
The language used in the specification has been principally selected for readability and instructional purposes, and it may not have been selected to delineate or circumscribe the inventive subject matter. It is therefore intended that the scope of the disclosure be limited not by this detailed description, but rather by any claims that issue on an application based hereon. Accordingly, the disclosure of the embodiments is intended to be illustrative, but not limiting, of the scope of the invention, which is set forth in the following claims.
This application claims priority under 35 USC § 119(e) to U.S. Provisional Patent Application No. 62/542,355 entitled “Changing a Density of a Nanofiber Sheet Using an Edged Surface,” filed on Aug. 8, 2017, which is incorporated by reference herein in its entirety.
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| Number | Date | Country | |
|---|---|---|---|
| 20190047247 A1 | Feb 2019 | US |
| Number | Date | Country | |
|---|---|---|---|
| 62542355 | Aug 2017 | US |
