This application is based on Japanese Patent Application No. 2017-251779, the content of which is incorporated herein to by reference.
1. Technical Field
The present invention relates to a circuit board having an electroconductive pattern formed on the surface of a base, a method of manufacturing the same, a touch panel sensor sheet having the circuit board, and a screen printing plate.
2. Related Art
In recent years, there has been a sharply increasing demand for a touch panel as disclosed in JP-A-2011-054122, as handheld devices such as smartphones become widespread. With the touch panel of the electrostatic capacitance type described in JP-A-2011-054122, implemented is a so-called, multi-touch function by which gestures of two or more fingers may slide screen contents, or steplessly enlarge or shrink them. There are known various configurations of sensor sheets used for the electrostatic capacitance type touch panel. Specific examples include those having X- and Y-sensor patterns formed respectively on both surfaces of a translucent base such as an organic film or glass plate, those configured by forming X- and Y-sensor patterns respectively on two translucent bases and then bonding the bases, and those configured by forming X- and Y-sensor patterns on one surface of a translucent base. Among them, the sensor sheet having the X- and Y-sensor patterns formed on one surface of a translucent base includes a transparent insulating material at the intersections of the transparent X- and Y-sensor patterns so as to avoid short-circuiting of the both.
In a touch panel sensor sheet described in JP-A-2011-243928, either one of the X- and Y-sensor patterns (X-sensor pattern, for example) is formed in an indiscrete manner, and the other sensor pattern (Y-sensor pattern, for example) is formed in a discrete manner. The discretely formed portions of the sensor pattern are bridged by a jumper structure composed of a transparent electroconductive pattern. More specifically, a part of the X-sensor pattern is covered with a transparent insulating material, and on the transparent insulating material, the transparent electroconductive pattern which extends in the Y-direction is formed. In this way, the discretely formed portions of the Y-sensor pattern are bridged. The transparent insulating material will be referred to as “transparent insulating pattern” or “jumper pattern”, hereinafter. In recent years, for the purpose of improving visible light transmissivity of the touch panel sensor sheet, efforts have been made on forming the transparent electroconductive pattern, by using transparent electroconductive materials in place of metal materials, relatively with smaller line widths. Published Japanese Translation of PCT International Publication for Patent Application No. 2002-500405 proposes use of a water-dispersed electroconductive paste such as polyethylene dioxythiophene (PEDOT) paste as the transparent electroconductive material, which is patterned by screen printing into a desired shape.
The PEDOT paste has a very large surface tension since water is used as a part of the solvent thereof, and it is therefore difficult to ensure a sufficient level of wettability on the surface of the underlying layer. In particular, for the case where the underlying layer is composed of a plurality of different materials including those for transparent insulating pattern, X- and Y-sensor patterns and so forth, the PEDOT paste will exhibit different levels of wettability from part to part on the underlying layer, making it difficult to form a thin-line jumper pattern in a stable manner. More specifically, an effort of forming the thin-line jumper pattern will result in fluid migration of the PEDOT pate in the middle of line, proving it difficult to form the jumper pattern with dimensions precisely as designed.
This sort of problem which possibly arises in the process of forming the electroconductive pattern is not an issue for the touch panel only. In recent years, many of electronic devices are required to have flexible substrates and shrunk electroconductive pattern, and in pursuit of formation of the electroconductive pattern with high quality and precise dimensions as designed.
The present invention was conceived in consideration of the problems described above, and is to provide a method of manufacturing a circuit board capable of forming a narrow-width electroconductive pattern with precise dimensions as designed, even if the transparent electroconductive material used herein has a large surface tension and can ensure a sufficient level of wettability on the printing base only with difficulty, just as exemplified by the PEDOT paste. The present invention is also to provide a circuit board manufacture by the method, and a screen printing plate used for the method of manufacturing.
According to the present invention, there is provided a method of manufacturing a circuit board, the method includes:
establishing stand-by by setting a screen printing plate so as to be opposed with a base, the screen printing plate having a line pattern formed therethrough, and the line pattern being configured by a plurality of dot-like through-holes discretely pierced and arrayed in a single line or in a plurality of lines;
coating an ink which contains a water-dispersed electroconductive paste into the surface of the screen printing plate;
ejecting the ink through the dot-like through-holes onto the surface of the base, by pressing the screen printing plate onto the base under sliding contact of a squeegee with the surface of the screen printing plate, and allowing ink dots ejected out from the adjacent through-holes to fuse on the surface of the base, to thereby form a linear ink puddle; and
drying the linear ink puddle to form an electroconductive pattern on the surface of the base.
According to the present invention, there is provided a circuit board which includes an electroconductive pattern composed of an organic electroconductive polymer, formed in a line pattern. The electroconductive pattern has dense areas and sparse areas alternately disposed repetitively in the longitudinal direction of the electroconductive pattern. The dense areas have, when counted in the widthwise direction, a large number of grains of the organic electroconductive polymer, and the sparse areas have a small number of grains.
According to the present invention, there is provided a touch panel sensor sheet which includes the circuit board described above. The base includes a flexible transparent sheet composed of a visible: light transmissive material; and a first electrode and a second electrode, which configure a first underlying area, and an insulating pattern which configures a second underlying area, both areas are formed on one surface of the transparent sheet. The first electrode contains a plurality of first electrode patterns arrayed repetitively in a first direction and connected with each other, and the second electrode contains a plurality of second electrode patterns arrayed in a second direction which crosses the first direction, while being spaced from the first electrode patterns. The insulating pattern covers an interconnect between the adjacent first electrode patterns, and the electroconductive pattern is formed above the interconnect, so as to configure a jumper pattern which connects the adjacent second electrode patterns.
According to the present invention, there is provided a screen printing plate having a line pattern formed therethrough. The line pattern is configured by a plurality of dot-like through-holes discretely pierced and arrayed in a single line or in a plurality of lines.
The above and other objects, advantages and features of the present invention will be more apparent from the following description of certain preferred embodiments taken in conjunction with the accompanying drawings, in which:
The invention will be now described herein with reference to illustrative embodiment. Those skilled in the art will recognize that many alternative embodiments can be accomplished using the teachings of the present invention and that the invention is not limited to the embodiments illustrated for explanatory purposes.
Embodiments of the present invention will now be explained referring to the attached drawings. Note that, in all drawings, all similar constituents will be given similar reference numerals or symbols, and the explanation will not always be repeated. The explanation will be made in some cases while defining the upward and downward directions, merely for the purpose of explaining relative positional relations among the constituent for convenience, without always meaning the vertical direction of gravity.
The method of manufacturing a circuit board according to an embodiment of the present invention (occasionally referred to as “the present method”, hereinafter) will be explained while dividing it into a plurality of steps in some cases, the order of description of which will not always restrict the order or timing of implementation of the individual steps. When the present method is implemented, the order of the plurality of steps may be modified without adversely affecting the gist, and a part of or entire portion of the timing of implementation of the plurality of steps may overlap.
First, a screen printing plate 10 used in the present method will be outlined.
The screen printing plate 10 of this embodiment characteristically has line patterns 20 formed therethrough, and each line pattern 20 is configured by a plurality of dot-like through-holes 30 discretely pierced and arrayed in a single line or in a plurality of lines. As illustrated in
The line pattern herein has a liner or curved oblong geometry, characterized by the longitudinal dimension larger than the widthwise dimension. Each line pattern 20 of this embodiment corresponds to an area occupied by an assembly of a plurality of through-holes 30 discretely formed and arrayed in a single line or in a plurality of lines.
Material and dimension of the screen printing plate 10 are not specifically limited. For example, the thickness may be 10 μm or larger and 200 μm or smaller, and more preferably 20 μm or larger and 50 μm or smaller. A metal mask is preferably used as the screen printing plate 10 of this embodiment. The line pattern 20 may be formed in the screen printing plate 10, by any method selectable from etching, laser working and electroforming (additive process). From the viewpoint of dimensional and positional accuracies of the through-holes 30, also the mask pattern may be formed by the additive process on the screen printing plate 10. Material for composing the screen printing plate 10 is exemplified by nickel-based alloys. Alternatively, also a screen mesh, configured by a metal mesh fabric with a part of openings thereof stopped with an emulsion, is usable as the screen printing plate 10. The metal mask is, however, used more suitably from the viewpoint of stability in the amount of election of ink, since the opening have neither weft nor warp exposed therein, unlike the openings of fabric.
The line pattern 20 is configured by the through-holes 30 arrayed in a single line or in a plurality of lines. In this embodiment, the through-holes 30 are arrayed in a plurality of (N) lines in the widthwise direction. In the longitudinal direction of line, there are arrayed through-holes 30, where the number of arrayed holes is larger than that (N) in the widthwise direction.
While
Next, the present method will be outlined referring to
The present method includes a stand-by step, a coating step (
In the stand-by step, the screen printing plate 10, which has line patterns 20 formed therethrough, each line pattern 20 being configured by a plurality of dot-like, through-holes 30 discretely pierced and arrayed in a single line or in a plurality of lines, is set so as to be opposed with a base 200. The direction of arrangement of the through-holes 30, that is, the direction in which the line patterns 20 extend, agrees with the rightward direction in
In the ejection step, a squeegee 170 is brought into sliding contact with the surface of the screen printing plate 10, and thereby the screen printing plate 10 is pressed onto the base 200. By the action, the ink 150 applied by scraper coating is ejected out from the dot-like through-holes 30 onto the surface of the base 200 to form in dots 152, and the ink dots 152 elected out from the adjacent through-holes 30 are allowed to fuse on the surface of the base 200, to thereby form a linear ink puddle. The ink dots 152 fused to form the linear in puddle are shown in
According to the present. method, it is now possible to form a narrow-width electroconductive pattern with high quality, even when an electroconductive ink used herein has a large surface tension and can ensure a sufficient level of wettability on the printing base only with difficulty.
Next, the present method will be explained in further detail.
The screen printing plate 10 used in the present method is a metal mask. in the stand-by step illustrated in
The ink 150 used in the coating step of the present method contains a water-dispersed electroconductive paste as a main ingredient. The water-dispersed electroconductive paste is configured by an organic electroconductive polymer dispersed in a water-based solvent.
The organic electroconductive polymer is exemplified by PEDOT (polyethylene dioxythiophene) polyaniline and polypyrrole. From the viewpoint of stability of forming of the electroconductive pattern 100, PEDOT is particularly preferable. PEDOT generally refers to a product obtained by mixing PSS (polystyrene sultanate) into PEDOT, and is also denoted as PEDOT/PSS. In this patent specification, the mixture is simply referred to as PEDOT or PEDOT paste.
In the ejection step, the squeegee 170 is slid over the surface of the screen printing plate 10 while being brought into contact therewith. By the action, the ink 150 is pushed through the through-holes 30 out onto the base 200, whereas an extra ink 150 is scraped off. Since the screen printing plate 10 is elastic, so that the screen printing plate 10 bends and is pressed onto the base 200, under sliding contact of the squeegee 170 with the screen printing plate 10. Relation between the direction of travel of the squeegee 170 and the direction in which the line patterns 20 extend is arbitrary. The squeegee 170 may be allowed to travel in parallel with, or obliquely to the longitudinal direction of the line patterns 20. As illustrated in
As illustrated in
The ink (ink dot 152) ejected out from one through-hole 30 is preferably allowed to fuse with another portion of the ink (ink dot 152), based on diffusion with the aids of wettability on the surface of the base 200 and creepage on the back surface out from the through-holes 30. In this case, the adjacent ink dots 152 ejected onto the base 200 may be fused in a successful manner, by appropriately adjusting various parameters which include the diameter (Dd) of the through-hole 30, center-to-center distance (Pd, Pw) of the adjacent through-holes 30, the thickness (Tm) of the screen printing plate, the viscosity of the ink 150, rate of volatilization of solvent in the ink 150, pressing force of the squeegee 170 against the screen printing plate 10, and the wettability on the surface of the base 200.
More specifically, when a metal mask is used as the screen printing plate 10, the thickness (TM) of the screen printing plate 10, the diameter (Dd) of the through-hole 30, and the center-to-center distance (P1) of the through-holes 30 which are adjacent in the direction of travel of the squeegee 170 may be set so as to satisfy Formula (1) below. In the formula, the right side of the formula means that the adjacent through-holes 30 are spaced from each other.
2.5×Tm≧P1−Dd>0 Formula (1)
Now, for the case where the squeegee 110 is allowed to travel in the direction in which the line patterns 20 extend, the center-to-center distance (P1) agrees with the linewise pitch (Pd). For the case where the squeegee 170 is allowed to travel in the widthwise direction of the line patterns 20, the center-to-center distance (P1) agrees with the widthwise pitch (Pw) (see
The center-to-center distance (P2) of the through-holes 30 adjacent in the direction orthogonal to the direction of travel. of the squeegee 170 may be determined so as to satisfy Formula (2) below:
1.5×Tm≧P2−Dd>0 Formula (2).
The linewise pitch (Pd) may be determined so as to satisfy Formula (3) below. When determined as above, the screen printing plate 10 may be processed in a successful manner.
Pd−Dd≧Tm Formula (3)
The linewise pitch (Pd) may be determined so as to satisfy Formula (4) below:
Pd>2×Tm Formula (4).
Assuming now that the through-hole 30 is circular, the diameter (Pd) means the diameter of the through-hole 30. If the through-hole 30 is not circular, the diameter is given by an average of the widthwise dimension of the through-holes measured in cross. sections, taken along a line which passes the centers of gravity of the through-holes 30 and extends in the longitudinal direction of the line pattern 20. The center-to-center distance (Pd) of the through-holes 30 is given by an average of the distance between the centers of gravity (face centers) of the adjacent through-holes 30.
Referring to the Formulae (1) and (2), it is understood that as the thickness (Tm) of the screen printing plate 10 is set large, the adjacent ink dots 152 will remain fusable with each other, even if the values of distance (P1−Dd) and (P2−Dd) between the adjacent edges of the through-holes 30 increase.
Referring to the Formula (4), thickness of undried ink dot. 152 is equivalent to the thickness (Tm) of the screen printing plate 10. When the electroconductive pattern 100 is formed by using the ink 150 mainly composed of an organic electroconductive polymer, electric resistance of the electroconductive pattern 100 may be suppressed to a desired level or below by suppressing the thickness (Tm) of the screen printing plate 10 and increasing the diameter (Dd), and not only the electroconductive pattern 100, but also the circuit board 50 may be improved in the flexibility by the thin film effect. In this case, it is recommendable to set the diameter (Dd) and the thickness (Tm) of the screen printing plate 10, so as to satisfy Formula (5) below:
Diameter (Dd)≧Thickness (Tm) of screen printing plate 10 Formula (5).
In the present method, the ink 150 is coated using the screen printing plate having formed therein a plurality of dot-like openings smaller than the design dimension of the electroconductive pattern 100, rather than using a screen printing plate with a dimension of openings equal to the design dimension of the electroconductive pattern 100. The electroconductive pattern 100 is converted to an assembly of discrete dots, the ink dots 152 are formed at the position of the dots, and the ink dots 152 are then fused to form the electroconductive pattern 100. By coating the ink 150 so as to be diversified into a large number of ink dot 152, a possible range of liquid migration of the ink 150 coated on the base 200 may be restricted within the individual dots. In addition, since the adjacent ink dots 152 may be fused by virtue of proximity of the through-holes 30, the electroconductive pattern 100 is ensured to have electro-conductivity. According to the present method, a single electroconductive pattern 100 of a desired dimension may be formed by piercing a large number of through-holes 30 in a plurality of lines, depending on a desired widthwise dimension of the electroconductive pattern 100 to be produced, and by fusing the ink dots 152 arrayed in the plurality of lines in the widthwise direction and the longitudinal direction. The linear electroconductive pattern 100 means that the length thereof is larger than the width, typically characterized by a ratio of the length to the width of 3 or larger. Dimensions of the electroconductive pattern 100 is not specifically limited. The widthwise dimension of the electroconductive pattern 100 may be 10 μm or larger, and even may be 1 mm or larger. For example the length may be 500 μm or longer, the width may be 100 μm or wider, and the ratio of length and width may be 5 or larger.
As illustrated in
As illustrated in
The circuit board 50 composing the touch panel sensor sheet 250 of this embodiment includes the base 200 and the electroconductive patterns 100 (see
More specifically, the base 200 has a transparent sheet 202, the first electrode 300, the second electrode 320 and the insulating patterns 340. The transparent sheet 202 is composed of a visible light transmissive resin material, film glass or the like. All of the first electrode 300, the second electrode 320 and the insulating patterns 340 are formed on one surface of the transparent sheet 202. The first electrode 300, the second electrode 320 and the insulating patterns 340 are provided on the same side of the transparent sheet 202. Each electroconductive pattern 100 is formed on each insulating pattern 340, and more specifically, formed so as to step over the first electrode 300 and the insulating pattern 340. In
The first electrode 300 and the second electrode 320 are formed on the surface of the base 200. The first electrode 300 in this embodiment is configured by a plurality of rectangular (rhombic) first electrode patterns 310 connected in succession with the narrower interconnects 312. in the Y-direction, a plurality of rectangular (rhombic) second electrode patterns 330 are discretely arranged to form an assembly. The adjacent second electrode patterns 330 arrayed in the Y-direction are electrically and physically connected through the electroconductive patterns 100. The insulating patterns 340 isolate the electroconductive patterns 100 from the first electrode 300. The electroconductive pattern 100 may have an unillustrated protective film formed thereon by coating.
For the transparent sheet 202, film materials such as highly transparent PET (polyethylene terephthalate) film, polycarbonate film and transparent polyimide film; and thin sheet type glass substrate may be used. The transparent sheet 202 is not specifically limited in terms of thickness, so long as it is flexible. The transparent sheet 202 may have a coated layer formed on the surface thereof, for the purpose of improving adhesiveness to the first electrode 300 and the second electrode 320, and uniformity of coating.
The insulating patterns 340 are obtained typically by preparing an ink or paste using a highly transparent resin material, forming a desired pattern using it by a technique such as ink-jet printing or screen printing, and allowing the pattern to dry or cure by heating or UV irradiation.
The first electrode patterns 310 and the second electrode patterns 330 have transparency and electrical conductivity, and have a sensing function which allows determination of point(s) where the finger(s) of the user came close to, based on changes in electrostatic capacitance which locally changes at the point(s).
The first electrode pattern 310 and second electrode pattern 330 are composed of any of transparent and electroconductive metal materials or resin materials. Examples of the material include metal oxide-based materials represented by ITO (tin-doped indium oxide), ATO (antimony-doped tin oxide) and FTC) (fluorine-doped tin oxide); transparent electroconductive polymer-based materials represented by PEDOT, polypyrrole and polyaniline; and nanowire-based materials having electroconductive nanowires scattered to form an irregular network pattern on the base 200, fixed in a resin. Materials for composing the electroconductive nanowires are exemplified by silver, metal alloy and carbon.
The draw-out lines 260 are metallized interconnects for transmitting position detection signals output from the first electrode patterns 310 and the second electrode patterns 330, to an external board or circuit. The draw-out lines 260 are formed by patterning a sputtered metal foil typically by a photolithographic technique, or formed pattern-wise using an electroconductive paste or ink by a printing technique such as screen printing, gravure printing or flexographic printing.
The insulating patterns 340 electrically isolate the electroconductive patterns 100 from the underlying first electrode patterns 310. The insulating patterns 340 prevent the second electrode patterns 330 and the first electrode patterns 310 from electrically conducting through the electroconductive patterns 100. The insulating patterns 340 have a band form wider in width than the interconnects 312, and extend in the direction (X-direction) in which the first electrode 300 is arrayed. The directions in which the insulating patterns 340 and the electroconductive patterns 100 respectively extend cross each other. As illustrated in
Also the electroconductive patterns 100 are preferably transparent, in order to satisfy requirements on transparency of the touch panel sensor sheet 250. For the electroconductive patterns 100, usable is a PEDOT paste which is configured by PEDOT (polyethylene dioxythiophene), a kind of transparent electroconductive polymer-based materials, modified to be adaptive to screen printing.
According to the present method, narrow-width and high-quality electroconductive patterns 100 may be formed, even if the wettability of the electroconductive patterns 100 differs from part to part on the underlying layer, for example on the second electrode patterns 330, the insulating patterns 340 and the transparent sheet 202.
As illustrated in
The electroconductive patterns 100 which compose the jumper patterns may have a form of single line, a form of a plurality of parallel lines, and any other form.
At boundary zones 240 between the first underlying areas 210 and the second underlying area 220, the electroconductive pattern 100 is widened as compared with intermediate zones 212, 222 of the first underlying areas 210 and the second underlying area 220, respectively. In other words, electroconductive patterns 110 formed at the boundary zones 240 have a width larger than that of the electroconductive pattern 112 formed in the intermediate zone 212 of the first underlying area 210 and in the intermediate zone 222 of the second underlying area 220. In this way, the electroconductive pattern 100 may be relieved from the risk of adhesion failure at the boundary zones 240 where properties of the surface of the underlying layer change, thereby generally improving the adhesiveness and electrical connection between the base 200 and the electroconductive patterns 100. When the electroconductive pattern 110 is widened over the electroconductive pattern 112, the number of through-holes 30 arrayed in the widthwise direction of the line pattern 20 may be increased, or the diameter of the individual through-holes 30 may be enlarged.
The first underlying areas 210 and the second underlying area 220 in this embodiment are contiguously formed, without leaving gaps in between, as illustrated in
The present invention will now be further detailed referring to Examples.
The electroconductive patterns were formed using each of the screen printing plates 10 having the single-row line pattern (referred to as single-row pattern, hereinafter) illustrated in
The electroconductive patterns were aimed to be linear with a target length of 1000 μm or longer, and a target width of 100 μm to 200 μm or around. For the single-row pattern, eight consecutive through-holes were provided with a diameter Dd of 100 μm and a linewise pitch Pd of 130 μm. For the double-row pattern, ten consecutive through-holes 30 were provided in the linewise direction, with a diameter Dd of 100 μm, a linewise pitch Pd of 130 μm, and a widthwise pitch Pw of 60 μm.
The ink used herein was a PEDOT paste prepared by mixing an aqueous dispersion of a PEDOT-PSS mixture, with a polyolefin resin as a binder, and ethylene glycol as the other additive. The PEDOT paste was adjusted to have a viscosity of 100 cP or above and 1000 cP or below. More specifically, a common PEDOT paste with a viscosity of 1000 cP was used in Example 1 to Example 4 below. The PEDOT paste was found to show a surface tension of liquid surface of 42 mN/m. The viscosity and surface tension of the PEDOT paste were measured at a normal temperature of 23° C. The viscosity of the PEDOT paste may be measured in compliance with JIS Z0803. The surface tension of the PEDOT paste may be measured by the ring method specified by JIS K2241.
A transparent electroconductive film was manufactured by scattering, on a PET film, silver nanowires to form an irregular network pattern, followed by fixation, to thereby produce an electroconductive underlying layer. On the other hand, as the insulating underlying layer, a highly-transparent resin paste was applied by printing onto a PET film by applying by printing, with the surface of which remained without adhesion enhancing treatment, the paste was then dried under heating to thereby for a coated film of approximately 3 μm thick.
On the electroconductive underlying layer and insulating underlying layer, the ink was respectively coated through the screen printing plates with the single-row pattern and the double-row pattern described above, to thereby form the electroconductive patterns. Example 1 relates to the electroconductive pattern formed through the single-row pattern onto the electroconductive underlying layer, and Example 2 relates to the electroconductive pattern formed through the single-row pattern onto the insulating underlying layer. Example 3 relates to the electroconductive pattern formed through the double-row pattern onto the electroconductive underlying layer, and Example 4 relates to the electroconductive pattern formed through the double-row pattern onto the insulating underlying layer.
It was found from Examples above that the linear, narrow-width electroconductive patterns were successfully formed using whichever of the single-row pattern and the double-row pattern, by electing the PEDOT paste to form the discrete ink dots, and then allowing the ink dots to fuse with each other to form a linear ink puddle. In particular from the results of Examples 3 and 4, it was found that, by using the multi-row line pattern, the linear electroconductive patterns with the target dimensions were successfully formed, not only on the electroconductive underlying layer with a good wettability to the PEDOT paste, but also on the insulating underlying layer with a poor wettability.
By coating the ink respectively on the electroconductive underlying layer and the insulating underlying layer, which largely differ in wettability to the water-based ink, the electroconductive patterns having close values of width were formed. More specifically, the line width in Example 1 was approximately 130 μm, and the line width in Example 2 was approximately 90 μm, which was approximately 70% of the line width in Example 1. It is understood from the results that, when the narrow-width electroconductive patterns 100 of 100 μm wide or around are formed so as to extend over both of the electroconductive underlying layer and the insulating underlying layer, the linear electroconductive patterns are successfully formed without disconnection, by coating the PEDOT paste so as to form consecutive dots.
While the PEDOT was used in Example 1 and Example 2 above, the principle of the present invention is also applicable to the case where any other water-dispersed electroconductive paste is used as the ink. While the underlying layers on which the ink is coated were exemplified by the electroconductive underlying layer and the insulating underlying layer, the present invention is not limited thereto. It is to be understood that the present invention is preferably used also when the linear electroconductive patterns are formed so as to extend over the electroconductive underlying layers having different levels of wettability, or over both of the insulating underlying layers having different levels of wettability.
The embodiments and Examples described above also embrace the technical ideas below.
(1) A method of manufacturing a circuit board, the method includes: establishing stand-by by setting a screen printing plate so as to be opposed with a base, the screen printing plate having a line pattern formed therethrough, and the line pattern being configured by a plurality of dot-like through-holes discretely pierced and arrayed in a single line or in a plurality of lines; coating an ink which contains a water-dispersed electroconductive paste onto the surface of the screen printing plate;
ejecting the ink through the dot-like through-holes onto the surface of the base, by pressing the screen printing plate onto the base under sliding contact of a squeegee with the surface of the screen printing plate, and allowing ink dots ejected out from the adjacent through-holes to fuse on the surface of the base, to thereby form a linear ink puddle; and drying the linear ink puddle to form an electroconductive pattern on the surface of the base.
(2) The method of manufacturing a circuit board of (1), wherein in the step of ejecting the ink, a portion of the ink, ejected from the through-hole and creeps forward in the direction of sliding contact of the squeegee into a gap between the screen printing plate and the base, is allowed to fuse with the ink dot(s) ejected cut through the other through-hole(s) adjacent in the direction of sliding contact.
(3) The method of manufacturing a circuit board of (1) or (2) implemented by using the screen printing plate having a line pattern formed therethrough, the line pattern being configured by a plurality of clot-like through-holes discretely pierced in a plurality of lines arrayed in the widthwise direction, wherein in the step of electing the ink, the ink dots ejected from the through-holes arrayed in the widthwise direction are allowed to fuse to form a single linear ink puddle.
(4) The method of manufacturing a circuit board of any one of (1) to (3), wherein the ink dot ejected from the through-hole is allowed to fuse with another ink dot, based on diffusion with the aids of wettability on the surface of the base and creepage on the back surface side of the through-hole.
(5) The method of manufacturing a circuit board of any one of (1) to (4), wherein Formula (1) below holds, with thickness Tm of the screen printing plate, diameter Dd of the through-hole, and center-to-center distance P1 of the through-holes adjacent in the travel direction of the squeegee:
2.5×Tm≧P1−Dd>0 Formula (1).
(6) The method of manufacturing a circuit board of any one of (1) to (5), wherein the water-dispersed electroconductive paste contains an organic electroconductive polymer dispersed in a water-based solvent.
(7) The method of manufacturing a circuit hoard of (6), wherein the organic electroconductive polymer is polyethylene dioxythiophene, polyaniline or polypyrrole.
(8) A circuit board which includes an electroconductive pattern composed of an organic electroconductive polymer, formed in a line pattern, the electroconductive pattern having dense areas and sparse areas alternately disposed repetitively in the longitudinal direction of the electroconductive pattern, the dense areas having, when counted in the widthwised direction, a large number of grains of the organic electroconductive polymer, and the sparse areas having a small number of grains.
(9) The circuit board of (8), wherein the electroconductive pattern has a widthwise dimension of 300 μm or smaller.
(10) The circuit board of (8) or (9), wherein the base has an electroconductive first underlying area and an insulating second underlying area, and the electroconductive pattern is contiguously formed so as to extend over the first underlying area and the second underlying area.
(11) The circuit board of (10), wherein the electroconductive pattern is widened at a boundary between the first underlying area and the second underlying area, as compared to that in an intermediate zone of the first underlying area or of the second underlying area.
(12) A touch panel sensor sheet which includes the circuit board described in (10) or (11), the base includes a flexible transparent sheet composed of a visible light transmissive material; and a first electrode and a second electrode which configure a first underlying area, and an insulating pattern which configures a second underlying area, both areas being formed on one surface of the transparent sheet, the first electrode containing a plurality of first electrode patterns arrayed repetitively in a first direction, the second electrode containing a plurality of second electrode patterns arrayed in a second direction which crosses the first direction, while being spaced from the first electrode patterns, the insulating pattern covering an interconnect between the adjacent first electrode patterns, and the electroconductive pattern configuring a jumper pattern which connects the adjacent second electrode patterns.
(13) A screen printing plate having a line pattern formed therethrough, the line pattern being configured by a plurality of dot-like through-holes discretely pierced and arrayed in a single line or in a plurality of lines.
(14) The screen printing plate of (13), configured as a metal mask having the line pattern formed in a substantially closed loop.
It is apparent that the present invention is not limited to the above embodiment, and may be modified and changed without departing from the scope and spirit of the invention.
Number | Date | Country | Kind |
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2012-251779 | Nov 2012 | JP | national |