1. Technical Field
The present disclosure relates to surface treating devices, and particularly, to a coating device.
2. Description of Related Art
Nano-films, such as zinc oxide (ZnO) nanostructures are usually synthesized by different kinds of technologies, such as ultrasonic spray pyrolysis or hydrothermal synthesis. Generally, an ultrasonic spray pyrolysis apparatus is only used in the ultrasonic spray pyrolysis coating process, and an autoclave is only used in the hydrothermal synthesis process. However, when a nano-film needs to be synthesized by both the above-mentioned two processes, workpieces need to be moved from the ultrasonic spray pyrolysis apparatus to the autoclave. This is inconvenient and can cause the workpieces to be contaminated.
Therefore, it is desirable to provide a new coating device, which can overcome the above-mentioned limitations.
Many aspects of the present disclosure should be better understood with reference to the following drawings. The components in the drawings are not necessarily drawn to scale, the emphasis instead being placed upon clearly illustrating the principles of the present disclosure. Moreover, in the drawings, like reference numerals designate corresponding parts throughout the several views.
Embodiments of the present disclosure will now be described in detail with reference to the drawings.
Referring to
The autoclave 100 includes an autoclave body 102 and a cover 104 covered on the top of the autoclave body 102. The autoclave body 102 includes a bottom plate 102a and a first side plate 102b extending upwards from the periphery of bottom plate 102a. The bottom plate 102a defines a feeding opening 102d. The feeding opening 102d communicates with a solution source (not shown). The inner surface of the first side plate 102b defines a number of holding grooves 102c configured for fixing a number of substrates (not shown). The first side plate 102b is thermally conductively connected to a heat source (not shown), thereby gaining heat from the heat source to heat the substrates and the solution (not shown) in the autoclave 100.
The cover 104 includes a top plate 104a and a second side plate 104b extending upwards from the periphery of the top plate 104a. The top plate 104a defines a shaft hole 104c at the center thereof. The inner diameter of the cover 104 substantially equals to the outer diameter of the autoclave body 102. When the cover 104 covers the autoclave body 102, the cover 104 substantially seals the autoclave body 102, thereby defining a coating cavity 106 therebetween.
The spray member 200 includes a spray body 210, four containers 220 positioned on the spray body 210, four ultrasonic atomization units 230 received in the four containers 220, and a fan unit 240 engaged with the spray body 210 and the containers 220.
The spray body 210 includes a first plate 212, a second plate 214, a third plate 216, and a fourth plate 218, each of which is cylindrical and stacked on its next plate in turn. The first plate 212 defines a first through hole 212a along the radial direction thereof. The first through hole 212a defines two first openings 212b on the two opposite sides of the first plate 212. The second plate 214, the third plate 216, and the fourth plate 218 each define a through hole therein in a same way as the first though hole 212a of the first plate 212, which are respectively indicated as a second through hole 214a, a third through hole 216a, and a fourth through hole 218a. Each of the second through hole 214a, the third through hole 216a, and the fourth through hole 218a defines two openings on two opposite sides of the corresponding plates, which are respectively indicated as a second opening 214b, a third opening 216b, and a fourth opening 218b. The first, second and third openings 212b, 214b, 216b face an inner surface of the autoclave body 102. The spray body 210 also defines a fifth through hole 219 spanning from the first plate 212 to the fourth plate 218 along the center axis thereof. The fifth through hole 219 communicates with the first through hole 212a, the second through hole 214a, the third through hole 216a, and the fourth through hole 218a. The fifth through hole 219 is threaded at a terminal portion close to the first plate 212.
The fan unit 240 includes a wind tube 242, four fans 244, and a supporting tube 246. The wind tube 242 includes four cylindrical tubes 242a which are joined together and forms a cross portion. Each of the cylindrical tubes 242a has an air outlet 2423 at the distal end, communicating with each other. A first connecting threaded hole 242b and a second connecting threaded hole 242c are defined at the center of two opposite sides of the cross portion. Each of the cylindrical tubes 242a defines a third connecting threaded hole 242d facing the spray body 210. The supporting tube 246 defines a pair of threaded portions at two ends thereof. Each fan 244 is positioned in the fan opening 2423. Wind is pumped into the wind tube 242 by the fans 244 and flows out from the first connecting threaded hole 242b.
The container 220 includes a box 222 and a connecting tube 224. The box 222 defines a cavity 222a therein and a fourth connecting thread hole 222b. The fourth connecting thread hole 222b communicates the cavity 222a to the outside of the box 222. Two ends of the connecting tube 224 are mated with the fourth connecting thread hole 222b and the third connecting thread hole 242d, to communicate the wind tube 242 with the container 220. The ultrasonic atomization units 230 are used for atomizing the solution. Each of the ultrasonic atomization units 230 is positioned in a respective one of the cavities 222a.
The actuator 300 includes a motor 302 and a shaft 304 engaged with and driven by the motor 302. The shaft 304 has a threaded end mated with the second connecting thread hole 242c. The motor 302 is mounted on the center of the top plate 104a of the cover 300, with the shaft 304 extending into the autoclave 100. The shaft 304 passes through the shaft hole 104c and screws into the second thread hole 242c. As such, the spray member 200 can be driven to rotate by the actuator 300.
In operation, the substrates are positioned in the holding grooves 102c. A solution, such as a solution made of Zn(acac)2 and methanol, is injected into each cavity 222a of the boxes 222 through the fourth connecting thread holes 222b. Then each of the connecting tubes 224 is screwed into the fourth connecting thread holes 222b and the third connecting thread hole 242d. Therefore, the containers 220 are fixed to the fan unit 240. After that, the supporting tube 246 is screwed into the first connecting thread hole 242b and the fifth through hole 219, so that the fan unit 240 is fixed to the spray body 210. The shaft 304 is screwed into the second connecting thread hole 242c, so that the spray member 200 is fixed to the actuator 300. Finally the cover 104 covers the autoclave body 102. As such, the spray member 200 is received in the coating cavity 106.
The ultrasonic atomization unit 230 emits an ultrasonic, with a frequency ranging from 2.4 kHz to 15 kHz for example, which atomizes the solution. The atomized solution flows into the wind tube 242 through the connecting tube 224. Meanwhile, the fans 244 pump wind into the wind tube 242. As such, the atomized solution is blown into the coating cavity 106 from those openings or holes 219, 212a, 212b, 214a, 214b, 216a, 216b, 218a and 218b. The actuator 300 rotates the spray member 200, so that the atomized solution evenly deposits on the surfaces of the substrates. The heat source heats the first side plate 102b evenly at very beginning to heat the substrates up to a working temperature, for example about 350 degrees centigrade. In this situation, the atomized solution disposes on the surfaces of the substrates to form a first film thereon. It is known that film formed by spray pyrolysis coating method is relatively more uniform than film formed by hydrothermal coating method, therefore, the first film could be used as a base for forming a second film.
After the first film is formed, the spray member 200 and the actuator 300 stop working. A solution, such as solution made of Zn(acac)2 and methanol is injected into the autoclave 100 from the solution source through the feeding opening 102d. The heat source just heats one side of the first side plate 102b, so that the solution is heated up to a working temperature, for example about 95 degrees centigrade. As just one side of the first side plate 102b is heated, the temperature of the solution near this side would raise faster than the solution at the other side that is opposite to the side being heated. Therefore, a temperature difference occurs between two opposite sides of the solution, which induces convection in the solution. During the convection, the solution is supersaturated, and the solute crystallizes out from the solution and accretes on the first film/seed to grow a second film that is desired, such as ZnO nanostructures.
When using the coating device 10 disclosed in the present embodiment, substrates can be coated by spray pyrolysis coating method and hydrothermal coating method. As such, transferring of substrates between different coating devices is avoided. Therefore, contamination has little chance to enter into the processing chamber to pollute the substrates, thereby improving the coating quality. Meanwhile, as the first film is relatively uniform and can be used as a base, the second film formed based on the first film will be more uniform compared to a film formed without the first film.
The container 220 is configured for forming a cavity 222a communicating with the first opening 212b, the second opening 214b, the third opening 216b, and the fourth opening 218b, which allows the atomized solution to flow onto the surfaces of substrates. It should be understood that the containers 220 are not limited to this embodiment. In alternative embodiments, different configurations and numbers of container may be utilized.
The actuator 300 is configured for rotating the spray member 200, so that the atomized solution can be sprayed on a number of substrates positioned around the coating cavity 106. It should be understood that in alternative embodiments, when all the substrates could be sprayed with the atomized solution without rotating the spray member 200, the actuator 300 could be omitted.
The fan unit 240 is configured for accelerating the flow of the atomized solution. As the atomized solution will diffuse itself, it should be understood that in alternative embodiments, the fan unit 240 might be omitted. In this condition, the containers 220 may communicate with the spray body 210.
It will be understood that the above particular embodiments is shown and described by way of illustration only. The principles and the features of the present disclosure may be employed in various and numerous embodiment thereof without departing from the scope of the disclosure as claimed. The above-described embodiments illustrate the scope of the disclosure but do not restrict the scope of the disclosure.
Number | Date | Country | Kind |
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99103993 A | Feb 2010 | TW | national |
Number | Name | Date | Kind |
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5219120 | Ehrenberg et al. | Jun 1993 | A |
8336485 | Pei | Dec 2012 | B2 |
Number | Date | Country |
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1766163 | May 2006 | CN |
Number | Date | Country | |
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20110192346 A1 | Aug 2011 | US |